SEARCH · USGS Science

Results for “Chemistry”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,297 records · Page 72Linked to original sources

USGS1997

Relation of hydrogeologic characteristics to distribution of radioactivity in ground water, Newark Basin, New Jersey

The distribution of radioactivity in ground water in the Newark Basin is controlled by the lithology of the aquifer and the degree of contact between the water that flows through the fractured strata and the radioactive lithologic units. The primary water-bearing lithologic units of the Newark Basin that contain elevated levels of radioactivity are the arkosic sandstones of the Stockton Formation and the black mudstones of the lower part of the Passaic Formation. Lithologic and hydrogeologic characteristics of these rock aquifers that affect the spatial distribution of radionuclides in the water include the concentration of radioactive minerals in the strata; the continuity of radioactive strata; the orientation, depth, interconnectedness, and continuity of regional and local fracture patterns; and the geochemical environment, which affects radionuclide solubility. The stratigraphic zones of uranium enrichment and the continuity of the radioactive strata differ between the Stockton Formation and the lower part of the Passaic Formation. Uranium enrichment in both formations, however, is identified in permeable sections of strata that have sharp contacts with, or that are enclosed by, less permeable zones. In the Stockton Formation, basal conglomerates overlying fine-grained mudstones are the most radioactive lithology. In interbedded red and black mudstones of the lower part of the Passaic Formation, the uranium-rich zones are the black and white carbonate-rich siltstone and mudstone laminae overlying massive fine-grained mudstones. Most samples of the arkosic sandstones of the Stockton Formation tended to be slightly enriched in uranium relative to thorium, whereas all samples of the black mudstones of the lower part of the Passaic Formation were heavily enriched in uranium with respect to thorium, with a maximum concentration of uranium of 6,200 parts per million (ppm). Spatial orientation of radioactive zones is controlled by the depositional environment of the host lithology. Radioactive strata in the arkosic sandstones of the Stockton Formation, which is deltaic or fluvial/deltaic in origin, arc stratigraphically discontinuous and nonplanar. In contrast, the radioactive lacustrine black mudstones of the lower part of the Passaic Formation are laterally continuous and planar. Geophysical logs of boreholes indicate that the number and depths of probable waterbearing fractures are greater in the arkoses of the Stockton Formation and red mudstones of the lower part of the Passaic Formation than in the interbedded red and black mudstones of the lower part of the Passaic Formation, despite the fact that fracture-density counts in cores indicate that black mudstones are more highly fractured than the other rock types. The total number of fractures is greater and bedding-plane fractures are generally more common in the lower part of the Passaic Formation than in the Stockton Formation. Fractures in the Stockton Formation form a well-connected network consisting of both bedding-plane and several sets of high-angle fractures present on a regional scale. The large-scale continuity of interconnected bedding-plane fractures and high-angle regional fractures may be partly responsible for the higher yields observed for wells in the Stockton Formation than for wells in the Passaic Formation and may facilitate migration of dissolved radionuclides far from their source. The well-connected fracture network may increase the likelihood that circulating water comes in contact with radioactive strata. Water in the black mudstones of the lower part of the Passaic Formation may also contain high levels of radioactivity, primarily as a result of the high frequency of radioactive strata and of fracturing, rather than the presence of a well-connected regional fracture system. Ground-water chemistry is dominated by the calcium cation and the bicarbonate anion, both derived from abundant secondary calcite in the fractures. The concentrations of uranium and radium in water that comes into contact with radioactive rock are controlled by the water chemistry. Uranium is the dominant alpha emitter in the oxidizing waters in the red mudstones of the Passaic Formation, whereas radium-226 (226Ra) is the dominant alpha emitter in the suboxic (reducing) water in the black mudstones of the lower part of the Passaic Formation. Because the lithology of the Stockton Formation and, in places, the lower part of the Passaic Formation varies greatly, wells can intercept multiple fracture zones that can contain oxic or suboxic waters, thereby resulting in the presence of both uranium and radium in detectable quantities in the same water sample.

New Jersey↗

USGS1997

Fish communities of benchmark streams in agricultural areas of eastern Wisconsin

Fish communities were surveyed at 20 stream sites in agricultural areas in eastern Wisconsin in 1993 and 1995 as part of the National Water-Quality Assessment (NAWQA) Program. These streams, designated "benchmark streams," were selected for study because of their potential use as regional references for healthy streams in agricultural areas, based on aquatic communities, habitat, and water chemistry. The agricultural benchmark streams were selected from four physical settings, or relatively homogeneous units (RHU's), that differ in bedrock type, texture of surficial deposits, and land use. Additional data were collected along with the fish-community data, including measures of habitat, water chemistry, and population surveys of algae and benthic invertebrates. Of the 20 sites, 19 are classified as trout (salmonid) streams. Fish species that require cold or cool water were the most commonly collected. At least one species of trout was collected at 18 sites, and trout were the most abundant species at 13 sites. The species with the greatest collective abundance, and collected at 18 of the 20 sites, were mottled sculpin (Cottus bairdi), a coldwater species. The next most abundant species were brown trout (Salmo trutta), followed by brook trout (Salvelinusfontinalis), creek chub (Semotilus atromaculatus), and longnose dace (Rhinichthys cataractae). In all, 31 species of fish were collected. The number of species per stream ranged from 2 to 14, and the number of individuals collected ranged from 19 to 264. According to Index of Biotic Integrity (IBI) scores, 5 sites were rated excellent, 10 sites rated good, 4 rated fair, and 1 rated poor. The ratings of the five sites in the fair to poor range were low for various reasons. Two sites appeared to have more warmwater species than was ideal for a high-quality coldwater stream. One was sampled during high flow and the results may not be valid for periods of normal flow; the other may have been populated by migrating warmwater species. Two sites had insufficient deep-water habitat to support large numbers offish, especially top carnivores. Finally, one stream may be too cool to support enough warmwater species and too warm to support trout. In general, two methods of evaluating site habitat indicate that habitat is not a limiting factor for fish communities. However, two sites were rated as fair according to both habitat evaluation methods due to low base flow. Two sites rated below good according to one habitat evaluation method but rated good or excellent according to the other. Detrended correspondence analysis (DCA) of data for 17 sites showed three station groupings. These groupings fell along RHU divisions and each group was associated with one of three trout species. A species-richness gradient was evident on the station-ordination diagram. Intolerant species were associated with each grouping, a reflection of the generally high water quality at the sites. However, no significant differences were found between IBI scores or habitat indices among the site groupings. The DCA axis 1 and 2 scores correlated with average velocity and percent pool as well as RHU factors percent sandy surficial deposits, percent wetland, percent agriculture, and bedrock. Average velocity was highest at three sites which also had among the highest measured flow and largest drainage areas. Percent pool was generally lower at sites with smaller percentages of sandy surficial deposits, with one exception. The usefulness of ordination methods in conjunction with more traditional methods of defining biotic integrity (IB I) has been noted in previous studies. In this study, however, perhaps because of the relative homogeneity of the benchmark streams, the IBI did not correlate with the same kinds of factors as the DCA axis scores did.

Wisconsin↗

USGS1997

Ground-water development and the effects on ground-water levels and water quality in the town of Atherton, San Mateo County, California

The installation of at least 100 residential wells in the town of Atherton, California, during the 198792 drought has raised concerns about the increased potential for land subsidence and salt water intrusion. Data were collected and monitor ing networks were established to assess current processes and to monitor future conditions affect ing these processes. Data include recorded pump age, recorded operation time, and measured pumpage rates from 38 wells; water levels from 49 wells; water chemistry samples from 20 wells, and land-surface elevation data from 22 survey sites, including one National Geodetic Survey estab lished bench mark. Geologic, lithologic, climato logic, well construction, well location, and historical information obtained from available reports and local, state, and Federal agencies were used in this assessment. Estimates of annual residential pumpage from 269 assumed active residential wells in the study area indicate that the average annual total pumping rate is between 395 and 570 acre-feet per year. The nine assumed active institutional wells are estimated to pump a total of about 200 acre- feet per year, or 35 to 50 percent of the total resi dential pumpage. Assuming that 510 acre-feet per year is the best estimate of annual residential pumpage, total pumpage of 710 acre-feet per year would represent about 19 percent of the study area's total water supply, as estimated. Depth-to-water-level measurements in wells during April 1993 through September 1995 typically ranged from less than 20 feet below land surface nearest to San Francisco Bay to more than 70 feet below land surface in upslope areas near exposed bedrock, depending on the season. This range, which is relatively high historically, is attributed to above normal rainfall between 1993 and 1995. Water levels expressed as hydraulic heads indicate the presence of three different hydrologic subareas on the basis of hydraulic-head contour configurations and flow direction. That all measured hydraulic heads in the study area from April 1993 through September 1995 were above sea level indicates that saltwater intrusion was unlikely during this period. The chemistry of 20 well-water samples is characterized as a calcium magnesium carbonate bicarbonate type water. There is no evidence of saltwater intrusion from San Francisco Bay; how ever, water samples from wells nearest the bay and bedrock assemblages indicate a greater concentra tion of dissolved constituents and salinity. Dissolved-solids concentrations of water samples from wells in these areas exceeded 1,000 milli grams per liter, and several samples contained a substantial fraction of sodium and chloride. Water hardness for the 20 wells sampled averaged 471 milligrams per liter as calcium carbonate, which is classified as very hard. One well sample exceeded the primary maximum contaminant level for drinking water in nitrate, several wells exceeded the secondary maximum contaminant level for chloride and sulfate, and all wells sampled exceeded the secondary maximum contaminant level for total dissolved solids. Land-subsidence and the resultant damage because of excessive ground-water pumping, in combination with periodic drought, have a well- documented history in the south San Francisco Bay area. Land-elevation surveying data from 1934 to 1967 indicate that subsidence ranged from 0.1 to approximately 0.5 foot in the vicinity of the study area. It could not be determined from land- surface elevation surveying data from 1993 whether subsidence is currently occurring in the study area.

Water-Resources Investigations Report↗

USGS1998

Geohydrology of the Winchester Subbasin, Riverside County, California

The 20-square-mile Winchester structural subbasin is an alluvium-filled paleocanyon that is as much as 900 feet deep. The alluvial aquifer is composed of detrital material that generally ranges in size from clay to fine gravel; the fine and coarse materials are mixed in some places and inter- bedded in others. The apparent lenticularity of fine- and coarse-grained materials and differing water quality with depth indicate that the aquifer is partly or locally confined. A ground-water divide exists east of the town of Winchester. West of the divide, ground water moves toward and into the South Perris and the Menifee subbasins. East of the divide, ground water moves toward and into the Hemet subbasin. The components of flow direction in the Winchester?Hemet subbasins border area are complex: along the border, some water moves from the southwest corner of the Hemet subbasin into the Winchester subbasin and then eastward subparallel to the border before moving back into the Hemet subbasin. The direction of ground-water movement between the Winchester and Hemet subbasins, and the position of the ground-water divide in the central part of the Winchester subbasin, have changed with time. Prior to about 1974, ground water moved both eastward from the divide and westward from the Hemet subbasin toward a local depression of the water table caused by pumping in the eastern part of the Winchester subbasin. Comparison of spring 1970 and spring 1993 ground-water levels indicates a net rise of as much as 150 feet in the east end of the Winchester subbasin. For this same period, water levels rose about 3 to 20 feet in the western and central parts of the subbasin. Ground-water chemistry in the Winchester subbasin and adjacent subbasins varies areally and vertically. In general, sodium, calcium, chloride, and sulfate are dominant ions. Water quality is generally poor: dissolved-solids concentration exceeded 2,000 milligrams per liter throughout much of the subbasin and was highest west of the town of Winchester. Eastward along the subbasin axis (toward the Hemet subbasin), the dissolved-solids concentration decreases and the pH increases (generally greater than 7.0). Samples from two multiple-well monitoring sites at the west and east ends of the subbasin indicate that the best quality water (dissolved-solids concentrations of 395 and 483 milligrams per liter) is from the deepest wells (perforated near the alluvium- bedrock contact). Samples from the deeper wells in the eastern part of the Winchester subbasin are similar in water type to a sample from a well in the western part of the Hemet subbasin, which suggests that the water may have flowed from the Hemet subbasin; alternatively, the chemistry may reflect the influence of good-quality water flowing from the fractured bedrock basement to the alluvium in the eastern part of the Winchester subbasin. In addition, the potential problem of poor-quality water moving from the Winchester subbasin into the Hemet subbasin may not exist at all depths; fair- to good-quality water may be present below a depth of about 450 feet. Dissolved-solids concentrations in the southwest part of the Hemet subbasin ranged from about 900 milligrams per liter at well 5S/1W-19Q1 about one-quarter mile north of the Winchester?Hemet subbasin boundary to about 3,500 milligrams per liter at well 5S/2W-24C2 near the bedrock outcrops southeast of the Lakeview Mountains. High dissolved-solids concentration in the vicinity of well 5S/2W-24C2 most likely is a result of dissolution of constituents from the aquifer matrix, evaporative processes, and agricultural practices that occur in that vicinity rather than a result of flow from the Winchester subbasin. Aquifer-test results indicate that the transmissivity is about 950 feet squared per day in the eastern part of the Winchester subbasin near the boundary with the Hemet subbasin and about 72 feet squared per day in the western part of the subbasin near the boundary with th

California↗

USGS1998

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma- fish communities in streams of the Ozark Plateaus and their relations to selected environmental factors

Fish communities from 22 reaches at 18 stations in the Ozark Plateaus were sampled in 1993, 1994, and 1995. The 18 stations were chosen to represent selected combinations of major environmental factors (geology/physiographic area, land use, and basin size). Additional physical, chemical, and biological factors also were measured for each of the 22 reaches and the influence of these factors upon the fish communities was investigated. Fish community samples collected at the 22 reaches identified differences in these communities that can be attributed to differences in land use and related water-quality and habitat characteristics. Communities from agriculture reaches tended to have more species, increased relative abundance of stonerollers and members of the sucker family, and decreased relative abundance of members of the sunfish and darter families. Several groups of environmental factors (concentrations of nutrients, organic carbon, suspended sediment, and dissolved oxygen; measures related to ionic strength; measures related to riparian vegetation; measures related to substrate; and measures related to stream size) appear to be related to land-use differences and fish community differences. Three multivariate analysis techniques (two ordination techniques and a classification technique) yielded similar results when applied to the fish community data. Fish communities from reaches with more similar land use in their basins and with similar drainage areas generally were grouped closer together in the analysis. Water quality, substrate, stream morphology, and riparian measures appear to be affecting fish communities at these reaches. The relations between land use, stream size, and fish communities have implications for water quality assessments of Ozark streams. Compared to other parts of the United States, many fish species live in the Ozark Plateaus. At least 19 of these species are endemic to the Ozarks area. Many of these species are intolerant of habitat or water chemistry degradation. This characteristic makes fish a useful tool for assessing water-chemistry and other habitat conditions of streams. Several environmental factors can contribute to differences in fish communities. Elevated nutrient concentrations and greater canopy angles can increase periphyton production. Greater canopy angles can raise water temperatures and, if they reflect less woody vegetation along the banks of streams, can be associated with greater streambank erosion. Elevated suspended sediment concentrations and finer and more embedded substrates can reduce benthic macroinvertebrate populations, decrease spawning success of many fish species, and decrease protection of benthic fish from water velocities and predators.

Arkansas, Kansas, Missouri, Oklahoma↗

USGS1999

Hydrogeology of the surficial aquifer in the vicinity of a former landfill, Naval Submarine Base Kings Bay, Camden County, Georgia

Neogene and Quaternary sediments constitute the surficial aquifer beneath the study area; in descending order from youngest to oldest these include-the Quaternary undifferentiated surficial sand and Satilla Formation; the Pliocene(?) Cypresshead Formation; and the middle Miocene Coosawhatchie Formation. Beneath the surficial aquifer, the upper Brunswick aquifer consists of part of the lower Miocene Marks Head Formation. The surficial aquifer is divided into three water-bearing zones on the basis of lithologic and geophysical properties of sediments, hydraulic-head differences between zones, and differences in ground-water chemistry. The shallowest zone-the water-table zone-consists of medium to fine sand and clayey sand and is present from land surface to a depth of about 77 feet. Below the water-table zone, the confined upper water-bearing zone consists of medium to very coarse sand and is present from a depth of about 110 to 132 feet. Beneath the upper water-bearing zone, the confined lower water-bearing zone consists of coarse sand and very fine gravel and is present from a depth of about 195 to 237 feet. Hydraulic separation is suggested by differences in water chemistry between the water-table zone and upper water-bearing zone. The sodium chloride type water in the water-table zone differs from the calcium bicarbonate type water in the upper water-bearing zone. Hydraulic separation also is indicated by hydraulic head differences of more than 6.5 feet between the water-table zone and the upper water-bearing zone. Continuous and synoptic water-level measurements in the water-table zone, from October 1995 to April 1997, indicate the presence of a water-table high beneath and adjacent to the former landfill-the surface of which varies about 5 feet with time because of recharge and discharge. Water-level data from clustered wells also suggest that restriction of vertical ground-water flow begins to occur at an altitude of about 5 to 10 feet below sea level (35 to 40 feet below land surface) in the water-table zone because of the increasing clay content of the Cypresshead Formation.

Georgia↗

USGS1999

External quality-assurance results for the National Atmospheric Deposition Program/National Trends Network, 1995-96

The U.S. Geological Survey operated four external quality-assurance programs for the National Atmospheric Deposition Program/National Trends Network (NADP/NTN) in 1995 and 1996: the intersite-comparison program, the blind-audit program, the interlaboratory- comparison program, and the collocated-sampler program. The intersite-comparison program assessed the precision and bias of pH and specific-conductance determinations made by NADP/NTN site operators. The analytical bias introduced during routine handling, processing, and shipping of wet-deposition samples and precision of analyte values was estimated using a blind-audit program. An interlaboratory-comparison program was used to evaluate differences between analytical results and to estimate the analytical precision of five North American laboratories that routinely analyzed wet deposition. A collocated-sampler program estimated the precision of the overall precipitation collection and analysis system from initial sample collection through final storage of the data. Results of two intersite-comparison studies completed in 1995 indicated 94.6 and 94.4 percent of the onsite pH determinations met the NADP/NTN accuracy goals, whereas 97.2 and 98.3 percent of the specific-conductance determinations were within the established limits. The percentages of onsite determinations that met the accuracy goals in 1996 were slightly less for both pH and specific-conductance than in 1995. In 1996, 93.2 and 87.5 percent of onsite pH determinations met the accuracy goals, whereas the percentage of onsite specific-conductance measurements that met the goals was 93.9 and 94.9 percent.The blind audit program utilizes a paired sample design to evaluate the effects of routine sample handling, processing and shipping on the chemistry of weekly precipitation samples. The portion of the blind audit sample subject to all of the normal onsite handling and processing steps of a regular weekly precipitation sample is referred to as the bucket portion, whereas the portion receiving only minimal handling is referred to as the bottle portion. Throughout the report, the term positive bias in regard to blind-audit results indicates that the bucket portion had a higher concentration than the bottle portion. The paired t-test of 1995 blind-audit data indicated that routine sample handling, processing, and shipping introduced a very small positive bias (a=0.05) for hydrogen ion and specific conductance and a slight negative bias (a =0.05) for ammonium and sodium. In 1995, the median paired differences between the bucket and bottle portions ranged from -0.02 milligram per liter for both ammonium and nitrate to +0.002 milligram per liter for calcium. Although the paired t-test indicated a very small positive bias for hydrogen ion, the median paired difference between the bucket and bottle portions was 0.00 microequivalents per liter, whereas for specific conductance, the median paired difference between the bucket and bottle portions was 0.200 microsiemens per centimeter in 1995. The paired t-test of blind-audit results in 1996 indicated statistically significant bias for 6 of the 10 analytes. Only chloride, nitrate, hydrogen ion, and specific conductance were not biased in 1996. However, the magnitude of the bias in 1996 was very small and only of limited importance from the viewpoint of an analytical chemist or data user. The median paired differences between the bucket and bottle portions ranged from -0.02 milligram per liter for both ammonium and chloride to +0.006 milligram per liter for calcium. For hydrogen ion, the median paired difference between the bucket and bottle portions was -0.357 microequivalent per liter; for specific conductance, the median paired difference between the bucket and bottle portions was 0.00 microsiemens per centimeter in 1996. Surface-chemistry effects due to different amounts of precipitation contacting the sample collection and shipping container surfac

Water-Resources Investigations Report↗

USGS1999

Relation of arsenic, iron, and manganese in ground water to aquifer type, bedrock lithogeochemistry, and land use in the New England coastal basins

In a study of arsenic concentrations in public-supply wells in the New England Coastal Basins, concentrations at or above 0.005 mg/L (milligrams per liter) were detected in more samples of water from wells completed in bedrock (25 percent of all samples) than in water from wells completed in stratified drift (7.5 percent of all samples). Iron and manganese were detected (at concentrations of 0.05 and 0.03 mg/L, respectively) at approximately the same frequency in water from wells in both types of aquifers. Concentrations of arsenic in public-supply wells drilled in bedrock (in the National Water-Quality Assessment Program New England Coastal Basins study unit) vary with the bedrock lithology. Broad groups of lithogeochemical units generalized from bedrock lithologic units shown on state geologic maps were used in the statistical analyses. Concentrations of arsenic in water from public-supply wells in metasedimentary bedrock units that contain slightly to moderately calcareous and calcsilicate rocks (lithogeochemical group M c ) were significantly higher than the concentrations in five other groups of bedrock units in the study unit. Arsenic was detected, at or above 0.005 mg/L, in water from 44 percent of the wells in the lithogeochemical group M c and in water from less than 28 percent of wells in the five other groups. Additionally, arsenic concentrations in ground water were the lowest in the metasedimentary rocks that are characterized as variably sulfidic (group M s ). Generally, concentrations of arsenic were low in water from bedrock wells in the felsic igneous rocks (group I f ) though locally some bedrock wells in granitic rocks are known to have ground water with high arsenic concentrations, especially in New Hampshire. The concentrations of arsenic in ground water also correlate with land-use data; significantly higher concentrations are found in areas identified as agricultural land use than in undeveloped areas. There is, however, more agricultural land in areas overlying the metasedimentary rocks of lithogeochemical groups M c and the minimally-deformed clastic sediments of group M md than in areas overlying other lithogeochemical groups. This correlation complicates the interpretation of sources of arsenic to ground water in bedrock. A test of this association revealed that relations between arsenic concentrations and the metasedimentary rocks of group M c are not weakened when data associated with agricultural land use is removed; the reverse is true, however, if the data associated with the group M c are removed from the analysis. The occurrence and variability of arsenic in water from bedrock supply wells could be related to several factors. These include (1) the distribution and chemical form of arsenic in soils and rocks that are part of the ground-water-flow system, (2) the characteristics that influence the solubility and transport of arsenic in ground water, (3) the differing degrees of vulnerability of ground-water supplies to surface contamination, and (4) the spatial associations between land use, geology, and ground-water-flow patterns. Strong relations between agricultural land use and the metasedimentary rocks of group M c complicate the interpretation of arsenic source to water in these bedrock aquifers. This is due in part to the past use of arsenical pesticides; additionally, few whole-rock geochemical data are available for the rock types in the lithogeochemical groups of aquifers that contain ground water with elevated concentrations of arsenic. Without such data, identifying specific bedrock types as arsenic sources is not possible. In southern Maine and south-central New Hampshire, and in northern Massachusetts, the few available whole-rock analyses suggest, at least for these local areas, a connection between known bedrock chemistry and ground-water arsenic levels. Although the lithogeochemical group and land-use category variables individually describe much of the variance in the concentrations of arsenic in ground water, the lithogeochemical relation is statistically stronger than the land-use relation. Low concentrations of arsenic in water from bedrock public-supply wells are associated with the metasedimentary rocks of group M s (characterized as variably sulfidic). This association could reflect a variety of factors and suggests that simple dissolution of arsenic-bearing iron phases, such as sulfides, may not explain concentrations of arsenic in water in this bedrock aquifer group. Whole-rock geochemical data and more complete water-chemistry data, as well as studies of historical variation of arsenic concentrations (time-line studies), and site-specific studies, will be critical in addressing the arsenic source issue.

New England coastal basins↗

USGS1981

Geochemistry of spring water, southeastern Uinta Basin, Utah and Colorado

The chemical quality of water in the southeastern Uinta Basin, Utah and Colorado, is important to the future development of the abundant oil-shale resources of the area. This report examines the observed changes in chemistry as water circulates in both shallow and deep ground-water systems. Mass-balance and mass- transfer calculations are used to define reactions that simulate the observed water chemistry in the mixed sandstone, siltstone, and carbonate lithology of the Green River Formation of Tertiary age. The mass-transfer calculations determine a reaction path particular to this system. The early dominance of calcite dissolution produces a calcium carbonate water. After calcite saturation, deeper circulation and further rock-water interaction cause the reprecipitation of calcite, the dissolution of dolomite and plagioclase, and the oxidation of pyrite; all combining to produce a calcium magnesium sodium bicarbonate sulfate water. The calculations suggest that silica concentrations are controlled by a kaolinite-Ca-montmorillonite phase boundary. Close agreement of mineral-saturation indices calculated by both an aqueous-equilibrium model and the mass-transfer model support the selection of reactions from the mass-transfer calculations.

Colorado, Utah↗

USGS1981

Geochemistry of water in the Fort Union formation of the northern Powder River basin, southeastern Montana

Shallow water in the coal-bearing Paleocene Fort Union Formation of southeastern Montana was investigated to provide a better understanding of its geochemistry. Springs, wells less than 200 feet deep, and wells greater than 200 feet deep were observed to have different water qualities. Overall, the ground water exists as two systems: a mosaic of shallow, chemically dynamic, and localized recharge-discharge cells superimposed on a deeper, chemically static regional system. Water chemistry is highly variable in the shallow system; whereas, waters containing sodium and bicarbonate characterize the deeper system. Within the shallow system, springs and wells less than 200 feet deep show predominantly sodium and sulfate enrichment processes from recharge to discharge. These processes are consistent with the observed aquifer mineralogy and aqueous chemistry. However, intermittent mixing with downward moving recharge waters or upward moving deeper waters, and bacterially catalyzed sulfate reduction, may cause apparent reversals in these processes.

Water Supply Paper↗

USGS1994

Humic and fulvic acids: sink or source in the availability of metals to the marine bivalves Macoma balthica and Potamocorbula amurensis ?

Humic acids (HA) and fulvic acids (FA) are common forms of organic matter in marine sediments, and are routinely ingested by deposit- and suspension-feeding animals. These compounds may be a sink for metals, implying that once metals are bound to humic substances they are no longer available to food webs. A series of experiments was conducted to quantitatively examine this premise using 2 estuarine bivalves from San Francisco Bay, USA: the suspension feeder Potarnocorbula arnurensis and the facultative deposit feeder Macoma balthica . HA and FA, isolated from marine sediments, were bound as organic coatings to either hydrous ferric oxides (HFO) or silica particles. Cd and Cr(II1) were adsorbed to the organic coatings or directly to uncoated HFO and silica particles. Pulse-chase laboratory feeding expenments using 109 Cd and 51 Cr(III) were then conducted to determine absorption efficiencies of Cd and Cr for individual specimens using each of the particle types. The results demonstrated that: (1) absorption of Cr(I1I) from all types of non-living particles was consistently low (< 11%). Ingested Cd showed greater bioavailability than Cr(IIl), perhaps due to differences in metal chemistry. (2) Bivalves absorbed Cd bound to uncoated HFO or silica particles (i.e. with no HA or FA present). (3) The presence of organic coatings on particles reduced Cd bioavailabhty compared with uncoated particles. (4) Both geochemical and biological conditions affected the food chain transfer of Cd. The data suggest that in marine systems inorganic and organic-coated particles are predominantly a sink for Cr in sediments. In the transfer of Cd to consumer animals, inorganic particles and humic substances can act as a link (although not a highly efficient one) under oxidized conditions.

Marine Ecology Progress Series↗

USGS2022

Bacteria common to rhizosphere communities of Asiatic bittersweet across a post-glacial landscape

Invasive plants such as Asiatic bittersweet ( Celastrus orbiculatus Thunb.) are a significant problem for land managers as they impact plant species composition, disrupt nutrient dynamics and structure of native ecosystems, and are difficult to eradicate. As a result of the increasing abundance of Asiatic bittersweet across the eastern U.S., we have been investigating underlying factors potentially contributing to the success of this plant. Recently, ecologists have been investigating the role of plant-soil-microbe interactions contributing to plant invasion. This work has led to question: are there certain microbes (e.g., bacteria, fungi) contributing to the success of some invasive plants? We hypothesize that despite differences in geologic age of soils where Asiatic bittersweet has established in the Indiana Dunes National Park there are sufficient common factors that led to common bacterial taxa in their rhizosphere. The objectives were to determine differences and commonalities in the soil chemistry, plant community and bacterial communities of Asiatic bittersweet plants. To achieve these objectives, bittersweet plants were collected at thirteen locations in the national park from soils ranging in geologic age from 150 to over 14,500 years. Surrounding soil chemistry, plant cover and the 16S rRNA gene amplicon sequences of rhizosphere soil bacterial communities of these Asiatic bittersweet were compared. Asiatic bittersweet coverage of sampling sites ranged from 2 to 77% averaging 52 ± 2%. There were statistically significant differences ( p < 0.05) in alpha diversity (Shannon, Faith’s PD and Pielou’s evenness) and beta diversity (Bray Curtis, Jaccard, unweighted Unifrac, weighted Unifrac) among the samples when grouped by soil age or habitat. Despite these differences in the bacterial communities from different soil ages and habitats, some bacterial taxa (e.g., Bacillus, Streptomyces, Sphingomonas and Rhizobiales) previously found in other studies to be beneficial to plant growth were found in every rhizosphere community sampled. These microbes provide insight into a possible contributing factor to the success of this invasive plant at the Indiana Dunes National Park, and a strategy for future work to reduce the impact of Asiatic bittersweet establishment and offer some new strategies to manage this nuisance species.

Frontiers of Ecology and Evolution↗

USGS2021

Integrating high-resolution coastal acidification monitoring data across seven United States estuaries

Beginning in 2015, the United States Environmental Protection Agency’s (EPA’s) National Estuary Program (NEP) started a collaboration with partners in seven estuaries along the East Coast (Barnegat Bay; Casco Bay), West Coast (Santa Monica Bay; San Francisco Bay; Tillamook Bay), and the Gulf of Mexico (GOM) Coast (Tampa Bay; Mission-Aransas Estuary) of the United States to expand the use of autonomous monitoring of partial pressure of carbon dioxide ( p CO 2 ) and pH. Analysis of high-frequency (hourly to sub-hourly) coastal acidification data including p CO 2 , pH, temperature, salinity, and dissolved oxygen (DO) indicate that the sensors effectively captured key parameter measurements under challenging environmental conditions, allowing for an initial characterization of daily to seasonal trends in carbonate chemistry across a range of estuarine settings. Multi-year monitoring showed that across all water bodies temperature and p CO 2 covaried, suggesting that p CO 2 variability was governed, in part, by seasonal temperature changes with average p CO 2 being lower in cooler, winter months and higher in warmer, summer months. Furthermore, the timing of seasonal shifts towards increasing (or decreasing) p CO 2 varied by location and appears to be related to regional climate conditions. Specifically, p CO 2 increases began earlier in the year in warmer water, lower latitude water bodies in the GOM (Tampa Bay; Mission-Aransas Estuary) as compared with cooler water, higher latitude water bodies in the northeast (Barnegat Bay; Casco Bay), and upwelling-influenced West Coast water bodies (Tillamook Bay; Santa Monica Bay; San Francisco Bay). Results suggest that both thermal and non-thermal influences are important drivers of p CO 2 in Tampa Bay and Mission-Aransas Estuary. Conversely, non-thermal processes, most notably the biogeochemical structure of coastal upwelling, appear to be largely responsible for the observed p CO 2 values in West Coast water bodies. The co-occurrence of high salinity, high p CO 2 , low DO, and low temperature water in Santa Monica Bay and San Francisco Bay characterize the coastal upwelling paradigm that is also evident in Tillamook Bay when upwelling dominates freshwater runoff and local processes. These data demonstrate that high-quality carbonate chemistry observations can be recorded from estuarine environments using autonomous sensors originally designed for open-ocean settings.

California, Florida, Maine, New Jersey, Oregon, Te↗

USGS2020

Life at the frozen limit: Microbial carbon metabolism across a Late Pleistocene permafrost chronosequence

Permafrost is an extreme habitat yet it hosts microbial populations that remain active over millennia. Using permafrost collected from a Pleistocene chronosequence (19 to 33 ka), we hypothesized that the functional genetic potential of microbial communities in permafrost would reflect microbial strategies to metabolize permafrost soluble organic matter (OM) in situ over geologic time. We also hypothesized that changes in the metagenome across the chronosequence would correlate with shifts in carbon chemistry, permafrost age, and paleoclimate at the time of permafrost formation. We combined high-resolution characterization of water-soluble OM by Fourier-transform ion-cyclotron-resonance mass spectrometry (FT-ICR MS), quantification of organic anions in permafrost water extracts, and metagenomic sequencing to better understand the relationships between the molecular-level composition of potentially bioavailable OM, the microbial community, and permafrost age. Both age and paleoclimate had marked effects on both the molecular composition of dissolved OM and the microbial community. The relative abundance of genes associated with hydrogenotrophic methanogenesis, carbohydrate active enzyme families, nominal oxidation state of carbon (NOSC), and number of identifiable molecular formulae significantly decreased with increasing age. In contrast, genes associated with fermentation of short chain fatty acids (SCFAs), the concentration of SCFAs and ammonium all significantly increased with age. We present a conceptual model of microbial metabolism in permafrost based on fermentation of OM and the buildup of organic acids that helps to explain the unique chemistry of ancient permafrost soils. These findings imply long-term in situ microbial turnover of ancient permafrost OM and that this pooled biolabile OM could prime ancient permafrost soils for a larger and more rapid microbial response to thaw compared to younger permafrost soils.

Alaska↗

USGS2024

Development of high surface area organosilicate nanoparticulate thin films for use in sensing hydrophobic compounds in sediment and water

The scope of this study was to apply advances in materials science, specifically the use of organosilicate nanoparticles as a high surface area platform for passive sampling of chemicals or pre-concentration for active sensing in multiple-phase complex environmental media. We have developed a novel nanoporous organosilicate (NPO) film as an extraction phase and proof of concept for application in adsorbing hydrophobic compounds in water and sediment. We characterized the NPO film properties and provided optimization for synthesis and coatings in order to apply the technology in environmental media. NPO films in this study had a very high surface area, up to 1325 m 2 /g due to the high level of mesoporosity in the film. The potential application of the NPO film as a sorbent phase for sensors or passive samplers was evaluated using a model hydrophobic chemical, polychlorinated biphenyls (PCB), in water and sediment. Sorption of PCB to this porous high surface area nanoparticle platform was highly correlated with the bioavailable fraction of PCB measured using whole sediment chemistry, porewater chemistry determined by solid-phase microextraction fiber methods, and the Lumbriculus variegatus bioaccumulation bioassay. The surface-modified NPO films in this study were found to highly sorb chemicals with a log octanol-water partition coefficient (K ow ) greater than four; however, surface modification of these particles would be required for application to other chemicals.

Biosensors↗

USGS2025

Flow cytometric detection of waterborne bacteria metabolic response to anthropogenic chemical inputs to aquatic ecosystems

Typical investigations into the biological consequences of suspected xenobiotics or nutrients introduced in watersheds include analytical chemistry screens of environmental samples—such as periphyton responses or studies of fish condition—which are all costly in terms of equipment, reagents, time, and human resources. An alternative is to assess pollutant effects on waterborne bacteria. A flow cytometric method was developed to yield rapid, same-day results that could be used to proactively screen for suspected chemical inputs into watersheds using water sampling methods that are identical to those in standard use. The analytical methods are microbe cultivation-independent, for use with waterborne bacteria that are typically viable but not culturable. The procedure is quick and inexpensive, generating measures of bacterial esterase that reflect metabolic activity and are sensitive and statistically robust. After phosphate-EDTA incubation to increase cell wall permeability, staining was performed with 5(6) carboxyfluorescein diacetate (enzyme activity) and propidium iodide (cell viability) with three bacterial species in exponential phase growth having been incubated with organic wastewater compounds (atrazine, pharmaceuticals [17α-ethynylestradiol and trenbolone], and antimicrobials [tylosin and butylparaben]). This method successfully detected metabolic changes in all bacterial species, with atrazine inducing the greatest change. Additional fluorescent stains can target specific microbial structures or functions of interest in a particular watershed. This biotechnology can inform analytical chemistry and study of biota at sites of interest and has the potential to be automated.

Cells↗

USGS2022

Plague and trace metals in natural systems

All pathogenic organisms are exposed to abiotic influences such as the microclimates and chemical constituents of their environments. Even those pathogens that exist primarily within their hosts or vectors can be influenced directly or indirectly. Yersinia pestis , the flea-borne bacterium causing plague, is influenced by climate and its survival in soil suggests a potentially strong influence of soil chemistry. We summarize a series of controlled studies conducted over four decades in Russia by Dr. Evgeny Rotshild and his colleagues that investigated correlations between trace metals in soils, plants, and insects, and the detection of plague in free-ranging small mammals. Trace metal concentrations in plots where plague was detected were up to 20-fold higher or lower compared to associated control plots, and these differences were >2-fold in 22 of 38 comparisons. The results were statistically supported in eight studies involving seven host species in three families and two orders of small mammals. Plague tended to be positively associated with manganese and cobalt, and the plague association was negative for copper, zinc, and molybdenum. In additional studies, these investigators detected similar connections between pasturellosis and concentrations of some chemical elements. A One Health narrative should recognize that the chemistry of soil and water may facilitate or impede epidemics in humans and epizootics in non-human animals.

International Journal of Environmental Research an↗

USGS2020

Reversal of forest soil acidification in the northeastern United States and eastern Canada: Site and soil factors contributing to recovery

As acidic deposition has decreased across Eastern North America, forest soils at some sites are beginning to show reversal of soil acidification. However, the degree of recovery appears to vary and is not fully explained by deposition declines alone. To assess if other site and soil factors can help to explain degree of recovery from acid deposition, soil resampling chemistry data (8- to 24-year time interval) from 23 sites in the United States and Canada, located across 25° longitude from Eastern Maine to Western Ontario, were explored. Site and soil factors included recovery years, sulfate (SO 4 2− ) deposition history, SO 4 2− reduction rate, C horizon pH and exchangeable calcium (Ca), O and B horizon pH, base saturation, and exchangeable Ca and aluminum (Al) at the time of the initial sampling. We found that O and B horizons that were initially acidified to a greater degree showed greater recovery and B horizon recovery was further associated with an increase in recovery years and lower initial SO 4 2− deposition. Forest soils that seemingly have low buffering capacity and a reduced potential for recovery have the resilience to recover from the effects of previous high levels of acidic deposition. This suggests, that predictions of where forest soils acidification reversal will occur across the landscape should be refined to acknowledge the importance of upper soil profile horizon chemistry rather than the more traditional approach using only parent material characteristics.

Soil Systems↗