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At least 1,261 records · Page 70Linked to original sources

USGS2013

Trace metal-rich Quaternary hydrothermal manganese oxide and barite deposit, Milos Island, Greece

The Cape Vani Mn oxide and barite deposit on Milos Island offers an excellent opportunity to study the three-dimensional characteristics of a shallow-water hydrothermal system. Milos Island is part of the active Aegean volcanic arc. A 1 km long basin located between two dacitic domes in northwest Milos is filled with a 35-50 m thick section of Quaternary volcaniclastic and pyroclastic rocks capped by reef limestone that were hydrothermally mineralized by Mn oxides and barite. Manganese occurs as thin layers, as cement of sandstone and as metasomatic replacement of the limestone, including abundant fossil shells. Manganese minerals include chiefly δ-MnO2, pyrolusite and ramsdellite. The MnO contents for single beds range up to 60%. The Mn oxide deposits are rich in Pb (to 3.4%), BaO (to 3.1%), Zn (to 0.8%), As (to 0.3%), Sb (to 0.2%) and Ag (to 10 ppm). Strontium isotopic compositions of the Mn oxide deposits and sulphur isotopic compositions of the associated barite show that the mineralizing fluids were predominantly sea water. The Mn oxide deposit formed in close geographical proximity to sulphide-sulphate-Au-Ag deposits and the two deposit types probably formed from the same hydrothermal system. Precipitation of Mn oxide took place at shallow burial depths and was promoted by the mixing of modified sea water (hydrothermal fluid) from which the sulphides precipitated at depth and sea water that penetrated along faults and fractures in the Cape Vani volcaniclastic and tuff deposits. The hydrothermal fluid was formed from predominantly sea water that was enriched in metals leached from the basement and overlying volcanogenic rocks. The hydrothermal fluids were driven by convection sustained by heat from cooling magma chambers. Barite was deposited throughout the time of Mn oxide mineralization, which occurred in at least two episodes. Manganese mineralization occurred by both focused and diffuse flow, the fluids mineralizing the beds of greatest porosity and filling dilatational fractures along with barite.

Milos Island↗

USGS1971

Sulfur isotope study of the "B" limestone and Galena fissure ore deposits of the U.S. mine, Bingham mining district, Utah

The delta S 34 values for 261 sulfide concentrates from the "B" limestone replacement and Galena fissure deposits of the U. S. mine range from +3.8 to --8.0 permil; the mean is +0.56 permil. The data indicate that (1) sulfides of the "B" limestone ore deposits are depleted in S 34 by 0.4 to 0.7 permil relative to those of the Galena fissure ore deposits; (2) sulfides of both deposits exhibit a primary fractionation trend characterized by increasing S 34 depletion in the sequence pyrite, sphalerite, tetrahedrite, and galena; (3) delta values for coexisting sulfide pairs of the "B" limestone deposit increase with increasing altitude; (4) sulfides of both deposits are increasingly depleted in S 34 with increasing altitude; (5) the paragenetic order of sulfide deposition is accompanied by an apparent depletion of S 34 that is independent of mineral species; and (6) pyrite disseminated in wall rocks is depleted in S 34 relative to pyrite from adjacent ore deposits. The similarity of delta S 34 values and isotopic trends to those of the central porphyry-type deposit at Bingham (Field, 1966) suggests that the hydrothermal deposits of the district were formed by fluids that originated from a common source during one episode of sequential mineralization. Gross isotopic differences between the deposits, consistent differences between coexisting sulfides, and systematic variations of delta values are attributed to temperature effects imposed upon sulfide exchange equilibria; isotopic temperatures suggest a lateral gradient between the "B" limestone and adjacent Galena fissure deposits and a possible vertical gradient within the "B" limestone deposit. The vertical zonation of delta S 34 values and trends related to pyrite physical occurrence and sulfide paragenesis are provisionally attributed to a pH-Eh control. Although the apparent trends are imperfectly resolved because of textural complexities, the marked depletion of S 34 in pyrite disseminated in country rocks warrants additional study as a potential exploration method.

Utah↗

USGS2017

Multiscale hyperspectral imaging of the Orange Hill Porphyry Copper Deposit, Alaska, USA, with laboratory-, field-, and aircraft-based imaging spectrometers

In the past decade, use of hyperspectral imaging (imaging spectroscopy) for mineral exploration and mining operations has been increasing at different spatial scales. In this paper, we focus on recent trends in applying imaging spectrometer data to: 1) airborne imaging of high latitude deposits, 2) field-based imaging of outcrops, and 3) laboratory-level imaging of geologic samples. Comparing mineral information derived from imaging spectrometer data acquired at these three scales in Alaska in areas of exposed porphyry Cu-Au-Mo deposits, Orange Hill and Bond Creek, we find notable consistency in identifications of spectrally predominant minerals, including white mica, chlorite, clays, and gypsum. Variations in the wavelength position of white mica 2200 nm Al-OH absorption seen at the airborne level are echoed by finerscale field and laboratory imaging, with wavelength positions spanning the 2199 to 2207 nm range. The longerwavelength micas associated with porphyry formation are more phengitic in composition, and thus distinct from mica in plutonic and volcanic arc rocks not affected by magmatic-hydrothermal fluids. The hillside imagery, collected on a cloudy day that would have precluded aircraft survey, gave comparable result to airborne and laboratory data, indicating field-based imaging spectroscopy can be a feasible alternative to airborne survey for accessible targets. Direct spectral observation of molybdenite in rocks collected from the Orange Hill deposit demonstratesthat additional important mineral information can be revealed with laboratory level imaging spectroscopy that is difficult to obtain in coarser scale data, commonly due to low areal extent of target minerals. The spatial association of the clinochlore + white mica and long wavelength white mica spectral classes to multi-element Cu-Mo-Au anomalies from geochemical analyses of rocks and sediments support a causative relationship with magmatic-hydrothermal alteration. Mineral maps from the airborne data were used to guide field sampling that found additional CuMo-Au mineralized areas, which were previously unknown or unreported. The results from this study provide support for utilization of imaging spectroscopy for assisting mineral exploration in other portions of the state of Alaska as well as other areas at high latitudes. Imaging spectroscopy has the potential to provide targeting information for follow-up sampling and investigations, potentially reducing subsequent exploration costs.

Alaska↗

USGS1990

An evaluation and geochemical survey of the Farah Garan East Prospect, Southeast Asir, Kingdom of Saudi Arabia

The Farah Garan East prospect (MODS 4886) is located in the southeastern part of the Precambrian Arabian Shield of Saudi Arabia, about 15 km east-northeast of Zahran Al Janub and 1 km northeast of the ancient mines at Farah Garan. Ore minerals at the Farah Garan East prospect are pyrite, tennantite, galena, and sphalerite. These are sparsely and erratically distributed in west-dipping beds of dolomite, dolomite-talc breccia, and carbonate-sericite phyllite, and in associated breccias and zones of carbonate-altered mafic metavolcanic rocks, all of Precambrian age. Concordant beds of dolomite and carbonate-sericite phyllite are interlayered with metavolcanic rocks and are interpreted as volcanic-related submarine hydrothermal deposits of Precambrian age. Funnel-shaped bodies of dolomite-talc breccia that crop out near the north and south ends of the dolomite beds are interpreted as submarine hot-spring vent breccias. Aprons of exhalative dolomite thin laterally outward from these vents. Discordant and concordant zones of carbonate-altered metavolcanic rocks, east of and structurally below the hot-spring vents, probably represent pathways of hydrothermal circulation along networks of fractures in volcanic rocks, subjacent to these Precambrian submarine hot-spring vents. Ore minerals in outcrops, and geochemically anomalous concentrations of gold, silver, copper, lead, zinc, arsenic, antimony, and tellurium are present in carbonate-rich rocks of the hot-spring assemblage. This indicates that the ore minerals and elements were deposited originally as constituents of the hot-spring assemblage. However, exposed ore-mineral occurrences are small and sparse, and geochemical anomalies are small, irregularly distributed, and of subeconomic grade. Furthermore, weak electromagnetic anomalies do not indicate the presence of subsurface bodies of concentrated, conductive ore minerals. Therefore, no drilling is recommended.

Open-File Report↗

USGS2026

Integrating detrital magnetite geochemistry and (U-Th)/He chronometry as a sediment provenance tool in geologic and metallogenic terranes

Magnetite is ubiquitous in porphyry Cu systems and in sediment sourcing both barren and mineralized regions, with potential as an indicator mineral in concealed and coarsely-mapped terranes. We develop and test a workflow for integrated geochemistry and (U–Th)/He (He) dating for inferring detrital magnetite (DMt) provenance in these settings. The ca. 70 Ma Taurus porphyry Cu–Mo(–Au) district in eastern interior Alaska serves as a test case. DMt from streams draining porphyry-related mineralization was characterized by geochemistry and mineral inclusion and microstructure observations, complemented by similar data for potential porphyry and host rock sources. Principal component analysis and clustering of DMt geochemical data resolve multiple populations in our samples geochemically and texturally compatible with derivation from metamorphic, porphyry-related hydrothermal, and igneous sources. Hydrothermal magnetite comprises ∼16–50% of DMt nearest porphyry mineralization but diminishes to ∼4% ∼15 km downstream. Subsampled grains within populations yield ∼160–110 Ma, ∼70 Ma, ∼55 Ma, and ∼20 Ma magnetite He date modes. Combined with provenance, He dates capture Early Cretaceous regional exhumation of metamorphic host rock and Late Cretaceous porphyry Cu mineralization. DMt grains showing partial hematite replacement yield ca. 55–20 Ma dates regardless of source, overlapping regional warm/wet climatic intervals. We interpret Cenozoic dates to reflect exhumation to near-surface oxidizing conditions and(or) supergene weathering. Magnetite is thus a promising target phase for (1) tracking the spatiotemporal distribution of porphyry systems, and (2) linking the formation and exhumation of these systems to a regional geologic history, both in Alaska and globally.

Alaska, Yukon↗

USGS1975

Interstitial solutions and diagenesis in deeply buried marine sediments: Results from the Deep Sea Drilling Project

Through the Deep Sea Drilling Project samples of interstitial solutions of deeply buried marine sediments throughout the World Ocean have been obtained and analyzed. The studies have shown that in all but the most slowly deposited sediments pore fluids exhibit changes in composition upon burial. These changes can be grouped into a few consistent patterns that facilitate identification of the diagenetic reactions occurring in the sediments. Pelagic clays and slowly deposited (<1 cm/10 3 yr) biogenic sediments are the only types that exhibit little evidence of reaction in the pore waters. In most biogenic sediments sea water undergoes considerable alteration. In sediments deposited at rates up to a few cm/10 3 yr the changes chiefly involve gains of Ca 2+ and Sr 2+ and losses of Mg 2+ which balance the Ca 2+ enrichment. The Ca-Mg substitution may often reach 30 mM/kg while Sr 2+ may be enriched 15-fold over sea water. These changes reflect recrystallization of biogenic calcite and the substitution of Mg 2+ for Ca 2+ during this reaction. The Ca-Mg-carbonate formed is most likely a dolomitic phase. A related but more complex pattern is found in carbonate sediments deposited at somewhat greater rates. Ca 2+ and Sr 2+ enrichment is again characteristic, but Mg 2+ losses exceed Ca 2+ gains with the excess being balanced by SO 4 post staggered2- losses. The data indicate that the reactions are similar to those noted above, except that the Ca 2+ released is not kept in solution but is precipitated by the HCO 3 post staggered- produced in SO 4 post staggered2- reduction. In both these types of pore waters Na + is usually conservative, but K + depletions are frequent. In several partly consolidated sediment sections approaching igneous basement contact, very marked interstitial calcium enrichment has been found (to 5.5 g/kg). These phenomena are marked by pronounced depletion in Na + , Si and CO 2 , and slight enhancement in Cl - . The changes are attributed to exchange of Na + for Ca 2+ in silicate minerals forming from submarine weathering of igneous rocks such as basalts. Water is also consumed in these reactions, accounting for minor increases in total interstitial salinity. Terrigenous, organic-rich sediments deposited rapidly along continental margins also exhibit significant evidences of alteration. Microbial reactions involving organic matter lead to complete removal of SO 4 post staggered2- , strong HCO 3 post staggered- enrichment, formation of NH 4 post staggered+ , and methane synthesis from H 2 and CO 2 once SO 4 post staggered2- is eliminated. K + and often Na + (slightly) are depleted in the interstitial waters. Ca 2+ depletion may occur owing to precipitation of CaCO 3 . In most cases interstitial Cl - remains relatively constant, but increases are noted over evaporitic strata, and decreases in interstitial Cl - are observed in some sediments adjacent to continents.

Geochimica et Cosmochimica Acta↗

USGS1993

Reconnaissance guidelines for gold exploration in Central Alaska

Distribution of more than 300 gold-bearing samples from the Livengood (Tolovana) and parts of the Fairbanks and Rampart mining districts in central Alaska, USA, indicate that the concentration of gold in placers is spatially related both to structural features and to Late Cretaceous and (or) Tertiary felsic plutons. The regional consistency of these spatial relationships is demonstrated by proximity analysis using a Geographic Information System (GIS), and suggests a genetic association between faults, felsic plutons, and gold occurrences. The local presence of gold within several of the plutons indicates that these are the source of some of the gold. In addition, some gold occurs proximal to faults where plutons are not present, suggesting that some of the gold was also derived from the country rock. We envision a model whereby weakly mineralized solutions, thermally driven by latent plutonic heat, were enriched by circulation through clastic units that may have had a naturally elevated gold background. The resultant enriched solutions were channeled and reconcentrated along or adjacent to large-scale fault systems. Future exploration to define individual target areas should be directed toward areas where Late Cretaceous and (or) Tertiary felsic plutons occur near major faults. ?? 1993.

Journal of Geochemical Exploration↗

USGS2015

Weathering and transport of chromium and nickel from serpentinite in the Coast Range ophiolite to the Sacramento Valley, California, USA

A soil geochemical study in northern California was done to investigate the role that weathering and transport play in the regional distribution and mobility of geogenic Cr and Ni, which are both potentially toxic and carcinogenic. These elements are enriched in ultramafic rocks (primarily serpentinite) and the soils derived from them (1700–10,000 mg Cr per kg soil and 1300–3900 mg Ni per kg soil) in the Coast Range ophiolite. Chromium and Ni have been transported eastward from the Coast Range into the western Sacramento Valley and as a result, valley soil is enriched in Cr (80–1420 mg kg −1 ) and Ni (65–224 mg kg −1 ) compared to median values of U.S. soils of 50 and 15 mg kg −1 , respectively. Nickel in ultramafic source rocks and soils is present in serpentine minerals (lizardite, antigorite, and chrysotile) and is more easily weathered compared to Cr, which primarily resides in highly refractory chromite ([Mg,Fe 2+ ][Cr 3+ ,Al,Fe 3+ ] 2 O 4 ). Although the majority of Cr and Ni in soils are in refractory chromite and serpentine minerals, the etching and dissolution of these minerals, presence of Cr- and Ni-enriched clay minerals and development of nanocrystalline Fe (hydr)oxides is evidence that a significant fractions of these elements have been transferred to potentially more labile phases.

California↗

USGS2004

A combined basalt and peridotite perspective on 14 million years of melt generation at the Atlantis Bank segment of the Southwest Indian Ridge: Evidence for temporal changes in mantle dynamics?

Little is known about temporal variations in melt generation and extraction at midocean ridges largely due to the paucity of sampling along flow lines. Here we present new whole-rock major and trace element data, and mineral and glass major element data, for 71 basaltic samples (lavas and dykes) and 23 peridotites from the same ridge segment (the Atlantis Bank segment of the Southwest Indian Ridge). These samples span an age range of almost 14 My and, in combination with the large amount of published data from this area, allow temporal variations in melting processes to be investigated. Basalts show systematic changes in incompatible trace element ratios with the older samples (from ???8-14 Ma) having more depleted incompatible trace element ratios than the younger ones. There is, however, no corresponding change in peridotite compositions. Peridotites come from the top of the melting column, where the extent of melting is highest, suggesting that the maximum degree of melting did not change over this interval of time. New and published Nd isotopic ratios of basalts, dykes and gabbros from this segment suggest that the average source composition has been approximately constant over this time interval. These data are most readily explained by a model in which the average source composition and temperature have not changed over the last 14 My, but the dynamics of mantle flow (active-to-passive) or melt extraction (less-to-more efficient extraction from the 'wings' of the melting column) has changed significantly. This hypothesised change in mantle dynamics occurs at roughly the same time as a change from a period of detachment faulting to 'normal' crustal accretion. We speculate that active mantle flow may impart sufficient shear stress on the base of the lithosphere to rotate the regional stress field and promote the formation of low angle normal faults. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS2011

Trace and minor element variations and sulfur isotopes in crystalline and colloform ZnS: Incorporation mechanisms and implications for their genesis

Various models have been proposed to explain the formation mechanism of colloform sphalerite, but the origin is still under debate. In order to decipher influences on trace element incorporation and sulfur isotope composition, crystalline and colloform sphalerite from the carbonate-hosted Mississippi-Valley Type (MVT) deposit near Wiesloch, SW Germany, were investigated and compared to sphalerite samples from 52 hydrothermal vein-type deposits in the Schwarzwald ore district, SW Germany to study the influence of different host rocks, formation mechanisms and fluid origin on trace element incorporation. Trace and minor element incorporation in sphalerite shows some correlation to their host rock and/or origin of fluid, gangue, paragenetic minerals and precipitation mechanisms (e.g., diagenetic processes, fluid cooling or fluid mixing). Furthermore, crystalline sphalerite is generally enriched in elements like Cd, Cu, Sb and Ag compared to colloform sphalerite that mainly incorporates elements like As, Pb and Tl. In addition, sulfur isotopes are characterized by positive values for crystalline and strongly negative values for colloform sphalerite. The combination of trace element contents, typical minerals associated with colloform sphalerite from Wiesloch, sulfur isotopes and thermodynamic considerations helped to evaluate the involvement of sulfate-reducing bacteria in water-filled karst cavities. Sulfate-reducing bacteria cause a sulfide-rich environment that leads in case of a metal-rich fluid supply to a sudden oversaturation of the fluid with respect to galena, sphalerite and pyrite. This, however, exactly coincides with the observed crystallization sequence of samples involving colloform sphalerite from the Wiesloch MVT deposit.

Wiesloch↗

USGS2011

Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: Implications for and modeling of speleothem paleoclimate records

A 4-year study in a central Texas cave quantifies multiple mechanisms that control dripwater composition and how these mechanisms vary at different drip sites. We monitored cave-air compositions, in situ calcite growth, dripwater composition and drip rate every 4–6 weeks. Three groups of drip sites are delineated (Groups 1–3) based on geochemical variations in dripwater composition. Quantitative modeling of mineral-solution reactions within the host carbonate rock and cave environments is used to identify mechanisms that can account for variations in dripwater compositions. The covariation of Mg/Ca (and Sr/Ca) and Sr isotopes is key in delineating whether Mg/Ca and Sr/Ca variations are dictated by water–rock interaction (i.e., calcite or dolomite recrystallization) or prior calcite precipitation (PCP). Group 1 dripwater compositions reflects a narrow range of the extent of water–rock interaction followed by varying amounts of prior calcite precipitation (PCP). Group 2 dripwater compositions are controlled by varying amounts of water–rock interaction with little to no PCP influence. Group 3 dripwater compositions are dictated by variable extents of both water–rock interaction and PCP. Group 1 drip sites show seasonal variations in dripwater Mg/Ca and Sr/Ca, whereas the other drip sites do not. In contrast to the findings of most previous dripwater Mg/Ca–Sr/Ca studies, these seasonal variations (at Group 1 drip sites) are independent of changes in water flux (i.e., rainfall and/or drip rate), and instead significantly correlate with changes in cave-air CO 2 concentrations. These results are consistent with lower cave-air CO 2 , related to cool season ventilation of the cave atmosphere, enhancing calcite precipitation and leading to dripwater geochemical evolution via PCP. Group 1 dripwater Mg/Ca and Sr/Ca seasonality and evidence for PCP as a mechanism that can account for that seasonality, have two implications for many other regions where seasonal ventilation of caves is likely: (1) speleothem trace-element records may provide seasonal signals, and (2) such records may be biased toward recording climate conditions during the season when calcite is depositing. Additionally, we use our results to construct a forward model that illustrates the types of speleothem Mg/Ca and Sr/Ca variations that would result from varying controls on dripwater compositions. The model provides a basis for interpreting paleo-dripwater controls from high frequency Mg/Ca and Sr/Ca variations for speleothems from caves at which long term monitoring studies are not feasible.

Geochimica et Cosmochimica Acta↗

USGS1991

Petrology of lower crustal and upper mantle xenoliths from the Cima Volcanic Field, California

Basaltic rocks of the Cima volcanic field in the southern Basin and Range province contain abundant gabbro, pyroxenite, and peridotite xenoliths. Composite xenoliths containing two or more rock types show that upper-mantle spinel peridotite was enriched by multiple dike intrusions in at least three episodes; the mantle was further enriched by intergranular and shear-zone melt infiltration in at least two episodes. The oldest dikes, now metamorphosed, are Cr-diopside websterite. Dikes of intermediate age are most abundant at Cima and consist of igneous-textured websterite and two-pyroxene gabbro and microgabbro of tholeiitic or calcalkalic parentage. The youngest dikes are igneous-textured clinopyroxenite, gabbro, and olivine microgabbro of alkalic parentage. The dikes in peridotite are interpreted as parts of a system of conduits through which tholeiitic (or calcalkalic) and alkalic magmas fed lower-crustal intrusions, which are represented by abundant xenoliths of the same igneous rock types as observed in the dikes. Mineral assemblages of dikes in peridotite indicate that an enriched uppermost mantle zone no thicker than 15 km could have been sampled. Because of their high densities, the gabbros and pyroxenites can occupy the zone immediately above the present Moho (modeled on seismic data as 10-13 km thick, with V p 6.8 km/s) only if their seismic velocities are reduced by the joints, partial melts, and fluid inclusions that occur in them. Alternatively, these xenoliths may have been derived entirely from beneath the Moho, in which case the Moho is not the local crust-mantle boundary.

Journal of Petrology↗

USGS1949

Hawaiian petrographic province

The lavas of the Hawaiian Islands range from mafic picrite-basalts and melilite-nepheline basalts to salic trachytes. Olivine basalt, by far the most abundant type, is regarded as representing the parent magma of the Hawaiian province. Closely associated with the olivine basalts are basalts, and picrite-basalts with many large phenocrysts of olivine. Further differentiation results in eruption of andesine andesite, oligoclase andesite, picritebasalt with abundant large augite phenocrysts, and more rarely trachyte. Following a long period of quiescence there have been erupted on some islands nepheline basanite, nepheline basalt, melilite-nepheline basalt, “linosaite,” and a third type of picrite-basalt. The mineral and chemical composition of the various rock types, and their distribution on the individual islands, are described. Starting with olivine basalt as the parent magma means of deriving the other rock types are considered. It is concluded that crystal differentiation has been the principal process, although assimilation of limestone may also have been important. The parts played by gaseous transfer and selective remelting are difficult to evaluate, though both probably operated to some extent. Comparison of the types of igneous rocks in the Hawaiian province with those recorded from other Pacific islands shows that the rocks throughout the true Pacific Basin are, for the most part, closely similar, and suggests essential uniformity of parent magma and petrogenic processes throughout the Pacific Basin.

Hawaii↗

USGS1992

Impact origin of the Avak Structure, Arctic Alaska, and genesis of the Barrow gas fields

Geophysical and subsurface geologic data suggest that the Avak structure, which underlies the Arctic Coastal Plain 12 km southeast of Barrow, Alaska, is a hypervelocity meteorite or comet impact structure. The structure is a roughly circular area of uplifted, chaotically deformed Upper Triassic to Lower Cretaceous sedimentary rocks 8 km in diameter that is bounded by a ring of anastomosing, inwardly dipping, listric normal faults 12 km in diameter. A zone of gently outward-dipping sedimentary country rocks forms a discontinuous ring of "rim anticlines" within the peripheral ring of normal faults. Beyond these anticlines, the sedimentary rocks are almost flat-lying. Basement consists of strongly deformed Ordovician and Silurian argillite. Density and acoustic impedance con rasts between the argillite and the overlying strata produce gravity and seismic-reflection signatures that define a ring of anticlines around the disturbed zone and a structural high surrounded by an annular structural low at its center. In the adjacent Barrow gas fields, the tops of the informally named Neocomian "pebble shale" unit and the gas-producing Lower Jurassic Barrow sand (local usage) lie at average subsea depths of 488 m and 670 m, respectively. In the Avak 1 well, drilled on the central high, the pebble shale and the Barrow sand lie near the surface, documenting more than 500 m of relative uplift at the high. The cores in this well have steep dips (30-90 degrees), mixed breccia with Franklinian argillite clasts 10 and 90 m above basement, quartz grains with shock mosaicism and multiple sets of shock lamellae, oriented concussion fractures in sand-size quartz grains, and shatter cones resembling those found in the peripheral zones of well-documented impact structures. In addition, above-background levels o fractured quartz grains in Barrow sand were found as far as 19 km beyond the rim of the Avak structure. Data concerning the age of the Avak structure are not definitive. If submarine landslide deposits in the upper part of the Aptian and Albian Torok Formation, in the subsurface 200 km to the east, were triggered by the Avak event, then the Avak meteorite struck a submerged marine shelf about 100 + or - 5 Ma. However, the impact features found at Avak (shatter cones, concussion fractures, shock lamellae and shock mosaicism in quartz grains, and widespread cataclasis) characterize the distal zones of meteorite impact structures. Fused rocks, plastic deformation, and shock-metamorphic minerals found in more proximal zones of impact structures are apparently missing. These observations, and the lack of Avak ejecta in cuttings and cores from the Torok Formation and Nanushuk Group (Albian to middle Cenomanian) in surrounding test wells, indicate that the impact event postdated these beds. In this case, the Avak meteorite struck a Late Cretaceous or Tertiary marine shelf or coastal plain between the Cenomanian (ca. 95 Ma), and deposition of the basal beds of the overlying late Pliocene and Quaternary Gubik Formation (ca. 3 Ma).

Alaska↗

USGS1983

The mobility and distribution of heavy metals during the formation of first cycle red beds

Holocene-Pliocene sequence sampled in northern Baja California. Geochemical data supported by petrographic, X-ray, and SEM observations of mineralogical transformations, fission-track radiography, and uranium decay series measurements. Results indicate that metal content of the studied samples is inherited from constituent detrital minerals and that reddening of whole-rock samples does not promote major open-system migration of heavy metals. The amount of secondary iron oxides and the fraction of whole-rock metals associated with the oxides increase during red-bed development. Results suggest that developed red beds which are well flushed by suitable pore fluids may be sources of significant quantities of heavy metals.

Economic Geology↗

USGS2015

Geochemistry and occurrence of selenium: An overview

Selenium (Se) is both beneficial and toxic to animals, plants, and humans. Consequently, it is imperative to know its concentration in the environment and to understand the processes controlling its distribution. Determinations of Se concentrations in a variety of materials indicate that Se is widely distributed throughout the environment. The processes responsible for its distribution include volcanic activity, the burning of fossil fuels, the weathering of rocks and soils, groundwater transport, precipitation of minerals, adsorption, chemical or bacterial reduction and oxidation, and metabolic uptake and release by plants and animals. The importance of a particular process in controlling the distribution of Se is intimately linked to the speciation of Se, which is controlled by the pH and redox conditions of the environment. Selenium can exist as selenide (Se 2− ), elemental Se (Se 0 ), selenite (SeO 2− 3 ), and selenate (SeO 2− 4 ). Each oxidation state exhibits different chemical behavior. Selenide and elemental Se occur in acidic, reducing, and organic-rich environments. Metal selenides, Se-sulfides, and elemental Se are insoluble, and therefore biologically unavailable. For the pH and redox conditions of most soil and aquatic environments, SeO 2− 3 and SeO 2− 4 ; should be the dominant forms of Se. Selenite is immobilized by adsorption onto particles, particularly Fe oxyhydroxides. Selenate is highly mobile and biologically available because of the solubility of its salts and its weak adsorption by particles. Microbial action can change the speciation of Se through oxidation or reduction, or through the formation of organic Se compounds.

Book chapter↗

USGS1967

Metalliferous lode deposits of Alaska

An important factor in any rebirth of metal mining in Alaska will be a thorough appraisal of the metalliferous lodes already known in the State. Any such appraisal probably will depend, at least in part, on an inventory of these 1 deposits and a knowledge of their geology. This report summarizes from repoAs of Federal and State agencies published before August 31, 1965, the geology of Alaska's metal-bearing lodes, including their structural or stratigraphic control, host rock, mode of origin, kinds of .Q minerals, grade, past production, and extent of exploration. In addition, the lists of mineral occurrences that accompany the 35 mineral-deposit location maps constitute an inventory of the State's known lodes. A total of 692 localities where m&alliferous deposits have been found are shown on the maps. The localities include 1,739 mines, prospects, and reported occurrences, of which 821 are described individually or otherwise cited in the text.

Alaska↗

USGS2005

Chapter K: Progress in the Evaluation of Alkali-Aggregate Reaction in Concrete Construction in the Pacific Northwest, United States and Canada

The supply of aggregates suitable for use in construction and maintenance of infrastructure in western North America is a continuing concern to the engineering and resources-management community. Steady population growth throughout the region has fueled demand for high-quality aggregates, in the face of rapid depletion of existing aggregate resources and slow and difficult permitting of new sources of traditional aggregate types. In addition to these challenges, the requirement for aggregates to meet various engineering standards continues to increase. In addition to their physical-mechanical properties, other performance characteristics of construction aggregates specifically depend on their mineralogy and texture. These properties can result in deleterious chemical reactions when aggregate is used in concrete mixes. When this chemical reaction-termed 'alkali-aggregate reaction' (AAR)-occurs, it can pose a major problem for concrete structures, reducing their service life and requiring expensive repair or even replacement of the concrete. AAR is thus to be avoided in order to promote the longevity of concrete structures and to ensure that public moneys invested in infrastructure are well spent. Because the AAR phenomenon is directly related to the mineral composition, texture, and petrogenesis of the rock particles that make up aggregates, an understanding of the relation between the geology and the performance of aggregates in concrete is important. In the Pacific Northwest, some aggregates have a moderate to high AAR potential, but many others have no or only a low AAR potential. Overall, AAR is not as widespread or serious a problem in the Pacific Northwest as in other regions of North America. The identification of reactive aggregates in the Pacific Northwest and the accurate prediction of their behavior in concrete continue to present challenges for the assessment and management of geologic resources to the owners and operators of pits and quarries and to the users of the concrete aggregates mined from these deposits. This situation is complicated by the length of time typically required for AAR to become noticeable in concrete construction in the Pacific Northwest, commonly on such a scale that other deterioration mechanisms may have masked the effects of AAR. Distinguishing between the effects of AAR and those related to other problems in concrete is important for understanding the nature and severity of AAR throughout the Pacific Northwest. Furthermore, developing an understanding of the extent of the problem will assist efforts to maximize the intelligent and stewardly use of aggregate resources in the Pacific Northwest. This chapter illustrates the current 'state of the art' of AAR studies in the Pacific Northwest, a region with a common geologic heritage as well as many distinct geologic elements. The optimal use of aggregates in the construction of concrete structures that will achieve their design life is possible through an understanding of the engineering and geologic properties of these aggregates and of their geologic setting.

Bulletin↗