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Recovery and validation of historical sediment quality data from coastal and estuarine areas: An integrated approach

A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1955 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray literature). Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations of Cu, Hg, and Zn of 40 to 60% over a 17-year period.A comprehensive database of sediment chemistry and environmental parameters has been compiled for Boston Harbor and Massachusetts Bay. This work illustrates methodologies for rescuing and validating sediment data from heterogeneous historical sources. It greatly expands spatial and temporal data coverage of estuarine and coastal sediments. The database contains about 3500 samples containing inorganic chemical, organic, texture and other environmental data dating from 1995 to 1994. Cooperation with local and federal agencies as well as universities was essential in locating and screening documents for the database. More than 80% of references utilized came from sources with limited distribution (gray Task sharing was facilitated by a comprehensive and clearly defined data dictionary for sediments. It also served as a data entry template and flat file format for data processing and as a basis for interpretation and graphical illustration. Standard QA/QC protocols are usually inapplicable to historical sediment data. In this work outliers and data quality problems were identified by batch screening techniques that also provide visualizations of data relationships and geochemical affinities. No data were excluded, but qualifying comments warn users of problem data. For Boston Harbor, the proportion of irreparable or seriously questioned data was remarkably small (<5%), although concentration values for metals and organic contaminants spanned 3 orders of magnitude for many elements or compounds. Data from the historical database provide alternatives to dated cores for measuring changes in surficial sediment contamination level with time. The data indicate that spatial inhomogeneity in harbor environments can be large with respect to sediment-hosted contaminants. Boston Inner Harbor surficial sediments showed decreases in concentrations Cu, Hg, and Zn of 40 to 60% over a 17-year period.

Massachusetts

An "optimal" filter for maps showing nominal data

An "optimal" filtering technique for use with nominal data, such as land use and land cover categories, has been developed. This method is based on the conditional probability joins of neighboring data elements. In addition to its use in performing filtering, the method can be used to calculate the likelihood of each data element being properly classified. The technique was tested on a land use data set for an area in Walnut Valley, Calif. The computer program performing the filtering process proved to be computationally efficient and produced satisfactory results. Useful statistics of the error estimation process were also generated. Future applications of the method to spectrally classified Landsat data are being explored.

Journal of Research of the U.S. Geological Survey

Predictions for an invaded world: A strategy to predict the distribution of native and non-indigenous species at multiple scales

Habitat models can be used to predict the distributions of marine and estuarine non-indigenous species (NIS) over several spatial scales. At an estuary scale, our goal is to predict the estuaries most likely to be invaded, but at a habitat scale, the goal is to predict the specific locations within an estuary that are most vulnerable to invasion. As an initial step in evaluating several habitat models, model performance for a suite of benthic species with reasonably well-known distributions on the Pacific coast of the US needs to be compared. We discuss the utility of non-parametric multiplicative regression (NPMR) for predicting habitat- and estuary-scale distributions of native and NIS. NPMR incorporates interactions among variables, allows qualitative and categorical variables, and utilizes data on absence as well as presence. Preliminary results indicate that NPMR generally performs well at both spatial scales and that distributions of NIS are predicted as well as those of native species. For most species, latitude was the single best predictor, although similar model performance could be obtained at both spatial scales with combinations of other habitat variables. Errors of commission were more frequent at a habitat scale, with omission and commission errors approximately equal at an estuary scale. ?? 2008 International Council for the Exploration of the Sea. Published by Oxford Journals. All rights reserved.

Conference Paper

Analysis of the rate of wildcat drilling and deposit discovery

The rate at which petroleum deposits were discovered during a 16-yr period (1957–72) was examined in relation to changes in a suite of economic and physical variables. The study area encompasses 11,000 mi 2 and is located on the eastern flank of the Powder River Basin. A two-stage multiple-regression model was used as a basis for this analysis. The variables employed in this model were: (1) the yearly wildcat drilling rate, (2) a measure of the extent of the physical exhaustion of the resource base of the region, (3) a proxy for the discovery expectation of the exploration operators active in the region, (4) an exploration price/cost ratio, and (5) the expected depths of the exploration targets sought. The rate at which wildcat wells were drilled was strongly correlated with the discovery expectation of the exploration operators. Small additional variations in the wildcat drilling rate were explained by the price/cost ratio and target-depth variables. The number of deposits discovered each year was highly dependent on the wildcat drilling rate, but the aggregate quantity of petroleum discovered each year was independent of the wildcat drilling rate. The independence between these last two variables is a consequence of the cyclical behavior of the exploration play mechanism. Although the discovery success ratio declined sharply during the initial phases of the two exploration plays which developed in the study area, a learning effect occurred whereby the discovery success ratio improved steadily with the passage of time during both exploration plays.

Journal of the International Association for Mathe

Contributions to a shallow aquifer study by reprocessed seismic sections from petroleum exploration surveys, eastern Abu Dhabi, United Arab Emirates

The US Geological Survey, in cooperation with the National Drilling Company of Abu Dhabi, is conducting a 4-year study of the fresh and slightly saline groundwater resources of the eastern Abu Dhabi Emirate. Most of this water occurs in a shallow aquifer, generally less than 150 m deep, in the Al Ain area. A critical part of the Al Ain area coincides with a former petroleum concession area where about 2780 km of vibroseis data were collected along 94 seismic lines during 1981–1983. Field methods, acquistion parameters, and section processing were originally designed to enhance reflections expected at depths ranging from 5000 to 6000 m, and subsurface features directly associated with the shallow aquifer system were deleted from the original seismic sections. The original field tapes from the vibroseis survey were reprocessed in an attempt to extract shallow subsurface information (depths less than 550 m) for investigating the shallow aquifer. A unique sequence of reproccessing parameters was established after reviewing the results from many experimental tests. Many enhancements to the resolution of shallow seismic reflections resulted from: (1) application of a 20-Hz, low-cut filter; (2) recomputation of static corrections to a datum nearer the land surface; (3) intensive velocity analyses; and (4) near-trace muting analyses. The number, resolution, and lateral continuity of shallow reflections were greatly enhanced on the reprocessed sections, as was the delineation of shallow, major faults. Reflections on a synthetic seismogram, created from a borehole drilled to a depth of 786 m on seismic line IQS-11, matched precisely with shallow reflections on the reprocessed section. The 33 reprocessed sections were instrumental in preparing a map showing the major structural features that affect the shallow aquifer system. Analysis of the map provides a better understanding of the effect of these shallow features on the regional occurrence, movement, and quality of groundwater in the concession area. Results from this study demonstrate that original seismic field tapes collected for deep petroleum exploration can be reprocessed to explore for groundwater.

Journal of Applied Geophysics

Candidate cave entrances on Mars

This paper presents newly discovered candidate cave entrances into Martian near-surface lava tubes, volcano-tectonic fracture systems, and pit craters and describes their characteristics and exploration possibilities. These candidates are all collapse features that occur either intermittently along laterally continuous trench-like depressions or in the floors of sheer-walled atypical pit craters. As viewed from orbit, locations of most candidates are visibly consistent with known terrestrial features such as tube-fed lava flows, volcano-tectonic fractures, and pit craters, each of which forms by mechanisms that can produce caves. Although we cannot determine subsurface extents of the Martian features discussed here, some may continue unimpeded for many kilometers if terrestrial examples are indeed analogous. The features presented here were identified in images acquired by the Mars Odyssey's Thermal Emission Imaging System visible-wavelength camera, and by the Mars Reconnaissance Orbiter's Context Camera. Select candidates have since been targeted by the High-Resolution Imaging Science Experiment. Martian caves are promising potential sites for future human habitation and astrobiology investigations; understanding their characteristics is critical for long-term mission planning and for developing the necessary exploration technologies.

Journal of Cave and Karst Studies

Borehole geophysical investigations in the south Texas uranium district

Contrasts of electrical properties between uranium deposits and their host rocks in South Texas are subtle. In places where deposits are small or deep, conventional geophysical well-logging techniques and hole-to-hole measurements may be the only practical method to detect changes in rock properties associated with the occurrence of uranium ore deposits. Two separate ore-producing areas in South Texas were chosen for studying borehole geophysical techniques applied to uranium-exploration problems. Extensive measurements of physical properties were made on cores and taken from holes where electrical-resistivity, induced-polarization and gamam-ray logs were run. These analyses show that: (1) induced-polarization anomalies are caused by a change in pyrite content and clay-sized material content and (2) resistivity anomalies are associated with a change in clay-sized material content and cementation. In addition to conventional borehole techniques, hole-to-hole induced-polarization and resistivity tests were made in South Texas. These measurements were made by placing a current source down one hole and a receiver cable down an adjacent hole whose separation ranged from 30 to 300 m and hole depths varied from 80 to 270 m. These tests show that hole-to-hole measurements can be used to detect changes in physical properties, associated with uranium ore, that occur between boreholes. Hole-to-hole measurements provide a link between surface measurements and well logs and can minimize the amount of drilling needed to locate an ore deposit. Accordingly, borehole geophysics will become an increasingly important evaluation tool as mineral exploration goes deeper.

Texas

Pancam and Microscopic Imager observations of dust on the Spirit Rover: Cleaning events, spectral properties, and aggregates

This work describes dust deposits on the Spirit Rover over 2000 sols through examination of Pancam and Microscopic Imager observations of specific locations on the rover body, including portions of the solar array, Pancam and Mini-TES calibration targets, and the magnets. This data set reveals the three "cleaning events" experienced by Spirit to date, the spectral properties of dust, and the tendency of dust particles to form aggregates 100 um and larger.

Mars, The International Journal of Mars Science an

Aqueous mineralogy and stratigraphy at and around the proposed Mawrth Vallis MSL Landing Site: New insights into the aqueous history of the region

In this work, we have confirmed the mineralogical stratigraphy previously inferred by other authors, but also demonstrate the presence of additional minerals, including a possible acid-leaching product near the top of the sequence, an Mh-OH bearing phyllosilicate at the to of the sequence, and potentially a Ca-sulfate at the bottom of the phyllosilicate sequence. The latter has important implications regarding the relative timing of sulfate vs clay formation on Mars.

Mars, The International Journal of Mars Science an

On-line access to geoscience bibliographic citations

On-line geoscience bibliographic citations and access points to citations are exponentially increasing as commercial, non-profit, and government agencies worldwide publish materials electronically. On-line bibliographic tools capture cited works, and open access content allows for freely obtained citations and documents. For this newsletter, citations from the numerous journals and books listed in the "Recent Papers" section of the EXPLORE newsletters from 2008-2011 were used to provide freely-accessible web sites to determine the availability of bibliographic information.

EXPLORE: Newsletter for the Association of Applied

The web of life: Natural science information on the Internet

As society has come to equate economic prosperity with the health of our living resources, national science policy has called for the development of a comprehensive digital knowledge base to support informed decision making and wise resource management. The Internet and World Wide Web demonstrate the earliest stages of this evolving virtual library of the natural world, offering an increasing array of high-quality, innovative resources and services in the natural science arena. This article discusses the leading providers of natural science information on the Internet and highlights some of the exemplary resources they are delivering online. The discussion concludes with a brief discussion of the role of the librarian in developing the Web of natural science knowledge online and provides a short Webliography of starting points for further exploration of this subject area. PDF

Journal of Library Administration

Economics and coal resource appraisal: strippable coal in the Illinois Basin ( USA)

Coal-resource appraisals generally describe the location and general characteristics of coal beds. Estimates are made of the average overburden depth (depth of the coal bed below the surface), bed thickness, and perhaps certain chemical properties of the coal [1]. Although such resource compilations represent an important initial step, neither they nor current estimates provide sufficient information to determine the costs of alternative options for National energy policy. Because coal is expected to provide an increasing part of future overall U.S. energy supply, it is crucial for long term planning that coalresource appraisals convey sufficient information regarding the degree of economic resource scarcity (escalation of unit costs for mining remaining deposits as the best deposits in an area are mined out) expected as coal consumption increases. However, assumptions embodied in most large-scale models of coal supply [13; 20] imply that the coal reserves that exist can be commercially produced as needed. As demonstrated by the embargo of 1973-1974 and more recent difficulties in obtaining crude oil, even a slight temporary commodity shortfall will result in significant economic losses when the commodity supplies a large proportion of the total energy used by an economy. For the United States, crude oil resource estimates did not give warning of a decline in domestic petroleum product. In this paper we argue that coal-resource estimates, as they are now made, will not give warning of future supply difficulties. A method for incorporating an economic dimension into appraisals of strippable coal resources is presented and is applied to a major U.S. coal-producing region, the Illinois part of the Illinois basin. Illinois accounts for nearly 70% of the demonstrated strippable coal reserve base of the Illinois basin [12]. In particular, a long-run incremental cost function (that is unit costs vs. cumulative reserves extracted) is estimated for strippable coal in Illinois. The estimated cost function exhibits an initial range over which costs increase at a constant rate-followed by a range where costs increase very rapidly and the function becomes quite inelastic. This long-run incremental cost function is significant for two reasons. Comparison of the demonstrated reserve base for strippable coal (14.8 billion tons) with cumulative production (since 1920 of 1.1 billion tons) might suggest that future depletion will not be significant when, in fact, the cost function presented here indicates otherwise. Because the only states having more reserves of strippable coal than Illinois are Montana and Wyoming [18], these results have implications for national coal-resource appraisal. Secondly, most models used to study the effects of alternative public policies in coal markets are static in nature [15; 16] and cannot consider the effects of increasing costs. Furthermore, models which are multi-period in nature [11; 13] appear to have little empirical basis for their assumptions regarding the escalation of production costs resulting from depletion. The plan of the paper is as follows. First a description of the analytical approach for constructing the long-run incremental cost-reserve function is discussed. Following this, the descriptions of the Illinois basin and the basic physical data are presented. In the concluding section, the main results are presented and their implications are explored

Southern Economic Journal

Guidelines to classification and nomenclature of Arabian felsic plutonic rocks

Well-defined procedures for classifying the felsic plutonic rocks of the Arabian Shield on the basis of petrographic, chemical and lithostratigraphic criteria and mineral-resource potential have been adopted and developed in the Saudi Arabian Deputy Ministry for Mineral Resources over the past decade. A number of problems with conventional classification schemes have been identified and resolved; others, notably those arising from difficulties in identifying precise mineral compositions, continue to present difficulties. The petrographic nomenclature used is essentially that recommended by the International Union of Geological Sciences. Problems that have arisen include the definition of: (1) rocks with sodic, zoned or perthitic feldspar, (2) trondhjemites, and (3) alkali granites. Chemical classification has been largely based on relative molar amounts of alumina, lime and alkalis, and the use of conventional variation diagrams, but pilot studies utilizing univariate and multivariate statistical techniques have been made. The classification used in Saudi Arabia for stratigraphic purposes is a hierarchy of formation-rank units, suites and super-suites as defined in the Saudi Arabian stratigraphic code. For genetic and petrological studies, a grouping as ‘associations’ of similar and genetically related lithologies is commonly used. In order to indicate mineral-resource potential, the felsic plutons are classed as common, precursor, specialized or mineralized, in order of increasing exploration significance.

Journal of African Earth Sciences

Ouachitas need more exploratory drilling

The Ouachita Mountains in southeastern Oklahoma and western Arkansas are part of a mostly buried late Paleozoic fold and thrust belt that extends from Alabama to northern Mexico. The principal hydrocarbon reservoirs in the Ouachita tectonic province can be subdivided into those that produce natural gas from shallow-water units and those that produce oil and/or natural gas from deep-water units. They can also be divided into those that are fractured and those that produce from primary pore spaces or vugs. The first successful oil well in the Ouachita Mountains was drilled in 1913 or 1914. Since the discovery of the Redden field, over 800 oil and gas wells have been drilled in the Ouachita tectonic province in Oklahoma. Yet, most of the region remains little explored.

Arkansas, Oklahoma

Survey of remote sensing applications

Data from the first earth resources technology satellite (ERTS) as well as from NASA and other aircraft, contain much of the information indicative of the distribution of groundwater and the extent of its utilization. Thermal infrared imagery from aircraft is particularly valuable in studying groundwater discharge to the sea and other surface water bodies. Color infrared photography from aircraft and space is also used to locate areas of potential groundwater development. Anomalies in vegetation, soils, moisture, and their pattern of distribution may be indicative of underlying groundwater conditions. Remote sensing may be used directly or indirectly to identify stream reaches for test holes or production wells. Similarly, location of submarine springs increase effectiveness of groundwater exploration in the coastal zone.

Water Well Journal