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At least 1,297 records · Page 72Linked to original sources
USGS2004

Calculation of individual isotope equilibrium constants for geochemical reactions

Theory is derived from the work of Urey (Urey H. C. [1947] The thermodynamic properties of isotopic substances. J. Chem. Soc . 562–581) to calculate equilibrium constants commonly used in geochemical equilibrium and reaction-transport models for reactions of individual isotopic species. Urey showed that equilibrium constants of isotope exchange reactions for molecules that contain two or more atoms of the same element in equivalent positions are related to isotope fractionation factors by α = (K ex ) 1/n , where n is the number of atoms exchanged. This relation is extended to include species containing multiple isotopes, for example 13 C 16 O 18 O and 1 H 2 H 18 O. The equilibrium constants of the isotope exchange reactions can be expressed as ratios of individual isotope equilibrium constants for geochemical reactions. Knowledge of the equilibrium constant for the dominant isotopic species can then be used to calculate the individual isotope equilibrium constants. Individual isotope equilibrium constants are calculated for the reaction CO 2g = CO 2aq for all species that can be formed from 12 C, 13 C, 16 O, and 18 O; for the reaction between 12 C 18 O 2aq and 1 H 2 18 O l ; and among the various 1 H, 2 H, 16 O, and 18 O species of H 2 O. This is a subset of a larger number of equilibrium constants calculated elsewhere (Thorstenson D. C. and Parkhurst D. L. [2002] Calculation of individual isotope equilibrium constants for implementation in geochemical models. Water-Resources Investigation Report 02-4172. U.S. Geological Survey). Activity coefficients, activity-concentration conventions for the isotopic variants of H 2 O in the solvent 1 H 2 16 O l , and salt effects on isotope fractionation have been included in the derivations. The effects of nonideality are small because of the chemical similarity of different isotopic species of the same molecule or ion. The temperature dependence of the individual isotope equilibrium constants can be calculated from the temperature dependence of the fractionation factors. The derivations can be extended to calculation of individual isotope equilibrium constants for ion pairs and equilibrium constants for isotopic species of other chemical elements. The individual isotope approach calculates the same phase isotopic compositions as existing methods, but also provides concentrations of individual species, which are needed in calculations of mass-dependent effects in transport processes. The equilibrium constants derived in this paper are used to calculate the example of gas-water equilibrium for CO 2 in an acidic aqueous solution.

Geochimica et Cosmochimica Acta↗
USGS2006

Gas-water-rock interactions in sedimentary basins: CO2 sequestration in the Frio Formation, Texas, USA

To investigate the potential for the geologic storage of CO2 in saline sedimentary aquifers, 1600??ton of CO2 were injected at ???1500 m depth into a 24-m sandstone section of the Frio Formation - a regional reservoir in the US Gulf Coast. Fluid samples obtained from the injection and observation wells before, during and after CO2 injection show a Na-Ca-Cl type brine with 93,000??mg/L TDS and near saturation of CH4 at reservoir conditions. As injected CO2 gas reached the observation well, results showed sharp drops in pH (6.5 to 5.7), pronounced increases in alkalinity (100 to 3000??mg/L as HCO3) and Fe (30 to 1100??mg/L), and significant shifts in the isotopic compositions of H2O and DIC. Geochemical modeling indicates that brine pH would have dropped lower, but for buffering by dissolution of calcite and Fe oxyhydroxides. Post-injection results show the brine gradually returning to its pre-injection composition. ?? 2006 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗
USGS2012

Landslides in Valles Marineris, Mars

Large landslides in the Martian equatorial troughs have been investigated with respect to morphology, geologic structure of the troughs, time of emplacement, similarity to terrestrial landslides, and origin and mechanism of transport. Viking Orbiter images provided a base for morphologic analyses, mapping, crater counts, and volumetric considerations. Results showed that the morphologic variations of the landslides can be attributed mainly to their degree of confinement on trough floors. Many prominent landslides appear to be of similar age and were emplaced after a major episode of faulting that created scarps of great relief. Most sliding apparently occurred after these scarps were dissected into spurs, gullies, and tributary canyons. Much of the slide activity coincided with a major late eruptive phase of the Tharsis volcanoes, as deduced from the crater density, over the total deposit area, of 570±130 craters larger than 1 km in diameter per 10 6 km 2 . The huge size of many landslides is due to their occurrence on fault scarps that may have attained several kilometers in height in the absence of vigorous fluvial erosion on Mars. The mechanical efficiency of the Martian landslides is high but in accord with predictions from large landslides on earth. The slides may have originated as gigantic mudflows with slump blocks at their heads; water that may have existed in aquifers in the wallrock below and behind a lid of ice may have been liberated through minor disturbances from Marsquakes. Liquefaction and collapse of extensive wall sections may then have ensued, and the debris rushed out onto the trough floors at speeds exceeding 100 km/h.

Journal of Geophysical Research Solid Earth↗
USGS2014

Notes on the relation between the moisture‐equivalent and the specific retention of water‐bearing materials

The moisture‐equivalent and specific retention have been widely used as quasi‐physical constants to measure the power of a water‐bearing material or a soil to retain water against gravitative force. Comparatively little has been demonstrated, however, as to the relation of one to the other. This paper is a preliminary statement of the apparent relation between these two measures of retentive power and is based on a study of alluvial materials made in connection with an investigation by the United States Geological Survey into the ground‐water resources of the Mokelumne Area, central California.

California↗
USGS2004

Evaluation of multidimensional transport through a field-scale compacted soil liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br - "> Br - from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br - "> Br - LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of k sat ⩽ 1 × 10 - 7 cm / s ; "> k sat ⩽ 1 × 10 − 7 cm / s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.

Journal of Geotechnical and Geoenvironmental Engin↗
USGS2014

Calibration of a conodont apatite-based Ordovician 87 Sr/ 86 Sr curve to biostratigraphy and geochronology: Implications for stratigraphic resolution

The Ordovician 87 Sr/ 86 Sr isotope seawater curve is well established and shows a decreasing trend until the mid-Katian. However, uncertainties in calibration of this curve to biostratigraphy and geochronology have made it difficult to determine how the rates of 87 Sr/ 86 Sr decrease may have varied, which has implications for both the stratigraphic resolution possible using Sr isotope stratigraphy and efforts to model the effects of Ordovician geologic events. We measured 87 Sr/ 86 Sr in conodont apatite in North American Ordovician sections that are well studied for conodont biostratigraphy, primarily in Nevada, Oklahoma, the Appalachian region, and Ohio Valley. Our results indicate that conodont apatite may provide an accurate medium for Sr isotope stratigraphy and strengthen previous reports that point toward a significant increase in the rate of fall in seawater 87 Sr/ 86 Sr during the Middle Ordovician Darriwilian Stage. Our 87 Sr/ 86 Sr results suggest that Sr isotope stratigraphy will be most useful as a high-resolution tool for global correlation in the mid-Darriwilian to mid-Sandbian, when the maximum rate of fall in 87 Sr/ 86 Sr is estimated at ∼5.0–10.0 × 10 –5 per m.y. Variable preservation of conodont elements limits the precision for individual stratigraphic horizons. Replicate conodont analyses from the same sample differ by an average of ∼4.0 × 10 –5 (the 2σ standard deviation is 6.2 × 10 –5 ), which in the best case scenario allows for subdivision of Ordovician time intervals characterized by the highest rates of fall in 87 Sr/ 86 Sr at a maximum resolution of ∼0.5–1.0 m.y. Links between the increased rate of fall in 87 Sr/ 86 Sr beginning in the mid-late Darriwilian ( Phragmodus polonicus to Pygodus serra conodont zones) and geologic events continue to be investigated, but the coincidence with a long-term rise in sea level (Sauk-Tippecanoe megasequence boundary) and tectonic events (Taconic orogeny) in North America provides a plausible explanation for the changing magnitude and 87 Sr/ 86 Sr of the riverine Sr flux to the oceans.

GSA Bulletin↗
USGS2015

Late Quaternary slip history of the Mill Creek strand of the San Andreas fault in San Gorgonio Pass, southern California: The role of a subsidiary left-lateral fault in strand switching

The fault history of the Mill Creek strand of the San Andreas fault (SAF) in the San Gorgonio Pass region, along with the reconstructed geomorphology surrounding this fault strand, reveals the important role of the left-lateral Pinto Mountain fault in the regional fault strand switching. The Mill Creek strand has 7.1–8.7 km total slip. Following this displacement, the Pinto Mountain fault offset the Mill Creek strand 1–1.25 km, as SAF slip transferred to the San Bernardino, Banning, and Garnet Hill strands. An alluvial complex within the Mission Creek watershed can be linked to palinspastic reconstruction of drainage segments to constrain slip history of the Mill Creek strand. We investigated surface remnants through detailed geologic mapping, morphometric and stratigraphic analysis, geochronology, and pedogenic analysis. The degree of soil development constrains the duration of surface stability when correlated to other regional, independently dated pedons. This correlation indicates that the oldest surfaces are significantly older than 500 ka. Luminescence dates of 106 ka and 95 ka from (respectively) 5 and 4 m beneath a younger fan surface are consistent with age estimates based on soil-profile development. Offset of the Mill Creek strand by the Pinto Mountain fault suggests a short-term slip rate of ∼10–12.5 mm/yr for the Pinto Mountain fault, and a lower long-term slip rate. Uplift of the Yucaipa Ridge block during the period of Mill Creek strand activity is consistent with thermochronologic modeled uplift estimates.

Geological Society of America Bulletin↗
USGS2006

Gas-water-rock interactions in Frio Formation following CO 2 injection: Implications for the storage of greenhouse gases in sedimentary basins

To investigate the potential for the geologic storage of CO 2 in saline sedimentary aquifers, 1600 t of CO 2 were injected at 1500 m depth into a 24-m-thick sandstone section of the Frio Formation, a regional brine and oil reservoir in the U.S. Gulf Coast. Fluid samples obtained from the injection and observation wells before CO 2 injection showed a Na-Ca-Cl–type brine with 93,000 mg/L total dissolved solids (TDS) at near saturation with CH 4 at reservoir conditions. Following CO 2 breakthrough, samples showed sharp drops in pH (6.5–5.7), pronounced increases in alkalinity (100–3000 mg/L as HCO 3 ) and Fe (30–1100 mg/L), and significant shifts in the isotopic compositions of H 2 O, dissolved inorganic carbon (DIC), and CH 4 . Geochemical modeling indicates that brine pH would have dropped lower but for the buffering by dissolution of carbonate and iron oxyhydroxides. This rapid dissolution of carbonate and other minerals could ultimately create pathways in the rock seals or well cements for CO 2 and brine leakage. Dissolution of minerals, especially iron oxyhydroxides, could mobilize toxic trace metals and, where residual oil or suitable organics are present, the injected CO 2 could also mobilize toxic organic compounds. Environmental impacts could be major if large brine volumes with mobilized toxic metals and organics migrated into potable groundwater. The δ 18 O values for brine and CO 2 samples indicate that supercritical CO 2 comprises ∼50% of pore-fluid volume ∼6 mo after the end of injection. Postinjection sampling, coupled with geochemical modeling, indicates that the brine gradually will return to its preinjection composition.

Geology↗
USGS1985

A nomogram for interpreting slope stability of fine-grained deposits in modern and ancient-marine environments.

Design of the nomogram is based on effective stress and combines consolidation theory as applicable to depositional environments with the infinite-slope model of slope-stability analysis. The link between the two combined theories is a term representing the effective overburden stress, which may be predicted from consolidation theory and a knowledge of sedimentation rate, time, and the coefficient of consolidation. In turn, if infinite-slope conditions are assumed to exist, the effective overburden stress can be used to derive a factor of safety against static slope failure by using the angle of internal friction and the slope angle. The nomogram applies to depostitional settings in which fine-grained sediment has accumulated at a relatively constant rate upon a base that is essentially impermeable. The model further assumes that the lateral extent of sediment affected by any mass movement will be great compared to its thickness and that no outside agents (e.g., cements, gas) are influencing the section. The nomogram is applicable to static conditions (inherent stability of the slope) and certain dynamic conditions (such as earthquakes). It may be used to investigate mass movements in the geologic past as well as those in modern environments.--Modified journal abstract.

Journal of Sedimentary Petrology↗
USGS1975

Stratigraphy of Atlantic coastal margin of United States north of Cape Hatteras: Brief survey

A synthesis of studies of sea-floor outcrops of the sedimentary wedge beneath the northeastern United States continental shelf and slope and a reassessment of coastal plain Mesozoic stratigraphy, particularly of the coastal margin, provide insight for estimating the oil and gas potential and provide geologic control for marine seismic investigations of the Atlantic continental margin. The oldest strata known to crop out on the continental slope are late Campanian in age. The Cretaceous-Tertiary contact along the slope ranges from a water depth of 0.6 to 1.5 km south of Georges Bank to 1.8 km in Hudson Canyon. Few samples are available from Tertiary and Late Cretaceous outcrops along the slope. Sediments of the Potomac Group, chiefly of Early Cretaceous age, constitute a major deltaic sequence in the emerged coastal plain. This thick sequence lies under coastal Virginia, Maryland, Delaware, southeastern New Jersey, and the adjacent continental shelf. Marine sands associated with this deltaic sequence may be present seaward under the outer continental shelf. South of the Norfolk arch, under coastal North Carolina, carbonate rocks interfinger with Lower Cretaceous clastic strata. From all available data, Mesozoic correlations in coastal wells between coastal Virginia and Long Island have been revised. The Upper-Lower Cretaceous boundary is placed at the transition between Albian and Cenomanian floras. Potential hydrocarbon source beds are present along the coast in the subsurface sediments of Cretaceous age. Potential reservoir sandstones are abundant in this sequence.

Atlantic coastal plain↗
USGS1946

Preliminary chemical correlation of chromite with the containing rocks

Chromite investigations of the U. S. Geological Survey since 1939 indicate that economic deposits of chromite rich in normative spinel ((Mg, Fe)Al 2 O 4 ) occur in peridotites which are closely associated with gabbro; high-chrome chromites occur in feldspar-free peridotites; and chromites rich in both normative chromite ((Mg, Fe)Cr 2 O 4 ) and magnetite (FeFe 2 O 4 ) are found in the pyroxene-rich stratiform complexes. Reaction of high-alumina chromite with diopsidic gabbro to form anorthite, olivine, and enstatite is described, and some probable equilibria between chromite and silicate minerals are discussed. A plot of 63 complete analyses on a triangular prism of composition shows that chromites from different geologic provinces in the Western Hemisphere vary consistently and fall in overlapping, but distinct, fields. The chromites of the Caribbean Province, which occur in dunite and troctolite, have the general formula Cr (sub 25-80) Al (sub 15-75) Fe (sub 1-5) (Mg (sub 65-75) ) and average about Cr 50 Al 47 (Mg 70 ). The chromites of the Pacific Coast, which occur in dunite and saxonite, average about Cr 70 Al 24 (Mg 60 ) in the range Cr (sub 60-77) Al (sub 16-35) Fe (sub 3-12) (Mg (sub 45-75) ). The stratiform deposits of the Stillwater and Bushveld complexes occur in harzburgite and bronzitite, and are very much alike, averaging Cr 60 Al 32 (Mg 52 ) and Cr 58 Al 34 (Mg 44 ) respectively. Chromites from gabbroic facies of the Bushveld complex are much richer in normative magnetite, presumably reflecting a higher CaO: Al 2 O 3 ratio in the silicate environment.

Economic Geology↗
USGS1993

Nonfuel mineral resources in the United States-Mexico border region: A progress report on information available from the Center for Inter-American Mineral Resource Investigations (CIMRI)

The exploitation of minerals has played a significant role in population growth and development of the U.S.Mexico border region. Recent proposed changes in regulations related to mining in the United States and changes in mining and investment regulations in Mexico have led to increased mineral exploration and development in Mexico, especially in the border region. As a preliminary step in the study of the mineral industry of this area, the Center for Inter-American Mineral Resource Investigations (CIMRI) of the U.S. Geological Survey has compiled mine and occurrence data for nonfuel minerals in the border region. Analysis of this information indicates that a wide variety of metallic and industrial mineral commodities are present which can be used in agriculture, infrastructure, environmental improvement, and other industries. Therefore, mining will continue to play a significant role in the economy of this region.

Circular↗
USGS1998

Water quality in the central Columbia Plateau, Washington and Idaho, 1992-95

Water quality in the Central Columbia Plateau of eastern Washington and western Idaho has been adversely affected by agriculture, especially in irrigated areas, according to the results of a five-year investigation by the U. S. Geological Survey (USGS). Some improvements, however, are noticeable, such as less sediment being washed into streams. These improvements may be the result of increased use of best management practices (BMPs) by area farmers. Areas with intensive fertilizer use and irrigation, such as in the Columbia Basin Irrigation Project (CBIP), showed the greatest impacts on ground-water quality. (The CBIP includes parts of Franklin, Grant, and Adams counties in eastern Washington.) <Shallow wells, generally those less than 150 feet deep, are the most susceptible to contamination, the USGS report says. A reassuring aspect of this finding, however, is that many public water supplies draw from wells at greater depths and are less susceptible to contamination from agricultural practices. From the standpoint of human health, we were most concerned about checking for nitrate and pesticides in drinking water,' said Sandy Williamson, USGS hydrologist and chief of the study. 'We found nitrate levels exceeding the maximum contaminant level in about 20 percent of all wells.' (A maximum contaminant level-or MCL-is a drinking water regulatory standard that is set by the U.S. Environmental Protection Agency.) 'The story on pesticides is a mixed bag,' Williamson said. 'We found at least one pesticide in nearly half of the drinking water wells sampled, but pesticide levels were only a very small fraction of their MCLs.' As a cautionary note, however, Williamson said that about half of the pesticides detected in Central Columbia Plateau wells do not have MCLs established. A lack of information makes it difficult to assess the significance of finding pesticides in drinking water. 'As scientists, we don't know enough yet about what happens when these pesticides are combined,' he said. 'In some of the very shallow wells that the USGS installed for monitoring purposes, we found up to seven different pesticides.' Encouraging news is that none of the newer pesticides, which break down more rapidly in the environment, were found at concentrations exceeding MCLs. Compounds that exceed drinking water standards were found in only 1 percent of the wells sampled-and those compounds have not been sold as pesticides since the mid-1980s. However, agricultural impacts on water quality go beyond the concerns for drinking water-the aquatic ecosystem of the plateau also has been significantly affected. 'Very little surface water is used for drinking water in this area, but fish are harmed by decreased stream-water quality,' said Mark Munn, the biologist for the USGS study. 'Pesticides and habitat degradation are the main concerns.' He noted that stream sampling by the USGS showed seven currently used pesticides at concentrations above the limits recommended for protecting aquatic life. Soil erosion, a long-term problem for farmers in the Palouse River Basin, transports some soil to streams, degrading habitat and carrying with it older pesticides and their breakdown products. A breakdown product of the banned insecticide DDT was found in both streambed sediment and bottom fish at concentrations exceeding guidelines for the protection of aquatic life. 'Another problem for fish habitat is excessive plant growth caused by high levels of nutrients in streams,' said Munn, who explained that these nutrients enter streams in runoff from agricultural fields and discharge from urban wastewater treatment plants. Some agricultural practices, such as allowing cattle to graze near streams, are associated with higher rates of erosion. However, increased use of BMPs may improve water quality of the plateau. The USGS study showed that use of sprinkler or drip rather than furrow irrigation has decreased soil erosion in the CBIP area. In the Palouse, erosion

Circular↗
USGS2013

Challenge theme 5: Current and future needs of energy and mineral resources in the Borderlands and the effects of their development: Chapter 7 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

Exploration and extraction activities related to energy and mineral resources in the Borderlands—such as coal-fired power plants, offshore drilling, and mining—can create issues that have potentially major economic and environmental implications. Resource assessments and development projects, environmental studies, and other related evaluations help to understand some of these issues, such as power plant emissions and the erosion/denudation of abandoned mine lands. Information from predictive modeling, monitoring, and environmental assessments are necessary to understand the full effects of energy and mineral exploration, development, and utilization. The exploitation of these resources can negatively affect human health and the environment, its natural resources, and its ecological services (air, water, soil, recreation, wildlife, etc.). This chapter describes the major energy and mineral issues of the Borderlands and how geologic frameworks, integrated interdisciplinary (geobiologic) investigations, and other related studies can address the anticipated increases in demands on natural resources in the region.

United States-Mexico Borderlands↗
USGS1953

Chemical quality of water and sedimentation in the Moreau River drainage basin, South Dakota

This report gives the results of an investigation by the U. S. Geological Survey of the sediments and dissolved minerals that are transported by the Moreau River. The Moreau River drainage basin is a narrow basin in northwestern South Dakota that covers about 5, 360 square miles of rolling, grassy plains, which are broken by buttes and by some small areas of badlands. It is underlain by shales, sandstones, siltstones, and limestones that are primarily of Cretaceous age. Precipitation averages about 16 inches per year. Average annual runoff is about 0. 7 inch but varies widely from year to year.

South Dakota↗
USGS2002

Escherichia coli in the swash zone at four Ohio bathing beaches

The zone of the shoreline that is constantly washed by waves or tides, called the swash zone, is an attractive recreational area, especially for children who play in the sand. The swash zone, however, has been suggested as a possible habitat for waterborne disease-causing microorganisms (pathogens). The spaces between the sand grains, or interstices, offer habitats that may support the survival of certain bacterial, viral, and protozoan pathogens (U.S. Environmental Protection Agency, 1999). To investigate this possibility, the U.S. Geological Survey (USGS) determined the distribution of Escherichia coli ( E. coli ) in subsurface sediments and interstitial waters collected from near the swash zone at three Lake Erie urban beaches and one inland lake during the recreational seasons of 2000 and 2001. Water and lake-bottom sediment samples were also collected within the bathing areas and were analyzed for E. coli ; these bathing-water data were compared to swash-zone data to determine whether swash-zone materials were enriched with E. coli .

Ohio↗