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At least 1,225 records · Page 68Linked to original sources

Morphological and chemical evidence of stromatolitic deposits in the 2.75 Ga Carajás banded iron formation, Brazil

We describe evidence of biogenicity in the morphology and carbon content of well-preserved, Neoarchean samples of banded iron formation (BIF) from Carajás, Brazil. Silica-rich BIF layers contain translucent ellipsoidal or trapezoidal structures (∼5–10 μm diameter) composed of silica, hematite, and kerogen, which are arranged in larger ring-like forms (rosettes). Stable carbon isotope analysis yields a δ 13 C value of −24.5‰ indicating that the contained carbon is likely biogenic. Raman and SEM analyses, as well as wavelength-dispersive X-ray elemental maps, show kerogen inside the rosette forms. Within the iron-rich BIF layers, tubular structures (0.5–5 μm) were observed between hematite granules and blades. Kerogen and kaolinite are present in these structures. Both the rosettes and the tubular structures resemble morphologies that are characteristic of some bacterial species. We hypothesize that the Carajás BIFs originated as biomats formed by one or more species that over time produced large stromatolitic structures. The rosettes and the tubular structures, associated with chert-rich and iron-rich BIF layers, respectively, may represent two different species, or perhaps, two phases of a bacterium life cycle. For example, some modern myxobacteria exhibit similar morphologies in their resting and vegetative stages. Fe(III) precipitation may have occurred by contact of Fe(II) with bacterial slime, leading to oxidation by chemical reactions with exposed polysaccharide hydroxyl and carboxyl groups. The Fe(III) would then have been available for use as a source of energy in a dissimilatory iron reduction type of metabolism. Organic carbon input presumably came from primary producers (not necessarily aerobic) within the local water column, perhaps in shallow-water communities. Alternatively, the carbon may have originated by Fischer–Tropsch synthesis at ocean hydrothermal vents. The observed lateral continuity of BIF layers may perhaps be explained by chemical signaling by the bacteria of favorable or unfavorable environmental conditions, leading to nearly synchronous cell morphogenesis from a vegetative to resting phase and vice versa.

Earth and Planetary Science Letters↗

Development of the LCMAP annual land cover product across Hawai'i

Following the completion of land cover and change (LCC) products for the conterminous United States (CONUS), the U.S. Geological Survey's (USGS’s) Land Change Monitoring, Assessment, and Projection initiative has broadened the capability of characterizing continuous historical land change across the full Landsat records for Hawaiʻi at 30-meter resolution. One of the challenges of implementing the LCMAP framework to process annual land cover maps in Hawaiʻi is to collect sufficient high-quality training data. Although multiple datasets depicting land cover information are available in Hawaiʻi, they covered limited time frames and were produced from various remote sensing sources with different, classification categories, spatial resolution, and mapping accuracies. No solo product is suitable to provide LCMAP training data labels on its own. In this paper, we focused on enhancing the LCMAP training datasets to generate land cover products from 2000 to 2019 in Hawaiʻi. A total of 200 independent reference data plots were generated and manually interpreted for validating the mapping results produced by the training datasets. The results revealed that using the appropriate filter of multiple products as training data pools improved the classification model performance. The effect of training datasets (e.g., spatial coverage, quality) on accuracies for different land cover types were summarized. The LCMAP land surface change products for Hawaiʻi are available at https://doi.org/10.5066/P91E8M23 .

Hawaii↗

Ice sheet load cycling and fluid underpressures in the Eastern Michigan Basin, Ontario, Canada

Strong fluid underpressures have been detected in Paleozoic strata in the eastern Michigan Basin, with hydraulic heads reaching ~400 m below land surface (~4 MPa underpressure) and ~200 m below sea level in strata where unusually low permeabilities (~10 −20 –10 −23  m 2 ) were measured in situ. Multiple glaciations, including three with as much as 3 km of ice cover at the site in the last 120 ka, suggest a causal link with the underpressures. We examined this possibility using a one-dimensional groundwater flow model incorporating mechanical loading from both ice weight and lithospheric flexure. Because hydrologic and mechanical changes during glaciation are not well characterized and subsurface properties are imperfectly known, the model was used inversely to estimate flexural loads and loosely constrained permeabilities by matching observed pressures. Acceptable matches were obtained for a surprisingly wide range of scenarios with permeabilities close to measured values and plausible flexural loads. Matches were not obtained when too many parameters were preselected, or when permeabilities were constrained to be significantly larger than measured values. In successful model runs groundwater expulsion under glacial-mechanical loads caused the underpressuring, and flexural loads were important if aquifer and sub-glacial pressures were significantly elevated during glaciation. Simulated fluid pressures in the low-permeability strata fluctuated by 30–40 MPa during glacial cycles but resulted in advective transport of only tens of meters or less. Although other mechanisms cannot be ruled out, we conclude that glacial-mechanical forcing of a water-saturated system can explain the observed underpressures.

Ontario↗

Structure of Sierra Madera, Texas, as a guide to central peaks of lunar craters

Like hundreds of other lunar craters of probable impact origin, Copernicus contains central peaks presumed to expose rocks uplifted from beneath the crater floor. A possible analog of these peaks on Earth is the central uplift of the Sierra Madera cryptoexplosion structure, a probable impact scar (astrobleme) in stratified Permian and Cretaceous rocks of west Texas. The most conspicuous part of this 12-km-wide structure is its central uplift, 6 to 8 km across, in which the oldest rocks have been raised 1,200 m above their normal position. The uplift is surrounded by a structural depression, beyond which is a concentric rim containing some folds and circumferential normal faults with downthrow toward the center. The intensity of folding and faulting increases inward from the flanks of the central uplift toward a central zone about 2 km across where dips and fold plunges are near vertical or overturned. As in salt domes, the beds moved inward as well as upward to occupy their present positions, causing faulting and radial folding due to crowding in the center. Repetition by folding due to inward movement of upper beds over lower appears to have been followed by upward movement of the core of the uplift pulling away from the flanks by faulting. Minor outward-directed thrusting may have been caused by gravitational spreading of the rising dome. The structural depression surrounding the uplift resulted from tectonic thinning accompanying the inward movement of rocks in the uplift. Analogy with experimental craters and with other cryptoexplosion structures indicates that the uplift at Sierra Madera protruded into a crater (since destroyed by erosion) that was about 12 km across. Inasmuch as the rocks forming such uplifts are derived from below the crater floors, analogous peaks in lunar craters such as Copernicus may offer samples of lunar crust uplifted from distances below the crater floor on the order of one-tenth of the crater diameter.

Texas↗

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] &infin; 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O &infin; 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

Linking channel hydrology with riparian wetland accretion in tidal rivers

The hydrologic processes by which tide affects river channel and riparian morphology within the tidal freshwater zone are poorly understood, yet are fundamental to predicting the fate of coastal rivers and wetlands as sea level rises. We investigated patterns of sediment accretion in riparian wetlands along the non-tidal through oligohaline portion of two coastal plain rivers in Maryland, U.S.A., and how flow velocity, water level, and suspended sediment concentration (SSC) in the channel may have contributed to those patterns. Sediment accretion was measured over a one year period using artificial marker horizons, channel hydrology was measured over a one month period using acoustic Doppler current profilers, and SSC was predicted from acoustic backscatter. Riparian sediment accretion was lowest at the non-tidal sites (mean and standard deviation = 8 ± 8 mm yr -1 ), highest at the upstream tidal freshwater forested wetlands (TFFW) (33 ± 28 mm yr -1 ), low at the midstream TFFW (12 ± 9 mm yr -1 ), and high at the oligohaline (fresh-to-brackish) marshes (19 ± 8 mm yr -1 ). Channel maximum flood and ebb velocity was 2-fold faster at the oligohaline than tidal freshwater zone on both tidal rivers, corresponding with the differences in in-channel SSC: the oligohaline zone's SSC was more than double the tidal freshwater zone's, and was greater than historical SSC at the non-tidal gages. The tidal wave characteristics differed between rivers, leading to significantly greater in-channel SSC during floodplain inundation in the weakly convergent than the strongly convergent tidal river. Overall sediment accretion was higher in the embayed river likely due to a single storm discharge and associated sedimentation.

Maryl↗

A frictional population model of seismicity rate change

We study models of seismicity rate changes caused by the application of a static stress perturbation to a population of faults and discuss our results with respect to the model proposed by Dieterich (1994). These models assume distribution of nucleation sites (e.g., faults) obeying rate-state frictional relations that fail at constant rate under tectonic loading alone, and predicts a positive static stress step at time to will cause an immediate increased seismicity rate that decays according to Omori's law. We show one way in which the Dieterich model may be constructed from simple general idead, illustratted using numerically computed synthetic seismicity and mathematical formulation. We show that seismicity rate change predicted by these models (1) depend on the particular relationship between the clock-advanced failure and fault maturity, (2) are largest for the faults closest to failure at to, (3) depend strongly on which state evolution law faults obey, and (4) are insensitive to some types of population hetrogeneity. We also find that if individual faults fail repeatedly and populations are finite, at timescales much longer than typical aftershock durations, quiescence follows at seismicity rate increase regardless of the specific frictional relations. For the examined models the quiescence duration is comparable to the ratio of stress change to stressing rate ????/??,which occurs after a time comparable to the average recurrence interval of the individual faults in the population and repeats in the absence of any new load may pertubations; this simple model may partly explain observations of repeated clustering of earthquakes. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

An ocean bottom seismometer study of shallow seismicity near the Mid- America Trench offshore Guatemala

Five ocean bottom seismometers recorded seismicity near the Mid-America Trench offshore Guatemala for 27 days in 1979. The array was emplaced in the lower slope region, just above the topographic trench, in the area investigated during Deep Sea Drilling Project legs 67 and 84. Approximately 170 events were recorded by three or more seismometers, and almost half were located with statistical hypocentral errors of less than 10 km. Most epicenters were located immediately landward of the trench axis, and many were further confined to a zone northwest of the array. In terms of depth, most events were located within the subducting Cocos plate rather than in the overlying plate or at the plate-plate boundary. Their apparent concentration in the lower crust and upper mantle may suggest that the upper crust does not have the strength to support earthquake-generating stresses. The data permit construction of a magnitude-duration scale, calibrated with m b magnitudes for events located by the World-Wide Standard Seismograph Network (WWSSN) and recorded by our array and by the network recording foreshocks and aftershocks of the 1979 Petatlan earthquake. Most magnitudes ranged between 3.0 and 4.0 m b , and the threshold magnitude of locatable events was about 2.8 m b . Two distinct composite focal mechanisms were determined. One appears to indicate high-angle reverse faulting in the subducting plate, in a plane parallel to trench axis strike. The other, constructed for some earthquakes in the zone northwest of the array, seems to show normal faulting along possible fault planes oriented quasi-perpendicular to the trench axis. The normal faulting is consistent with the segmentation of the Cocos plate that has been proposed from land evidence. Such segmentation might be evidenced offshore by normal faulting along planes subperpendicular to trench strike. Alternatively, the seismicity zone and associated normal faulting mechanism may be the subsurface expression of the tectonics responsible for the San Jose Canyon, a prominent submarine canyon located farther upslope. Finally, projection of our seismicity sample and of well-located WWSSN events from 1954 to 1980 onto a plane perpendicular to the trench axis shows a distinct gap between the shallow seismicity located by our array, and the deeper Wadati-Benioff zone seismicity located by the WWSSN. We tentatively ascribe this gap to inadequate sampling, but we suggest that it requires further investigation.

Journal of Geophysical Research Solid Earth↗

Effects of baseline conditions on the simulated hydrologic response to projected climate change

Changes in temperature and precipitation projected from five general circulation models, using one late-twentieth-century and three twenty-first-century emission scenarios, were downscaled to three different baseline conditions. Baseline conditions are periods of measured temperature and precipitation data selected to represent twentieth-century climate. The hydrologic effects of the climate projections are evaluated using the Precipitation-Runoff Modeling System (PRMS), which is a watershed hydrology simulation model. The Almanor Catchment in the North Fork of the Feather River basin, California, is used as a case study. Differences and similarities between PRMS simulations of hydrologic components (i.e., snowpack formation and melt, evapotranspiration, and streamflow) are examined, and results indicate that the selection of a specific time period used for baseline conditions has a substantial effect on some, but not all, hydrologic variables. This effect seems to be amplified in hydrologic variables, which accumulate over time, such as soil-moisture content. Results also indicate that uncertainty related to the selection of baseline conditions should be evaluated using a range of different baseline conditions. This is particularly important for studies in basins with highly variable climate, such as the Almanor Catchment.

California↗

An economic value of remote-sensing information—Application to agricultural production and maintaining groundwater quality

Does remote-sensing information provide economic benefits to society, and can a value be assigned to those benefits? Can resource management and policy decisions be better informed by coupling past and present Earth observations with groundwater nitrate measurements? Using an integrated assessment approach, the U.S. Geological Survey (USGS) applied an established conceptual framework to answer these questions, as well as to estimate the value of information (VOI) for remote-sensing imagery. The approach uses moderate-resolution land-imagery (MRLI) data from the Landsat and Advanced Wide Field Sensor satellites that has been classified by the National Agricultural Statistics Service into the Cropland Data Layer (CDL). Within the constraint of the U.S. Environmental Protection Agency's public health threshold for potable groundwater resources, the USGS modeled the relation between a population of the CDL's land uses and dynamic nitrate (NO3-) contamination of aquifers in a case study region in northeastern Iowa. Employing various multiscaled, multitemporal geospatial datasets with MRLI to maximize the value of agricultural production, the approach develops and uses multiple environmental science models to address dynamic nitrogen loading and transport at specified distances from specific sites (wells) and at landscape scales (for example, across 35 counties and two aquifers). In addition to the ecosystem service of potable groundwater, this effort focuses on the use of MRLI for the management of the major land uses in the study region-the production of corn and soybeans, which can impact groundwater quality. Derived methods and results include (1) economic and dynamic nitrate-pollution models, (2) probabilities of the survival of groundwater, and (3) a VOI for remote sensing. For the northeastern Iowa study region, the marginal benefit of the MRLI VOI (in 2010 dollars) is $858 million ±$197 million annualized, which corresponds to a net present value of $38.1 billion ±$8.8 billion for that flow of benefits in perpetuity. Given that these economic estimates are derived from one case study in a part of only one State, the estimates provide a lower estimate related to the potential value of the Landsat Data Continuity Mission.

Professional Paper↗

Debris-flow monitoring and warning: Review and examples

Debris flows represent one of the most dangerous types of mass movements, because of their high velocities, large impact forces and long runout distances. This review describes the available debris-flow monitoring techniques and proposes recommendations to inform the design of future monitoring and warning/alarm systems. The selection and application of these techniques is highly dependent on site and hazard characterization, which is illustrated through detailed descriptions of nine monitoring sites: five in Europe, three in Asia and one in the USA. Most of these monitored catchments cover less than ∼10 km 2 and are topographically rugged with Melton Indices greater than 0.5. Hourly rainfall intensities between 5 and 15 mm/h are sufficient to trigger debris flows at many of the sites, and observed debris-flow volumes range from a few hundred up to almost one million cubic meters. The sensors found in these monitoring systems can be separated into two classes: a class measuring the initiation mechanisms, and another class measuring the flow dynamics. The first class principally includes rain gauges, but also contains of soil moisture and pore-water pressure sensors. The second class involves a large variety of sensors focusing on flow stage or ground vibrations and commonly includes video cameras to validate and aid in the data interpretation. Given the sporadic nature of debris flows, an essential characteristic of the monitoring systems is the differentiation between a continuous mode that samples at low frequency (“non-event mode”) and another mode that records the measurements at high frequency (“event mode”). The event detection algorithm, used to switch into the “event mode” depends on a threshold that is typically based on rainfall or ground vibration. Identifying the correct definition of these thresholds is a fundamental task not only for monitoring purposes, but also for the implementation of warning and alarm systems.

Earth-Science Reviews↗

Carbon dioxide and helium emissions from a reservoir of magmatic gas beneath Mammoth Mountain, California

Carbon dioxide and helium with isotopic compositions indicative of a magmatic source ( δ 13 C = −4.5 to −5‰, 3 He/ 4 He = 4.5 to 6.7 R A ) are discharging at anomalous rates from Mammoth Mountain, on the southwestern rim of the Long Valley caldera in eastern California. The gas is released mainly as diffuse emissions from normal‐temperature soils, but some gas issues from steam vents or leaves the mountain dissolved in cold groundwater. The rate of gas discharge increased significantly in 1989 following a 6‐month period of persistent earthquake swarms and associated strain and ground deformation that has been attributed to dike emplacement beneath the mountain. An increase in the magmatic component of helium discharging in a steam vent on the north side of Mammoth Mountain, which also began in 1989, has persisted until the present time. Anomalous CO 2 discharge from soils first occurred during the winter of 1990 and was followed by observations of several areas of tree kill and/or heavier than normal needlecast the following summer. Subsequent measurements have confirmed that the tree kills are associated with CO 2 concentrations of 30–90% in soil gas and gas flow rates of up to 31,000 g m −2 d −1 at the soil surface. Each of the tree‐kill areas and one area of CO 2 discharge above tree line occurs in close proximity to one or more normal faults, which may provide conduits for gas flow from depth. We estimate that the total diffuse CO 2 flux from the mountain is approximately 520 t/d, and that 30–50 t/d of CO 2 are dissolved in cold groundwater flowing off the flanks of the mountain. Isotopic and chemical analyses of soil and fumarolic gas demonstrate a remarkable homogeneity in composition, suggesting that the CO 2 and associated helium and excess nitrogen may be derived from a common gas reservoir whose source is associated with some combination of magmatic degassing and thermal metamorphism of metasedimentary rocks. Furthermore, N 2 /Ar ratios and nitrogen isotopic values indicate that the Mammoth Mountain gases are derived from sources separate from those that supply gas to the hydrothermal system within the Long Valley caldera. Various data suggest that the Mammoth Mountain gas reservoir is a large, low‐temperature cap over an isolated hydrothermal system, that it predates the 1989 intrusion, and that it could remain a source of gas discharge for some time.

Journal of Geophysical Research B: Solid Earth↗

Nitrogen and carbon flow from rock to water: Regulation through soil biogeochemical processes, Mokelumne River watershed, California, and Grand Valley, Colorado

Soil denitrification is an ecologically important nitrogen removal mechanism that releases to the atmosphere the greenhouse gas N2O, an intermediate product from the reduction of NO3- to N 2. In this study we evaluate the relationship between soil carbon and denitrification potential in watersheds with bedrock acting as a nonpoint source of nitrogen, testing the hypothesis that nitrate leaching to stream water is in part regulated by denitrification. Two sites, one in a Mediterranean climate and the other in an arid climate, were investigated to understand the interplay between carbon and denitrification potential. Both sites included carbonaceous bedrock with relatively high nitrogen concentrations (> 1,000 mg N kg-1) and had low background nitrogen concentrations in surface and groundwater. There was a net accumulation of carbon and nitrogen in soil relative to the corresponding bedrock, with the exception of carbonaceous shale from the arid site. There the concentration of carbon in the soil (15,620 mg C kg-1) was less than the shale parent (22,460 mg C kg-1), consistent with the bedrock being a source of soil carbon. Rates of denitrification potential (0.5-83 ??g N kg-1 hr-1) derived from laboratory incubations appeared to be related to the ratio of dissolved organic carbon and nitrate extracted from soils. These data indicate that microbial processes such as denitrification can help maintain background nitrogen concentrations to tens of ??M N in relatively undisturbed ecosystems when nitrogen inputs from weathering bedrock are accompanied by sufficient organic carbon concentrations to promote microbial nitrogen transformations.

Journal of Geophysical Research F: Earth Surface↗

Isotopic insights into biological regulation of zinc in contaminated systems

Aquatic organisms use a variety of biogeochemical reactions to regulate essential and non-essential trace metals. Many of these mechanisms can lead to isotopic fractionation, thus measurement of metal isotopes may yield insights into the processes by which organisms respond to metal exposure. We illustrate these concepts with two case studies, one involving an intra- and the other an extra-cellular mechanism of Zn sequestration. In the first study, the mayfly Neocloeon triangulifer was grown in the laboratory, and fed a diet of Zn-doped diatoms at Zn levels exceeding the requirements for normal mayfly life functions. The N. triangulifer larvae consumed the diatoms and retained their Zn isotopic signature. Upon metamorphosis, the subimago life stage lost Zn mass either in the exuvia or by excretion, and the Zn retained was isotopically enriched. Thus, Zn uptake is nonfractionating, but Zn regulation favors the lighter isotope. Thus the Zn remaining in the subimago was isotopically heavier. In the second study, Zn was adsorbed on the cell walls and exopolysaccharide secretions of cyanobacteria, which favored the heavier Zn isotope. Continued adsorption eventually resulted in nucleation and biomineralization of hydrozincite {Zn5(CO3)2(OH)6}. These case studies demonstrate the utility of Zn isotopes to provide insights into how aquatic insects respond to metal exposure.

Procedia Earth and Planetary Science↗

Ecosystem development in the Girdwood area, south-central Alaska, following late Wisconsin glaciation

Pollen analysis of two cores with discontinuous records from a peat bog near Girdwood, in south-central Alaska, provides the basis for reconstructing the first radiocarbon-dated outline of postglacial history of vegetation in the upper Turnagain Arm area of Cook Inlet. Pollen data from clayey silt underlying peat at one site indicate that the earliest known vegetation in the Girdwood area was shrub–herb tundra. Tundra vegetation developed by ∼13 800 cal years BP, soon after local retreat of glacial ice from the maximum position of the Elmendorf glacial advance (∼15 000 – 11 000 cal years BP). By ∼10 900 cal years BP, the tundra vegetation became shrubbier as Betula nana , Salix , and Ericales increased, and scattered Alnus shrubs began to colonize Turnagain Arm. By ∼9600 cal years BP, Alnus thickets with Polypodiaceae ferns became the dominant vegetation. By ∼6600 cal years BP, birch trees ( Betula neoalaskana , B. kenaica ) from the Anchorage and Kenai lowlands began to spread eastward into eastern Turnagain Arm. Mountain hemlock ( Tsuga mertensiana ) began to colonize the Girdwood area by ∼3400 cal years BP, followed soon after by Sitka spruce ( Picea sitchensis ), both Pacific coastal forest species that spread westward from Prince William Sound after a long migration from southeastern Alaska. For at least the past 2700 cal years, Pacific coastal forest composed mostly of Tsuga mertensiana , Picea sitchensis , and Alnus has been the dominant vegetation of eastern Turnagain Arm.

Alaska↗

U.S. Geological Survey Streamgage Operation and Maintenance Cost Evaluation...from the National Streamflow Information Program

To help meet the goal of providing earth-science information to the Nation, the U.S. Geological Survey (USGS) operates and maintains the largest streamgage network in the world, with over 7,600 active streamgages in 2010. This network is operated in cooperation with over 850 Federal, tribal, State, and local funding partners. The streamflow information provided by the USGS is used for the protection of life and property; for the assessment, allocation, and management of water resources; for the design of roads, bridges, dams, and water works; for the delineation of flood plains; for the assessment and evaluation of habitat; for understanding the effects of land-use, water-use, and climate changes; for evaluation of water quality; and for recreational safety and enjoyment. USGS streamgages are managed and operated to rigorous national standards, allowing analyses of data from streamgages in different areas and spanning long time periods, some with more than 100 years of data. About 90 percent of USGS streamgages provide streamflow information real-time on the web. Physical measurements of streamflow are made at streamgages multiple times a year, depending on flow conditions, to ensure the highest level of accuracy possible. In addition, multiple reviews and quality assurance checks are performed before the data is finalized. In 2006, the USGS reviewed all activities, operations, equipment, support, and costs associated with operating and maintaining a streamgage program (Norris and others, 2008). A summary of the percentages of costs associated with activities required to operate a streamgage on an annual basis are presented in figure 1. This information represents what it costs to fund a 'typical' USGS streamgage and how those funds are utilized. It should be noted that some USGS streamgages have higher percentages for some categories than do others depending on location and conditions. Forty-one percent of the funding for the typical USGS streamgage is for labor costs of the USGS staff responsible for the measurement of the streamflow in the field and the time in the office to quality assure and finalize the data. It is reasonable that funding for the entire national streamgage network would closely follow the percentages shown in figure 1 as to how the funds are invested in the network. However, actual costs are specific to a particular streamgage and can vary substantially depending on location and operational issues.

Fact Sheet↗

Hydrology of the Wibaux-Beach lignite deposit area, eastern Montana and western North Dakota

The Paleocene Harmon lignite, the principal commercial bed of the Wihaux-Beach deposit, underlies at least 150 square miles along the Montana-North Dakota border. An estimated 1 billion tons of strippable reserves underlies about 50 square miles. The Harmon lignite bed also is the most consistently occurring shallow aquifer in the area. This study was conducted to determine possible impacts of surface mining on the area's water resources. Two aquifer systems, the lower Tongue River and the upper Ludlow, were identified within about 300 feet below the Harmon lignite aquifer, but none were identified within the overlying 350 feet. The aquifers (systems) are separated by varying thicknesses of interbedded clay and silt. The Harmon lignite aquifer extends uninterrupted for several miles eastward (down dip) from the outcrop. It is from 3 to 34 feet thick and from zero to 350 feet deep. The top of the lower Tongue River aquifer system is from 0 to 115 feet below the Harmon lignite and the system is 13 to 98 feet thick. The upper Ludlow aquifer system is 128 to 214 feet below the Harmon lignite and is 5 to 84 feet thick. Both the lower Tongue River and upper Ludlow aquifer systems consist of discontinuous, vertically stacked, sinuous sand bodies deposited as channel fill in meandering and braided streams. The probability of encountering a sand bed within the aquifer systems at any one location in the study area is about 60 percent for the lower Tongue River aquifer system and 80 percent for the upper Ludlow aquifer system. Water in each aquifer flows toward the northeast and occurs under confined conditions, except in the Harmon lignite aquifer near its outcrop. Recharge occurs directly by precipitation at the outcrops and by downward leakage elsewhere. The major discharge from each aquifer is by downward leakage, although the Harmon lignite aquifer discharges less than 0.20 cubic foot per second to surface drainages within the study area. Differences in chemical quality of water among the three aquifers are subtle, but significant. The mean dissolved-solids concentrations are: Harmon lignite aquifer, 1,930 milligrams per liter; lower Tongue River aquifer system, 1,810 milligrams per liter; and upper Ludlow aquifer system, 1,550 milligrams per liter. Alkalinity, calcium, and magnesium concentrations decrease with aquifer depth. The majority of the samples were a sodium sulfate-bicarbonate type. The median pH values, from the uppermost to the lowermost aquifer, were 8.1, 8.3, and 8.5. The chemical quality of water in the Harmon lignite aquifer near the outcrop is affected by reactions in the aerated soil zone and unsaturated parts of the aquifer. Where the outcrop is heavily clinkered, recharge waters reach the aquifer rapidly and have little opportunity for solute uptake in the unsaturated zone. In nonclinkered areas, recharge waters slowly percolate through chemically active soil and unsaturated parts of the aquifer. The resulting water commonly contains 2,500 to 5,000 milligrams per liter of dissolved solids, is a calcium-magnesium sulfate type, and has a pH of less than 7.0. The impacts of mining on streamflow and stream water quality should be manageable through the effective use of earth structures for routing and impoundment of runoff water. Mining-induced potentiometric declines in the Harmon lignite aquifer probably will be several feet up to 2 or 3 miles from the mine. Mining impacts on other aquifers will be minor.

Water-Resources Investigations Report↗

Snow processes in mountain forests: Interception modeling for coarse-scale applications

Snow interception by the forest canopy controls the spatial heterogeneity of subcanopy snow accumulation leading to significant differences between forested and nonforested areas at a variety of scales. Snow intercepted by the forest canopy can also drastically change the surface albedo. As such, accurately modeling snow interception is of importance for various model applications such as hydrological, weather, and climate predictions. Due to difficulties in the direct measurements of snow interception, previous empirical snow interception models were developed at just the point scale. The lack of spatially extensive data sets has hindered the validation of snow interception models in different snow climates, forest types, and at various spatial scales and has reduced the accurate representation of snow interception in coarse-scale models. We present two novel empirical models for the spatial mean and one for the standard deviation of snow interception derived from an extensive snow interception data set collected in an evergreen coniferous forest in the Swiss Alps. Besides open-site snowfall, subgrid model input parameters include the standard deviation of the DSM (digital surface model) and/or the sky view factor, both of which can be easily precomputed. Validation of both models was performed with snow interception data sets acquired in geographically different locations under disparate weather conditions. Snow interception data sets from the Rocky Mountains, US, and the French Alps compared well to the modeled snow interception with a normalized root mean square error (NRMSE) for the spatial mean of ≤10 % for both models and NRMSE of the standard deviation of ≤13 %. Compared to a previous model for the spatial mean interception of snow water equivalent, the presented models show improved model performances. Our results indicate that the proposed snow interception models can be applied in coarse land surface model grid cells provided that a sufficiently fine-scale DSM is available to derive subgrid forest parameters.

Utah↗