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USGS2007

Evaluation of Streamflow Gain-Loss Characteristics of Hubbard Creek, in the Vicinity of a Mine-Permit Area, Delta County, Colorado, 2007

In 2007, the U.S. Geological Survey, in cooperation with Bowie Mining Company, initiated a study to characterize the streamflow and streamflow gain-loss in a reach of Hubbard Creek in Delta County, Colorado, in the vicinity of a mine-permit area planned for future coal mining. Premining streamflow characteristics and streamflow gain-loss variation were determined so that pre- and postmining gain-loss characteristics could be compared. This report describes the methods used in this study and the results of two streamflow-measurement sets collected during low-flow conditions. Streamflow gain-loss measurements were collected using rhodamine WT and sodium bromide tracers at four sites spanning the mine-permit area on June 26-28, 2007. Streamflows were estimated and compared between four measurement sites within three stream subreaches of the study reach. Data from two streamflow-gaging stations on Hubbard Creek upstream and downstream from the mine-permit area were evaluated. Streamflows at the stations were continuous, and flow at the upstream station nearly always exceeded the streamflow at the downstream station. Furthermore, streamflow at both stations showed similar diurnal patterns with traveltime offsets. On June 26, streamflow from the gain-loss measurements was greater at site 1 (most upstream site) than at site 4 (most downstream site); on June 27, streamflow was greater at site 4 than at site 2; and on June 27, there was no difference in streamflow between sites 2 and 3. Data from streamflow-gaging stations 09132940 and 09132960 showed diurnal variations and overall decreasing streamflow over time. The data indicate a dynamic system, and streamflow can increase or decrease depending on hydrologic conditions. The streamflow within the study reach was greater than the streamflows at either the upstream or downstream stations. A second set of gain-loss measurements was collected at sites 2 and 4 on November 8-9, 2007. On November 8, streamflow was greater at site 4 than at site 2, and on the following day, November 9, streamflow was greater at site 2 than at site 4. Data collection on November 8 occurred while the streamflow was increasing due to contributions from stream ice melting throughout different parts of the basin. Data collection on November 9 occurred earlier in the day with less stream ice melting and more steady-state conditions, so the indication that streamflow decreased between sites 2 and 4 may be more accurate. Diurnal variations in streamflow are common at both the upper and the lower streamflow-gaging stations. The upper streamflow-gaging station shows a melt-freeze influence from tributaries to Hubbard Creek during the winter season. Downstream from the study reach, observed diurnal variation is likely due to evapotranspiration associated with dense flood-plain vegetation, which consumes water from the creek during the middle of the day. Varying diurnal patterns in streamflow, combined with possible variations in tributary inflows to Hubbard Creek in the study reach, probably account for the observed variations in streamflow at the tracer measurement sites. During both sampling periods in June and November 2007, conditions were less than ideal and not steady state. The June 27 sampling indicates that the streamflow was increasing between measurement sites 2 and 4, and the November 9 sampling indicates that the streamflow was decreasing between measurement sites 2 and 4. The data collected during the diurnal and day-to-day variations in streamflow indicated that the streamflow reach is dynamic and can be gaining, losing, or constant.

Scientific Investigations Report↗

USGS2005

Status of and changes in water quality monitored for the Idaho statewide surface-water-quality network, 1989—2002

The Idaho statewide surface-water-quality monitoring network consists of 56 sites that have been monitored from 1989 through 2002 to provide data to document status and changes in the quality of Idaho streams. Sampling at 33 sites has covered a wide range of flows and seasons that describe water-quality variations representing both natural conditions and human influences. Targeting additional high- or low-flow sampling would better describe conditions at 20 sites during hydrologic extremes. At the three spring site types, sampling covered the range of flow conditions from 1989 through 2002 well. However, high flows at these sites since 1989 were lower than historical high flows as a result of declining ground-water levels in the Snake River Plain. Summertime stream temperatures at 45 sites commonly exceeded 19 and 22 degrees Celsius, the Idaho maximum daily mean and daily maximum criteria, respectively, for the protection of coldwater aquatic life. Criteria exceedances in stream basins with minimal development suggest that such high temperatures may occur naturally in many Idaho streams. Suspended-sediment concentrations were generally higher in southern Idaho than in central and northern Idaho, and network data suggest that the turbidity criteria are most likely to be exceeded at sites in southern Idaho and other sections of the Columbia Plateaus geomorphic province. This is probably because this province has more fine-grained soils that are subject to erosion and disturbance by land uses than the Northern Rocky Mountains province of northern and central Idaho has. Although erodable soils are likely a cause of elevated turbidities, suspended-sediment concentrations were not strongly correlated with turbidities. Dissolved-solids and hardness concentrations were strongly correlated. This is probably because the limestones present in some basins are more soluble than the igneous rocks that predominate in others. Low hardness in streams of northern Idaho, where watersheds are underlain by resistant igneous rocks, enhances the toxicity of some trace elements to aquatic life in these streams. Only a few measurements of dissolved-oxygen concentrations at six sites were less than 6.0 milligrams per liter, the Idaho minimum criterion for protection of aquatic organisms. High supersaturations of dissolved oxygen at four sites suggest excessive photosynthetic activity by algal communities. Nighttime monitoring would help determine whether dissolved-oxygen concentrations at these sites might fall below the Idaho criterion. Data from four sites suggest that dissolved-oxygen concentrations may have decreased over time. The pH at 15 sites sometimes fell outside the range specified (6.5-9.0) for the protection of aquatic organisms in Idaho streams. Values exceeded 9.0 at 10 sites, probably because of excessive algal photosynthetic activity in waters where carbonate rocks are present. Values were sometimes less than 6.5 at five sites in areas of mountain bedrock geology where pH is likely to be naturally low. Mining activities also may contribute to low pH at some of these sites. Inorganic nitrogen and total phosphorus concentrations commonly exceeded those considered sufficient for supporting excess algal production (0.3 and 0.1 milligrams per liter, respectively). Data from a few sites suggest that nitrogen and(or) phosphorus concentrations might be changing over time. Low concentrations of nitrogen and phosphorus at six sites, most representing forested basins, might make them good candidates as reference sites that represent naturally occurring nutrient concentrations. Trace elements examined for this report were cadmium, copper, lead, mercury, selenium, and zinc. In water, many trace-element concentrations were below the minimum analytical reporting levels. Concentrations of cadmium, copper, lead, and zinc generally were highest in mined and other mineral-rich basins in northern Idaho. Concentrations of mercury were

Idaho↗

USGS2023

Characterization of streamflow and nutrient occurrence in the upper White River Basin, Colorado, 1980–2020

In 2016, Colorado Parks and Wildlife identified filamentous algae collected from the main stem White River as Cladophora glomerata , a pervasive nuisance aquatic alga. Excessive levels of filamentous algae can compromise aesthetic quality, limit recreational activities, and have negative effects on aquatic life including strong fluctuations in dissolved oxygen levels and a reduction in overall biodiversity. To increase understanding of the biology of the upper White River Basin in Colorado, identify potential factors promoting or limiting nuisance algal abundance, and outline information to aid in the understanding and protection of water resources, the U.S. Geological Survey (USGS), in cooperation with the White River and Douglas Creek Conservation Districts and the White River Algae Technical Advisory Group, initiated a study to collect and analyze physical, chemical, and biological information for the upper White River Basin. The report describes long-term changes and spatial variations in streamflow and nutrient concentrations and loads in the upper White River Basin and identifies possible nutrient sources in the basin. Long-term streamflow and nutrient data indicate that conditions in the upper White River Basin have become more favorable to benthic algae over varying timescales. Upward trends in total phosphorus concentrations and loads were found at three sites across the basin from 2000 to 2020. Total phosphorus loads increased around 50 percent, ranging from 18 to 48 pounds per year. Annual estimated concentrations of total phosphorus from 2005 to 2020 were above algal-specific nutrient criteria at the North Fork White River at Buford, Colo., indicating that phosphorus concentrations at this site likely promote algal growth. Discrete concentrations of total phosphorus exceeded algal-specific nutrient criteria on the South Fork and main stem White River during the summer season, though less frequently than samples collected from the North Fork White River. Nitrogen to phosphorus molar ratios collected from July to September indicate movement from colimitation (10–22) to nitrogen limited (less than 13) conditions at the North Fork White River at Buford, Colo. and the South Fork White River at Buford, Colo. starting in 2012. The magnitude of trends in phosphorus loads were generally greater than trends in concentrations across all sites, indicating that the largest changes in concentrations occurred during greater streamflow periods. At White River above Coal Creek, near Meeker, Colo., significant downward trends in streamflow were found in August and September for mean streamflow (15 and 14 percent per decade, respectively) and 7-day minimum streamflows (23 and 22 percent per decade, respectively). Significant downward trends in annual 7-day minimum streamflows of 24 percent per decade, or 66 percent over the 40-year period of analysis, were also observed. Though not significant based on 90-percent confidence intervals, downward trends in 1-day maximum and mean streamflows in May and June and corresponding increases in April may indicate a shift toward earlier snowmelt runoff, as observed across western North America and the Colorado River Basin. Alteration of the annual hydrograph can influence factors that influence algae including nutrient input and dilution potential, water temperature, dissolved oxygen, light availability, and physical disturbance. Results from a synoptic-style sampling identified the lower North Fork White River subbasin as a large source of phosphorus to the downstream system. Large increases in phosphorus loads were observed below Marvine Creek. Synoptic samples and samples collected during spring and summer of 2019 and 2020 also show large increases in total nitrogen, orthophosphate, and total phosphorus occurring at the furthest three downstream sites on the White River. To further evaluate sources of nitrogen in the upper White River Basin, the dual isotopic composition of nitrate was compared across four sites. The isotopic compositions of nitrate were all within the expected range of typical soil-derived nitrate, though the same values can also be derived from a mixture of agricultural fertilizer and manure or septic sources.

Colorado↗

USGS1988

Water resources of the Apostle Islands National Lakeshore, northern Wisconsin

The Apostle Islands National Lakeshore consists of 21 islands, part of the Bayfield Peninsula, and the adjacent waters of Lake Superior. Selected water resources of the Apostle Islands National Lakeshore were assessed to aid the National Park Service in developing and managing the Lakeshore and to provide a data base against which future changes can be compared. This summary of water-resources data, collected by the U.S. Geological Survey during 1979-84, provides a qualitative description of selected hydrologic components of the Lakeshore. Streamflow in the Lakeshore area is characterized by typical seasonal fluctuations. Flow in Sand River at State Highway 13 ranged from 3.9 to 1,630 cubic feet per second. The recurrence interval of the maximum observed discharge was about 4 years. The minimum observed 7-day low flow was 3.86 cubic feet per second. The greatest concentrations of most chemical constituents in Bayfield Peninsula streams occurred during base flow. Annual sediment loads in Sand River at State Highway 13 ranged from 977 tons in 1980 water year to 24,600 tons in 1984 water year.The average annual sediment load transported by Bayfield Peninsula streams to the National Lakeshore area of Lake Superior is estimated to be 44,000 tons. Annual phosphorus loads ranged from 1,400 pounds in 1980 water year to 11,100 pounds in 1984 water year. The average annual phosphorus load transported by Bayfield Peninsula streams to the National Lakeshore area of Lake Superior is estimated to be 21,500 pounds. Few island streams flow perennially, but Oak Island streams generally yield more base-flow runoff than Stockton Island streams. The base flow of Oak Island streams is dominated by ground-water discharge, whereas Stockton Island stream base flow is sustained by seepage from wetlands and beaver ponds. There are two major lagoons in the Lakeshore, the Outer Island Lagoon's area is 53 acres and its maximum depth is 7 feet. Dominant inflow to the lagoon is from precipitation on its surface and seepage from an adjacent bog. Outflow during open-water periods is dominated by evaporation. Ground-water seepage from the lagoon toward Lake Superior occurs yearround. The lagoon's water is acidic and has low specific conductance and generally small concentrations of most chemical constituents. The Michigan Island Lagoon is about 4 acres in area and its maximum depth is 6.5 feet. The most significant sources of inflow appear to be precipitation and wave washover from Lake Superior. Water from four deep-water monitoring sites in Lake Superior revealed concentrations of total phosphorus, organic carbon, and recoverable mercury ranging from <0.01 to 0.02 milligrams per liter, 1.1 to 5.3 milligrams per liter and <0.1 to 0.1 micrograms per liter, respectively. Neither pesticide residues nor fecal coliform bacteria were detected in the water column. Total phosphorus concentrations in bottom sediment ranged from 50 to 470 milligrams per kilogram and were related directly to the percentage of fine-grained (< 0.0625 millimeters) sediment particles. Traces of only two pesticide residues- DDE and DDT were detected in sediment. The most abundant benthic macroinvertebrate was Pontoporeia affinis, which was found in densities of from 960 to 2,100 organisms per square meter. No adverse affects resulting from visitor use were detected in the shallow-water, heavy-use areas in Presque Isle Bay off Stockton Island or in the waters between Rocky and South Twin Islands. Phosphorus and organic-carbon concentrations were similar to those observed in the deep-water area; mercury was not detected in water from either area. Ground-water use in the National Lakeshore is primarily for consumption by Lakeshore visitors and employees. Of 14 wells constructed from 1979-84, 4 were finished in glacial sand and gravel, and 10 were finished in sandstone. Specific capacities ranged from 0.63 to 50 gallon per minute per foot. Average concentrations of dissolved solids are moderate and concentrations of heavy metals did not exceed Wisconsin's primary health standard.

Wisconsin↗

USGS2010

Nitrogen Loads in Groundwater Entering Back Bays and Ocean from Fire Island National Seashore, Long Island, New York

Fire Island is a barrier island that lies south of central Long Island, N.Y. It is about 60 km (37 mi) long and 0.5 km (1/4 mi) wide and is bounded by the Great South Bay, Narrow Bay, and Moriches Bay estuaries to the north; by the Atlantic Ocean to the south; by Fire Island Inlet to the west; and by Moriches Inlet to the east (fig. 1). Fire Island National Seashore (FIIS) encompasses a 42-km (26-mi) length of Fire Island that is bordered by Robert Moses State Park to the west and Smith Point County Park to the east (fig. 2). Interspersed throughout FIIS are 17 residential beach communities that together contain about 4,100 homes. The barrier island's summer population increases 50-fold through the arrival of summer residents and vacationers. The National Park Service (NPS) has established several facilities on the island to accommodate visitors to FIIS. About 2.2 million people visit at least one of the 17 communities and (or) Smith Point County Park, the waterways surrounding Fire Island, or a FIIS facility annually (National Park Service, 2007). Combined visitation on a peak-season weekend day can be as high as 100,000 (National Park Service, 2002). Most homes and businesses in the 17 barrier-island communities discharge untreated wastewater directly to the shallow (water-table) aquifer through private septic systems and cesspools; the NPS facilities discharge wastewater to this aquifer through leach fields and cesspools. (The community of Ocean Beach (fig. 2) has a treatment plant that discharges to tidewater.) Contaminants in sewage entering the shallow groundwater move through the flow system and are ultimately discharged to adjacent marine surface waters, where they can pose a threat to coastal habitats. A contaminant of major concern is nitrogen, which is derived from fertilizers and human waste. The continuous inflow of nitrogen to surface-water bodies can lead to increased production of phytoplankton and macroalgae, which in turn can cause oxygen depletion, decreases in size of estuarine fish and shellfish communities, and loss of submerged seagrass habitat through light limitation (Valiela and others, 1992). The FIIS boundary extends roughly 1.2 km (0.8 mi) into the back-barrier estuaries of Great South Bay, Narrow Bay, and Moriches Bay (fig. 1). Within this estuarine zone are extensive areas of seagrass, shellfish, and finfish habitat, as well as intense recreational activity (Bokuniewicz and others, 1993). Management strategies for protection of these habitats require data on (1) concentrations and movement of nutrients and other human-derived contaminants that enter the groundwater system from on-site septic systems, and (2) aquifer characteristics and groundwater flow patterns. These data can then be used in three-dimensional flow models of the shallow aquifer system to predict the rates of groundwater discharge to the marine surface waters that bound Fire Island and the concentrations of nitrogen entering these water bodies from the aquifer's discharge zones. In 2004, the U.S. Geological Survey (USGS), in cooperation with the NPS, began a 3-year investigation to (1) measure groundwater levels within four local study areas at FIIS, (2) collect groundwater samples from these areas for nutrient (nitrogen) analysis, (3) develop a three-dimensional model of the hydrologic system and adjacent saltwater bodies for groundwater-flow delineation and particle tracking, and (4) apply the results of groundwater-discharge simulations to calculate the annual nitrogen loads in these discharges, particularly those entering Great South Bay, which together with the other back bays receives an estimated 80 percent of the total groundwater discharge from Fire Island. The four areas on which the investigation focused were the communities of Kismet and Robbins Rest, the NPS Visitor Center at Watch Hill, and the undeveloped Otis Pike Fire Island High Dune Wilderness (shown in panels A, B, C, and D in fig. 2); these were

Open-File Report↗

USGS2003

Hydrologic conditions and assessment of water resources in the Turkey Creek watershed, Jefferson County, Colorado, 1998-2001

The 47.2-square-mile Turkey Creek watershed, in Jefferson County southwest of Denver, Colorado, is relatively steep with about 4,000 feet of relief and is in an area of fractured crystalline rocks of Precambrian age. Water needs for about 4,900 households in the watershed are served by domestic wells and individual sewage-disposal systems. Hydrologic conditions are described on the basis of contemporary hydrologic and geologic data collected in the watershed from early spring 1998 through September 2001. The water resources are assessed using discrete fracture-network modeling to estimate porosity and a physically based, distributed-parameter watershed runoff model to develop estimates of water-balance terms. A variety of climatologic and hydrologic data were collected. Direct measurements of evapotranspiration indicate that a large amount (3 calendar-year mean of 82.9 percent) of precipitation is returned to the atmosphere. Surface-water records from January 1, 1999, through September 30, 2001, indicate that about 9 percent of precipitation leaves the watershed as streamflow in a seasonal pattern, with highest streamflows generally occurring in spring related to snowmelt and precipitation. Although conditions vary considerably within the watershed, overall watershed streamflow, based on several records collected during the 1940's, 1950's, 1980', and 1990's near the downstream part of watershed, can be as high as about 200 cubic feet per second on a daily basis during spring. Streamflow typically recedes to about 1 cubic foot per second or less during rainless periods and is rarely zero. Ground-water level data indicate a seasonal pattern similar to that of surface water in which water levels are highest, rising tens of feet in some locations, in the spring and then receding during rainless periods at relatively constant rates until recharged. Synoptic measurements of water levels in 131 mostly domestic wells in fall of 2001 indicate a water-table surface that conforms to topography. Analyses of reported well-construction records indicate a median reported well yield of 4 gallons per minute and a spatial distribution for reported well yield that has relatively uniform conditions of small-scale variability. Results from quarterly samples collected in water year 1999 at about 112 wells and 22 streams indicate relatively concentrated calcium-bicarbonate to calcium-chloride type water that has a higher concentration of chloride than would be expected on the basis of chloride content in precipitation and evapotranspiration rates. Comparison of the 1999 data to similar data collected in the 1970's indicates that concentrations for many constituents appear to have increased. Reconnaissance sampling in the fall of 2000 indicates that most ground water in the watershed was recharged recently, although some ground water was recharged more than 50 years ago. Additional reconnaissance sampling in the spring and fall of 2001 identified some compounds indicative of human wastewater in ground water and surface water. Outcrop fracture measurements were used to estimate potential porosities in three rock groups (metamorphic, intrusive, and fault zone) that have distinct fracture characteristics. The characterization, assuming a uniform aperture size of 100 microns, indicates very low potential fracture porosities, on the order of hundredths of a percent for metamorphic and intrusive rocks and up to about 2 percent for fault-zone rocks. A fourth rock group, Pikes Peak Granite, was defined on the basis of weathering characteristics. Short-term continuous and synoptic measurements of streamflow were used to describe base-flow characteristics in areas of the watershed underlain by each of the four rock groups and are the basis for characterization of base flow in a physically based, distributed-parameter watershed model. The watershed model, the Precipitation-Runoff Modeling System (PRMS), was used to characterize hydrologic conditions

Water-Resources Investigations Report↗

USGS1997

Preliminary geologic map of the San Fernando 7.5' quadrangle, southern California: A digital database

The city of San Fernando sits atop a structurally complex, sedimentologically diverse, and tectonically evolving late Tertiary-Quaternary basin situated within the Transverse Ranges of southern California. The surrounding San Fernando Valley (SFV) contains the headwaters of the Los Angeles River and its tributaries. Prior to the advent of flood control, the valley floor was composed of active alluvial fans and floodplains. Seasonal streams emanating from Pacoima and Big Tujunga Canyons drain the complex western San Gabriel Mountains and deposit coarse, highly permeable alluvium that contains generally high-quality ground water. The more shallow western part derives mainly from Tertiary and pre-Tertiary sedimentary rocks, and is underlain by less permeable, fine-grained deposits containing persistent shallow ground water and poorer water quality. Home of the 1971 San Fernando and the 1994 Northridge earthquakes, the SFV experienced near-record levels of strong ground motion in 1994 that caused widespread damage from strong shaking and ground failure. A new map of late Quaternary deposits of the San Fernando area shows that the SFV is a structural trough that has been filled from the sides, with the major source of sediment being large drainages in the San Gabriel Mountains. Deposition on the major alluvial fan of Tujunga Wash and Pacoima Wash, which issues from the San Gabriel Mountains, and on smaller fans, has been influenced by ongoing compressional tectonics in the valley. Late Pleistocene deposits have been cut by active faults and warped over growing folds. Holocene alluvial fans are locally ponded behind active uplifts. The resulting complex pattern of deposits has a major effect on liquefaction hazards. Young sandy sediments generally are highly susceptible to liquefaction where they are saturated, but the distribution of young deposits, their grain size characteristics, and the level of ground water all are complexly dependent on the tectonics of the valley. The San Fernando area lies on the southern slopes of the San Gabriel Mountains. The basement rocks here include high-grade metamorphic rocks of Precambrian age. The mountains are largely composed of crystalline basement that includes the Pelona Scist of probable Mesozoic age that has been overthrust by Precambrian gneisses; the gneisses were subsequently intruded by Mesozoic plutons prior to overthrusting along the latest Cretaceous Vincent thrust. Gneisses of somewhat variable composition and possibly varying ages are found in four terranes, but not all are in contact with Pelona Schist. Large tracts of Precambrian (1.2 billion years old) andesine anorthosite are intrusive into 1.7 billion year-old Mendenhall gneiss, and are found in the western part of the San Gabriels. Mixed with these are younger marble, limestone, and schist of possible Paleozoic age found in association with plutons along the southern margin of the range. The older rocks are intruded by diorite, quartz diorite, and granodiorite of Jurassic age. Also present are siliceous sedimentary rocks of Jurassic age. A thick section of Tertiary sedimentary and volcanic rocks overlie these units. The sediments located south of the San Gabriel Fault are totally different in character from those on the northern range flank, and mostly resemble the western Transverse Ranges due to their deposition in the southeastern Ventura basin; approximately 3,000 m of these sediments are exposed north and west of the city of San Fernando in the Tujunga syncline. Some of the Tertiary rocks are Paleocene and Eocene in age, but the bulk of these rocks are Oligocene and Miocene in age. The Vasquez and Sespe Formations of basal basaltic volcanic and sandstone are Oligocene and lower Miocene in age. These are overlain by clastic rocks of Tick Canyon and Mint Canyon Formations of middle to late Miocene age. Above these rocks are the Castaic, Modelo, and Santa Margarita Formations of fossiliferous marine shale, sand

California↗

USGS2006

Ground-Water Levels in Huron County, Michigan, 2004-05

In 1990, the U.S. Geological Survey (USGS) completed a study of the hydrogeology of Huron County, Michigan (Sweat, 1991). In 1993, Huron County and the USGS entered into a continuing agreement to measure water levels at selected wells throughout Huron County. As part of the agreement, USGS has operated four continuous water-level recorders, installed from 1988 to 1991 on wells in Bingham, Fairhaven, Grant, and Lake Townships (fig. 1) and summarized the data collected in an annual or bi-annual report. The agreement was altered in 2003, and beginning January 1, 2004, only the wells in Fairhaven and Lake Townships retained continuous waterlevel recorders, while the wells in Grant and Bingham Townships reverted primarily to periodic or quarterly measurement status. USGS also has provided training for County or Huron Conservation District personnel to measure the water level, on a quarterly basis, in 25 wells. USGS personnel regularly accompany County or Huron Conservation District personnel to provide a quality assurance/quality control check of all measurements being made. Water-level data collected from the 25 periodically or quarterly-measured wells is summarized in an annual or bi-annual report. In 1998, the USGS also completed a temporal and spatial analysis of the monitoring well network in Huron County (Holtschlag and Sweat, 1998). The altitude of Lake Huron and precipitation are good indicators of general climatic conditions and, therefore, provide an environmental context for ground-water levels in Huron County. Figure 2 shows the mean-monthly water-level altitude of Lake Huron, averaged from measurements made by the U.S. Army Corps of Engineers at sites near Essexville or Harbor Beach, or both (National Oceanic and Atmospheric Administration, 2003-05), and monthly precipitation measured in Bad Axe (National Oceanic and Atmospheric Administration, 2003-05). In March 2003, a new low-water level for the period from 1991 through 2005 was measured in Lake Huron. There was almost no net change in the water level of Lake Huron from January 2004 through December 2005. In 2004, annual precipitation measured in Port Hope was about 3.7 inches above normal, but precipitation measured in Bad Axe was about 1.4 inches below normal. About 14.5 inches of precipitation was measured in Bad Axe during the 2004 summer growing season (May through August), which is about the same as was measured in Port Hope during the same period. Provisional precipitation totals for 2005 were 30.7 inches for January through November in Port Hope, and about 31.7 inches for the year in Bad Axe. About 10.6 inches of precipitation was measured in Bad Axe during the 2005 summer growing season, which is about 0.2 inches more than was recorded at Port Hope during the same period. Two wells equipped with continuous-data recorders are completed in the Saginaw and Marshall aquifers in Fairhaven and Lake Townships, respectively. From January 2004 through December 2005, the net rise in the water level in the Fairhaven Township well was 0.71 ft, and the net rise in the Lake Township well was 0.98 ft. The Fairhaven Township well is drilled adjacent to Saginaw Bay (Lake Huron), and, as previously noted, there was almost no net change in the water level in Saginaw Bay over the same period. Hydrographs showing water levels are presented for the two wells equipped with continuous-data recorders. Continuous-data recorders were discontinued in the Grant and Bingham Township wells at the end of 2003 due to budget constraints. The decision of which two wells to discontinue was based on an analysis of the intrinsic value to Huron County of data from each well. The Grant Township well was selected for periodic or quarterly measurement at that time because it is completed in the glacial aquifer, which is little used for drinking water purposes or absent in much of Huron County. The Bingham Township well, which is completed in the Marshall aquifer, was selected for periodic or quarterly measurement because water levels in the well are often perturbed as a result of pumpage from nearby production wells and do not reflect baseline conditions within the aquifer. Twenty five wells were measured on a periodic or quarterly basis in 2004-05. These wells are completed in the glacial, Saginaw, and Marshall aquifers, and the Coldwater confining unit. Although each quarterly measurement only provides a “snapshot” water level (measured in feet below land surface), the data adequately define the generalized water-level trend in the aquifer near the well. Water levels in 15 quarterlymeasured wells had a net rise ranging from 0.20 to 1.31 ft for the period from January 2004 to December 2005, while water levels in 10 of the wells had a net decline ranging from 0.07 to 0.99 ft over the same period (fig. 3; table 1). Period-of-record (the time period when water levels have been measured by U.S. Geological Survey or their cooperators) minimum depths to water (high-water levels) were measured in March 2004 in two quarterly-measured wells completed in the Marshall aquifer in Lake and Hume Townships. Period-of-record maximum depths to water were measured in September 2005 in three wells completed in the Marshall aquifer near Bad Axe. Water levels in those three wells recovered about 3 to 5 ft between September and December 2005. No period-of-record minimum or maximum depths to water were measured for the period from January 2004 through December 2005 in wells completed in either the glacial and Saginaw aquifers, or the Coldwater confining unit. Hydrographs showing water levels measured in each well are presented for the 25 wells measured on a quarterly basis. Water-level trends measured for the period from January 2004 through December 2005 in other wells in Lower Michigan have similarities to those measured in Huron County wells. Several external factors influence water-level trends including proximity to nearby production wells, amount and timing of precipitation events, evapotranspiration and type of prevalent ground cover, proximity of aquifer to the surface, and hydraulic characteristics of overlying geologic materials.

Michigan↗

USGS2006

Ground-water levels in Huron County, Michigan, 2004-05

Michigan↗

USGS1999

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada↗

USGS1993

Hydrology, vegetation, and soils of four north Florida River flood plains with an evaluation of state and federal wetland determinations

A study of hydrologic conditions, vegetation, and soils was made in wetland forests of four north Florida streams from 1987 to 1990. The study was conducted by the U.S. Geological Survey in cooperation with the Florida Department of Environmental Regulation to support State and Federal efforts to improve wetland delineation methodology in flood plains. Plant communities and soils were described and related to topographic position and long-term hydrologic conditions at 10 study plots located on 4 streams. Detailed appendixes give average duration, frequency, and depth of flooding; canopy, subcanopy, and ground-cover vegetation; and taxonomic classification, series, and profile descriptions of soils for each plot. Topographic relief, range in stage, and depth of flooding were greatest on the alluvial flood plain of the Ochlockonee River, the largest of the four streams. Soils were silty in the lower elevations of the flood plain, and tree communities were distinctly different in each topographic zone. The Aucilla River flood plain was dominated by levees and terraces with very few depressions or low backwater areas. Oaks dominated the canopy of both lower and upper terraces of the Aucilla flood plain. Telogia Creek is a blackwater stream that is a major tributary of the Ochlockonee River. Its low, wet flood plain was dominated by Wyssa ogeche (Ogeechee tupelo) trees, had soils with mucky horizons, and was inundated by frequent floods of very short duration. The St. Marks River, a spring-fed stream with high base flow, had the least topographic relief and lowest range in stage of the four streams. St. Marks soils had a higher clay content than the other streams, and limestone bedrock was relatively close to the surface. Wetland determinations of the study plots based on State and Federal regulatory criteria were evaluated. Most State and Federal wetland determinations are based primarily on vegetation and soil characteristics because hydrologic records are usually not available. In this study, plots were located near long-term gaging stations, thus wetland determinations based on plant and soil characteristics could be evaluated at sites where long-term hydrologic conditions were known. Inconsistencies among hydrology, vegetation, and soil determinations were greatest on levee communities of the Ochlockonee and Aucilla River flood plains. Duration of average annual longest flood was almost 2 weeks for both plots. The wetland species list currently used (1991) by the State lacks many ground-cover species common to forested flood plains of north Florida rivers. There were 102 ground-cover species considered upland plants by the State that were present on the nine annually flooded plots of this study. Among them were 34 species that grew in areas continuously flooded for an average of 5 weeks or more each year. Common flood-plain species considered upland plants by the State were: Hypoxis leptocarpa (yellow star-grass), and two woody vines, Brunnichia ovata (ladies' eardrops) and Campsis radican s (trumpet-creeper), which were common in areas flooded continuously for 6 to 9 weeks a year; Sebastiania fruticosa (Sebastian-bush), Chasmanthium laxum (spikegrass), and Panicum dichotomum (panic grass), which typically grew in areas flooded an average of 2 to 3 weeks or more per year; Vitis rotundifolia (muscadine) and Toxicodendron radicans (poison-ivy), usually occurring in areas flooded an average of 1 to 2 weeks a year; and Quercus virginiana (live oak) present most often in areas flooded approximately 1 week a year. Federal wetland regulations (1989) limited wetland jurisdiction to only those areas that are inundated or saturated during the growing season. However, year-round hydrologic records were chosen in this report to describe the influence of hydrology on vegetation, because saturation, inundation, or flowing water can have a variety of both beneficial and adverse effects on flood-plain vegetation at any time of the year. These effects can occur because: (1) Soil temperatures in north Florida are probably high enough in winter for anaerobic conditions to develop in saturated soils. (2) Many plants in the flood plains of north Florida are active in the nongrowing season and might be adapted to anaerobic conditions in winter. (3) Other effects of standing water, such as decreased light penetration, prevention of seed germination, and protection of seeds from herbivores; and effects of flowing water, such as scouring and deposition of sediments, seed dispersal, and mechanical injury, can occur any time of year.

Florida↗

USGS2013

Assessment of water-quality data from Long Lake National Wildlife Refuge, North Dakota--2008 through 2012

ong Lake National Wildlife Refuge, located in south-central North Dakota, is an important habitat for numerous migratory birds and waterfowl, including several threatened or endangered species. The refuge is distinguished by Long Lake, which is approximately 65 square kilometers and consists of four primary water management units. Water levels in the Long Lake units are maintained by low-level dikes and water-control structures, which after construction during the 1930s increased the water-storage capacity of Long Lake and reduced the frequency and volume of flushing flows downstream. The altered water regime, along with the negative precipitation:evaporation ratio of the region, may be contributing to the accumulation of water-borne chemical constituents such as salts, trace metals, and other constituents, which at certain threshold concentrations may impair aquatic plant, invertebrate, and bird communities of the refuge. The refuge’s comprehensive conservation planning process identified the need for water-quality monitoring to assess current (2013) conditions, establish comparative baselines, evaluate changes over time (trends), and support adaptive management of the wetland units. In 2008, the U.S. Geological Survey, U.S. Fish and Wildlife Service, and North Dakota Department of Health began a water-quality monitoring program at Long Lake National Wildlife Refuge to address these needs. Biweekly water-quality samples were collected for ions, trace metals, and nutrients; and in situ sensors and data loggers were installed for the continuous measurement of specific conductance and water depth. Long Lake was characterized primarily by sodium, bicarbonate, and sulfate ions. Overall results for total alkalinity and hardness were 580 and 329 milligrams per liter, respectively; thus, Long Lake is considered alkaline and classified as very hard. The mean pH and sodium adsorption ratio for Long Lake were 8.8 and 10, respectively. Total dissolved solids concentrations averaged approximately 1,750 milligrams per liter, and ranged from 117 to 39,700 milligrams per liter. Twelve of the 14 trace metals detected in the water samples had established North Dakota water-quality standards for aquatic life, and only aluminum and copper consistently exceeded these criteria. Aluminum is considered harmful to aquatic biota in acidic (pH less than 5.5) systems and most of the copper standard exceedances were collected from highly concentrated waters because of evaporation and seasonally low water levels. Concentrations for various forms of nitrogen and phosphorus generally were similar to reported regional values. Specific conductance of Long Lake varied seasonally and annually both within and among management units, with values ranging from less than 500 to nearly 40,000 microsiemens per centimeter at 25 degrees Celsius. Long Lake was characterized by consistent seasonal patterns of increasing specific conductance from spring (March and April) to fall (September and October), with levels stabilizing through the end of the sampling season (November). These seasonal patterns in specific conductance were associated with decreasing water levels throughout the summer due primarily to evaporation and continuous water releases through the Unit 1 outlet structure, which resulted in the concentration of salts. Specific conductance of each unit, along with water levels, also varied among years. Overall, specific conductance levels were greatest during the drier year of 2008 when water levels were low. Specific conductance levels were lowest during the spring of 2009 following above-average volumes of fresh water from snowmelt runoff. Comparisons of specific conductance among sample sites that were spatially distributed within each management unit suggested that spatial variability within units was low except for areas associated with local inflows. Data collected during this study revealed consistent seasonal patterns and low within-unit spatial variability of specific conductance. Based on these data results, future sample collection efforts may be reduced, as well as the number of sample locations, to limit sampling costs. Water-quality samples collected monthly or seasonally during the growing season (spring, summer, and fall) from a single representative location within each water-management unit should provide sufficient data to assess seasonal changes in water-quality over time and provide information for Long Lake management decisions.

North Dakota↗

USGS2008

Multiple Landslide-Hazard Scenarios Modeled for the Oakland-Berkeley Area, Northern California

With the exception of Los Angeles, perhaps no urban area in the United States is more at risk from landsliding, triggered by either precipitation or earthquake, than the San Francisco Bay region of northern California. By January each year, seasonal winter storms usually bring moisture levels of San Francisco Bay region hillsides to the point of saturation, after which additional heavy rainfall may induce landslides of various types and levels of severity. In addition, movement at any time along one of several active faults in the area may generate an earthquake large enough to trigger landslides. The danger to life and property rises each year as local populations continue to expand and more hillsides are graded for development of residential housing and its supporting infrastructure. The chapters in the text consist of: *Introduction by Russell W. Graymer *Chapter 1 Rainfall Thresholds for Landslide Activity, San Francisco Bay Region, Northern California by Raymond C. Wilson *Chapter 2 Susceptibility to Deep-Seated Landsliding Modeled for the Oakland-Berkeley Area, Northern California by Richard J. Pike and Steven Sobieszczyk *Chapter 3 Susceptibility to Shallow Landsliding Modeled for the Oakland-Berkeley Area, Northern California by Kevin M. Schmidt and Steven Sobieszczyk *Chapter 4 Landslide Hazard Modeled for the Cities of Oakland, Piedmont, and Berkeley, Northern California, from a M=7.1 Scenario Earthquake on the Hayward Fault Zone by Scott B. Miles and David K. Keefer *Chapter 5 Synthesis of Landslide-Hazard Scenarios Modeled for the Oakland-Berkeley Area, Northern California by Richard J. Pike The plates consist of: *Plate 1 Susceptibility to Deep-Seated Landsliding Modeled for the Oakland-Berkeley Area, Northern California by Richard J. Pike, Russell W. Graymer, Sebastian Roberts, Naomi B. Kalman, and Steven Sobieszczyk *Plate 2 Susceptibility to Shallow Landsliding Modeled for the Oakland-Berkeley Area, Northern California by Kevin M. Schmidt and Steven Sobieszczyk *Plate 3 Susceptibility to Shallow Landsliding Modeled for the Cities of Oakland and Piedmont Northern California by Kevin M. Schmidt and Steven Sobieszczyk *Plate 4 Seismic Landslide Hazard Modeled for the Cities of Oakland, Piedmont, and Berkeley, Northern California by Scott B. Miles and David K. Keefer III The relative hazard for each of several landslide scenarios is presented as a geospatial database. This publication includes ARC/INFO (Environmental Systems Research Institute, http://www.esri.com) version 8.1.2 grids and associated tables and four text files of FGDC-compliant metadata for each grid.

Scientific Investigations Report↗

USGS2001

Water quality and nutrient loading in the Klamath River between Keno, Oregon and Seiad Valley, CA from 1996-1998

A water quality study was performed in the mainstem Klamath River from Keno, Oregon to Seiad Valley, California during 1996 through 1998. Four sites within the study area were continuously monitored using multiparameter recorders. Water quality sampling was also performed at these four locations in 1996 and 1997. Additional water quality sampling sites were added in 1998 for a total of 8 locations between Keno and Seiad. Temperature ranged from near zero °C to >25 °C with cooler temperatures in early spring and fall, and maximum temperatures occurring in july and August of each year. Dissolved oxygen concentration ranged from near zero mg/L to >13 mg/L with highest DO occurring in early spring and fall and lowest DO occurring in mid-summer. Air temperature was generally highly correlated with water temperature with r values ranging from 0.8 to 0.9 during the study period from 1996-1998. Water temperature in the study area exceeded chronic (>16°C) and acute (>22°C) criteria for salmonids during the summer months. Although chronic DO «7 mg/L) criteria were exceeded throughout most of the study area during the summer, in the free-flowing river below Iron Gate Dam the acute DO «5.5 mg/L) criteria were not exceeded. Nonpoint source pollution in the form of agricultural return flows, industrial, or sewage effluent entering the stream may have resulted in higher ammonia and total organic nitrogen concentrations at the upstream locations in the Klamath River study area (Keno and J.C. Boyle Powerplant). Nitrification of ammonia and organic nitrogen seemed to result in higher concentrations of nitrate in the downstream Klamath River (Iron Gate Dam). Total phosphorus concentration stayed relatively stable through the reservoirs in the study area, but decreased in the downstream direction between Iron Gate Dam and Seiad. Ortho-phosphorus concentrations increased longitudinally through the reservoirs, then decreased in the downstream direction between Iron Gate Dam and Seiad. An increase in ortho-phosphorus concentration can indicate internal cycling occurring in the reservoirs as well as photosynthesis. On an annual basis total phosphorus loading increased longitudinally from up- to downstream between Keno and Seiad. The increase was statistically significant (p =.03) indicating that the reservoirs in series in the Klamath River study area do not function as a nutrient sink. However, during the summer there was no statistically significant difference in total P loading when Keno, Iron Gate and Seia~ locations were compared, therefore, the reservoirs may act as a nutrient sink seasonally. The Klamath River study locations were generally nitrogen limited, although at Keno, a regUlar change from N limitation to P limitation occurred during the fall of all three years of the study. When the Klamath River annual nutrient loading values are compared to other rivers in the vicinity, the Carson, Truckee, and Long Tom Rivers also appear to be nutrient enriched. The Carson and South Yamhill Rivers seem to be N limited systems and the Wood, Long Tom, Snake and Truckee Rivers seem to be P limited systems. Implementing management strategies for reservoir operations to improve water quality and reduce nutrient concentration or loading in the Klamath River study area to benefit anadromous fisheries may be difficult and expensive. However, improving the thermal regime in spring to benefit YOY salmonids may be possible as is short-term relief in late summer for oversummering species. Decreases in nutrient concentration or loading accomplished through best management practices in the water shed may allow general protection of water resources in the Klamath Basin for future needs.

California, Oregon↗

USGS2015

Hydrology of the middle San Pedro area, southeastern Arizona

In the middle San Pedro Watershed in southeastern Arizona, groundwater is the primary source of water supply for municipal, domestic, industrial, and agricultural use. The watershed comprises two smaller subareas, the Benson subarea and the Narrows-Redington subarea. Early 21st century projections for heavy population growth in the watershed have not yet become a reality, but increased groundwater withdrawals could have undesired consequences - such as decreased base flow to the San Pedro River, and groundwater-level declines - that would lead to the need to deepen existing wells. This report describes the hydrology, hydrochemistry, water quality, and development of a groundwater budget for the middle San Pedro Watershed, focusing primarily on the elements of groundwater movement that could be most useful for the development of a groundwater model Precipitation data from Tombstone, Arizona, and base flow at the stream-gaging station on the San Pedro River at Charleston both show relatively dry periods during the 1960s through the mid-1980s and in the mid-1990s to 2009, and wetter periods from the mid-1980s through the mid-1990s. Water levels in four out of five wells near the mountain fronts show cyclical patterns of recharge, with rates of recharge greatest in the early 1980s through the mid-1990s. Three wells near the San Pedro River recorded their lowest levels during the 1950s to the mid-1960s. The water-level record from one well, completed in the confined part of the coarse-grained lower basin fill, showed a decline of approximately 21 meters. Annual flow of the San Pedro River, measured at the Charleston and Redington gages, has decreased since the 1940s. The median annual streamflow and base flow at the gaging station on the river near Tombstone has decreased by 50 percent between the periods 1968–1986 and 1997–2009. Estimates of streamflow infiltration along the San Pedro River during 1914–2009 have decreased 44 percent, with the largest decreases in the months June–October in the Benson subarea. In the Narrows-Redington subarea, streamflow infiltration has decreased about 65 percent during 1914–2009. The average annual outflow (27.6 hm 3 /year [cubic hectometers per year]) from the Benson subarea aquifer for water years 2001 through 2009 exceeded the inflows (20.0 hm 3 / yr) by 7.60 hm 3 /yr. In the Narrows-Redington subarea for the same period, the average annual outflow (15.7 hm 3 /yr) from the aquifer system exceeded the inflows (13.8 hm 3 /yr) by nearly 2 hm 3 /yr. The largest withdrawals of groundwater in both subareas are for irrigation; these withdrawals peaked in 1973 and have been steadily decreasing since then. Recharge from streamflow infiltration exceeded recharge from the mountain-front and from ephemeral channels in the Benson subarea. In the Narrows-Redington subarea, however, recharge from mountain-front and ephemeral channel recharge exceeded recharge from streamflow infiltration. Evapotranspiration by phreatophytes accounts for the largest outflow of groundwater for both subareas—78 percent of the outflow in the Narrows-Redington subarea and 62 percent of the outflow in the Benson subarea. Precipitation, surface-water, and groundwater chemistry and isotope data indicated the relative age and residence time of groundwater, the amount of interaction between geologic sources and groundwater, and how recharge elevation and season were related to the presence of modern water. The bedrock aquifer receives modern recharge (

Arizona↗

USGS2012

Occurrence of pesticides in water and sediment collected from amphibian habitats located throughout the United States, 2009-10

Water and bed-sediment samples were collected by the U.S. Geological Survey (USGS) in 2009 and 2010 from 11 sites within California and 18 sites total in Colorado, Georgia, Idaho, Louisiana, Maine, and Oregon, and were analyzed for a suite of pesticides by the USGS. Water samples and bed-sediment samples were collected from perennial or seasonal ponds located in amphibian habitats in conjunction with research conducted by the USGS Amphibian Research and Monitoring Initiative and the USGS Toxic Substances Hydrology Program. Sites selected for this study in three of the states (California, Colorado, and Orgeon) have no direct pesticide application and are considered undeveloped and remote. Sites selected in Georgia, Idaho, Louisiana, and Maine were in close proximity to either agricultural or suburban areas. Water and sediment samples were collected once in 2009 during amphibian breeding seasons. In 2010, water samples were collected twice. The first sampling event coincided with the beginning of the frog breeding season for the species of interest, and the second event occurred 10-12 weeks later when pesticides were being applied to the surrounding areas. Additionally, water was collected during each sampling event to measure dissolved organic carbon, nutrients, and the fungus, Batrachochytrium dendrobatidis , which has been linked to amphibian declines worldwide. Bed-sediment samples were collected once during the beginning of the frog breeding season, when the amphibians are thought to be most at risk to pesticides. Results of this study are reported for the following two geographic scales: (1) for a national scale, by using data from the 29 sites that were sampled from seven states, and (2) for California, by using data from the 11 sampled sites in that state. Water samples were analyzed for 96 pesticides by using gas chromatography/mass spectrometry. A total of 24 pesticides were detected in one or more of the 54 water samples, including 7 fungicides, 10 herbicides, 4 insecticides, 1 synergist, and 2 pesticide degradates. On a national scale, aminomethylphosphonic acid (AMPA), the primary degradate of the herbicide glyphosate, which is the active ingredient in Roundup®, was the most frequently detected pesticide in water (16 of 54 samples) followed by glyphosate (8 of 54 samples). The maximum number of pesticides observed at a single site was nine compounds in a water sample from a site in Louisiana. The maximum concentration of a pesticide or degradate observed in water was 2,880 nanograms per liter of clomazone (a herbicide) at a site in Louisiana. In California, a total of eight pesticides were detected among all of the low and high elevation sites; AMPA was the most frequently detected pesticide, but glyphosate was detected at the highest concentrations (1.1 micrograms per liter). Bed-sediment samples were analyzed for 94 pesticides by using accelerated solvent extraction, gel permeation chromatography for sulfur removal, and carbon/alumina stacked solid-phase extraction cartridges to remove interfering sediment matrices. In bed sediment, 22 pesticides were detected in one or more of the samples, including 9 fungicides, 3 pyrethroid insecticides, p,p' -dichlorodiphenyltrichloroethane ( p,p' -DDT) and its major degradates, as well as several herbicides. Pyraclostrobin, a strobilurin fungicide, and bifenthrin, a pyrethroid insecticide, were detected most frequently. Maximum pesticide concentrations ranged from less than their respective method detection limits to 1,380 micrograms per kilogram (tebuconazole in California). The number of pesticides detected in samples from each site ranged from zero to six compounds. The sites with the greatest number of pesticides were in Maine and Oregon with six pesticides detected in one sample from each state, followed by Georgia with four pesticides in one sample. For California, a total of 10 pesticides were detected among all sites, and 4 pesticides were detected at both low and high elevation sites; tebuconazole and pyraclostrobin were the two most frequently detected pesticides in California. For the other six selected states, the most frequently detected pesticides in bed sediment were pyraclostrobin (detected in 17 of 42 samples), bifenthrin (detected in 14 of 42 samples), and tebuconazole (detected in 10 of 42 samples). The fungus, Batrachochytrium dendrobatidis (Bd), was detected in water samples in sites from four of the seven states during 2009 and 2010, and the number of zoospore equivalents per liter of water in samples where Bd was detected ranged from 1.6 to 343. Bd was not detected in water samples from sites in Georgia, Louisiana, and Oregon.

Data Series↗

USGS2009

Comparative Hydrology, Water Quality, and Ecology of Selected Natural and Augmented Freshwater Wetlands in West-Central Florida

Comparing altered wetlands to natural wetlands in the same region improves the ability to interpret the gradual and cumulative effects of human development on freshwater wetlands. Hydrologic differences require explicit attention because they affect nearly all wetland functions and are an overriding influence on other comparisons involving wetland water quality and ecology. This study adopts several new approaches to quantify wetland hydrologic characteristics and then describes and compares the hydrology, water quality, and ecology of 10 isolated freshwater marsh and cypress wetlands in the mantled karst landscape of central Florida. Four of the wetlands are natural, and the other six have water levels indirectly lowered by ground-water withdrawals on municipally owned well fields. For several decades, the water levels in four of these altered wetlands have been raised by adding ground water in a mitigation process called augmentation. The two wetlands left unaugmented were impaired because their water levels were lowered. Multifaceted comparisons between the altered and natural wetlands are used to examine differences between marshes and cypress wetlands and to describe the effects of augmentation practices on the wetland ecosystems. In the karstic geologic setting, both natural and altered wetlands predominantly lost water to the surficial aquifer. Water leaking out of the wetlands created water-table mounds below the wetlands. The smallest mounds radiated only slightly beyond the vegetated area of the wetlands. The largest and steepest mounds occurred below two of the augmented wetlands. There, rapid leakage rates regenerated a largely absent surficial aquifer and mounds encompassed areas 7-8 times as large as the wetlands. Wetland leakage rates, estimated using a daily water-budget analysis applied over multiple years and normalized as inches per day, varied thirtyfold from the slowest leaking natural wetland to the fastest leaking augmented wetland. Leakage rates increased as the size of the flooded area decreased and as the downward head difference between the wetland and the underlying Upper Floridan aquifer increased. Allowing one of the augmented wetlands to dry up for about 2.5 months in the spring of 2004, and then refilling it, generated a net savings of augmentation water despite the amount of water required to recreate the water-table mound beneath the wetland. Runoff from the surrounding uplands was an important component of the water budget in all of the unaugmented wetlands and two of the augmented wetlands. At a minimum, runoff contributed from half (45 percent) to twice (182 percent) as much water as direct rainfall at individual wetlands. Wetland flooded areas, derived using wetland water levels and bathymetric data and presented as a percentage of total wetland area, were used to compare and contrast hydrologic conditions among the 10 wetlands. The percentages of the natural wetland areas that flooded during the study were comparable, despite differences in the sizes of the wetlands. The percent flooded area in each wetland was calculated daily over the study period and monthly for up to 16 years using historical water-level data. Historical flooding in the natural wetlands spanned a greater range in area and had more pronounced seasonality than historical flooding at either the impaired or augmented wetlands. Flooding in the impaired and natural wetlands was similar, however, during 2 years of the study with substantially reduced well-field pumping and above average rainfall. Comparisons indicated several hydrologic differences between the marsh and cypress wetlands in this study. The natural and impaired marshes leaked at about half the rate of the natural and impaired cypress wetlands, and the marshes collectively were underlain by geologic material with lower vertical leakance values than the cypress wetlands. The natural marshes had higher evaporation rates compared to cypress

Professional Paper↗

USGS2002

Geohydrology of a deep-aquifer system monitoring-well site at Marina, Monterey County, California

In 2000, a deep-aquifer system monitoring-well site (DMW1) was completed at Marina, California to provide basic geologic and hydrologic information about the deep-aquifer system in the coastal region of the Salinas Valley. The monitoring-well site contains four wells in a single borehole; one completed from 930 to 950 feet below land surface (bls) in the Paso Robles Formation (DMW1-4); one 1,040 to 1,060 feet below land surface in the upper Purisima Formation (DMW1-3); one from 1,410 to 1,430 feet below land surface in the middle Purisima Formation (DMW1-2); and one from 1,820 to 1,860 feet below land surface in the lower Purisima Formation (DMW1-1). The monitoring site is installed between the coast and several deep-aquifer system supply wells in the Marina Coast Water District, and the completion depths are within the zones screened in those supply wells. Sediments below a depth of 955 feet at DMW1 are Pliocene age, whereas the sediments encountered at the water-supply wells are Pleistocene age at an equivalent depth. Water levels are below sea level in DMW1 and the Marina Water District deep-aquifer system supply wells, which indicate that the potential for seawater intrusion exists in the deep-aquifer system. If the aquifers at DMW1 are hydraulically connected with the submarine outcrops in Monterey Bay, then the water levels at the DMW1 site are 8 to 27 feet below the level necessary to prevent seawater intrusion. Numerous thick fine-grained interbeds and confining units in the aquifer systems retard the vertical movement of fresh and saline ground water between aquifers and restrict the movement of seawater to narrow water-bearing zones in the upper-aquifer system.Hydraulic testing of the DMW1 and the Marina Water District supply wells indicates that the tested zones within the deep-aquifer system are transmissive water-bearing units with hydraulic conductivities ranging from 2 to 14.5 feet per day. The hydraulic properties of the supply wells and monitoring wells are similar, even though the wells are completed in different geologic formations.Geophysical logs collected at the DMW1 site indicate saline water in most water-bearing zones shallower than 720 feet below land surface and from about 1,025 to 1,130 feet below land surface, and indicate fresher water from about 910 to 950 feet below land surface (DMW1-4), 1,130 to 1,550 feet below land surface, and below 1,650 feet below land surface. Temporal differences between electromagnetic induction logs indicate possible seasonal seawater intrusion in five water-bearing zones from 350 to 675 feet below land surface in the upper-aquifer system.The water-chemistry analyses from the deep-aquifer system monitoring and supply wells indicate that these deep aquifers in the Marina area contain potable water with the exception of the saline water in well DMW1-3. The saline water from well DMW1-3 has a chloride concentration of 10,800 milligrams per liter and dissolved solids concentration of 23,800 milligrams per liter. The source of this water was determined not to be recent seawater based on geochemical indicators and the age of the ground water. The high salinity of this ground water may be related to the dissolution of salts from the saline marine clays that surround the water-bearing zone screened by DMW1-3. The major ion water chemistry of the monitoring wells and the nearby MCWD water-supply wells are similar, which may indicate they are in hydraulic connection, even though the stratigraphic layers differ below 955 feet below land surface.No tritium was detected in samples from the deep monitoring wells. The lack of tritium suggest that there is no recent recharge water (less than 50 years old) in the deep-aquifer system at the DMW1 site. The carbon-14 analyses of these samples indicate ground water from the monitoring site was recharged thousands of years ago.

California↗