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U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

Quality of wet deposition in the Grand Calumet River Watershed, northwestern Indiana, April 29, 1997–April 28, 1998

The Grand Calumet River, in northwestern Indiana, drains a heavily industrialized area along the southern shore of Lake Michigan. Steel production and petroleum refining are two of the area’s predominant industries. High-temperature processes, such as fossil fuel combustion and steel production, release contaminants to the atmosphere that may result in wet deposition being a major contributor to major-ion and trace-metal loadings in northwestern Indiana and Lake Michigan. A wet-deposition collection site was established at the Gary (Indiana) Regional Airport to monitor the quantity and chemical quality of wet deposition. During a first phase of sampling, 48 wet-deposition samples were collected weekly between June 30, 1992, and August 31, 1993. During a second phase of sampling, 40 wet-deposition samples were collected between October 17, 1995, and November 12, 1996. Forty-two wet-deposition samples were collected during a third phase of sampling, which began April 29, 1997, and was completed April 28, 1998. Wet- deposition samples were analyzed for pH, specific conductance, and selected major ions and trace metals. This report describes the quantity and quality of wet-deposition samples collected during the third sampling phase and compares these findings to the results of the first and second sampling phases. All of the samples collected during the third phase of sampling were of sufficient volumes for at least some of the analyses to be performed. Constituent concentrations from the third sampling phase were not significantly different (at the 5-percent significance level) from those for the second sampling phase. Significant increases, however, were observed in the concentrations of potassium, iron, lead, and zinc when compared to the concentrations observed in the first sampling phase. Weekly loadings were estimated for each constituent measured during the third sampling phase. If constituent concentrations were reported less than the method reporting limit, a range for the weekly loading was computed. The estimated annual loadings of chloride, silica, bromide, copper, and zinc during the third sampling phase were greater than those estimated for the first two sampling phases. The only estimated annual loading in the third sampling phase that was less than the estimated annual loadings observed during the first two sampling phases was sulfate. The estimated annual loadings of calcium, magnesium, nitrate, potassium, barium, lead, iron, and manganese observed during the third sampling phase were greater than the loadings observed during the first sampling phase but less than those observed during the second sampling phase. No significant differences were observed between the quantity of wet deposition collected during the three sampling phases.

Indiana↗

Quality of wet deposition in the Grand Calumet River Watershed, northwestern Indiana, October 17, 1995–November 12, 1996

In June 1992, a wet-deposition collection site was established at the Gary (Indiana) Regional Airport to monitor the quantity and chemical quality of wet deposition. During the first phase of sampling, 48 wet-deposition samples were collected between June 30, 1992, and August 31, 1993. A second phase of sampling began in October 1995. During the second phase of sampling, 40 wet-deposition samples were collected between October 17, 1995, and November 12, 1996. This report presents the findings for the second phase of sampling and compares those results to the first phase of sampling. Northwestern Indiana is a heavily industrialized area. Steel production and petroleum refining are two of the area’s predominant industries. High-temperature processes, such as fossil-fuel combustion and steel production, release contaminants to the atmosphere that may result in wet deposition being a major contributor to major-ion and trace-metal loadings in northwestern Indiana and Lake Michigan. Wet-deposition samples collected during the first and second phases of sampling were analyzed for pH, specific conductance, and selected major ions and trace metals. Forty weekly wet-deposition samples were collected at the Gary (Indiana) Regional Airport during the second phase of sampling. Approximately 1.2 times as much wet deposition was collected during the second phase of sampling compared to the first phase. Statistically significant increases (at the 5-percent significance level) in concentrations of potassium, iron, lead, and zinc were determined for samples collected during the second phase of sampling when compared to the first. No statistically significant differences were determined in constituent concentrations between samples collected during warm weather (April 1 through October 31) and during cold weather (November 1 through March 31). Annual loadings for the second phase of sampling were greater than 2 times the loadings determined during the first phase of sampling for silica, iron, potassium, lead, and zinc.

Indiana↗

Deposition and chemistry of bottom sediments in Cochiti Lake, north-central New Mexico

Bottom sediments were sampled at seven sites in Cochiti Lake in September 1996. Sediment cores penetrating the entire lacustrine sediment sequence were collected at one site near the dam. Surficial sediments were sampled at the near-dam site and six other sites located along the length of the reservoir. Analyses included grain size, major and trace elements, organochlorine compounds, polycyclic aromatic hydrocarbons (PAH's), and radionuclides. Concentrations of trace elements, organic compounds, and radionuclides are similar to those in other Rio Grande reservoirs and are low compared to published sediment-quality guidelines. Most elements and compounds that were detected did not show trends in the age estimated sediment cores with the exception of a decreasing trend in total DDT concentrations from about 1980 to 1992. The mixture of PAH's suggests that the increase is caused by inputs of fuel-related PAH and not combustion- related PAH.

New Mexico↗

Annotated bibliography on artificial recharge of ground water, 1955-67

Artificial ground-water recharge has become more important as water use by agriculture, industry, and municipalities increases. Water management agencies are increasingly interested in potential use of recharge for pollution abatement, waste-water disposal, and re-use and reclamation of locally available supplies. Research projects and theoretical analyses of operational recharge systems show increased scientific emphasis on the practice. Overall ground-water basin management systems generally now contain considerations of artificial recharge, whether by direct or indirect methods. Artificial ground-water recharge is a means of conserving surface runoff for future use in places where it would otherwise be lost, of protecting ground-water basins from salt-water encroachment along coastal areas, and of storing and distributing imported water. The biblio-graphy emphasizes technology; however, annotations of articles on waste-water reclamation, ground-water management and ground-water basin management are included. Subjects closely related to artificial recharge, including colloidal flow through porous media, field or laboratory instrumentation, and waste disposal by deep well injection are included where they specifically relate to potential recharge problems. Where almost the same material has been published in several journals, all references are included on the assumption that some publications may be more readily available to interested persons than others. Other publications, especially those of foreign literature, provided abstracts that were used freely as time limitations precluded obtaining and annotating all materials. Abstracts taken from published sources are noted. These are: "Abstracts of North American Geology," U.S. Department of the Interior, Geological Survey; "Abstracts of Recent Published Material on Foil and Water Conservation," ARS-41 series, Agricultural F.esearch Service, U.S. Department of Agriculture; "Water and1 Water Engineering," published by Fuel and Metallurgical Journals, Ltd., London, England; "Journal of Geophysical Research," American Geophysical Union, Washington, D.C.; "American Society of Civil Engineers Transactions," New York; "Selected Bibliography of Hydrology, United Kingdom, for the Years 1955-59," International Association of Scientific Hydrology; "Water Wells, an Annotated Bibliography," California University Water Resources Center Archives Report 13; "Re-use of Effluent in the Future With an Annotated Bibliography," by G. A. Whetstone, Texas Water Development Board Report 8, Austin, Tex.; "Journal of Water Pollution Control Federation," Washington, D.C.; and "A List of Selected Technical References on Artificial Recharge of Ground-Water Reservoirs," compiled by Roy W. Graves, Tulsa University, Information Services Department, Tulsa, Okla. Other notations are self-explanatory, and initials are those of the authors (DCS, DJG, WK). An unpublished compilation of recharge references by Arnon Arad sponsored by the United Nations Educational, Scientific, and Cultural Organization during a training period with the U.S. Geological Survey was also used. The bibliography is arranged alphabetically by author. Where an author has more than one publication, the arrangement is chronological; where an author has more than one publication in a given year, a, b, c, . . . are added. The indexing is by subject and geographic location. Each article was assigned the key words or phrases to best characterize its contents. Units of measure are as they were in the original article; abbreviations retained are generally those in common use such as mg/1 (milligrams per liter), ppm (parts per million), gpm (gallons per minute), km (kilometers), m (meters), cu m per hr (cubic meters p^r hour), cfs (cubic feet per second), me/1 (milliequivalents per liter), psi (pounds per square inch), BOD (biochemical oxygen demand), sq m (square meters), gpd (gallons per day), and mgd (million gallons per day). The bibliography was prepared because of the worldwide interest in the field of artificial recharge and the need for a single source of references to the literature published since 1954. The work is a sequel to the "Annotated Bibliography on Artificial Recharge of Ground Water Through 1954," by D. K. Todd, U.S. Geological Survey Water-Supply Paper 1477, published in 1959.

Water Supply Paper↗

Movement and fate of creosote waste in ground water, Pensacola, Florida; U.S. Geological Survey toxic waste-ground-water contamination program

Ground- and surface-water contamination by pesticides used in the wood-preserving industry is widespread in the United States. Pine poles were treated with wood preservatives from 1902 to 1981 at a creosote works near Pensacola, Florida. Diesel fuel, creosote, and pentachlorophenol were discharged to two unlined impoundments that had a direct hydraulic connection to the sand-and-gravel aquifer. Evidence of wood-preserving waste contamination appears to be confined to the upper 30 meters of the aquifer. The waste plume extends downgradient approximately 300 meters south toward Pensacola Bay. In 1983, the creosote works site was selected by the U.S. Geological Survey's Office of Hazardous Waste Hydrology as a national research demonstration area to apply the latest techniques for characterizing hazardous waste problems. The multidisciplinary research effort is aimed at studying processes that affect the occurrence, transport, transformations, and fate of the toxic contaminants associated with wood preservatives in the environment. Clusters of two to five wells were constructed at different depths at nine sites to define the depth of contamination. Research studies are investigating sorption, dispersion, dilution, chemical reactions, bacterially mediated transformations, quality assurance, plume hydrodynamics, and the ultimate fate of these complex organic wastes.

Florida↗

Protecting the wildland-urban interface in California: Greenbelts vs thinning for wildfire threats to homes

This study utilized native chaparral and sage scrub shrubs to evaluate the impact of light summer irrigation on live fuel moisture content (LFMC) and predicted fire behavior. As to be expected LFMC varied markedly throughout the year being over 100% in winter in all species and treatments but differed markedly by treatment in the summer and fall. For most species lightly irrigated plants had the highest LFMC in the summer and fall, followed by thinned treatments and controls. These differences in moisture content coupled with structural differences in the vegetation contributed to expected differences in flame length and rate of spread. Lightly irrigated native shrubs planted around homes can reduce fire hazard and at the same time increase faunal diversity and other desirable features of utilizing native vegetation.

California↗

Benthic sulfate reduction along the Chesapeake Bay central channel. II. Temporal controls

Seasonal and interannual controls of benthic sulfate reduction (SR) were examined at 3 sites (upper [UB], mid- [MB] and lower [LB] bay) along the Chesapeake Bay central channel, from early spring through fall, for 6 yr (1989 to 1994). The combined influences of temperature, sulfate, organic loading and bioturbation affected seasonal SR rates differently in the 3 regions. Consistently low SR rates at UB resulted from low overlying-water sulfate concentrations and the dominance of refractory organic terrestrial material. Combined seasonal variation in temperature and sulfate accounted for 50% of the annual variability in 0 to 2 cm depth interval SR rates, while sediment organic content had no significant seasonal influence. In contrast, MB and LB sites had high rates of SR fostered by high levels of overlying water SO42- and organic input dominated by labile phytoplankton detritus. New organic loading (measured as chl a) stimulated 0 to 2 cm SR during spring at both sites. Combined organic quantity (as particulate C and/or N) and temperature accounted for > 75% of the variability in 0 to 2 cm SR at MB during spring and fall. Molecular diffusion supplied 25 to 45% of the SO 42- needed to fuel 0 to 12 cm depth interval SR at MB, with the balance presumably supplied by S-recycling. Interannual differences in summertime SR rates were linked to the extent of freshwater flow during spring, with high-flow years associated with high SR rates at UB and MB, and low rates at LB. The negative trend between benthic SR and river flow at LB may result from the up-estuary transport of senescing organic matter in bottom water, which increases in the lower reach of the estuary with increasing freshwater inflow.

Chesapeake Bay↗

Geochemistry of coastal permafrost and erosion-driven organic matter fluxes to the Beaufort Sea near Drew Point, Alaska

Accelerating erosion of the Alaska Beaufort Sea coast is increasing inputs of organic matter from land to the Arctic Ocean, and improved estimates of organic matter stocks in eroding coastal permafrost are needed to assess their mobilization rates under contemporary conditions. We collected three permafrost cores (4.5–7.5 m long) along a geomorphic gradient near Drew Point, Alaska, where recent erosion rates average 17.2 m year −1 . Down-core patterns indicate that organic-rich soils and lacustrine sediments (12–45% total organic carbon; TOC) in the active layer and upper permafrost accumulated during the Holocene. Deeper permafrost (below 3 m elevation) mainly consists of Late Pleistocene marine sediments with lower organic matter content (∼1% TOC), lower C:N ratios, and higher δ 13 C values. Radiocarbon-based estimates of organic carbon accumulation rates were 11.3 ± 3.6 g TOC m −2 year −1 during the Holocene and 0.5 ± 0.1 g TOC m −2 year −1 during the Late Pleistocene (12–38 kyr BP). Within relict marine sediments, porewater salinities increased with depth. Elevated salinity near sea level (∼20–37 in thawed samples) inhibited freezing despite year-round temperatures below 0°C. We used organic matter stock estimates from the cores in combination with remote sensing time-series data to estimate carbon fluxes for a 9 km stretch of coastline near Drew Point. Erosional fluxes of TOC averaged 1,369 kg C m −1 year −1 during the 21st century (2002–2018), nearly doubling the average flux of the previous half-century (1955–2002). Our estimate of the 21st century erosional TOC flux year −1 from this 9 km coastline (12,318 metric tons C year −1 ) is similar to the annual TOC flux from the Kuparuk River, which drains a 8,107 km 2 area east of Drew Point and ranks as the third largest river on the North Slope of Alaska. Total nitrogen fluxes via coastal erosion at Drew Point were also quantified, and were similar to those from the Kuparuk River. This study emphasizes that coastal erosion represents a significant pathway for carbon and nitrogen trapped in permafrost to enter modern biogeochemical cycles, where it may fuel food webs and greenhouse gas emissions in the marine environment.

Alaska↗

Complex styles of phreatomagmatic explosions at Kīlauea Volcano, Hawaii, controlled by magma structure

Explosive eruptions at basaltic volcanoes remain poorly understood. Kīlauea Volcano is a type locality for basaltic eruptions and is well-known for effusive activity. However, more than 7 m of phreatomagmatic Keanakākoʻi Tephra unit D deposits from explosive eruptions crown the southern rim of the summit caldera and provide a stark reminder of Kīlauea’s explosive past and future potential. We used detailed field observations as well as granulometric and morphological analysis of 100 samples from two proximal sections to assess the eruption style and fragmentation mechanism. The deposits can be divided into four subunits, six different lithofacies, and contain three juvenile tephra components. Each juvenile component shows distinct shape variability resulting from molten fuel-coolant interaction (MFCI) explosions of magma of variable vesicularity. Fragmentation of dense glass generates olive-green ash, fragmentation of low to moderately vesicular magma generates a dark gray ash-lapilli component, and fragmentation of highly vesicular magma generates light-yellow pumice. Our work shows that magma structure impacts MFCI explosion efficiency. Small-scale planar bedding throughout most of the deposit points to a general eruption style of small, frequent explosions generating low plumes. Thicker beds of accretionary lapilli of fine-extremely fine ash are related to very efficient magma-water mixing. Pyroclastic density current (PDC) deposits in the upper part of the stratigraphy contain at least three flows but show no significant dune or cross-bedding structures. We suggest that this is a function of the vent being situated in a caldera that was then ∼600 m deep, where the caldera wall acted as a barrier and changed the flow dynamics to very dilute overspills and co-PDC plume falls over the wall. Deconvolution modeling of the polymodal grain size distributions is used to assess grain size changes of each juvenile component for this deposit, which greatly improves interpretation of lithofacies generation and eruption dynamics. Size-correlated shape parameters show that shape data across a wide size range are needed to accurately track grain shapes. This study demonstrates how careful examination of grain size and shape of juvenile tephra clasts can help volcanologists understand how effusive basaltic volcanoes can become violently explosive.

Hawaii↗

Operationalizing resilience and resistance concepts to address invasive grass-fire cycles

Plant invasions can affect fuel characteristics, fire behavior, and fire regimes resulting in invasive plant-fire cycles and alternative, self-perpetuating states that can be difficult, if not impossible, to reverse. Concepts related to general resilience to disturbance and resistance to invasive plants provide the basis for managing landscapes to increase their capacity to reorganize and adjust following fire, while concepts related to spatial resilience provide the basis for managing landscapes to conserve resources and habitats and maintain connectivity. New, spatially explicit approaches and decision-tools enable managers to understand and evaluate general and spatial resilience to fire and resistance to invasive grasses across large landscapes in arid and semi-arid shrublands and woodlands. These approaches and tools provide the capacity to locate management actions strategically to prevent development of invasive grass-fire cycles and maintain or improve resources and habitats. In this review, we discuss the factors that influence fire regimes, general and spatial resilience to fire, resistance to invasive annual grasses, and thus invasive grass-fire cycles in global arid and semi-arid shrublands and woodlands. The Cold Deserts, Mediterranean Ecoregion, and Warm Deserts of North America are used as model systems to describe how and why resilience to disturbance and resistance to invasive annuals differ over large landscapes. The Cold Deserts are used to illustrate an approach and decision tools for prioritizing areas on the landscape for management actions to prevent development of invasive grass-fire cycles and protect high value resources and habitats and for determining effective management strategies. The concepts and approach herein represent a paradigm shift in the management of these ecosystems, which allows managers to use geospatial tools to identify resilience to disturbance and resistance to invasive plants in order to target conservation and restoration actions where they will provide the greatest benefits.

Frontiers in Ecology and Evolution↗

Modest residual effects of short-term warming, altered hydration, and biocrust successional state on dryland soil heterotrophic carbon and nitrogen cycling

Biological soil crusts (biocrusts) on the Colorado Plateau may fuel carbon (C) and nitrogen (N) cycling of soil heterotrophic organisms throughout the region. Late successional moss and lichen biocrusts, in particular, can increase soil C and N availability, but some data suggest these biocrust types will be replaced by early successional cyanobacterial biocrusts as the region undergoes warming and aridification. In this study, we evaluated the short-term interactive effects of biocrust successional state and elevated temperature on soil heterotrophic C and N cycling (specifically, soil respiration, N 2 O emissions, microbial biomass C and N, and soluble C and N). We collected soils following an 87-day greenhouse mesocosm experiment where the soils had been topped with different biocrust successional states (moss-dominated, cyanobacteria-dominated, or no biocrust) and had experienced different temperatures (ambient and warmed), under an artificial precipitation regime. Following this pre-incubation mesocosm phase, the soils were assessed using a short-term (2-day) laboratory incubation to determine the cumulative effect of the elevated temperature and altered biocrust successional state on the temperature sensitivity of soil heterotrophic C and N cycling. We found that there were interactive effects of biocrust successional state and exposure to warmer temperatures during the mesocosm phase under greenhouse conditions on the rate and temperature sensitivity of soil heterotrophic C and N cycling in laboratory incubations. Soils collected from beneath late successional biocrusts exhibited higher C and N cycling rates than those from beneath early successional crusts, while warming reduced both the magnitude and the temperature sensitivity of C and N cycling. The inhibiting effect of warming, was most evident in soils from beneath late successional biocrusts, which, during the mesocosm phase, also exhibited the greatest reductions in gross primary production and respiration in response to the warming treatment. Taken together, these data suggest that an overall effect of climate warming may be increasing resource limitation of the soil heterotrophic C and N cycles in the region, which may magnify alterations associated with the changes in biocrust community structure documented in previous studies. Overall, results from this study suggest that soil heterotrophic biogeochemical cycling is affected by interactions between temperature and the biocrust community that lives atop the mineral soil, with important implications for C and N cycling into the future.

Nevada↗

Grassification and fast-evolving fire connectivity and risk in the Sonoran Desert, United States

In the southwestern United States, non-native grass invasions have increased wildfire occurrence in deserts and the likelihood of fire spread to and from other biomes with disparate fire regimes. The elevational transition between desertscrub and montane grasslands, woodlands, and forests generally occurs at ∼1,200 masl and has experienced fast suburbanization and an expanding wildland-urban interface (WUI). In summer 2020, the Bighorn Fire in the Santa Catalina Mountains burned 486 km 2 and prompted alerts and evacuations along a 40-km stretch of WUI below 1,200 masl on the outskirts of Tucson, Arizona, a metropolitan area of >1M people. To better understand the changing nature of the WUI here and elsewhere in the region, we took a multidimensional and timely approach to assess fire dynamics along the Desertscrub-Semi-desert Grassland ecotone in the Catalina foothills, which is in various stages of non-native grass invasion. The Bighorn Fire was principally a forest fire driven by a long-history of fire suppression, accumulation of fine fuels following a wet winter and spring, and two decades of hotter droughts, culminating in the hottest and second driest summer in the 125-yr Tucson weather record. Saguaro ( Carnegia gigantea ), a giant columnar cactus, experienced high mortality. Resprouting by several desert shrub species may confer some post-fire resiliency in desertscrub. Buffelgrass and other non-native species played a minor role in carrying the fire due to the patchiness of infestation at the upper edge of the Desertscrub biome. Coupled state-and-transition fire-spread simulation models suggest a marked increase in both burned area and fire frequency if buffelgrass patches continue to expand and coalesce at the Desertscrub/Semi-desert Grassland interface. A survey of area residents six months after the fire showed awareness of buffelgrass was significantly higher among residents that were evacuated or lost recreation access, with higher awareness of fire risk, saguaro loss and declining property values, in that order. Sustained and timely efforts to document and assess fast-evolving fire connectivity due to grass invasions, and social awareness and perceptions, are needed to understand and motivate mitigation of an increasingly fire-prone future in the region.

Arizona↗

Millennial-scale climate and human drivers of environmental change and fire activity in a dry, mixed-conifer forest of northwestern Montana

Warm summer temperatures and longer fire seasons are promoting larger, and in some cases, more fires that are severe in low- and mid-elevation, dry mixed-conifer forests of the Northern Rocky Mountains (NRM). Long-term historical fire conditions and human influence on past fire activity are not well understood for these topographically and biophysically heterogeneous forests. We developed reconstructions of millennial-scale fire activity, vegetation change, and human presence at Black Lake, a small closed-basin lake on the Flathead Indian Reservation in the Mission Valley, Northwestern Montana, United States. Fossil pollen, charcoal, and biomarkers associated with human presence were used to evaluate the interaction between climate variability, fire activity, vegetation change and human activity for the past 7000 years. Comparisons among multiple proxies suggest climate variability acted as the primary control on fire activity and vegetation change from the early Holocene until the late Holocene when records suggest fire activity and climate variability decoupled. Specific biomarkers (5β-stanols including coprostanol and epi-coprostanol) associated with human presence indicate humans were present within the Black Lake watershed for thousands of years, although the inferred intensity of human presence is highly variable. A strong relationship between climate variability and fire activity during the early and mid-Holocene weakens during the last few thousand years, suggesting possible increased influence of humans in mediating fire activity in recent millennia, and/or a shift in the interaction between the distribution and abundance of woody fuel and fire severity. Human-set fires during the cooler and wetter late Holocene may have been aimed at maintaining important cultural resources associated with the heterogeneous mosaic of mixed conifer forests within the Black Lake watershed. The paleoenvironmental reconstruction at Black Lake corroborates archeological records that show humans were present within the Black Lake watershed for over 7000 years. Further research is needed to evaluate the evidence for this continuous presence and the possible role that people played in shaping fire regimes and vegetation within low- to mid-elevation mixed-conifer ecosystems of the NRM.

Montana↗

Environmental drivers of differences in microbial community structure in crude oil reservoirs across a methanogenic gradient

Stimulating in situ microbial communities in oil reservoirs to produce natural gas is a potentially viable strategy for recovering additional fossil fuel resources following traditional recovery operations. Little is known about what geochemical parameters drive microbial population dynamics in biodegraded, methanogenic oil reservoirs. We investigated if microbial community structure was significantly impacted by the extent of crude oil biodegradation, extent of biogenic methane production, and formation water chemistry. Twenty-two oil production wells from north central Louisiana, USA, were sampled for analysis of microbial community structure and fluid geochemistry. Archaea were the dominant microbial community in the majority of the wells sampled. Methanogens, including hydrogenotrophic and methylotrophic organisms, were numerically dominant in every well, accounting for, on average, over 98% of the total Archaea present. The dominant Bacteria groups were Pseudomonas, Acinetobacter , Enterobacteriaceae, and Clostridiales, which have also been identified in other microbially-altered oil reservoirs. Comparing microbial community structure to fluid (gas, water, and oil) geochemistry revealed that the relative extent of biodegradation, salinity, and spatial location were the major drivers of microbial diversity. Archaeal relative abundance was independent of the extent of methanogenesis, but closely correlated to the extent of crude oil biodegradation; therefore, microbial community structure is likely not a good sole predictor of methanogenic activity, but may predict the extent of crude oil biodegradation. However, when the shallow, highly biodegraded, low salinity wells were excluded from the statistical analysis, no environmental parameters could explain the differences in microbial community structure. This suggests that the microbial community structure of the 5 shallow, up-dip wells was different than the 17 deeper, down-dip wells. Also, the 17 down-dip wells had statistically similar microbial communities despite significant changes in environmental parameters between oil fields. Together, this implies that no single microbial population is a reliable indicator of a reservoir's ability to degrade crude oil to methane, and that geochemistry may be a more important indicator for selecting a reservoir suitable for microbial enhancement of natural gas generation.

Louisiana↗

Integrating urban planning and water management through green infrastructure in the United States-Mexico border

Creating sustainable, resilient, and livable cities calls for integrative approaches and collaborative practices across temporal and spatial scales. However, practicability is challenged by institutional, social, and technical complexities and the need to build collective understanding of integrated approaches. Rapid urbanization along the United States-Mexico border, fueled by industrialization, trade, and migration, has resulted in cities confronted with recurrent flooding risk, extended drought, water pollution, habitat destruction and systemic vulnerabilities. The international border, which separates natural and built ecosystems, is both a challenge and an opportunity, making a unique social and institutional setting ideal for testing the integration of urban planning and water management. Our research focuses on fusing multi-functional and multi-scalar green infrastructure to restore ecosystem services through a strategic binational planning process. This paper describes this planning process, including the development and application of both a land suitability analysis and a hydrological model to optimally site green infrastructure in the Nogales, Arizona, United States—Nogales, Sonora, Mexico, cross border region. We draw lessons from this process and stakeholder feedback focused on the potential for urban green infrastructure, to allow for adaptation and even transformation in the face of current and future challenges such as limited resources, underdeveloped governance, bordering, and climate change. In sum, a cross border network of green infrastructure can provide a backbone to connect this transboundary watershed while providing both hydrological and social benefits.

Frontiers in Water↗

Forest resistance to extended drought enhanced by prescribed fire in low elevation forests of the Sierra Nevada

Prescribed fire reduces fire hazards by removing dead and live fuels (small trees and shrubs). Reductions in forest density following prescribed fire treatments (often in concert with mechanical treatments) may also lessen competition so that residual trees might be more likely to survive when confronted with additional stressors, such as drought. The current evidence for these effects is mixed and additional study is needed. Previous work found increased tree survivorship in low elevation forests with a recent history of fire during the early years of an intense drought (2012 to 2014) in national parks in the southern Sierra Nevada. We extend these observations through additional years of intense drought and continuing elevated tree mortality through 2017 at Sequoia and Kings Canyon National Parks. Relative to unburned sites, we found that burned sites had lower stem density and had lower proportions of recently dead trees (for stems ≤47.5 cm dbh) that presumably died during the drought. Differences in recent tree mortality among burned and unburned sites held for both fir (white fir and red fir) and pine (sugar pine and ponderosa pine) species. Unlike earlier results, models of individual tree mortality probability supported an interaction between plot burn status and tree size, suggesting the effect of prescribed fire was limited to small trees. We consider differences with other recent results and discuss potential management implications including trade-offs between large tree mortality following prescribed fire and increased drought resistance.

California↗

Mapping tree density in forests of the southwestern USA using Landsat 8 data

The increase of tree density in forests of the American Southwest promotes extreme fire events, understory biodiversity losses, and degraded habitat conditions for many wildlife species. To ameliorate these changes, managers and scientists have begun planning treatments aimed at reducing fuels and increasing understory biodiversity. However, spatial variability in tree density across the landscape is not well-characterized, and if better known, could greatly influence planning efforts. We used reflectance values from individual Landsat 8 bands (bands 2, 3, 4, 5, 6, and 7) and calculated vegetation indices (difference vegetation index, simple ratios, and normalized vegetation indices) to estimate tree density in an area planned for treatment in the Jemez Mountains, New Mexico, characterized by multiple vegetation types and a complex topography. Because different vegetation types have different spectral signatures, we derived models with multiple predictor variables for each vegetation type, rather than using a single model for the entire project area, and compared the model-derived values to values collected from on-the-ground transects. Among conifer-dominated areas (73% of the project area), the best models (as determined by corrected Akaike Information Criteria (AICc)) included Landsat bands 2, 3, 4, and 7 along with simple ratios, normalized vegetation indices, and the difference vegetation index ( R 2 values for ponderosa: 0.47, piñon-juniper: 0.52, and spruce-fir: 0.66). On the other hand, in aspen-dominated areas (9% of the project area), the best model included individual bands 4 and 2, simple ratio, and normalized vegetation index ( R 2 value: 0.97). Most areas dominated by ponderosa, pinyon-juniper, or spruce-fir had more than 100 trees per hectare. About 54% of the study area has medium to high density of trees (100–1000 trees/hectare), and a small fraction (4.5%) of the area has very high density (>1000 trees/hectare). Our results provide a better understanding of tree density for identifying areas in need of treatment and planning for more effective treatment. Our analysis also provides an integrated method of estimating tree density across complex landscapes that could be useful for further restoration planning.

New Mexico↗