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Streamflow gains and losses along San Francisquito Creek and characterization of surface-water and ground-water quality, southern San Mateo and northern Santa Clara counties, California, 1996-97

San Francisquito Creek is an important source of recharge to the 22-square-mile San Francisquito Creek alluvial fan ground-water subbasin in the southern San Mateo and northern Santa Clara Counties of California. Ground water supplies as much as 20 percent of the water to some area communities. Local residents are concerned that infiltration and consequently ground-water recharge would be reduced if additional flood-control measures are implemented along San Francisquito Creek. To improve the understanding of the surface-water/ground-water interaction between San Francisquito Creek and the San Francisquito Creek alluvial fan, the U.S. Geological Survey (USGS) estimated streamflow gains and losses along San Francisquito Creek and determined the chemical quality and isotopic composition of surface and ground water in the study area.Streamflow was measured at 13 temporary streamflow-measurement stations to determine streamflow gains and losses along a 8.4-mile section of San Francisquito Creek. A series of five seepage runs between April 1996 and May 1997 indicate that losses in San Francisquito Creek were negligible until it crossed the Pulgas Fault at Sand Hill Road. Streamflow losses increased between Sand Hill Road and Middlefield Road where the alluvial deposits are predominantly coarse-grained and the water table is below the bottom of the channel. The greatest streamflow losses were measured along a 1.8-mile section of the creek between the San Mateo Drive bike bridge and Middlefield Road; average losses between San Mateo Drive and Alma Street and from there to Middlefield Road were 3.1 and 2.5 acre-feet per day, respectively.Downstream from Middlefield Road, streamflow gains and losses owing to seepage may be masked by urban runoff, changes in bank storage, and tidal effects from San Francisco Bay. Streamflow gains measured between Middlefield Road and the 1200 block of Woodland Avenue may be attributable to urban runoff and (or) ground-water inflow. Water-level measurements from nearby wells indicate that the regional water table may coincide with the channel bottom along this reach of San Francisquito Creek, particularly during the winter and early spring when water levels usually reach their maximum. Streamflow losses resumed below the 1200 block of Woodland Avenue, extending downstream to Newell Road. Discharge from a large storm drain between Newell Road and East Bayshore Road may account for the streamflow gains measured between these sites. Streamflow gains were measured between East Bayshore Road and the Palo Alto Municipal Golf Course, but this reach is difficult to characterize because of the probable influence of high tides.Estimated average streamflow losses totaled approximately 1,050 acre-feet per year for the reaches between USGS stream gage 11164500 at Stanford University (upstream of Junipero Serra Boulevard) and the Palo Alto Municipal Golf Course, including approximately 595 acre-feet per year for the 1.8-mile section between San Mateo Drive and Middlefield Road. Approximately 58 percent, or 550 acre-feet, of the total estimated average annual recharge from San Francisquito Creek occurs between the San Mateo Drive and Middlefield Road sites.The chemical composition of San Francisquito Creek water varies as a function of seasonal changes in hydrologic conditions. Measurements of specific conductance indicate that during dry weather and low flow, the dissolved-solids concentrations tends to be high, and during wet weather, the concentration tends to be low owing to dilution by surface water. Compared with water samples from upstream sites at USGS stream gage 11164500 and San Mateo Drive, the samples from the downstream sites at Alma Street and Woodland Avenue had low specific conductance; low concentrations of magnesium, sodium, sulfate, chloride, boron, and total dissolved solids; high nutrient concentrations; and light isotopic compositions indicating that urban runoff constitutes most of the streamflow

Water-Resources Investigations Report

Maps showing distribution of dissolved solids and dominant chemical type in ground water, Basin and Range Province, Southern California

This map report is one of a series of geologic and hydrologic maps of States in the Basin and Range Province. These map reports contain information on ground-water hydrology, ground-water quality, surface distribution of selected rock types, data on tectonic conditions, areal geophysical data, Pleistocene lakes and marshes and natural resources. This information is the basis for a summary report that characterizes the Basin and Range Province. The geologic and hydrologic characterization will be used to evaluate the Province for prospective regions for further study relative to isolation of high-level radioactive waste. (Bedinger, Sargent and Reed, 1984).

California

Maps showing distribution of dissolved solids and dominant chemical type in ground water, Basin and Range Province, New Mexico

This map report is one of a series of geologic and hydrologic maps of States in the Basin and Range Province. These map reports contain information on ground-water hydrology, ground-water quality, surface distribution of selected rock types, data on tectonic conditions, areal geophysical data, Pleistocene lakes and marshes and natural resources. This information is the basis for a summary report that characterizes the Basin and Range Province. The geologic and hydrologic characterization will be used to evaluate the Province for prospective regions for further study relative to isolation of high-level radioactive waste. (Bedinger, Sargent and Reed, 1984).

New Mexico

Chemicals of emerging concern in water and bottom sediment in the Great Lakes Basin, 2012: collection methods, analytical methods, quality assurance, and study data

In synoptic surveys of surface-water quality across the United States, a large group of organic chemicals associated with agricultural, household, and industrial waste have been detected. These chemicals are referred to collectively as chemicals of emerging concern (CECs) and include prescription drugs and antibiotics, over-the-counter medications, reproductive hormones, personal-care products, detergent metabolites, and flame retardants. The U.S. Geological Survey (USGS) collaborated with the U.S. Fish and Wildlife Service and the U.S. Environmental Protection Agency on a study to identify the presence of CECs in water and bottom-sediment samples collected during 2012 at 66 sites throughout the Great Lakes Basin. The 2012 effort is part of a long-term study that was initiated in 2010. The purposes of this report are to document the collection and analytical methods, provide the quality-assurance data and analyses, and provide the water and bottom-sediment data for this study of CECs in the Great Lakes Basin for 2012. A previous report documents data collected during 2010 and 2011. The methods used for chemical analyses were identical between the 2010–11 and 2012 studies, with the exception that a method to determine nontarget chemicals was used during 2010–11. The data from this study are published as a USGS Data Series Report to ensure adequate documentation of the original methods and provide a citable source for study data. This report contains no interpretations of the study data. The chemical data are as reported by the laboratory and have not been censored or adjusted unless otherwise noted. Field measurements were recorded and samples were collected in April and May and in September 2012, by U.S. Geological Survey, U.S. Fish and Wildlife Service, and U.S. Environmental Protection Agency personnel. Study sites included tributaries to the Great Lakes located near Duluth, Minnesota; King, Wisconsin; Green Bay, Wis.; Detroit, Michigan; Monroe, Mich.; Toledo, Ohio, and Rochester, New York. Water and bottom-sediment samples were analyzed at the USGS National Water Quality Laboratory in Denver, Colorado, for a broad suite of CECs. During this 2012 study, 140 environmental and 8 field duplicate samples of surface water and wastewater effluent, 1 field blank water sample, and 5 field spike water samples were collected or prepared. Water samples were analyzed at the USGS National Water Quality Laboratory using laboratory schedule 4433 for wastewater indicators, research method 8244 for pharmaceuticals, and laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A. For wastewater indicators in unfiltered water, 61 of the 68 chemicals analyzed using laboratory schedule 4433 had detectable concentrations ranging from 0.002 to 64.4 micrograms per liter. Thirty-eight of the 48 chemicals analyzed using research method 8244 for pharmaceuticals in unfiltered water had detectable concentrations ranging from 0.002 to 3.32 micrograms per liter. Twelve of the 20 chemicals analyzed using laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A in unfiltered water had detectable concentrations ranging from 0.43 to 120,000 nanograms per liter. During this study, 53 environmental samples, 4 field duplicate samples, and 8 field spike samples of bottom sediment and laboratory matrix-spike samples were analyzed for a wide variety of CECs at the USGS National Water Quality Laboratory using laboratory schedule 5433 for wastewater indicators; research method 6434 for steroid hormones, sterols, and bisphenol A; and research method 9008 for human-use pharmaceuticals and antidepressants. Forty of the 57 chemicals analyzed using laboratory schedule 5433 had detectable concentrations ranging from 1 to 49,000 micrograms per kilogram. Fourteen of the 20 chemicals analyzed using research method 6434 had detectable concentrations ranging from 0.04 to 24,940 nanograms per gram. Ten of the 20 chemicals analyzed using research method 9008 had detectable concentrations ranging from 0.59 to 197.5 micrograms per kilogram. Five of the 11 chemicals analyzed using research method 9008 had detectable concentrations ranging from 1.16 to 25.0 micrograms per kilogram.

Great Lakes Basin

Water resources of Monroe County, New York, water years 1994-96, with emphasis on water quality in the Irondequoit Creek basin: Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek drains 169 square miles in the eastern part of Monroe County. Nutrients transported by Irondequoit Creek to Irondequoit Bay on Lake Ontario have contributed to the eutrophication of the Bay. Sewage-treatment-plant effluent, a major source of nutrients to the creek and its tributaries, was eliminated from the basin in 1979 by diversion to a regional wastewater-treatment facility, but sediment and contaminants from nonpoint sources continue to enter the creek and Irondequoit Bay. This report analyzes data from five surface-water monitoring sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek at Pittsford, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard. It is the third in a series of reports that present interpretive analyses of the hydrologic data collected in Monroe County since 1984. Also included are data from a site on Northrup Creek, which drains a 23.5-square-mile basin west of the Genesee River in western Monroe County, to provide information on surface-water quality in a stream west of the Genesee River and on loads of nutrients delivered to Long Pond, a small eutrophic embayment of Lake Ontario, and data from the Genesee River for comparison of historical water-quality conditions with 1994-96 conditions. Water-level and water-quality data from nine observation wells in Ellison Park, and atmospheric-deposition data from Mendon Ponds, also are included. Average annual yields of chemical constituents from atmospheric deposition for 1994-96 were generally similar to those for the previous 10 years (1984-93), except for dissolved sodium, dissolved potassium, total phosphorus, and orthophosphate, which ranged from 42 percent (dissolved sodium) to 275 percent (dissolved potassium) greater than during 1984-93, and dissolved sulfate and ammonia, which were about 30 percent less than in 1984-93. Loads of all nutrients deposited in the Irondequoit Creek basin from atmospheric sources during water years 1994-96 exceeded those removed by Irondequoit Creek at Blossom Road—ammonia by 5,600 percent, orthophosphate by 2,500 percent, ammonia + organic nitrogen by 350 percent, total phosphorus by 300 percent and nitrite + nitrate by 140 percent. Average yields of dissolved chloride and dissolved sulfate from atmospheric deposition were much less than those transported in streamflow—yields of dissolved chloride from atmospheric sources were only 1.9 percent, and yields of sulfate were only 9.2 percent, of those transported in streamflow at Blossom Road. Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends from the beginning of their period of record through 1996. The constituents that showed the greatest number of statistically significant trends were dissolved chloride, ammonia, and ammonia + organic nitrogen. Dissolved chloride showed an upward trend at Blossom Road, Allen Creek, and Empire Boulevard and a downward trend at Railroad Mills. Ammonia showed downward trends at Allen Creek, Blossom Road and Railroad Mills. Ammonia + organic nitrogen showed a downward trend at Allen Creek, Blossom Road, and Empire Boulevard. Nitrite + nitrate showed a downward trend at Allen Creek, and orthophosphate showed an upward trend at that site. Turbidity and total suspended solids showed a downward trend at Empire Boulevard. Neither total phosphorus nor volatile suspended solids showed statistically significant trends in concentration at any of the Irondequoit basin sites. Northrup Creek showed a downward trend in total suspended solids and ammonia + organic nitrogen, and an upward trend in dissolved chloride. The Genesee River showed a downward trend in ammonia + organic nitrogen and chloride, and an upward trend in orthophosphate. Most constituents for the 1994-96 water years showed lower average yields at Blossom Road than for the 1989-93 water years, but dissolved chloride showed higher yields for the 1994-96 water years at all sites except Blossom Road. Ammonia + organic nitrogen and total phosphorus showed a decrease in yield at all sites after 1993, and nitrite + nitrate showed slightly higher yields for 1994-96 at the upstream, predominantly rural sites, and lower yields at the downstream, more urban sites, than during 1989-93. The trends and changes in surface-water quality after 1993 can be attributed to several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) streamflow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1994-96 were in the normal range (75th to 25th percentile), although Allen Creek showed a statistically significant downward trend in monthly mean streamflow over the 1984-96 water years.

New York

Biological data for water in Lake Powell and from Glen Canyon Dam releases, Utah and Arizona, 1990–2009

Biological samples from various locations on Lake Powell and in the Colorado River in the tail water downstream of Glen Canyon Dam were collected by the Bureau of Reclamation and U.S. Geological Survey from December 1990 through December 2009 as part of a long-term water-quality monitoring program that began in 1964. These samples consisted of discrete (1-m deep) chlorophyll samples, discrete (1-m deep) wholewater phytoplankton samples, and 30-m vertically composited zooplankton samples filtered through an 80-µm plankton net. Chlorophyll concentration was determined by acetone extraction followed by trichromatic spectroscopy on 2,051 samples. Phytoplankton analysis consisted of identification to the genus or species level, enumeration, and estimation of biovolume on 1,397 samples. Phytoplankton analysis identified 646 different phytoplankton taxa. Zooplankton analysis consisted of identification to the genus or species level, enumeration, and estimation of biomass from 1,898 samples. Zooplankton analysis identified 114 different zooplankton taxa. The results of these analyses are presented in this report. From this record, further interpretation may be made concerning primary and secondary production in Lake Powell. These data provide a linkage between physical and chemical water-quality data and fisheries investigations in Lake Powell. They also provide information regarding the export of biological material from Glen Canyon Dam.

Utah, Arizona

Data compilation for assessing sediment and toxic chemical loads from the Green River to the lower Duwamish Waterway, Washington

Between February and June 2013, the U.S. Geological Survey collected representative samples of whole water, suspended sediment, and (or) bed sediment from a single strategically located site on the Duwamish River, Washington, during seven periods of different flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including polycyclic aromatic hydrocarbons and other semivolatile compounds, polychlorinated biphenyl Aroclors and the 209 congeners, metals, dioxins/furans, volatile organic compounds, pesticides, butyltins, hexavalent chromium, and total organic carbon. Chemical concentrations associated with bulk bed sediment (<2 mm) and fine bed sediment (<62.5 μm) fractions were compared to chemical concentrations associated with suspended sediment. Bulk bed sediment concentrations generally were lower than fine bed sediment and suspended-sediment concentrations. Concurrent with the chemistry sampling, additional parameters were measured, including instantaneous river discharge, suspended-sediment concentration, sediment particle-size distribution, and general water-quality parameters. From these data, estimates of instantaneous sediment and chemical loads from the Green River to the Lower Duwamish Waterway were calculated.

Washington

Effects of an extreme flood on trace elements in river water—From urban stream to major river basin

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the South Platte River, Colorado, USA. Weekly time-series water samples were collected from 3 urban source waters (municipal tap water, streamwater, and wastewater treatment facility effluent) under normal-flow and flood conditions. In addition, water samples were collected during the flood at 5 locations along the South Platte River and from 7 tributaries along the Colorado Front Range. Samples were analyzed for 54 major and trace elements. Specific chemical tracers, representing different natural and anthropogenic sources and geochemical behaviors, were used to compare streamwater composition before and during the flood. The results differentiate hydrological processes that affected water quality: (1) in the upper watershed, runoff diluted most dissolved constituents, (2) in the urban corridor and lower watershed, runoff mobilized soluble constituents accumulated on the landscape and contributed to stream loading, and (3) flood-induced groundwater discharge mobilized soluble constituents stored in the vadose zone.

Colorado

Chemical analyses of surface waters in Colorado, October 1959 to September 1962

Data presented herein are records of water quality for the period October 1959 to September 1962 for the sampling sites shown below and on the enclosed map. The data are preliminary and subject to revision. Final records are published in the annual series of Geological Survey Water-Supply Papers entitled "Quality of Surface Waters of the United States, " which can be obtained from the Superintendent of Documents, U. S. Government Printing Office, Washington, D. C. 20242.

Colorado

Water Resources Data for Massachusetts and Rhode Island, 1998

INTRODUCTION The Water Resources Division of the U.S. Geological Survey, in cooperation with State agencies, obtains a large amount of data pertaining to the water resources of Massachusetts and Rhode Island each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the States. To make these data readily available to interested parties outside the Geological Survey, the data are published annually in this report series entitled 'Water Resources Data-Massachusetts and Rhode Island.' Hydrologic data are also available through the Massachusetts-Rhode Island District Home Page on the world-wide web (http://ma.water.usgs.gov). Historical data and real-time data (for sites equipped with satellite gageheight telemeter) are also available. The home page also contains a link to the U.S. Geological Survey National Home Page where streamflow data from locations throughout the United States can be retrieved. This report series includes records of stage, discharge, and water quality of streams; contents of lakes and reservoirs; and water levels of ground-water wells. This volume contains discharge records at 93 gaging stations; monthend contents of 4 lakes and reservoirs; water quality at 22 gaging stations; and water levels for 139 observation wells. Locations of these sites are shown in figures 1 and 2. Miscellaneous hydrologic data were collected at various sites that were not involved in the systematic data-collection program and are published as miscellaneous discharge measurements. The data in this report represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State and Federal agencies in Massachusetts and Rhode Island. This series of annual reports for Massachusetts and Rhode Island began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report format was changed to present, in one volume, data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to introduction of this series and for several water years concurrent with it, water-resources data for Massachusetts and Rhode Island were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage and on lake or reservoir contents and stage, through September 1960, were published annually under the title 'Surface-Water Supply of the United States, Parts 1A and 1B.' For the 1961 through 1970 water years, the data were published in two 5-year reports. Data on chemical quality, temperature, and suspended sediment for the 1941 through 1970 water years were published annually under the title 'Quality of Surface Waters of the United States,' and water levels for the 1939 through 1974 water years were published under the title 'Ground-Water Levels in the United States.' The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from U.S. Geological Survey, Information Services, Box 25286, Denver Federal Center, Box 25425, Denver, CO 80225-0286. Publications similar to this report are published annually by the Geological Survey for all States. These official Survey reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as 'U.S. Geological Survey Water-Data Report MARI-98-1.' For archiving and general distribution, the reports for 1971-74 water years also are identified as water-data reports. These water-data reports are for sale in paper copy or in microfiche by the National Technical Information Service, U.S. Department of Comme

Water Data Report

Water Resources Data Massachusetts and Rhode Island Water Year 1999

INTRODUCTION The Water Resources Division of the U.S. Geological Survey, in cooperation with State agencies, obtains a large amount of data pertaining to the water resources of Massachusetts and Rhode Island each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the States. To make these data readily available to interested parties outside the Geological Survey, the data are published annually in this report series entitled 'Water Resources Data-Massachusetts and Rhode Island.' Hydrologic data are also available through the Massachusetts-Rhode Island District Home Page on the world-wide web (http://ma.water.usgs.gov). Historical data and real-time data (for sites equipped with satellite gage-height telemeter) are also available. The home page also contains a link to the U.S. Geological Survey National Home Page where streamflow data from locations throughout the United States can be retrieved. This report series includes records of stage, discharge, and water quality of streams; contents of lakes and reservoirs; water levels of ground-water wells; and water quality of ground-water wells. This volume contains discharge records at 90 gaging stations; stage records at 2 gaging stations; monthend contents of 4 lakes and reservoirs; water quality at 31 gaging stations; water quality at 27 observation wells; and water levels for 139 observation wells. Locations of these sites are shown in figures 1 and 2. Short-term water-quality data were collected at 21 gaging stations and 27 observation wells and are shown in figure 3. Miscellaneous hydrologic data were collected at various sites that were not involved in the systematic data-collection program and are published as miscellaneous discharge measurements. The data in this report represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State and Federal agencies in Massachusetts and Rhode Island. This series of annual reports for Massachusetts and Rhode Island began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report format was changed to present, in one volume, data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to introduction of this series and for several water years concurrent with it, water-resources data for Massachusetts and Rhode Island were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage and on lake or reservoir contents and stage, through September 1960, were published annually under the title 'Surface-Water Supply of the United States, Parts 1A and 1B.' For the 1961 through 1970 water years, the data were published in two 5-year reports. Data on chemical quality, temperature, and suspended sediment for the 1941 through 1970 water years were published annually under the title 'Quality of Surface Waters of the United States,' and water levels for the 1939 through 1974 water years were published under the title 'Ground-Water Levels in the United States.' The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from U.S. Geological Survey, Information Services, Box 25286, Denver Federal Center, Box 25425, Denver, CO 80225-0286. Publications similar to this report are published annually by the Geological Survey for all States. These official Survey reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as 'U.S. Geological Survey Water-Data Report MARI-98-1.' For archiving and general d

Water Data Report

Summary of West Virginia Water-Resource Data through September 2008

The West Virginia Water Science Center of the U.S. Geological Survey, in cooperation with State and Federal agencies, obtains a large amount of data pertaining to the water resources of West Virginia each water year. A water year is the 12-month period beginning October 1 and ending September 30. These data, accumulated during many years, constitute a valuable database for developing an improved understanding of the water resources of the State. These data are maintained in the National Water Information System (NWIS) and are available through its World-Wide Web interface, NWISWeb, at http://waterdata.usgs.gov/wv/nwis. Data can be retrieved in a variety of common formats, and a tutorial is available at http://nwis.waterdata.usgs.gov/tutorial. Location information for all continuous-record gaging stations operated in West Virginia through September 2008 is provided in this report, as well as statistical summaries of the available daily records. This report can serve as an index to the daily records data available on the World-Wide Web. Hydrologic data for nearly all of the gaging stations identified in this report are also available in the annual publication series titled Water-Resources Data - West Virginia. This series of annual reports for West Virginia began with the 1961 water year with a report that contained only data relating to quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report format was changed to include data on quantities of surface water, quality of surface water and groundwater, and groundwater levels. Prior to the introduction of the Water-Resources Data - West Virginia series and for several water years concurrent with it, water-resources data for West Virginia were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage and on lake or reservoir contents and stage through September 1960 were published annually under the title Surface-Water Supply of the United States, Parts 6A and 6B. For the 1961 through 1970 water years, the data were published in two 5-year reports. Data on chemical quality, temperature, and suspended sediment for the 1941 through 1970 water years were published annually under the title Quality of Surface Water of the United States, and water levels for the 1935 through 1974 water years were published under the title Ground-Water Levels in the United States. Many of the above mentioned Water-Supply Papers are available at the USGS Publications Warehouse (http://pubs.er.usgs.gov), and most of the others may be found in the collections of large libraries or may be purchased from the U.S. Geological Survey, Books and Open-File Reports, Federal Center, Box 25425, Denver, Colorado 80225. Annual reports on hydrologic data are published by the Geological Survey for all states, and each has an identification number consisting of the two-letter state abbreviation, the last two digits of the water year, and the volume number. For example, the 2005 water year report for West Virginia is identified as U.S. Geological Survey Water-Data Report WV-05-01. Water-Data Reports for West Virginia for 2001-2005 are available online at http://pubs.usgs.gov/wdr/#WV. Water-Data Reports for water years prior to 2006 are for sale in paper copy or microfiche by the National Technical Information Service, U.S. Department of Commerce, Springfield, Virginia 22161. Since the 2006 water year, the report is published online only and is available at http://wdr.water.usgs.gov/. When substantial errors in published records are discovered, the records are revised. Such revisions are routine and are made to records regardless of the age of the original records. Revisions have been made for many stations for which data are published in this report. The USGS National Water Information System always contains the most recent data revisions. For critical a

Open-File Report

Baseline ecological risk assessment of the Calcasieu Estuary, Louisiana: 1. Overview and problem formulation

A remedial investigation/feasibility study (RI/FS) of the Calcasieu Estuary cooperative site was initiated in 1998. This site, which is located in the southwestern portion of Louisiana in the vicinity of Lake Charles, includes the portion of the estuary from the saltwater barrier on the Calcasieu River to Moss Lake. As part of the RI/FS, a baseline ecological risk assessment (BERA) was conducted to assess the risks to aquatic organisms and aquatic-dependent wildlife exposed to environmental contaminants. The purpose of the BERA was to determine if adverse effects on ecological receptors are occurring in the estuary; to evaluate the nature, severity, and areal extent of any such effects; and to identify the substances that are causing or substantially contributing to effects on ecological receptors. This article describes the environmental setting and site history, identifies the chemicals of potential concern, presents the exposure scenarios and conceptual model for the site, and summarizes the assessment and measurement endpoints that were used in the investigation. Two additional articles in this series describe the results of an evaluation of effects-based sediment-quality guidelines as well as an assessment of risks to benthic invertebrates associated with exposure to contaminated sediment.

Louisiana

Sedimentation and chemical quality of surface waters in the Wind River basin, Wyoming

This report gives results of an investigation by the U. S. Geological Survey of chemical quality of surface waters and sedimentation in the Wind River Basin, Wyo. The sedimentation study was begun in 1946 to determine the quantity of sediment that is transported by the streams in the basin; the probable sources of the sediment; the effect of large irrigation projects on sediment yield, particularly along Fivemile Creek; and the probable specific weight of the sediment when initially deposited in a reservoir. The study of the chemical quality of the water was begun in 1945 to obtain information on the sources, nature, and amounts of dissolved material that is transported by streams and on the suitability of the waters for different uses. Phases of geology and hydrology pertinent to the sedimentation and chemical quality were studied. Results of the investigation through September 30, 1952, and some special studies that were made during the 1953 and 1954 water years are reported. The rocks in the Wind River Basin are granite, schist, and gneiss of Precambrian age and a thick series of sedimentary strata that range in age from Cambrian to Recent. Rocks of Precambrian and Paleozoic age are confined to the mountains, rocks of Mesozoic age crop out along the flank of the Wind River and Owl Creek Mountains and in denuded anticlines in the floor of the basin, and rocks of Tertiary age cover the greater part of the floor of the basin. Deposits of debris from glaciers are in the mountains, and remnants of gravel-capped terraces of Pleistocene age are on the floor of the basin. The lateral extent and depth of alluvial deposits of Recent age along all the streams are highly variable. The climate of the floor of the basin is arid. The foothills probably receive a greater amount of intense rainfall than the areas at lower altitudes. Most precipitation in the Wind River Mountains falls as snow. The foothill sections, in general, are transitional zones between the cold, humid climate of the high mountains and the warmer, drier climate of the basin floor. Average annual runoff in the basin is about 3.6 inches on the basis of adjusted streamflow records for the Bighorn River near Thermopolis. Runoff from the mountains is high and is mostly from melting of snow and from spring and early summer rains. It does not vary greatly from year to year because annual water losses are small in comparison to annual precipitation. In the areas on the floor of the basin, where runoff is low, the runoff is mostly the result of storms in late spring and early summer. The annual water losses nearly equal the annual precipitation; therefore, runoff is extremely variable, in terms of percentage changes, from year to year and from point to point during any 1 year.

Water Supply Paper

Water-quality and lake-stage data for Wisconsin lakes, water year 2005

The U.S. Geological Survey (USGS), in cooperation with local and other agencies, collects data at selected lakes throughout Wisconsin. These data, accumulated over many years, provide a data base for developing an improved understanding of the water quality of lakes. The purpose of this report is to provide information about the chemical and physical charac-teristics of Wisconsin lakes. Data that have been collected at specific lakes, and information to aid in the interpretation of those data, are included in this report. Data collected include measure-ments of in-lake water quality and lake stage. Time series graphs of Secchi depths, surface total phosphorus and chlorophyll a concentrations collected during non-frozen periods are included for all lakes. Graphs of vertical profiles of temperature, dissolved oxygen, pH, and specific conductance are included for sites where these parameters were measured. Descriptive infor-mation for each lake includes: location of the lake, area of the lake's watershed, period for which data are available, revisions to previously published records, and pertinent remarks.

Open-File Report

Discrete and continuous water-quality data and hydrologic parameters from seven agricultural watersheds in the United States, 2002-09

Field and analytical methods; discrete organic and non-organic water-quality data and associated quality-control data; and continuous hydrologic and water-quality parameters are reported for sites in California, Indiana, Iowa, Maryland, Mississippi, Nebraska, and Washington. The sites were sampled as part of the U.S. Geological Survey National Water-Quality Assessment Program?s Agricultural Chemicals Team study to better understand how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment.

Data Series

Geology and ground-water resources of the island of Hawaii

Hawaii, the largest island in the Hawaiian group, is 93 miles long, 76 miles wide, and covers 4,030 square miles. Mauna Loa Volcano is 13,680 feet high and Mauna Kea is 13,784 feet high. Plate 1 shows the geology, wells, springs, and water-development tunnels. Plate 2 is a map and description of points of geologic interest along the main highways. Plate 3 (same sheet as plate 2) shows highways and points of geologic interest in Hawaii National Park area. The volcanic terms used in the report are defined. Hawaii was built by five volcanoes. All the rocks are volcanic, except for minor amounts of sedimentary rock derived from them. Mauna Loa and Kilauea volcanoes erupt often; Hualalai Volcano last erupted in 1801; Mauna Kea has had Recent but no historic eruptions; Kohala Mountain has long been extinct. Kohala Mountain constitutes the northern end of the island. It is built largely of rocks of the Pololu volcanic series which are dominantly olivine basalt with a few thin intercalated beds of vitric basaltic ash. After the eruption of this series, Kohala Volcano was deeply eroded on the windward (northeastern) side, and a deep soil formed on its other slopes. Later, oligoclase andesite and trachyte lava flows, named the Hawi volcanic series, were erupted. They rest on soil at the top of the Pololu series, and lie in the valleys cut into the Pololu lavas on the windward slope. Both the Pololu and Hawi volcanics were erupted from three rift zones trending N. 35&deg; W., S. 65&deg; E., and S. 50&deg; W. from the summit of the mountain. The rift zones are marked at the surface by rows or cinder cones, and beneath the surface by innumerable dikes. A caldera occupied the summit of the mountain at the beginning of the eruption of the Hawi lavas, and for a time confined the flows. It was gradually filled and the lava escaped northeastward into the large valleys. Some of the caldera faults can still be traced. A shallow graben indents the summit now. South of Kohala Mountain lies the much larger volcano of Mauna Kea. The early rocks of Mauna Kea constitute the Hamakua volcanic series. The lower member of this series consists chiefly of olivine basalt flows with intercalated thin beds of vitric basaltic ash. The olivine basalt of the lower member changes gradationally into the upper member, in which basalt and olivine basalt arc still abundant, but andesite also is present. Lavas of the upper member interfinger with Hawi lavas of Kohala Mountain. The Hamakua volcanic series is mantled with Pahala ash 5 to 20 feet thick, above which lie the rocks of the Laupahoehoe volcanic series. Locally the two series are separated by erosional unconformity, The Laupahoehoe lavas are dominantly andesite. The andesites erupted after the last glacial epoch are mapped separately on plate 1. The Laupahoehoe volcanic series, and probably also the Hamakua volcanic series, were erupted principally from three rift zones, trending west, northeast and south-southeast from the summit of the mountain. The upper slopes are studded with many large cinder cones, lying principally along the rift zones. Late in its geologic history, Mauna Kea was capped by a small glacier, presumably contemporaneous with the Wisconsin stage of glaciation in North America, which left conspicuous terminal, lateral, and ground moraines. Deposits exposed in canyons on the southern slope, formerly believed to be of glacial origin, are now believed to be volcanic explosion breccias. The main bulk of Hualalai Volcano is built of basalts of the Hualalai volcanic series. One flow of andesite has been found. The cinder and spatter cones lie principally along three rift zones which trend northwest, north, and southeast from the summit. On the northern slope of Hualalai Volcano lies the large trachyte pumice cone of Puu Waawaa, and its thick flow of trachyte. These are grouped together as the Waawaa volcanics. They are partly buried by later basalts from both Hualalai and Mauna Loa. The last eruption of Hualalai Volcano, in 1800&ndash;1801, produced olivine basalt. The earliest exposed rocks of Mauna Loa comprise the Ninole volcanic series. Several beds of altered vitric ash are intercalated with the lavas. Following eruption of the Ninole series, a long period or quiescence occurred, during which deep amphitheater-headed valleys were cut. This was followed by the eruption of the Kahuku volcanic series, consisting mostly of lavas with some thin beds of ash. The Rahuku series is overlain by the Pahala ash, which overlies also the Hilina volcanic series on Kilauea, the Hamakua volcanic series on Mauna Kea, and the Hawi volcanic series on Kohala, providing a rough datum for correlation of the lavas of the four mountains. Deposition of the Pahala ash was followed on Mauna Loa by eruption of the Kau volcanic series, which has continued until the present time. The historic and flaws of the Kau series are mapped separately on plate 1. The historic eruptions and volcanic activity of Mauna Loa are briefly described. The western and southern slopes of Mauna Loa are cut by normal faults along which the lower flanks of the mountain have slipped seaward. The Kau volcanic series and presumably also the Kahuku and Ninole volcanic series were erupted principally from vents along two rift zones which extend northeast and southwest from the summit caldera. The lavas of all three series are preponderantly olivine basalt. Many of the lavas contain small amounts of hypersthene. The Pahala ash on the northeastern and eastern slopes of Mauna Loa was derived largely from Mauna Kea. West and south of Kilauea Caldera, however, it was derived principally from Kilauea. Minor amounts were contributed by eruptions of Mauna Loa. It is a vitric basaltic ash, now generally altered to palagonite. The earliest exposed lavas and thin intercalated ash beds of Kilauea Volcano comprise the Hilina volcanic series. These are capped by the Pahala ash, which in turn, is overlain by the lavas and thin ash beds of the Puna volcanic series. The volcanics of both series were erupted along two rift zones, one extending southwestward from Kilauea Caldera, and the other extending southeastward for 5 miles and then bending sharply east by north. The lavas of both series are very largely olivine basalt. A few flows contain hypersthene. Augite phenocrysts are common in Mauna Loa lavas, but rare in those of Kilauea, indicating that crystallization has not progressed as far in the magma chamber of Kilauea Volcano as in that of Mauna Loa. Eruption of the Puna volcanic series has continued until the present time, the historic flows being separated from the prehistoric ones on plate 1. The historic eruptions and volcanic activity of Kilauea are briefly described. Kilauea Volcano originated on the southern slope of Mauna Loa where faults intersected the Eastern Fundamental Fissure of the Hawaiian Archipelago. The southern flank of Kilauea is cut by normal faults, along which the southern part is sliding seaward. The volcanoes of the island of Hawaii are believed to have started their activity in the Tertiary period. The great erosional period which followed deposition of the Pololu and Ninole volcanic series is placed near the end of the Pliocene. The Hilina and Hamakua volcanic series were probably erupted in the late Pliocene and earlier Pleistocene. The Hawi volcanic series and the Waawaa volcanics are probably early or middle Pleistocene in age. The main period of deposition of the Pahala ash was probably late in the middle Pleistocene or early in the upper Pleistocene. The Laupahoehoe volcanic series is late Pleistocene and Recent in age, most of the flows antedating the Wisconsin glaciation. The Hualalai volcanic series probably extends from Tertiary to historic time, and the Kau and Puna volcanic series from late Pleistocene to the present. A chapter is devoted to the petrography of the rocks in which are listed all reliable chemical rock analyses. The rocks of the island are highly permeable. Most of the rainfall sinks quickly into the ground. Perennial streams are present only on the windward slopes of Kohala Mountain and Mauna Kea. Most of the water sinks rapidly to the basal water table, where it floats on salt water according to the Ghyben-Herzberg principle. Basal water escapes in springs at or near sea level all along the coast. Only a very small proportion of it is recovered in wells. Along the windward coasts the basal water is of good quality and large supplies await development. Along the leeward coasts most of the basal water is brackish. In Kohala Mountain, much water is perched on ash beds in the Pololu volcanic series and on ash and soil at the base of the Hawi volcanic series. It escapes in perched springs in the big valleys and along the windward sea cliff and is recovered in tunnels. Along the windward slope of Mauna Keu, small amounts of water are perched by ash beds and dense lava flows in the Hamakua volcanic series. Small perched springs issue from these structures and water is recovered by tunnels. In the Kau District ash beds perch considerable water, which is recovered by many tunnels. On the southern slope of Mauna Kea small springs are perched by beds of hill wash. Dikes in the rift zones are relatively impermeable, but enclose masses of permeable rock. Water is confined at high level in the interdike compartments in Kohala Mountain, and probably in the other volcanoes. It escapes in high-level springs in the deep valleys on Kohala Mountain; some of it is recovered by tunnels. It is estimated that an average of about 13,085 million gallons of water a day falls as rain over the whole island. Of this only about 2.5 percent is visibly discharged from wells, tunnels, and springs. Large supplies of basal groundwater await development. Projects for development of additional water for the city of Hilo and the Kona District are described. Chemical analyses of water, water supplies of towns and villages, descriptions of wells, springs, and tunnels, and discharge records of numerous springs and tunnels are given in tabulated form.

Hawaii

Toxicity of alkalinity to Hyalella azteca

Toxicity testing and chemical analyses of sediment pore water have been suggested for use in sediment quality assessments and sediment toxicity identification evaluations. However, caution should be exercised in interpreting pore-water chemistry and toxicity due to inherent chemical characteristics and confounding relationships. High concentrations of alkalinity, which are typical of sediment pore waters from many regions, have been shown to be toxic to test animals. A series of tests were conducted to assess the significance of elevated alkalinity concentrations to Hyalella azteca, an amphipod commonly used for sediment and pore-water toxicity testing. Toxicity tests with 14-d old and 7-d old animals were conducted in serial dilutions of sodium bicarbonate (NaHCO3) solutions producing alkalinities ranging between 250 to 2000 mg/L as CaCO3. A sodium chloride (NaCl) toxicity test was also conducted to verify that toxicity was due to bicarbonate and not sodium. Alkalinity was toxic at concentrations frequently encountered in sediment pore water. There was also a significant difference in the toxicity of alkalinity between 14-d old and 7-d old animals. The average 96-h LC50 for alkalinity was 1212 mg/L (as CaCO3) for 14-d old animals and 662 mg/L for the younger animals. Sodium was not toxic at levels present in the NaHCO3 toxicity tests. Alkalinity should be routinely measured in pore-water toxicity tests, and interpretation of toxicity should consider alkalinity concentration and test-organism tolerance.

Bulletin of Environmental Contamination and Toxico