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Decadal-scale changes of nitrate in ground water of the United States, 1988-2004

This study evaluated decadal-scale changes of nitrate concentrations in groundwater samples collected by the USGS National Water-Quality Assessment Program from 495 wells in 24 well networks across the USA in predominantly agricultural areas. Each well network was sampled once during 1988-1995 and resampled once during 2000-2004. Statistical tests of decadal-scale changes of nitrate concentrations in water from all 495 wells combined indicate there is a significant increase in nitrate concentrations in the data set as a whole. Eight out of the 24 well networks, or about 33%, had significant changes of nitrate concentrations. Of the eight well networks with significant decadal-scale changes of nitrate, all except one, the Willamette Valley of Oregon, had increasing nitrate concentrations. Median nitrate concentrations of three of those eight well networks increased above the USEPA maximum contaminant level of 10 mg L-1. Nitrate in water from wells with reduced conditions had significantly smaller decadal-scale changes in nitrate concentrations than oxidized and mixed waters. A subset of wells had data on ground water recharge date; nitrate concentrations increased in response to the increase of N fertilizer use since about 1950. Determining ground water recharge dates is an important component of a ground water trends investigation because recharge dates provide a link between changes in ground water quality and changes in land-use practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

Geology and ground-water resources of Dane County, Wisconsin

The purpose of the ground-water investigation of Dane County, Wis., was to determine the occurrence, movement, quantity, quality, and availability of ground water in the unconsolidated deposits and the underlying bedrock. The relationships between ground water and surface water were studied in general in Dane County and in detail in the Madison metropolitan area. An analysis was made of the hydrologic system of the Yahara River valley and of the effects of ground-water pumpage on that system.

Wisconsin↗

Reconnaissance of ground-water quality in the Papio-Missouri River Natural Resources District, eastern Nebraska, July through September 1992

A reconnaissance of ground-water quality was conducted in the Papio-Missouri River Natural Resources District of eastern Nebraska. Sixty-one irrigation, municipal, domestic, and industrial wells completed in the principal aquifers--the unconfined Elkhorn, Missouri, and Platte River Valley alluvial aquifers, the upland area alluvial aquifers, and the Dakota aquifer--were selected for water-quality sampling during July, August, and September 1992. Analyses of water samples from the wells included determination of dissolved nitrate as nitrogen and triazine and acetanilide herbicides. Waterquality analyses of a subset of 42 water samples included dissolved solids, major ions, metals, trace elements, and radionuclides. Concentrations of dissolved nitrate as nitrogen in water samples from 2 of 13 wells completed in the upland area alluvial aquifers exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level for drinking water of 10 milligrams per liter. Thirty-nine percent of the dissolved nitrate-as-nitrogen concentrations were less than the detection level of 0.05 milligram per liter. The largest median dissolved nitrate-as-nitrogen concentrations were in water from the upland area alluvial aquifers and the Dakota aquifer. Water from all principal aquifers, except the Dakota aquifer, had detectable concentrations of herbicides. Herbicides detected included alachlor (1 detection), atrazine (13 detections), cyanazine (5 detections), deisopropylatrazine (6 detections), deethylatrazine (9 detections), metolachlor (6 detections), metribuzin (1 detection), prometon (6 detections), and simazine (2 detections). Herbicide concentrations did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels for drinking water. In areas where the hydraulic gradient favors loss of surface water to ground water, the detection of herbicides in water from wells along the banks of the Platte River indicates that the river could act as a line source of herbicides. Water from the alluvial and bedrock aquifers generally was a calcium bicarbonate type and was hard. Two of nine water samples collected from the Dakota aquifer contained calcium sulfate type water. Results of analyses of 42 groundwater samples for major ions, metals, trace elements, and radionuclide constituents indicated that statistically at least one principal aquifer had significant differences in its water chemistry. In general, the water chemistry of the Dakota aquifer was similar to the water chemistry of the upland area alluvial aquifers in areas where there was a hydraulic connection. The water from the Dakota aquifer had large dissolved-solids, calcium, sulfate, chloride, iron, lithium, manganese, and strontium concentrations in areas where the aquifer is thought not to be in hydraulic connection with the Missouri River Valley and upland area alluvial aquifers. Ground-water quality in the Papio-MissouriRiver Natural Resources District is generally suitable for most uses. However, the numerous occurrences of herbicides in water of the Elkhorn and Platte River Valley alluvial aquifers, especially near the Platte River, are of concern because U.S. Environmental Protection Agency Maximum Contaminant Levels could be exceeded. Concentrations in three of nine water samples collected from wells completed in the Dakota aquifer exceeded the U.S. Environmental Protection Agency Maximum Contaminant Levels or Secondary Maximum Contaminant Levels for gross alpha activity, radon-222 activity, dissolved solids, sulfate, or iron. Also of concern are the exceedances of the U.S Environmental Protection Agency proposed Maximum Contaminant Level for radon-222 activity.

Water-Resources Investigations Report↗

Ground-water quality in selected areas of Wisconsin

Analysis of 2,071 ground-water samples from 970 wells throughout Wisconsin indicate large variations in ground-water quality. Ground water in Wisconsin is generally suitable for most uses, but in some areas concentrations of chemical constituents exceed recommended drinking-water standards. Iron, manganese, and nitrate commonly exceed recommended drinking-water standards and dissolved solids, sulfate, heavy metals, and phenolic materials may present local problems. (USGS)

Wisconsin↗

Records of wells, drillers' logs, water-level measurements, and chemical analyses of ground water in Harris and Galveston Counties, Texas, 1980-84

Information on major new water wells in Harris and Galveston Counties was compiled by the U.S. Geological Survey from 1980 to 1984. This report presents the results of the hydro!ogic data collection on new large-capacity and other selected wells, including well location and completion data, drillers 1 logs of the strata penetrated, water levels, and chemical quality of the produced water. These water-well data are supplementary to similar data on older wells in these counties and to descriptive evaluations of the ground-water resources which have been published previously.

Texas↗

Hydrogeology and analysis of ground-water-flow system, Sagamore Marsh area, southeastern Massachusetts

A study of the hydrogeology and an analysis of the ground-water-flow system near Sagamore Marsh, southeastern Massachusetts, was undertaken to improve the understanding of the current (1994­ 95) hydrogeologic conditions near the marsh and how the ground-water system might respond to proposed changes in the tidal-stage regime of streams that flood and drain the marsh. Sagamore Marsh is in a coastal area that is bounded to the east by Cape Cod Bay and to the south by the Cape Cod Canal. The regional geology is characterized by deltaic and glaciolacustrine sediments. The sediments consist of gravel, sand, silt, and clay and are part of the Plymouth-Carver regional aquifer system. The glacial sediments are hounded laterally by marine sand, silt, and clay along the coast. The principal aquifer in the area consists of fine to coarse glacial sand and is locally confined by fine-grained glaciolacustrine deposits consisting of silt and sandy clay and fine-grained salt-marsh sediments consisting of peat and clay. The aquifer is underlain by finer grained glaciolacustrine sediments in upland areas and by marine clay along the coast. Shallow ground water discharges primarily along the edge of the marsh, whereas deeper ground water flows beneath the marsh and discharges to Cape Cod Bay. Tidal pulses originating from Cape Cod Bay and from tidal channels in the marsh are rapidly attenuated in the subsurface. Tidal ranges in Cape Cod Bay and in the tidal channels were on the order of 9 and 1.5 feet, respectively, whereas tidal ranges in the ground-water levels were less than 0.2 foot. Tidal pulses measured in the water table beneath a barrier beach between the marsh and Cape Cod Bay were more in phase with tidal pulses from Cape Cod Bay than with tidal pulses from the tidal channels in Sagamore Marsh, whereas tidal pulses in the regional aquifer were more in phase with tidal pulses from the tidal channels. A 5-day aquifer test at a public-supply well adjacent to the marsh gave a transmissivity of the regional aquifer of 9,300 to 10,900 feet squared per day and a hydraulic conductivity of 181 to 213 feet per day, assuming a saturated thickness of the aquifer of 51.3 feet. The regional aquifer became unconfined near the pumped well during the test. The ratio of tidal ranges in the tidal channel to the ranges in the underlying aquifer at two sites (the lower and upper marsh) indicated aquifer diffusivities for the marsh sediments of 380 and 170 feet squared per day; these values correspond to hydraulic conductivities of 2.5 x 10 -3 and 1.7 x 10 -3 feet per day, respectively. The maximum distances from the tidal channel at the lower and upper marsh sites where tidal ranges would exceed 0.01 foot, as calculated from aquifer diffusivities and current (1995) tidal ranges in the tidal channels, were 24.4 and 26.7 feet, respectively. The maximum distances from the tidal channel where tidal pulses in the ground water would exceed 0.01 foot, using potential increased tidal stages resulting from proposed tidal-stage modifications and predicted by the U.S. Army Corps of Engineers, were 37.1 and 42.0 feet, respectively. A numerical model of the marsh and surrounding aquifer system indicated that the contributing area for the supply well adjacent to the marsh, for current (1994) pumping conditions, extends toward Great Herring Pond, about 2 miles northwest (upgradient) of the well, and does not extend beneath the marsh. The model also indicates that the predicted increases in tidal stages in the marsh will have a negligible effect on local ground-water levels.

Massachusetts↗

Ground-Water Resource Assessment in the Rio Grande de Manati Alluvial Plain, Rio Arriba Saliente Area, Puerto Rico

The alluvial aquifer within a 160-acre area of the Rio Grande de Manati alluvial plain was investigated to evaluate its potential as a water-supply source for the Barrios Rio Arriba Saliente and Pugnado Afuera, municipio of Manati, Puerto Rico. Analysis of well boring samples and the results of electric resistivity surveys indicate that the average thickness of the unconsolidated alluvial deposits in the study area is about 100 to 110 feet. The alluvium is a mixture of sand and gravel, which generally has a porosity of 0.2 to 0.35. Short-duration pump tests in small-diameter piezometers indicate that the alluvial aquifer has a hydraulic conductivity of about 200 feet per day and a transmissivity of about 7,900 feet squared per day. Analyses of water levels in piezometers, combined with stage measurements at a series of surveyed reference points along the Rio Grande de Manati channel, indicate that the water-table gradient in the alluvial aquifer is about 0.001, and that ground-water flow is generally from south to north, in the general direction of river flow. The water-table data indicate that the Rio Grande de Manati is the principal source of ground-water recharge to the alluvial aquifer in the study area. Because base flow for the Rio Grande de Manati is usually greater than 44 cubic feet per second, a continuous withdrawal rate of 0.5 to 1.0 cubic foot per second (225 to 450 gallons per minute) from a production well is possible. Chemical analysis of a ground-water sample indicates that the alluvial aquifer water meets U.S. Environmental Protection Agency secondary standards for selected constituents. Bacteriological analysis of ground-water samples indicates that the ground water contains little or no fecal coliform or fecal streptococcus bacteria. Although long-term data from upstream of the study area indicate high levels of fecal coliform and fecal streptococcus prior to 1996, bacteriological analyses of Rio Grande de Manati water samples obtained during the present study indicate that fecal coliform and fecal streptococcus concentrations are within the standards for surface water intended for use (or with the potential for use) as a raw source of public water supply in Puerto Rico. If a production well were constructed in the study area, it would be located close to the river channel (within 500 to 800 feet). Pumping from the porous and permeable alluvial aquifer close to the river channel could substantially enhance recharge from the Rio Grande de Manati channel to the aquifer. Enhanced recharge could shorten travel times for ground water in the aquifer, which might not allow sufficient time to attenuate bacteria and viruses. Travel times for bacteria moving from the river channel to a hypothetical production well were estimated using the numerical transport model MODFLOW/MT3DMS with an uncalibrated model of the alluvial aquifer. The model assumes a well pumping at 1 cubic foot per second. The transport of particles from the river to the well is most sensitive to the porosity of the aquifer and the pumping rate of the well. Sensitivity analysis indicates that a decrease in pumpage will increase the time of travel for particles to move from the river to the pumping well. The model indicates that the leading edge of a plume would reach the production well in about 40 days assuming a porosity of 0.20, 60 days assuming a porosity of 0.275, and about 70 days assuming a porosity of 0.35. If the well were moved 50 feet further from the river, the leading edge of the plume would reach the well in about 50 days assuming a porosity of 0.20 and about 70 days assuming a porosity of 0.275. These estimates are considered worse case estimates because no decay rate was included in the simulation, and because the hypothetical well was located in the center of the alluvial plain rather than further eastward, away from the river channel.

Water-Resources Investigations Report↗

Potential effects of the Hawaii Geothermal Project on ground-water resources on the island of Hawaii

In 1990, the State of Hawaii proposed the Hawaii Geothermal Project for the development of as much as 500 MW of electric power from the geothermal system in the East Rift Zone of Kilauea Volcano. This report uses data from 31 wells and 8 springs to describe the properties of the ground-water system in and adjacent to the East Rift Zone. Potential effects of this project on ground-water resources are also discussed. Data show differences in ground-water chemistry and heads within the study area that appear to be related to mixing of waters of different origins and ground-water impoundment by volcanic dikes. East of Pahoa, the ground-water system within the rift is highly transmissive and receives abundant recharge from precipitation; therefore, the pumping of freshwater to support geothermal development in that part of the rift zone would have a minimal effect on ground-water levels. To the southwest of Pahoa, dike impoundment reduces the transmissivity of the ground-water system to such an extent that wells might not be capable of supplying sufficient fresh water to support geothermal operations. Contamination of ground-water resources by accidental release of geothermal fluids into shallow aquifers is possible because of corrosive conditions in the geothermal wells, potential well blowouts, and high ground-water velocities in parts of the region. Hydrologic monitoring of water level, temperature, and chemistry in observation wells should continue throughout development of geothermal resources for the Hawaii Geothermal Project for early detection of leakage and migration of geothermal fluids within the groundwater system.

Water-Resources Investigations Report↗

Use of tree-ring chemistry to document historical ground-water contamination events

The annual growth rings of tulip trees ( Liriodendron tulipifera L.) appear to preserve a chemical record of ground-water contamination at a landfill in Maryland. Zones of elevated iron and chlorine concentrations in growth rings from trees immediately downgradient from the landfill are closely correlated temporally with activities in the landfill expected to generate iron and chloride contamination in the ground water. Successively later iron peaks in trees increasingly distant from the landfill along the general direction of ground-water flow imply movement of iron-contaminated ground water away from the landfill. The historical velocity of iron movement (2 to 9 m/yr) and chloride movement (at least 40 m/yr) in ground water at the site was estimated from element-concentration trends of trees at successive distances from the landfill. The tree-ring-derived chloride-transport velocity approximates the known ground-water velocity (30 to 80 m/yr). A minimum horizontal hydraulic conductivity (0.01 to .02 cm/s) calculated from chloride velocity agrees well with values derived from aquifer tests (about 0.07 cm/s) and from ground-water modeling results (0.009 to 0.04 cm/s).

Groundwater↗

Evaluation of the Feasibility of Freshwater Injection Wells in Mitigating Ground-Water Quality Degradation at Selected Well Fields in Duval County, Florida

The Fernandina permeable zone contains brackish water in parts of Duval County, Florida. Upward flow from the Fernandina permeable zone to the upper zone of the Lower Floridan aquifer increases chloride concentrations in ground water in parts of Duval County. Numerical models of the ground-water flow system in parts of Duval, St. Johns, and Clay Counties, Florida, were used to (1) estimate the vertical flows between the low-quality water of the Fernandina permeable zone and the high-quality water of the upper zone of the Lower Floridan aquifer in the vicinity of Deerwood 3 and Brierwood well fields, based on 2000 ground-water withdrawal rates; (2) determine how such vertical flows change as several scenarios of injection, withdrawal, and intervening rest periods are simulated in the two well fields; and (3) evaluate the effects of changes in less certain hydraulic parameters on the vertical flows between the Fernandina permeable zone and the upper zone of the Lower Floridan aquifer. The ground-water flow system was simulated with a four-layer model using MODFLOW-2000, which was developed by the U.S. Geological Survey. The first layer consists of specified-head cells simulating the surficial aquifer system with prescribed water levels. The second layer simulates the Upper Floridan aquifer. The third and fourth layers simulate the upper zone of the Lower Floridan aquifer and the Fernandina permeable zone, respectively. Average flow conditions in 2000 were approximated with a steady-state simulation. The changes in upward flow from the Fernandina permeable zone due to periods of injections and withdrawals were analyzed with transient simulations. The grid used for the ground-water flow model was uniform and composed of square 250-foot cells, with 400 columns and 400 rows. The active model area encompasses about 360 square miles in parts of Duval, St. Johns, and Clay Counties, Florida. Ground-water flow simulation was limited vertically to the bottom of the Fernandina permeable zone. The steady-state ground-water flow model was calibrated using time-averaged 2000 heads at 20 control points. Environmental-water heads in the Fernandina permeable zone were calculated for wells with variable water density. Transmissivity of the Upper Floridan aquifer, the upper zone of the Lower Floridan aquifer, and the Fernandina permeable zone, and the leakance of the intermediate confining unit, the middle semiconfining unit, and the semiconfining unit were obtained from regional ground-water flow models and adjusted until a reasonable fit between simulated and computed heads was obtained. The calibrated hydraulic properties from the steady-state ground-water flow model, and the calibrated storage coefficient from the transient model, were used to simulate hypothetical transient scenarios of injection, withdrawal, and intervening rest periods to assess changes in flow between the Fernandina permeable zone and the upper zone of the Lower Floridan aquifer. Based on the simulated flows between the Fernandina permeable zone and the upper zone of the Lower Floridan aquifer and the 18 million gallons per day of water available for injection, the reversal of the prevailing upward flow from the Fernandina permeable zone was not achieved. However, steady-state and transient simulations indicate that the upward flow of water from the Fernandina permeable zone could be reduced by as much as 64 percent, from 0.11 to 0.04 cubic foot per second, if only injection periods are simulated.

Water-Resources Investigations Report↗

Geohydrology and simulation of ground-water flow in the Red Clay Creek Basin, Chester County, Pennsylvania, and New Castle County, Delaware

The 54-square-mile Red Clay Creek Basin, located in the lower Delaware River Basin, is underlain primarily by metamorphic rocks that range from Precambrian to Lower Paleozoic in age. Ground water flows through secondary openings in fractured crystalline rock and through primary openings below the water table in the overlying saprolite. Secondary porosity and permeability vary with hydrogeologic unit, topographic setting, and depth. Thirty-nine percent of the water-bearing zones are encountered within 100 feet of the land surface, and 79 percent are within 200 feet. The fractured crystalline rock and overlying saprolite act as a single aquifer under unconfined conditions. The water table is a subdued replica of the land surface. Local ground-water flow systems predominate in the basin, and natural ground-water discharge is to streams, comprising 62 to 71 percent of streamflow. Water budgets for 1988-90 for the 45-square-mile effective drainage area above the Woodale, Del., streamflow-measurement station show that annual precipitation ranged from 43.59 to 59.14 inches and averaged 49.81 inches, annual streamflow ranged from 15.35 to 26.33 inches and averaged 20.24 inches, and annual evapotranspiration ranged from 27.87 to 30.43 inches and averaged 28.98 inches. The crystalline rocks of the Red Clay Creek Basin were simulated two-dimensionally as a single aquifer under unconfined conditions. The model was calibrated for short-term steady-state conditions on November 2, 1990. Recharge was 8.32 inches per year. Values of aquifer hydraulic conductivity in hillside topographic settings ranged from 0.07 to 2.60 feet per day. Values of streambed hydraulic conductivity ranged from 0.08 to 26.0 feet per day. Prior to simulations where ground-water development was increased, the calibrated steady-state model was modified to approximate long-term average conditions in the basin. Base flow of 11.98 inches per year and a ground-water evapotranspiration rate of 2.17 inches per year were simulated by the model. Different combinations of ground-water supply and wastewater-disposal plans were simulated to assess their effects on the stream-aquifer system. Six of the simulations represent an increase in population of 14,283 and water use of 1.07 million gallons per day. One simulation represents an increase in population of 28,566 and water use of 2.14 million gallons per day. Reduction of average base flow is greatest for development plans with wastewater removed from the basin through sewers and is proportional to the amount of water removed from the basin. The development plan that had the least effect on water levels and base flow included on-lot wells and on-lot septic systems. Five organochlorine insecticides--lindane, DDT, dieldrin, heptachlor, and methoxychlor--were detected in ground water. Four organophosphorus insecticides--malathion, parathion, diazinon, and phorate--were detected in ground water. Four volatile organic compounds--benzene, toluene, tetrachloroethylene, and trichloroethylene--were detected in ground water. Phenol was detected at concentrations up to 8 micrograms per liter in water from 50 percent of 14 wells sampled. The concentration of dissolved nitrate in water from 18 percent of wells sampled exceeded 10 milligrams per liter as nitrogen; concentration of nitrate were as high as 19 milligrams per liter. PCB was detected in the bottom material of West Branch Red Clay Creek at Kennet Square at concentrations up to 5,600 micrograms per kilogram.

Delaware, Pennsylvania↗

Chloride in ground water and surface water in the vicinity of selected surface-water sampling sites of the beneficial use monitoring program of Oklahoma, 2003

The Oklahoma Water Resources Board Beneficial Use Monitoring Program reported exceedances of beneficial-use standards for chloride at 11 surface-water sampling sites from January to October 2002. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, conducted a study to determine the chloride concentrations in ground water in the vicinity of Beneficial Use Monitoring Program surface-water sampling sites not meeting beneficial use standards for chloride and compare chloride concentrations in ground water and surface water. The chloride-impaired Beneficial Use Monitoring Program surface-water sampling sites are located in the western and southern regions of Oklahoma. The ground-water sampling sites were placed in proximity to the 11 surface-water sampling sites designated impaired by chloride by the Oklahoma Water Resources Board. Two surface-water sampling sites were located on the Beaver River (headwaters of the North Canadian River), three sites on the Cimarron River, one site on Sandy Creek, one site on North Fork Red River, and four sites on the Red River. Six ground-water samples were collected, when possible, from two test holes located upstream from each of the 11 Beneficial Use Monitoring Program surface-water sampling sites. One test hole was placed on the left bank and right bank, when possible, of each Beneficial Use Monitoring Program surfacewater sampling site. All test holes were located on alluvial deposits adjacent to the Beneficial Use Monitoring Program surface-water sampling sites within 0.5 mile of the stream. Top, middle, and bottom ground-water samples were collected from the alluvium at each test hole, when possible. Water properties of specific conductance, pH, water temperature, and dissolved oxygen were recorded in the field before sampling for chloride. The ground-water median chloride concentrations at 8 of the 11 Beneficial Use Monitoring Program sites were less than the surface-water median chloride concentrations. The Turpin and Beaver sites had similar ground-water and surface-water median chloride concentrations. The Buffalo site was the only site that had a large difference between the ground-water and surface-water chloride concentrations. The ground-water median chloride concentration was approximately 14,500 mg/L greater than the surface-water median chloride concentration at the Buffalo site.

Scientific Investigations Report↗

Ground-water quality, levels, and flow direction near Fort Cobb Reservoir, Caddo County, Oklahoma, 1998-2000

Fort Cobb Reservoir in northwest Caddo County Oklahoma is managed by the Bureau of Reclamation for water supply, recreation, flood control, and wildlife. Excessive amounts of nitrogen in the watershed have the potential to cause long-term eutrophication of the reservoir and increase already elevated concentrations of nitrogen in the Rush Springs aquifer. The U.S. Geological Survey in cooperation with the Bureau of Reclamation studied ground water in the area surrounding a swine feeding operation located less than 2 miles upgradient from Fort Cobb Reservoir in Caddo County, Oklahoma. Objectives of the study were to (1) determine if the operation was contributing nitrogen to the ground water and (2) measure changes in ground-water levels and determine the local ground-water flow direction in the area surrounding the swine feeding operation. Nitrate concentrations (28.1 and 31.5 milligrams per liter) were largest in two ground-water samples from a well upgradient of the wastewater lagoon. Nitrate concentrations ranged from 4.30 to 8.20 milligrams per liter in samples from downgradient wells. Traces of ammonia and nitrite were detected in a downgradient well, but not in upgradient wells. d15N values indicate atmospheric nitrogen, synthetic fertilizer, or plants were the predominate sources of nitrate in ground water from the downgradient wells. The d15N values in these samples are depleted in nitrogen-15, indicating that animal waste was not a significant contributor of nitrate. Manganese concentrations (1,150 and 965 micrograms per liter) in samples from a downgradient well were substantially larger than concentrations in samples from other wells, exceeding the secondary drinking-water standard of 50 micrograms per liter. Larger concentrations of bicarbonate, magnesium, fluoride, and iron and a higher pH were also measured in water from a downgradient well. Ground-water levels in an observation well were higher from April to mid-July and lower during the late summer and in the fall due to a seasonal decrease in precipitation, increase in water withdrawals, and increase in evapotranspiration. Ground water near the wastewater spray field moved south-southeast toward Willow Creek along a gradient of about 50 feet per mile. Analysis of ground-water samples suggest that commercial fertilizer is contributing nitrate upgradient of the swine feeding operation and that wastewater from the lagoon is contributing reduced forms of nitrogen, ammonia and nitrite. Additional downgradient wells would be needed to (1) determine if the swine feeding operation is adding excessive amounts of nitrogen to ground water, (2) determine the vertical dimension of wastewater flow, and (3) the extent of wastewater downgradient of the lagoon.

Water-Resources Investigations Report↗

Ground-water resources data for Baldwin County, Alabama

Geologic and hydrologic data for 237 wells were collected, and water-levels in 223 wells in Baldwin and Escambia Counties were measured. Long-term water water-level data, available for many wells, indicate that ground-water levels in most of Baldwin County show no significant trends for the period of record. However, ground-water levels have declined in the general vicinity of Spanish Fort and Daphne, and ground-water levels in the Gulf Shores and Orange Beach areas are less than 5 feet above sea level in places. The quality of ground water generally is good, but problems with iron, sulfur, turbidity, and color occur. The water from most private wells in Baldwin County is used without treatment or filtration. Alabama public- health law requires that water from public-supply wells be chlorinated. Beyond that, the most common treatment of ground water by public-water suppliers in Baldwin County consists of pH adjustment, iron removal, and aeration. The transmissivity of the Miocene-Pliocene aquifer was determined at 10 locations in Baldwin County. Estimates of transmissivity ranged from 700 to 5,400 feet squared per day. In general, aquifer transmissivity was greatest in the southeastern part of the county, and least in the western part of the county near Mobile Bay. A storage coefficient of 1.5 x 10-3 was determined for the Miocene-Pliocene aquifer near Loxley.

Open-File Report↗

Ground-Water Temperature Data, Nevada Test Site and Vicinity, Nye, Clark, and Lincoln Counties, Nevada, 2000-2006

Ground-water temperature data were collected by the U.S. Geological Survey in wells at and in the vicinity of the Nevada Test Site during the years 2000-2006. Periodic ground-water temperatures were collected in 166 wells. In general, periodic ground-water temperatures were measured annually in each well at 5 and 55 feet below the water surface. Ground-water temperature profiles were collected in 73 wells. Temperatures were measured at multiple depths below the water surface to produce these profiles. Databases were constructed to present the ground-water temperature data.

Data Series↗

Simulation of ground-water flow and potential land subsidence, upper Santa Cruz Basin, Arizona

A numerical ground-water flow model of the upper Santa Cruz basin in Pinal, Pima, and Santa Cruz Counties was developed to evaluate predevelopment conditions in 1940, ground-water withdrawals for 1940-86, and potential water-level declines and land subsidence for 1987-2024. Simulations of steady-state ground-water conditions indicate 12,900 acre-feet of ground-water inflow, 15,260 acre-feet of outflow, 53,000 acre-feet of pre- development pumpage, 29,840 acre-feet of mountain- front recharge, and 34,020 acre-feet of streamflow infiltration in 1940. Simulations of transient ground-water conditions indicate a total of 6.6 million acre-feet of net pumpage and 3.4 million acre-feet of water removed from aquifer storage for 1941-86. A difference of 1.2 million acre-feet between estimated and net pumpage is attributed to increased recharge from irrigation return flow, mine return flow, and infiltration of sewage effluent. Estimated natural recharge represents 40 percent of pumpage for 1966-86 and averaged 63,860 acre-feet per year for 1940-57 and 76,250 acre-feet per year for 1958-86. The increase in recharge after 1958 was coincident with above- average winter streamflow in the Santa Cruz River for 1959-86. Increased recharge after 1958 and decreased pumpage after 1975 contributed to decreased water-level declines or to recoveries after 1977 in wells near the Santa Cruz River and its tributaries. The results of projection simu- lations indicate that a maximum potential subsi- dence for 1987-2024 ranges from 1.2 feet for an inelastic specific storage of .0001 ft to 12 feet for an inelastic specific storage of .0015 ft. The simulations were made on the basis of pumpage and recharge rates from 1986 and by using a preconso- lidation-stress threshold of 100 feet. A permanent reduction in acquitard storage can range from 1 to 12 percent of the potential loss of 3.9 million acre-feet in aquifer-system storage for 1987-2024.

Water-Resources Investigations Report↗

Geohydrology and simulated ground-water flow, Plymouth-Carver aquifer, southeastern Massachusetts

The Plymouth-Carver aquifer underlies an area of 140 square miles and is the second largest aquifer in areal extent in Massachusetts. It is composed primarily of saturated glacial sand and gravel. The water-table and bedrock surface were mapped and used to determine saturated thickness of the aquifer, which ranged from less than 20 feet to greater than 200 feet. Ground water is present mainly under unconfined conditions, except in a few local areas such as beneath Plymouth Harbor. Recharge to the aquifer is derived almost entirely from precipitation and averages about 1.15 million gallons per day per square mile. Water discharges from the aquifer by pumping, evapotranspiration, direct evaporation from the water table, and seepage to streams, ponds, wetlands, bogs, and the ocean. In 1985, water use was about 59.6 million gallons per day, of which 82 percent was used for cranberry production. The Plymouth-Carver aquifer was simulated by a three-dimensional, finite difference ground-water-flow model. Most model boundaries represent the natural hydrologic boundaries of the aquifer. The model simulates aquifer recharge, withdrawals by pumped wells, leakage through streambeds, and discharge to the ocean. The model was calibrated for steady-state and transient conditions. Model results were compared with measured values of hydraulic head and ground-water discharge. Results of simulations indicate that the modeled ground-water system closely simulates actual aquifer conditions. Four hypothetical ground-water development alternatives were simulated to demonstrate the use of the model and to examine the effects on the ground-water system. Simulation of a 2-year period of no recharge and average pumping rates that occurred from 1980-85 resulted in water-level declines exceeding 5 feet throughout most of the aquifer and a decrease of 54 percent in average ground-water discharge to streams. In a second simulation, four wells in the northern part of the area were pumped at 10.4 million gallons per day in excess of rates simulated in the steady-state model for the four wells. This resulted in water-level declines of 2 feet or more in an area of 25 square miles and a decline in average ground-water discharge to streams of 6 percent. When this pumpage was simulated as recharge to the aquifer, water levels beneath the recharge area rose more than 40 feet, and ground-water discharge remained equal to average discharge in the calibrated steady-state model. In a third simulation, all 21 existing production wells were pumped at nearly the design capacity of 17.8 million gallons per day; this pumping rate produced water-level declines of less than 2 feet throughout most of the aquifer. When simulated pumpage was increased to 32.8 million gallons per day from existing wells and from 15 additional wells, the area where water-level declines exceeded 2 feet significantly increased. In another set of simulations, a well field close to a stream was pumped at rates of 2, 4, and 6 million gallons per day. At a pumping rate of 6 million gallons per day, ground-water discharge to the stream decreased 34 percent during periods of normal precipitation and 56 percent during drought conditions.

Massachusetts↗

Ground-water-level monitoring, basin boundaries, and potentiometric surfaces of the aquifer system at Edwards Air Force Base, California, 1992

A ground-water-level monitoring program was implemented at Edwards Air Force Base, California, from January through December 1992 to monitor spatial and temporal changes in poten-tiometric surfaces that largely are affected by ground-water pumping. Potentiometric-surface maps are needed to determine the correlation between declining ground- water levels and the distribution of land subsidence. The monitoring program focused on areas of the base where pumping has occurred, especially near Rogers Lake, and involved three phases of data collection: (1) well canvassing and selection, (2) geodetic surveys, and (3) monthly ground-water-level measurements. Construction and historical water- level data were compiled for 118 wells and pi-ezometers on or near the base, and monthly ground-water-level measurements were made in 82 wells and piezometers on the base. The compiled water-level data were used in conjunction with previously collected geologic data to identify three types of no-flow boundaries in the aquifer system: structural boundaries, a principal-aquifer boundary, and ground-water divides. Heads were computed from ground-water-level measurements and land-surface altitudes and then were used to map seasonal potentiometric surfaces for the principal and deep aquifers underlying the base. Pumping has created a regional depression in the potentiometric surface of the deep aquifer in the South Track, South Base, and Branch Park well-field area. A 15-foot decline in the potentiometric surface from April to September 1992 and 20- to 30-foot drawdowns in the three production wells in the South Track well field caused locally unconfined conditions in the deep aquifer.

California↗