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Petrology and geochronology of metamorphosed volcanic rocks and a middle Cretaceous volcanic neck in the east-central Sierra Nevada, California

Metamorphosed Mesozoic volcanic rocks from the east-central Sierra Nevada range in composition from basalt to rhyolite and have ages, based on whole rock Rb-Sr and U-Pb zircon dating, of about 237–224, 185, 163, 134, and 100 m.y. The major plutons of the batholith in this area are of Triassic (215–200 m.y.) and Cretaceous (94–80 m.y.) ages. Initial 87 Sr/ 86 Sr values for the metamorphosed volcanic rocks of the area are in the range from 0.7042 to 0.7058 and are generally different from the values for the surrounding batholithic rocks (0.7056–0.7066). A circular, zoned granitic pluton, with an outcrop area of 2.5 km 2 , similar in appearance to a ring dike complex, was apparently a conduit for some or possibly all of the middle-Cretaceous metamorphosed volcanic rocks exposed about 5 km to the south in the western part of the Ritter Range. Samples from the metamorphosed volcanic rocks and the pluton yield a Rb-Sr whole rock isochron age of 99.9 ± 2.2 m.y. with an initial 87 Sr/ 86 Sr of 0.7048 ± 0.0001. Major element variation diagrams of the pluton and volcanic rocks define coincident compositional trends. The pluton, intruded into Early Jurassic metamorphosed volcanic rocks (Rb-Sr whole rock isochron age of 185 ± 6 m.y., initial 87 / 86 Sr = 0.70474 ± 0.00009), is composed of a central body of granite that is intruded into and almost completely surrounded by a crescent-shaped outer rim of quartz monzodiorite. Contact relations between the granitic rocks, intrusive in some places and completely gradational at other places, indicate that the quartz monzodiorite was not completely crystallized prior to the intrusion of the granite. Modal minerology within the pluton is also consistent with this inferred crystallization history. The granitic rock textures are cataclastic, characterized by a groundmass of feldspar and quartz that surrounds larger grains of feldspar, hornblende, and biotite. Widely spaced aplite dikes from the granite intrude the quartz monzodiorite along the contact between the granitic rocks. The aplite dikes and interstitial alkali feldspar associated with myrmekite in the pluton, being undeformed, indicate crystallization of a small amount of silicate liquid after cataclasis. Aplite compositions suggest a minimum crystallization pressure of 0.5 kb (1–2 km); this depth is consistent with crystallization near the base of a large stratovolcano. The pluton is characterized by steep, linear features, defined by mineral clots and inclusions, that probably formed during the upward movement of the nearly crystallized magma in the volcanic conduit. The ages of volcanic events relative to the ages of the major intrusive epochs and the major element and isotopic compositions of the volcanic rocks relative to the major plutons indicate that the volcanic rocks are not simply or directly related to the major plutons in the Sierra Nevada.

Journal of Geophysical Research Solid Earth

Petrology and comparative thermal and mechanical histories of clasts in breccia 62236

Lunar breccia 62236 contains large lithic fragments of troctolite, norite, and anorthosite. The mafic phases, olivine, inverted pigeonite, and augite, fill interstitial areas between larger plagioclases and appear to be cumulate phases with extensive adcumulus growth. Pyroxene compositional homogeneity indicates that cation exchange during cooling was limited to an area of about 1 mm. Primary augite and pigeonite both contain 30 μm-wide lamellae of the other along ‘001’. Pigeonite inverted to orthopyroxene without retaining any crystallographic orientation and subsequently exsolved fine lamellae of augite on (100). Profiles across orthopyroxene-augite interfaces obtained in the analytical transmission electron microscope show an increase of ∼5% wollastonite in augite within 0.5 μm of the interface, suggesting that short-range cation exchange continued to temperatures below 500°C. The entire sample has undergone heterogeneous shock deformation. Shock melting of the troctolitic clast suggests pressures of 200–300 kb and well-developed basal twinning in augite from the norite clasts suggests pressures of 50–300 kbars. The present evidence indicates that 62236 contains parts of a slowly cooled microlayered adcumulate that has been heterogeneously shocked several times and combined into the present breccia.

Journal of Geophysical Research Solid Earth

Petrology and geochemistry of alkali gabbronorites from Lunar Breccia 67975

Clasts of an unusual type of lunar highlands igneous rock, alkali gabbronorite, have been found in Apollo 16 breccia 67975. The alkali gabbronorites form two distinct subgroups, magnesian and ferroan. Modes and bulk compositions are highly varied. The magnesian alkali gabbronorites are composed of bytownitic plagioclase (OrAn), hypersthene (WoEn), augite (WoEn), a silica mineral, and trace Ba‐rich K‐feldspar. The ferroan alkali gabbronorites are composed of ternary plagioclase (OrAn), pigeonite (WoEn), augite (WoEn), Ba‐rich K‐feldspar, and a silica mineral. Trace minerals in both subgroups are apatite, REE‐rich whitlockite, and zircon. The magnesian and ferroan alkali gabbronorites appear to have formed by progressive differentiation of the same, or closely related, parent magmas; the compositional data indicate that these magmas were REE‐rich. The ternary plagioclase is probably a high‐temperature metastable phase formed during crystallization. In composition and mineralogy, the 67975 alkali gabbronorites show many similarities to Apollo 12 and 14 alkali norites, alkali gabbronorites, and alkali anorthosites, and all these rocks together constitute a distinctive alkali suite. In addition, the alkali gabbronorites show some similarities to KREEP basalts, Mg‐norites, and some felsites. These data suggest genetic links between some or all of these types of pristine rocks. Two types of relationships are possible. The first is that alkali‐suite rocks crystallized in plutons of KREEP basalt magma, and KREEP basalts are their extrusive equivalents. The second is that the alkali‐suite rocks and some felsites all crystallized in plutons of Mg‐norite parent magmas, and KREEP basalt magmas formed by remelting of these plutons. Additional studies are needed to resolve which of these hypotheses is correct.

Journal of Geophysical Research B: Solid Earth

Petrology and structure of the Moa Chromite district, Oriente Province, Cuba

Chromite deposits In the Moa district, on the north coast of Oriente Province, Cuba, form one facies of the ultramafic complex in which they occur. Two planar structures, one a compositional layering due to variations in the relative proportions of olivine, pyroxene, plagioclase feldspar, and chromite, and the other a foliation caused by the orientation of pyroxene crystals in peridotite, are in general parallel, but diverge in a few places. Dips are fairly constant, being moderate to the northwest over most of the area, but sharp reversals occur immediately adjacent to irregularities in the chromite deposits. Two prominent joint sets are present: (1) Cross joints striking parallel to the strike of the foliation and dipping approximately at right angles to it; and (2) longitudinal joints striking parallel to the direction of dip of the foliation and nearly vertical. Gabbro dikes follow the first set, chrysotlle veins the second. Within the ore bodies dikes are commonly coarser‐grained, larger, and far more abundant than in peridotite; they enclose coarse, angular fragments of chromite. ©1947. American Geophysical Union. All Rights Reserved.

Eos, Transactions, American Geophysical Union

Petrological, magnetic and chemical properties of basalt dredged from an abyssal hill in the North-east pacific

OVER the years, samples of basalt from the oceanic crust have been taken mainly from seamounts, fracture zones and ridge and rise crests 1–6 , and rarely from the vast fields of abyssal hills which cover a large part of the deep-sea floor. The basalt sampled from the deeper regions of the oceanic crust (for example, on fault scarps) is a distinct variety of tholeiitic basalt, while alkali basalt is restricted to the volcanic edifices 4 . Oceanic tholeiitic basalt differs from alkali basalt and continental tholeiite chiefly in having a relatively low percentage of K 2 O (0.2 weight per cent) 4 . Some authors have speculated that this type of tholeiitic basalt is the major extrusion from the upper mantle and constitutes the predominant rock type in the upper oceanic crust.

Nature

Structure and petrology of the alpine-type peridotite at Burro Mountain, California, U.S.A.

The alpine-type peridotite at Burro Mountain is a partially serpentinized harzburgite-dunite body approximately 2 km in diameter. It lies in a chaotic mélange derived from the Franciscan Formation (Upper Jurassic to Upper Cretaceous) of the southern Coast Ranges of California. The peridotite is bounded on the east by a vertical fault in the Nacimiento fault zone that brings sedimentary rocks of Taliaferro's (1943 b ) Asuncion Group (Upper Cretaceous) into contact with the peridotite. The peridotite appears to be one of a number of tectonic lenses, having a wide range in size, that make up the mélange . These lenses include metagraywacke, metachert, greenstone, amphibolite, and blueschist, as well as ultramafic rocks, and represent a wide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinite zone 10–15 m thick. The peridotite was tectonically emplaced at its present level as a cold solid mass and had little effect on the mineral assemblages of the Franciscan Formation. Local development of lawsonite and aragonite in shear zones may be related to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of the peridotite. It is a lithologically uniform rock that has an olivine: orthopyroxene ratio of approximately 75:25. Accessory clinopyroxene and chromian spinel generally make up less than 5 per cent of the harzburgite. Dunite, composed of olivine, accessory chromian spinel (< 5 per cent), and trace amounts of pyroxene, makes up approximately 40 per cent of the peridotite and occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositional variations and chromian spinel shows a large range in the cation ratio Cr/(Cr+Al+ Fe 3+ ). The compositional variations in these minerals are related to original differences in bulk chemical composition. The following compositional ranges were determined for minerals in the harzburgite: olivine, Fo 91.1 −Fo 91.4 ; orthopyroxene, En 89.8 −En 91.1 ; clinopyroxene, Ca 47.0 Mg 50.0 Fe 3.0 −Ca 48.7 Mg 48.2 Fe 3.1 ; chromian spinel, Cr/(Cr+Al+Fe 3+ ) 0.37−0.55. The pyroxenes have a range in A1 2 O 3 content of 1.3−3.0 wt per cent. Olivine from dunite ranges from Fo 91 to Fo 92 7 and the chromian spinel has a range in the Cr/(Cr+Al+Fe 3+ ) ratio of 0.30−0.75. Although all the dunites are lithologically similar, three distinct types are recognized on the basis of composition of coexisting olivine and chromian spinel. Structural relations between the three types of dunite suggest three periods of emplacement (possibly overlapping) of dunite into harzburgite. The evidence indicates that the dunite, and probably also the harzburgite crystallized from an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotite was subjected to a deep-seated plastic deformation and recrystallization. The first phase of the deformation produced a pervasive, planar structural element (S 1 ) that crosscuts many harzburgite-dunite contacts. It is probable that some of the dunite sills were emplaced during this deformation. The foliation, S 1 , is defined by layers of different orthopyroxene content in harzburgite, and by discontinuous layers of chromian spinel in dunite. Flow or slip along S 1 produced slip folds in harzburgite—dunite contacts with axial planes parallel to S 1 . At a later stage, isoclinal folds developed in S 1 , and the present olivine microfabric was probably formed by recrystallization in the stress field that produced the isoclinal folding. In the olivine microfabric, X tends to be perpendicular to the axial planes (S 2 ) of the isoclinal folds and Y and Z tend to form double maxima in S 2 approximately 90° apart. Mg−Fe 2+ distribution between coexisting mineral pairs yields a calculated temperature of formation of approximately 1200 °C. Although this temperature is only a nominal value, it indicates that the mineral pairs equilibrated at a significantly high temperature. In view of the deformation and recrystallization, the calculated temperature possibly represents subsolidus re-equilibration of the minerals during this event. The deformation and recrystallization probably occurred shortly after crystallization while the peridotite was still at a high temperature. A later deep-seated deformation produced small scattered kink folds in S 1 that tend to disrupt the major olivine microfabric. The kink folding was accompanied or followed by the development of kink bands in olivine that reflect intragranular gliding on the system T = [ Okl ], t = [100]. The kink bands probably formed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took place in the mantle, the peridotite mass was tectonically detached and moved upward to its present level in the crust. Cleavages, joints, and faults provided channels for water to pervade the peridotite and allow alteration of the primary minerals.

California

Statistical perspective on the petrologic utility of polyphase groundmass compositions inferred via defocused beam electron probe microanalysis

Polyphase groundmasses (micro-scale minerals with or without glass) are generated from silicate liquids during the cooling of natural lavas often alongside larger minerals formed long before eruption. Many researchers have posited that compositions gleaned from the analysis of groundmasses closely approximate the compositions of the melts they were derived from, and these have been used frequently to model pre-eruptive magma conditions. However, it is difficult to confidently identify and sample these groundmasses once they are formed. Using a sample of lava that exhibits a wide degree of textural variation (ranging from holocrystalline to hypohyaline) we show that compositions of groundmasses sampled using defocused electron beams are significantly different from glass compositions in terms of mean composition and covariance. Despite this, several groundmass compositions qualify as ‘in equilibrium’ with matrix/rim olivine. When processed using available thermometers, however, modelled equilibrium temperatures are significantly higher than those produced using glass data, on average. Because of this, we prescribe caution in using polyphase groundmass data generated using defocused beam analysis even as a rudimentary approach.

Geostandards and Geoanalytical Research

Mineralogy and petrology of comet 81P/wild 2 nucleus samples

The bulk of the comet 81P/Wild 2 (hereafter Wild 2) samples returned to Earth by the Stardust spacecraft appear to be weakly constructed mixtures of nanometer-scale grains, with occasional much larger (over 1 micrometer) ferromagnesian silicates, Fe-Ni sulfides, Fe-Ni metal, and accessory phases. The very wide range of olivine and low-Ca pyroxene compositions in comet Wild 2 requires a wide range of formation conditions, probably reflecting very different formation locations in the protoplanetary disk. The restricted compositional ranges of Fe-Ni sulfides, the wide range for silicates, and the absence of hydrous phases indicate that comet Wild 2 experienced little or no aqueous alteration. Less abundant Wild 2 materials include a refractory particle, whose presence appears to require radial transport in the early protoplanetary disk.

Science

Petrology of unshocked crystalline rocks and shock effects in lunar rocks and minerals

On the basis of rock modes, textures, and mineralogy, unshocked crystalline rocks are classified into a dominant ilmenite-rich suite (subdivided into intersertal, ophitic, and hornfels types) and a subordinate feldspar-rich suite (subdivided into poikilitic and granular types). Weakly to moderately shocked rocks show high strain-rate deformation and solid-state transformation of minerals to glasses; intensely shocked rocks are converted to rock glasses. Data on an unknown calcium-bearing iron metasilicate are presented.

Science

Time and metamorphic petrology: Calcite to aragonite experiments

Although the equilibrium phase relations of many mineral systems are generally well established, the rates of transformations, particularly in polycrystalline rocks, are not. The results of experiments on the calcite to aragonite transformation in polycrystalline marble are different from those for earlier experiments on powdered and single-crystal calcite. The transformation in the polycrystalline samples occurs by different mechanisms, with a different temperature dependence, and at a markedly slower rate. This work demonstrates the importance of kinetic studies on fully dense polycrystalline aggregates for understanding mineralogic phase changes in nature. Extrapolation of these results to geological time scales suggests that transformation of calcite to aragonite does not occur in the absence of volatiles at temperatures below 200°C. Kinetic hindrance is likely to extend to higher temperatures in more complex transformations.

Science

Mineralogy and petrology of the currant creek magnesite deposits and associated rocks of Nevada

Cryptocrystalline magnesite occurs as relatively small dense, white masses in a Tertiary volcanic tuff, here named the Currant tuff, in White Pine and Nye counties, 29 miles southwest of Ely, Nevada. The deposits are small, but some of the magnesite is of very high quality with almost no iron or aluminum. However, much of the magnesite is mixed with dolomite and calcite, and a serpentinelike mineral occurs in one of the deposits in sufficient abundance to be of possible use in ceramics. In scattered areas the tuff has been altered by solutions rich in magnesium and bicarbonic acid to dolomite, magnesite, magnesium silicate, and calcite. Mineral and chemical characteristics are the same throughout the entire rock assemblage of flows and tuffs, suggesting that all the rocks have been derived from the same parent magma. The tuff formation, which ranges in thickness from a few feet to over 400 feet, occurs between two groups of volcanic flows here referred to as the lower volcanics and the upper volcanics. The lower volcanics is composed mainly of flows of hypersthene dacite, but in the southwestern part of the area flows of a hypersthene andesite of balsaltic habit occur between the dacite and the overlying Currant tuff. The upper volcanics which overlie the Currant tuff consist of porphyritic quartz latite and an overlying massive latite crystal tuff. The Currant tuff containing the magnesite has both unmodified and reworked tuff members. The formation of hydrothermal dolomite, magnesite, and deweylite is discussed in detail, and the physical chemistry of solutions containing calcium, magnesium, and carbon dioxide is applied in an explanation of the origin of magnesium-rich solutions.

Nevada

Petrology of granophyre in diabase near Dillsburg, Pennsylvania

Small bodies of granophyre occur in the upper part of diabase bodies of Triassic age in southeastern Pennsylvania. One near Harrisburg was penetrated by a diamond-drill. Drill core specimens show a gradation from diabase to granophyre. New data include 10 chemical analyses, spectrographic determinations of trace elements, and the results of petrographic study of specimens from the drill core. The sequence, from diabase to granophyre, includes a chilled zone that represents an original magma of tholeiitic composition, normal diabase, pegmatitic facies of diabase, and granophyric diabase that is intermediate in composition and petrographic characteristics between diabase and granophyre, and finally granophyre. Alkalies and silica increase progressively from diabase to granophyre; iron increases to a maximum in transitional granophyric diabase, then decreases in the granophyre. It is concluded that crystal fractionation in a large sheetlike body of tholeiitic magma yielded a small amount of granophyre. Prior to complete solidification, a residual liquid rich in iron, alkalies, and silica accumulated locally in the upper part of the diabase sheet. In places volatile-rich iron-bearing solutions escaped into the overlying sedimentary rocks and deposited magnetite; the remaining liquid crystallized t o fine-grained granophyre.

Pennsylvania

A further contribution to the petrology of Haleakala volcano, Hawaii

Sixteen new chemical analyses of the later rocks of Haleakala Volcano , on the island of Maui, Hawaii , add to the differentiation picture for that volcano . The early rocks of the volcano are tholeiitic. These are followed by dominant hawaiites with less abundant alkalic olivine basalts, picrite-basalts of ankaramite type, and a few mugearites. Still later rocks, separated from earlier ones by a profound erosional unconformity, include some hawaiites and ankaramites, but are dominantly alkalic olivine basalts (basanitoids) containing as much as 16.5 percent normative nepheline, some of them transitional to ankaramite. The progression toward ultramafic, strongly undersaturated rocks (nephelinites), characteristic of the post-erosional lavas of other Hawaiian volcanoes, appears to have just begun at Haleakala .

Hawaii

Metamorphism of Precambrian granitic xenoliths in a mica peridotite at Rose Dome, Woodson County, Kansas: Part 2, petrologic and mineralogic studies

Field, drill-core, petrographic, and mineralogic studies show that the Precambrian granitic rocks exposed on Rose Dome, Woodson County, Kansas, were emplaced as inclusions of basement rock in a mica peridotite magma that intruded the Pennsylvanian section of Rose Dome during Late Cretaceous time. High temperatures of the alkaline ultramafic magma (probably greater than 800° C) led to metamorphism of the granitic inclusions and the formation of high sanidine and high albite from original microcline and albite. Contact metamorphic effects on country rock include the development of buchite-like sanidine-magnesian biotite hornfels from Weston Shale (Pennsylvanian) that was intruded by the mica peridotite. The high temperatures of the peridotite magma also led to partial melting of the granitic rocks; a quartzofeldspathic matrix shows volcanic textures and binds mineral and rock fragments together to produce the varied range of textures and structures of the granitic xenoliths. Partial melting of the granitic rocks accounts for those features that led earlier workers to conclude that the “granite” on Rose Dome had intruded the Pennsylvanian section. Those features included xenoliths of hornfels enclosed by granitic material and apparently intrusive relationships between the granitic rocks and metamorphosed shale. The lack of concordance in the Rb-Sr ages of the granitic rocks (Part 1) may stem partly from melting of the “granite” and exchange of ions with the mica peridotite magma, from the “sampling” of different levels of granitic crust by the upwelling peridotite magma, or from weathering.

Kansas

Petrologic and geophysical nature of serpentinites

Mineralogically, serpentinites consist predominantly of lizardite, clinochrysotile, and antigorite. Recent work has shown that these minerals are not polymorphs. Chrysotile is the only mineral recognized as a synthetic product in experimental studies of the system MgO-SiO 2 -H 2 O. Antigorite seems to be stable at higher temperatures than lizardite or chrysotile. The density of individual serpentine species is dependent on their morphology; the low-density serpentinites (<2.55g/cc) consist predominantly of clino-chrysotile. Seismic velocities and magnetic susceptibilities of serpentinites are related to the degree of serpentinization. The transition of massive serpentinites from ductile to brittle behavior in laboratory experiments at high confining pressures and temperatures above 300°C has been related to dehydration which may provide a mechanism for developing deep-focus earthquakes along Benioff zones. Serpentinite is formed by direct hydration of ultramafic protolith in the crust. The most common ultramafic protoliths are harzburgite, dunite, and Iherzolite. The assemblage generally developed from these is lizardite + chrysotile + brucite + magnetite. In areas of high-grade metamorphism, antigorite is the predominant serpentine mineral. The common, large, alpine-type serpentinized ultramafic masses contain brucite and have MgO/SiO 2 ratios similar to those of their protolith, resulting in volume increase during serpentinization. Metamorphic serpentinites and some highly sheared alpine-type serpentinites have lower MgO/SiO 2 ratios than their protolith, lack brucite, and appear t o have been formed by volume-for-volume replacement with concomitant loss of magnesium or addition of silica. Many large, young masses of peridotite appear to be slabs of oceanic mantle over-thrust onto continental edges. Subsequent sedimentation, serpentinization, and tectonism have greatly modified these original slabs so that their recognition in older orogenic zones is equivocal. The concept of the tectonic evolution of ultramafic rocks from oceanic crust-mantle slabs invading continental margins and being incrementally serpentinized and moved by later tectonic events provides a working hypothesis that allows a better explanation of the many peculiar and varied occurrences of serpentinite. The evidence does not support Hess' suggestion that the third layer of the oceanic crust consists of partly serpentinized mantle peridotite.

Bulletin of the Geological Society of America

Petrology of the Vulcan Peak alpine-type peridotite, southwestern Oregon

The alpine-type peridotite in the area of Vulcan Peak, Oregon, is part of the larger Josephine ultramafic complex in the Klamath Mountains geologic province. Partially serpentinized, foliated harzburgite with 15 to 30 percent orthopyroxene makes up approximately 90 percent of the body. The remaining 10 percent is dunite that occurs in the harzburgite as concordant and discordant layers and as irregular bodies. In general, the peridotite at Vulcan Peak is similar in structure, texture, mineralogy, and chemistry to the peridotite at Burro Mountain, California. Structures, textures, and compositions of coexisting phases are consistent with high-temperature (1,000° to 1,200°C) deformation and recrystallization in the upper mantle, and tectonic emplacement into its present crustal position. Evidence to indicate whether the peridotite originated as a refractory residue during partial fusion processes that produced mafic melt or by crystallization from an ultramafic or picritic magma remains inconclusive; poikilitic clinopyroxene enclosing olivine in some dunites, and certain chromitite textures, may represent relict igneous features suggesting a magmatic stage in the history of the peridotite.

Oregon