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At least 127 records · Page 7Linked to original sources
USGS2011

Estimating groundwater recharge

Groundwater recharge is the entry of fresh water into the saturated portion of the subsurface part of the hydrologic cycle, the modifier “saturated” indicating that the pressure of the pore water is greater than atmospheric. Briefly stated, recharge is downward flux across the water table. The term “groundwater recharge” can refer either to the multiple interacting processes generating and controlling the flux or to the flux R itself. When referring to flux, R can represent either (1) a value integrated over large areas and long periods of time or (2) a point value, or instantaneous flux density, that varies erratically as well as continuously in time and space. Knowing how R is distributed through space and time is required for understanding the dynamics of groundwater flow and transport in any watershed, aquifer, or selected domain of interest and for understanding heads, flow paths, and discharges to streams, wetlands, and other surface water bodies. Clearly among the most important of hydrologic fluxes, R is also one of the most difficult to measure. Advancements in hydrologic science have proceeded surprisingly in lockstep with advances in determining R .

Eos, Transactions, American Geophysical Union↗
USGS2017

Increased sediment load during a large-scale dam removal changes nearshore subtidal communities

The coastal marine ecosystem near the Elwha River was altered by a massive sediment influx—over 10 million tonnes—during the staged three-year removal of two hydropower dams. We used time series of bathymetry, substrate grain size, remotely sensed turbidity, scuba dive surveys, and towed video observations collected before and during dam removal to assess responses of the nearshore subtidal community (3 m to 17 m depth). Biological changes were primarily driven by sediment deposition and elevated suspended sediment concentrations. Macroalgae, predominantly kelp and foliose red algae, were abundant before dam removal with combined cover levels greater than 50%. Where persistent sediment deposits formed, macroalgae decreased greatly or were eliminated. In areas lacking deposition, macroalgae cover decreased inversely to suspended sediment concentration, suggesting impacts from light reduction or scour. Densities of most invertebrate and fish taxa decreased in areas with persistent sediment deposition; however, bivalve densities increased where mud deposited over sand, and flatfish and Pacific sand lance densities increased where sand deposited over gravel. In areas without sediment deposition, most invertebrate and fish taxa were unaffected by increased suspended sediment or the loss of algae cover associated with it; however, densities of tubeworms and flatfish, and primary cover of sessile invertebrates increased suggesting benefits of increased particulate matter or relaxed competition with macroalgae for space. As dam removal neared completion, we saw evidence of macroalgal recovery that likely owed to water column clearing, indicating that long-term recovery from dam removal effects may be starting. Our results are relevant to future dam removal projects in coastal areas and more generally to understanding effects of increased sedimentation on nearshore subtidal benthic communities.

Washington↗
USGS2008

A multi-disciplinary approach to the removal of emerging contaminants in municipal wastewater treatment plants in New York state (2003-2004)

Across the United States, there is a rapidly growing awareness of the occurrence and the toxicological impacts of natural and synthetic trace compounds in the environment. These trace compounds, referred to as emerging contaminants (ECs), are reported to cause a range of negative impacts in the environment, such as adverse effects on biota in receiving streams and interference with the normal functions of the endocrine system, which controls growth and development in living organisms.

New York↗
USGS2002

Spatial patterns and temporal variability in water quality from City of Albuquerque drinking-water supply wells and piezometer nests, with implications for the ground-water flow system

Water-quality data for 93 City of Albuquerque drinking-water supply wells, 7 deep piezometer nests, and selected additional wells were examined to improve understanding of the regional ground-water system and its response to pumpage. Plots of median values of several major parameters showed discernible water-quality differences both areally and with depth in the aquifer. Areal differences were sufficiently large to enable delineation of five regions of generally distinct water quality, which are consistent with areas of separate recharge defined by previous investigators. Data for deep piezometer nests indicate that water quality generally degrades somewhat with depth, except in areas where local recharge influenced by evapotranspiration or contamination could be affecting shallow water. The orientations of the five water-quality regions indicate that the direction of ground-water flow has historically been primarily north to south. This is generally consistent with maps of predevelopment hydraulic heads, although some areas lack consistency, possibly because of differences in time scales or depths represented by water quality as opposed to hydraulic head. The primary sources of recharge to ground water in the study area appear to be mountain-front recharge along the Sandia Mountains to the east and the Jemez Mountains to the north, seepage from the Rio Grande, and infiltration through Tijeras Arroyo. Elevated concentrations of many chemical constituents in part of the study area appear to be associated with a source of water having large dissolved solids, possibly moving upward from depth. Hydraulic-head data for deep piezometer nests indicate that vertical head gradients differ in direction and magnitude across the study area. Hydraulic-head gradients are downward in the central and western parts of the study area and upward across much of the eastern part, except at the mountain front. Water-quality data for the piezometers indicate that the ground water is not well mixed, even in areas of large vertical gradients. Water levels in most piezometers respond to short-term variations in ground-water withdrawals and to the cumulative effect of long-term withdrawals throughout the area. In most piezometers screened below the water table, water levels respond clearly to seasonal variations in ground-water withdrawals. Water levels decline from about April through July and rise from about September through January. Water levels seem to be declining in most piezometers at a rate less than 1 foot per year. Water-quality data for unfiltered samples collected over a 10-year period from 93 City of Albuquerque drinking-water supply wells were examined for variability and temporal trends in 10 selected parameters. Variability generally was found to be greatest in the Western and Northeast water-quality regions of the study area. For the 10 parameters investigated, temporal trends were found in 5 to 57 wells. Dissolved-solids, sodium, sulfate, chloride, and silica concentrations showed more increasing than decreasing trends; calcium, bicarbonate, and arsenic concentrations, field pH, and water temperature showed more decreasing than increasing trends. The median magnitudes of most of these trends over a 1-year period were not particularly large (generally less than 1.0 milligram per liter), although the magnitudes for a few individual wells were significant. For the 10 parameters investigated, correlations with monthly pumpage volumes were found in 10 to 32 wells. Calcium and sulfate concentrations, field pH, and water temperature showed more positive than negative correlations with monthly pumpage; dissolved-solids, sodium, bicarbonate, chloride, silica, and arsenic concentrations showed more negative than positive correlations.

New Mexico↗
USGS2021

Blue waters, green bottoms: Benthic filamentous algal blooms are an emerging threat to clear lakes worldwide

Nearshore (littoral) habitats of clear lakes with high water quality are increasingly experiencing unexplained proliferations of filamentous algae that grow on submerged surfaces. These filamentous algal blooms (FABs) are sometimes associated with nutrient pollution in groundwater, but complex changes in climate, nutrient transport, lake hydrodynamics, and food web structure may also facilitate this emerging threat to clear lakes. A coordinated effort among members of the public, managers, and scientists is needed to document the occurrence of FABs, to standardize methods for measuring their severity, to adapt existing data collection networks to include nearshore habitats, and to mitigate and reverse this profound structural change in lake ecosystems. Current models of lake eutrophication do not explain this littoral greening. However, a cohesive response to it is essential for protecting some of the world's most valued lakes and the flora, fauna, and ecosystem services they sustain.

BioScience↗
USGS1948

Turbidity as a factor in the decline of Great Lakes fishes with special reference to Lake Erie

Fish live and thrive in water with turbidities that range above 400 p.p.m. and average 200 p.p.m. The waters of the Great Lakes usually are clear except in Lake Erie where the turbidities of the inshore areas averaged 37 p.p.m.; the turbidities of the offshore waters averaged less. Lake Erie waters were no clearer 50 years ago than they are now. In fact, the turbidity values are less now than they were in the earlier years; the annual average of the inshore waters dropped from 44 p.p.m. before 1930 to 32 p.p.m. in 1930 and later, and the April-May values decreased from 72 p.p.m. to 46 p.p.m. Any general decline in the Lake Erie fishes cannot be attributed to increased turbidities. Furthermore, these turbidities averaged well below 100 p.p.m. and, therefore, were too low to affect fishes adversely. Turbidity in the open waters of Lake Erie is primarily the result of wave action induced by winds. River discharge is a minor factor even in the western end of the lake. Other probable factors are plankton, the eastward movement of the water mass, currents, seiches, and possibly bacteria. Wave action is undoubtedly the dominant agency in soil erosion along the shores of all of the Great Lakes. No evidence exists that fluctuations in the abundance of zooplankton, the basic food of fishes, and of the fishes themselves are positively correlated in Lake Erie or that the plankton crop in this lake is ever in short supply. On the contrary, all available evidence shows that Lake Erie is comparatively rich in plankton and that the western end in spite of its turbidity is richer than the eastern. Some factor other than turbidity dominates the basic productivity of western Lake Erie. With respect to turbidity Lake Erie has not become less suitable for fishes. This conclusion also receives support from the study of the fishes themselves. It was demonstrated that the growth of the western Lake Erie fishes compared very favorably with that of fishes in the other Great Lakes or similar waters. It was shown further that the known occurrence of relatively strong year classes in this lake was not consistently associated with low turbidities and conversely that the known low turbidities of the Lake Erie waters were not always accompanied by large year classes. Also, contrary to the “turbidity theory,” certain clean-water varieties, such as the walleye, have increased tremendously in recent years in Lake Erie, whereas the supposedly turbid-water forms, such as the sauger, have decreased in abundance. Reference was made to Doan's work, wherein he attempted to show correlation between turbidity and abundance for several species of Lake Erie fish but failed to do so except for the sauger where he reported a positive correlation. With respect to the productivity of fishes Lake Erie ranks first among the Great Lakes, and the western end in spite of its greater turbidity surpasses the eastern. As judged by certain accepted standards of water suitability, Lake Erie ranks high, and the western end again surpasses the eastern. Finally, it was pointed out that fishes which inhabit the clear waters of the Great Lakes declined as well as those which live in the more turbid waters and that turbidity, therefore, cannot be a factor in the depletion of all Great Lakes fishes. Furthermore, the reduction in abundance repeatedly has been associated with increased fishing intensity. All of the evidence indicates, then, that soil erosion on farms and the turbidity of the water were not major factors, if operative at all, in the decline of Great Lakes fishes and that they did not make Lake Erie unsuitable for fish life.

Transactions of the American Fisheries Society↗
USGS2006

Cross-shore velocity shear, eddies and heterogeneity in water column properties over fringing coral reefs: West Maui, Hawaii

A multi-day hydrographic survey cruise was conducted to acquire spatially extensive, but temporally limited, high-resolution, three-dimensional measurements of currents, temperature, salinity and turbidity off West Maui in the summer of 2003 to better understand coastal dynamics along a complex island shoreline with coral reefs. These data complement long-term, high-resolution tide, wave, current, temperature, salinity and turbidity measurements made at a number of fixed locations in the study area starting in 2001. Analyses of these hydrographic data, in conjunction with numerous field observations, evoke the following conceptual model of water and turbidity flux along West Maui. Wave- and wind-driven flows appear to be the primary control on flow over shallower portions of the reefs while tidal and subtidal currents dominate flow over the outer portions of the reefs and insular shelf. When the direction of these flows counter one another, which is quite common, they cause a zone of cross-shore horizontal shear and often form a front, with turbid, lower-salinity water inshore of the front and clear, higher-salinity water offshore of the front. It is not clear whether these zones of high shear and fronts are the cause or the result of the location of the fore reef, but they appear to be correlated alongshore over relatively large horizontal distances (orders of kilometers). When two flows converge or when a single flow is bathymetrically steered, eddies can be generated that, in the absence of large ocean surface waves, tend to accumulate material. Areas of higher turbidity and lower salinity tend to correlate with regions of poor coral health or the absence of well-developed reefs, suggesting that the oceanographic processes that concentrate and/or transport nutrients, contaminants, low-salinity water or suspended sediment might strongly influence coral reef ecosystem health and sustainability.

Continental Shelf Research↗
USGS2016

Selected techniques for monitoring water movement through unsaturated alluvium during managed aquifer recharge

Managed aquifer recharge is used to augment natural recharge to aquifers. It can be used to replenish aquifers depleted by pumping or to store water during wetter years for withdrawal during drier years. Infiltration from ponds is a commonly used, inexpensive approach for managed aquifer recharge. At some managed aquifer-recharge sites, the time when infiltrated water arrives at the water table is not always clearly shown by water-level data. As part of site characterization and operation, it can be desirable to track downward movement of infiltrated water through the unsaturated zone to identify when it arrives at the water table.

California↗
USGS1998

Oyster resource zones of the Barataria and Terrebonne estuaries of Louisiana

A 1:100,000 scale map delineating the subtidal oyster resource zones within the Barataria and Terrebonne estuaries was developed. Strategies to accomplish the task included interviews with Louisiana oystermen and state biologists to develop a draft map, field sampling to document oyster (Crassostrea virginica), Dermo (Perkinsus marinus), and oyster drill (Stramonita haemastoma) abundances, use of historical salinity data to aid in map verification, and public meetings to allow comment on a draft before final map preparation. Four oyster resource zones were delineated on the final map: a dry zone where subtidal oysters may be found when salinities increase, a wet zone where subtidal oysters may be found when salinities are suppressed, a wet-dry zone where subtidal oysters may be consistently found due to favorable salinities, and a high-salinity zone where natural oyster populations are predominantly found in intertidal and shallow waters. The dry zone is largely coincident with the brackish-marsh habitat, with some intermediate-type marsh. The wet-dry zone is found at the interface of the brackish and saline marshes, but extends further seaward than up-estuary. The wet zone and the high salinity zones are areas of mostly open water fringed by salt marshes. The dry zone encompasses 91,775 hectares, of which 48,788 hectares are water (53%). The wet zone encompasses 83,525 hectares, of which 66,958 hectares are water (80%). The wet-dry zone encompasses 171,893 hectares, of which 104,733 hectares are water (61%). The high salinity zone encompasses 125,705 hectares, of which 113,369 hectares are water (90%). There is a clear trend of increasing water habitat in the four zones over the past 30 years, and oysters are now cultivated on bottoms that were once marsh. The map should be useful in managing the effects upon oysters of freshwater diversions into the estuaries. It provides a pre-diversion record of the location of oyster resource zones and should prove helpful in the seaward relocation of oysters leases.

Journal of Shellfish Research↗
USGS2006

Synthesis of monthly and annual streamflow records (water years 1950-2003) for Big Sandy, Clear, Peoples, and Beaver Creeks in the Milk River basin, Montana

To address concerns expressed by the State of Montana about the apportionment of water in the St. Mary and Milk River basins between Canada and the United States, the International Joint Commission requested information from the United States government about water that originates in the United States but does not cross the border into Canada. In response to this request, the U.S. Geological Survey synthesized monthly and annual streamflow records for Big Sandy, Clear, Peoples, and Beaver Creeks, all of which are in the Milk River basin in Montana, for water years 1950-2003. This report presents the synthesized values of monthly and annual streamflow for Big Sandy, Clear, Peoples, and Beaver Creeks in Montana. Synthesized values were derived from recorded and estimated streamflows. Statistics, including long-term medians and averages and flows for various exceedance probabilities, were computed from the synthesized data. Beaver Creek had the largest median annual discharge (19,490 acre-feet), and Clear Creek had the smallest median annual discharge (6,680 acre-feet). Big Sandy Creek, the stream with the largest drainage area, had the second smallest median annual discharge (9,640 acre-feet), whereas Peoples Creek, the stream with the second smallest drainage area, had the second largest median annual discharge (11,700 acre-feet). The combined median annual discharge for the four streams was 45,400 acre-feet. The largest combined median monthly discharge for the four creeks was 6,930 acre-feet in March, and the smallest combined median monthly discharge was 48 acre-feet in January. The combined median monthly values were substantially smaller than the average monthly values. Overall, synthesized flow records for the four creeks are considered to be reasonable given the prevailing climatic conditions in the region during the 1950-2003 base period. Individual estimates of monthly streamflow may have large errors, however. Linear regression was used to relate logarithms of combined annual streamflow to water years 1950-2003. The results of the regression analysis indicated a significant downward trend (regression line slope was -0.00977) for combined annual streamflow. A regression analysis using data from 1956-2003 indicated a slight, but not significant, downward trend for combined annual streamflow.

Scientific Investigations Report↗
USGS2006

Solute sources in stream water during consecutive fall storms in a northern hardwood forest watershed: A combined hydrological, chemical and isotopic approach

Understanding the effects of climate change including precipitation patterns has important implications for evaluating the biogeochemical responses of watersheds. We focused on four storms in late summer and early fall that occurred after an exceptionally dry period in 2002. We analyzed not only the influence of these storms on episodic chemistry and the role of different water sources in affecting surface water chemistry, but also the relative contributions of these storms to annual biogeochemical mass balances. The study site was a well studied 135-ha watershed in the Adirondack Park of New York State (USA). Our analyses integrated measurements on hydrology, solute chemistry and the isotopic composition of NO 3 − (δ 15 N and δ 18 O) and SO 4 2− (δ 34 S and δ 18 O) to evaluate how these storms affected surface water chemistry. Precipitation amounts varied among the storms (Storm 1: Sept. 14–18, 18.5 mm; Storm 2: Sept. 21–24, 33 mm; Storm 3: Sept. 27–29, 42.9 mm; Storm 4: Oct. 16–21, 67.6 mm). Among the four storms, there was an increase in water yields from 2 to 14%. These water yields were much less than in studies of storms in previous years at this same watershed when antecedent moisture conditions were higher. In the current study, early storms resulted in relatively small changes in water chemistry. With progressive storms the changes in water chemistry became more marked with particularly major changes in C b (sum of base cations), Si, NO 3 − , and SO 4 2− , DOC and pH. Analyses of the relationships between Si, DOC, discharge and water table height clearly indicated that there was a decrease in ground water contributions (i.e., lower Si concentrations and higher DOC concentrations) as the watershed wetness increased with storm succession. The marked changes in chemistry were also reflected in changes in the isotopic composition of SO 4 2− and NO 3 − . There was a strong inverse relationship between SO 4 2− concentrations and δ 34 S values suggesting the importance of S biogeochemical redox processes in contributing to SO 4 2− export. The isotopic composition of NO 3 − in stream water indicated that this N had been microbially processed. Linkages between SO 4 2− and DOC concentrations suggest that wetlands were major sources of these solutes to drainage waters while the chemical and isotopic response of NO 3 − suggested that upland sources were more important. Although these late summer and fall storms did not play a major role in the overall annual mass balances of solutes for this watershed, these events had distinctive chemistry including depressed pH and therefore have important consequences to watershed processes such as episodic acidification, and the linkage of these processes to climate change.

Biogeochemistry↗
USGS1964

Water resources of the English River, Old Mans Creek, and Clear Creek basins in Iowa

The surface and ground water resources of a 991 square mile area comprising the drainage basins of English River, Old Mans Creek and Clear Creek are presented. These basins lie to the west and southwest of Iowa City, Iowa, and all three streams are tributary to the Iowa River. The area is comprised of rolling uplands with relatively broad valleys and is devoted mainly to agriculture and livestock farming. In general, the surface water use is adversely affected by the high variability of flows and particularly by the critically small minimum flows. Augmentation of the minimum flows by means of storage reservoirs is possible but may be uneconomical in the broad valleys which require a high area to volume ratio. The surface water supply is presented in the form of tables and graphs which show information on maximum and minimum flows, mean flow, duration of flow, frequency of low flow and flood flow and storage requirements. Low-flow discharge. profiles for the English River and South Fork English River derived from measurements at partial record and supplementary sites are also shown. Ground water is available from shallow wells in nearly all of the area; however, the wells vary widely in productivity and reliability during a drouth. Potentially excellent aquifers may be found in the alluvium which underlies the valleys since similar areas along the lower Iowa River basin have produced yield up to 100 gallons per minute. However, the best and most reliable source of good ground water is the Jordan Sandstone. This aquifer varies from 1,375 feet below ground level in the eastern part of the area to 2,200 feet below ground level at the western end of the area. It is capable of supplying as much as 1,000 gallons per minute to individual wells. Its location is shown in the report by means of map contours referenced to mean sea level.

Iowa↗
USGS2000

Evaluation of biological data, Guanella Pass Area, Clear Creek and Park Counties, Colorado, water years 1995-97

Macroinvertebrate and algal community samples were collected during a 3-year period at sites located near Guanella Pass, Colorado, to provide baseline characterization data. Water-quality sampling and habitat evaluations were used to aid in the interpretation of the biological data. The study was part of an environmental investigation for a proposed roadway reconstruction project on Guanella Pass. Discharge was strongly affected by snowmelt during May–July. Habitat scores were optimal (147–199), as determined by U.S. Environmental Protection Agency Rapid Bioassessment Protocol methods. Generally, low median concentrations of nitrogen and phosphorus (less than 0.02 milligram per liter) were detected at all sites. The water temperatures ranged from 0.4 to 11.2 degrees Celsius. The average pH for all sites was neutral, and specific conductivities were dilute (less than 160 microsiemens per centimeter at 25 degrees Celsius). The median suspended-sediment concentration was less than 20 milligrams per liter at all sites. During the study, 100 macroinvertebrate taxa were identified. The dominant taxonomic groups of macroinvertebrates were Diptera (true flies), Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies). Macroinvertebrate density ranged from 6.6 to 4,300 organisms per square meter at sampled sites. Shannon-Weaver diversity values for the macroinvertebrate samples ranged from 1.6 to 4.5. Collector-gatherers dominated the functional feeding groups at most sites. Average abundance of Ephemeroptera, Plecoptera, and Trichoptera (EPT) was 56.7 percent; EPT:Chironomidae ratios were greater than 2:1 for every site except during water years 1996 and 1997. Chironomids were greater than EPT at four sites in water year 1996 and at one site in water year 1997. The percentage of macroinvertebrate community similarity between site pairs varied from 0 to 80 percent. The number of algal taxa identified was 280. The dominant algal divisions, in terms of density, were Cyanophyta (blue-green algae), Chrysophyta (diatoms), Chlorophyta (green algae), Rhodophyta (red algae), and Euglenophyta (euglenoids). In general, diatom biovolumes dominated the algal assemblage, followed by blue-green algae, green algae, red algae, and euglenoids. Algal densities ranged from 3.1 X 10 2 to more than 4.7 X 10 6 cells per square centimeter, and algal biovolume ranged from 2.3 X 10 4 to 4.6 X 10 9 cells per cubic centimeter. Diversity values for diatoms ranged from 1.5 to 4.9. The pollution tolerance index (PTI) for diatoms ranged from 1.8 to 3.0. Sensitive diatoms were present at each site and ranged from 21 to 97 percent. The percentage of motile diatoms ranged from 0 to 13 percent. The presence of acid-tolerant diatoms ranged from less than 0.5 to greater than 20 percent. The percentage of community similarity between site pairs ranged from 1 to 97 percent. Overall, the biotic metrics that were evaluated during this study indicate that the macroinvertebrate and algal communities in the streams on Guanella Pass are not degraded by the existing road. Erosion may cause some localized effects but may not affect the overall health of the whole stream system. The degraded condition of Geneva Creek probably is due to natural effects as opposed to road effects. Although upper South Clear Creek, upstream from Naylor Creek, is located downstream from several sources of road runoff, the biological community at this site does not seem to be negatively affected.

Colorado↗
USGS2017

Bathymetry of Clear Creek Reservoir, Chaffee County, Colorado, 2016

To better characterize the water supply capacity of Clear Creek Reservoir, Chaffee County, Colorado, the U.S. Geological Survey, in cooperation with the Pueblo Board of Water Works and Colorado Mountain College, carried out a bathymetry survey of Clear Creek Reservoir. A bathymetry map of the reservoir is presented here with the elevation-surface area and the elevation-volume relations. The bathymetry survey was carried out June 6–9, 2016, using a man-operated boat-mounted, multibeam echo sounder integrated with a Global Positioning System and a terrestrial survey using real-time kinematic Global Navigation Satellite Systems. The two collected datasets were merged and imported into geographic information system software. The equipment and methods used in this study allowed water-resource managers to maintain typical reservoir operations, eliminating the need to empty the reservoir to carry out the survey.

Colorado↗
USGS1975

Fossil fishes from the Pliocene or Pleistocene Cache Formation, Lake County, California

The remains of fossil fishes comprising three species were found in the Cache Formation in Lake County, Calif. The rocks containing the fossils are considered to be late Pliocene or early Pleistocene. The species are all freshwater and primarily quiet-water types that now live in Clear Lake and the waters of the surrounding area, suggesting continuity between the present lake and a lake represented by the rocks of the Cache Formation.

California↗
USGS2015

Hexavalent and total chromium at low reporting concentrations in source-water aquifers and surface waters used for public supply in Illinois, 2013

On the basis of their recent review of the human health effects of hexavalent chromium [Cr(VI)] in public drinking water, the U.S. Environmental Protection Agency is considering the need for Federal regulation of Cr(VI). Presently, only total chromium is regulated, at a Maximum Contaminant Level (MCL) of 100 micrograms per liter (µg/L). The occurrence of Cr(VI) in groundwater and surface waters generally is attributed to industrial sources, but can be of natural origin. California’s recently established MCL for Cr(VI) of 10 µg/L illustrates the drinking-water concerns associated with Cr(VI). To improve understanding of the possible impact of a Cr(VI)-specific standard that approximates the California level on the management of Illinois’ public drinking water, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, assessed the occurrence and distribution of Cr(VI) in the State’s public-water supplies. During 2013, untreated water samples were collected to be analyzed for Cr(VI) and total chromium [Cr(T)] at 119 water-supply wells and 32 surface-water intakes; also, 32 treated surface-water samples were collected near the point of treatment and 32 near the furthest point of distribution. Public-supply sample sites were selected by a stratified random method. Samples typically were analyzed within 24 hours of collection at reporting limits of 0.02 µg/L for Cr(VI) and 0.1 µg/L for Cr(T). The occurrence of Cr(VI) was compared with selected geophysical, physical, and sampling factors that might more fully explain its distribution and magnitude of concentrations. The maximum concentration of Cr(VI) in groundwater was 2.1 µg/L. Maximum concentrations in untreated and treated surface water were 0.29 µg/L and 2.4 µg/L, respectively. All sample concentrations were below the California MCL; only 35 percent were below that State’s non-enforceable public health goal of 0.02 of µg/L. Cr(VI) was undetected in 43 percent of untreated groundwater samples, with a median of 0.06 µg/L when detected. All but two (94 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.09 µg/L, whereas in treated (tap and distributed) water the median was 0.20 µg/L. Surface waters treated with lime for softening typically had the greatest Cr(VI) concentrations (maximum, 2.4 µg/L; median, 1.2 µg/L). The maximum concentration of Cr(T) in groundwater was 1.8 µg/L. Maximum concentrations in untreated and treated surface water were 1.8 µg/L and 2.5 µg/L, respectively. All sample concentrations were below the Federal MCL. Total chromium was detected in 65 percent of untreated groundwater samples, with a median of 0.40 µg/L, when detected. All but one (97 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.40 µg/L, whereas in treated (tap and distributed) water the median was 0.30 µg/L. As with Cr(VI), surface waters treated with lime typically had the greatest Cr(T) concentrations. Examination of factors that might account for or be associated with the occurrence of Cr(VI) in public-supply source waters found few clearly evident factors. Associations in frequencies of occurrence and range of concentrations indicate that surface waters and groundwaters of shallow, unconsolidated, unconfined aquifers, particularly alluvial aquifers, are possibly most commonly affected by anthropogenic sources of Cr(VI). Groundwaters of deep (greater than 500 feet) bedrock aquifers, particularly the Cambrian-Ordovician aquifer system, are possibly most commonly affected by geologic sources of Cr(VI). Additional study, with supporting geologic and geochemical data that were not collected in this study, would be necessary to verify these associations. There was a weak positive relation (ρ = 0.23) between concentrations of Cr(VI) and Cr(T) in untreated water samples, with a much stronger positive relation (ρ = 0.86 and ρ = 0.90, respectively) in samples collected soon after treatment and near the endpoint of distribution. The stronger relation and greater similarity between Cr(VI) and Cr(T) concentrations in treated water samples indicate that Cr(VI) represents a greater proportion of the measured concentrations of Cr(T) in treated waters than in untreated waters. The analysis of spikes and other quality-assurance samples indicate uncertainties associated with obtaining or confirming consistently accurate analytical results for Cr(VI) at near the applied reporting limit of 0.02 µg/L.

Illinois↗