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Toward a new framework to evaluate process-based model configurations and quantify data worth prior to calibration

Model criticism, discrimination, and selection methods often rely on calibrated model outputs. Because calibration can be computationally expensive, model criticism can first be undertaken by assessing model outputs obtained from limited prior parameter ensembles. However, such prior-based methods are often heuristic and do not formalize the notion of balancing model consistency with data and model complexity (i.e., model adequacy). We present a new framework to discriminate among candidate models prior to calibration that formalizes prior-to-calibration model adequacy into a metric to implicitly balance prior model output data coverage with model complexity represented by prior output (co)variance. The prior model adequacy metric “Mahalanobis distance deviation” quantifies the deviation of (a) the set of squared Mahalanobis distances of data from a prior model output distribution from (b) the set of squared Mahalanobis distances of data from their own distribution. A new data worth metric “discernment value” is also presented which quantifies the value of data for screening less-adequate models prior to calibration. Discernment value is calculated from the change in variance of a weighted average of prior model outputs from all candidate models due to less-adequate model outputs receiving lower weight. The framework is demonstrated using a one-dimensional groundwater flow model with eight possible configurations. A synthetic data network is used to test the framework. Results show the framework identifies the candidate models most similar to the true model used to create the synthetic data. Discernment values show variation in the value of different data types and locations for screening less-adequate models.

Water Resources Research

Applying U-Th disequilbrium for dating siliceous sinters

Continental hydrothermal systems are critical avenues for the crustal transport of heat and mass captured for geothermal energy and mineral exploration. Thus, understanding their temporal evolution and longevity is important for resource characterization. Deposits of microlaminated siliceous sinter, common surface expressions of high temperature reservoirs (> 170 °C), have the potential to trace hydrothermal histories. Geothermal reservoirs are often located within uranium-bearing silicic volcanic rock where subsurface fluid-rock interactions extract U into hydrothermal fluids. U incorporated in the surface sinter deposit has the potential to provide a U— Th disequilibrium dating option. We focus on samples from El Tatio geyser field in the Altiplano of northern Chile, the largest geothermal system in the Andes. Our resulting 230 Th/U ages, along with the water and deposit elemental compositions, suggest concentrations of U and Th vary predictably along the sinter apron. While distal facies containing the highest U concentrations (> 50 μg/g) are least affected by detrital Th corrections, they can display suspected open-system behavior. In contrast, more medial facies, where bacterial mats and other porous textures are co mmonly concentrated, have only trace amounts of U (< 0.1 μg/g), which leads to unreliable or geologically improbable dates. Proximal facies tend to date most consistently. By comparing existing 14 C ages with 230 Th/U results, 230 Th/U ages tend to be younger than the 14 C ages, supporting the presence of a 14 C-dead carbon influence. New data confirm that the onset of geothermal activity at El Tatio goes back to the late Pleistocene.

Altiplano, El Tatio geyser field

Towards a refined definition of “tidal influence” for the coastal wetland sciences

The astronomical tide relates to lunar (and to a lesser extent solar) influences on rising and falling water bodies, and is a key control of many coastal processes. However, tides manifest along coastal margins in different ways to muddle application beyond Sir Isaac Newton’s first descriptions. Here, we argue that tide, or specifically “tidal,” has not been adequately defined for the coastal wetland sciences to facilitate contemporary interdisciplinary distinction for rapidly changing coastlines and future climate adaptation planning. We provide a brief history of the tidal concept, and we describe tides in a diversity of uncommonly recognized marginal coastal environments. Common astronomical tide manifestations are described through hydrographic examples, then expanded to include those tidal environments exposed additionally to fluvial, meteorological (wind), or groundwater influences. Our expanded definition of “tidal” is intended to be a forward-looking construct as environments will inevitably change with sea-level rise, water extraction, and anthropogenic flow alteration. Our definition of wetland tidal influence, which we broaden, includes those “wetlands affected by astronomic water level fluctuations within coastally restricted environments causing frequent or infrequent surface inundation or groundwater tidal variation that affects the biogeochemistry of the soil (e.g., ion exchange capacity, oxygen state, mineralization processes)”. Astronomic water level fluctuations are often amplified or dampened by non-astronomical events, such as wind. Expanding the definition of what is considered tidal by the scientific community is critical for improved understanding of coastal wetland function and the suite of ecosystem services they provide people and society, including climate mitigation opportunity, management, and adaptation.

Wetlands

Unlocking ecological insights from sub-seasonal visible-to-shortwave infrared imaging spectroscopy: The SHIFT campaign

We stand at the threshold of a transformative era in Earth observation, marked by space-borne visible-to-shortwave infrared (VSWIR) imaging spectrometers that promise consistent global observations of ecosystem function, phenology, and inter- and intra-annual change. However, the full value of repeat spectroscopy, the information embedded within different temporal scales, and the reliability of existing algorithms across diverse ecosystem types and vegetation phenophases have remained elusive due to the absence of suitable sub-seasonal spectroscopy data. In response, the Surface Biology and Geology (SBG) High-Frequency Time Series (SHIFT) campaign was initiated during late February 2022 in Santa Barbara County, California. SHIFT, designed to support NASA's SBG mission, addressed mission scoping, scientific advancement, applications development, and community building. This ambitious endeavor included weekly Airborne Visible InfraRed Imaging Spectrometer-Next Generation (AVIRIS-NG) imagery acquisitions for 13 weeks (spanning February 24 to May 29, 2022), accompanied by coordinated terrestrial vegetation and coastal aquatic data collection. We describe the rich datasets collected and illustrate how the complex sub-seasonal patterns of change can be linked to biological science and applications, surpassing insights from multispectral observations. Leveraging open-source processing methods and cloud-based analysis tools, the SHIFT campaign showcases the readiness of the scientific community to harness ecological insights from remotely sensed hyperspectral time series. We provide an overview of SHIFT's goals, data collections, preliminary results, and the collaborative efforts of early career scientists committed to unlocking the transformative potential of high-frequency time series data from space-borne VSWIR imaging spectrometers.

Ecosphere

Channel morphology and large wood control postfire debris-flow erosion and deposition

Runoff-generated debris flows are a known response to wildfire, and accurately predicting the volume of these debris flows is important for estimating the magnitude of downstream hazards. Prior data collection efforts have focused on debris-flow volume measurements at catchment outlets, but few studies have considered how erosion and deposition modulate the volume of sediment arriving at catchment outlets. This study takes advantage of a high-resolution dataset to document the factors that control the total debris-flow volume reaching the catchment outlet during a fatal postfire debris flow. Using pre- and post-event airborne lidar, satellite imagery and field mapping, we found that a postfire debris flow in the Black Hollow catchment in northern Colorado eroded 136,000 ± 30,000 m 3 and redeposited 27,000 ± 7,500 m 3 in the main channel. Most of the in-channel deposition (52% by volume) occurred where a confined channel reach transitioned to an unconfined channel reach downstream, allowing the flow to widen and deposit material. Wood jams played multiple roles in the debris-flow dynamics, both nucleating deposition (25% of the deposit volume was stored behind wood jams) and exacerbating erosion (50% of the total erosion occurred downstream from a wood dam break). The remaining deposition occurred due to spatial changes in channel slope as well as deposition observed at newly formed channel bars. Using these data in this study, we identified topographic and vegetation metrics that can be used (pre-event) to anticipate where deposition may occur in channels prior to a debris flow.

Colorado

Potential corrosivity of untreated groundwater in Louisiana

Corrosive groundwater can cause lead, copper, and other metals to leach from pipes and plumbing fixtures in water distribution systems. Metals, if ingested, could lead to serious health implications to the nearly 2.9 million people in Louisiana who obtain their drinking water from groundwater sources. Four indices—the Langelier Saturation Index (LSI), Ryznar Stability Index (RSI), Puckorius Scaling Index (PSI), and the Potential to Promote Galvanic Corrosion (PPGC)—in addition to an analysis which normalized the results from the existing indices, the Combined Index (CI), were used to assess the corrosivity of groundwater in Louisiana and identify areas within eight major aquifers and aquifer systems with moderate to high corrosivity potential. The purpose of this study is to provide State and local governments, public water system managers, and the nearly 500,000 private well owners in Louisiana with information needed to manage drinking-water supplies and mitigate potential health risks related to leaching of metals from water pipes and fixtures. The average scores of untreated groundwater samples from approximately 375 wells by index are as follows: LSI, −1.28; RSI, 9.78; PSI, 9.34; and CI, 4.14. The PPGC does not produce a numerical score, but the total percentage of class counts can be used to assign a classification; overall, samples in Louisiana were classified as significant concern. The percentages of groundwater samples from wells classified as potentially corrosive, by index, are as follows: LSI, 53 percent; RSI, 94 percent; PSI, 81 percent; PPGC, 98 percent; and CI, 81 percent. The percentages of samples classified as indeterminate, by index, are as follows: LSI, 46 percent; RSI, 5 percent; PSI, 12 percent; PPGC, 0 percent; and CI, 18 percent.

Louisiana

Investigation of land cover within wetland complexes at Dixie Meadows, Churchill County, Nevada, from October 2015 to January 2022

The U.S. Geological Survey investigated land cover at subannual time steps within six wetland areas in Dixie Valley, Churchill County, Nevada, from October 2015 to January 2022. As requested by the U.S. Fish and Wildlife Service, we used aerial photography and satellite remote sensing data to map surface water and other land cover types within the wetland complexes. We identified five land cover classes using the green normalized difference vegetation index (gNDVI) and its inverse relationship to the normalized difference water index (NDWI) within three U.S. Department of Agriculture National Agriculture Imagery Program aerial images (acquired in 2015, 2017, and 2019) and 110 European Space Agency Sentinel-2 satellite images (acquired 2015–2022). The relative wetness of soil conditions within each land cover class is estimated by comparison to previously published observations of relative conductivity measured by 79 field-based sensors within the wetlands from 2019 to 2021. We mapped the areal coverage of the five land cover classes for approximately 385 acres (1,559,000 square meters [m²]) comprising six individual wetland complexes as well as a larger 1,298- acre (5,254,000-m 2 ) area of interest inclusive of the wetland complexes and adjacent landscape. Land cover of open water (Class 5) primarily within ponds at one of the wetland complexes comprised 8,333 m 2 , on average, of the wetland complexes. Land cover of mixed shallow surface water, saturated soil, and vegetation (Class 4) comprised 111,723 m 2 on average of the wetland complexes. Land cover of dense green vegetation canopy cover (Class 3) that often (46 percent of observations) had underlying surface water or saturated soil conditions comprised 592,522 m 2 on average of the wetland complexes. The remaining areas of the wetland complexes not mapped as these three land cover types (Classes 2 and 1) had sparse vegetation or bare soil cover and commonly (greater than or equal to 67 percent of observations) had dry soil conditions. The investigation of land cover detailed in this report could inform future efforts to map land cover more precisely via higher resolution remote sensing or ground-based surveying or could be incorporated with other environmental monitoring data to characterize habitat and hydrology of the wetland complexes at Dixie Meadows.

Nevada

Divisions of geologic time—Major chronostratigraphic and geochronologic units

Effective communication in the geosciences requires consistent uses of stratigraphic nomenclature, especially divisions of geologic time. A geologic time scale is composed of standard stratigraphic divisions based on rock sequences and calibrated in years. Over the years, the development of new dating methods and refinement of previous ones have stimulated revisions to geologic time scales. Since the mid-1990s, geologists from the U.S. Geological Survey (USGS), State geological surveys, academia, and other organizations have sought a consistent time scale to be used in communicating ages of geologic units in the United States. Many international debates have occurred over names and boundaries of units, and various time scales have been used by the geoscience community. For consistency purposes, the USGS Geologic Names Committee and the Association of American State Geologists developed Divisions of Geologic Time .

Fact Sheet

Invasion of perennial sagebrush steppe by shallow-rooted exotic cheatgrass reduces stable forms of soil carbon in a warmer but not cooler ecoregion

Soil organic carbon ('SOC') in drylands comprises nearly a third of the global SOC pool and has relatively rapid turnover and thus is a key driver of variability in the global carbon cycle. SOC is also a sensitive indicator of longer-term directional change and disturbance-responses of ecosystem C storage. Biome-scale disruption of the dryland carbon cycle by exotic annual grass invasions (mainly Bromus tectorum, 'Cheatgrass') threatens carbon storage and corresponding benefits to soil hydrology and nutrient retention. Past studies on cheatgrass impacts mainly focused on total C, and of the few that evaluated SOC, none compared the very different fractions of SOC, such as relatively unstable particulate organic carbon (POC) or relatively stable, mineral-associated organic carbon (MAOC). We measured SOC and its POC and MAOC constituents in the surface soils of sites that had sagebrush canopies but differed in whether their understories had been invaded by cheatgrass or not, in both warm and relatively colder ecoregions of the western USA. MAOC stocks were 36.1% less in the 0–10 cm depth and 46.1% less in the 10–20 cm depth in the cheatgrass-invaded stands compared to the uninvaded stands of the warmer Colorado Plateau, but not in the cooler and more carbon-rich Wyoming Basin ecoregion. In plots where cheatgrass increased SOC, it was via unstable POC. These findings indicate that cheatgrass effects on the distribution of soil carbon among POC and MAOC fractions may vary among ecoregions, and that cheatgrass can reduce forms of carbon that are otherwise considered stable and 'secure', i.e. sequestered.

Environmental Research Communications

Ambient flow and transport in long-screened, sand-packed wells: Insights into cross contamination and wellbore flow

The presence of long-screened wells with a surrounding sand pack can have a major effect on the redistribution of contaminants in groundwater, particularly when the wells are set in low-hydraulic conductivity aquifers. Such redistribution, or cross contamination, can occur through vertical flow and advective transport or by in-well mixing via multiple non-advective transport processes. A multi-method approach, including the use of single borehole dilution tracer (SBDT) logging, was undertaken to estimate vertical transport of trichloroethylene (TCE) in 8 discontinued remedial extraction wells, all constructed with long screens (100 ft, or 30.6 m long) and surrounding sand packs, at Site 25, Edwards Air Force Base, California. The site is within an enclosed drainage basin that is underlain primarily by quartz-monzonite-granitic rocks in various states of weathering. Prior to this study, little information was available on the depths of fracture zones intersecting the wellbores. Results indicate that because of in-well mixing processes, a potential redistribution of TCE of up to 9 g/d per well occurs as a consequence of leaving the wells inactive (unpumped) and unsealed, as measured by SBDT logging. Simulations of flow made with a generic model of the site show that if the wells were to be sealed with well liners, with the intent of reducing vertical TCE transport but the sand pack left intact, TCE transport decreases by 53% overall compared to leaving the wells unlined.

Environmental Earth Sciences

Arctic fold-and-thrust belts

The modern Arctic has been formed through a series of continent–continent collisions, accretion of terranes and phases of crustal extension. The Neoproterozoic Timanian, Paleozoic Caledonian and Uralian, and late Mesozoic Verkhoyansk–Kolyma, Chukotkan and Brookian orogenies formed several large fold-and-thrust belts (FTBs). The FTBs are exposed across vast areas of continents and continue offshore to form a complex tectonic basement for thick sedimentary basins, playing an important role in the history of accumulation and deformation of younger unmetamorphosed sedimentary successions that are the subject of this volume. Recognition of the importance of FTBs in the Arctic geological history and their role as a controlling factor of development of Arctic sedimentary basins resulted in this chapter, in which we review the current state of knowledge about Arctic FTBs and highlight questions that remain to be addressed. Enclosure D , a map showing boundaries of the FTB and their internal first-order structural fabric, is a part of the overview.

Book chapter

USGS Geochron Database

Introduction Geochronology helps us understand Earth’s history by determining when important events, like volcanic eruptions, the rise of mountains, the formation of mineral resources, and changes in the landscape, happened. Geochronological data directly support geologic mapping and can inform decisions about geologic hazard mitigation, natural resource management, and infrastructure resilience. The U.S. Geological Survey (USGS) Geochron database provides access to more than 300,000 published, publicly available age measurements from more than 40,000 geological samples. This database is the result of a collaborative effort with State geological surveys and geoscientists from across the globe. The USGS Geochron database is the most comprehensive collection of geochronological data available for the United States. Users can view data through an interactive map explorer, download datasets, and integrate data into geospatial software or other analysis tools.

Fact Sheet

Global maps of critical mineral production in 2023

Introduction The global production of many mineral commodities, especially critical minerals, is concentrated in a few countries that have mineral resources and the infrastructure necessary to mine and process those resources. For this reason, the type and amount of mineral production differ by country. For example, many countries produce such metallic ores as gold and silver, whereas only a few countries produce magnesium, niobium, platinum-group metals, and rare earths. The concentration of mining and processing in certain countries necessitates the existence of a global supply chain. A mineral supply chain is the sequence of mining and processing of minerals and manufacturing of products. Mineral supply chains are global in scale, complex, and dynamic. Supply chain data can be used to understand how a country’s mineral resources and various economic, technical, and environmental factors affect the complexity of global supply chains. This fact sheet summarizes the world’s leading countries (those accounting for 5 percent or more of a commodity’s global production in 2023) for production of select mineral commodities (mainly critical minerals) in the mining and processing stages. These countries and the minerals they produce are synthesized on global maps to communicate the status of, and potential risk to, mineral commodity supply chains from geographic production concentration. Trade data from United Nations Statistics Division (2025) is used to support assessments of the observed production data.

Fact Sheet

Uranium—Deposits, production and resources, market dynamics, and supply chain risks

Introduction Interest in nuclear power for the generation of electricity has risen with the increase in the need for more diverse baseload power, enhanced energy security, and the development of new technologies, such as small modular reactors (SMRs), which could provide power for remote areas, industrial applications, and artificial intelligence (AI) data centers. In 2024, the U.S. Department of Energy received $2.7 billion in congressional funding to bolster the domestic uranium production and nuclear fuel supply chain and address reliance on imports from foreign suppliers. In 2025, the U.S. Government issued several Executive and Secretary’s orders aimed at revitalizing the U.S. nuclear sector. If SMRs are to be as widely deployed in the United States and worldwide as envisioned, demand for uranium (nuclear reactor fuel) will likely increase. After the Fukushima nuclear accident in 2011, the market spot price of uranium began a decline, followed by a decrease in U.S. and global uranium exploration and mine development expenditures that led to a uranium supply deficit until 2020, when prices started to recover, prompting a resurgence in uranium exploration and development. In January of 2024, the uranium spot price rose to a 17-year high $106 (U.S. dollars) per pound of U3O8 (triuranium oxide, commonly known as “yellowcake”), which is expected to increase uranium exploration, mine development, and uranium production domestically and worldwide.

Fact Sheet

Hydroacoustic observations reveal drivers of mixing and salinization of a karst subterranean estuary during intense precipitation

Karst subterranean estuaries within globally ubiquitous carbonate aquifers are coastal groundwater ecosystems that provide an essential water resource for human populations. To understand the drivers of salinization within a coastal aquifer in the Yucatan Peninsula (Mexico), we employed hydroacoustics in flooded caves to observe how oceanic and atmospheric events facilitate mixing between the meteoric lens (fresh-brackish groundwater) and the saline groundwater on tidal and episodic timescales. Precipitation during Tropical Storm Carlotta increased the flow and salinity of the meteoric lens without evidence for vertical mixing across the halocline. We postulate that vertical migration of haloclines in the conduit relative to those within the rock matrix during precipitation creates lateral density gradients that drive mixing, and ultimately creates a brackish layer within the meteoric lens. These results provide a mechanistic explanation for vertical and lateral exchange in a coastal carbonate aquifer, which has implications for groundwater response to future climatic change.

Ox Bel Ha cave system, Yucatan peninsula

On connecting hydro-social parameters to vegetation greenness differences in an evolving groundwater-dependent ecosystem

Understanding groundwater-dependent ecosystems (i.e., areas with a relatively shallow water table that plays a major role in supporting vegetation health) is key to sustaining water resources in the western United States. Groundwater-dependent ecosystems (GDEs) in Colorado have non-pristine temporal and spatial patterns, compared to agro-ecosystems, which make it difficult to quantify how these ecosystems are impacted by changes in water availability. The goal of this study is to examine how key hydrosocial parameters perturb GDE water use in time and in space. The temporal approach tests for the additive impacts of precipitation, surface water discharge, surface water mass balance as a surrogate for surface–groundwater exchange, and groundwater depth on the monthly Landsat normalized difference vegetation index (NDVI). The spatial approach tests for the additive impacts of river confluences, canal augmentation, development, perennial tributary confluences, and farmland modification on temporally integrated NDVI. Model results show a temporal trend (monthly, 1984–2019) is identifiable along segments of the Arkansas River at resolutions finer than 10 km. The temporal impacts of river discharge correlate with riparian water use sooner in time compared to precipitation, but this result is spatially variable and dependent on the covariates tested. Spatially, areal segments of the Arkansas River that have confluences with perennial streams have increased cumulative vegetation density. Quantifying temporal and spatial dependencies between the sources and effects of GDEs could aid in preventing the loss of a vulnerable ecosystem to increased water demand, changing climate, and evolving irrigation methodologies.

Colorado

Groundwater spatial variability within an atoll island: Assessing shallow aquifer heterogeneity with geophysical and physicochemical measurements

This study examines the spatial variability of shallow groundwater on Dhigelaabadhoo Island using electromagnetic induction surveys, groundwater monitoring, and sediment analyses. The research reveals how variations in island morphology—such as differences in elevation, reef flat width, and sediment composition—affect the spatial distribution of groundwater lenses and the overall aquifer dynamics. Saltwater intrusion is especially pronounced in low elevated areas, with narrow reef flat plate and areas where higher hydraulic conductivity—driven by the presence of coarser sediments—is observed, whereas regions characterized by finer sediments, higher elevation, and wider reef flat plates tend to support more symmetric and less saline groundwater lenses. The geophysical investigations reveal that tidal oscillations alter groundwater movement by markedly changing water levels and conductivity, thereby underscoring the critical need to account for temporal dynamics in atoll coastal aquifer systems and the importance of integrating tidal dynamics into the aquifer zone. The findings highlight the significant role of intrinsic morphological and external hydrodynamic factors in shaping groundwater distribution on atoll islands, offering critical insights for sustainable freshwater resource management.

Dhigelaabadhoo Island

The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes

To understand the effects of burial diagenesis on the stable isotope geochemistry of soil-formed clay and carbonate minerals in paleosols, samples were collected from seven cores, spanning middle- to upper-Pennsylvanian strata of the Illinois Basin, with varied maximum burial depths of 1–3 km. Mixed-layer illite-smectite and kaolinite mixtures give δ 2 H and δ 18 O values of −83 ‰ to −36 ‰ and 11.9 ‰ to 21.1 ‰ (VSMOW), respectively. After carbonates were screened petrographically for diagenetic textures using transmitted light and cathodoluminescence, measured clumped isotope Δ 47 values range from 0.504 to 0.563 ‰ (I-CDES). Resulting mineral formation temperatures for phyllosilicate mineral mixtures are 28 to 66 °C (mean = 47 °C), whereas T(Δ 47 ) estimates for calcites are 36 to 61 °C (mean = 45 °C). Calculated δ 18 O water values from which phyllosilicate minerals and calcites precipitated under isotopic equilibrium ranges from −7.1 to −1.2 ‰ and − 1.4 to +4.9 ‰, respectively. Closed and open-system phyllosilicate-fluid exchange modeling indicates that phyllosilicate alteration occurred in the presence of a low temperature brine or meteoric water and is interpreted to occur in a layer-by-layer illitization transformation. Due to the lack of diagenetic textures and positively correlated T(Δ 47 ) and δ 18 O water , calcites are interpreted to have undergone solid-state bond reordering. Despite low to moderate temperatures (<125 °C) and varying depths of shallow burial (1–3 km), solid-state transformation of phyllosilicates and calcites indicates paleosols had prolonged exposure to burial conditions which has implications for the use of paleosol minerals for paleoenvironmental reconstructions.

Illinois, Indiana, Kentucky