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Geochemical assessment of metals and dioxin in sediment from the San Carlos Reservoir and the Gila, San Carlos, and San Francisco Rivers, Arizona

In October 2004, we sampled stream-bed sediment, terrace sediment, and sediment from the San Carlos Reservoir to determine the spatial and chronological variation of six potentially toxic metals-Cu, Pb, Zn, Cd, As, and Hg. Water levels in the San Carlos Reservoir were at a 20-year low at an elevation of 2,409 ft (734.3 m). Four cores were taken from the reservoir: one from the San Carlos River arm, one from the Gila River arm, and two from the San Carlos Reservoir just west of the Pinal County line. Radioisotope chronometry (7Be, 137Cs, and 210Pb) conducted on sediment from the reservoir cores provides a good chronological record back to 1959. Chronology prior to that, during the 1950s, is based on our interpretation of the 137Cs anomaly in reservoir cores. During and prior to the 1950s, the reservoir was dry and sediment-accumulation rates were irregular; age control based on radioisotope data was not possible. We recovered sediment at the base of one 4-m-long core that may date back to the late 1930s. The sedimentological record contains two discrete events, one about 1978-83 and one about 1957, where the Cu concentration in reservoir sediment exceeded recommended sediment quality guidelines and should have had an effect on sensitive aquatic and benthic organisms. Concentrations of Zn determined in sediment deposited during the 1957(?) event also exceeded recommended sediment quality guidelines. Concentration data for Cu from the four cores clearly indicate that the source of this material was upstream on the Gila River. Lead isotope data, coupled with the geochemical data from a 2M HCl-1 percent H2O2 leach of selected sediment samples, show two discrete populations of data. One represents the dominant sediment load derived from the Safford Valley, and a second reflects sediment derived from the San Francisco River. The Cu concentration spikes in the reservoir cores have chemical and Pb isotope signatures that indicate that deposits in a porphyry copper deposit from the Morenci district is the likely source of these Cu-rich sedimentary deposits. Copper concentrations and Pb isotope data in premining terrace-sediment deposits indicate that the Cu peaks could not have resulted from erosion of premining sediment from terrace deposits downstream on the Gila River. The chemical and Pb isotope data also indicate that agricultural practices in the Safford Valley have resulted in an increased sediment load to the Gila River since large-scale farming began, prior to the time when the San Carlos Reservoir was built. Analyses of dioxin, which is an impurity in one of the herbicides used in the late 1960s and early 1970s, were completed in sediment from one of the cores in the reservoir to determine whether any of these pesticide residues have accumulated in the reservoir sediment. Dioxin concentration is expressed in terms of its toxicity (toxic equivalent concentration or TEQ). Concentrations of dioxin in the sediment ranged from 0.68 to 1.37 pg/g and are less than any of the benchmark concentrations recommended as threshold values for adverse effects of dioxin in sediment (> 2.5-10 pg/g).

Scientific Investigations Report↗

Sediment transport by streams in the Walla Walla River basin, Washington and Oregon, July 1962 - June 1965

The Walla Walla River basin covers about 1,760 square miles in southeastern Washington and northeastern Oregon. From the 6,000-foot crest of the Blue Mountains on the east to the 340-foot altitude of Lake Wallula (Columbia River) on the west, the basin is drained by the Touchet River and Dry Creek, entirely within Washington, and by Mill Creek, North and South Forks Walla Walla River, and Pine Creek-Dry Creek, which all head in Oregon. The central lowland of the basin is bordered on the north by Eureka Flat, Touchet slope, and Skyrocket Hills, on the east by the Blue Mountains, and on the south by the Horse Heaven Hills. The basin is underlain by basalt of the Columbia River Group, which .is the only consolidated rock to crop out in the region. Various unconsolidated fluviatile, lacustrine, and eolian sediments cover the basalt. In the western part of the basin the basalt is overlain by lacustrine deposits of silt and sand which in places are mantled by varying thicknesses of loessal deposits. In the northern and central parts of the basin the loess is at least 100 feet thick. The mountainous eastern part of the basin is underlain at shallow depth by basalt which has a residual soil mantle weathered from the rock. The slopes of the mountains are characterized by alluvial fans and deeply cut stream valleys ,filled with alluvium of sand, gravel, and cobbles. Average annual precipitation in the basin ranges from less than 10 inches in the desert-like areas of the west to more than 45 inches in the timbered mountains of the east; 65 percent of the precipitation occurs from October through March. The average runoff from the basin is about 4.8 inches per year. Most of the runoff occurs during late winter and early spring. Exceptionally high runoff generally results from rainfall and rapid melting of snow on partially frozen ground. During the study period, July 1964-June 1965, average annual sediment yields in the basin ranged from 420 tons per square mile in the mountainous area to more than 4,000 tons per square mile in the extensively cultivated northern and central parts of the basin, which are drained by the Touchet River and Dry Creek. The Touchet River and Dry Creek transported approximately 80 percent of the total sediment load discharged from the Walla Walla River basin. The highest concentrations were contributed by the loessal deposits in the Dry Creek drainage. Two runoff events resulting from rain and snowmelt on partially frozen ground produced 76 percent of the suspended sediment discharged from the basin during the study period. The maximum concentration measured, 316,000 milligrams per liter, was recorded for Dry Creek at Lowden on December 23. 1964. Daily suspended-sediment concentrations for the Walla Walla River near Touchet exceeded 700 milligrams per liter about 10 percent of the time, and 14,000 milligrams per liter about 1 percent of the time. The discharge-weighted mean concentration for the 3-year period of study was 7,000 milligrams per liter. Silt predominates in the suspended sediment transported by all streams in the basin. On the average, sediment from streams draining the Blue Mountains was composed of 20 percent sand, 60 percent silt, and 20 percent clay ; for streams draining the Blue Mountains slope-Horse Heaven Hills area, the percentages are 9, 65, and 26, respectively ; and for those draining the Skyrocket Hills-Touchet slope, the percentages are 5, 75, and 20, respectively. The bedload in the mountain and upland streams was estimated to be about 5-12 percent as much as the suspended load. For the Walla Walla River and its tributaries in the lower basin area, the bedload was estimated to be only about 2-8 percent as much as the suspended load.

Oregon, Washington↗

Geomorphology, active tectonics, and landscape evolution in the Mid-Atlantic region

In 2014, the geomorphology community marked the 125th birthday of one of its most influential papers, “The Rivers and Valleys of Pennsylvania” by William Morris Davis. Inspired by Davis’s work, the Appalachian landscape rapidly became fertile ground for the development and testing of several grand landscape evolution paradigms, culminating with John Hack’s dynamic equilibrium in 1960. As part of the 2015 GSA Annual Meeting, the Geomorphology, Active Tectonics, and Landscape Evolution field trip offers an excellent venue for exploring Appalachian geomorphology through the lens of the Appalachian landscape, leveraging exciting research by a new generation of process-oriented geomorphologists and geologic field mapping. Important geomorphologic scholarship has recently used the Appalachian landscape as the testing ground for ideas on long- and short-term erosion, dynamic topography, glacial-isostatic adjustments, active tectonics in an intraplate setting, river incision, periglacial processes, and soil-saprolite formation. This field trip explores a geologic and geomorphic transect of the mid-Atlantic margin, starting in the Blue Ridge of Virginia and proceeding to the east across the Piedmont to the Coastal Plain. The emphasis here will not only be on the geomorphology, but also the underlying geology that establishes the template and foundation upon which surface processes have etched out the familiar Appalachian landscape. The first day focuses on new and published work that highlights Cenozoic sedimentary deposits, soils, paleosols, and geomorphic markers (terraces and knickpoints) that are being used to reconstruct a late Cenozoic history of erosion, deposition, climate change, and active tectonics. The second day is similarly devoted to new and published work documenting the fluvial geomorphic response to active tectonics in the Central Virginia seismic zone (CVSZ), site of the 2011 M 5.8 Mineral earthquake and the integrated record of Appalachian erosion preserved on the Coastal Plain. The trip concludes on Day 3, joining the Kirk Bryan Field Trip at Great Falls, Virginia/ Maryland, to explore and discuss the dramatic processes of base-level fall, fluvial incision, and knickpoint retreat.

Virginia↗

Sequence stratigraphic and sedimentologic significance of biogenic structures from a late Paleozoic marginal- to open-marine reservoir, Morrow Sandstone, subsurface of southwest Kansas, USA

Integrated ichnologic, sedimentologic, and stratigraphic studies of cores and well logs from Lower Pennsylvanian oil and gas reservoirs (lower Morrow Sandstone, southwest Kansas) allow distinction between fluvio-estuarine and open marine deposits in the Gentzler and Arroyo fields. The fluvio-estuarine facies assemblage is composed of both interfluve and valley-fill deposits, encompassing a variety of depositional environments such as fluvial channel, interfluve paleosol, bay head delta, estuary bay, restricted tidal flat, intertidal channel, and estuary mouth. Deposition in a brackish-water estuarine valley is supported by the presence of a low diversity, opportunistic, impoverished marine ichnofaunal assemblage dominated by infaunal structures, representing an example of a mixed, depauperate Cruziana and Skolithos ichnofacies. Overall distribution of ichnofossils along the estuarine valley was mainly controlled by the salinity gradient, with other parameters, such as oxygenation, substrate and energy, acting at a more local scale. The lower Morrow estuarine system displays the classical tripartite division of wave-dominated estuaries (i.e. seaward-marine sand plug, fine-grained central bay, and sandy landward zone), but tidal action is also recorded. The estuarine valley displays a northwest-southeast trend, draining to the open sea in the southeast. Recognition of valley-fill sandstones in the lower Morrow has implications for reservoir characterization. While the open marine model predicts a "layer-cake" style of facies distribution as a consequence of strandline shoreline progradation, identification of valley-fill sequences points to more compartmentalized reservoirs, due to the heterogeneity created by valley incision and subsequent infill. The open-marine facies assemblage comprises upper, middle, and lower shoreface; offshore transition; offshore; and shelf deposits. In contrast to the estuarine assemblage, open marine ichnofaunas are characterized by a high diversity of biogenic structures representing the activity of a benthic fauna developed under normal salinity conditions. Trace fossil and facies analyses allow environmental subdivision of the shoreface-offshore successions and suggest deposition in a weakly storm-affected nearshore area. An onshore-offshore replacement of the Skolithos ichnofacies by the Cruziana ichnofacies is clearly displayed. The lower Morrow fluvio-estuarine valley was incised during a drop of sea level coincident with the Mississippian-Pennsylvanian transition, but was mostly filled during a subsequent transgression. The transgressive nature of the estuarine infill is further indicated by the upward replacement of depauperate brackish-water trace fossil assemblages by the open-marine Cruziana ichnofacies. Additional stratal surfaces of allostratigraphic significance identified within the estuary include the bayline surface, the tidal ravinement surface, the wave ravinement surface, and a basinwide flooding surface recording inundation of the valley interfluves. A younger sequence boundary within the lower Morrow is also recorded in the Gentzler field at the base of a forced regression shoreface, demarcated by the firmground Glossifungites ichnofacies, indicating a rapid basinward facies migration during a sea-level drop. Trace fossil models derived from the analysis of Mesozoic and Cenozoic reservoirs are generally applicable to the study of these late Paleozoic reservoirs. Pennsylvanian brackish-water facies differ ichnologically from their post-Paleozoic counterparts, however, in that they have: (1) lower trace fossil diversity, (2) lower degree of bioturbation, (3) scarcity of crustacean burrows, (4) absence of firmground suites, and (5) absence of ichnotaxa displaying specific architectures designed to protect the tracemaker from salinity fluctuations. Morrow open-marine ichnofaunas closely resemble their post-Paleozoic equivalents. ?? 2002 Elsevier Science B.V. All rights reserved.

Sedimentary Geology↗

Dated wood from Alaska and the Yukon: Implications for forest refugia in Beringia

Postulations on the existence of forest refugia in parts of Beringia during the last glacial have been, in large part, based on ambiguous evidence. Existing data on radiocarbon-dated and identified fossil wood and macrofossils from Alaska and northwest Canada are synthesized here and are augmented by results of palynological studies in an effort to show the persistence of some, and total extinction of other, tree and large shrub species. Possible dispersal routes taken by species that reinvaded Beringia in postglacial times are also reconstructed from the fossil record. Macrofossil and pollen evidence, when combined with climatic factors, makes cottonwood a good candidate for survival during the last glacial. Larch and aspen are also candidates, though the evidence for them is less positive. Pollen and macrofossils of alder are very scarce in deposits of the last glacial age, and if it survived at all, it was probably in very isolated vegetatively reproducing clones. Shrub birch may have been present in Beringia, but tree birch probably was reintroduced during the Holocene. Spruce also appears to have been absent in Alaska from about 30,000 to 11,500 yr ago and probably reinvaded Beringia from a refugium south of the Laurentide ice sheet.

Alaska↗

Uranium-series ages of corals, sea level history, and palaeozoogeography, Canary Islands, Spain: an exploratory study for two Quaternary interglacial periods

We present the first U-series ages of corals from emergent marine deposits on the Canary Islands. Deposits at + 20 m are 481 ± 39 ka, possibly correlative to marine isotope stage (or MIS) 11, while those at + 12 and + 8 m are 120.5 ± 0.8 ka and 130.2 ± 0.8 ka, respectively, correlative to MIS 5.5. The age, elevations, and uplift rates derived from MIS 5.5 deposits on the Canary Islands allow calculations of hypothetical palaeo-sea levels during the MIS 11 high sea stand. Estimates indicate that the MIS 11 high sea stand likely was at least + 9 m (relative to present sea level) and could have been as high as + 24 m. The most conservative estimates of palaeo-sea level during MIS 11 would require an ice mass loss equivalent to all of the modern Greenland and West Antarctic ice sheets; the more extreme estimates would require additional ice mass loss from the East Antarctic ice sheet. Extralimital southern species of mollusks, found in both MIS 11 and MIS 5.5 deposits on the Canary Islands, imply warmer-than-modern sea surface temperatures during at least a part of MIS 11 and much warmer sea surface temperatures during at least a part of MIS 5.5. Both MIS 11 and MIS 5.5 marine deposits on the Canary Islands contain extralimital northern species of mollusks as well, indicating cooler-than-present waters at times during these interglacial periods. We hypothesize that the co-occurrence of extralimital southern and northern species of marine invertebrates in the fossil record of the Canary Islands reflects its geographic location with respect to major synoptic-scale controls on climate and ocean currents. Previous interglacials may have been characterized by early, insolation-forced warming, along with northward migration of the intertropical convergence zone (ITCZ), accompanied by weakened trade winds and diminished upwelling. This allowed the arrival of extralimital southern taxa from the tropical Senegalese faunal province. During later parts of the MIS 11 and 5.5 interglacials, decreased insolation may have resulted in southward migration of the ITCZ, strengthened trade winds, and re-establishment of upwelling. Such conditions may have brought about not only local extinction of the Senegalese fauna, but allowed southward migration of the cooler-water Mediterranean fauna to the Canary Islands in the later parts of interglacials, a complex palaeoclimate record that is mirrored in the deep-sea core record.

Canary Islands↗

Making it and breaking it in the Midwest: Continental assembly and rifting from modeling of EarthScope magnetotelluric data

A three-dimensional lithospheric-scale resistivity model of the North American mid-continent has been estimated based upon EarthScope magnetotelluric data. Details of the resistivity model are discussed in relation to lithospheric sutures, defined primarily from aeromagnetic and geochronologic data, which record the southward growth of the Laurentian margin in the Proterozoic. The resistivity signature of the 1.1 Ga Mid-continent Rift System is examined in detail, in particular as relates to rift geometry, extent, and segmentation. An unrecognized expanse of (concealed) Proterozoic deltaic deposits in Kansas is identified and speculated to result from axial drainage along the southwest rift arm akin to the Rio Grande delta which drains multiple rift basins. A prominent conductor traces out Cambrian rifting in Arkansas, Missouri, Tennessee, and Kentucky; this linear conductor has not been imaged before and suggests that the Cambrian rift system may have been more extensive than previously thought. The highest conductivity within the mid-continent is imaged in Minnesota, Michigan, and Wisconsin where it is coincident with Paleoproterozoic metasedimentary rocks. The high conductivity is attributed to metallic sulfides, and in some cases, graphite. The former is a potential source of sulfur for multiple mineral deposits types, occurrences of which are found throughout the region. Finally, the imprint left within the mantle following the 1.1 Ga rifting event is examined. Variations in lithospheric mantle conductivity are observed and are interpreted to reflect variations in water content (depleted versus metasomatized mantle) imprinted upon the mantle by the Keweenawan mantle plume.

Precambrian Research↗

Isotopes in North American Rocky Mountain snowpack 1993–2014

We present ∼1300 new isotopic measurements (δ 18 O and δ 2 H) from a network of snowpack sites in the Rocky Mountains that have been sampled since 1993. The network includes 177 locations where depth-integrated snow samples are collected each spring near peak accumulation. At 57 of these locations snowpack samples were obtained for 10–21 years and their isotopic measurements provide unprecedented spatial and temporal documentation of snowpack isotope values at mid-latitudes. For environments where snowfall accounts for the majority of annual precipitation, snowmelt is likely to have the strongest influence on isotope values retained in proxy archives. In this first presentation of the dataset we (1) describe the basic features of the isotope values in relation to the Global Meteoric Water Line (GMWL), (2) evaluate space for time substitutions traditionally used to establish δ 18 O-temperature relations, (3) evaluate site-to-site similarities across the network and identify those that are the most regionally representative, (4) examine atmospheric circulation patterns for several years with spatially coherent isotope patterns, and (5) provide examples of the implications this new dataset has for interpreting paleoclimate records (Bison Lake, Colorado and Minnetonka Cave, Idaho). Results indicate that snowpack δ 18 O is rarely a simple proxy of temperature. Instead, it exhibits a high degree of spatial heterogeneity and temporal variance that reflect additional processes such as vapor transport and post-depositional modification. Despite these complexities we identify consistent climate-isotope patterns and regionally representative locations that serve to better define Holocene hydroclimate estimates and their uncertainty. Climate change has and will affect western U.S. snowpack and we suggest these changes can be better understood and anticipated by oxygen and hydrogen isotope-based reconstructions of Holocene hydroclimate using a process-based understanding of the controls on snowpack isotope ratios.

Colorado, Idaho, Montana, New Mexico, Wyoming↗

Structure and stress state of Hawaiian island basalts penetrated by the Hawaii Scientific Drilling Project deep core hole

As part of the Hawaii Scientific Drilling Project (HSDP), an exploratory hole was drilled in 1993 to a depth of 1056 meters below sea level (mbsl) and a deeper hole was drilled to 3098 mbsl in 1999. A set of geophysical well logs was obtained in the deeper hole that provides fundamental information regarding the structure and the state of stress that exist within a volcanic shield. The acoustic televiewer generates digital, magnetically oriented images of the borehole wall, and inspection of this log yields a continuous record of fracture orientation with depth and also with age to 540 ka. The data depict a clockwise rotation in fracture strike through the surficial Mauna Loa basalts that settles to a constant heading in the underlying Mauna Kea rocks. This behavior reflects the depositional slope directions of lavas and the locations of volcanic sources relative to the drill site. The deviation log delineates the trajectory of the well bore in three-dimensional space. This path closely follows changes in fracture orientation with depth as the drill bit is generally prodded perpendicular to fracture strike during the drilling process. Stress-induced breakouts observed in the televiewer log identify the orientations ot the maximum and minimum horizontal principal stresses to be north-south and east-west, respectively. This stress state is attributed to the combination of a sharp break in onshore-offshore slope that reduces stress east-west and the emergence of Kilauea that increases stress north-south. Breakouts are extensive and appear over approximately 30% of the open hole. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Deformation of the late Miocene to Pliocene Inyo Surface, eastern Sierra region, California

A middle and late Miocene erosion surface, the Inyo Surface, underlies late Miocene mafic flows in the White Mountains and late Miocene and (or) early Pliocene flows elsewhere in the eastern Sierra region. The Inyo Surface is correlated with an erosion surface that underlies late Miocene mafic flows in the central and northern Sierra Nevada. The mafic flows had outpourings similar to flood basalts, although of smaller volume, providing paleohorizontal and paleolowland indicators. The flows filed and locally topped the existing landscape forming broad plateau-like flats. Topographic relief in the region was characterized by weathered and rounded slopesp rior to late Miocene mafic magmatism. Relicts of the older landscape lie adjacent to late Miocene and early Pliocene basalt-covered lowlands that now occur within the crests of ranges that have 2500-3000 m relief and dramatically steep escarpments. Late Miocene mafic flows that lie on the crest of the Sierra Nevada adjacent to the White Mountains predate significant activity on the Sierra Nevada frontal fault zone. These deposits and accompanying erosion surfaces provide excellent strain markers for reconstructing part of the Walker Lane north of the Garlock fault and west of the Amargosa drainage, here referred to as the eastern Sierra region. The Inyo Surface is a compound erosional surface that records at least four major erosion events during the Cenozoic. These four surfaces were first recognized on the Kern Plateau and named from oldest to youngest, the Summit Upland, the Subsummit Plateau, the Chagoopa Plateau, and the Canyon. The three older surfaces have also been subsequently modifi ed by Pleistocene glaciation. The compound erosion surface, which is locally overlain by late Miocene mafic flows in the northern and central Sierra Nevada, is here referred to as the Lindgren Surface. Correlatives in the eastern Sierra region are found in the White Mountains, Inyo Mountains, Darwin Plateau, Coso Range, and nearby ranges. Copyright ?? 2009 The Geological Society of America.

Special Paper of the Geological Society of America↗

Erosion, storage, and transport of sediment in two subbasins of the Rio Puerco, New Mexico

Arroyos in the American Southwest proceed through cut-and-fill cycles that operate at centennial to millennial time scales. The geomorphic community has put much effort into understanding the causes of arroyo cutting in the late Quaternary and in the modern record (late 1800s), while little effort has gone into understanding how arroyos fill and the sources of this fill. Here, we successfully develop a geographic information system (GIS)-modeled sediment budget that is based on detailed field measurements of hillslope and channel erosion and deposition. Field measurements were made in two arroyo basins draining different lithologies and undergoing different land disturbance (Volcano Hill Wash, 9.30 km 2 ; Arroyo Chavez, 2.11 km 2 ) over a 3 yr period. Both basins have incised channels that formed in response to the late nineteenth-century incision of the Rio Puerco. Large volumes of sediment were generated during arroyo incision, equal to more than 100 yr of the current annual total sediment load (bed load + suspended load) in each basin. Downstream reaches in both arroyos are presently aggrading, and the main source of the sediment is from channel erosion in upstream reaches and first- and second-order tributaries. The sediment budget shows that channel erosion is the largest source of sediment in the current stage of the arroyo cycle: 98% and 80% of the sediment exported out of Volcano Hill Wash and Arroyo Chavez, respectively. The geomorphic surface most affected by arroyo incision and one of the most important sediment sources is the valley alluvium, where channel erosion, gullying, soil piping, and grazing all occur. Erosion rates calculated for the entire Volcano Hill Wash (-0.26 mm/yr) and Arroyo Chavez (-0.53 mm/yr) basins are higher than the modeled upland erosion rates in each basin, reflecting the large contributions from channel erosion. Erosion rates in each basin are affected by a combination of land disturbance (grazing) and lithology--erodible sandstones and shales in Arroyo Chavez compared with basalt for Volcano Hill Wash. Despite these differences, hillslope sediment yields are similar to long-term denudation rates. As the arroyo fills over time from mouth to headwaters, hillslope sediment becomes a more significant sediment source.

New Mexico↗

A single-degree-of-freedom model for non-linear soil amplification

For proper understanding of soil behavior during earthquakes and assessment of a realistic surface motion, studies of the large-strain dynamic response of non-linear hysteretic soil systems are indispensable. Most of the presently available studies are based on the assumption that the response of a soil deposit is mainly due to the upward propagation of horizontally polarized shear waves from the underlying bedrock. Equivalent-linear procedures, currently in common use in non-linear soil response analysis, provide a simple approach and have been favorably compared with the actual recorded motions in some particular cases. Strain compatibility in these equivalent-linear approaches is maintained by selecting values of shear moduli and damping ratios in accordance with the average soil strains, in an iterative manner. Truly non-linear constitutive models with complete strain compatibility have also been employed. The equivalent-linear approaches often raise some doubt as to the reliability of their results concerning the system response in high frequency regions. In these frequency regions the equivalent-linear methods may underestimate the surface motion by as much as a factor of two or more. Although studies are complete in their methods of analysis, they inevitably provide applications pertaining only to a few specific soil systems, and do not lead to general conclusions about soil behavior. This report attempts to provide a general picture of the soil response through the use of a single-degree-of-freedom non-linear-hysteretic model. Although the investigation is based on a specific type of nonlinearity and a set of dynamic soil properties, the method described does not limit itself to these assumptions and is equally applicable to other types of nonlinearity and soil parameters.

Open-File Report↗

Structural and stratigraphic framework, and spatial distribution of permeability of the Atlantic Coastal Plain, North Carolina to New York

This report describes and interprets the results of a detailed subsurface mapping program undertaken in that part of the Atlantic Coastal Plain which extends from the South Carolina and North Carolina border through Long Island, N.Y. Data obtained from more than 2,200 wells are analyzed. Seventeen chronostratigraphic units are mapped in the subsurface. They range in age from Jurassic(?) to post-Miocene. The purpose of the mapping program was to determine the external and internal geometry of mappable chronostratigraphic units and to derive and construct a permeability-distribution network for each unit based upon contrasts in the textures and compositions of its contained sediments. The report contains a structure map and a combined isopach, lithofacies, and permeability-distribution map for each of the chronostratigraphic units delineated in the subsurface. In addition, it contains a map of the top of the basement surface. These maps, together with 36 stratigraphic cross sections, present a three-dimensional view of the regional subsurface hydrogeology. They provide focal points of reference for a discussion of regional tectonics, structure, stratigraphy, and permeability distribution. Taken together and in chronologic sequence, the maps constitute a detailed sedimentary model, the first such model to be constructed for the middle Atlantic Coastal Plain. The chronostratigraphic units mapped record a structural history dominated by lateral and vertical movement along a system of intersecting hinge zones. Taphrogeny, related to transcurrent faulting, is the dominant type of deformation that controlled the geometry of the sedimentary model. Twelve of the seventeen chronostratigraphic units mapped have depositional alinements and thickening trends that are independent of the present-day configuration of the underlying basement surface. These 12 units, classified as genetically unrooted units, are assigned to a first-order tectonic stage. A structural model is proposed whose alinements of positive and negative structural features are accordant with the depositional geometry of the chronostratigraphic units assigned to this tectonic stage. The dominant features of the structural model are northeast-plunging half grabens arranged en echelon and bordered by northeast-plunging fault-block anticlines. Tension-type hinge zones that strike north lie athwart the half grabens. Five of the seventeen chronostratigraphic units mapped have depositional alinements and thickening trends that are accordant with the present-day configuration of the underlying basement surface. These five units, classified as genetically rooted units, are assigned to a second-order tectonic stage. A structural model is proposed whose alinements of positive and negative features are accordant with the depositional geometry of the chronostratigraphic units assigned to this tectonic stage. The dominant feature of this model is a graben that stands tangential to southeast-plunging asymmetrical anticlines. Tension-type hinge zones that strike northeast lie athwart the graben.

Delaware, Maryland, New Jersey, New York, North Ca↗

Water-Quality Conditions of Chester Creek, Anchorage, Alaska, 1998-2001

Between October 1998 and September 2001, the U.S. Geological Survey's National Water-Quality Assessment Program evaluated the water-quality conditions of Chester Creek, a stream draining forest and urban settings in Anchorage, Alaska. Data collection included water, streambed sediments, lakebed sediments, and aquatic organisms samples from urban sites along the stream. Urban land use ranged from less than 1 percent of the basin above the furthest upstream site to 46 percent above the most downstream site. Findings suggest that water quality of Chester Creek declines in the downstream direction and as urbanization in the watershed increases. Water samples were collected monthly and during storms at a site near the stream's mouth (Chester Creek at Arctic Boulevard) and analyzed for major ions and nutrients. Water samples collected during water year 1999 were analyzed for selected pesticides and volatile organic compounds. Concentrations of fecal-indicator bacteria were determined monthly during calendar year 2000. During winter, spring, and summer, four water samples were collected at a site upstream of urban development (South Branch of South Fork Chester Creek at Tank Trail) and five from an intermediate site (South Branch of South Fork Chester Creek at Boniface Parkway). Concentrations of calcium, magnesium, sodium, chloride, and sulfate in water increased in the downstream direction. Nitrate concentrations were similar at the three sites and all were less than the drinking-water standard. About one-quarter of the samples from the Arctic Boulevard site had concentrations of phosphorus that exceeded the U.S. Environmental Protection Agency (USEPA) guideline for preventing nuisance plant growth. Water samples collected at the Arctic Boulevard site contained concentrations of the insecticide carbaryl that exceeded the guideline for protecting aquatic life. Every water sample revealed a low concentration of volatile organic compounds, including benzene, toluene, tetrachloroethylene, methyl tert-butyl ether, and chloroform. No water samples contained volatile organic compounds concentrations that exceeded any USEPA drinking-water standard or guideline. Fecal-indicator bacteria concentrations in water from the Arctic Boulevard site commonly exceeded Federal and State guidelines for water-contact recreation. Concentrations of cadmium, copper, lead, and zinc in streambed sediments increased in the downstream direction. Some concentrations of arsenic, chromium, lead, and zinc in sediments were at levels that can adversely affect aquatic organisms. Analysis of sediment chemistry in successive lakebed-sediment layers from Westchester Lagoon near the stream's mouth provided a record of water-quality trends since about 1970. Concentrations of lead have decreased from peak levels in the mid-1970s, most likely because of removing lead from gasoline and lower lead content in other products. However, concen-trations in recently-deposited lakebed sediments are still about 10 times greater than measured in streambed sediments at the upstream Tank Trail site. Zinc concentrations in lakebed sediments also increased in the early 1970s to levels that exceeded guidelines to protect aquatic life and have remained at elevated but variable levels. Pyrene, benz[a]anthracene, and phenanthrene in lakebed sediments also have varied in concentrations and have exceeded protection guidelines for aquatic life since the 1970s. Concentrations of dichloro-diphenyl-trichloroethane, polychlorinated biphenyls (PCBs), or their by-products generally were highest in lakebed sediments deposited in the 1970s. More recent sediments have concentrations that vary widely and do not show distinct temporal trends. Tissue samples of whole slimy sculpin (Cottus cognatus), a non-migratory species of fish, showed con-centrations of trace elements and organic contaminants. Of the constituents analyzed, only selenium concentra-tions showed levels of potential concern for

Scientific Investigations Report↗

An assessment of the variability in performance of wet atmospheric deposition samplers

The variability in performance of two brands of wet/dry atmospheric deposition samplers were compared for 1 year at a sincle site. A total of nine samplers were used. Samples were collected weekly and analyzed for pH, specific conductance, common chemical constituents, and sample volume. Additionally, data on the duration of each sampler opening were recorded using a microdatalogger. These data disprove the common perception that samplers remain open throughout a precipitation event. The sensitivity of sampler sensors within the range tested did not have a defineable impact on sample collection. The nonnormal distribution within the data set necessitated application of the nonparametric Friedman Test to assess comparability of sample chemical composition and volume between and within sampler brands. Statistically significant differences existed for most comparisons, however the test did not permit quantification of their magnitudes. Differences in analyte concentrations between samplers were small. (USGS)

Water-Resources Investigations Report↗

Comparative microhabitat characteristics at oviposition sites of the California red-legged frog ( Rana draytonii )

We studied the microhabitat characteristics of 747 egg masses of the federally-threatened Rana draytonii (California red-legged frog) at eight sites in California. our study showed that a broad range of aquatic habitats are utilized by ovipositing R. draytonii , including sites with perennial and ephemeral water sources, natural and constructed wetlands, lentic and lotic hydrology, and sites surrounded by protected lands and nested within modified urban areas. We recorded 45 different egg mass attachment types, although the use of only a few types was common at each site. These attachment types ranged from branches and roots of riparian trees, emergent and submergent wetland vegetation, flooded upland grassland/ruderal vegetation, and debris. eggs were deposited in relatively shallow water (mean 39.7 cm) when compared to maximum site depths. We found that most frogs in artificial pond, natural creek, and artificial channel habitats deposited egg masses within one meter of the shore, while egg masses in a seasonal marsh averaged 27.3 m from the shore due to extensive emergent vegetation. Rana draytonii appeared to delay breeding in lotic habitats and in more inland sites compared to lentic habitats and coastal sites. eggs occurred as early as mid-december at a coastal artificial pond and as late as mid-April in an inland natural creek. We speculate that this delay in breeding may represent a method of avoiding high-flow events and/or freezing temperatures. Understanding the factors related to the reproductive needs of this species can contribute to creating, managing, or preserving appropriate habitat, and promoting species recovery.

Herpetological Conservation and Biology↗

Flow recommendations for maintaining riparian vegetation along the Upper Missouri River, Montana

Montana Power Company, Inc. (MPC) submitted a final license application to the Federal Energy Regulatory Commission (FERC) on November 30, 1992. In this application, MPC proposed a plan for the protection of fish, wildlife, habitat, and water-quality resources. One concern was maintenance of woody riparian vegetation along the Missouri River, especially along the Wild and Scenic reach of the river, where the riparian forest occurs in relatively small discontinuous stands. The objectives of this project were 1) to recommend flows that would protect and enhance riparian forests along the Missouri River, and 2) to develop elements of an environmental monitoring program that could be used to assess the effectiveness of the recommended flows. Plains cottonwood ( Populus deltoides subsp. monilifera ) is the key structural component of riparian forests along the Missouri River. Therefore, we focused our analysis on factors affecting populations of this species. Previous work had demonstrated that the age structure of cottonwood populations is strongly influenced by aspects of flow that promote successfully establishment. In this study our approach was to determine the precise age of plains cottonwood trees growing along the Upper Missouri River and to relate years of establishment to the flow record. Our work was carried out between Coal Banks Landing and the Fred G. Robinson Bridge within the Wild and Scenic portion of the Missouri River. This segment of the river occupies a narrow valley and exhibits little channel migration. Maps and notes from the journals of Lewis and Clark (1804-1806) suggest that the present distribution and abundance of cottonwoods within the study reach is generally similar to presettlement conditions. Flows in the study reach are influenced by a number of dams and diversions, most importantly, Canyon Ferry and Tiber Dams. Although flow regulation has decreased peak flows and increased low flows, the gross seasonal pattern of flow has not been greatly altered. Most cottonwood establishment in our study reach occurred in years with a peak mean daily flow greater than 1,400 m 3 /s (49,434 cfs), or in the two years following such a flow. These years include 35 out of the 111 years of record, and account for establishment of 47 of 60 trees examined, a highly significant relationship. Infrequent establishment of cottonwood trees is not the result of scarcity of seed or seedlings. In the study reach seedlings become established most years on bare, relatively low surfaces deposited by the river. However, the high elevation of establishment of all trees dating to before 1978 indicates that only individuals established on high flood deposits are able to survive subsequent floods and ice jams. In order to maintain the present abundance of plains cottonwood in the study area we recommend flood flows in excess of 1,400 m 3 /s (49,434 cfs) measures as mean daily discharge at Fort Benton (U.S. Geological Survey gage 06090800) with a recurrence interval of approximately 9 years. Because cottonwood seeds remain viable for only a few weeks, and because seedling require a moist, bare surface, we further recommend maintenance of the historic timing of flooding with peak flood flows occurring between mid-May and late-June. Flow is not the only factor influencing cottonwood regeneration along this reach of the Missouri River. Land management, especially cattle grazing, is clearly having an impact, and changes in cottonwood populations could be expected if these practices were altered. However, the dependence of cottonwood establishment on high flow is clear in this reach in spite of the effects of other factors. Given the value of the resource, we strongly suggest establishment of a monitoring program to determine the effectiveness of the recommended flows and to provide the data necessary for refining them. We recommend a monitoring program that would include: 1) ten permanent, widely space channel cross sections for annual measurement of channel geometry and cottonwood establishment, growth, and survival; 2) five livestock enclosures to monitor the influence of grazing in the study area; and 3) low-elevation aerial photography of the reach every five years and after every flood to detect changes in channel geometry and forested area. Because cottonwood establishment is episodic, a long-term commitment to the monitoring effort is essential. In addition, cross sections and exclosures should be easy enough to access that measurements during flood years are possible.

Montana↗

Devonian rocks of the Yukon-Porcupine Rivers area and their tectonic relation to other Devonian sequences in Alaska

Devonian rocks along the Yukon River near the Alaska-Yukon boundary comprise 250 feet of limestone and shale and 800 feet of chert and siliceous shale, all referred to the McCann Hill Chert of Early to Late Devonian age; about 3,000 feet of non-marine chert-pebble conglomerate, graywacke, and shale of the Nation River Formation (Late Devonian); and about 3,000 feet of an unnamed chert and siliceous shale formation, of Late Devonian to Early or Late Mississippian age. The McCann Hill Chert apparently rests disconformably on graptolitic shale of the Road River Formation that has a succession of graptolite zones ranging in age from Ordovician to possibly Early Devonian. The Devonian succession along the Porcupine River, 170 miles north of the Yukon River locality, consists of 600 feet of Salmon-trout Limestone, overlain by 200 feet of unnamed shale and about 500 feet of unnamed dolomite. The Salmontrout Limestone rests accordantly and probably conformably on graptolitic shale with Monograptus hercynicus of Late Silurian or Early Devonian age, and the dolomite is overlain unconformably by limestone and shale of Carboniferous age. Tentaculitid faunas from the top of the Salmontrout Limestone and from the basal limestone and shale member of the McCann Hill Chert are similar and indicate that the units are partly correlative. These faunas and others throughout the Salmontrout resemble those from the Lower Devonian of Bohemia, indicating that the Salmontrout Limestone and the limestone and shale member of the McCann Hill Chert are somewhat older than previously reported. The faunas, and those from the underlying graptolitic shales, also suggest that sedimentation in this area of Alaska was nearly continuous from Late Silurian into the Earliest Devonian, and that there is little record of Caledonian earth movements. The stratigraphy of the Porcupine River area is not as yet well enough established to determine if rocks equivalent in age to the Nation River Formation are present, were once present and have since been eroded, or were never deposited. Pillow basalt and andesitic breccia, although closely associated with Devonian limestone in the western part of the Yukon-Porcupine Rivers area, seem only structurally related and of different age. Devonian rocks in southern and southeastern Alaska consist of several thousand feet of graywacke, shale and volcanic rocks deposited in the northern Cordilleran geosyncline. A combination of strike-slip and thrust faults of Tertiary and Mesozoic age may have since displaced the Devonian geosynclinal rocks relatively northward into central Alaska.

Alaska↗