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At least 1,261 records · Page 70Linked to original sources

Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine

Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c 11 to m 3 Carboniferous coals, mercury contents range from 0.02 to 3.5 ppm (whole-coal dry basis). Mercury is well correlated with pyritic sulfur (0.01 to 3.2 wt.%), with an r 2 of 0.614 (one outlier excluded). Sulfides in these samples show enrichment of minor constituents in late-stage pyrite formed as a result of interaction of coal with hydrothermal fluids. Mine water sampled at depth and at surface collection points does not show enrichment of trace metals at harmful levels, indicating pyrite stability at subsurface conditions. Four samples of coal exposed in the defunct open-cast Nikitovka mercury mines in Gorlovka have extreme mercury contents of 12.8 to 25.5 ppm. This coal was formerly produced as a byproduct of extracting sandstone-hosted cinnabar ore. Access to these workings is unrestricted and small amounts of extreme mercury-rich coal are collected for domestic use, posing a limited human health hazard. More widespread hazards are posed by the abandoned Nikitovka mercury processing plant, the extensive mercury mine tailings, and mercury enrichment of soils extending into residential areas of Gorlovka.

Donbas mines↗

The coefficient of friction of chrysotile gouge at seismogenic depths

We report new strength data for the serpentine mineral chrysotile at effective normal stresses, σ n between 40 and 200 MPa in the temperature range 25°-280°C. Overall, the coefficient of friction, μ (= shear stress/effective normal stress) of water-saturated chrysotile gouge increases both with increasing temperature and σ n , but the rates vary and the temperature-related increases begin at ~100°C. As a result, a frictional strength minimum (μ = 0.1) occurs at low σ n at about 100°C. Maximum strength (μ = 0.55) results from a combination of high normal stress and high temperature. The low-strength region is characterized by velocity strengthening and the high-strength region by velocity-weakening behavior. Thoroughly dried chrysotile has μ = 0.7 and is velocity-weakening. The frictional properties of chrysotile can be explained by its tendency to adsorb large amounts of water that acts as a lubricant during shear. The water is progressively driven off the fiber surfaces with increasing temperature and pressure, causing chrysotile to approach its dry strength. Depth profiles for a chrysotile-lined fault constructed from these data would pass through a strength minimum at ~3 km depth, where sliding should be stable. Below that depth, strength increases rapidly as does the tendency for unstable (seismic) slip. Such a trend would not have been predicted from the room-temperature data. These results therefore illustrate the potential hazards of extrapolating room-temperature friction data to predict fault zone behavior at depth. This depth profile for chrysotile is consistent with the pattern of slip on the Hayward fault, which creeps aseismically at shallow depths but which may be locked below 5 km depth.

International Geology Review↗

Global biotic events evident in the Paleogene marine strata of the eastern San Francisco Bay area, California

Paleogene marine strata in the eastern San Francisco Bay area are exposed in discontinuous outcrops in the various tectonic blocks. Although there are many missing intervals, the strata were previously thought to span most of the Paleocene and Eocene. Revision of biochronology and calibration to the international time scale as well as to the global oxygen isotope curve and sea-level curves indicate that the strata are latest Paleocene through middle Eocene in age and contain faunal changes that are linked to the overall global climate trends and hyperthermals of that time. The Paleocene-Eocene thermal maximum, third Eocene thermal maximum, early Eocene climatic optimum, and middle Eocene climatic optimum are all identified in the eastern San Francisco Bay marine strata. The dominance of smoothly finished, dissolution-resistant agglutinated benthic foraminiferal species corresponds with a rapid shoaling and rapid deepening (overcorrection) of the calcium compensation depth associated with the Paleocene-Eocene thermal maximum. The benthic foraminiferal extinction event was a dramatic turnover of benthic foraminiferal species that occurred shortly after the onset of the Paleocene-Eocene thermal maximum. Opportunistic species such as Bulimina , which indicate environmental stress and lower oxygen conditions, are commonly associated with the Paleocene-Eocene thermal maximum. Environmental changes similar to those observed during the Paleocene-Eocene thermal maximum also characterize the third Eocene thermal maximum, based on the agglutinated and opportunistic species. The early Eocene climatic optimum is noted by the presence of foraminiferal assemblages that indicate a stable, warmer water mass, abundant food, and an influx of terrigenous material. The onset and end of the middle Eocene climatic optimum are recognized by the dominance of siliceous microfossils. This research updates the age and environmental interpretations of the Paleogene formations occurring in the vicinity of Mount Diablo, eastern San Francisco Bay area. The revised interpretations, which are based on foraminifers and calcareous nannoplankton, make it possible to identify various global climatic and biotic events.

California↗

Hydrology of the San Luis Valley, south-central Colorado

An investigation of the water resources of the Colorado part of the San Luis Valley was begun in 1966 by the U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board. (See index map, fig. 1). The purpose of the investigation is to provide information for planning and implementing improved water-development and management practices. The major water problems in the San Luis Valley include (1) waterlogging, (2) waste of water by nonbeneficial evapotranspiration, (3) deterioration of ground-water chemical quality, and (4) failure of Colorado to deliver water to New Mexico and Texas in accordance with the Rio Grande Compact. This report describes the hydrologic environment, extent of water-resource development, and some of the problems related to that development. Information presented is based on data collected from 1966 to 1968 and on previous studies. Subsequent reports are planned as the investigation progresses. The San Luis Valley extends about 100 miles from Poncha Pass near the northeast corner of Saguache County, Colo., to a point about 16 miles south of the Colorado-New Mexico State line. The total area is 3,125 square miles, of which about 3,000 are in Colorado. The valley is nearly flat except for the San Luis Hills and a few other small areas. The Colorado part of the San Luis Valley, which is described in this report, has an average altitude of about 7,700 feet. Bounding the valley on the west are the San Juan Mountains and on the east the Sangre de Cristo Mountains. Most of the valley floor is bordered by alluvial fans deposited by streams originating in the mountains, the most extensive being the Rio Grande fan (see block diagram, fig. 2 in pocket). Most of the streamflow is derived from snowmelt from 4,700 square miles of watershed in the surrounding mountains. The northern half of the San Luis Valley is internally drained and is referred to as the closed basin. The lowest part of this area is known locally as the "sump." The remainder of the valley is drained by the Rio Grande and its tributaries. The climate of the San Luis Valley is arid, and a successful agricultural economy would not be possible without irrigation. It is characterized by cold winters, moderate summers, and much sunshine. The average annual precipitation on the valley floor ranges from 7 to 10 inches. More than half the precipitation occurs from July to September. Moisture deficiency in the valley is shown by the graph comparing pan evaporation and precipitation {fig. 3}. For the years 1961-67 average pan evaporation for the period April through September was 52.25 inches, but average precipitation for the period was only 5.02 inches. Average annual precipitation was 7.8 inches. Owing to the short growing season (90-120 days), crops a.re restricted mainly to barley, oats, potatoes, and other vegetables.

Colorado↗

Monitoring Colonias Development along the United States-Mexico Border: A Process Application using GIS and Remote Sensing in Douglas, Arizona, and Agua Prieta, Sonora

The U.S. Department of Housing and Urban Development (HUD) and the U.S. Geological Survey (USGS) have developed a joint project to create Internet-enabled geographic information systems (GIS) that will help cities along the United States-Mexico border deal with issues related to colonias. HUD defines colonias as rural neighborhoods in the United States-Mexico border region that lack adequate infrastructure or housing and other basic services. They typically have high poverty rates that make it difficult for residents to pay for roads, sanitary water and sewer systems, decent housing, street lighting, and other services through assessment. Many Federal agencies recognize colonias designations and provide funding assistance. It is the intention of this project to empower Arizona-Sonora borderland neighborhoods and community members by recognizing them as colonias. This recognition will result in eligibility for available economic subsidies and accessibility to geospatial tools and information for urban planning. The steps to achieve this goal include delineation of colonia-like neighborhoods, identification of their urbanization over time, development of geospatial databases describing their infrastructure, and establishment of a framework for distributing Web-based GIS decision support systems. A combination of imagery and infrastructure information was used to help delineate colonia boundaries. A land-use change analysis, focused on urbanization in the cities over a 30-year timeframe, was implemented. The results of this project are being served over the Internet, providing data to the public as well as to participating agencies. One of the initial study areas for this project was the City of Douglas, Ariz., and its Mexican sister-city Agua Prieta, Sonora, which are described herein. Because of its location on the border, this twin-cities area is especially well suited to international manufacturing and commerce, which has, in turn, led to an uncontrolled spread of colonias. The USGS worked with local organizations in developing the Web-based GIS database. Community involvement ensured that the database and map server would meet the current and long-term needs of the communities and end users. Partners include Federal agencies, State agencies, county officials, town representatives, universities, and youth organizations, as well as interested local advocacy groups and individuals. A significant component of this project was development of relationships and partnerships in the border towns for facilitating binational approaches to land management.

Open-File Report↗

Storm tide monitoring during the blizzard of January 26-28, 2015, in eastern Massachusetts

The U.S. Geological Survey (USGS) deployed a temporary monitoring network of six storm surge sensors and four barometric pressure sensors along the Atlantic coast in eastern Massachusetts, from Plymouth to Newburyport, before the blizzard of January 26–28, 2015 (Blizzard of January 2015), to record the timing and magnitude of storm tide at select locations where forecasters had predicted the potential for coastal flooding. Additionally, water-level data were recorded and transmitted in near real-time from four permanent USGS tidal stations—three on Cape Cod and one near the mouth of the Merrimack River in Newburyport. The storm surge sensors were deployed at previously established fixed sites outfitted with presurveyed mounting brackets. The mounting brackets were installed in 2014 as part of the USGS Surge, Wave, and Tide Hydrodynamic (SWaTH) Network ( https://water.usgs.gov/floods/STN/ ), which was funded through congressional supplemental appropriations for the U.S. Department of the Interior after the devastating landfall of Hurricane Sandy on October 29, 2012 (Simmons and others, 2014). The USGS received this funding to enable better understanding of coastal flooding hazards in the region, to improve preparedness for future coastal storms, and to increase the resilience of coastal cities, infrastructure, and natural systems in the region (Buxton and others, 2013). The USGS established 163 monitoring locations along the New England coast for the SWaTH Network, including 70 sites in Massachusetts. The Blizzard of January 2015 was a powerful and destructive storm that threatened public safety and led to widespread cancellations and delays at transportation hubs, schools, and businesses in Massachusetts, including, for example, the closure of General Edward Lawrence Logan (Boston-Logan) International Airport and cancellation of all flights on January 27 and a statewide travel ban issued for January 28. A total of 24.6 inches of snowfall and winds up to 45 miles per hour (mi/hr) were recorded at the airport. Several coastal communities were affected and experienced flooding, overwash, and damage to seawalls, dwellings, and other infrastructure. In Scituate, the National Guard was sent to rescue people from flooding, and power was cut to some areas of the town to prevent electrical fires.

Massachusetts↗

Proceedings of the 2015 international summit on fibropapillomatosis: Global status, trends, and population impacts

The 2015 International Summit on Fibropapillomatosis (FP) was convened in Honolulu, Hawaii June 11-14, 2015. Scientists from around the world were invited to present results from sea turtle monitoring and research programs as they relate to the global status, trends, and population impacts of FP on green turtles. The participants engaged in discussions that resulted in the following conclusions: 1.Globally, FP has long been present in wild sea turtle populations the earliest mention was in the late 1800s in the Florida Keys. 2.FP primarily affects medium-sized immature turtles in coastal foraging pastures. 3.Expression of FP differs across ocean basins and to some degree within basins. Turtles in the Southeast US, Caribbean, Brazil, and Australia rarely have oral tumors (inside the mouth cavity), whereas they are common and often severe in Hawaii. Internal tumors (on vital organs) occur in the Atlantic and Hawaii, but only rarely in Australia. Liver tumors are common in Florida but not in Hawaii. 4.Recovery from FP through natural processes, when the affliction is not severe, has been documented in wild populations globally. 5.FP causes reduced survivorship, but documented mortality rates in Australia and Hawaii are low. The mortality impact of FP is not currently exceeding population growth rates in some intensively monitored populations (e.g., Florida, Hawaii) as evidenced by increasing nesting trends despite the incidence of FP in immature foraging populations. 6.Pathogens, hosts, and potential disease and environmental cofactors have the capacity to change; while we are having success now, there needs to be continued monitoring to detect changes in the distribution, occurrence, and severity of the disease. 7.While we do not have clear evidence to provide the direct link, globally, the preponderance of sites with a high frequency of FP tumors are areas with some degree of degradation resulting from altered watersheds. Watershed management and responsible coastal development may be the best approach for reducing the spread and prevalence of the disease. 8.Future research efforts should employ a multi-factorial ecological approach (e.g., virology, parasitology, genetics, health, diet, habitat use, water quality, etc.) since there are likely several environmental cofactors involved in the expression of the disease, which is still thought to be caused by a herpesvirus. 9.Minimum FP data collection in new areas should include: individual identification (photo ID, PIT tags, etc.), standard measurements (length and weight), presence/absence of tumors, tumor severity, body condition, oral examination, method of capture, and effort

NOAA Technical Memorandum↗

An evaluation of a reagentless method for the determination of total mercury in aquatic life

Multiple treatment (i.e., drying, chemical digestion, and oxidation) steps are often required during preparation of biological matrices for quantitative analysis of mercury; these multiple steps could potentially lead to systematic errors and poor recovery of the analyte. In this study, the Direct Mercury Analyzer (Milestone Inc., Monroe, CT) was utilized to measure total mercury in fish tissue by integrating steps of drying, sample combustion and gold sequestration with successive identification using atomic absorption spectrometry. We also evaluated the differences between the mercury concentrations found in samples that were homogenized and samples with no preparation. These results were confirmed with cold vapor atomic absorbance and fluorescence spectrometric methods of analysis. Finally, total mercury in wild captured largemouth bass (n = 20) were assessed using the Direct Mercury Analyzer to examine internal variability between mercury concentrations in muscle, liver and brain organs. Direct analysis of total mercury measured in muscle tissue was strongly correlated with muscle tissue that was homogenized before analysis (r = 0.81, p < 0.0001). Additionally, results using this integrated method compared favorably (p < 0.05) with conventional cold vapor spectrometry with atomic absorbance and fluorescence detection methods. Mercury concentrations in brain were significantly lower than concentrations in muscle (p < 0.001) and liver (p < 0.05) tissues. This integrated method can measure a wide range of mercury concentrations (0-500 ??g) using small sample sizes. Total mercury measurements in this study are comparative to the methods (cold vapor) commonly used for total mercury analysis and are devoid of laborious sample preparation and expensive hazardous waste. ?? Springer 2006.

Water, Air, & Soil Pollution↗

Influence of an igneous intrusion on the inorganic geochemistry of a bituminous coal from Pitkin County, Colorado

Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions of the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resources potential for coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions on the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resource potential of coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.

International Journal of Coal Geology↗

Examining progress toward achieving the Ten Steps of the Rome Declaration on Responsible Inland Fisheries

Inland capture fisheries provide food for nearly a billion people and are important in the livelihoods of millions of households worldwide. Although there are limitations to evaluating many of the contributions made by inland capture fisheries, there is growing recognition by the international community that these services make critical contributions, most notably to food security and livelihoods in rural populations in those low-income countries with extensive freshwater resources. With the increasing appreciation of the key role of inland fisheries to the health and well-being of human populations globally, the Food and Agriculture Organization of the United Nations and Michigan State University convened the 2015 global conference, Freshwater, fish, and the future – cross-sectoral approaches to sustain livelihoods, food security, and aquatic ecosystems. What emerged from the interactions between inland fisheries scientists, resource managers, policy makers, and community representatives from across the world, was a forward-looking call-to-action culminating with the 2015 Rome Declaration “Ten Steps to Responsible Inland Fisheries” (FAO and MSU 2016). Four years after this landmark conference and Declaration, we seek to advance discussion on the “Ten Steps,” namely, what successful implementation looks like, assess current examples of implementation, suggest potential signals of progress, and provide some specific, indicative examples of progress for each step. While there are promising signs of progress, we conclude that there remains a strong need to galvanize momentum for sustained action to ensure that inland fish and fisheries are accounted for and incorporated into broader water resource management discussions and frameworks.

Fish and Fisheries↗

Mercury and halogens in coal

Apart from mercury itself, coal rank and halogen content are among the most important factors inherent in coal that determine the proportion of mercury captured by conventional controls during coal combustion. This chapter reviews how mercury in coal occurs, gives available concentration data for mercury in U.S. and international commercial coals, and provides an overview of the natural variation in halogens that influence mercury capture. Three databases, the U.S. Geological Survey coal quality (USGS COALQUAL) database for in-ground coals, and the 1999 and 2010 U.S. Environmental Protection Agency (EPA) Information Collection Request (ICR) databases for coals delivered to power stations, provide extensive results for mercury and other parameters that are compared in this chapter. In addition to the United States, detailed characterization of mercury is available on a nationwide basis for China, whose mean values in recent compilations are very similar to the United States in-ground mean of 0.17&thinsp;ppm mercury. Available data for the next five largest producers (India, Australia, South Africa, the Russian Federation, and Indonesia) are more limited and with the possible exceptions of Australia and the Russian Federation, do not allow nationwide means for mercury in coal to be calculated. Chlorine in coal varies as a function of rank and correspondingly, depth of burial. As discussed elsewhere in this volume, on a proportional basis, bromine is more effective than chlorine in promoting mercury oxidation in flue gas and capture by conventional controls. The ratio of bromine to chlorine in coal is indicative of the proportion of halogens present in formation waters within a coal basin. This ratio is relatively constant except in coals that have interacted with deep-basin brines that have reached halite saturation, enriching residual fluids in bromine. Results presented here help optimize mercury capture by conventional controls and provide a starting point for implementation of mercury-specific controls discussed elsewhere in this volume.

Book chapter↗

Projecting species’ vulnerability to climate change: Which uncertainty sources matter most and extrapolate best?

Species distribution models (SDMs) are commonly used to assess potential climate change impacts on biodiversity, but several critical methodological decisions are often made arbitrarily. We compare variability arising from these decisions to the uncertainty in future climate change itself. We also test whether certain choices offer improved skill for extrapolating to a changed climate and whether internal cross-validation skill indicates extrapolative skill. We compared projected vulnerability for 29 wetland-dependent bird species breeding in the climatically dynamic Prairie Pothole Region, USA. For each species we built 1,080 SDMs to represent a unique combination of: future climate, class of climate covariates, collinearity level, and thresholding procedure. We examined the variation in projected vulnerability attributed to each uncertainty source. To assess extrapolation skill under a changed climate, we compared model predictions with observations from historic drought years. Uncertainty in projected vulnerability was substantial, and the largest source was that of future climate change. Large uncertainty was also attributed to climate covariate class with hydrological covariates projecting half the range loss of bioclimatic covariates or other summaries of temperature and precipitation. We found that choices based on performance in cross-validation improved skill in extrapolation. Qualitative rankings were also highly uncertain. Given uncertainty in projected vulnerability and resulting uncertainty in rankings used for conservation prioritization, a number of considerations appear critical for using bioclimatic SDMs to inform climate change mitigation strategies. Our results emphasize explicitly selecting climate summaries that most closely represent processes likely to underlie ecological response to climate change. For example, hydrological covariates projected substantially reduced vulnerability, highlighting the importance of considering whether water availability may be a more proximal driver than precipitation. However, because cross-validation results were correlated with extrapolation results, the use of cross-validation performance metrics to guide modeling choices where knowledge is limited was supported.

Prairie Pothole Region↗

Summary of November 2010 meeting to evaluate turbidite data for constraining the recurrence parameters of great Cascadia earthquakes for the update of national seismic hazard maps

This report summarizes a meeting of geologists, marine sedimentologists, geophysicists, and seismologists that was held on November 18&ndash;19, 2010 at Oregon State University in Corvallis, Oregon. The overall goal of the meeting was to evaluate observations of turbidite deposits to provide constraints on the recurrence time and rupture extent of great Cascadia subduction zone (CSZ) earthquakes for the next update of the U.S. national seismic hazard maps (NSHM). The meeting was convened at Oregon State University because this is the major center for collecting and evaluating turbidite evidence of great Cascadia earthquakes by Chris Goldfinger and his colleagues. We especially wanted the participants to see some of the numerous deep sea cores this group has collected that contain the turbidite deposits. Great earthquakes on the CSZ pose a major tsunami, ground-shaking, and ground-failure hazard to the Pacific Northwest. Figure 1 shows a map of the Pacific Northwest with a model for the rupture zone of a moment magnitude M w 9.0 earthquake on the CSZ and the ground shaking intensity (in ShakeMap format) expected from such an earthquake, based on empirical ground-motion prediction equations. The damaging effects of such an earthquake would occur over a wide swath of the Pacific Northwest and an accompanying tsunami would likely cause devastation along the Pacifc Northwest coast and possibly cause damage and loss of life in other areas of the Pacific. A magnitude 8 earthquake on the CSZ would cause damaging ground shaking and ground failure over a substantial area and could also generate a destructive tsunami. The recent tragic occurrence of the 2011 M w 9.0 Tohoku-Oki, Japan, earthquake highlights the importance of having accurate estimates of the recurrence times and magnitudes of great earthquakes on subduction zones. For the U.S. national seismic hazard maps, estimating the hazard from the Cascadia subduction zone has been based on coastal paleoseismic evidence of great earthquakes over the past 5,000 years. The instrumental catalog of earthquakes is of little use for constraining the hazard of the CSZ, because there are virtually no recorded earthquakes on most of the plate interface of the CSZ. There are no historical accounts in the past 150 years of large earthquakes on most of the CSZ. Until about 20 years ago, some interpreted this lack of recent and historical earthquakes as an indicator that the subduction zone was slipping aseismically and could not produce a great earthquake. The work of Brian Atwater and others, in the late 1980s and the 1990s (Atwater, 1987, 1992; Atwater and others, 1995; Nelson and others, 1996; Clague, 1997; Atwater and Hemphill-Haley, 1997; Atwater and others, 2004) demonstrated that submerged forests, buried soils, tsunami deposits, and liquefaction along and near the coast were compelling evidence of repeated great Cascadia earthquakes over at least the past 5,000 years. Atwater and Hemphill-Haley (1997) concluded from paleoseismic evidence at Willapa Bay, Washington, that great earthquakes ruptured the CSZ with an average recurrence time of about 500 years. The date of the last great CSZ earthquake, January 26, 1700, was established from historical records of the so-called orphan tsunami in Japan that is inferred to have been produced by this earthquake (Satake and others, 1996, 2003; Atwater and others, 2005) and is consistent with tree-ring data from drowned forests in Washington and Oregon. From modeling the observations of the tsunami, Satake and others (2003) estimated a moment magnitude of about 9.0 for this earthquake. Many other paleoseismic sites have been investigated along the Pacific Northwest coast from Vancouver Island to northern California and show evidence of great CSZ earthquakes. Nelson and others (2006) summarized the dates found from these studies and proposed correlations between sites indicating the extent of rupture for individual events. Dating of inferred tsunami deposits in Bradley Lake, Oregon by Kelsey and others (2005), as well as tsunami and subsidence evidence from Six Rivers, Oregon (Kelsey and others, 2002) and Coquille River (Witter and others, 2003), indicates that there were probably M w 8 ruptures in the southern portion of the CSZ in addition to the M w 9 events that rupture the whole length of the CSZ (Nelson and others, 2006). A parallel development over the past 20 years or more is the use of deep-sea turbidite deposits for identifying and dating great Cascadia earthquakes over the past 10,000 years (Adams, 1990; Goldfinger and others, 2003, 2008, in press; Goldfinger, 2011). Turbidites are sediment deposits in the deep ocean from turbidity currents, which are energetic flows of sediment and water along the continental shelf and slope. Adams (1990), using the counts of turbidites in deep-sea cores off the coast of Oregon and Washington collected and analyzed by Griggs (1969) and Griggs and others (1969), proposed that these turbidites were caused by the shaking of great Cascadia earthquakes. Part of his reasoning was that the number (13) of turbidite deposits that occurred since deposition of the Mazama Ash 7,000 years ago gave a recurrence time of about 500 years, consistent with that derived from the coastal submergence data. Adams (1990) also proposed the &ldquo;confluence test&rdquo; which evaluates the number of turbidites for submarine channels that form a confluence. He reported that the number of turbidites in the single downstream channel equaled the number in each of the tributary channels. He reasoned that this indicated that the turbidites in each tributary were simultaneously triggered and were, therefore, caused by a common forcing agent. He concluded that shaking from extended ruptures of great Cascadia earthquakes was the most likely cause of these turbidites. Based on the paleoseismic evidence of past great earthquakes, the hazard from the Cascadia subduction zone was included in the 1996 U.S. NSHM (Frankel and others, 1996), which were the basis for seismic provisions in the 2000 International Building Code. These hazard maps used the paleoseismic studies to constrain the recurrence rate of great CSZ earthquakes. Goldfinger and his colleagues have since collected many more deep ocean cores and done extensive analysis on the turbidite deposits that they identified in the cores (Goldfinger and others, 2003, 2008, in press; Goldfinger, 2011). Using their dating of the sediments and correlation of features in the logs of density and magnetic susceptibility between cores, they developed a detailed chronology of great earthquakes along the CSZ for the past 10,000 years (Goldfinger and others, in press). These correlations consist of attempting to match the peaks and valleys in logs of density and magnetic susceptibility between cores separated, in some cases, by hundreds of kilometers. Based on this work, Goldfinger and others (2003, 2008, in press) proposed that the turbidite evidence indicated the occurrence of great earthquakes (M w 8) that only ruptured the southern portion of the CSZ, as well as earthquakes with about M w 9 that ruptured the entire length of the CSZ. For the southernmost portion of the CSZ, Goldfinger and others (in press) proposed a recurrence time of M w 8 or larger earthquakes of about 230 years. This proposed recurrence time was shorter than the 500 year time that was incorporated in one scenario in the NSHM&rsquo;s. It is important to note that the hazard maps of 1996 and later also included a scenario or set of scenarios with a shorter recurrence time for M w 8 earthquakes, using rupture zones that are distributed along the length of the CSZ (Frankel and others, 1996; Petersen and others, 2008). Originally, this scenario was meant to correspond to the idea that some of the 500-year averaged ruptures seen in the paleoseismic evidence could have been a series of M w 8 earthquakes that occurred over a short period of time (a few decades), rather than M w 9 earthquakes. Figure 2 shows the logic tree for the CSZ used in the 2008 NSHM&rsquo;s (Petersen and others, 2008). This logic tree includes whole CSZ rupture earthquakes (M w 8.8&ndash;9.2) and partial CSZ rupture earthquakes (M w 8.0&ndash;8.7). In this latest version of the NSHM&rsquo;s, the effective recurrence time of earthquakes on the CSZ with moment magnitudes greater than or equal to 8.0 over the various models is about 270 years (Petersen and others, 2008). This recurrence time applies to the entire CSZ, so that the hazard from great earthquakes was approximately equal along the whole zone, although the hazard estimates taper on the northern and southern ends of the CSZ, because of the way rupture zones of M w 8 earthquakes were distributed along the strike of the CSZ. The NSHM will be updated in 2013, as part of the standard update cycle that corresponds to the update cycle of the national model building codes that are based on the seismic hazard maps. A meeting was necessary to assemble a wide group of experts to hear Dr. Goldfinger explain his methodology for dating and correlating the turbidites and for developing the earthquake chronology. The overall goal of the workshop was to evaluate observations of turbidite deposits to provide constraints on the recurrence times and rupture extents of great Cascadia subduction zone earthquakes for the next update of the NSHM. Before the meeting, participants were supplied with the U.S. Geological Survey (USGS) Professional Paper of Goldfinger and others (in press), as well as material from Brian Atwater and Alan Nelson. The agenda of the meeting was developed by Art Frankel, with assistance from Chris Goldfinger, Brian Atwater, Alan Nelson, Mark Petersen, and Craig Weaver. The meeting was hosted by Chris Goldfinger of Oregon State University. We stress that it is difficult to evaluate in a two-day meeting the large amount of work that Goldfinger and his colleagues have done over the past 15 years or more. This meeting is the first step in a process that develops the inputs to the update of the national maps. The conclusions of this workshop will be discussed and possibly modified at the regional Pacific Northwest workshop for the hazard maps to be held in early 2012. Vetting new research results using informed expert opinion is an integral part of updating the national maps and does not reflect on the veracity of these results.

Cascadia↗

National assessment of shoreline change: historical change along the north coast of Alaska, U.S.-Canadian border to Icy Cape

Beach erosion is a persistent problem along most open-ocean shores of the United States. Along the Arctic coast of Alaska, coastal erosion is widespread, may be accelerating, and is threatening defense and energy-related infrastructure, coastal habitats, and Native communities. As coastal populations continue to expand and infrastructure and habitat are increasingly threatened by erosion, there is increased demand for accurate information regarding past and present trends and rates of shoreline movement. There also is a need for a comprehensive analysis of shoreline change with metrics that are consistent from one coastal region to another. To meet these national needs, the U.S. Geological Survey is conducting an analysis of historical shoreline changes along the open-ocean sandy shores of the conterminous United States and parts of Hawaii, Alaska, and the Great Lakes. One purpose of this work is to develop standard, repeatable methods for mapping and analyzing shoreline change so that periodic, systematic, and internally consistent updates regarding coastal erosion and land loss can be made nationally. This report on shoreline change along the north coast of Alaska, between the U.S.-Canadian border and Icy Cape, is one in a series of regionally focused reports on historical shoreline change. Previous investigations include analyses and descriptive reports for the coasts of the U.S. Gulf of Mexico, the Southeast Atlantic, California, the New England and Mid-Atlantic, portions of Hawaii, and the Pacific Northwest coasts of Oregon and Washington. Similar to the earlier reports in this series, this report summarizes the methods of analysis, documents and describes the results of the analysis, and explains historical trends and rates of shoreline change. This Alaska shoreline change assessment differs from previously published shoreline change assessments in that: (1) only two historical shorelines (from the 1940s and 2000s eras) were available for the Alaska study area whereas four or more shorelines (from 1850 to 2002) were available for the other assessments and, thus, only end-point rates for one long-term analysis period are reported here, compared to a combination of long-term and short-term rates as reported in other studies; (2) modern (2000s era) shorelines in this study represent a visually derived land-water interface position versus an elevation based, tidally referenced shoreline position; and (3) both exposed open-ocean and sheltered mainland-lagoon shorelines and rates of change are included in this study compared to other locations where only exposed open-ocean sandy shorelines or bluff edges were evaluated. No distinction was made between sand or gravel beaches, and the base of the unconsolidated coastal bluff was considered the shoreline where no fronting beach existed.

Alaska↗

Source switching maintains dissolved organic matter chemostasis across discharge levels in a large temperate river network

Dissolved organic matter (DOM) helps regulate aquatic ecosystem structure and function. In small streams, DOM concentrations are controlled by transport of terrestrial materials to waterways, and are thus highly variable. As rivers become larger, the River Continuum Concept hypothesizes that internal primary production is an increasingly important DOM source, but direct evidence is limited. Recently, the Pulse-Shunt Concept postulated that terrestrial DOM concentrations in larger rivers increase with flow and temperature, which seemingly contradicts previously reported DOM chemostasis in large rivers. This study estimates daily gross primary production (GPP) in 13 streams and rivers across the Connecticut River watershed (watershed areas 0.4–25,019 km 2 ) from 2015 through 2017. Chemostasis of DOM concentrations is maintained by a switch from autochthonous sources of DOM at low flows to terrestrial sources of DOM at high flows in a large temperate river and to a lesser degree in smaller tributaries. At low flow, autochthonous DOM linked to aquatic GPP is the dominant fraction of the DOM pool in large rivers. This autochthonous DOM maintains chemostasis in the main stem and to a lesser extent upstream. Thus, in larger rivers, low-flow autochthonous production stabilizes DOM concentrations during the summer, a critical time for riverine ecology. Consistent with the Pulse-Shunt Concept, terrigenous DOM is the dominant fraction of DOM during higher flow periods and about 70% of annual DOM fluxes to the coast are terrestrial. This pattern of DOM switching is potentially widespread in temperate watersheds with implications to both inland waters and coastal ecosystems.

Ecosystems↗

A software tool for rapid flood inundation mapping

The GIS Flood Tool (GFT) was developed by the U.S. Geological Survey with support from the U.S. Agency for International Development’s Office of U.S. Foreign Disaster Assistance to provide a means for production of reconnaissance-level flood inundation mapping for data-sparse and resource-limited areas of the world. The GFT has also attracted interest as a tool for rapid assessment flood inundation mapping for the Flood Inundation Mapping Program of the U.S. Geological Survey. The GFT can fill an important gap for communities that lack flood inundation mapping by providing a first-estimate of inundation zones, pending availability of resources to complete an engineering study. The tool can also help identify priority areas for application of scarce flood inundation mapping resources. The technical basis of the GFT is an application of the Manning equation for steady flow in an open channel, operating on specially processed digital elevation data. The GFT is implemented as a software extension in ArcGIS. Output maps from the GFT were validated at 11 sites with inundation maps produced previously by the Flood Inundation Mapping Program using standard one-dimensional hydraulic modeling techniques. In 80 percent of the cases, the GFT inundation patterns matched 75 percent or more of the one-dimensional hydraulic model inundation patterns. Lower rates of pattern agreement were seen at sites with low relief and subtle surface water divides. Although the GFT is simple to use, it should be applied with the oversight or review of a qualified hydraulic engineer who understands the simplifying assumptions of the approach.

Open-File Report↗

Sea turtles, light pollution, and citizen science: A preliminary report

Sea turtles are an important ecological resource for Gulf Islands National Seashore’s (Gulf Islands) waters and shorelines. Regionally, sea turtles face anthropogenic threats from situations such as entanglement in fishing gear and ingestion of marine debris, as well as possible changes in sex ratios due to increasing temperatures related to human-induced global warming. Locally, light pollution from residential, commercial, and industrial neighborhoods from nearby cities impacts the entirety of Gulf Islands, which spans 160 miles along the Gulf Coast, from Florida to Mississippi, and includes critical habitat for threatened and endangered sea turtles. Because light pollution has been hypothesized to negatively impact sea turtle nesting and hatchling survival, Gulf Islands undertook an effort to understand the relationship between light pollution and sea turtles and create unique educational and outreach opportunities by launching a citizen science program called Turtle Teens Helping in the Seashore (Turtle THIS). At the onset, the Turtle THIS program had two primary goals: quantify the association between light pollution and sea turtle nesting and hatching events using rigorous scientific methods; and initiate a citizen science volunteer program to provide youth with hands-on science and environmental stewardship roles, where they also gain employable skills and career opportunities. With multiple scientific hypotheses to consider, the development of a citizen science program became crucial. Such circumstances allowed Turtle THIS to grow a volunteer and intern program, quantify hypothesized light effects on sea turtles through developed methods, and begin to gather preliminary findings.

Florida↗

Biogenic origin of coalbed gas in the northern Gulf of Mexico Coastal Plain, U.S.A

New coal-gas exploration and production in northern Louisiana and south-central Mississippi, Gulf of Mexico Basin, is focused on the Wilcox Group (Paleocene–Eocene), where the depth to targeted subbituminous C to high volatile C bituminous coal beds ranges from 300 to 1680 m, and individual coal beds have a maximum thickness of about 6 m. Total gas content (generally excluding residual gas) of the coal beds ranges from less than 0.37 cm 3 /g (as-analyzed or raw basis; 1.2 cm 3 /g, dry, ash free basis, daf) at depths less than 400 m, to greater than 7.3 cm 3 /g (as-analyzed basis; 8.76 cm 3 /g, daf) in deeper (> 1,500 m) parts of the basin. About 20 Wilcox coal-gas wells in northern Louisiana produce from 200 to 6485 m 3 of gas/day and cumulative gas production from these wells is approximately 25 million m 3 (as of December, 2006). U.S. Geological Survey assessment of undiscovered, technically recoverable gas resources in the Gulf of Mexico Coastal Plain, including northern and south-central Mississippi, indicates that coal beds of the Wilcox Group contain an estimated mean total 109.3 million m 3 (3.86 trillion ft 3 ) of producible natural gas. To determine the origin of the Wilcox Group coal gases in northern Louisiana, samples of gas, water, and oil were collected from Wilcox coal and sandstone reservoirs and from under- and overlying Late Cretaceous and Eocene carbonate and sandstone reservoirs. Isotopic data from Wilcox coal-gas samples have an average δ 13 C CH4 value of − 62.6‰ VPDB (relative to Vienna Peedee Belemnite) and an average δ D CH4 value of − 199.9‰ VSMOW (relative to Vienna Standard Mean Ocean Water). Values of δ 13 C CO2 range from − 25.4 to 3.42‰ VPDB. Produced Wilcox saline water collected from oil, conventional gas, and coalbed gas wells have δ D H2O values that range from − 27.3 to − 18.0‰ VSMOW. These data suggest that the coal gases primarily are generated in saline formation water by bacterial reduction of CO 2 . Shallow (< 150 m) Wilcox coal beds containing freshwater have little or no biogenic gas. Molecular and isotopic analyses of gas samples collected from conventional gas and oil wells suggests that both biogenic and thermogenic gases are present in and adjacent to the Wilcox intervals that contain biogenic coal gases. Oil, probably sourced from thermally mature, down-structural-dip parts of the Wilcox Group, is produced from sandstones within the coal-bearing interval. Gas chromatograms of C 10+ saturated hydrocarbons from Wilcox oils show a depletion of n -alkanes probably resulting from biodegradation of the oil. Isotopic composition of the gases associated with the oils is of mixed themogenic and biogenic origin (average δ 13 C CH4 = − 44.4‰ VPDB, and average δ D CH4 = − 182.4‰ VSMOW).

International Journal of Coal Geology↗