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Status and understanding of groundwater quality in the Cascade Range and Modoc Plateau study unit, 2010: California GAMA Priority Basin Project

Groundwater quality in the Cascade Range and Modoc Plateau study unit was investigated as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The study was designed to provide a statistically unbiased assessment of untreated groundwater quality in the primary aquifer system. The depth of the primary aquifer system for the Cascade Range and Modoc Plateau study unit was delineated by the depths of the screened or open intervals of wells in the State of California’s database of public-supply wells. Two types of assessments were made: a status assessment that described the current quality of the groundwater resource, and an understanding assessment that made evaluations of relations between groundwater quality and potential explanatory factors representing characteristics of the primary aquifer system. The assessments characterize the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on water-quality data collected in 2010 by the U.S. Geological Survey from 90 wells and springs (USGS-grid wells) and on water-quality data compiled from the State of California’s regulatory compliance database for samples collected from 240 public-supply wells between September 2007 and September 2010. To provide context, the water-quality data discussed in this report were compared to California and Federal drinking-water regulatory and non-regulatory benchmarks for treated drinking water. Groundwater quality is defined in terms of relative concentrations (RCs), which are calculated by dividing the concentration of a constituent in groundwater by the concentration of the benchmark for that constituent. The RCs for inorganic constituents (major ions, trace elements, nutrients, and radioactive constituents) were classified as “high” (the RC is greater than 1.0, indicating that the concentration is above the benchmark), “moderate” (the RC is from 1.0 to greater than 0.5), or “low” (the RC is less than or equal to 0.5). For organic constituents (volatile organic compounds and pesticides) and special-interest constituents (perchlorate), the boundary between moderate and low RCs was set at 0.1. All benchmarks used for organic constituents were health-based. For inorganic constituents, health-based and aesthetic-based benchmarks were used. Constituents without benchmarks were not considered in the status assessment . The primary metric used for quantifying regional-scale groundwater quality was the aquifer-scale proportion—the areal percentages of the primary aquifer system with high, moderate, and low RCs for a given constituent or class of constituents. The study unit was divided into six study areas on the basis of geologic differences (Eastside Sacramento Valley, Honey Lake Valley groundwater basin, Cascade Range and Modoc Plateau Low Use Basins, Quaternary Volcanic Areas, Shasta Valley and Mount Shasta Volcanic Area, and Tertiary Volcanic Areas), and each study area was divided into equal-area grid cells. Aquifer-scale proportions were calculated for individual constituents and constituent classes for each of the six study areas and for the study unit as a whole by using grid-based (one well per cell) and spatially weighted (many wells per cell) statistical methods. The status assessment showed that inorganic constituents were present at high and moderate RCs in greater proportions of the Cascade Range and Modoc Plateau study unit than were organic constituents. One or more inorganic constituents with health-based benchmarks were present at high RCs in 9.4 percent, and at moderate RCs in 14.7 percent of the primary aquifer system. Arsenic was present at high RCs in approximately 3 percent of the primary aquifer system; boron, molybdenum, uranium, and vanadium each were present at high RCs in approximately 2 percent of the primary aquifer system. One or more inorganic constituents with aesthetic-based benchmarks were present at high RCs in 15.1 percent of the primary aquifer system and at moderate RCs in 4.9 percent. Manganese, iron, and total dissolved solids were present at high RCs in approximately 12 percent, 5 percent, and 2 percent, respectively, of the primary aquifer system. Organic constituents were not detected at high or moderate RCs in the primary aquifer system, and one or more organic constituents were detected at low RCs in approximately 40 percent of the primary aquifer system. Two classes of organic constituents were detected in more than 10 percent of the primary aquifer system: trihalomethanes (chloroform only) and herbicides. The special interest constituent perchlorate was not detected at high RCs, but was detected at moderate RCs in approximately 2 percent of the primary aquifer system. The understanding assessment relied on statistical tests to evaluate relations between concentrations of constituents and values of potential explanatory factors representing geology, land use, well construction, hydrologic conditions, groundwater age, and geochemical conditions. The majority of the high and moderate RCs of arsenic, boron, molybdenum, uranium, and total dissolved solids were in samples from the Honey Lake Valley groundwater basin study area. Groundwater mixing with hydrothermal fluids present in the study area, evaporative concentration of groundwater in the Honey Lake playa, presence of uranium-bearing sediment derived from the adjacent Sierra Nevada, and release of arsenic and other trace elements from sediments under high pH and low dissolved oxygen conditions all appeared to contribute to these elevated concentrations. Thermal springs are in many parts of the Cascade Range and Modoc Plateau study unit and could account for locally elevated concentrations of arsenic, boron, molybdenum, and total dissolved solids in samples from the other study areas. Vanadium concentrations were greater in oxic samples than in anoxic samples, but were not correlated with pH, contrary to expectations from previous studies. Organic constituents were not detected at high or moderate RCs, and the occurrence of low organic constituents at low RCs ranged from 27 percent to 73 percent of the primary aquifers system in the six study areas. The Shasta Valley and Mount Shasta Volcanic study area had significantly greater occurrence of low RCs of herbicides compared to all of the other study areas, which could reflect the greater prevalence of modern groundwater in the Shasta Valley and Mount Shasta Volcanic study area and the presence of potential sources of herbicides, including applications to timberlands and roadside rights-of-way. The Eastside Sacramento Valley study area had the greatest occurrence of low concentrations of chloroform, and chloroform occurrence was most strongly associated with the combination of septic-tank density greater than two tanks per square kilometer and urban land use greater than 10 percent within a radius of 500 meters of the well. These conditions were most prevalent in the Eastside Sacramento Valley study area. The detection frequency of low concentrations of perchlorate was consistent with the probability of occurrence expected under natural conditions, except in the Eastside Sacramento Valley study area, where detection frequencies were much higher than expected and could not be explained by known anthropogenic sources of perchlorate.

California↗

Assessment of undiscovered oil and gas resources in conventional and continuous petroleum systems in the Upper Cretaceous Eagle Ford Group, U.S. Gulf Coast region, 2011

Using a geology-based assessment methodology, the U.S. Geological Survey assessed means of (1) 141 million barrels of oil (MMBO), 502 billion cubic feet of natural gas (BCFG), and 16 million barrels of natural gas liquids (MMBNGL) in the conventional Eagle Ford Updip Sandstone Oil and Gas Assessment Unit (AU); (2) 853 MMBO, 1,707 BCFG, and 34 MMBNGL in the continuous Eagle Ford Shale Oil AU; and (3) 50,219 BCFG and 2,009 MMBNGL in the continuous Eagle Ford Shale Gas AU in onshore lands and State waters of the Gulf Coast.

Gulf Coast Region↗

Surficial sediment character of the Louisiana offshore continental shelf region: A GIS compilation

The Louisiana coastal zone, comprising the Mississippi River delta plain stretching nearly 400 km from Sabine Pass at the Texas border east to the Chandeleur Islands at the Mississippi border, represents one of North America’s most important coastal ecosystems in terms of natural resources, human infrastructure, and cultural heritage. At the same time, this region has the highest rates of coastal erosion and wetland loss in the Nation due to a complex combination of natural processes and anthropogenic actions over the past century. Comparison of historical maps dating back to 1855 and recent aerial photography show the Louisiana coast undergoing net erosion at highly variable rates. Rates have increased significantly during the past several decades. Earlier published statewide average shoreline erosion rates were >6 m/yr; rates have increased recently to >10 m/yr. The increase is attributable to collective action of storms, rapid subsidence, and pervasive man-made alterations of the rivers and the coast. In response to the dramatic landloss, regional-scale restoration plans are being developed by a partnership of federal and state agencies for the delta plain that have the objectives of maintaining the barrier islands, reducing wetland loss, and enhancing the natural sediment delivery processes. There is growing awareness that the sustainability of coastal Louisiana's natural resources and human infrastructure depends on the successful restoration of natural geologic processes. Critical to the long term success of restoration is scientific understanding of the geologic history and processes of the coastal zone region, including interactions between the rivers, wetlands, coast, and inner shelf. A variety of geophysical studies and mapping of Late Quaternary sedimentary framework and coastal processes by U.S. Geological Survey and other scientists during the past 50 years document that the Louisiana delta plain is the product of a complex history of cyclic delta switching by the Mississippi River and its distributaries over the past ~10,000 years that resulted in laterally overlapping deltaic depocenters. The interactions among riverine, coastal, and inner shelf processes have been superimposed on the Holocene transgression resulting in distinctive landforms and sedimentary sequences. Four Holocene shelf-phase delta complexes have been identified using seismic reflection data and vibracores. Each delta complex is bounded by transgressive surfaces. Following each cycle of deposition and abandonment, the delta lobes undergo regional subsidence and marine reworking that forms transgressive coastal systems and barrier islands. Ultimately, the distal end of each of the abandoned delta lobes is marked by submerged marine sand bodies representing drowned barriers. These sand bodies (e.g. Ship Shoal, Outer Shoal, Trinity Shoal, Tiger Shoal, St. Bernard Shoal) offer the largest volumes and highest quality sand for beach nourishment and shoreline and wetlands restoration. These four large sand shoals on inner continental shelf, representing the reworked remnants of former prograded deltaic headlands that existed on the continental shelf at lower sea level, were generated in the retreat path of the Mississippi River delta plain during the Holocene transgression. Penland and others (1989) have shown these sand bodies represent former shoreline positions associated with lower still stands in sea level. Short periods of rapid relative sea-level rise led to the transgressive submergence of the shorelines which today can be recognized at the -10 m to -20 m isobaths on the Louisiana continental shelf. Trinity Shoal and Ship Shoal represent the -10 m middle-to-late Holocene shoreline trend, whereas Outer Shoal and the St. Bernard Shoals define the -20 m early Holocene shoreline trend (Penland and others, 1989). Collectively, these sand shoals constitute a large volume of high quality sandy sediment potentially suitable for barrier island nourishment and coastal restoration. The USGS has actively supported coastal and wetlands geologic research for the past two decades in partnership with universities (e.g., Louisiana State University, University of New Orleans), state agencies (e.g. Louisiana Geological Survey, Louisiana Department of Natural Resources), and private organizations (Williams and others, 1992a,b; Williams and Cichon, 1993; List and others, 1994). These studies have focused on regional-scale mapping of coastal and wetland change and developing a better understanding of the processes that cause coastal erosion and wetlands loss, particularly the rapid deterioration of Louisiana's barrier islands, estuaries, and wetlands environments. With a better understanding of these processes, the ability to model and predict erosion and wetlands loss will improve. More accurate predictions will, in turn, allow for proper management of coastal resources. Improved predictions will also allow for better assessments of the utility of different restoration alternatives.

Louisiana↗

Physical habitat monitoring strategy (PHAMS) for reach-scale restoration effectiveness monitoring

Habitat restoration efforts by the Confederated Tribes of the Umatilla Indian Reservation (CTUIR) have shifted from the site scale (1-10 meters) to the reach scale (100-1,000 meters). This shift was in response to the growing scientific emphasis on process-based restoration and to support from the 2007 Accords Agreement with the Bonneville Power Administration. With the increased size of restoration projects, the CTUIR and other agencies are in need of applicable monitoring methods for assessing large-scale changes in river and floodplain habitats following restoration. The goal of the Physical Habitat Monitoring Strategy is to outline methods that are useful for capturing reach-scale changes in surface and groundwater hydrology, geomorphology, hydrologic connectivity, and riparian vegetation at restoration projects. The Physical Habitat Monitoring Strategy aims to avoid duplication with existing regional effectiveness monitoring protocols by identifying complimentary reach-scale metrics and methods that may improve the ability of CTUIR and others to detect instream and riparian changes at large restoration projects.

Idaho, Oregon, Washington↗

A comparison of contemporary and historical hydrology and water quality in the foothills and coastal plain of the Arctic National Wildlife Refuge, Arctic Slope, northern Alaska

The Arctic National Wildlife Refuge is a unique landscape in northern Alaska with limited water resources, substantial biodiversity of rare and threatened species, as well as oil and gas resources. The region has unique hydrology related to perennial springs, and the formation of large aufeis fields—sheets of ice that grow in the river channels where water reaches the surface in the winter and freezes. This work aims to update our understanding of water resources and water quality in the springs, streams, rivers, and lakes of this region, returning to sites sampled by the U.S. Geological Survey in the 1970s. We resampled eight streams, four springs, and six lakes for hydrological metrics, water quality, and macroinvertebrates, and recalculated flood-frequency metrics for rivers using updated data and modern techniques. Aufeis field melt rates were also assessed for the past several decades. Although the available data preclude trend determinations in most cases, our analysis and comparison to the historical sampling indicates an increase in dissolved ions for streams and springs, faster and earlier aufeis melt, and similar macroinvertebrate populations.

Alaska↗

Geophysics- and geochemistry-based assessment of the geochemical characteristics and groundwater-flow system of the U.S. part of the Mesilla Basin/Conejos-Médanos aquifer system in Doña Ana County, New Mexico, and El Paso County, Texas, 2010–12

One of the largest rechargeable groundwater systems by total available volume in the Rio Grande/Río Bravo Basin (hereinafter referred to as the “Rio Grande”) region of the United States and Mexico, the Mesilla Basin/Conejos-Médanos aquifer system, supplies water for irrigation as well as for cities of El Paso, Texas; Las Cruces, New Mexico; and Ciudad Juárez, Chihuahua, Mexico. The U.S. Geological Survey in cooperation with the Bureau of Reclamation assessed the groundwater resources in the Mesilla Basin and surrounding areas in Doña Ana County, N. Mex., and El Paso County, Tex., by using a combination of geophysical and geochemical methods. The study area consists of approximately 1,400 square miles in Doña Ana County, N. Mex., and 100 square miles in El Paso County, Tex. The Mesilla Basin composes most of the study area and can be divided into three parts: the Mesilla Valley, the West Mesa, and the East Bench. The Mesilla Valley is the part of the Mesilla Basin that was incised by the Rio Grande between Selden Canyon to the north and by a narrow valley (about 4 miles wide) to the southeast near El Paso, Tex., named the Paso del Norte, which is sometimes referred to in the literature as the “El Paso Narrows.” Previously published geophysical data for the study area were compiled and these data were augmented by collecting additional geophysical and geochemical data. Geophysical resistivity measurements from previously published helicopter frequency domain electromagnetic data, previously published direct-current resistivity soundings, and newly collected (2012) time-domain electromagnetic soundings were used in the study to detect spatial changes in the electrical properties of the subsurface, which reflect changes that occur within the hydrogeology. The geochemistry of the groundwater system was evaluated by analyzing groundwater samples collected in November 2010 for physicochemical properties, major ions, trace elements, nutrients, pesticides (reported but not used in the assessment), and environmental tracers. The data obtained from these samples (with the exception of the pesticide data) were used to gain insights into processes controlling the groundwater movement through the groundwater system in the study area. Results from the geophysical and geochemical assessments facilitated the interpretation of the geochemical characteristics of the groundwater sources and geochemical groups within the groundwater system. The groundwater-flow system in the study area consists primarily of the Mesilla Basin aquifer system, which can be divided into four hydrogeologic units by using an informal classification scheme based on basin-fill stratigraphy and sedimentology with an emphasis on aquifer characteristics. The four hydrogeologic units are (1) the Rio Grande alluvium, which is the shallow aquifer of the Mesilla Basin within the confines of the Mesilla Valley, and the three hydrogeologic units that compose the Santa Fe Group: (2) the lower part of the Santa Fe Group, which is the least productive zone, (3) the middle part of the Santa Fe Group, which is the primary water-bearing hydrogeologic unit in the basin and is generally saturated, and (4) the upper part of the Santa Fe Group, which is the most productive water-bearing unit within the Santa Fe Group but is only partially saturated in the north and largely unsaturated in the south and western parts of the Mesilla Basin. The helicopter frequency domain electromagnetic survey results indicated that approximately half of the resistivity values were less than 10 ohm-meters at depths of 50 and 100 feet with a transition where the resistivity values changed from relatively high values (greater than 20 ohm-meters) to relatively low resistivity values (less than 10 ohm-meters) near Vado, New Mexico. Slightly more than 25 percent of the gridded resistivity values from the three-dimensional grid of the combined inverse modeling results of the direct-current resistivity and time-domain electromagnetic soundings were equal to or less than 10 ohm-meters with large regions of low resistivity becoming apparent in the southernmost part of the study area near the Paso Del Norte where these low resistivity features are spatially the widest at or below the top of the bedrock. These low resistivity values might represent clayey deposits, sediments composed largely of sand and gravel saturated with saline water, or both. Historical dissolved-solids-concentration data within the surface geophysical subset area of the study area were compiled and compared to the inverse modeling results of the combined direct-current resistivity and time-domain soundings; this comparison was done to strengthen the interpretation made from the combined inverse modeling results that the low resistivity features were representative of sand and gravel deposits saturated with saline water and not clayey deposits. Water-level altitudes within the Rio Grande alluvium generally decreased from north to south, with a west to east decrease in water-level altitudes near Las Cruces, New Mexico, as a result of groundwater pumping. Groundwater flow within the Santa Fe Group is more complex than the groundwater flow within the Rio Grande alluvium because of the larger lateral and vertical extent of the Santa Fe Group compared to the Rio Grande alluvium. Groundwater from the Organ Mountains flows directly south towards the Paso del Norte. Groundwater from the Robledo Mountains, the Rough and Ready Hills, and the Sleeping Lady Hills generally flows to the southeast. Groundwater flowing near the north end of the midbasin uplift generally continues east towards the Rio Grande and then flows south on the east side of the midbasin uplift. Groundwater flowing near the west side of the midbasin uplift generally continues south parallel to the faults that make up the midbasin uplift and then flows east towards the Paso del Norte when it reaches the south end of the midbasin uplift. Groundwater from the Aden Hills and the East and West Potrillo Mountains flows to the south end of the midbasin uplift and then continues east towards the Paso del Norte. Throughout most of the Mesilla Valley, the vertical hydraulic gradient was downward because the water-level altitude in the Rio Grande alluvium was higher than it was in the Santa Fe Group, but in some areas (typically in the middle and southern parts of the Mesilla Valley), the vertical hydraulic gradient was substantially reduced or even reversed to an upward hydraulic gradient. The geochemistry data indicate that there was a complex system of multiple geochemical endmembers and mixing between these endmembers with recharge to the Rio Grande alluvium and Santa Fe Group composed mostly of seepage from the Rio Grande, inflows from deeper or neighboring water systems, and mountain-front recharge. Five distinct geochemical groups were identified in the Mesilla Basin study area: (1) ancestral Rio Grande (pre-Pleistocene) geochemical group, (2) modern Rio Grande (Pleistocene to present) geochemical group, (3) mountain-front geochemical group, (4) deep groundwater upwelling geochemical group, and (5) unknown freshwater geochemical group. The ancestral Rio Grande groundwater was water that recharged into the system as seepage losses from the ancestral Rio Grande; this groundwater generally flows from north to south-southeast towards the Paso del Norte. Groundwater on the west side of the midbasin uplift generally flows south until it reaches the southern part of the study area; from the southern part of the study area, the groundwater flows east towards the Paso del Norte. Groundwater on the east side of the midbasin uplift flows south-southeast towards the Paso del Norte where it mixes with groundwater from the modern Rio Grande, uplifted areas in the west, and the deep saline source. The water type of the modern Rio Grande geochemical group ranged from calcium-sulfate water type in the northern part of the study area to sodium-chloride-sulfate water type in the southern part of the study area; from north to south there was a substantial increase in specific conductance, strontium-87/strontium-86 ratio, potassium, and the trace metals of iron and lithium, changing the water chemistry such that it became similar to the water chemistry of the deep groundwater upwelling geochemical group. From age-dating results, water in the modern Rio Grande geochemical group was recharged to the Rio Grande alluvium within the past 10 years. The mountain-front geochemical group was generally old water (apparent age was greater than 10,000 carbon-14 years before present) that was somewhat mineralized and has relatively high concentrations of fluoride and silica, which might indicate longer exposure to volcanic and siliciclastic rocks or aluminosilicate minerals. There were five different locations of recharge determined from the groundwater geochemistry within the mountain-front geochemical group, all having a slightly different geochemical signature: (1) the Rough and Ready Hills, Robledo Mountains, and the Sleeping Lady Hills, (2) the Doña Ana Mountains, (3) the Aden Hills and West Potrillo Mountains, (4) the East Potrillo Mountains, and (5) the Sierra Juárez in Mexico. The groundwater from the Rough and Ready Hills, Robledo Mountains, the Sleeping Lady Hills, and the Doña Ana Mountains generally flows toward the Rio Grande and eventually mixes together and with the modern Rio Grande groundwater. The groundwater originating from the Aden Hills and East and West Potrillo Mountains generally flows east to southeast at a slow rate and eventually mixes and continues east, where it mixes with groundwater from the ancestral Rio Grande geochemical group and with the groundwater from the Sierra Juárez. The groundwater from the Sierra Juárez flows north and then east towards the Paso del Norte where it mixes with groundwater from the uplifted areas in the west, ancestral and modern Rio Grande groundwater, and the upwelling groundwater from a deep saline source. The deep groundwater upwelling geochemical group had the highest concentrations of bicarbonate, potassium, silica, aluminum, iron, and lithium within the study area, indicating that it had been in contact with carbonate and siliciclastic rocks for a much longer period of time and at higher temperatures compared to the other geochemical groups, and was most likely ancient marine groundwater originating from the Paleozoic and Cretaceous carbonate rocks which was upwelling into the Mesilla Basin aquifer system in the southeastern part of the study area through the extensive fault systems. Direct-current resistivity and time-domain electromagnetic soundings support the interpretation of ancient marine groundwater upwelling into the Mesilla Basin aquifer system, as do the analytical results from wells, and the helicopter frequency domain electromagnetic data collected along the Rio Grande. The hydrogen-2/hydrogen-1 ratio and oxygen-18/oxygen-16 ratio isotopic results for samples in the unknown freshwater geochemical group did not plot on the Rio Grande evaporation line, indicating this group did not have a Rio Grande signature (that is, there was no isotopic evidence of a component of Rio Grande water) and it also had the lowest mineralized content of any geochemical group in the study area.

New Mexico, Texas↗

Numbers of wildlife fatalities at renewable energy facilities in a targeted development region

Increased interest in renewable energy has fostered development of wind and solar energy facilities globally. However, energy development sometimes has negative environmental impacts, such as wildlife fatalities. Efforts by regional land managers to balance energy potential while minimizing fatality risk currently rely on datasets that are aggregated at continental, but not regional scales, that focus on single species, or that implement meta-analyses that inappropriately use inferential statistics. We compiled and summarized fatality data from 87 reports for solar and wind facilities in the Mojave and Sonoran Deserts region of southern California within the Desert Renewable Energy Conservation Plan area. Our goal was to evaluate potential temporal and guild-specific patterns in fatalities, especially for priority species of conservation concern. We also aimed to provide a perspective on approaches interpreting these types of data, given inherent limitations in how they were collected. Mourning doves ( Zenaida macroura ), Chukar ( Alectoris chukar ) and California Quail ( Callipepla californica ), and passerines ( Passeriformes ), accounted for the most commonly reported fatalities. However, our aggregated count data were derived from raw, uncorrected totals, and thus reflect an absolute minimum number of fatalities for the monitored period. Additionally, patterns in the raw data suggested that many species commonly documented as fatalities (e.g., waterbirds and other nocturnal migrants, bats) are rarely counted during typical pre-construction use surveys. This may explain the more commonly observed mismatch between pre-construction risk assessment and actual fatalities. Our work may serve to guide design of future scientific research to address temporal and spatial patterns in fatalities and to apply rigorous guild-specific survey methodologies to estimate populations at risk from renewable energy development.

California↗

Relative abundance, seasonal occurrence, and distribution of marine birds in the northern Gulf of Mexico

Marine birds in the U.S. Gulf of Mexico have long been poorly studied. Given statutory obligations to protect migratory birds and endangered species, three broad-scale vessel and aerial programs initiated since 2010 have now surveyed the entire northern Gulf. Vessel coverage alone exceeds 700 d and 74,000 km of observer effort using 300-m strip transects. We supplemented these survey data with earlier, smaller-scale studies, eBird checklists, literature reviews, and other less accessible sources to create snapshot summaries of relative abundance, seasonal occurrence, and regional distribution for 117 taxa of marine and water birds reported from the northern Gulf (113 of which were substantiated with physical evidence). Using taxonomic and functional criteria, we identified 56 taxa characteristic of open shelf, slope, and pelagic waters (federal jurisdiction), 41 taxa with primarily coastal affinities (state and federal jurisdiction), and 20 taxa of sea and diving ducks. High species richness of marine birds in the northern Gulf is attributed to (1) a temperate-to-tropical gradient facilitating diverse marine environments year-round; (2) varied geographic origins of marine bird species using the Gulf; and (3) a mostly enclosed sea basin acting as a vagrant trap for wide-ranging species. Our taxonomic list and status updates seek to bridge information gaps for marine birds now subject to accelerated commercial uses of this region's continental shelf, including newly proposed offshore wind energy development. Other applications include guiding risk and vulnerability assessments of Gulf marine birds, providing core content for seabird observer training, and prioritizing environmental impact reviews and monitoring programs in offshore energy construction and operations plans.

Marine Ornithology: Journal of Seabird Research an↗

National Assessment of Shoreline Change Part 3: Historical Shoreline Change and Associated Coastal Land Loss Along Sandy Shorelines of the California Coast

Beach erosion is a chronic problem along many open-ocean shores of the United States. As coastal populations continue to grow and community infrastructures are threatened by erosion, there is increased demand for accurate information regarding past and present trends and rates of shoreline movement. There is also a need for a comprehensive analysis of shoreline movement that is consistent from one coastal region to another. To meet these national needs, the U.S. Geological Survey is conducting an analysis of historical shoreline changes along open-ocean sandy shores of the conterminous United States and parts of Hawaii and Alaska. One purpose of this work is to develop standard repeatable methods for mapping and analyzing shoreline movement so that periodic updates regarding coastal erosion and land loss can be made nationally that are systematic and internally consistent. In the case of this study, the shoreline being measured is the boundary between the ocean water surface and the sandy beach. This report on the California Coast represents the first of two reports on long-term sandy shoreline change for the western U.S., the second of which will include the coast of the Pacific NW, including Oregon and Washington. A report for the Gulf of Mexico shoreline was completed in 2004 and is available at: http://pubs.usgs.gov/of/2004/1043/. This report summarizes the methods of analysis, interprets the results, provides explanations regarding long-term and short-term trends and rates of change, and describes how different coastal communities are responding to coastal erosion. Shoreline change evaluations are based on comparing three historical shorelines digitized from maps, with a recent shoreline derived from lidar (Light Detection and Ranging) topographic surveys. The historical shorelines generally represent the following periods: 1800s, 1920s-1930s, and 1950s-1970s, whereas the lidar shoreline is from 1998-2002. Long-term rates of change are calculated using all four shorelines (1800s to lidar shoreline), whereas short-term rates of change are calculated for only the most recent period (1950s-1970s to lidar shoreline). The rates of change presented in this report represent past conditions and therefore are not intended for predicting future shoreline positions or rates of change. Due to the geomorphology of the California Coast (rocky coastline instead of beach) as well as to data gaps in some areas, this report presents beach erosion rates for 45% of California's 1100 km of coast. The average rate of long-term shoreline change for the State of California was 0.2?0.1 m/yr, an accretional trend. This is based on shoreline change rates averaged from 14,562 individual transects, of which 40% were eroding. Of the transects on which the shoreline was eroding, the long-term erosion rates were generally lowest in Southern California where coastal engineering projects have greatly altered the natural shoreline movement. On a regional scale, long-term accretion rates were either equal to (Central California) or greater than (Northern and Southern California) the long-term erosion rates, yielding the net accretional trend for the entire state. This accretional trend is most likely due to changes in the large volumes of sediment that are added to the system from large rivers and to the impact from coastal engineering and beach nourishment projects. The average rate of short-term shoreline change for the state was erosional. The net short-term rate as averaged along 16,142 transects was -0.2?0.4 m/yr. Of the transects used to measure short-term change, 66% had erosional trends. In addition erosion rates were higher in the short-term period, possibly related to the localized artificial nourishment that occurred over much of the 20th century but that has recently slowed or stopped (Flick, 1993; Wiegel, 1994). Short-term accretion rates were highest in Northern California where the overall magnitudes of shoreline change are systematically higher than in Central and Southern California. The most stable (low erosion and accretion rates) California beaches were most commonly found in Central California. Seawalls and/or riprap revetments have been constructed in all three sections of California, although many of these structures were built to protect houses and infrastructures from the erosion of coastal cliffs and bluffs rather than to protect against long-term beach erosion. California permits shoreline stabilization structures where homes, buildings or other community infrastructure are imminently threatened by erosion. A second California report that is following this publication will include analyses and reports on long-term coastal cliff erosion, as this hazard is of equal or greater concern to coastal communities in many areas along the California Coast.

Open-File Report↗

Methods and Indicators for Assessment of Regional Ground-Water Conditions in the Southwestern United States

Monitoring the status and trends in the availability of the Nation's ground-water supplies is important to scientists, planners, water managers, and the general public. This is especially true in the semiarid to arid southwestern United States where rapid population growth and limited surface-water resources have led to increased use of ground-water supplies and water-level declines of several hundred feet in many aquifers. Individual well observations may only represent aquifer conditions in a limited area, and wells may be screened over single or multiple aquifers, further complicating single-well interpretations. Additionally, changes in ground-water conditions may involve time scales ranging from days to many decades, depending on the timing of recharge, soil and aquifer properties, and depth to the water table. The lack of an easily identifiable ground-water property indicative of current conditions, combined with differing time scales of water-level changes, makes the presentation of ground-water conditions a difficult task, particularly on a regional basis. One approach is to spatially present several indicators of ground-water conditions that address different time scales and attributes of the aquifer systems. This report describes several methods and indicators for presenting differing aspects of ground-water conditions using water-level observations in existing data-sets. The indicators of ground-water conditions developed in this study include areas experiencing water-level decline and water-level rise, recent trends in ground-water levels, and current depth to ground water. The computer programs written to create these indicators of ground-water conditions and display them in an interactive geographic information systems (GIS) format are explained and results illustrated through analyses of ground-water conditions for selected alluvial basins in the Lower Colorado River Basin in Arizona.

Scientific Investigations Report↗

Shotgun sequencing of airborne eDNA achieves rapid assessment of whole biomes, population genetics and genomic variation

Biodiversity and its associated genetic diversity are being lost at an unprecedented rate. Simultaneously, the distributions of flora, fauna, fungi, microbes and pathogens are rapidly changing. Novel technology can help to capture and record genetic diversity before it is lost and to measure population shifts and pathogen distributions. Here we report the rapid application of shotgun long-read environmental DNA (eDNA) analysis for non-invasive biodiversity, genetic diversity and pathogen assessments from air. We also compared air eDNA with water and soil eDNA. Coupling long-read sequencing with established cloud-based biodiversity pipelines enabled a 2-day turnaround from airborne sample collection to completed analysis by a single investigator. To determine the full utility of airborne eDNA, we also conducted a local bioinformatic analysis and deep short-read shotgun sequencing. From outdoor air eDNA alone, comprehensive genetic analysis was performed, including population genetics (phylogenetic placement) of a charismatic mammal (bobcat, Lynx rufus ) and a venomous spider (golden silk orb weaver, Trichonephila clavipes ), and haplotyping humans ( Homo sapiens ) from natural complex community settings, such as subtropical forests and temperate locations. The rich datasets also enabled deeper analysis of specific species and genomic regions of interest, including viral variant calling, human variant analysis and antimicrobial resistance gene surveillance from airborne DNA. Our results highlight the speed, versatility and specificity of pan-biodiversity monitoring via non-invasive eDNA sampling using current benchtop/portable and cloud-based approaches. Furthermore, they reveal the future feasibility of scaling down (equipment and temporally) these approaches for near real-time analysis. Together these approaches can enable rapid simultaneous detection of all life and its genetic diversity from air, water and sediment samples for unbiased non-targeted information-rich genomics-empowered (1) biodiversity monitoring, (2) population genetics, (3) pathogen and disease-vector genomic surveillance, (4) allergen and narcotic surveillance, (5) antimicrobial resistance surveillance and (6) bioprospecting.

Nature Ecology & Evolution↗

Geochemical, isotopic, and dissolved gas characteristics of groundwater in a fractured crystalline-rock aquifer, Savage Municipal Well Superfund site, Milford, New Hampshire, 2011

Tetrachloroethylene (PCE), a volatile organic compound, was detected in groundwater from deep (more than (>) 300 feet (ft) below land surface) fractures in monitoring wells tapping a crystalline-rock aquifer beneath operable unit 1 (OU1) of the Savage Municipal Well Superfund site (Weston, Inc., 2010). Operable units define remedial areas of contaminant concern. PCE contamination within the fractured-rock aquifer has been designated as a separate operable unit, operable unit 3 (OU3; Weston, Inc., 2010). PCE contamination was previously detected in the overlying glacial sand and gravel deposits and basal till, hereafter termed the Milford-Souhegan glacial-drift (MSGD) aquifer (Harte, 2004, 2006). Operable units 1 and 2 encompass areas within the MSGD aquifer, whereas the extent of the underlying OU3 has yet to be defined. The primary original source of contamination has been identified as a former manufacturing facility—the OK Tool manufacturing facility; hence OU1 sometimes has been referred to as the OK Tool Source Area (New Hampshire Department of Environmental Services, undated). A residential neighborhood of 30 to 40 houses is located in close proximity (one-quarter of a mile) from the PCE-contaminated monitoring wells. Each house has its own water-supply well installed in similar rocks as those of the monitoring wells, as indicated by the New Hampshire State geologic map (Lyons and others, 1997). An investigation was initiated in 2010 by the U.S. Environmental Protection Agency (USEPA) region 1, and the New Hampshire Department of Environmental Services (NHDES) to assess the potential for PCE transport from known contaminant locations (monitoring wells) to the residential wells. The U.S. Geological Survey (USGS) and the NHDES entered into a cooperative agreement in 2011 to assist in the evaluation of PCE transport in the fractured-rock aquifer. Periodic sampling over the last decade by the USEPA and NHDES has yet to detect PCE in groundwater from the residential-supply wells (as of 2012). However, part of assessing the potential for PCE transport involves understanding the origin of the groundwater in the monitoring and residential wells. One of the tools in delineating the movement of groundwater to wells, particularly in complex, highly heterogeneous fractured-rock aquifers, is the understanding of the geochemical and isotopic composition of groundwater (Lipfert and Reeve, 2004; Harte and others, 2012). This report summarizes findings from analyses of geochemical, isotopic, and dissolved gas characteristics of groundwater. Samples of groundwater were collected in 2011 from monitoring wells and nearby residential-supply wells in proximity to OU1.

New Hampshire↗

Nitrate (NO2+NO3–N) in ground water of the Upper Snake River basin, Idaho and western Wyoming, 1991–95

Factors related to contamination of ground water by dissolved nitrite plus nitrate as nitrogen (NO 2 +NO 3 -N) in parts of the upper Snake River Basin were evaluated at regional and local scales. Regional-scale relations between NO 2 +NO 3 -N concentrations and depth to first-encountered ground water, land use, precipitation, and soils were evaluated using a geographic information system. Local-scale relations between NO 2 +NO 3 -N concentrations and other nutrients, major ions, nitrogen isotopes, stable isotopes, and tritium in five areas with different hydrogeologic settings, land use, and sources of irrigation water were evaluated to determine the factors causing differences in NO 2 +NO 3 -N. Data were collected and analyzed as part of the U.S. Geological Survey's National Water-Quality Assessment Program, which began in 1991.

Idaho, Wyoming↗

Gulf of Mexico Marine Assessment Project for Protected Species: Sea Turtles

The overarching goal of the Gulf of Mexico Marine Assessment Project for Protected Species: sea turtles (GOMMAPPS) study was to collect broad-scale information on the distribution and abundance of sea turtles in the Gulf to inform seasonally- and spatially-explicit density estimates for priority species. GOMMAPPS represents a multi-agency partnership between BOEM, USFWS, NOAA, and USGS, all of whom collect information on large marine vertebrates to provide improved spatially-explicit density distributions for multiple management objectives. Though GOMMAPPS is intended to provide broad-scale information, specific locations identified for satellite tagging targeted regions of highest oil and gas activity (i.e., in the Central and Western Gulf of Mexico).

Report↗

GIS Representation of Coal-Bearing Areas in Africa

The African continent contains approximately 5 percent of the world's proven recoverable reserves of coal (World Energy Council, 2007). Energy consumption in Africa is projected to grow at an annual rate of 2.3 percent from 2004 through 2030, while average consumption in first-world nations is expected to rise at 1.4 percent annually (Energy Information Administration, 2007). Coal reserves will undoubtedly continue to be part of Africa's energy portfolio as it grows in the future. A review of academic and industrial literature indicates that 27 nations in Africa contain coal-bearing rock. South Africa accounts for 96 percent of Africa's total proven recoverable coal reserves, ranking it sixth in the world. This report is a digital compilation of information on Africa's coal-bearing geology found in the literature and is intended to be used in small scale spatial investigations in a Geographic Information System (GIS) and as a visual aid for the discussion of Africa's coal resources. Many maps of African coal resources often include points for mine locations or regional scale polygons with generalized borders depicting basin edges. Point locations are detailed but provide no information regarding extent, and generalized polygons do not have sufficient detail. In this dataset, the polygons are representative of the actual coal-bearing lithology both in location and regional extent. Existing U.S. Geological Survey (USGS) digital geology datasets provide the majority of the base geologic polygons. Polygons for the coal-bearing localities were clipped from the base geology that represented the age and extent of the coal deposit as indicated in the literature. Where the 1:5,000,000-scale geology base layer's ages conflicted with those in the publications, polygons were generated directly from the regional African coal maps (1:500,000 scale, approximately) in the published material. In these cases, coal-bearing polygons were clipped to the literature's indicated coal extent, without regard to the underlying geology base or topographic constraints. Indication of the presence of African coal is based on multiple sources. However, the quality of the sources varies and there is often disagreement in the literature. This dataset includes the rank, age, and location of coal in Africa as well as the detailed source information responsible for each coal-bearing polygon. The dataset is not appropriate for use in resource assessments of any kind. Attributes necessary for tasks, such as number of coal seams, thickness of seams, and depth to coal are rarely provided in the literature and accordingly not represented in this data set. Small-scale investigations, representations and display uses are most appropriate for this product. This product is the first to show coal distribution as bounded by actual geologic contacts for the entire African continent. In addition to the spatial component of this dataset, complete references to source material are provided for each polygon, making this product a useful first step resource in African coal research. Greater detail regarding the creation of this dataset as well as the sources used is provided in the metadata file for the Africa_coal.shp file.

Open-File Report↗

Groundwater chemistry in the vicinity of the Puna Geothermal Venture Power Plant, Hawai‘i, after two decades of production

We report chemical data for selected shallow wells and coastal springs that were sampled in 2014 to determine whether geothermal power production in the Puna area over the past two decades has affected the characteristics of regional groundwater. The samples were analyzed for major and minor chemical species, trace metals of environmental concern, stable isotopes of water, and two organic compounds (pentane and isopropanol) that are injected into the deep geothermal reservoir at the power plant. Isopropanol was not detected in any of the groundwaters; confirmed detection of pentane was restricted to one monitoring well near the power plant at a low concentration not indicative of source. Thus, neither organic compound linked geothermal operations to groundwater contamination, though chemical stability and transport velocity questions exist for both tracers. Based on our chemical analysis of geothermal fluid at the power plant and on many similar results from commercially analyzed samples, we could not show that geothermal constituents in the groundwaters we sampled came from the commercially developed reservoir. Our data are consistent with a long-held view that heat moves by conduction from the geothermal reservoir into shallow groundwaters through a zone of low permeability rock that blocks passage of geothermal water. The data do not rule out all impacts of geothermal production on groundwater. Removal of heat during production, for example, may be responsible for minor changes that have occurred in some groundwater over time, such as the decline in temperature of one monitoring well near the power plant. Such indirect impacts are much harder to assess, but point out the need for an ongoing groundwater monitoring program that should include the coastal springs down-gradient from the power plant.

Hawaii↗