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At least 127 records · Page 7Linked to original sources

Chemical and textural controls on phosphorus mobility in drylands of southeastern Utah

We investigated several forms of phosphorus (P) in dryland soils to examine the chemical and textural controls on P stabilization on a diverse set of substrates. We examined three P fractions including labile, moderately labile, and occluded as determined by a modified Hedley fractionation technique. The P fractions were compared to texture measurements and total elemental concentrations determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Labile P related to the absence of materials involved in P sorption. Moderately labile P was most strongly associated with high total Al & Fe content that we interpret to represent oxides and 1:1 clay minerals. The occluded P fraction was strongly associated with low total Al & Fe environments and interpreted to represent 2:1 clay minerals where ligand exchange tightly sequesters P. The results indicate that the controls on P fraction distribution are initially closely tied to the chemical and physical properties of the bedrock units that contribute to soil formation. Further, these results suggest that the progression of stabilized P forms in dryland areas differs from the progression observed in mesic environments. Soil development in dryland settings, such as the formation of pedogenic carbonates, may lead to differing controls on P availability and the proportional size of the moderately labile fraction.

Utah↗

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper↗

Mineral resource of the month: barite

Also called barytes, barite forms in various geologic environments and is frequently found with both metallic and nonmetallic minerals. Most barite is produced by open-pit mining techniques, and most crude barite requires some upgrading to meet minimum purity or specific gravity levels.

Geotimes↗

Iron formation and associated rocks in the Iron River district, Michigan

The iron formation of the Iron River district is part of a Precambrian sequence of strata characterized by a high iron content and varied mineralogy. The iron formation, where unoxidized, consists largely of interlaminated chert and siderite. It is underlain by a graphitic slate containing about 20 per cent iron in the form of very finely disseminated pyrite. Graywacke overlies the iron formation with at least local disconformity; this rock consists of clastic grains in a matrix of siderite or iron-rich chlorite. Above the gray-wacke is a magnetic ironstone, a laminated rock that now consists of iron-rich chlorite, magnetite, chert, and siderite, each layer being an intermixture of two or more of these constituents. The average iron content of the entire sequence, including the iron formation, is approximately 20 per cent. The rocks are only slightly metamorphosed, although the area is one of intense structural deformation. The origin of the rocks is discussed, and it is concluded that the high iron content is primary. The rocks are believed to be the products of an era of iron-rich sedimentation in which the specific iron mineral formed —sulfide, carbonate, or silicate—depended upon the immediate depositional environment. Inasmuch as the formation of iron-rich minerals continued despite extensive changes in both the basin of deposition and the adjacent land areas, the ultimate cause for such an epoch is one that transcended such factors. Evidence is presented to show that the climate of the era, when linked with certain other factors, is entirely adequate to explain the formation of these iron-rich rocks.

Michigan↗

Maturation study of vitrinite in carbonaceous shales and coals: Insights from hydrous pyrolysis

The presence of vitrinite in sedimentary rocks of post-Silurian age allows its reflectance to be used to estimate the thermal maturation of organic matter in petroleum systems. Increasing reflectance of vitrinite, which is primarily driven by aromaticity, depends primarily on the time and temperature attributes of its evolutionary pathway. This study evaluated carbonaceous shales proximal to coal measures and coal samples via isothermal hydrous pyrolysis (HP) to compare differences in the maturation pathways of vitrinite. Sample residues were analysed via vitrinite reflectance (VRo), geochemical screening tests (organic carbon and programmed temperature pyrolysis), and infrared spectroscopy. The study included samples from Indian and North American basins, to observe differences in vitrinite evolution with respect to enclosing mineral matrix, starting degree of aromaticity, organic matter types, stratigraphic age, and depositional environment. The organic content of HP residues shows an intuitive response to the thermal stress of HP, e.g., a general depletion of total organic carbon (TOC) content, pyrolyzate (S2), and hydrogen index with increasing HP temperature. Infrared proxies including C-factor and CH2/CH3 generally decrease with increasing thermal maturity indicating loss of O via CO2 generation and the thermal cracking of aliphatic organic matter. Tmax, production index (PI), and VRo show intuitive increasing values with respect to HP temperature. The least mature sample (0.48 ± 0.05% VRo) generally experienced the maximum change in these parameters during maturation, whereas the most mature sample (0.99 ± 0.06% VRo) generally showed the least change. This observation is consistent with higher kinetic barriers to reaction in more aromatic vitrinite which contains higher bond dissociation energies. Devolatilization of vitrinite during HP causes formation of gas evacuation vacuoles and contraction cracks in the vitrinite grains of both coal and carbonaceous shale. Similarities in vitrinite response to HP between coal and carbonaceous shale suggest that thermal evolution of the vitrinite maceral is principally controlled by inherent rate-limiting kinetic parameters related to its molecular structure. Whereas, the stratigraphic age, sedimentary environment, surrounding organic matter, lithology, and catalysis by mineral composition have less effect. To further improve our understanding of vitrinite aromatization and kinetic parameters, future studies of vitrinite reflectance thermal evolution with temperature should include coal and carbonaceous shale from the same stratigraphic section and extant woody tissue from modern vascular plants.

International Journal of Coal Geology↗

Swatara Creek basin of southeastern Pennsylvania: An evaluation of its hydrologic system

Local concentrations of population in the Swatara Creek basin of Pennsylvania find it necessary to store, transport, and treat water because local supplies are either deficient or have been contaminated by disposal of wastes in upstream areas. Water in the basin is available for the deficient areas and for dilution of the coal-mine drainage in the northern parts and the sewage wastes in the southern parts. Swatara Creek drains 576 square miles just east of Harrisburg, Pa., and is the largest tributary to the Susquehanna River from the north side below Harrisburg. It rises in the southern Pocono Mountains and flows southwestward across the Lebanon Plateau. On an average day Swatara Creek discharges more than 630 million gallons into the Susquehanna River at Middletown, Pa. In a year this amounts to about 23 inches of water over the entire basin and is the residual from an average annual precipitation of 45.5 inches. During an average year the flow in Swatara Creek from the upper third of the basin above Harper Tavern is always greater than 1,300 mgd (million gallons per day) for at least 15 days and is always greater than 25 mgd for at least 350 days. The daily streamflow from the basin averages 1.1 mgd per sq mi, but yields from different areas range from 0.97 to 1.22 mgd per sq mi. These variations are caused chiefly by differences in precipitation and land cover. The area of lowest yield is in the valleys west of Tremont, and the highest yields are in the Upper and Lower Little Swatara Creek subbasins. At high and medium stages the chemical character of the water in the streams is suitable for public and private supplies. At lower stages, defending on the areas and the amounts of contamination by coal-mine drainage and sewage pollution, the natural flow may require some treatment. At low stages the chemical characteristics of the natural flow not affected by man is almost identical with that of the ground water in the area drained by the stream. In general, the total dissolved solids range from about 25 to 400 parts per million and the hardness is as much as about 300 parts per million. The ground-water increment to the base flow of Swatara Creek averages about 240 mgd, or about 8.8 inches annually, for the basin. Generally, ground-water supplies in amounts of less than 0.5 mgd can be developed south of Blue Mountain. Supplies of several million gallons per day have been developed for industrial use from the permeable limestones in the south-central part of the basin. More intensive investigation in other parts of the basin would indicate areas where supplies of more than 0.5 mgd could be developed from properly spaced wells. The chemical character of water from wells depends largely on the host rock. In highly soluble rocks water contains large amount of dissolved solids; in more resistant rocks concentrations are lower. The chemical character of unpolluted ground water generally reflects the composition of the more readily soluble minerals in the local geologic environment. Areas contaminated by septic- tank effluent may have above normal amounts of nitrate and detergent products. Except where polluted, most ground water is suitable for public and industrial uses without extensive treatment. Sites for storage of surface water exist in the part of the basin lying in the valley and ridge area. As much as 30 to 40 percent of the annual flow could be impounded for release as low-flow augmentation for dilution of mine drainage and other wastes in the basin. Low sediment yields of supplying drainage areas would ensure a long life expectancy of reservoirs at these sites. Overbank flooding of the main stem of the Swatara Creek and its tributaries has occurred many times in the past. However, it has not been a hazard because urban development has not encroached on the flood plain. An inundation map of the August 1933 flood provides a basis that urban planners may use to avoid future damage. As water in the Swatara Creek moves downstream to the Susquehanna River, the flow is influenced consecutively by a large annual rainfall on the northern valley and ridge area, the wastes of surface and subsurface coal-mining activities, and less annual rainfall on the part of the basin lying in the Lebanon Plateau area; the flow is supplemented and further influenced by many tributaries and by the industrial and domestic wastes that are carried by these secondary streams. The annual precipitation ranges from 52 inches at the east edge and 49 inches at the west edge of the mountainous part of the basin to about 41 inches at the southwestern part at Middletown. The rainfall generally is adequate during the growing season to mature the crops. The mean annual temperature at Lebanon is about 52°F, and the growing season is about 180 days. In this report the basin has been divided into eight hydrologic zones, leased on runoff, natural use of water, and chemical character of water. Four zones lie in the valley and ridge area, three lie in the Lebanon Plateau area, and one lies in the highland along the southeastern basin boundary. In each of the zones the hydrologic characteristics are virtually the same, but they may be completely different from those in adjacent zones. The boundaries of the zones generally coincide with boundaries between geologic formations, and the areas in each zone include rocks of similar influence on water. Streams in zone 4 at the northeast edge of the plateau have the highest average surface runoff from 1.2 to 1.1 mgd per sq mi whereas those in zone 2 at the northwest edge of the valley and ridge area have the lowest, about 1.0 mgd. Streams in zone 8, along the southeast edge of the basin, have the largest sustained low-flow yield, about 0.26 to 0.19 mgd per sq mi; those in zone 5 overlying the Martinsburg Shale east of Harrisburg have the smallest sustained low-flow yields, 0.03 to 0.01 mgd. Streams in the limestone area of zone 7 have the greatest range in low-flow yields in any one zone from 0.60 to 0 mgd per sq mi. Low-flow yields in zones 1 through 4 range from 0.13 to 0.03 mgd per sq mi. Surface flows from zones 1 and 2 are generally acidic and contain high concentrations of sulfate, iron, and total dissolved solids especially where contaminated with mine wastes. Surface flows from zones 3 and 4 are dilute, slightly alkaline, and suitable for public water supplies. Surface flows from zones 5, 6, and 7 are alkaline and contain moderate concentrations of dissolved solids with waters of highest hardness occurring in zone 7. Surface flows from zone 8 are dilute to moderately mineralized and are relatively high in silica concentration. Nitrate concentrations are high in surf Fee flows below sewage outfalls and in ground water contaminated by septic tank effluent and industrial wastes. Average annual sediment yields of 550 to 650 tons per square mile are characteristic of zones 1 and 2 where strip mining has destroyed the forest cover and coal culm is carried into the streams. From agricultural lands on the Martinsburg Shale in zones 5 and 6, annual sediment yields range from 300 to 350 tons per square mile; but from agricultural lands on the siliceous rocks in zone 8 and zones 3 and 4 in the valley and ridge area, the sediment yield ranges from 200 to 250 tons annually per square mile. Lowest annual sediment yields in the basin are in the forested areas of siliceous rocks in zones 2, 3, 4, and 5, and in the sinkhole topography of the limestones in zone 7 where the yield ranges from 30 to 35 tons and 50 to 60 tons per square mile, respectively. The amount of ground water that can be developed in the basin is dependent on the ability of the underlying rocks to yield water to wells. More than 300 gpm (gallons per minute) can be obtained from wells in alluvial materials in the valley bottoms and in some of the limestones where large solution channels and fractures are penetrated by the wells. From 50 to 300 gpm can be obtained from wells in loosely cemented sandstones and in fractured limestones. From 10 to 50 gpm can be developed from wells in the shales and harder sandstones. The most dense rocks will yield from 1 to 10 gpm from fractures and crevices. Most wells yield water from the upper 350 feet of the formation, for this part contains the most fractures or solution channels. Studies show that the velocity at which a contaminant will move downstream in the basin is related to the discharge of the stream at the time. At a stream discharge of about 400 mgd at Pine Grove, a contaminant in Swatara Creek would require about 40 hours to move from Pine Grove to Middletown. As a result of dispersion and dilution, the maximum concentration of the contaminant at Middletown would be less than 20 percent the concentration at Pine Grove under these conditions. An evaluation of the availability of water in the basin indicates that about I,239 mgd enters as precipitation, 630 mgd leaves as streamflow, 580 mgd is evaporated and transpired, and 56 mgd is diverted for use by man. Not all the diversions for man's use are lost to the basin, as about 27 mgd is returned as sewage for reuse. About one-fourth of the waste water is returned to the ground and the remainder to stream drainageways. Of that diverted by man, 11.6 mgd is used for public supply and 44.4 mgd for industrial and private supplies. Diversions of streamflow furnish 86 percent of the public supply and 27 percent of the industrial supply, and ground-water sources yield the remainder. Municipal and private sewage treatment plants are upgrading the waste water in many places, but no provisions are being made for treatment other than natural dilution and assimilation for the 15 mgd of coal-nine drainage in the northern part of the basin. Technology for economic treatment of mine water is not available at this time, although research in this field is being done. Urbanization eastward from Harrisburg and around Lebanon has increased the population density of the basin. Densities of 500 people per square mile and water use exceeding 2.0 mgd per sq mi can be expected in the future. By the year 2000 the population of the basin may increase 60 percent; and if the per capita rate of use increases 0.5 percent per year the domestic requirements for water will be about two times the present use, or 23 mgd. Similarly, if the present 1:4 ratio of domestic use to industrial use of water continues, at least 89 mgd will be needed for industry in the future. Although an increase to twice the present use of water can be foreseen, or 112 mgd, water for the dilution and assimilation of wastes from treatment systems are not included. Providing water for dilution of wastes from treatment plants has not been a problem, but in the future the amounts needed for this purpose will be greater as the population increases. As water becomes more valuable, treatment of sewage wastes to reduce the biochemical-oxygen-demand load by at least 80 to 90 percent will be necessary to conserve water for more productive uses. As much as 100 mgd may be needed for waste dilution in the basin by year 2000. The present trends in suburban and light industrial development will probably persist in the basin. Problems arising through changes in economic value of water, conflicts in use, and alternatives in development are typical of those confronting the manager of a water-resource system.

Pennsylvania↗

An aem-tem study of weathering and diagenesis, Abert Lake, Oregon: I. Weathering reactions in the volcanics

Abert Lake in south-central Oregon provides a site suitable for the study of sequential weathering and diagenetic events. In this first of two papers, transmission electron microscopy was used to characterize the igneous mineralogy, subsolidus alteration assemblage, and the structural and chemical aspects of silicate weathering reactions that occur in the volcanic rocks (basalts, basaltic andesites, and dacitic/ rhyolitic extrusive and pyroclastics) that outcrop around the lake. Olivine and pyroxene replacement occurred topotactically, whereas feldspar and glass alteration produced randomly oriented smectite in channels and cavities. The tetrahedral, octahedral, and interlayer compositions of the weathering products, largely dioctahedral smectites, varied with primary mineral composition, rock type, and as the result of addition of elements released from adjacent reaction sites. Weathering of the highly evolved, Fe-rich Jug Mountain complex at the north end of the lake produced a homogeneous smectite assemblage that contrasts with the heterogeneous smectite assemblage replacing the volcanics along the eastern margin of the lake. The variability within and between the smectite assemblages highlights the microenvironmental diversity, fluctuating redox conditions, and variable solution chemistry associated with mineral weathering reactions in the surficial environment. Late-stage exhalative and aqueous alteration of the volcanics redistributed many components and formed a variety of alkali and alkali-earth carbonate, chloride, sulfate, and fluoride minerals in vugs and cracks. Overall, substantial Mg, Si, Na, Ca, and K are released by weathering reactions that include the almost complete destruction of the Mg-smectite that initially replaced olivine. The leaching of these elements from the volcanics provides an important source of these constituents in the lake water. The nature of subsequent diagenetic reactions resulting from the interaction between the materials transported to the lake and the solution will be described in part II ( Banfield et al., 1991).

Geochimica et Cosmochimica Acta↗

Crystal chemistry of thallium in marine ferromanganese deposits

Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO 2 ), the principle manganate mineral in oxic and suboxic environments, and (2) being able to determine the sorption sites and bonding environments of the Tl(I) and Tl(III) complexes on vernadite. We investigated these foundations by determining the oxidation state and chemical form of Tl in FeMn crusts and nodules from the global oceans at a Tl concentration ranging from several hundred ppm (mg/kg) down to the low ppm level. Seventeen hydrogenetic crusts and eleven nodules from the Pacific, Atlantic, Arctic, and Indian Oceans and Baltic Sea were characterized by chemical analysis, X-ray diffraction, Raman spectroscopy, Mn K-edge X-ray absorption near-edge structure (XANES) spectroscopy, Tl L 3 -edge high energy-resolution XANES (HR-XANES) spectroscopy, and extended X-ray absorption fine structure (EXAFS) spectroscopy. The Tl concentration increases linearly from 1.5 to 319 ppm with the Mn/Fe ratio in Fe-vernadite from hydrogenetic crusts, whereas the percentage of Tl(III) to total Tl varies between 62 and 100% independent of both the Mn/Fe and Mn(III)/Mn(IV) ratios. The data, complemented by molecular modeling of the Tl(III) coordination and by XANES calculations, suggest that the enrichment of Tl in Fe-vernadite is driven by (1) the oxidative uptake of octahedrally coordinated Tl(III) above the vacant Mn(IV) sites and on the layer edges of the vernadite layers, and (2) the sorption of Tl(I) on the crystallographic site of Ba at the surface of the vernadite layers, which is an analogue to the surface site of K. Thus, Tl has a high affinity for vernadite regardless of its oxidation state, and the lack of correlation between Tl(III) and the Mn/Fe ratio in FeMn crusts is explained by the affinity of Tl(I) for the Ba site. The Tl concentration varies between 2 and 112 ppm in surface and buried nodules independent of the Mn/Fe ratio, and the percentage of Tl(III) varies between 0 and 100%. Nodules subjected to sediment diagenesis with replacement of layered vernadite by tunneled todorokite are depleted in Tl and have more reduced thallium. Knowledge of the complex interplay of mineralogy, surface chemical processes, and crystallographic siting is required to understand the variability of Tl concentrations, redox state, and acquisition processes by marine FeMn deposits.

ACS Earth and Space Chemistry↗

Surficial geology

Surficial materials are those at or near the Earth's surface. They constitute, by far, the largest and most used part of the ground around us. Areas not covered by surficial deposits--bare bedrock--form probably less than 5 percent of our land surface. Most surficial deposits are composed of poorly consolidated clay, silt, sand, or gravel-sized particles that are produced chiefly by erosion and are transported by and finally deposited by water, wind, or ice, but are also partly produced by the in-situ weathering of bedrock. The major genetic categories are shown on the map by various colors; the principal compositional types in each category are indicated by patterns. Colors, patterns, and letter symbols are given in the explanation which follows this summary description. Surficial deposits have characteristics important to our environment--water-bearing properties, mineral resources, and suitability as a natural foundation for buildings. They are also susceptible to flooding, erosion, ground subsidence, land slides, and earthquakes.

National Atlas of the United States of America↗

U. S. Geological Survey programs in Pennsylvania

The U.S. Geological Survey (USGS) is involved in mapping and studying land, mineral, biological, and water resources and determining the risk from earthquakes and other natural hazards, which are of importance to the citizens of Pennsylvania. This Fact Sheet describes how the USGS is addressing some of the major environmental issues in Pennsylvania, which include availability of mineral resources; contamination of the environment by hazardous wastes; effects of coal mining, oil and gas production, and agriculture on the environment; nutrient input to streams and estuaries; and adequacy of good-quality water supplies. Information on acquiring the thousands of map, book, and aerial photographic products of the USGS also is given.

Fact Sheet↗

U.S. Geological Survey (USGS) Western Region: Alaska Coastal and Ocean Science

The U.S. Geological Survey (USGS), a bureau of the Department of the Interior (DOI), is the Nation's largest water, earth, and biological science and mapping agency. The bureau's science strategy 'Facing Tomorrow's Challenges - U.S. Geological Survey Science in the Decade 2007-2017' describes the USGS vision for its science in six integrated areas of societal concern: Understanding Ecosystems and Predicting Ecosystem Change; Climate Variability and Change; Energy and Minerals; Hazards, Risk, and Resilience; Environment and Wildlife in Human Health; and Water Census of the United States. USGS has three Regions that encompass nine geographic Areas. This fact sheet describes examples of USGS science conducted in coastal, nearshore terrestrial, and ocean environments in the Alaska Area.

Fact Sheet↗

Geologic insights and suggestions on mineral potential based on analyses of geophysical data for the southern Toquima Range, Nye County, Nevada

Aeromagnetic and gravity data provide confirmation of major structural and lithologic units in the southern Toquima Range, Nevada. These units include Cretaceous granite plutons and Tertiary calderas. In addition, the geophysical maps pinpoint numerous faults and lesser intrusions, and they suggest locations of several inferred subsurface intrusions. They also corroborate a system of northwesterly and northeasterly conjugate structures that probably are fundamental to the structural framework of the Toquima Range. A combination of geophysical, geochemical, and geologic data available for the widely mineralized and productive area suggests additional mineral resource potential, especially in and (or) adjacent to the Round Mountain, Jefferson, Manhattan, and Belmont mining districts. Also, evidence for mineral potential exists for areas near the Flower mercury mine south of Mount Jefferson caldera, and in the Bald Mountain Canyon belt of gold-quartz veins in the Manhattan caldera. A few other areas also show potential for mineral resources. The various geologic environments indicated within the map area suggest base- and precious-metal potential in porphyry deposits as well as in quartz-vein and skarn deposits associated with intrusive stocks.

Nevada↗

Zeolite-clay mineral zonation of volcaniclastic sediments within the McDermitt caldera complex of Nevada and Oregon

Volcaniclastic sediments deposited in the moat of the collapsed McDermitt caldera complex have been altered chiefly to zeolites and potassium feldspar. The original rhyolitic and peralkaline ash-flow tuffs are included in conglomerates at the caldera rims and grade into a lacustrine series near the center of the collapse. The tuffs show a lateral zeolitic alteration from almost fresh glass to clinoptilolite, clinoptilolite-mordenite, and erionite; to analcime-potassium feldspar; and finally to potassium feldspar. Vertical zonation is in approximately the same order. Clay minerals in associated mudstones, on the other hand, show little lateral variation but a distinct vertical zonation, having a basal dioctahedral smectite, a medial trioctahedral smectite, and an upper dioctahedral smectite. The medial trioctahedral smectite is enriched in lithium (as much as 6,800 ppm Li). Hydrothermal alteration of the volcaniclastic sediments, forming both mercury and uranium deposits, caused a distinct zeolite and clay-mineral zonation within the general lateral zonation. The center of alteration is generally potassium feldspar, commonly associated with alunite. Potassium feldspar grades laterally and vertically to either clinoptilolite or clinoptilolite-mordenite, generally associated with gypsum. This zone then grades vertically and laterally into fresh glass. The clay minerals are a dioctahedral smectite, a mixed-layer clay mineral, and a 7-A clay mineral. The mixed-layer and 7-A clay minerals are associated with the potassium feldspar-alunite zone of alteration, and the dioctahedral smectite is associated with clinoptilolite. This mineralogical zonation may be an exploration guide for mercury and uranium mineralization in the caldera complex environment.

Open-File Report↗

A simple Bouguer gravity anomaly map of southwestern Saudi Arabia and an initial interpretation

Approximately 2,200 gravity stations on a 10-km2 grid were used to construct a simple Bouguer gravity anomaly map at 1:2,000,000 scale along a 150-km-wide by 850-km-long strip of the Arabian Peninsula from Sanam, southwest of Ar Riyad, through the Farasan Islands and including offshore islands, the coastal plain, and the Hijaz-Asir escarpment from Jiddah to the Yemen border. On the Precambrian Arabian Shield, local positive gravity anomalies are associated with greenstone belts, gneiss domes, and the Najd fault zones. Local negative gravity anomalies correlate with granitic plutonic rocks. A steep gravity gradient of as much as 4 mgal-km-1 marks the continental margin on the coastal plain near the southwestern end of the strip. Bouguer gravity anomaly values range from -10 to +40 mgal southwest of this gradient and from -170 to -100 mgal in a 300-km-wide gravity minimum northeast of the gradient. Farther northeast, the minimum is terminated by a regional gradient of about 0.1 mgal-km-1 that increases toward the Arabian Gulf. The regional gravity anomaly pattern has been modeled by using seismic refraction and Raleigh wave studies, heat-flow measurements, and isostatic considerations as constraints. The model is consistent with the hypothesis of upwelling of hot mantle material beneath the Red Sea and lateral mantle flow beneath the Arabian plate. The model yields best-fitting average crustal densities of 2.80 g-cm-3 (0-20 km depth) and 3.00 g-cm-3 (20-40 km depth) southwest of the Nabitah suture zone and 2.74 g-cm-3 (0-20 km depth) and 2.94 g-cm-3 (20-40 km depth) northeast of the suture zone. The gravity model requires that the crust be about 20 km thick at the continental margin and that the lower crust between the margin and Bishah (lat 20? N., long 42.5? E.) be somewhat denser than the lower crust to the northeast. Detailed correlations between 1:250,000- and 1:500,000-scale geologic maps and the gravity anomaly map suggest that the greenstone belts associated with gravity highs contain a large proportion of gabbroic and dioritic intrusive rocks and that the bulk density of the upper crust associated with some of the batholithic complexes has been lowered by the large-scale intrusion of granitic material at depth, as well as by that exposed at the surface. A comparison of known base and precious metals occurrences with the Bouguer gravity anomaly field shows, in some cases, a correlation between such occurrences and the features of the gravity anomaly map. Several areas were identified between known mineral occurrences along gravity-defined structures that may contain mineral deposits if the lithologic environment is favorable.

Open-File Report↗

Apparent Consumption vs. Total Consumption--A Lead-Acid Battery Case Study

Introduction: This report compares estimates of U.S. apparent consumption of lead with estimates of total U.S. consumption of this mineral commodity from a materials flow perspective. The difference, attributed to the amount of lead contained in imported and exported products, was found to be significant for this sector. The study also assesses the effects of including mineral commodities incorporated in manufactured products on the interpretation of observed trends in minerals consumption and trade. Materials flow is a systems approach to understanding what happens to the materials we use from the time a material is extracted, through its processing and manufacturing, to its ultimate disposition. The U.S. Geological Survey (USGS) provides accurate and detailed mineral production and mineral commodity consumption statistics that are essential for government, nongovernment organizations, and the public to gain a better understanding of how and where materials are used and their effect on the environment and society. Published statistics on mineral apparent consumption are limited to estimates of consumption of raw material forms (ore, concentrate, and [or] refined metal). For this study, apparent consumption is defined as mine production + secondary refined production + imports (concentrates and refined metal) ? exports (concentrates and refined metal) + adjustments for government and industry stock changes. These estimates do not account for the amount of mineral commodities contained in manufactured products that are imported to the United States, nor do they deduct the amount of these mineral commodities contained in manufactured products that are exported from the United States. When imports or exports of manufactured products contribute significantly to the total use of a particular raw material, an estimate of consumption that does not consider the incorporated forms of these mineral commodities within imported or exported manufactured products can be either under- or overreported (depending on the net trade flow). Factors that influence consumption and trade patterns include variations in industry structure, labor or financial markets, legislation, and technology. As U.S. trade patterns of manufactured products change, omitting mineral commodities incorporated into these goods as part of U.S. mineral commodity consumption estimates may affect the interpretation of observed trends in minerals consumption and trade. Although it may be desirable to include minerals contained in manufactured products as part of consumption estimates, collection and estimation of these data are sometimes difficult. Consumption and trade data for every traded product may not be readily available. Compiling comprehensive consumption statistics for mineral commodities, which have many end uses, each including multiple products, may be time consuming. For these reasons, studies of all mineral commodities are not feasible. Mineral commodity selection for this study is based on data accessibility considerations and the relative importance of lead contained in imported and exported products when considered part of total U.S. lead consumption. Lead was selected for this initial evaluation of total mineral consumption because of the need to understand the consumption pattern of this potentially toxic metal and its compounds, the relative simplicity of this sector?s end-use structure, and the availability of trade data. This study draws upon the findings of an earlier lead consumption study (Biviano and others, 1999) conducted by the USGS for the period 1984 to 1993, but uses a different study methodology for an industry whose structure has changed from that considered in the earlier study. Figure 1 shows the quantity of material contributing to U.S. total consumption of lead metal from domestic and foreign industrial sectors in 2004, based upon trade data reported by the USGS and the U.S. International Trade Commission (USITC). For

Scientific Investigations Report↗

What was the groundwater quality before mining in a mineralized region? Lessons from the Questa Project

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department and supported by Molycorp, Inc (currently Chevron Minerals), has completed a 5-year investigation (2001-2006) to determine the pre-mining ground-water quality at Molycorp's Questa molybdenum mine in northern New Mexico. Current mine-site ground waters are often contaminated with mine-waste leachates and no data exists on premining ground-water quality so that pre-mining conditions must be inferred. Ground-water quality undisturbed by mining is often worse than New Mexico standards and data are needed to help establish closure requirements. The key to determining pre-mining conditions was to study the hydrogeochemistry of a proximal natural analog site, the Straight Creek catchment. Main rock types exposed to weathering include a Tertiary andesite and the Tertiary Amalia tuff (rhyolitic composition), both hydrothermally altered to various degrees. Two types of ground water are common in mineralized areas, acidic ground waters in alluvial debris fans with pH 3-4 and bedrock ground waters with pH 6-8. Siderite, ferrihydrite, rhodochrosite, amorphous to microcrystalline Al(OH)3, calcite, gypsum, barite, and amorphous silica mineral solubilities control concentrations of Fe(II), Fe(III), Mn(II), Al, Ca, Ba, and SiO2, depending on pH and solution composition. Concentrations at low pH are governed by element abundance and mineral weathering rates. Concentrations of Zn and Cd range from detection up to about 10 and 0.05 mg/L, respectively, and are derived primarily from sphalerite dissolution. Concentrations of Ni and Co range from detection up to 1 and 0.4 mg/L, respectively, and are derived primarily from pyrite dissolution. Concentrations of Ca and SO4 are derived from secondary gypsum dissolution and weathering of calcite and pyrite. Metal:sulfate concentration ratios are relatively constant for acidic waters, suggesting consistent weathering rates, independent of catchment. These trends, combined with lithology, mineralogy, and mineral solubility controls, provide useful constraints on pre-mining ground-water quality for the mine site where the lithology is known.

Geosciences Journal↗

Preliminary report on Tertiary volcanism and uranium mineralization in the Thomas Range and northern Drum Mountains, Juab County, Utah

The Thomas Range and northern Drum Mountains have a history of volcanism, faulting, and mineralization that began about 42 m.y. ago. Volcanic activity and mineralization in the area can be divided into three stages according to the time-related occurrence of rock types, trace element associations, and chemical nature of mineralization. Volcanic activity switched abruptly from rhyodacite-quartz latite (42-39 m.y. ago) to rhyolite (38-32 m.y. ago) to alkali rhyolite stages (21 and 6-7 m.y. ago); these stages correspond to periods of chalcophile and siderophile metal mineralization, no mineralization, and lithophile metal mineralization, respectively. Angular unconformities record episodes of cauldron collapse and block faulting between the stages of volcanic activity and mineralization. The youngest angular unconformity formed between 21 and 7 m.y. ago during basin-and-range faulting. Early rhyodacite-quartz latite volcanism from composite volcanoes and fissures produced flows, breccias, and ash-flow tuff of the Drum Mountains Rhyodacite and Mt. Laird Tuff. Eruption of the Mt. Laird Tuff about 39 m.y. ago from an area north of Joy townsite was accompanied by collapse of the Thomas caldera. Part of the roof of the magma chamber did not collapse, or the magma was resurgent, as is indicated by porphyry dikes and plugs in the Drum Mountains. Chalcophile and siderophile metal mineralization, including copper, gold, and manganese, accompanied early volcanism. The middle stage of volcanic activity was characterized by explosive eruption of rhyolitic ash-flow tuffs and collapse of the Dugway Valley cauldron. Eruption of the Joy Tuff 38 m.y. ago was accompanied by subsidence of this cauldron and followed by collapse and sliding of Paleozoic rocks from the west wall of the cauldron. Landslides in The Dell were covered by the Dell Tuff, erupted 32 m.y. ago from an unknown source to the east. An ash-flow of the Needles Range Formation was erupted 30-31 m.y. ago, probably from a distant source outside the volcanic field. The rhyolitic stage of volcanism was barren of mineralization. The last stage of volcanism was contemporaneous with basin-and-range faulting and was characterized by explosive eruption of ash and pumice, forming stratified tuff, and by quiet eruption of alkali rhyolite as viscous flows and domes. The first episode of alkali rhyolite volcanism deposited the beryllium tuff and porphyritic rhyolite members of the Spor Mountain Formation 21 m.y. ago. After a period of block faulting, the stratified tuff and alkali rhyolite of the Topaz Mountain Rhyolite were erupted 6-7 m.y. ago along faults and fault intersections. Erosion of Spor Mountain may have provided abundant dolomite detritus to the beryllium tuff member. The alkali rhyolite of both formations is fluorine-rich, as is evident from abundant topaz, and contains anomalous amounts of lithophile metals. Alkali rhyolite volcanism was accompanied by lithophile metal mineralization which deposited fluorite, beryllium, and uranium. The structure of the area is dominated by the Thomas caldera, and the younger Dugway Valley cauldron, which is nested within the Thomas caldera; the Thomas caldera is surrounded by a rim of Paleozoic rocks at Spor Mountain and Paleozoic to Precambrian rocks in the Drum Mountains. The Joy fault and Dell fault system mark the ring fracture zone of the Thomas caldera. These structural features began to form about 39 m.y. ago during eruption of the Mt. Laird Tuff and cauldon subsidence. The Dugway Valley cauldron sank along a series of step-like normal faults southeast of Topaz Mountain in response to collapse of the magma chamber of the Joy Tuff. The caldera structure was modified by block faulting between 21 and 7 m.y. ago, the time of widespread extensional faulting in the basin-and-range province. Vents erupted alkali rhyolite 6-7 m.y. ago along basin-and-range faults. Uranium mineralization was associated with the stage of alkali rhyolite volcanism, extensional basin-and-range faulting, and lithophile metal mineralization; it occurred at least 11 m.y. after the end of the caldera cycle. Uranium, derived from alkali rhyolite magma, was concentrated in trace amounts by magmatic fluids and in potentially economic amounts by hydrothermal fluids and ground water. Hydrothermal fluids deposited uraniferous fluorite as pipes in carbonate rocks of Paleozoic age on Spor Mountain and uranium-bearing disseminated deposits of fluorite and beryllium in the beryllium tuff member of the Spor Mountain Formation. Uranium of hydrothermal origin is dispersed in fluorite and opal. Uranium in fluorite may be tetravalent(?) but that in opal is probably hexavalent; no primary minerals of tetravalent uranium are known to occur. Ground waters have concentrated significant ores of hexavalent uranium minerals in the beryllium tuff member of the Spor Mountain Formation at the Yellow Chief Mine, and are probably also responsible for widespread low concentrations (0.0X percent) of uranium that occur separately from beryllium ore in the beryllium tuff member. More deposits of the Yellow Chief type may occur in down-faulted sections of beryllium tuff beneath the Thomas Range. The ground water ores show no evidence of a reducing environment; instead, precipitation of hexavalent uranium minerals occurred by evaporation, decline in concentration of complexing ions such as carbonate, or some other mechanism. Reducing environments for hydrothermal deposits must be sought around rhyolite vents and in a hypothesized pluton of alkali rhyolite composition beneath Spor Mountain; for ground-water deposits, reducing environments may occur in basin fill such as that of the Dugway Valley cauldron.

Utah↗

Carbonatites of the world, explored deposits of Nb and REE— Database and grade and tonnage models

This report is based on published tonnage and grade data on 58 Nb- and rare-earth-element (REE)-bearing carbonatite deposits that are mostly well explored and are partially mined or contain resources of these elements. The deposits represent only a part of the known 527 carbonatites around the world, but they are characterized by reliable quantitative data on ore tonnages and grades of niobium and REE. Grade and tonnage models are an important component of mineral resource assessments. Carbonatites present one of the main natural sources of niobium and rare-earth elements, the economic importance of which grows consistently. A purpose of this report is to update earlier publications. New information about known deposits, as well as data on new deposits published during the last decade, are incorporated in the present paper. The compiled database (appendix 1; linked to right) contains 60 explored Nb- and REE-bearing carbonatite deposits - resources of 55 of these deposits are taken from publications. In the present updated grade-tonnage model we have added 24 deposits comparing with the previous model of Singer (1998). Resources of most deposits are residuum ores in the upper part of carbonatite bodies. Mineral-deposit models are important in exploration planning and quantitative resource assessments for two reasons: (1) grades and tonnages among deposit types vary significantly, and (2) deposits of different types are present in distinct geologic settings that can be identified from geologic maps. Mineral-deposit models combine the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Globally based deposit models allow recognition of important features and demonstrate how common different features are. Well-designed deposit models allow geologists to deduce possible mineral-deposit types in a given geologic environment, and the grade and tonnage models allow economists to estimate the possible economic viability of these resources. Thus, mineral-deposit models play a central role in presenting geoscience information in a useful form to policy makers. The foundation of mineral-deposit models is information about known deposits. This publication presents the latest geologic information and newly developed grade and tonnage models for Nb- and REE-carbonatite deposits in digital form. The publication contains computer files with information on deposits from around the world. It also contains a text file allowing locations of all deposits to be plotted in geographic information system (GIS) programs. The data are presented in FileMaker Pro as well as in .xls and text files to make the information available to a broadly based audience. The value of this information and any derived analyses depends critically on the consistent manner of data gathering. For this reason, we first discuss the rules used in this compilation. Next, the fields of the database are explained. Finally, we provide new grade and tonnage models and analysis of the information in the file.

Open-File Report↗