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At least 1,243 records · Page 69Linked to original sources
USGS2013

Volatile fluxes through the Big Bend section of the San Andreas Fault, California: helium and carbon-dioxide systematics

To investigate the source of volatiles and their relationship to the San Andreas Fault System (SAFS), 18 groundwater samples were collected from wells near the Big Bend section of the SAFS in southern California and analyzed for helium and carbon abundance and isotopes. Concentrations of 4 He, corrected for air-bubble entrainment, vary from 4.15 to 62.7 (× 10 − 8 ) cm 3 STP g − 1 H 2 O. 3 He/ 4 He ratios vary from 0.09 to 3.52 R A (where R A = air 3 He/ 4 He), consistent with up to 44% mantle helium in samples. A subset of 10 samples was analyzed for the major volatile phase (CO 2 ) — the hypothesized carrier phase of the helium in the mantle–crust system: CO 2 / 3 He ratios vary from 0.614 to 142 (× 10 11 ), and δ 13 C (CO 2 ) values vary from − 21.5 to − 11.9‰ (vs. PDB). 3 He/ 4 He ratios and CO 2 concentrations are highest in the wells located in the Mil Potrero and Cuddy valleys adjacent to the SAFS. The elevated 3 He/ 4 He ratios are interpreted to be a consequence of a mantle volatile flux though the SAFS diluted by radiogenic He produced in the crust. Samples with the highest 3 He/ 4 He ratios also had the lowest CO 2 / 3 He ratios. The combined helium isotope, He–CO 2 elemental relationships, and δ 13 C (CO 2 ) values of the groundwater volatiles reveal a mixture of mantle and deep crustal (metamorphic) fluid origins. The flux of fluids into the seismogenic zone at high hydrostatic pressure may cause fault rupture, and transfer volatiles into the shallow crust. We calculate an upward fluid flow rate of 147 mm a − 1 along the SAFS, up to 37 times higher than previous estimates (Kennedy et al., 1997). However, using newly identified characteristics of the SAFS, we calculate a total flux of 3 He along the SAFS of 7.4 × 103 cm 3 STP a − 1 (0.33 mol 3 He a − 1 ), and a CO 2 flux of 1.5 × 10 13 cm 3 STP a − 1 (6.6 × 10 8 mol a − 1 ), ~ 1% of previous estimates. Lower fluxes along the Big Bend section of the SAFS suggest that the flux of mantle volatiles alone is insufficient to cause the super hydrostatic pressure in the seismogenic zone; however, results identify crustal (metamorphic) fluids as a major component of the CO 2 volatile budget, which may represent the additional flux necessary for fault weakening pressure in the SAFS.

California↗
USGS2025

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California↗
USGS2017

Enhanced coal-dependent methanogenesis coupled with algal biofuels: Potential water recycle and carbon capture

Many coal beds contain microbial communities that can convert coal to natural gas (coalbed methane). Native microorganisms were obtained from Powder River Basin (PRB) coal seams with a diffusive microbial sampler placed downhole and used as an inoculum for enrichments with different nutrients to investigate microbially-enhanced coalbed methane production (MECoM). Coal-dependent methanogenesis more than doubled when yeast extract (YE) and several less complex components (proteins and amino acids) were added to the laboratory microcosms. Stimulated coal-dependent methanogenesis with peptone was 86% of that with YE while glutamate-stimulated activity was 65% of that with YE, and a vitamin mix had only 33% of the YE stimulated activity. For field application of MECoM, there is interest in identifying cost-effective alternatives to YE and other expensive nutrients. In laboratory studies, adding algal extract (AE) with lipids removed stimulated coal-dependent methanogenesis and the activity was 60% of that with YE at 27 d and almost 90% of YE activity at 1406 d. Analysis of British Thermal Unit (BTU) content of coal (a measure of potential energy yield) from long-term incubations indicated > 99.5% of BTU content remained after coalbed methane (CBM) stimulation with either AE or YE. Thus, the coal resource remains largely unchanged following stimulated microbial methane production. Algal CBM stimulation could lead to technologies that utilize coupled biological systems (photosynthesis and methane production) that sustainably enhance CBM production and generate algal biofuels while also sequestering carbon dioxide (CO 2 ).

International Journal of Coal Geology↗
USGS2019

Aluminum- and iron-based coagulation for in-situ removal of dissolved organic carbon, disinfection byproducts, mercury and other constituents from agricultural drain water

Agricultural production on wetland soils can be significant sources of dissolved organic carbon (DOC), disinfection byproduct precursors, mercury and nutrients to downstream water bodies and accelerate land subsidence. Presented as a potential solution for in-situ water quality improvement and land subsidence mitigation, chemically enhanced treatment wetlands (CETWs) were used to leverage both coagulation and wetland processes. In this study, we evaluated the performance of coagulants ferric sulfate (Fe dosing) and polyaluminum chloride (Al dosing) to remove pollutants from agricultural drain water using the coagulation system designed for CETWs. Both coagulation treatments removed over 70% DOC from source waters, resulting in removal efficiencies (mg-DOC removed per mg-metal dosed) of 1 under Al dosing and 0.5 under Fe dosing. Coagulation by both treatments preferentially removed UV254 active compounds compared to the bulk DOC concentration, suggesting coagulation targeted aromatics more effectively. Phosphates and haloacetic acids were also removed more readily, whereas trihalomethanes, dissolved organic nitrogen and filtered mercury species were removed at similar or lower rates than DOC. Dissolved inorganic nitrogen was not amenable to coagulation and removal was not observed. Freundlich, Langmuir and Monod models explained 33% of the variance for Al dosing and 78 – 89% of the variance for Fe dosing. All three models indicated Al dosing had higher removal efficiency and affinity for DOC than Fe dosing under study conditions, but when used to predict maximum removal efficiency there was no cohesiveness between the three models due to different model assumptions. Consideration of fluorescence dissolved organic matter and UV254 as surrogates for DOC concentration showed both were equally suitable before coagulant application, but as surrogates after coagulant application, neither could be deemed more fit as a surrogate since both were shown suitable for different treatment scenarios.

Ecological Engineering↗
USGS2008

The Importance of Uncertainty and Sensitivity Analysis in Process-based Models of Carbon and Nitrogen Cycling in Terrestrial Ecosystems with Particular Emphasis on Forest Ecosystems — Selected Papers from a Workshop Organized by the International Society for Ecological Modelling (ISEM) at the Third Biennal Meeting of the International Environmental Modelling and Software Society (IEMSS) in Burlington, Vermont, USA, August 9-13, 2006

Many process-based models of carbon (C) and nitrogen (N) cycles have been developed for terrestrial ecosystems, including forest ecosystems. They address many basic issues of ecosystems structure and functioning, such as the role of internal feedback in ecosystem dynamics. The critical factor in these phenomena is scale, as these processes operate at scales from the minute (e.g. particulate pollution impacts on trees and other organisms) to the global (e.g. climate change). Research efforts remain important to improve the capability of such models to better represent the dynamics of terrestrial ecosystems, including the C, nutrient, (e.g. N) and water cycles. Existing models are sufficiently well advanced to help decision makers develop sustainable management policies and planning of terrestrial ecosystems, as they make realistic predictions when used appropriately. However, decision makers must be aware of their limitations by having the opportunity to evaluate the uncertainty associated with process-based models ( Smith and Heath, 2001 and Allen et al., 2004 ). The variation in scale of issues currently being addressed by modelling efforts makes the evaluation of uncertainty a daunting task.

Ecological Modelling↗
USGS2017

Simulating the effects of management practices on cropland soil organic carbon changes in the Temperate Prairies Ecoregion of the United States from 1980 to 2012

Understanding the effects of management practices on soil organic carbon (SOC) is important for designing effective policies to mitigate greenhouse gas emissions in agriculture. In the Midwest United States, management practices in the croplands have been improved to increase crop production and reduce SOC loss since the 1980s. Many studies of SOC dynamics in croplands have been performed to understand the effects of management, but the results are still not conclusive. This study quantified SOC dynamics in the Midwest croplands from 1980 to 2012 with the General Ensemble Biogeochemical Modelling System (GEMS) and available management data. Our results showed that the total SOC in the croplands decreased from 1190 Tg C in 1980 to 1107 TgC in 1995, and then increased to 1176 TgC in 2012. Continuous cropping and intensive tillage may have driven SOC loss in the early period. The increase of crop production and adoption of conservation tillage increased the total SOC so that the decrease in the total SOC stock after 32 years was only 1%. The small change in average SOC did not reflect the large spatial variations of SOC change in the region. Major SOC losses occurred in the north and south of the region, where SOC baseline values were high and cropland production was low. The SOC gains took place in the central part of the region where SOC baseline values were moderate and cropland production was higher than the other areas. We simulated multiple land-use land-cover (LULC) change scenarios and analyzed the results. The analysis showed that among all the LULC changes, agricultural technology that increased cropland production had the greatest impact on SOC changes, followed by the tillage practices, changes in crop species, and the conversions of cropland to other land use. Information on management practice induced spatial variation in SOC can be useful for policy makers and farm managers to develop long-term management strategies for increasing SOC sequestration in different areas.

Ecological Modelling↗
USGS2021

Changes in organic carbon source and storage with sea level rise-induced transgression in a Chesapeake Bay marsh

Organic matter (OM) accumulation in marsh soils affects marsh survival under rapid sea-level rise (SLR). This work describes the changing organic geochemistry of a salt marsh located in the Blackwater National Wildlife Refuge on the eastern shore of Chesapeake Bay that has transgressed inland with SLR over the past 35–75 years. Marsh soils and vegetation were sampled along an elevation gradient from the intertidal zone to the adjacent forest, representing a space-for-time substitution of the process of marsh transgression. Stable carbon isotope analysis of bulk OM gives evidence for a transition from C3 upland-sourced OM to C4-dominated marsh vegetation over time. The vegetative source of the OM changes along a marsh-upland mixing line from herbaceous angiosperm-sourced lignin in the lower elevation marsh to a woody gymnosperm signature at the upper border of the marsh. The results of stable isotope and lignin analyses illustrate that landward encroachment of marsh grasses results in deposition of herbaceous tissues exhibiting relatively little decay. This presents a possible mechanism for OM stabilization as marshes migrate inland.

Maryland↗
USGS2009

Geochemical Modeling of Carbon Sequestration, MMV, and EOR in the Illinois Basin

The Illinois State Geologic Survey is conducting several ongoing CO 2 sequestration projects that require geochemical models to gain an understanding of the processes occurring in the subsurface. The ISGS has collected brine and freshwater samples associated with an enhanced oil recovery project in the Loudon oil field. Geochemical modeling allows us to understand reactions with carbonate and silicate minerals in the reservoir, and the effects they have had on brine composition. For the Illinois Basin Decatur project, geochemical models should allow predictions of the reactions that will take place before CO 2 injection begins. ?? 2009 Elsevier Ltd. All rights reserved.

Conference Paper↗
USGS2014

The U. S. Geological Survey carbon dioxide storage efficiency value methodology: Results and observations

In order to complete the 2013 U.S. Geological Survey (USGS) assessment of carbon dioxide (CO 2 ) storage resources , a methodology was needed to determine the CO 2 storage efficiency of individual rock strata . The method that was used involved a storage efficiency approximation by MacMinn et al. , combined with a brine viscosity model by Mao and Duan, and thermal and pressure data from petroleum fields across basins . The resulting efficiencies indicated that both salinity of the pore fluid and the thermal gradient have a strong effect on the amount of CO 2 that strata could store.

Energy Procedia↗
USGS2014

Significance of carbon dioxide density estimates for basin-scale storage resource assessments

The geologic carbon dioxide (CO 2 ) storage resource size is a function of the density of CO 2 in the subsurface. The pressure and temperature of the storage reservoir at depth affect the CO 2 density. Therefore, knowing these subsurface conditions allows for improved resource estimates of potential geologic CO 2 storage capacity. In 2012, the U.S. Geological Survey (USGS) completed an assessment of geologic CO 2 storage resources for large sedimentary basins in onshore and State waters areas of the U.S. Evaluating the subsurface conditions and CO 2 density in these basins was integral to the assessment. To better understand these conditions, investigations of pressure and temperature gradients, typically derived from borehole data and analog studies, were assembled at the basin scale. Based on the USGS assessment results and findings here, changes in subsurface pressure and temperature may yield density changes up to 40 percent, which may translate into significant changes in storage resource estimates.

Energy Procedia↗
USGS2008

Influence of natural dissolved organic carbon on the bioavailability of mercury to a freshwater alga

Bioavailability of mercury (Hg) to Selenastrum capricornutum was assessed in bioassays containing field-collected freshwater of varying dissolved organic carbon (DOC) concentrations. Bioconcentration factor (BCF) was measured using stable isotopes of methylmercury (MeHg) and inorganic Hg(II). BCFs for MeHg in low-DOC lake water were significantly larger than those in mixtures of lake water and high-DOC river water. The BCF for MeHg in rainwater (lowest DOC) was the largest of any treatment. Rainwater and lake water also had larger BCFs for Hg(II) than river water. Moreover, in freshwater collected from several US and Canadian field sites, BCFs for Hg(II) and MeHg were low when DOC concentrations were >5 mg L-1. These results suggest high concentrations of DOC inhibit bioavailability, while low concentrations may provide optimal conditions for algal uptake of Hg. However, variability of BCFs at low DOC indicates that DOC composition or other ligands may determine site-specific bioavailability of Hg.

Environmental Pollution↗
USGS2016

Mercury remediation in wetland sediment using zero-valent iron and granular activated carbon

Wetlands are hotspots for production of toxic methylmercury (MeHg) that can bioaccumulate in the food web. The objective of this study was to determine whether the application of zero-valent iron (ZVI) or granular activated carbon (GAC) to wetland sediment could reduce MeHg production and bioavailability to benthic organisms. Field mesocosms were installed in a wetland fringing Hodgdon Pond (Maine, USA), and ZVI and GAC were applied. Pore-water MeHg concentrations were lower in treated compared with untreated mesocosms; however, sediment MeHg, as well as total Hg (THg), concentrations were not significantly different between treated and untreated mesocosms, suggesting that smaller pore-water MeHg concentrations in treated sediment were likely due to adsorption to ZVI and GAC, rather than inhibition of MeHg production. In laboratory experiments with intact vegetated sediment clumps, amendments did not significantly change sediment THg and MeHg concentrations; however, the mean pore-water MeHg and MeHg:THg ratios were lower in the amended sediment than the control. In the laboratory microcosms, snails ( Lymnaea stagnalis ) accumulated less MeHg in sediment treated with ZVI or GAC. The study results suggest that both GAC and ZVI have potential for reducing MeHg bioaccumulation in wetland sediment.

Environmental Pollution↗
USGS2009

Thallium isotope evidence for a permanent increase in marine organic carbon export in the early Eocene

The first high resolution thallium (Tl) isotope records in two ferromanganese crusts (Fe-Mn crusts), CD29 and D11 from the Pacific Ocean are presented. The crusts record pronounced but systematic changes in 205Tl/203Tl that are unlikely to reflect diagenetic overprinting or changes in isotope fractionation between seawater and Fe-Mn crusts. It appears more likely that the Fe-Mn crusts track the Tl isotope composition of seawater over time. The present-day oceanic residence time of Tl is estimated to be about 20,000??yr, such that the isotopic composition should reflect ocean-wide events. New and published Os isotope data are used to construct age models for these crusts that are consistent with each other and significantly different from previous age models. Application of these age models reveals that the Tl isotope composition of seawater changed systematically between ~ 55??Ma and ~ 45??Ma. Using a simple box model it is shown that the present day Tl isotope composition of seawater depends almost exclusively on the ratio between the two principal output fluxes of marine Tl. These fluxes are the rate of removal of Tl from seawater via scavenging by authigenic Fe-Mn oxyhydroxide precipitation and the uptake rate of Tl during low temperature alteration of oceanic crust. It is highly unlikely that the latter has changed greatly. Therefore, assuming that the marine Tl budget has also not changed significantly during the Cenozoic, the low 205Tl/203Tl during the Paleocene is best explained by a more than four-fold higher sequestration of Tl by Fe-Mn oxyhydroxides compared with at the present day. The calculated Cenozoic Tl isotopic seawater curve displays a striking similarity to that of S, providing evidence that both systems may have responded to the same change in the marine environment. A plausible explanation is a marked and permanent increase in organic carbon export from ~ 55??Ma to ~ 45??Ma, which led to higher pyrite burial rates and a significantly reduced flux of Fe-Mn oxide removal as a result of increased biological uptake of Fe and Mn. ?? 2008 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2013

Variations of iron flux and organic carbon remineralization in a subterranean estuary caused by interannual variations in recharge

We determine the inter-annual variations in diagenetic reaction rates of sedimentary iron (Fe ) in an east Florida subterranean estuary and evaluate the connection between metal fluxes and recharge to the coastal aquifer. Over the three-year study period (from 2004 to 2007), the amount of Fe-oxides reduced at the study site decreased from 192 g/yr to 153 g/yr and associated organic carbon (OC) remineralization decreased from 48 g/yr to 38 g/yr. These reductions occurred although the Fe-oxide reduction rates remained constant around 1 mg/cm 2 /yr. These results suggest that changes in flow rates of submarine groundwater discharge (SGD) related to changes in precipitation may be important to fluxes of the diagenetic reaction products. Rainfall at a weather station approximately 5 km from the field area decreased from 12.6 cm/month to 8.4 cm/month from 2004 to 2007. Monthly potential evapotranspiration (PET) calculated from Thornthwaite’s method indicated potential evapotranspiration cycled from about 3 cm/month in the winter to about 15 cm/month in the summer so that net annual recharge to the aquifer decreased from 40 cm in 2004 to -10 cm in 2007. Simultaneously, with the decrease in recharge of groundwater, freshwater SGD decreased by around 20% and caused the originally 25 m wide freshwater seepage face to decrease in width by about 5 m. The smaller seepage face reduced the area under which Fe-oxides were undergoing reductive dissolution. Consequently, the observed decrease in Fe flux is controlled by hydrology of the subterranean estuary. These results point out the need to better understand linkages between temporal variations in diagenetic reactions and changes in flow within subterranean estuaries in order to accurately constrain their contribution to oceanic fluxes of solutes from subterranean estuaries.

Florida↗
USGS2015

Uranium isotopes and dissolved organic carbon in loess permafrost: Modeling the age of ancient ice

The residence time of ice in permafrost is an indicator of past climate history, and of the resilience and vulnerability of high-latitude ecosystems to global change. Development of geochemical indicators of ground-ice residence times in permafrost will advance understanding of the circumstances and evidence of permafrost formation, preservation, and thaw in response to climate warming and other disturbance. We used uranium isotopes to evaluate the residence time of segregated ground ice from ice-rich loess permafrost cores in central Alaska. Activity ratios of 234 U vs. 238 U ( 234 U/ 238 U) in water from thawed core sections ranged between 1.163 and 1.904 due to contact of ice and associated liquid water with mineral surfaces over time. Measured ( 234 U/ 238 U) values in ground ice showed an overall increase with depth in a series of five neighboring cores up to 21 m deep. This is consistent with increasing residence time of ice with depth as a result of accumulation of loess over time, as well as characteristic ice morphologies, high segregated ice content, and wedge ice, all of which support an interpretation of syngenetic permafrost formation associated with loess deposition. At the same time, stratigraphic evidence indicates some past sediment redistribution and possibly shallow thaw among cores, with local mixing of aged thaw waters. Using measures of surface area and a leaching experiment to determine U distribution, a geometric model of ( 234 U/ 238 U) evolution suggests mean ages of up to ∼200 ky BP in the deepest core, with estimated uncertainties of up to an order of magnitude. Evidence of secondary coatings on loess grains with elevated ( 234 U/ 238 U) values and U concentrations suggests that refinement of the geometric model to account for weathering processes is needed to reduce uncertainty. We suggest that in this area of deep ice-rich loess permafrost, ice bodies have been preserved from the last glacial period (10–100 ky BP), despite subsequent fluctuations in climate, fire disturbance and vegetation. Radiocarbon ( 14 C) analysis of dissolved organic carbon (DOC) in thaw waters supports ages greater than ∼40 ky BP below 10 m. DOC concentrations in thaw waters increased with depth to maxima of >1000 ppm, despite little change in ice content or cryostructures. These relations suggest time-dependent production of old DOC that will be released upon permafrost thaw at a rate that is mediated by sediment transport, among other factors.

Alaska↗
USGS2019

A high carbon content of the Hawaiian mantle from olivine-hosted melt inclusions

The deep mantle carbon content and flux are fundamental quantities in understanding global volatile cycles and distributions. Here, we present CO2 concentrations measured in 407 olivine-hosted melt inclusions from Hualalai, Kilauea, Koolau, Loihi, and Mauna Loa to constrain the Hawaiian mantle CO2 content and flux. Quantification of melt inclusion CO2 is complicated by the ubiquitous presence of vapor or “shrinkage” bubbles. The contribution from exsolved shrinkage bubble CO2 was determined from the measured bubble size and a CO2 equation of state, and added to the dissolved CO2 to reconstruct total melt inclusion CO2 concentrations. Bubbles typically contain ~90% of melt inclusion C, much of which may be sequestered in precipitated phases on bubble walls, and thus not amenable to measurement by Raman spectroscopy. Based on our dataset of total (dissolved + bubble) CO2 concentrations, we estimate that parental melts from the five Hawaiian volcanoes have CO2 concentrations ranging from 3900 to 10,000 ppm CO2. Among the active volcanoes, CO2 concentrations decrease to the northwest, likely reflecting mantle source heterogeneity, although differences in the depths of the magma chambers may also play a role. Mantle sources of the Hawaiian volcanoes range from 380 to 480 ppm CO2 suggesting that the Hawaiian plume is at least a factor of ~4 more C-rich than the MORB mantle. This enrichment is likely due to the presence of recycled surficial C and/or C-rich primitive material in the Hawaiian mantle.

Hawaii↗
USGS2008

Distinguishing black carbon from biogenic humic substances in soil clay fractions

Most models of soil humic substances include a substantial component of aromatic C either as the backbone of humic heteropolymers or as a significant component of supramolecular aggregates of degraded biopolymers. We physically separated coarse (0.2–2.0 μm e.s.d.), medium (0.02–0.2 μm e.s.d.), and fine (> 0.02 μm e.s.d.) clay subfractions from three Midwestern soils and characterized the organic material associated with these subfractions using 13 C-CPMAS-NMR, DTG, SEM-EDX, incubations, and radiocarbon age. Most of the C in the coarse clay subfraction was present as discrete particles (0.2–5 μm as seen in SEM images) of black carbon (BC) and consisted of approximately 60% aromatic C, with the remainder being a mixture of aliphatic, anomeric and carboxylic C. We hypothesize that BC particles were originally charcoal formed during prairie fires. As the BC particles aged in soil their surfaces were oxidized to form carboxylic groups and anomeric and aliphatic C accumulated in the BC particles either by adsorption of dissolved biogenic compounds from the soil solution or by direct deposition of biogenic materials from microbes living within the BC particles. The biogenic soil organic matter was physically separated with the medium and fine clay subfractions and was dominated by aliphatic, anomeric, and carboxylic C. The results indicate that the biogenic humic materials in our soils have little aromatic C, which is inconsistent with the traditional heteropolymer model of humic substances.

Geoderma↗
USGS2014

Evaluation of a model framework to estimate soil and soil organic carbon redistribution by water and tillage using 137 Cs in two U.S. Midwest agricultural fields

Cultivated lands in the U.S. Midwest have been affected by soil erosion, causing soil organic carbon (SOC) redistribution in the landscape and other environmental and agricultural problems. The importance of SOC redistribution on soil productivity and crop yield, however, is still uncertain. In this study, we used a model framework, which includes the Unit Stream Power-based Erosion Deposition (USPED) and the Tillage Erosion Prediction (TEP) models, to understand the soil and SOC redistribution caused by water and tillage erosion in two agricultural fields in the U.S. Midwest. This model framework was evaluated for different digital elevation model (DEM) spatial resolutions (10-m, 24-m, 30-m, and 56-m) and topographic exponents ( m = 1.0–1.6 and n = 1.0–1.3) using soil redistribution rates from 137 Cs measurements. The results showed that the aggregated 24-m DEM, m = 1.4 and n = 1.0 for rill erosion, and m = 1.0 and n = 1.0 for sheet erosion, provided the best fit with the observation data at both sites. Moreover, estimated average SOC redistributions were 1.3 ± 9.8 g C m − 2 yr − 1 in field site 1 and 3.6 ± 14.3 g C m − 2 yr − 1 in field site 2. Spatial distribution patterns showed SOC loss (negative values) in the eroded areas and SOC gain (positive value) in the deposition areas. This study demonstrated the importance of the spatial resolution and the topographic exponents to estimate and map soil redistribution and the SOC dynamics throughout the landscape, helping to identify places where erosion and deposition from water and tillage are occurring at high rates. Additional research is needed to improve the application of the model framework for use in local and regional studies where rainfall erosivity and cover management factors vary. Therefore, using this model framework can help to improve the information about the spatial distribution of soil erosion across agricultural landscapes and to gain a better understanding of SOC dynamics within eroding and previously eroded fields.

Iowa↗