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At least 1,243 records · Page 69Linked to original sources
USGS2018

Preferential groundwater seepage in karst terrane inferred from geoelectric measurements

The Ellenburger–San Saba aquifer discharges spring flows into the overlying Hamilton Creek bed in Burnet County, central Texas. The aquifer is susceptible to contamination from surface‐water reservoirs because of the presence of dissolution cavities that are hydraulically connected to the reservoirs in some locations. There is concern that preferential groundwater seepage from reservoirs into the aquifer in these locations might ultimately degrade the quality of the springwater that enters Hamilton Creek. To investigate preferential groundwater seepage patterns and hydraulic connectivity between surface‐water reservoirs and the Ellenburger–San Saba aquifer, geophysical reconnaissance surveys were completed between July 2017 and January 2018 to map dissolution cavities and locate preferential groundwater seepage within a specific region of the aquifer. Two‐dimensional electric resistivity tomography and self‐potential profiling were utilized, and a simplified, three‐dimensional finite‐element model of the field site was constructed to provide an interpretive aid. The self‐potential data indicated the occurrence of preferential groundwater seepage through a porous seepage conduit that was imaged by the electric resistivity tomography data but did not indicate the occurrence of groundwater seepage through two fluid‐filled dissolution cavities that were imaged by electric resistivity tomography data. Collectively, the surveying and modelling results demonstrate the efficacy of geoelectric methods for mapping the locations of dissolution cavities and preferential groundwater seepage in the electrically resistive karst terrane of the Ellenburger–San Saba aquifer.

Near Surface Geophysics↗
USGS2006

Recharge rates of principal aquifers in Lake County, Indiana

The upper 350 to 400 feet of rocks underlying Lake County , Indiana , form a single but complex hydrologic system. The rock units composing this system consist ( in ascending order) of dolomite, clay till (unit 4), glaciofluvial sand (unit 3), clay till (unit 2), and lacustrine sand, silt, and clay (unit 1). The dolomite and unit 3 form the principal aquifers and the clay tills, units 4 and 2, the confining layers. The geohydrology of the confining layers controls to a large extent the rate at which the aquifers are recharged from local precipitation and, thereby, their potential yield. Unit 4, the dolomite's confining layer, has an estimated average vertical permeability of about 0.003 gpd (gallon per day) per square foot. Under present conditions of head difference, the rate of recharge to the dolomite through unit 4 is estimated to average 20,000 gpd per square mile. Unit 2, the confining layer for unit 3, has an average estimated vertical permeability of about 0.007 gpd per square foot. Under present conditions of head difference the recharge through unit 3's confining layer is estimated to average about 100,000 gpd per square mile. However, these rates of recharge can be expected to increase as the head difference across each confining layer increases with extensive development of the aquifer .

Indiana↗
USGS2006

Waste injection into a deep limestone in northwestern Florida

During a three-month trial period, 70 million gallons of industrial wastes were successfully injected at moderate pressures into a deep limestone in the westernmost part of Florida. The movement of these wastes is expected to be predominantly southward toward the natural discharge area which is presumed to be far out in the Gulf of Mexico. The limestone lies between two thick beds of clay (aquicludes) and contains 13,000 parts per million salty water. A series of aquifers and aquicludes appear capable of preventing contamination of the overlying fresh-water aquifers.

Florida↗
USGS2006

Application of continuous seismic reflection methods to hydrologic studies

Oil and gas exploration and engineering studies in water‐covered areas routinely use continuous seismic profiling techniques to obtain subsurface geologic information. Such profiling also can be used effectively in hydrologic studies to define the geologic framework of aquifer systems, to locate hydrologic boundaries, and in some places, to interpret the lithologic character of aquifers and confining beds. High‐resolution continuous seismic profiling, through the use of nonexplosive sound sources, can be used to produce continuous records that require little data processing before hydrogeologic interpretation. High‐resolution tuned transducer, minisparker, Uniboom, and small airgun systems operating from small boats in shallow water are capable of transmitting energy that can penetrate up to a hundred meters of earth materials. The resulting analog records of the reflected seismic signal closely resemble geologic sections. Surveys on the Housatonic River in Connecticut and Massachusetts, and on the Connecticut River, in water from 1 to 10 meters deep, have defined the bedrock surface beneath 60 meters of stratified drift. Seismic‐reflection profiling also was used to determine the extent and thickness of recent lake‐bottom deposits in two Connecticut lakes. Surveys along 90 kilometers of river channels in the Sarasota‐port Charlotte, Florida, area defined in detail the stratigrapahy and continuity of the shallow aquifers.

Connecticut, Massachusetts↗
USGS1986

Hydrologic reconnaissance and summary of existing data on surface and ground-water resources in the Missouri River valley in Woodbury and Monona counties, Iowa, 1985

A hydrologic reconnaissance of the Missouri River valley in western Iowa was begun in 1985. The study area is about 400 sq mi of Missouri River flood plain used mainly for agricultural purposes and is located mostly in parts of Woodbury and Monona Counties, Iowa. The reconnaissance was conducted to determine the extent of hydrologic information available for the study area and to determine if the existing data base is sufficient to support an interpretive investigation to quantify the groundwater/surface water relationships in the area. Extensive information concerning the surface water resources of the area, particularly the Missouri River, is available. Very little information concerning the geometry, hydraulic characteristics and groundwater flow relationships in the alluvial aquifer is available. Information needs to be collected to create an adequate data base for future simulation of groundwater flow and to calibrate any estimates of flow. (USGS)

Open-File Report↗
USGS1982

Water levels in Nassau County Sewer Districts 2 and 3, Long Island, New York, 1978-79

Prior to development on Long Island, about 95 percent of total streamflow originated as groundwater seepage from the upper glacial aquifer; the remaining 5 percent consisted of direct storm runoff. Thus, the streams on Long Island function as groundwater drains. Their flow in dry weather is directly controlled by groundwater levels adjacent to the stream channels. Sewage systems in Nassau County have caused a general lowering of groundwater levels, which in turn has severely reduced streamflow. This report presents monthly water-level measurements in 259 wells in Nassau county from 1978-79 to provide a data base to evaluate the need to replace streamflow lost through lowering of the water table. (USGS)

Water-Resources Investigations Report↗
USGS2007

A simulation of groundwater discharge and nitrate delivery to chesapeake bay from the lowermost delmarva peninsula, USA

A groundwater model has been developed for the lowermost Delmarva Peninsula, USA, that simulates saltwater intrusion into local confined aquifers and nitrate delivery to the Chesapeake Bay from the surficial aquifer. A flow path and groundwater-age analysis was performed using the model to estimate the timing of nitrate delivery to the bay over the next several decades. The simulated mean and median residence times of groundwater in the lowermost peninsula are 30 and 15 years, respectively. Current and future nitrate concentrations in coastal groundwater discharge were simulated based on local well data that include nitrate concentrations and groundwater age. A simulated future-trends analysis indicates that nitrate that has been applied to agricultural regions over the last few decades will continue to discharge into the bay for several decades to come. This study highlights the importance of considering the groundwater lag time that affects the mean transport time from diffuse contamination sources.

Conference Paper↗
USGS2018

Hydrogeologic controls and geochemical indicators of groundwater movement in the Niles Cone and southern East Bay Plain groundwater subbasins, Alameda County, California

Beginning in the 1970s, Alameda County Water District began infiltrating imported water through ponds in repurposed gravel quarries at the Quarry Lakes Regional Park, in the Niles Cone groundwater subbasin, to recharge groundwater and to minimize intrusion of saline, San Francisco Bay water into freshwater aquifers. Hydraulic connection between distinct aquifers underlying Quarry Lakes allows water to recharge the upper aquifer system to depths of 400 feet below land surface, and the Deep aquifer to depths of more than 650 feet. Previous studies of the Niles Cone and southern East Bay Plain groundwater subbasins suggested that these two subbasins may be hydraulically connected. Characterization of storage capacities and hydraulic properties of the complex aquifers and the structural and stratigraphic controls on groundwater movement aids in optimal storage and recovery of recharged water and provides information on the ability of aquifers shared by different water management agencies to fulfill competing storage and extraction demands. The movement of recharge water through the Niles Cone groundwater subbasin from Quarry Lakes and the possible hydraulic connection between the Niles Cone and the southern East Bay Plain groundwater subbasins were investigated using interferometric synthetic aperture radar (InSAR), water-chemistry, and isotopic data, including tritium/helium-3, helium-4, and carbon-14 age-dating techniques. InSAR data collected during refilling of the Quarry Lakes recharge ponds show corresponding ground-surface displacement. Maximum uplift was about 0.8 inches, reasonable for elastic expansion of sedimentary materials experiencing an increase in hydraulic head that resulted from pond refilling. Sodium concentrations increase while calcium and magnesium concentrations in groundwater decrease along groundwater flowpaths from the Niles Cone groundwater subbasin through the Deep aquifer to the northwest toward the southern East Bay Plain groundwater subbasin. Residual effects of pre-1970s intrusion of saline water from San Francisco Bay, including high chloride concentrations in groundwater, are evident in parts of the Niles Cone subbasin. Noble gas recharge temperatures indicate two primary recharge sources (Quarry Lakes and Alameda Creek) in the Niles Cone groundwater subbasin. Although recharge at Quarry Lakes affects hydraulic heads as far as the transition zone between the Niles Cone and East Bay Plain groundwater subbasins (about 5 miles), the effect of recharged water on water quality is only apparent in wells near (less than 2 miles) recharge sources. Groundwater chemistry from upper aquifer system wells near Quarry Lakes showed an evaporated signal (less negative oxygen and hydrogen isotopic values) relative to surrounding groundwater and a tritium concentration (2 tritium units) consistent with recently recharged water from a surface-water impoundment. Uncorrected carbon-14 activities measured in water sampled from wells in the Niles Cone groundwater subbasin range from 16 to 100 percent modern carbon (pmC). The geochemical reaction modeling software NETPATH was used to interpret carbon-14 ages along a flowpath from Quarry Lakes toward the East Bay Plain groundwater subbasin. Model results indicate that changes in groundwater chemistry are controlled by cation exchange on clay minerals and weathering of primary silicate minerals. Old groundwater (lower carbon-14 activities) is characterized by high dissolved silica and pH. Interpreted carbon-14 ages ranged from 830 to more than 7,000 years before present and are less than helium-4 ages that range from 2,000 to greater than 11,000 years before present. The average horizontal groundwater velocity along the studied flowpath, as calculated using interpreted carbon-14 ages, through the Deep aquifer of the Niles Cone groundwater subbasin is between 3 and 12 feet per year. The groundwater velocity decreases near the boundary of the transition zone to the southern East Bay Plain groundwater subbasin to about 0.5 feet per year. These changes may result from water recharged from different sources converging in flowpaths north of the transition zone, or a boundary to flow between the Niles Cone and southern East Bay Plain groundwater subbasins, likely owing to changes in lithology caused by depositional patterns.

California↗
USGS2016

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado↗
USGS2013

Effects of recent climate variability on groundwater levels in eastern Arkansas

Water-level fluctuations in wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas were compared to variability in annual precipitation, an indicator of climate variability. The wettest year on record in Little Rock, Arkansas, occurred in 2009 with 81.79 inches of precipitation compared to an average of 47.1 inches per year. In contrast, 2005 and 2010 were the 7th and 14th driest years on record with 34.55 and 36.52 inches per year, respectively. This variability in precipitation was reflected in water-level altitude changes between 2004 and 2008 and 2006 and 2010. Generally, drier conditions between 2004 and 2008 led to an average decline in water levels of 1.62 feet, whereas wetter conditions between 2006 and 2010 led to an average rise in water levels of 1.36 feet. Drier periods likely resulted in less recharge compared to wetter periods. Groundwater use from the alluvial aquifer peaked in 2000 and has since declined, in part, because of conservation measures and substantial reduction in aquifer saturated thickness. Groundwater-flow model results showed some areas of the alluvial aquifer simulated as dry in 2010, indicating a reduced capacity of the alluvial aquifer to produce water in those areas. Additional factors affecting groundwater use include the types of crops grown in an area and the availabitiliy of crop subsidies. Real-time continuous water-level measurements in wells allow for a more accurate assessment of the effect of variability in precipitation and water use than periodic water-level measurements.

Arkansas↗
USGS1986

Simulation of ground-water flow and infiltration from the Susquehanna River to a shallow aquifer at Kirkwood and Conklin, Broome County, New York

A four-layer finite difference model was developed to simulate groundwater flow and induced infiltration to an aquifer underlying the Susquehanna River in the Towns of Kirkwood and Conklin in Broome County, NY. The aquifer consists of sand and gravel deposited in an ancestral river valley during the recession of glacial ice and is in hydraulic connection with the Susquehanna River. In 1984, he aquifer supplied 1.2 million gal/day to well fields in Kirkwood and Conklin. Horizontal hydraulic conductivity of the sand and gravel in the calibrated model ranges from 50 to 10,000 ft/day. Vertical hydraulic conductivity ranges from 1.0 to 80 ft/day. The riverbed thickness was estimated from results of piezometer tests to be 2 ft; the hydraulic conductivity of the riverbed was estimated to be 0.2 ft/day. Root-mean-square differences between computed drawdowns and drawdowns measured in observation wells and piezometers during aquifer tests at the Kirkwood well field ranged from 17% to 24%. The sizes of the well field catchment areas were estimated from a model generated flow net showing the direction and rate of groundwater flow. The Kirkwood catchment area was estimated to be 250 acres, and the Conklin catchment area was 51 acres. Groundwater budgets computed by steady-state simulations showed that 58% of the groundwater withdrawn by the Kirkwood well field is derived from the Susquehanna River during the periods of low river stage and low recharge. The factor to which induced-infiltration rate and size of well field catchment areas are most sensitive, is riverbed hydraulic conductivity.

New York↗
USGS1997

Groundwater record of halocarbon transport by the Danube River

Groundwater dating studies have supported the concept that aquifers with low coefficients of dispersion may contain coherent records of past conditions in recharge areas. Groundwater records can provide unique information about natural or anthropogenic changes in the atmosphere and hydrosphere where long-term monitoring data are not available. Here we describe a 40-year record of halocarbon contamination in the Danube River that was retrieved from a shallow aquifer in northwest Hungary. The time scale is based on 3H and He isotope dating of groundwaters that were recharged by the Danube River and moved horizontally away from the river in a surficial gravel aquifer with minor dispersion at a maximum rate of at least 500 m/yr. Analyses of dated groundwaters along a flow path indicate that the river loads of selected compounds (including CFC-12, CFC-113, and trichloroethane) were negligible before about 1950, rose rapidly to peak values in the 1960s and 1970s, and then decreased by varying degrees to the present. Peak concentrations are tentatively attributed to point sources in upstream urban-industrial centers; while recent decreases presumably resulted from declining manufacturing rates and(or) improvements in control of urban- industrial runoff and sewage effluent entering the river in upstream areas.

Danube River↗
USGS1988

Nitrogen transport in a shallow outwash aquifer at Olean, Cattaraugus County, New York

Groundwater beneath an industrial park at Olean, New York, contained nitrogen compounds in concentrations that in 1983 ranged from 10 to 1,280 mg/L as nitrogen, mainly in the form of ammonium. Continuous pumping from an industrial well field creates a cone of depression that prevents the nitrogen compounds from migrating to municipal-supply wells, 7,000 ft away. A two-dimensional solute transport model was used to simulate changes in nitrogen concentrations that would result from a permanent shutdown of the well field. The model assumed the nitrogen source decayed at an exponential rate with a decay constant of 0.3/year to account for nitrogen removed from the aquifer by pumping during 1978-84. The source of contamination was found to be sensitive to the volume of pumpage at the industrial well field, which altered the rate of groundwater flow through the contaminated area. Simulations of a permanent shutdown of the well field, assuming nitrogen migrates as a conservative solute, indicated that nitrogen-bearing groundwater would reach the municipal well field within 5 years and the peak concentrations at the municipal well field would range from 2 to 5 mg/L. Simulations of Langmuir adsorption of the dissolved ammonium with a one-dimensional model indicated that the arrival of the solute front at the municipal well field would be retarded by a factor of three.

New York↗
USGS1998

Biodegradation of crude oil into nonvolatile organic acids in a contaminated aquifer near Bemidji, Minnesota

As the result of a pipeline burst, a body of light aliphatic crude oil floats atop the groundwater in a shallow sand and gravel aquifer in a remote area outside Bemidji, Minnesota. Biodegradation has resulted in the formation of a plume of DOC downgradient from the oil body. Groundwater has also been contaminated in an area known as the spray zone, from vertical infiltration of DOC resulting from biodegradation of crude oil in the overlying unsaturated zone. The majority of DOC in the contaminated groundwater is in the form of nonvolatile organic acids (NVOA's) which represent the partial oxidation products of the crude oil constituents. The NVOA's have been classified into three fractions according to their isolation on XAD resins: hydrophobic neutrals (HPO-N), hydrophobic acids (HPO-A) and hydrophilic acids (HPI-A). These fractions of NVOA's were isolated from a well downgradient from the oil body (well 530; DOC=21 mg C/l), from a well in the spray zone (well 603; DOC=15 mg C/l) and from an uncontaminated well upgradient of the oil body where the naturally occurring DOC is 2.9 mg C/l (well 310). The three sets of NVOA's were characterized by elemental analyses, molecular weight determinations, 14 C ages and liquid phase 1 H and 13 C NMR. The crude oil and the saturate, aromatic, resin and asphaltene fractions of the crude oil were similarly analyzed by elemental analysis and NMR. The NVOA's from the contaminated wells were clearly distinguishable from the naturally occurring groundwater DOC. Based upon molecular weights, sulfur contents, aromaticities and the presence of methyl groups bonded to aromatic rings, the characterization data suggests that the NVOA's originate from the C 18 or greater alkylaromatic, naphthenoaromatic and sulfur-containing constituents of the crude oil, including possibly the resins and asphaltenes.

Minnesota↗
USGS2014

Survival of bacterial indicators and the functional diversity of native microbial communities in the Floridan aquifer system, south Florida

The Upper Floridan aquifer in the southern region of Florida is a multi-use, regional scale aquifer that is used as a potable water source and as a repository for passively recharged untreated surface waters, and injected treated surface water and wastewater, industrial wastes, including those which contain greenhouse gases (for example, carbon dioxide). The presence of confined zones within the Floridan aquifer that range in salinity from fresh to brackish allow regulatory agencies to permit the injection of these different types of product waters into specific zones without detrimental effects to humans and terrestrial and aquatic ecosystems. The type of recharge that has received the most regulatory attention in south Florida is aquifer storage and recovery (ASR). The treated water, prior to injection and during recovery, must meet primary and secondary drinking water standards. The primary microbiology drinking water standard is total coliforms, which have been shown to be difficult to inactivate below the regulatory standard during the treatment process at some ASR facilities. The inefficient inactivation of this group of indicator bacteria permits their direct injection into the storage zones of the Floridan aquifer. Prior to this study, the inactivation rates for any member of the total coliform group during exposure to native geochemical conditions in groundwater from any zone of the Floridan aquifer had not been derived. Aboveground flow through mesocosms and diffusion chambers were used to quantify the inactivation rates of two bacterial indicators, Escherichia coli and Pseudomonas aeruginosa, during exposure to groundwater from six wells. These wells collect water from two ASR storage zones: the Upper Floridan aquifer (UFA) and Avon Park Permeable Zone (APPZ). Both bacterial strains followed a biphasic inactivation model. The E. coli populations had slower inactivation rates in the UFA (range: 0.217–0.628 per hour (h -1 )) during the first phase of the model than when exposed to groundwater from the APPZ (range: 0.540–0.684 h -1 ). The inactivation rates for the first phase of the models for P. aeruginosa were not significantly different between the UFA (range: 0.144–0.770 h -1 ) and APPZ (range: 0.159–0.772 h -1 ) aquifer zones. The inactivation rates for the second phase of the model for this P. aeruginosa were also similar between UFA (range: 0.003–0.008 h -1 ) and APPZ (0.004–0.005 h -1 ) zones, although significantly slower than the model’s first phase rates for this bacterial species. Geochemical data were used to determine which dissimilatory biogeochemical reactions were most likely to occur under the native conditions in the UFA and APPZ zones using thermodynamics principles to calculate free energy yields and other cell-related energetics data. The biogeochemical processes of acetotrophic and hydrogenotrophic sulfate reduction, methanogenesis and anaerobic oxidation of methane dominated in all six groundwater sites. A high throughput DNA microarray sequencing technology was used to characterize the diversity in the native aquifer bacterial communities (bacteria and archaea) and assign putative physiological capabilities to the members of those communities. The bacterial communities in both zones of the aquifer were shown to possess the capabilities for primary and secondary fermentation, acetogenesis, methanogenesis, anaerobic methane oxidation, syntrophy with methanogens, ammonification, and sulfate reduction. The data from this study provide the first determination of bacterial indicator survival during exposure to native geochemical conditions of the Floridan aquifer in south Florida. Additionally, the energetics and functional bacterial diversity characterizations are the first descriptions of native bacterial communities in this region of the Floridan aquifer and reveal how these communities persist under such extreme conditions. Collectively, these types of data can be used to develop and refine groundwater models.

Florida↗
USGS2014

Hydrologic conditions in urban Miami-Dade County, Florida, and the effect of groundwater pumpage and increased sea level on canal leakage and regional groundwater flow

The extensive and highly managed surface-water system in southeastern Florida constructed during the 20th Century has allowed for the westward expansion of urban and agricultural activities in Miami-Dade County. In urban areas of the county, the surface-water system is used to (1) control urban flooding, (2) supply recharge to production well fields, and (3) control seawater intrusion. Previous studies in Miami-Dade County have determined that on a local scale, leakage from canals adjacent to well fields can supply a large percentage (46 to 78 percent) of the total groundwater pumpage from production well fields. Canals in the urban areas also receive seepage from the Biscayne aquifer that is derived from a combination of local rainfall and groundwater flow from Water Conservation Area 3 and Everglades National Park, which are west of urban areas of Miami-Dade County. To evaluate the effects of groundwater pumpage on canal leakage and regional groundwater flow, the U.S. Geological Survey (USGS) developed and calibrated a coupled surface-water/groundwater model of the urban areas of Miami-Dade County, Florida. The model was calibrated by using observation data collected from January 1997 through December 2004. The model calibration was verified using observation data collected from January 2005 through December 2010. A 1-year warmup period (January 1996 through December 1996) was added prior to the start of the calibration period to reduce the effects of inaccurate initial conditions on model calibration. The model is designed to simulate surface-water stage and discharge in the managed canal system and dynamic canal leakage to the Biscayne aquifer as well as seepage to the canal from the aquifer. The model was developed using USGS MODFLOW–NWT with the Surface-Water Routing (SWR1) Process to simulate surface-water stage, surface-water discharge, and surface-water/groundwater interaction and the Seawater Intrusion (SWI2) Package to simulate seawater intrusion, respectively. Automated parameter estimation software (PEST) and highly parameterized inversion techniques were used to calibrate the model to observed surface-water stage, surface-water discharge, net surface-water subbasin discharge, and groundwater level data from 1997 through 2004 by modifying hydraulic conductivity, specific storage coefficients, specific yield, evapotranspiration parameters, canal roughness coefficients (Manning’s n values), and canal leakance coefficients. Tikhonov regularization was used to produce parameter distributions that provide an acceptable fit between model outputs and observation data, while simultaneously minimizing deviations from preferred values based on field measurements and expert knowledge. Analytical and simulated water budgets for the period from 1996 through 2010 indicate that most of the water discharging through the salinity control structures is derived from within the urban parts of the study area and that, on average, the canals are draining the Biscayne aquifer. Simulated groundwater discharge from the urban areas to the coast is approximately 7 percent of the total surface-water inflow to Biscayne Bay and is consistent with previous estimates of fresh groundwater discharge to Biscayne Bay. Simulated groundwater budgets indicate that groundwater pumpage in some surface-water basins ranges from 13 to 27 percent of the sum of local sources of groundwater inflow. The largest percentage of groundwater pumpage to local sources of groundwater inflow occurs in the basins that have the highest pumping rates (C–2 and C–100 Basins). The ratio of groundwater pumpage to simulated local sources of groundwater inflow is less than values calculated in previous local-scale studies. The position of the freshwater-seawater interface at the base of the Biscayne aquifer did not change notably during the simulation period (1996–2010), consistent with the similar positions of the interface in 1984, 1995, and 2011 under similar hydrologic and groundwater pumping conditions. Landward movement of the freshwater-seawater interface above the base of the aquifer is more prone to occur during relatively dry years. The model was used to evaluate the effect of increased groundwater pumpage and (or) increased sea level on canal leakage, regional groundwater flow, and the position of the freshwater-seawater interface. Permitted groundwater pumping rates, which generally exceed historical groundwater pumping rates, were used for Miami-Dade County Water and Sewer Department groundwater pumping wells in the base-case future scenario. Base-case future and increased pumping scenario results suggest seawater intrusion may occur at the Miami-Springs well field if the Miami Springs, Hialeah, and Preston well fields are operated using current permitted groundwater pumping rates. Scenario simulations also show that, in general, the canal system limits the adverse effects of proposed groundwater pumpage increases on water-level changes and saltwater intrusion. Proposed increases (up to a 7 percent increase) in groundwater pumpage do not have a notable effect on movement of the freshwater-seawater interface. Increased groundwater pumpage increased lateral groundwater inflow into basins subject to additional groundwater pumpage; however, most (55 percent) of the additional groundwater extracted from pumping wells was supplied by changes in canal seepage and leakage in urban areas of the model. Increased sea level caused increased water-table elevations in urban areas and decreased hydraulic gradients across the system; the largest increases in water-table elevations occurred seaward of the salinity control structures. The extent of flood-prone areas and the percentage of time water-table elevations in flood-prone areas were less than 0.5 foot below land surface increased with increased sea level. Increased sea level also resulted in landward migration of the freshwater-seawater interface; the largest changes in the position of the interface occurred seaward of the salinity control structures except in parts of the model area that were inundated by increased sea level. Decreased water-table gradients reduced groundwater inflow, groundwater outflow, canal exchanges, surface-water inflow, and surface-water outflow through salinity control structures. Results for the scenario that evaluated the combination of increased groundwater pumpage and increased sea level did not differ substantially from the scenario that evaluated increased sea level alone. Groundwater inflow, groundwater outflow, and canal exchanges were reduced in urban areas of the study area as a result of decreased water-table gradients across the system, although reductions were less than those in the increased sea-level scenario. The decline in groundwater levels caused by increased groundwater pumpage was less under the increased sea-level scenario than under the increased groundwater-pumpage scenario. The largest reductions in surface-water outflow from the salinity control structures occurred with increased sea level and increased groundwater pumpage. The model was designed specifically to evaluate the effect of groundwater pumpage on canal leakage at the surface-water-basin scale and thus may not be appropriate for (1) predictions that are dependent on data not included in the calibration process (for example, subdaily simulation of high-intensity events and travel times) and (or) (2) hydrologic conditions that are substantially different from those during the calibration and verification periods. The reliability of the model is limited by the conceptual model of the surface-water and groundwater system, the spatial distribution of physical properties, the scale and discretization of the system, and specified boundary conditions. Some of the model limitations are manifested in model errors. Despite these limitations, however, the model represents the complexities of the interconnected surface-water and groundwater systems that affect how the systems respond to groundwater pumpage, sea-level rise, and other hydrologic stresses. The model also quantifies the relative effects of groundwater pumpage and sea-level rise on the surface-water and groundwater systems.

Florida↗
USGS1994

Geohydrology and ground-water quality in the vicinity of a ground-water-contamination site in Rockford, Illinois

A geohydrologic investigation was performed by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to determine the distribution of volatile organic compounds in a fractured-rock aquifer near the Southeast Rockford Groundwater Contamination Site in Rockford, Ill. The geologic units of concern are the St. Peter Sandstone and Glenwood Formation; the dolomites of the Platteville and Galena Groups of Ordovician age; and the sands, gravels, silts, and clays of Quaternary age. The hydraulic units of concern are the unconsolidated aquifer, composed of sand and gravel; the fractured- dolomite aquifer, composed of the Galena and Platteville Groups and the dolomitic sections of the Glenwood Formation; and the sandstone aquifer, composed of the St. Peter Sandstone and the sandstone beds in the Glenwood Formation. The dolomite aquifer is well connected hydraulically to the overlying unconsolidated aquifer and the underlying sandstone aquifer. Caliper and acoustic-televiewer logs show several subhorizontal fractures in the dolomite that can be correlated throughout the study area. Comparison of televiewer and flowmeter logs indicates that most of the flow in the dolomite aquifer is through these fractures. Ground-water flow through two of the fractures can be correlated over large parts of the study area. Volatile organic compounds, in concentrations exceeding 2,000 micrograms per liter, were detected within the entire thickness of the dolomite aquifer where flow is measurable. Volatile organic compounds were detected in an area of the aquifer where they were thought to be absent in previous investigations.

Illinois↗
USGS1986

Hydrologic appraisal of the Pine Barrens, Suffolk County, New York

The groundwater resources of the Pine Barrens, in southeastern Suffolk County, were appraised during 1982-83 for their potential for use as a supply of potable water. The study area encompasses approximately 50 square miles. The Precambrian bedrock is overlain by Cretaceous, Pleistocene, and Holocene deposits. The surficial material consists of morainal and outwash deposits overlain by recent beach and marsh deposits. The groundwater reservoir consists of three aquifers--the Lloyd and the Magothy of Cretaceous age and the upper glacial of Pleistocene age. The water is generally of suitable quality for drinking and most other uses except in several localized spots where point-source contamination has been documented. Precipitation is the sole source of recharge. Average annual precipitation recorded in the area during 1943-82 was 43 inches, about half of which reaches the groundwater reservoir. Overland runoff is estimated to be 0.5 inches per year, and evapotranspiration 23 inches per year. Total public water-supply withdrawal in the area in 1982 is estimated to have been 9.09 million gallons per day (Mgal/d). The upper glacial aquifer is the major source of public water; pumpage in 1982 was 7.88 Mgal/d; pumpage from the Magothy was 1.02 Mgal/d, and pumpage from the Lloyd aquifer was 0.19 Mgal/d. Stream discharge is measured periodically at 17 streamflow measurement sites on the 11 streams in the Pine Barrens. (USGS)

Water-Resources Investigations Report↗