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USGS2026

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado↗
USGS2026

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗
USGS2025

ShakeAlert® version 3: Expected performance in large earthquakes

The ShakeAlert earthquake early warning (EEW) system partners along with U.S. Geological Survey (USGS) licensed operators deliver EEW alerts to the public and trigger automated systems when a significant earthquake is expected to impact California, Oregon, or Washington. ShakeAlert’s primary goal is to provide usable warning times before the arrival of damaging shaking. EEW is most likely to achieve this goal in large‐magnitude earthquakes. In recent years, ShakeAlert has gone through a series of upgrades to its underlying scientific algorithms aimed at improved performance during large earthquakes. Version 3 of this software recently went live in the production system and includes improvements to all algorithms. The main seismic algorithms that detect an earthquake and characterize its location, magnitude, and fault rupture orientation are faster than older versions. Other key changes include: using real‐time geodetic data to characterize the magnitude growth in large earthquakes; the introduction of an alert pause procedure to compromise between speed near the epicenter and improved accuracy at larger distances; and the inclusion of a nonergodic site‐response model in the ground‐motion predictions. ShakeAlert has achieved its primary goal of usable warning times before strong shaking at some locations in real‐time operations in recent M 6 earthquakes. Using offline tests, we demonstrate usable warning times are possible for many sites with peak shaking values of modified Mercalli intensity (MMI) 7–8 in M 7+ earthquakes and also for many MMI 8–9 sites in M 8+ earthquakes. ShakeAlert partners use a variety of MMI and magnitude thresholds in deciding when to alert their users within bounds set by the USGS. Our study shows that there is room to raise the magnitude thresholds up to about M 5.5 without adversely affecting performance in large earthquakes. The ground‐motion criteria are more complex owing to a significant drop‐off in warning times between the MMI 4 and 5 levels of predicted shaking. However, widely used ShakeAlert products, such as the MMI 3 and 4 contour products, can provide sufficiently long warning times before strong shaking in moderate‐to‐great earthquakes to enable a range of protective actions.

Bulletin of the Seismological Society of America↗
USGS2026

Evaluating machine learning approaches to identify and predict oil and gas produced water lithium concentrations

Recently, the demand for battery-grade lithium has substantially increased, largely due to electrification of the transportation sector. The search for new lithium sources has turned to produced waters (frequently brines), a large-volume wastewater by-product of oil and gas extraction. Geochemical analysis indicates the presence of varying concentrations of lithium from produced water samples collected across the United States and represented in the U.S. Geological Survey’s National Produced Water Geochemical Database, as well as mixtures of Marcellus Shale produced water included in the Pennsylvania Department of Environmental Protection’s Oil and Gas Well Waste Reports. We first examined whether the geochemical signature of the lithium-bearing produced waters is sufficiently distinct so that machine learning (ML) can be used to correctly classify samples to the formation of origin. The produced water sample data used to assess classification accuracy were from the Marcellus Shale, Utica Shale and Point Pleasant Formation (Utica), and Smackover Formation oil and gas wells. Further, we evaluated the potential for ML to accurately classify Marcellus Shale produced water spatially (i.e., northeast versus southwest Pennsylvania). We then investigated whether ML algorithms applied to a suite of geochemical concentration data (i.e. Ba, Br, Cl, K, Mg, Sr) may be used to predict the lithium concentration of an unknown sample. Finally, we applied an estimated economic lithium grade cutoff of 150 milligrams per liter (mg/l) and assessed the utility of ML to predict whether a produced water sample would fall above or below the grade cutoff based on the suite of geochemical parameters. Four machine learning algorithms—Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Networks (DNN) were assessed. This study successfully demonstrates that all four machine learning methods can precisely and accurately estimate lithium concentrations and geologic formation classification. The products of this study contribute to the growing body of knowledge aimed at expanding the lithium resource base within the United States.

Alabama, Arkansas, Florida, Georgia, Louisiana, Mi↗
USGS2025

Simulated effects of future water availability and protected species habitat in a perennial wetland, Santa Barbara County, California

This study evaluates the potential water availability in Barka Slough and the effects of changing hydrological conditions on the aquatic habitat of five protected species. Barka Slough is a historically perennial wetland at the downstream western end of the San Antonio Creek Valley watershed (SACVW). A previously published hydrologic model of the SACVW for 1948–2018 was extended to include 2019–2021 and then modified to simulate the future years of 2022–2051. Two models simulating the future years of 2022–2051 were constructed, each with different climate inputs: (1) a repeated historical climate and (2) a 2070-centered Drier Extreme Warming climate (2070 DEW). The model with the 2070 DEW climate had warmer temperatures and an increase in average annual precipitation driven by larger, albeit more infrequent, precipitation events than the model with the historical climate. Simulated groundwater pumpage resulted in cumulative groundwater storage depletion and groundwater-level decline in Barka Slough in both future models. The simulations indicate that Barka Slough may transition from a perennial to an ephemeral wetland. Streamflow, stream disconnection, and depth to groundwater are key habitat metrics for federally listed species in Barka Slough. Future seasonal conditions for each metric are more likely to affect federally listed species’ habitats under 2070 DEW climatic conditions. Future seasonal streamflow volume may negatively impact unarmored threespine stickleback ( Gasterosteus aculeatus williamsoni ) and tidewater goby ( Eucyclogobis newberryi) habitats. Future seasonal stream disconnection may negatively impact the unarmored threespine stickleback habitat. Future groundwater-level decline may negatively impact Gambel’s watercress ( Nasturtium gambelii ) and La Graciosa thistle ( Cirsium scariosum var. loncholepis ) habitats and could influence the ability to use Barka Slough as a restoration or reintroduction site for these species. Results from this study can be used to inform water management decisions to sustain future groundwater availability in the SACVW.

California↗
USGS2025

Risk implications of Poisson assumptions and declustering inferred from a fully time-dependent earthquake forecast

We use the Third Uniform California Earthquake Rupture Forecast Epidemic Type Aftershock Sequence model, which is fully time-dependent in terms of including spatiotemporal clustering, to evaluate the effects of the Poisson assumption and declustering algorithms on statewide loss exceedance curves. The model is simulation based, meaning it produces synthetic catalogs that exhibit realistic behavior with respect to aftershocks and multi-fault earthquakes. A Poisson version of the model was constructed by randomizing event times, and the influence of two declustering algorithms was examined as well. We demonstrate that the probability of one-or-more loss exceedances (occurrence exceedance probability) is greater for the Poisson model because it has fewer seismically quiet time windows. The discrepancy between dollar loss estimates with a given exceedance probability is up to a factor of 32% but varies depending on the loss threshold (the x-axis value) and the forecast duration (we examined a range between 24 h and 50 years, with the discrepancy for the latter being negligible). We discuss how the one-or-more loss exceedance metric is questionable because it ignores all but the maximum loss experienced in each timeframe. An alternative metric based on total aggregate loss in each time window (aggregate exceedance probability) was therefore also examined, for which the Poisson model again implies higher risk at intermediate losses but lower risk at higher losses (because large, triggered events now contribute to total aggregate losses for the fully time-dependent model). We also argue that declustering is not a scientifically justifiable way to deal with full time dependence, in agreement with a chorus from other recent studies. It is difficult to draw generally applicable conclusions from our study, in part because application specific details will likely be important, but our results highlight how full time dependence can be reckoned with once authoritative forecast models are made available.

California↗
USGS1986

Potential for leakage among principal aquifers in the Memphis area, Tennessee

The principal aquifers in the Memphis area consist primarily of sand or sand and gravel, and the confining beds consist of clay, silt, sand, and lignite. The Jackson Formation and upper part of the Claiborne Group serve as the confining bed separating the water table aquifers from the Memphis Sand; the Flour Island Formation separates the Memphis Sand from the Fort Pillow Sand. Differences in total hydraulic head among the principal aquifers in the Memphis urban area result in vertical hydraulic gradients which create a potential for inter-aquifer exchange of water. Throughout this area, the gradient is downward from the water table aquifers to the Memphis Sand. In the central part of the Memphis urban area, the vertical hydraulic gradient is upward from the Fort Pillow Sand to the Memphis Sand, and in the eastern and western parts, it is downward from the Memphis Sand to the Fort Pillow Sand. The vertical distribution of carbon-14 data for water from the fluvial deposits, Memphis Sand, and Fort Pillow Sand shows an increase in the relative age of the water with depth. The areal distribution of carbon-14 data for water from the upper part of the Memphis Sand indicates that relatively recent water has been brought into the major cone of depression in the potentiometric surface of the Memphis Sand, either by horizontal movement or from downward vertical leakage. The normal, near-surface geothermal gradient in the Memphis area was determined to be 0.6 C/100 ft. Deviations from the normal geothermal gradient, in areas affected by intense pumping from the Memphis Sand, indicate that downward vertical leakage occurs from the water table aquifers through the Jackson-upper Claiborne confining bed to the Memphis Sand. The velocity of downward vertical leakage of water from the Memphis Sand through the Flour Island confining bed to the Fort Pillow Sand was determined to be 0.0066 ft/day by analysis of borehole temperature data from an observation well in the northeastern part of the Memphis area. From this velocity and the head difference between the Memphis Sand and the Fort Pillow Sand at this locality, the hydraulic conductivity of the Flour Island confining bed was determined to be 0.00114 ft/day. (Lantz-PTT)

Tennessee↗
USGS2025

Probing lower-crustal fault properties with frequency-dependent tidal tremor triggering

The way seismicity responds to periodic stress perturbations offers crucial insights into the processes that can trigger an earthquake. Laboratory and theoretical analyses have shown that the period of imposed forcing and source properties affect the sensitivity to triggering, but frequency-dependent triggering of tectonic faults is poorly understood. The rate of low-frequency earthquakes (LFEs) near Parkfield, California has been found to be strongly correlated with solid earth tides. Tidal forcing acts over multiple frequencies, and the sensitivity to tidal triggering of LFEs therefore provides a unique opportunity to probe the physics of earthquake triggering and underlying fault properties. Here, we find that the response of LFEs to solid earth tides at diurnal and semi-diurnal frequencies is highly variable but spatially coherent along the San Andreas Fault. Using rate-state friction modeling, we find that the variation of the amplitude of tidal modulation is mainly affected by the spatial variation of the background effective normal stress, whereas the spatially varied tidal modulation at diurnal and semi-diurnal frequencies is mainly affected by the fault frictional property. The spatial variations of the LFE response reveal a heterogeneous lower-crustal geologic structure and complex physical faulting processes below the rupture zone of eventual great earthquakes.

California↗
USGS2024

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin↗
USGS2024

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗
USGS2024

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets↗
USGS2025

Mineral commodity summaries 2025

Introduction Each mineral commodity chapter of the 2025 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2024 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the MCS 2025 are welcomed.

Mineral Commodity Summaries↗
USGS2026

Mineral commodity summaries 2026

Introduction Each mineral commodity chapter of the 2026 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2025 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the 2026 MCS are welcomed.

Mineral Commodity Summaries↗
USGS2025

Relationship between peak and cumulative ground motions from 49 Mw 3-6 earthquakes in the San Francisco Bay Area

We examine the relationship between peak ground velocity (PGV) and cumulative absolute displacement (CAD) for 49 M w 3 – 6 earthquakes in the San Francisco Bay Area (SFBA) and gain insight into the spatiotemporal partitioning of seismic energy in ground motion records with respect to source, path, and site effects. PGV and CAD are positively correlated, but there can be large deviations from the average trend. For example, ground motion records with either very long duration resonance or short pulse-like motions will have higher or lower CAD, respectively, but could have very similar PGV. We perform principal component analysis (PCA) on PGV-CAD for >7000 records in the SFBA with the goal of investigating what influences positive or negative anomalies in cumulative motions. PCA rotates the PGV-CAD datapoints into two principal components, where the one with the larger variance, which we call the “primary intensity” represents mostly the distance-dependence of ground motion amplitudes. The other principal component, which we call the “excess motion”, represents the deviation from cumulative motions that would be typical for a ground motion record with a given PGV. The excess motion will be positive in the case of records with long duration ringing and will be negative for short duration pulse-like ground motions. We find that excess motion is generally positive at sites in sedimentary basins and in soft sediments around the SF Bay. Excess motion is generally negative in the very near field, as well as at sites on hard bedrock. We discuss the findings here in terms of implications for seismic hazard applications and other wave propagation phenomena.

California↗
USGS2024

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2021–22

Between the 1950s and 1980s, wastewater generated at the Idaho National Laboratory contained Iodine-129 ( 129 I); this wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well, unlined infiltration ponds, or leaked from distribution systems below industrial facilities. During 2021–22, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy and the Idaho Department of Environmental Quality Idaho National Laboratory Oversight Program, collected groundwater samples from 64 monitoring wells in the ESRP aquifer, 6 of which are part of a multilevel monitoring system, to determine the concentration of 129 I in the groundwater. These samples were analyzed by accelerator mass spectrometry as part of a long-term ongoing study to track trends and occurrences of this carcinogenic, long-lived radionuclide in the environment. Concentrations ranged from slightly above the locally determined background concentration of 5.4×10 −6 picocuries per liter, to just below the U.S. Environmental Protection Agency’s maximum contaminant level of 1 picocurie per liter. Discharge of wastewater containing 129 I has been discontinued to the aquifer, and long-term trends from a subset (n=15) of sampled wells show decreasing 129 I concentrations over the last three decades. Concentrations of 129 I in groundwater from monitoring wells near facilities at the Idaho National Laboratory are affected by episodic recharge from an ephemeral surface-water source and by the fracture-flow dominated hydrologic regime in the ESRP aquifer. The spatially focused sampling effort has also identified a low-level 129 I plume that affects long-term water quality near and downgradient from the Advanced Test Reactor Complex in the southwestern part of the facility that had not been clearly defined in previous sampling efforts, although the definition of the plume is somewhat limited by available data.

Idaho↗
USGS2025

Lithium from magma to mine in an early Yellowstone hotspot caldera

Renewable energy technologies rely on the extraction of metals not historically in high demand, such as lithium (Li), for which ore deposit models are incompletely understood. One of the world’s largest Li deposits is hosted in lake sediments of the 16.4 Ma McDermitt caldera, which formed during the early stages of Yellowstone hotspot volcanism in the western United States. Eruptive and posteruptive mobility of Li are major challenges in elucidating deposit formation. Melt inclusions preserved in quartz crystals provide a means to assess pre-eruptive magmatic Li contents. Concentrations of Li determined by ion microprobe for melt inclusions in a McDermitt rhyolite lava are 400−1350 ppm, compared to 20−70 ppm Li in matrix rhyolite glasses. Synthesis with melt inclusion data for eight additional calderas demonstrates a recurrence of Li-rich rhyolitic magmas (200−2000 ppm Li) in the western part of the Yellowstone hotspot track. However, unlike the multicyclic caldera complexes with overlapping fault networks that may have compromised Li retention, the McDermitt caldera remained a closed hydrologic system throughout its evolution. Modeling indicates 100 km 3 of resurgent magma could yield 25−150 Mt Li in a magmatic fluid and supports accumulation of Li-rich magmatic fluid in a closed intracaldera lake, followed by evaporative concentration and sequestration of Li within clay minerals to generate the McDermitt deposit.

Idaho, Nevada, Oregon, Wyoming↗
USGS2024

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island↗
USGS2000

Water-quality conditions and relation to drainage-basin characteristics in the Scituate Reservoir Basin, Rhode Island, 1982-95

The Scituate Reservoir Basin covers about 94 square miles in north central Rhode Island and supplies more than 60 percent of the State of Rhode Island's drinking water. The basin includes the Scituate Reservoir Basin and six smaller tributary reservoirs with a combined capacity of about 40 billion gallons. Most of the basin is forested and undeveloped. However, because of its proximity to the Providence, Rhode Island, metropolitan area, the basin is subject to increasing development pressure and there is concern that this may lead to the degradation of the water supply. Selected water-quality constituent concentrations, loads, and trends in the Scituate Reservoir Basin, Rhode Island, were investigated locate parts of the basin likely responsible for exporting disproportionately large amounts of water-quality constituents to streams, rivers, and tributary reservoirs, and to determine whether water quality in the basin has been changing with time. Water-quality data collected between 1982 and 1995 by the Providence Water Supply Board PWSB) in 34 subbasins of the Scituate Reservoir Basin were analyzed. Subbasin loads and yields of total coliform bacteria, chloride, nitrate, iron, and manganese, estimated from constituent concentrations and estimated mean daily discharge records for the 1995 water year, were used to determine which subbasins contributed disproportionately large amounts of these constituents. Measurements of pH, color, turbidity, and concentrations of total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese made between 1982 and 1995 by the PWSB were evaluated for trends. To determine the potential effects of human-induced changes in drainage- basin characteristics on water quality in the basin, relations between drainage-basin characteristics and concentrations of selected water-quality constituents also were investigated. Median values for pH, turbidity, total coliform bacteria, sodium, alkalinity, chloride, nitrate, and iron were largest in subbasins with predominately residential land use. Median instantaneous loads reflected drainage-basin size. However, loads normalized by drainage area (median instantaneous yields) also were largest in residential areas where point and non-point sources are likely, and in areas of poorly drained soils. Significant trends in water-quality constituents from 1982 to 1995 in the Scituate Reservoir Basin indicate that the quality of the water resources in the basin may be slowly changing. Scituate Reservoir subbasins with large amounts of residential land use showed increasing trends in alkalinity and chloride. In contrast, subbasins distributed throughout the drainage basin showed increasing trends in pH, color, nitrate, and iron concentrations, indicating that these characteristics and constituents may be affected more by atmospheric deposition. Although changing, water-quality constituent concentrations in the Scituate Reservoir Basin only occasionally exceeded Rhode Island and USEPA water-quality guidelines and standards. Result of correlation analysis between pH, color, turbidity, and concentrations total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese and land use, geology, wetlands, slope, soil drainability, and roads indicated that the percentage of wetlands, roads, and slope appear have the greatest effect on water-quality in the Scituate Reservoir Basin. The percentage of urban, residential, and commercial land use also are important, but to a lesser degree than wetlands, roads, and slope. Finally, geology appears to have the least effect on water quality compared to other drainage-basin characteristics investigated.

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