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Refinements to the attenuated propagation of local earthquake shaking (APPLES) ground-motion-based earthquake early warning algorithm

We refined the Attenuated ProPagation of Local Earthquake Shaking (APPLES) ground-motion-based earthquake early warning (EEW) approach, and directly compare APPLES performance with that of the source-characterization-based U.S. ShakeAlert EEW system for a suite of historical earthquakes in the U.S. West Coast and Japan. APPLES is an extension of the Propagation of Local Undamped Motion (PLUM) algorithm in which observed shaking intensity at seismic stations is used to forward-predict intensity distributions to surrounding areas using an attenuation model derived from an intensity prediction equation. We test new configuration options within APPLES, such as using the second highest estimated ground motion rather than the maximum, to better match median ground-motion observations and reduce alerts for small magnitude earthquakes, both of which are key alerting priorities within ShakeAlert. We evaluate these configurations alongside ShakeAlert by comparing the ground-motion estimation accuracy and available warning times relative to station observations and ShakeMap distributions. Our preferred APPLES configuration produces accurate ground-motion estimates and corresponds better with median observations compared to ShakeAlert’s estimates. This preferred configuration substantially reduces alert issuance for M < 5.0 earthquakes compared to the previous APPLES configuration, and alert-release criteria can further restrict alerts to primarily M ≥ 5.5 earthquakes without requiring magnitude estimation. Prioritizing matching median-observed ground motions may reduce APPLES warning times compared to configurations that were tuned to avoid missed alerts (such as those that use the maximum estimated ground motions), which can lead to shorter warning times compared to ShakeAlert for the same alert threshold. However, station-based warning time assessments demonstrate that APPLES can outperform ShakeAlert for high target thresholds. APPLES is a simple, independent EEW approach that may improve the robustness of EEW for the West Coast of the U.S.

California, Oregon, Washington

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Characteristics of the fault damage zone From high-resolution seismic imaging along the Palos Verdes Fault, California

The distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in-situ distribution of fault damage remain limited and along-strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub-bottom profiles. The combination of high-resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi-trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

California

Core microbiomes as a potential fingerprinting method of Western USA dust sources

Introduction: Changing frequency and intensity of dust emissions impacts ecosystems and human health. Dust carries microbes, nutrients, heavy metals, and other materials that may change environmental biogeochemistry at deposition sites. Identifying dust sources provides key information on where and when mitigation strategies should be employed. However, commonly used geochemical or isotopic tracers are often not capable of distinguishing between geographic regions. Methods: We explored whether soil bacterial communities may provide distinct fingerprints of dust sources in the western United States. We identified bacterial core communities of dust from ten locations monitored by the National Wind Erosion Research Network (NWERN) with varied land use (cropland, rangeland, and playa), and compared communities to location, soil, and regional characteristics. Samples were collected monthly from Modified Wilson and Cooke (MWAC) samplers, composited by season (spring, summer, and fall), and analyzed using 16S rRNA sequencing. Results: We found distinct bacterial core communities that reflected dust source characteristics. In order of importance, precipitation levels ( p = 0.0001), location ( p = 0.0001), soil texture ( p = 0.0001), seasonality ( p = 0.0001), and elevation (p = 0.0002) were correlated with bacterial community composition. Discussion: Distinct bacterial core communities were associated with site characteristics such as biocrusts, playas, and military base proximity. Our results suggest that the use of core microbiomes may offer a fingerprinting method to identify dust source regions.

Colorado, Nevada, New Mexico, North Dakota, Oklaho

Widespread anhydrite saturation in Laramide-age arc magmas of southwestern USA

Anhydrite is considered a rare mineral phase in magmas, with only ∼33 documented occurrences worldwide. However, anhydrite readily decomposes in the near-surface environment, making it difficult to recognize its former presence in rocks collected at or near Earth’s surface. In such samples, only small anhydrite inclusions fully shielded within other minerals can have survived. During a recent field trip to the southwestern USA, we sampled 17 Laramide-age (ca. 40−80 Ma) magma systems, most of which are associated with porphyry copper deposits. A systematic search for anhydrite inclusions preserved within apatite, amphibole, plagioclase, and quartz phenocrysts in ∼100 rock samples by optical microscopy and Raman spectroscopy revealed that each of these 17 magma systems was at least temporarily anhydrite-saturated. Also, most previously identified magmatic anhydrite-bearing intrusions are associated with porphyry copper deposits, and both intrusive and volcanic rocks containing magmatic anhydrite show high Sr/Y ratios. These observations suggest that anhydrite saturation and porphyry copper formation are linked via magma fractionation at high pressure. Compared to average arc magmas, anhydrite-bearing magmas are unusually oxidized and sulfur-rich and seem to also be unusually water-rich. Hence, our preferred interpretation is that magma generation and/or fractionation at high pressure promotes the formation of superhydrous and oxidized magmas, which in turn promotes high sulfur contents and ultimately the precipitation of anhydrite. The high mineralization potential of these magmas does not need to result from their high sulfur content but could be caused by other properties of high-pressure magmas.

Arizona, New Mexico

Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

Washington

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California

Landsliding follows signatures of wildfire history and vegetative regrowth in a steep coastal shrubland

Five years after the deadly and destructive 9 January 2018 Montecito debris flows (Santa Barbara County, California, USA), an atmospheric river storm on 9 January 2023 triggered widespread landsliding that affected many of the same drainages in the Santa Ynez Mountains. Using high-resolution aerial imagery, we identified >10,000 landslides over an ∼160 km 2 area. Most of the landslides were shallow (<1 m in depth) translational debris slides that initiated on steep (∼40°), south-facing hillslopes, with the highest incidence of landsliding in a sandstone-dominated bedrock unit. The landslides mobilized into debris flows and delivered substantial quantities of sediment downstream, which contributed to costly infrastructure impairments. We detected order-of-magnitude differences in landslide density across the study area that could not be attributed to variations in geomorphology (topographic aspect and slope), geology (bedrock type), or hydrology (seasonal antecedent rainfall, peak hourly storm rainfall intensity, total storm rainfall), which are usually considered relevant factors for shallow landsliding. Rather, we found that vegetation regrowth following wildfire was likely a relevant factor associated with the highly variable landslide densities. Hillslopes with less and different types of vegetation regrowth after fire appear to have been more susceptible to shallow landslides. We identify a possible vegetation control on postfire landsliding, which highlights an opportunity for hypothesis testing using more advanced techniques to track the evolution of vegetation cover and vegetation type in steep shrubland environments following wildfire.

California

Validating antler- and movement-based estimates of caribou reproduction using video camera collars

Wildlife agencies invest substantial resources in monitoring ungulate reproductive rates given ongoing concerns about population trends and their implications for management. For barren-ground caribou ( Rangifer tarandus ) in the North American Arctic, data on parturition and neonate survival have traditionally been collected using visual observations of antler retention and calf presence from small, fixed-wing aircraft. However, these surveys are weather-dependent, expensive, and dangerous, motivating the development of movement-based approaches that infer reproductive events from global positioning system (GPS) location data. We had the unique opportunity to use video camera collars to validate both antler- and movement-based methods for estimating reproduction in barren-ground caribou, using data from the Porcupine (2018–2023) and Western Arctic (2021, 2023) herds in Alaska, USA, and Yukon, Canada. For the movement-based approaches, we assessed individual-based and population-based methods, which both inferred parturition following a sharp decline in movement and inferred calf loss following a sharp increase in movement. We investigated these approaches using rarified 1-, 2-, 4-, and 8-hour fix intervals. Based on video collar observations, we found that antler retention at the onset of the calving period was highly accurate for predicting parturition (96% accuracy) but became unreliable as calving progressed, as approximately 80% of parturient females shed their antlers during the calving period. In contrast, both movement methods performed marginally for estimating caribou parturition (~70% accuracy), with estimates from the individual-based method exhibiting greater bias than those from the population-based method. The individual-based method also poorly predicted neonate survival (≤49% accuracy for detecting parturition and calf fate for the Porcupine Herd). Video data revealed that inaccuracies with the movement methods often occurred when caribou bedded during storms, rested after traversing mountainous terrain, lost a calf shortly after birth, or increased movement to evade insects. These results have important implications for management agencies using antler- and movement-based methods to estimate caribou reproduction, particularly when informing assessments of population decline or recovery. Our results demonstrate the utility of video collar data for validating reproductive monitoring approaches and provide insights into how these approaches can be improved.

Alaska, Yukon

Slow slip detectability in seafloor pressure records offshore Alaska

In subduction zones worldwide, seafloor pressure data are used to observe tectonic deformation, particularly from megathrust earthquakes and slow slip events (SSEs). However, such measurements are also sensitive to oceanographic circulation-generated pressures over a range of frequencies that conflate with tectonic signals of interest. Using seafloor pressure and temperature data from the Alaska Amphibious Community Seismic Experiment, and sea surface height data from satellite altimetry, we evaluate the efficacy of various seasonal and oceanographic pressure signal proxy corrections and conduct synthetic tests to determine their impact on the timing and amplitude prediction of ramp-like signals typical of SSEs. We find that subtracting out the first mode of the complex empirical orthogonal functions of the pressure records on either the shelf or slope yields signal root-mean-square error (RMS) reductions up to 73% or 80%, respectively. Additional correction with proxies that exploit the depth-dependent spatial coherence of pressure records provides cumulative variance reductions up to 83% and 93%, respectively. Our detectability tests show that the timing and amplitude of synthetic SSE-like ramps can be well constrained for ramp amplitudes ≥4 cm on the shelf and ≥2 cm on the slope, using a fully automated detector. The principal limits on detectability are residual abrupt changes in pressure that occur as part of the transition to and from summer to winter conditions but are not adequately characterized by our seasonal corrections, as well as the inability to properly account for instrumental drift, which is not readily separated from the seasonal signal.

Alaska

Numerical modeling of Late Pleistocene to Holocene earthquake-induced progressive rock slope damage in the paraglacial Serpentine valley, Prince William Sound, Alaska

Landslides in deglaciating fjords pose a potential tsunami threat to nearby communities; however, processes contributing to long-term progressive rock damage and landslide conditioning remain poorly constrained in paraglacial settings. Here, we analyse the role of earthquake-induced rock mass damage over late Pleistocene to Holocene time scales, as a conditioning factor for modern landslides, using distinct element numerical modelling to assess spatial and temporal patterns of fracture propagation influenced by varying glacier thickness. Conceptualised numerical models were parameterised by in situ rock mass, glacial and topographic conditions in Serpentine valley, located in Prince William Sound, Alaska, where several large landslides are actively developing along the western valley wall. Results show that although rigid glacier buttressing reduces co-seismic rock mass damage, it does not suppress it completely, and damage occurs both above and below the glacier surface elevation. We demonstrate that topography, and especially steep slopes with topographic convexity, as well as preexisting damage of joint networks and faults inherited from tectonic and exhumation induced stresses, exert primary control on the location of new co-seismic damage. Simulations representing a simplified deglaciation sequence over the past 25 ka, with a series of 10 evenly spaced earthquakes, generated rock mass damage patterns that qualitatively match in situ landslide structural and kinematic observations at one instability in Serpentine valley. Our conceptual study helps clarify the role of repeated seismicity over glacial timescales as a long-term conditioning process for paraglacial rock slope failure, highlighting spatial and temporal patterns of progressive damage accumulation, with outcomes relevant for modern landslide hazard assessment.

Alaska

Deformation by pressure solution and grain boundary sliding in a retrograde shear zone in southern New England, USA

Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by 40 Ar/ 39 Ar dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

Connecticut

Technique for simulating peak-flow hydrographs in Maryland

The efficient design and management of many bridges, culverts, embankments, and flood-protection structures may require the estimation of time-of-inundation and (or) storage of floodwater relating to such structures. These estimates can be made on the basis of information derived from the peak-flow hydrograph. Average peak-flow hydrographs corresponding to a peak discharge of specific recurrence interval can be simulated for drainage basins having drainage areas less than 500 square miles in Maryland, using a direct technique of known accuracy. The technique uses dimensionless hydrographs in conjunction with estimates of basin lagtime and instantaneous peak flow. Ordinary least-squares regression analysis was used to develop an equation for estimating basin lagtime in Maryland. Drainage area, main channel slope, forest cover, and impervious area were determined to be the significant explanatory variables necessary to estimate average basin lagtime at the 95-percent confidence interval. Qualitative variables included in the equation adequately correct for geographic bias across the State. The average standard error of prediction associated with the equation is approximated as plus or minus (+/-) 37.6 percent. Volume correction factors may be applied to the basin lagtime on the basis of a comparison between actual and estimated hydrograph volumes prior to hydrograph simulation. Three dimensionless hydrographs were developed and tested using data collected during 278 significant rainfall-runoff events at 81 stream-gaging stations distributed throughout Maryland and Delaware. The data represent a range of drainage area sizes and basin conditions. The technique was verified by applying it to the simulation of 20 peak-flow events and comparing actual and simulated hydrograph widths at 50 and 75 percent of the observed peak-flow levels. The events chosen are considered extreme in that the average recurrence interval of the selected peak flows is 130 years. The average standard errors of prediction were +/- 61 and +/- 56 percent at the 50 and 75 percent of peak-flow hydrograph widths, respectively.

Maryland

Sand provenance boundary in the Mu Us Sandy Land of northern China

Desert dunes are often assumed to have uniform mineral compositions due to extensive mixing during lateral transport, which complicates provenance studies. The Mu Us Sandy Land in north-central China, near the East Asian summer monsoon precipitation boundary, experiences a wetter climate than most deserts. Climate wetting as a result of a warming climate, and the ‘Sand Control Project’ implemented by the Chinese government to decrease the lateral movement of sand dunes in this area provide an opportunity to study surface processes of sand production and transport. Previous studies using zircon U Pb geochronology and heavy mineral composition indicate distinct sand sources for the Mu Us Sandy Land: local basement-derived middle Yellow River sediments and recycled dried-up lacustrine sediments for the eastern part, and northeastern Tibetan Plateau-derived upper Yellow River sediments for the western part. However, zircons and heavy minerals only represent trace amounts of the bulk mineralogy within a sand dune, so broader provenance analysis targeting common minerals is essential. We focus on the area near the proposed provenance difference boundary between the western and eastern Mu Us Sandy Land, using comprehensive sampling and provenance techniques to confirm distinct provenance characteristics and delineate the provenance boundary. Our findings reveal that sand from most of the Mu Us Sandy Land originated from the erosion of local basement by the middle Yellow River and recycled local dried-up lacustrine sediments, whereas the southwestern corner and the neighboring western-central Chinese Loess Plateau received sediments from the distal northeastern Tibetan Plateau.

Mu Us Sandy Land

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana

Uncertainty reduction for subaerial landslide-tsunami hazards

Subaerial rock slopes may generate a tsunami by rapidly moving into the water. Large uncertainty in landslide characteristics propagates into large uncertainty in tsunami hazard, making hazard assessment more difficult for land and emergency managers. Once a potentially tsunamigenic landslide is identified, it may not be clear which landslide characteristics contribute most significantly to uncertainty in the tsunami hazard. Our aim is to document the relative worth of different landslide characteristics (e.g., size, material properties) for reducing uncertainty in landslide-tsunami hazard assessments. Isolating the relative importance of specific landslide characteristics may inform prioritization of data collection and improve efficiency in understanding hazard. To accomplish this, we generated a set of 288 landslide-tsunami simulations in which we systematically varied the size and material properties of possible failure extents at the Barry Arm landslide complex in northwestern Prince William Sound, Alaska, USA. We find that for landslides smaller than the receiving waterbody, the landslide volume has the strongest effect on resulting wave characteristics and thus the highest leverage on reducing uncertainty in tsunami hazard. In contrast, for landslides substantially larger than the waterbody, the duration of rapid movement of the landslide has the highest leverage. Based on our results, we propose a classification scheme for subaerial landslides based on the relative size of the landslide and waterbody. Additionally, our results support the generation of a tsunami height transfer function between existing tide gages and a nearby coastal city. These results have direct implications for the practice of operational early warning.

Alaska