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USGS2008

Effects of forest harvesting on ecosystem health in the headwaters of the New York City Water Supply, Catskill Mountains, New York

The effects of forest clearcutting and selective harvesting on forest soils, soil and stream water chemistry, forest regrowth, and aquatic communities were studied in four small headwater catchments. This research was conducted to identify the sensitivity of forested ecosystems to forest disturbance in the northeastern United States. The study area was in the headwaters of the Neversink Reservoir watershed, part of the New York City water supply system, in the Catskill Mountains of southeastern New York. Two sub-catchments of the Shelter Creek watershed were selectively harvested, one in its northern half and one more heavily in its southern half in 1995?96, the Dry Creek watershed was clearcut in the winter of 1996?97, and the Clear Creek watershed was left undisturbed and monitored as a control site. Monitoring was conducted from 4 years before the harvests until 4 years after the harvests. Clearcutting caused a large release of nitrate (NO3-) from watershed soils and a concurrent release of inorganic monomeric aluminum (Alim), which is toxic to some aquatic biota. The increased soil NO3- concentrations measured after the harvest could be completely accounted for by the decrease in nitrogen (N) uptake by watershed trees, rather than an increase in N mineralization and nitrification. The large increase in stream water NO3- and Alim concentrations caused 100-percent mortality of caged brook trout (Salvelinus fontinalis) during the first year after the clearcut and adversely affected macroinvertebrate communities for 2 years after the harvest. Nutrient uptake and biomass accumulation increased in uncut mature trees after the two selective harvests. There was no increase in stream-water NO3- or Alim concentrations, and so there were no adverse affects on macroinvertebrate or trout communities. The amount of tree biomass that can be removed without causing a sharp increase in stream-water NO3- and Alim stream-water concentrations is unknown, but probably depends on the history of forest-disturbance and acid deposition and the level of soil acidification. Results of this study indicate that macroinvertebrate and brook trout communities were sensitive to clearcutting and that deer browsing may affect water quality by suppressing forest regeneration and nutrient uptake. Further studies of selective harvests could identify the harvesting threshold below which changes in water quality and soil chemistry are minimized, and nutrient retention is maximized, thus reducing the damage that logging can inflict on stream and aquatic communities.

New York↗

USGS2009

Quality of Streams in Johnson County, Kansas, and Relations to Environmental Variables, 2003-07

The quality of streams and relations to environmental variables in Johnson County, northeastern Kansas, were evaluated using water, streambed sediment, land use, streamflow, habitat, algal periphyton (benthic algae), and benthic macroinvertebrate data. Water, streambed sediment, and macroinvertebrate samples were collected in March 2007 during base flow at 20 stream sites that represent 11 different watersheds in the county. In addition, algal periphyton samples were collected twice (spring and summer 2007) at one-half of the sites. Environmental data including water and streambed-sediment chemistry data (primarily nutrients, fecal-indicator bacteria, and organic wastewater compounds), land use, streamflow, and habitat data were used in statistical analyses to evaluate relations between biological conditions and variables that may affect them. This report includes an evaluation of water and streambed-sediment chemistry, assessment of habitat conditions, comparison of biological community attributes (such as composition, diversity, and abundance) among sampling sites, placement of sampling sites into impairment categories, evaluation of biological data relative to environmental variables, and evaluation of changes in biological communities and effects of urbanization. This evaluation is useful for understanding factors that affect stream quality, for improving water-quality management programs, and for documenting changing conditions over time. The information will become increasingly important for protecting streams in the future as urbanization continues. Results of this study indicate that the biological quality at nearly all biological sampling sites in Johnson County has some level of impairment. Periphyton taxa generally were indicative of somewhat degraded conditions with small to moderate amounts of organic enrichment. Camp Branch in the Blue River watershed was the only site that met State criteria for full support of aquatic life in 2007. Since 2003, biological quality improved at one rural sampling site, possibly because of changes in wastewater affecting the site, and declined at three urban sites possibly because of the combined effects of ongoing development. Rural streams in the western and southern parts of the county, with land-use conditions similar to those found at the State reference site (Captain Creek), continue to support some organisms normally associated with healthy streams. Several environmental factors contribute to biological indicators of stream quality. The primary factor explaining biological quality at sites in Johnson County was the amount of urbanization upstream in the watershed. Specific conductance of stream water, which is a measure of dissolved solids in water and is determined primarily by the amount of groundwater contributing to streamflow, the amount of urbanization, and discharges from wastewater and industrial sites, was strongly negatively correlated with biological stream quality as indicated by macroinvertebrate metrics. Concentration of polycyclic aromatic hydrocarbons (PAHs) in streambed sediment also was negatively correlated with biological stream quality. Individual habitat variables that most commonly were positively correlated with biological indicators included stream sinuosity, buffer length, and substrate cover diversity. Riffle substrate embeddedness and sediment deposition commonly were negatively correlated with favorable metric scores. Statistical analysis indicated that specific conductance, impervious surface area (a measure of urbanization), and stream sinuosity explained 85 percent of the variance in macroinvertebrate communities. Management practices affecting environmental variables that appear to be most important for Johnson County streams include protection of stream corridors, measures that reduce the effects of impervious surfaces associated with urbanization, reduction of dissolved solids in stream water, reduction of PAHs entering streams and

Scientific Investigations Report↗

USGS2010

Status and understanding of groundwater quality in the central-eastside San Joaquin Basin, 2006: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,695-square-mile Central Eastside San Joaquin Basin (Central Eastside) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001, and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Central Eastside study unit was designed to provide a spatially unbiased assessment of untreated-groundwater quality, as well as a statistically consistent basis for comparing water quality throughout California. During March through June 2006, samples were collected from 78 wells in Stanislaus and Merced Counties, 58 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 20 of which were sampled to evaluate changes in water chemistry along groundwater-flow paths (understanding wells). Water-quality data from the California Department of Public Health (CDPH) database also were used for the assessment. An assessment of the current status of the groundwater quality included collecting samples from wells for analysis of anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring constituents such as major ions and trace elements. The assessment of status is intended to characterize the quality of untreated-groundwater resources within the primary aquifer system, not the treated drinking water delivered to consumers by water purveyors. The primary aquifer system (hereinafter, primary aquifer) is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the CDPH database for the Central Eastside study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer; shallower groundwater may be more vulnerable to surficial contamination. The primary aquifer is represented by the grid wells, of which 90 percent had depths to the tops of their perforations of about 80 to 330 feet and depths to bottom of about 100 to 670 feet. Relative-concentrations (sample concentration divided by benchmark concentration) were used as the primary metric for assessing the status of water quality for those constituents that have Federal and (or) California human health or aesthetic benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.1), or low (≤0.1). For inorganic constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.5), or low (≤0.5). The threshold between low and moderate classifications was lower for organic and special interest constituents than for inorganic constituents because organic constituents generally are less prevalent and have smaller relative-concentrations than inorganic constituents. Grid-based and spatially-weighted approaches, the latter incorporating data from all CDPH wells, were used to evaluate the proportion of the primary aquifer (aquifer-scale proportions) with high, moderate, or low relative-concentrations. For individual constituents or classes of constituents, the aquifer-scale high proportion is the percentage of the area of the study unit having high relative-concentrations within the depth-zones of the primary aquifer. Aquifer-scale moderate and low proportions are defined similarly. Spatially-weighted aquifer-scale high proportions nearly always fell within the 90-percent confidence interval of grid-based aquifer-scale high proportions, indicating that the grid-based approach yielded statistically equivalent results to the spatially-weighted approach incorporating CDPH data. The status assessment for inorganic constituents showed that inorganic constituents (one or more) were high, relative to human-health benchmarks, in 18.0 percent of the primary aquifer, moderate in 44.0 percent, and low in 38.0 percent. Of inorganic constituents with human-health benchmarks, arsenic, vanadium, and nitrate were detected at high relative-concentrations in 15.6 percent, 3.6 percent, and 2.1 percent, respectively, of the primary aquifer. Of inorganic constituents with secondary maximum contaminant levels (SMCL), manganese, iron, and TDS were detected at high relative-concentrations in 4.5 percent, 2.2 percent, and 1.7 percent, respectively, of the primary aquifer. The status assessment for organic constituents showed that organic constituents (one or more) were high, relative to human-health benchmarks, in a smaller proportion of the primary aquifer (1.2 percent) than inorganic constituents (18.0 percent). Organic constituents had moderate relative-concentrations in 14.3 percent, and had low relative-concentrations or were not detected in 84.5 percent, of the primary aquifer. The proportion of the primary aquifer with high relative-concentrations of organic constituents reflected high proportions of the discontinued soil fumigant 1,2-dibromo-3-chlororopane (DBCP; 1.0 percent) and the solvent tetrachloroethene (PCE; 0.2 percent). Most of the organic and special interest constituents detected in groundwater in the Central Eastside study unit have human-health benchmarks. Of the 205 organic and special interest constituents analyzed for, 36 constituents were detected. Of these constituents, 32 were detected only at low relative-concentrations. Four constituents, chloroform, carbon tetrachloride, DBCP, and perchlorate, were detected at moderate relative-concentrations in grid wells. Nine organic and special-interest constituents were detected frequently (detected in greater than 10 percent of samples): the trihalomethanes chloroform, bromoform, bromodichloromethane, and dibromochloromethane; the solvent PCE; the herbicides atrazine, simazine, and metolachlor, and special-interest constituent perchlorate. An assessment of understanding of the groundwater quality included sampling of understanding wells, some of which were perforated in shallower or deeper portions of the aquifer system than the primary aquifer, and analysis of correlations of groundwater quality with land use, depth, age classification, and other potential explanatory factors. The understanding assessment indicated that the concentrations of many constituents were related to depth and groundwater age. However, concentrations of individual constituents or constituent classes also were sometimes related to geochemical conditions, lateral position in the flow system, or land use. High and moderate relative-concentrations of uranium, nitrate, and total dissolved solids (TDS) were detected in some wells where the tops of perforations are within the upper 200 feet of the aquifer system. In wells with the depth to the top of perforations below this depth, concentrations were low. A similar pattern occurred for the sum of herbicide concentrations. These vertical water-chemistry patterns are consistent with the hydrogeologic setting, in which return flows from agricultural and urban land use are the major source of recharge, and withdrawals for irrigation and urban supply are the major source of discharge, resulting in substantial vertical components of groundwater flow. The decrease in concentrations of many constituents with depth reflects in part that groundwater gets older with depth. Tritium, helium-isotopes, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years, up to tens of thousands of years, ago), and mixed (mixtures of waters with modern and pre-modern ages). Uranium, nitrate, and herbicide concentrations were significantly higher in groundwater having modern- and mixed-ages than pre-modern ages, indicating that these constituents may be affected by anthropogenic activities in the last 50 years. Other patterns in the distribution of nitrate, uranium, and TDS are evident. Isotopic and geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the western and deeper parts of the flow system. Uranium and TDS concentrations increase from east to west across the valley, along the direction of regional lateral groundwater flow. High and moderate relative-concentrations of arsenic can be attributed to reductive dissolution of manganese or iron oxides, or to desorption by high pH waters. Arsenic concentrations also increased with increasing depth and groundwater age. High to moderate relative-concentrations of vanadium primarily are related to high pH under oxic conditions. The frequency of detections of DBCP was greater in areas with orchard-vineyard land use >40 percent and at depths <200 feet. THMs and solvents were correlated positively with percent urban land use. Herbicide concentrations were correlated negatively with percent natural land use. Perchlorate concentrations were significantly greater in waters having modern and mixed ages than waters having pre-modern ages and were significantly and positively correlated with two land uses—percent orchard/vineyard land use and percent urban land use.

California↗

USGS2010

Temporal change in biological community structure in the Fountain Creek basin, Colorado, 2001-2008

In 2001, the U.S. Geological Survey, in cooperation with Colorado Springs City Engineering, began a study to better understand the relations between environmental characteristics and biological communities in the Fountain Creek basin in order to aide water-resource management and guide future monitoring activities. To accomplish this task, environmental (streamflow, habitat, and water chemistry) and biological (fish and macroinvertebrate) data were collected annually at 24 sites over a 6- or 8-year period (fish, 2003 to 2008; macroinvertebrates, 2001 to 2008). For this report, these data were first analyzed to determine the presence of temporal change in macroinvertebrate and fish community structure among years using nonparametric multivariate statistics. Where temporal change in the biological communities was found, these data were further analyzed using additional nonparametric multivariate techniques to determine which subset of selected streamflow, habitat, or water-chemistry variables best described site-specific changes in community structure relative to a gradient of urbanization. This study identified significant directional patterns of temporal change in macroinvertebrate and fish community structure at 15 of 24 sites in the Fountain Creek basin. At four of these sites, changes in environmental variables were significantly correlated with the concurrent temporal change identified in macroinvertebrate and fish community structure (Monument Creek above Woodmen Road at Colorado Springs, Colo.; Monument Creek at Bijou Street at Colorado Springs, Colo.; Bear Creek near Colorado Springs, Colo.; Fountain Creek at Security, Colo.). Combinations of environmental variables describing directional temporal change in the biota appeared to be site specific as no single variable dominated the results; however, substrate composition variables (percent substrate composition composed of sand, gravel, or cobble) collectively were present in 80 percent of the environmental variable subsets that were significantly correlated with temporal change in the macroinvertebrate and fish community structure. Other important environmental variables related to temporal change in the biological community structure included those describing channel form (streambank height) and streamflow (normalized annual mean daily flow, high flood-pulse count). Site-specific results from this study were derived from a relatively small number of observations (6 or 8 years of data); therefore, additional years of data may reveal other sites with temporal change in biological community structure, or could define stronger and more consistent linkages between environmental variables and observed temporal change. Likewise current variable subsets could become weaker. Nonetheless, there were several sites where temporal change was detected in this study that could not be explained by the available environmental variables studied herein. Modification of current data-collection activities may be necessary to better understand site-specific temporal relations between biological communities and environmental variables.

Scientific Investigations Report↗

USGS2011

Meteoric precipitation at Yucca Mountain, Nevada: Chemical and stable isotope analyses, 2006-09

Meteoric precipitation samples collected in 2006-09 at Yucca Mountain, Nevada, were analyzed for chemistry and stable isotope composition. Precipitation is the major source of infiltration to the unsaturated zone and of recharge to the saturated zone at Yucca Mountain. On February 28, 2005, seepage of water was observed about 40 to 80 meters below the ground surface within the Tiva Canyon Tuff in the South Ramp of the Exploratory Studies Facility tunnel within Yucca Mountain. This seepage was preceded by a 5-month period of above-average precipitation. Chemical and isotopic analysis of this seepage could not be used to estimate travel time, extent of water-rock interaction, and (or) evaporative water loss during percolation through the unsaturated zone due to the lack of corresponding chemical and isotopic analyses of precipitation inputs to the infiltration events that produced the seepage. In February 2006, collection of precipitation samples for chemical (major ions), delta oxygen-18 (&delta 18 O), and delta deuterium (&deltaD) analyses began at seven meteorological monitoring stations to provide baseline isotopic and chemical analyses. The sampling stations range in elevation from 1,131 to 1,562 meters. Each site has two collectors-one for chemical analysis and the other for isotopic analysis of precipitation. The collectors were sampled and emptied after each precipitation event. In 2006-09, 36 distinct precipitation events, with an average 3- to 4-day duration and an average 9.9 millimeters of accumulation, have been analyzed. The chemical composition of these samples of Yucca Mountain precipitation is relatively dilute but contains measurable and variable concentrations of Na + , Ca 2+ , NH + , NO 3 - , and SO 4 2- . Dust transported by typical winter storms and generated from soil carbonates is the main contributor to this precipitation chemistry. Elevated nitrate and ammonium concentrations may be linked to agriculture in the nearby Amargosa River valley to the south and west of Yucca Mountain. Cumulatively, &delta 18 O values range from 3.0 to -20.4 per mil (%o) and &deltaD values range from 10 to -14%o. Winter-season precipitation commonly has isotopically lighter compositions. The cumulative &delta18O plotted against &deltaD shows that precipitation samples define a line with slope of 6.4, less than the 8 of the Global Meteoric Water Line. This difference in slope, typical of arid environments, is chiefly the result of evaporation of falling raindrops due to warmer air temperatures. ;

Scientific Investigations Report↗

USGS2011

Toxicity of nickel-spiked freshwater sediments to benthic invertebrates-Spiking methodology, species sensitivity, and nickel bioavailability

This report summarizes data from studies of the toxicity and bioavailability of nickel in nickel-spiked freshwater sediments. The goal of these studies was to generate toxicity and chemistry data to support development of broadly applicable sediment quality guidelines for nickel. The studies were conducted as three tasks, which are presented here as three chapters: Task 1, Development of methods for preparation and toxicity testing of nickel-spiked freshwater sediments; Task 2, Sensitivity of benthic invertebrates to toxicity of nickel-spiked freshwater sediments; and Task 3, Effect of sediment characteristics on nickel bioavailability. Appendices with additional methodological details and raw chemistry and toxicity data for the three tasks are available online at http://pubs.usgs.gov/sir/2011/5225/downloads/.

Scientific Investigations Report↗

USGS2013

Chemical and biological consequences of using carbon dioxide versus acid additions in ocean acidification experiments

Use of different approaches for manipulating seawater chemistry during ocean acidification experiments has confounded comparison of results from various experimental studies. Some of these discrepancies have been attributed to whether addition of acid (such as hydrochloric acid, HCl) or carbon dioxide (CO 2 ) gas has been used to adjust carbonate system parameters. Experimental simulations of carbonate system parameter scenarios for the years 1766, 2007, and 2100 were performed using the carbonate speciation program CO2SYS to demonstrate the variation in seawater chemistry that can result from use of these approaches. Results showed that carbonate system parameters were 3 percent and 8 percent lower than target values in closed-system acid additions, and 1 percent and 5 percent higher in closed-system CO 2 additions for the 2007 and 2100 simulations, respectively. Open-system simulations showed that carbonate system parameters can deviate by up to 52 percent to 70 percent from target values in both acid addition and CO 2 addition experiments. Results from simulations for the year 2100 were applied to empirically derived equations that relate biogenic calcification to carbonate system parameters for calcifying marine organisms including coccolithophores, corals, and foraminifera. Calculated calcification rates for coccolithophores, corals, and foraminifera differed from rates at target conditions by 0.5 percent to 2.5 percent in closed-system CO 2 gas additions, from 0.8 percent to 15 percent in the closed-system acid additions, from 4.8 percent to 94 percent in open-system acid additions, and from 7 percent to 142 percent in open-system CO 2 additions.

Scientific Investigations Report↗

USGS2012

Water-quality characteristics and trend analyses for the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins, Wyoming and Montana, for selected periods, water years 1991 through 2010

The Powder River structural basin in northeastern Wyoming and southeastern Montana is an area of ongoing coalbed natural gas (CBNG) development. Waters produced during CBNG development are managed with a variety of techniques, including surface impoundments and discharges into stream drainages. The interaction of CBNG-produced waters with the atmosphere and the semiarid soils of the Powder River structural basin can affect water chemistry in several ways. Specific conductance and sodium adsorption ratios (SAR) of CBNG-produced waters that are discharged to streams have been of particular concern because they have the potential to affect the use of the water for irrigation. Water-quality monitoring has been conducted since 2001 at main-stem and tributary sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins in response to concerns about CBNG effects. A study was conducted to summarize characteristics of stream-water quality for water years 2001–10 (October 1, 2000, to September 30, 2010) and examine trends in specific conductance, SAR, and primary constituents that contribute to specific conductance and SAR for changes through time (water years 1991–2010) that may have occurred as a result of CBNG development. Specific conductance and SAR are the focus characteristics of this report. Dissolved calcium, magnesium, and sodium, which are primary contributors to specific conductance and SAR, as well as dissolved alkalinity, chloride, and sulfate, which are other primary contributors to specific conductance, also are described. Stream-water quality in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins was variable during water years 2001–10, in part because of variations in streamflow. In general, annual runoff was less than average during water years 2001–06 and near or above average during water years 2007–10. Stream water of the Tongue River had the smallest specific conductance values, sodium adsorption ratios, and major ion concentrations of the main-stem streams. Sites in the Tongue River drainage basin typically had the smallest range of specific conductance and SAR values. The water chemistry of sites in the Powder River drainage basin generally was the most variable as a result of diverse characteristics of that basin. Plains tributaries in the Powder River drainage basin had the largest range of specific conductance and SAR values, in part due to the many tributaries that receive CBNG-produced waters. Trends were analyzed using the seasonal Kendall test with flow-adjusted concentrations to determine changes to water quality through time at sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Trends were evaluated for water years 2001–10 for 17 sites, which generally were on the main-stem streams and primary tributaries. Trends were evaluated for water years 2005–10 for 26 sites to increase the spatial coverage of sites. Trends were evaluated for water years 1991–2010 for eight sites to include water-quality data collected prior to widespread CBNG development and expand the temporal context of trends. Consistent patterns were not observed in trend results for water years 2001–10 for flow-adjusted specific conductance and SAR values in the Tongue, Powder, and Belle Fourche River drainage basins. Significant (p-values less than 0.05) upward trends in flow-adjusted specific conductance values were determined for 3 sites, a downward trend was determined for 1 site, and no significant (p-value greater than 0.05) trends were determined for 13 sites. One of the sites with a significant upward trend was the Tongue River at the Wyoming-Montana State line. No trend in flow-adjusted specific conductance values was determined for the Powder River at Moorhead, Mont. Significant upward trends in flow-adjusted SAR values were determined for 2 sites and no significant trends were determined for 15 sites. No trends in flow-adjusted SAR values were determined for the Tongue River at the Wyoming-Montana State line or for the Powder River at Moorhead, Mont. One of the sites with a significant upward trend in flow-adjusted SAR values was the Powder River at Arvada, Wyo. For water years 2005–10, significant upward trends in flow-adjusted specific conductance values were determined no significant trends were determined for 13 sites. A significant upward trend was determined for flow-adjusted specific conductance values for the Tongue River at the Wyoming-Montana State line. No trend in flow-adjusted specific conductance values was determined for the Powder River at Moorhead, Mont. Significant upward trends in flow-adjusted SAR values were determined for 4 sites, downward trends were determined for 5 sites, and no significant trend was determined for 17 sites. No trends in flow-adjusted SAR values were determined for the Tongue River at the Wyoming-Montana State line or for the Powder River at Moorhead, Mont. Results of the seasonal Kendall test applied to flow-adjusted specific conductance values for water years 1991–2010 indicated no significant trend for eight sites in the Tongue, Powder, and Belle Fourche River drainage basins. No significant trend in flow-adjusted specific conductance was determined for the Tongue River at the Wyoming-Montana State line or the Powder River at Moorhead, Mont. Results of the seasonal Kendall test applied to flow-adjusted SAR values for water years 1991–2010 indicated an upward trend for one site and no significant trend for four sites in the Powder and Belle Fourche River drainage basins. The significant upward trend in flow-adjusted SAR values was determined for the Powder River at Arvada, Wyo., for water years 1991–2010. Results indicate that CBNG development in the Powder River structural basin may have contributed to some trends, such as the upward trend in flow-adjusted SAR for the Powder River at Arvada, Wyo., for water years 1991–2010. An upward trend in flow-adjusted alkalinity concentrations for water years 2001–10 also was determined for the Powder River at Arvada, Wyo. Trend results are consistent with changes that can occur from the addition of sodium and bicarbonate associated with CBNG-produced waters to the Powder River. Upward trends in constituents at other sites, including the Belle Fourche River, may be the result of declining CBNG development, indicating that CBNG-produced waters may have had a dilution effect on some streams. The factors affecting other trends could not be determined because multiple factors could have been affecting the stream-water quality or because trends were observed at sites upstream from CBNG development that may have affected water-quality trends at sites downstream.

Wyoming;Montana↗

USGS2012

Streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, 2008-10

The U.S. Geological Survey-in cooperation with the U.S. Army Corps of Engineers, The Nature Conservancy, the Real Edwards Conservation and Reclamation District, and the Texas Parks and Wildlife Department-investigated streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, specifically in the watersheds of the West Nueces, Nueces, Dry Frio, Frio, and Sabinal Rivers upstream from the Edwards aquifer outcrop. Streamflow in these rivers is sustained by groundwater contributions (for example, from springs) and storm runoff from rainfall events. To date (2012), there are few data available that describe streamflow and water-quality conditions of the rivers within the upper Nueces River Basin. This report describes streamflow gain-loss characteristics from three reconnaissance-level synoptic measurement surveys (hereinafter referred to as "surveys") during 2008-10 in the upper Nueces River Basin. To help characterize the hydrology, groundwater-level measurements were made, and water-quality samples were collected from both surface-water and groundwater sites in the study area from two surveys during 2009-10. The hydrologic (streamflow, springflow, and groundwater) measurements were made during three reconnaissance-level synoptic measurement surveys occurring in July 21-23, 2008; August 8-18, 2009; and March 22-24, 2010. These survey periods were selected to represent different hydrologic conditions. Streamflow gains and losses were based on streamflow and springflow measurements made at 74 sites in the study area, although not all sites were measured during each survey. Possible water chemistry relations among sample types (streamflow, springflow, or groundwater), between surveys, and among watersheds were examined using water-quality samples collected from as many as 20 sites in the study area. During the three surveys, reaches of gaining, losing, or no verifiable change in streamflow were observed in the watersheds in the study area. Reaches of generally consistent gaining or losing streamflow were identified in the Nueces, Frio, and Sabinal River watersheds. The water-quality data indicate that the streamflow, springflow, and groundwater have similar major ion chemical characteristics and generally can be categorized as a calcium-carbonate water type. Those data also indicate that the major ion chemistry was similar during the 2009 and 2010 surveys. Graphical comparisons among ratios of major ions, trace elements, and isotopes (for example, magnesium/calcium ratios to strontium isotopic ratios) indicate that samples collected from each watershed generally clustered together. Determining the source areas and other possible contributors on the basis of these data is not possible because of the small sample size of the water-quality dataset (both in number of samples and spatial distribution of samples). The different relations among the water-quality data indicate that the surface water in the different watersheds is likely influenced by differences in source areas, geochemical evolution, groundwater flow paths and residence time, local stratigraphy, or some combination thereof.

Texas↗

USGS2012

Residence time, chemical and isotopic analysis of nitrate in the groundwater and surface water of a small agricultural watershed in the Coastal Plain, Bucks Branch, Sussex County, Delaware

Nitrate is a common contaminant in groundwater and surface water throughout the Nation, and water-resource managers need more detailed small-scale watershed research to guide conservation efforts aimed at improving water quality. Concentrations of nitrate in Bucks Branch are among the highest in the state of Delaware and a scientific investigation was performed to provide water-quality information to assist with the management of agriculture and water resources. A combination of major-ion chemistry, nitrogen isotopic composition and age-dating techniques was used to estimate the residence time and provide a chemical and isotopic analysis of nitrate in the groundwater in the surficial aquifer of the Bucks Branch watershed in Sussex County, Delaware. The land use was more than 90 percent agricultural and most nitrogen inputs were from manure and fertilizer. The apparent median age of sampled groundwater is 18 years and the estimated residence time of groundwater contributing to the streamflow for the entire Bucks Branch watershed at the outlet is approximately 19 years. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency drinking-water standard of 10 milligrams per liter (as nitrogen) in 60 percent of groundwater samples and 42 percent of surface-water samples. The overall geochemistry in the Bucks Branch watershed indicates that agriculture is the predominant source of nitrate contamination and the observed patterns in major-ion chemistry are similar to those observed in other studies on the Mid-Atlantic Coastal Plain. The pattern of enrichment in nitrogen and oxygen isotopes (δ15N and δ18O) of nitrate in groundwater and surface water indicates there is some loss of nitrate through denitrification, but this process is not sufficient to remove all of the nitrate from groundwater discharging to streams, and concentrations of nitrate in streams remain elevated.

Delaware↗

USGS2013

Preliminary hydrogeologic assessment near Tassi and Pakoon Springs, western part of Grand Canyon-Parashant National Monument, Arizona

Tassi and Pakoon Springs are both in the Grand Wash Trough in the western part of Grand Canyon-Parashant National Monument on the Arizona Strip. The monument is jointly managed by the National Park Service (NPS) and the Bureau of Land Management. This study was in response to NPS’s need to better understand the influence from regional increases in groundwater withdrawals near Grand Canyon-Parashant on the groundwater discharge from Tassi and Pakoon Springs. The climate of the Arizona Strip is generally semiarid to arid, and springs in the monument provide the water for the fragile ecosystems that are commonly separated by large areas of dry washes in canyons with pinyon and juniper. Available hydrogeologic data from previous investigations included water levels from the few existing wells, location information for springs, water chemistry from springs, and geologic maps. Available groundwater-elevation data from the wells and springs in the monument indicate that groundwater in the Grand Wash Trough is moving from north to south, discharging to springs and into the Colorado River. Groundwater may also be moving from east to west from Paleozoic rocks in the Grand Wash Cliffs into sedimentary deposits in the Grand Wash Trough. Finally, groundwater may be moving from the northwest in the Mesoproterozoic crystalline rocks of the Virgin Mountains into the northern part of the Grand Wash Trough. Water discharging from Tassi and Pakoon Springs has a major-ion chemistry similar to that of other springs in the western part of Grand Canyon-Parashant. Stable-isotopic signatures for oxygen-18 and hydrogen-2 are depleted in the water from both Tassi and Pakoon Springs in comparison to other springs on the Arizona Strip. Tassi Spring discharges from multiple seeps along the Wheeler Fault, and the depleted isotopic signatures suggest that water may be flowing from multiple places into Lake Mead and seems to have a higher elevation or an older climate source. Elevated water temperatures and a depleted stable-isotopic signature for Pakoon Springs suggest that the water may be traveling along a deep circulating flowpath, have multiple sources of water, been recharged at a high elevation, and (or) has an older climate source.

Arizona↗

USGS2012

Quality of streams in Johnson County, Kansas, 2002--10

Stream quality in Johnson County, northeastern Kansas, was assessed on the basis of land use, hydrology, stream-water and streambed-sediment chemistry, riparian and in-stream habitat, and periphyton and macroinvertebrate community data collected from 22 sites during 2002 through 2010. Stream conditions at the end of the study period are evaluated and compared to previous years, stream biological communities and physical and chemical conditions are characterized, streams are described relative to Kansas Department of Health and Environment impairment categories and water-quality standards, and environmental factors that most strongly correlate with biological stream quality are evaluated. The information is useful for improving water-quality management programs, documenting changing conditions with time, and evaluating compliance with water-quality standards, total maximum daily loads (TMDLs), National Pollutant Discharge Elimination System (NPDES) permit conditions, and other established guidelines and goals. Constituent concentrations in water during base flow varied across the study area and 2010 conditions were not markedly different from those measured in 2003, 2004, and 2007. Generally the highest specific conductance and concentrations of dissolved solids and major ions in water occurred at urban sites except the upstream Cedar Creek site, which is rural and has a large area of commercial and industrial land less than 1 mile upstream on both sides of the creek. The highest base-flow nutrient concentrations in water occurred downstream from wastewater treatment facilities. Water chemistry data represent base-flow conditions only, and do not show the variability in concentrations that occurs during stormwater runoff. Constituent concentrations in streambed sediment also varied across the study area and some notable changes occurred from previously collected data. High organic carbon and nutrient concentrations at the rural Big Bull Creek site in 2003 decreased to at least one-fourth of those concentrations in 2007 and 2010 likely because of the reduction in upstream wastewater discharge contributions. The highest concentrations of trace metals in 2010 occurred at urban sites on Mill and Indian Creeks. Zinc was the only metal to exceed the probable effects concentration in 2010, which occurred at a site on Indian Creek. In 2007, chromium and nickel at the upstream urban Cedar Creek site exceeded the probable effects concentrations, and in 2003, no metals exceeded the probable effects concentrations. Of 72 organic compounds analyzed in streambed sediment, 26 were detected including pesticides, polycyclic aromatic hydrocarbons (PAHs), fuel products, fragrances, preservatives, plasticizers, manufacturing byproducts, flame retardants, and disinfectants. All 6 PAH compounds analyzed were detected, and the probable effects concentrations for 4 of the 6 PAH compounds analyzed were exceeded in 2010. Only five pesticide compounds were detected in streambed sediment, including carbazole and four pyrethroid compounds. Chronic toxicity guidelines for pyrethroid compounds were exceeded at five sites. Biological conditions reflected a gradient in urban land use, with the less disturbed streams located in rural areas of Johnson County. About 19 percent of sites in 2010 (four sites) were fully supporting of aquatic life on the basis of the four metrics used by Kansas Department of Health and Environment to categorize sites. This is a notable difference compared to previous years when no sites (in 2003 and 2004) or just one site (in 2007) was fully supporting of aquatic life. Multimetric macroinvertebrate scores improved at the Big Bull Creek site where wastewater discharges were reduced in 2007. Environmental variables that consistently were highly negatively correlated with biological conditions were percent impervious surface and percent urban land use. In addition, density of stormwater outfall points adjacent to streams was significantly negatively correlated with biological conditions. Specific conductance of water and sum of PAH concentrations in streambed sediment also were significantly negatively correlated with biological conditions. Total nitrogen in water and total phosphorus in streambed sediment were correlated with most of the invertebrate variables, which is a notable difference from previous analyses using smaller datasets, in which nutrient relations were weak or not detected. The most important habitat variables were sinuosity, length and continuity of natural buffers, riffle substrate embeddedness, and substrate cover diversity, each of which was correlated with all invertebrate metrics including a 10-metric combined score. Correlation analysis indicated that if riparian and in-stream habitat conditions improve then so might invertebrate communities and stream biological quality. Sixty-two percent of the variance in macroinvertebrate community metrics was explained by the single environmental factor, percent impervious surface. Invertebrate responses to urbanization in Johnson County indicated linearity rather than identifiable thresholds. Multiple linear regression models developed for each of the four macroinvertebrate metrics used to determine aquatic-life-support status indicated that percent impervious surface, as a measure of urban land use, explained 34 to 67 percent of the variability in biological communities. Results indicate that although multiple factors are correlated with stream quality degradation, general urbanization, as indicated by impervious surface area or urban land use, consistently is determined to be the fundamental factor causing change in stream quality. Effects of urbanization on Johnson County streams are similar to effects described in national studies that assess effects of urbanization on stream health. Individually important environmental factors such as specific conductance of water, PAHs in streambed sediment, and stream buffer conditions, are affected by urbanization and, collectively, all contribute to stream impairments. Policies and management practices that may be most important in protecting the health of streams in Johnson County are those minimizing the effects of impervious surface, protecting stream corridors, and decreasing the loads of sediment, nutrients, and toxic chemicals that directly enter streams through stormwater runoff and discharges.

Kansas↗

USGS2013

Springs, streams, and gas vent on and near Mount Adams volcano, Washington

Springs and some streams on Mount Adams volcano have been sampled for chemistry and light stable isotopes of water. Spring temperatures are generally cooler than air temperatures from weather stations at the same elevation. Spring chemistry generally reflects weathering of volcanic rock from dissolved carbon dioxide. Water in some springs and streams has either dissolved hydrothermal minerals or has reacted with them to add sulfate to the water. Some samples appear to have obtained their sulfate from dissolution of gypsum while some probably involve reaction with sulfide minerals such as pyrite. Light stable isotope data for water from springs follow a local meteoric water line, and the variation of isotopes with elevation indicate that some springs have very local recharge and others have water from elevations a few hundred meters higher. No evidence was found for thermal or slightly thermal springs on Mount Adams. A sample from a seeping gas vent on Mount Adams was at ambient temperature, but the gas is similar to that found on other Cascade volcanoes. Helium isotopes are 4.4 times the value in air, indicating that there is a significant component of mantle helium. The lack of fumaroles on Mount Adams and the ambient temperature of the gas indicates that the gas is from a hydrothermal system that is no longer active.

Washington↗

USGS2013

Relation between organic-wastewater compounds, groundwater geochemistry, and well characteristics for selected wells in Lansing, Michigan

In 2010, groundwater from 20 Lansing Board of Water and Light (BWL) production wells was tested for 69 organic-wastewater compounds (OWCs). The OWCs detected in one-half of the sampled wells are widely used in industrial and environmental applications and commonly occur in many wastes and stormwater. To identify factors that contribute to the occurrence of these constituents in BWL wells, the U.S. Geological Survey (USGS) interpreted the results of these analyses and related detections of OWCs to local characteristics and groundwater geochemistry. Analysis of groundwater-chemistry data collected by the BWL during routine monitoring from 1969 to 2011 indicates that the geochemistry of the BWL wells has changed over time, with the major difference being an increase in sodium and chloride. The concentrations of sodium and chloride were positively correlated to frequency of OWC detections. The BWL wells studied are all completed in the Saginaw aquifer, which consists of water-bearing sandstones of Pennsylvanian age. The Saginaw aquifer is underlain by the Parma-Bayport aquifer, and overlain by the Glacial aquifer. Two possible sources of sodium and chloride were evaluated: basin brines by way of the Parma-Bayport aquifer, and surficial sources by way of the Glacial aquifer. To determine if water from the underlying aquifer had influenced well-water geochemistry over time, the total dissolved solids concentration and changes in major ion concentrations were examined with respect to well depth, age, and pumping rate. To address a possible surficial source of sodium and chloride, 25 well, aquifer, or hydrologic characteristics, and 2 groundwater geochemistry variables that might influence whether, or the rate at which, water from the land surface could reach each well were compared to OWC detections and well chemistry. The statistical tests performed during this study, using available variables, indicated that reduced time of travel of water from the land surface to the well opening was significantly correlated with detections of OWCs. No specific well or aquifer characteristic was correlated with OWC detections; however, wells with detections tended to have less modeled confining material thickness (as simulated in the regional groundwater flow model), which is an estimate of the amount of clay or shale between the Glacial and Saginaw aquifers. Additional analyses and collection of other data would be required to more conclusively identify the source and to determine the potential vulnerability of other wells because each BWL well may have a somewhat unique set of characteristics that governs its response to pumping. Therefore, it is possible that a relevant explanatory variable was not included in this analysis. The current patterns of geochemistry, and the relation between these patterns and volume of pumpage for the BWL wells, indicates other wells may be susceptible to OWCs in the future.

Michigan↗

USGS2014

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents and evaluates natural and human-related processes that affect water quality. Findings are synthesized to assess the vulnerability of the Denver Basin aquifer system to groundwater contamination. The chemistry of groundwater samples collected from the water-table wells was generally different from that of samples collected from the bedrock-aquifer wells. Samples from the water-table wells tended to have higher concentrations of total dissolved solids and most major ions. Concentrations of several constituents with potential human-health concerns, including nitrate, selenium, uranium, and arsenic, decreased with depth and were highest in samples from the water-table wells. Exceedances of drinking-water standards and water-quality benchmarks were more frequently associated with shallow groundwater samples; concentrations of total dissolved solids and sulfate exceeded water-quality benchmarks for about half or more of samples from the water-table wells. The sediments and rocks of the Denver Basin are natural sources of the trace elements selenium, uranium, and arsenic, which affect their concentrations in groundwater. Detections of organic contaminants, which are typically indicative of human sources of contamination to groundwater, were more frequent in samples from the water-table wells. Pesticide compounds and volatile organic compounds were detected in 33 and 62 percent, respectively, of water-table well samples. Detected organic contaminant concentrations were much less than the associated drinking-water standards. Samples collected from the bedrock aquifers had lower concentrations of total dissolved solids than did samples collected from the water-table wells, although within the bedrock-aquifer samples, concentrations increased from the Dawson to Denver to Arapahoe to Laramie-Fox Hills aquifers. Concentrations of total dissolved solids and many constituents varied spatially and with depth in the bedrock aquifers, likely as a result of ion-exchange and oxidation-reduction reactions, which are important processes affecting water quality. Major-ion chemistry generally evolved from a calcium-bicarbonate to calcium-sulfate composition, with some sodium-bicarbonate and sodium-sulfate facies in the deeper bedrock aquifers, likely resulting from longer residence times and more extensive water-rock interaction. Oxidation-reduction conditions generally evolved from oxic at the water table to anoxic with increasing depth in the bedrock aquifers. Most samples from the bedrock aquifers were anoxic. Exceedances of drinking-water standards and water-quality benchmarks for the bedrock aquifers occurred in 1 percent or less of samples for nitrate, selenium, or arsenic; there were no exceedances for uranium. Exceedances for total dissolved solids, sulfate, manganese, and iron were generally between about 10 and 20 percent for the bedrock-aquifer samples. Radon concentrations, which were only measured in samples collected from two of the bedrock aquifers, exceeded the lower proposed drinking-water standard for more than 90 percent of samples but exceeded the higher alternative standard for less than 5 percent of samples. Pesticide compounds and volatile organic compounds were detected in 3 and 22 percent, respectively, of bedrock-aquifer samples, all at concentrations that were that were much less than drinking-water standards. Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Colorado↗

USGS2014

Effects of wastewater effluent discharge and treatment facility upgrades on environmental and biological conditions of Indian Creek, Johnson County, Kansas, June 2004 through June 2013

Indian Creek is one of the most urban drainage basins in Johnson County, Kansas, and environmental and biological conditions of the creek are affected by contaminants from point and other urban sources. The Johnson County Douglas L. Smith Middle Basin (hereafter referred to as the “Middle Basin”) and Tomahawk Creek Wastewater Treatment Facilities (WWTFs) discharge to Indian Creek. In summer 2010, upgrades were completed to increase capacity and include biological nutrient removal at the Middle Basin facility. There have been no recent infrastructure changes at the Tomahawk Creek facility; however, during 2009, chemically enhanced primary treatment was added to the treatment process for better process settling before disinfection and discharge with the added effect of enhanced phosphorus removal. The U.S. Geological Survey, in cooperation with Johnson County Wastewater, assessed the effects of wastewater effluent on environmental and biological conditions of Indian Creek by comparing two upstream sites to four sites located downstream from the WWTFs using data collected during June 2004 through June 2013. Environmental conditions were evaluated using previously and newly collected discrete and continuous data and were compared with an assessment of biological community composition and ecosystem function along the upstream-downstream gradient. This study improves the understanding of the effects of wastewater effluent on stream-water and streambed sediment quality, biological community composition, and ecosystem function in urban areas. After the addition of biological nutrient removal to the Middle Basin WWTF in 2010, annual mean total nitrogen concentrations in effluent decreased by 46 percent, but still exceeded the National Pollutant Discharge Elimination System (NPDES) wastewater effluent permit concentration goal of 8.0 milligrams per liter (mg/L); however, the NPDES wastewater effluent permit total phosphorus concentration goal of 1.5 mg/L or less was achieved at the Middle Basin WWTF. At the Tomahawk Creek WWTF, after the addition of chemically enhanced primary treatment in 2009, effluent discharges also had total phosphorus concentrations below 1.5 mg/L. After the addition of biological nutrient removal, annual total nitrogen and phosphorus loads from the Middle Basin WWTF decreased by 42 and 54 percent, respectively, even though effluent volume increased by 11 percent. Annual total phosphorus loads from the Tomahawk Creek WWTF after the addition of chemically enhanced primary treatment decreased by 54 percent despite a 33-percent increase in effluent volume. Total nitrogen and phosphorus from the WWTFs contributed between 30 and nearly 100 percent to annual nutrient loads in Indian Creek depending on streamflow conditions. In-stream total nitrogen primarily came from wastewater effluent except during years with the highest streamflows. Most of the in-stream total phosphorus typically came from effluent during dry years and from other urban sources during wet years. During 2010 through 2013, annual mean discharge from the Middle Basin WWTF was about 75 percent of permitted design capacity. Annual nutrient loads likely will increase when the facility is operated at permitted design capacity; however, estimated maximum annual nutrient loads from the Middle Basin WWTF were 27 to 38 percent lower than before capacity upgrades and the addition of biological nutrient removal to treatment processes. Thus, the addition of biological nutrient removal to the Middle Basin wastewater treatment process should reduce overall nutrient loads from the facility even when the facility is operated at permitted design capacity. The effects of wastewater effluent on the water quality of Indian Creek were most evident during below-normal and normal streamflows (about 75 percent of the time) when wastewater effluent represented about 24 percent or more of total streamflow. Wastewater effluent had the most substantial effect on nutrient concentrations in Indian Creek. Total and inorganic nutrient concentrations at the downstream sites during below-normal and normal streamflows were 10 to 100 times higher than at the upstream sites, even after changes in treatment practices at the WWTFs. Median total phosphorus concentrations during below-normal and normal streamflows at a downstream site were 43 percent lower following improvements in wastewater treatment processes. Similar decreases in total nitrogen were not observed, likely because total nitrogen concentrations only decreased in Middle Basin effluent and wastewater contributed a higher percentage to streamflows when nutrient samples were collected during the after-upgrade period. The wastewater effluent discharges to Indian Creek caused changes in stream-water quality that may affect biological community structure and ecosystem processes, including higher concentrations of bioavailable nutrients (nitrate and orthophosphorus) and warmer water temperatures during winter months. Other urban sources of contaminants also caused changes in stream-water quality that may affect biological community structure and ecosystem processes, including higher turbidities downstream from construction areas and higher specific conductance and chloride concentrations during winter months. Chloride concentrations exceeded acute and chronic exposure criteria at all Indian Creek study sites, regardless of wastewater influence, for weeks or months during winter. Streambed sediment chemistry was affected by wastewater (elevated nutrient and organic wastewater-indicator compound concentrations) and other contaminants from urban sources (elevated polyaromatic hydrocarbon concentrations). Overall habitat conditions were suboptimal or marginal at all sites; general decline in habitat conditions along the upstream-downstream gradient likely was caused by the cumulative effects of urbanization with increasing drainage basin size. Wastewater effluent likely affected algal periphyton biomass and community composition, primary production, and community respiration in Indian Creek. Functional stream health, evaluated using a preliminary framework based on primary production and community respiration, was mildly or severely impaired at most downstream sites relative to an urban upstream Indian Creek site. The mechanistic cause of the changes in these biological variables are unclear, though elevated nutrient concentrations were positively correlated with algal biomass, primary production, and community respiration. Macroinvertebrate communities indicated impairment at all sites, and Kansas Department of Health and Environment aquatic life support scores indicated conditions nonsupporting of aquatic life, regardless of wastewater influences. Urban influences, other than wastewater effluent discharge, likely control macroinvertebrate community structure in Indian Creek. Changes in treatment processes at the Middle Basin and Tomahawk Creek WWTFs improved wastewater effluent quality and decreased nutrient loads, but wastewater effluent discharges still had negative effects on the environmental and biological conditions at downstream Indian Creek sites. Wastewater effluent discharge into Indian Creek likely contributed to changes in measures of ecosystem structure (streamflow, water and streambed-sediment chemistry, algal biomass, and algal periphyton community composition) and function (primary production and community respiration) along the upstream-downstream gradient. Wastewater effluent discharges maintained streamflows and increased nutrient concentrations, algal biomass, primary production, and community respiration at the downstream sites. Functional stream health was severely impaired downstream from the Middle Basin WWTF and mildly impaired downstream from the Tomahawk WWTF relative to the urban upstream site. As distance from the Middle Basin WWTF increased, nutrient concentrations, algal biomass, primary production, and community respiration decreased, and functional stream health was no longer impaired 9.5 kilometers downstream from the discharge relative to the urban upstream site. Therefore, although wastewater effluent caused persistent changes in environmental and biological conditions and functional stream health at sites located immediately downstream from WWTF effluent discharges, some recovery to conditions more similar to the urban upstream site occurred within a relatively short distance.

Kansas↗

USGS2015

Characterization of hydrology and water quality of Piceance Creek in the Alkali Flat area, Rio Blanco County, Colorado, March 2012

Previous studies by the U.S. Geological Survey identified Alkali Flat as an area of groundwater upwelling, with increases in concentrations of total dissolved solids, and streamflow loss, but additional study was needed to better characterize these observations. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, White River Field Office, conducted a study to characterize the hydrology and water quality of Piceance Creek in the Alkali Flat area of Rio Blanco County, Colorado. Water-quality samples were collected at five springs on March 27, 2012, to determine field properties, major ions, trace elements, and stable isotopes of water. Major-ion and trace-element chemistry indicated that the springs sampled as part of this study were likely recharged by the bedrock aquifer. Isotopic values for the springs plotted close to that of groundwater from the Parachute Creek Member of the Green River Formation, and the isotopic values from both of these sources are similar to the values for Grand Mesa snow. Based on fluoride, lithium, and strontium concentrations, one spring appeared to have different source water than the other four springs. The spring also had higher concentrations of calcium, magnesium, and sulfate relative to the other four springs. Trace-element and major-ion data indicate that this spring was sourced from the Uinta Formation. It was likely the other four springs were primarily sourced from the lower part of the Parachute Creek Member of the Green River Formation as indicated by low sulfate concentrations and high fluoride, lithium, and boron concentrations. Water-quality samples were collected at 16 surface-water-quality sites on March 14, 2012, to determine field properties, major ions, and trace elements. Sodium was the dominant cation and concentrations increased steadily from upstream to downstream along the study reach. Calcium, magnesium, and potassium concentrations remained relatively stable along the study reach. Strontium concentrations were relatively stable along the study reach, whereas boron and lithium concentrations increased appreciably at site PC22031 and remained elevated to the end of the study reach. Loading profiles were used to further refine areas of spring and groundwater input and streamflow gains and losses. Although there was a minor gain in streamflow from sites PC21543 to PC21816 (58 to 59 cubic feet per second (ft 3 /s) during March 2014), the observed increase in dissolved solids load indicated groundwater contribution to Piceance Creek between these two sites. From sites PC22737 to PC22980, dissolved solids load decreased, which was not observed in concentration profiles and indicated that streamflow loss occurred between these two sites. Barium, boron, lithium, and strontium loads showed similar patterns to that of the major ions along the study reach and indicated similar areas of groundwater gain and loss. Boron and lithium load were not observed to decrease in a similar pattern to that of barium and strontium load which would suggest the contribution to the stream from sources with similar chemistry to that of spring sites PCSP2 through PCSP5. Sodium, chloride, and bicarbonate loads increased and decreased along the study reach in a pattern similar to that of dissolved solids load. A chemical mass balance was used to estimate the amount of groundwater and (or) spring water that contributed to the observed changes in water quality along Piceance Creek. This analysis indicated only 5 percent spring water would need to reach Piceance Creek to result in the observed changes in water quality. Instantaneous streamflow was measured from sites PC20133 to PC23721 during field reconnaissance (February 2012) and during synoptic sampling (March 2012). During both February and March, the study reach from sites PC20133 to PC23721 was a losing reach with net losses that ranged from 0.5 ft 3 /s (February) to 3 ft 3 /s (March). Observed changes in streamflow along the study reach helped to depict interactions between groundwater and surface water in the Alkali Flat area. Water-quality samples were collected at five surface-water sites in December 2010 that were sampled as part of a previous USGS study in 2000. Water-quality data collected during December 2010 showed no appreciable difference from water-quality data collected during December 2000 at the five sites.

Colorado↗

USGS2016

Budgets and chemical characterization of groundwater for the Diamond Valley flow system, central Nevada, 2011–12

The Diamond Valley flow system consists of six hydraulically connected hydrographic areas in central Nevada. The general down-gradient order of the areas are southern and northern Monitor Valleys, Antelope Valley, Kobeh Valley, Stevens Basin, and Diamond Valley. Groundwater flow in the Diamond Valley flow system terminates at a large playa in the northern part of Diamond Valley. Concerns relating to continued water-resources development of the flow system resulted in a phased hydrologic investigation that began in 2005 by the U.S. Geological Survey in cooperation with Eureka County. This report presents the culmination of the phased investigation to increase understanding of the groundwater resources of the basin-fill aquifers in the Diamond Valley flow system through evaluations of groundwater chemistry and budgets. Groundwater chemistry was characterized using major ions and stable isotopes from groundwater and precipitation samples. Groundwater budgets accounted for all inflows, outflows, and changes in storage, and were developed for pre-development (pre-1950) and recent (average annual 2011–12) conditions. Major budget components include groundwater discharge by evapotranspiration and groundwater withdrawals; groundwater recharge by precipitation, and interbasin flow; and storage change. Groundwater in the basin-fill aquifer of the Diamond Valley flow system was mostly a calcium or sodium bicarbonate water type and generally within acceptable drinking-water standards. The general water type was similar among the individual hydrographic areas. Stable isotopes of oxygen-18 and deuterium from precipitation varied seasonally, such that enrichment from evaporation was greater during warmer months than cooler months. The isotopic signature of shallow groundwater was similar to cool season precipitation, indicating recharge was relatively recent (similar to recent climatic conditions) and was derived from cool season precipitation. Site-scale groundwater evapotranspiration was estimated from eddy-covariance and micrometeorological measurements collected at four sites and ranged from 0.15 feet per year in sparse, undisturbed shrubland to 1.13 feet per year in a grassland meadow. Vegetation indices calculated from satellite imagery and field mapping were used to define three evapotranspiration units (shrubland, grassland, and playa) and to extrapolate site-scale groundwater evapotranspiration rates to basin-scale estimates. Annual pre-development groundwater evapotranspiration for individual hydrographic areas ranged from 2,900 acre-feet per year (acre-ft/yr) in northern Monitor Valley to 35,000 acre-ft/yr in Diamond Valley. Total groundwater evapotranspiration from the Diamond Valley flow system under pre-development conditions was about 70,000 acre-ft/yr. Areas of irrigated land in the Diamond Valley flow system increased from less than 5,000 acres in the early 1960s to more than 25,000 acres in 2012 and are mostly for growing alfalfa in southern Diamond Valley. Annual (2011–12) net groundwater withdrawals for irrigation, assumed to be the volume of groundwater consumed by crops and pastureland, ranged from about 420 acre-ft/yr in Antelope Valley to 67,000 acre-ft/yr in Diamond Valley. Total net groundwater withdrawals for irrigation in the Diamond Valley flow system were about 69,000 acre-ft/yr (2011–12). Groundwater recharge, the largest inflow component to the Diamond Valley flow system, was determined as the sum of groundwater evapotranspiration and net subsurface outflow (subsurface outflow minus subsurface inflow). Annual groundwater recharge estimates ranged from 200 acre-ft/yr in Stevens Basin to 35,000 acre-ft/yr in Diamond Valley. Subsurface flow between hydrographic basins was evaluated using estimated transmissivity, groundwater-flow sections derived from remotely sensed imagery, and hydraulic gradients determined from 2012 water-level data. Subsurface outflow ranged from 0 acre-ft/yr for Diamond Valley to 3,400 acre-ft/yr for northern Monitor Valley into western Kobeh Valley. Subsurface inflow ranged from 0 acre-ft/yr for southern Monitor Valley to 4,200 acre-ft/yr for Kobeh Valley from northern Monitor and Antelope Valleys. The pre-development, steady state, groundwater budget for the Diamond Valley flow system was estimated at about 70,000 acre-ft/yr of inflow and outflow. During years 2011–12, inflow components of groundwater recharge from precipitation and subsurface inflow from adjacent basins totaled 70,000 acre-ft/yr for the DVFS, whereas outflow components included 64,000 acre-ft/yr of groundwater evapotranspiration and 69,000 acre-ft/yr of net groundwater withdrawals, or net pumpage. Spring discharge in northern Diamond Valley declined about 6,000 acre-ft/yr between pre-development time and years 2011–12. Assuming net groundwater withdrawals minus spring flow decline is equivalent to the storage change, the 2011–12 summation of inflow and storage change was balanced with outflow at about 133,000 acre-ft/yr.

Nevada↗