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At least 1,225 records · Page 68Linked to original sources
USGS1988

U.S. Geological Survey ground-water studies in Utah

Ground water is an important natural resource in Utah. In the basins west of the Wasatch Front, and in many other parts of Utah, ground water is the primary source of water. In many of the basins of the western desert and in parts of the Colorado Plateau, ground water is the only reliable source of water. Along the Wasatch Front to the north and south of Salt Lake City, in the Uinta Basin, and in the Sevier River drainage, surface water is the primary source of water. Ground-water sources supply about 20 percent of all water used in Utah and about 63 percent of the water for public supply. Of the total amount of ground water used, 44 percent is for irrigation, 35 percent is for public supply, 11 percent is for industry, 5 percent is for rural domestic supplies, and 5 percent is for livestock. The major issues related to ground water in Utah are: -Development of additional ground-water supplies while protecting existing water rights and minimizing effects on water levels, water quality, and streamflow, and -Protection of ground-water resources from contamination by pollutants from various types of land-use and waste-disposal practices.

Utah↗
USGS2001

Simulated effects of 1994 salt-mine collapse on ground-water flow and land subsidence in a glacial aquifer system, Livingston County, New York

This report describes the hydrogeology of the Genesee Valley and the effects of the ceiling collapse of the Retsof salt mine on the aquifer system. It discusses the origin and character of glacial sediments; the occurrence, flow directions, and chemical quality of water in the aquifer system before the collapse; the effects of the collapse on the aquifer system in terms of land subsidence, water-level declines, changes in water quality, and exsolution of natural gas, and design and calibration of the ground-water-flow model. It also presents results of flow-model simulations, including an estimated ground-water budget and graphs showing the simulated water-level recovery; and results of subsidence simulations, including maps and graphs showing the extent of land subsidence.

New York↗
USGS1969

Water resources of the Salmon Falls Creek basin, Idaho-Nevada

The northern part of the Salmon Falls Creek basin, referred to as the Salmon Falls tract, contains a large acreage of good agricultural land, but the surface-water supply is inadequate to develop the area fully. Attempts to develop ground water for irrigation have been successful only locally. Specific capacities of wells drilled for irrigation and for test purposes ranged from less than 0.5 to 70 gallons per minute per foot of drawdown. The surface-water supply averages 107,000 acre-feet annually, of which about 76,000 acre-feet is diverted for irrigation. The Idavada Volcanics, the most widespread and oldest water-bearing formation in the Salmon Falls tract, consists of massive, dense, thick flows and blankets of welded silicic tuff with associated fine- to coarse-grained ash, clay, silt, sand, and gravel. Fault zones and jointed rock yield large amounts of water to wells, but massive nonjointed units yield little water. Sand, tuff, and ash beds yield moderate quantities of water. Clay, sandy clay, sand, and pea gravel occur in topographic lows on the Idavada Volcanics. The finegrained sediments yield little water to wells, but the gravel yields moderate quantities. Vesicular porphyritic irregularly jointed olivine basalt flows, which overlie the Idavada Volcanics, underlie almost all the Salmon Falls tract. Lenticular fine-grained sedimentary beds as much as 15 feet thick separate some of the flows. Joints and contacts between flows yield small to moderate amounts of water to wells. Alluvial and windblown deposits blanket most of the tract. Where they occur below the water table, the alluvial deposits yield adequate supplies for stock and domestic wells. Perched water in the alluvium along Deep Creek supplies some stock and domestic wells during most years. Ground-water supplies adequate for domestic and stock use can be obtained everywhere in the tract, but extensive exploration has discovered only five local areas where pumping ground water for irrigation is presently economically feasible. About 8,000 acre-feet was withdrawn for all uses in 1960. Natural discharge of ground water is northward -- toward the Twin Falls South Side Project and the Snake River--and is provisionally estimated to be 115,000 acre-feet annually. Ground water in the Salmon Falls tract has a medium- to high salinity hazard and a low sodium hazard. The salinity does not appear to affect crops presently grown in the tract. The southern part of the Salmon Falls Creek basin, referred to as the upper drainage basin, has little agricultural development and is used mostly for grazing livestock. Silicic volcanic rocks and tuffaceous sedimentary rocks of Tertiary age and alluvial deposits yield water to livestock, domestic, and commercial wells.

Idaho;Nevada↗
USGS1975

Hydrologic reconnaissance of the southern Uinta basin, Utah and Colorado

This report summarizes the findings of an investigation of the water resources of the southern Uinta Basin conducted by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. The purpose of the investigation was to evaluate the water resources of the southern Uinta Basin on a reconnaissance level and to provide information to assist in future planning and development of the water and related land resources.

Utah↗
USGS1971

Water resources of Salt Lake County, Utah

This report is the eighth in a series prepared by the U. S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, that describes the water resources of the western basins of Utah. (See fig. 1.) Its purpose is to present available hydrologic data on the Park Valley area, to provide an evaluation of the potential water-resource development of the area, and to identify needed studies that would improve understanding of the area's water supply.

Utah↗
USGS1992

Sampling and analysis for radon-222 dissolved in ground water and surface water

Radon-222 is a naturally occurring radioactive gas in the uranium-238 decay series that has traditionally been called, simply, radon. The lung cancer risks associated with the inhalation of radon decay products have been well documented by epidemiological studies on populations of uranium miners. The realization that radon is a public health hazard has raised the need for sampling and analytical guidelines for field personnel. Several sampling and analytical methods are being used to document radon concentrations in ground water and surface water worldwide but no convenient, single set of guidelines is available. Three different sampling and analytical methods-bubbler, liquid scintillation, and field screening-are discussed in this paper. The bubbler and liquid scintillation methods have high accuracy and precision, and small analytical method detection limits of 0.2 and 10 pCi/l (picocuries per liter), respectively. The field screening method generally is used as a qualitative reconnaissance tool.

Environmental Monitoring and Assessment↗
USGS2014

Simulation of natural flows in major river basins in Alabama

The Office of Water Resources (OWR) in the Alabama Department of Economic and Community Affairs (ADECA) is charged with the assessment of the State’s water resources. This study developed a watershed model for the major river basins that are within Alabama or that cross Alabama’s borders, which serves as a planning tool for water-resource decisionmakers. The watershed model chosen to assess the natural amount of available water was the Precipitation-Runoff Modeling System (PRMS). Models were configured and calibrated for the following four river basins: Mobile, Gulf of Mexico, Middle Tennessee, and Chattahoochee. These models required calibrating unregulated U.S. Geological Survey (USGS) streamflow gaging stations to estimate natural flows, with emphases on low-flow calibration. The target calibration criteria required the errors be within the range of: (1) ±10 percent for total-streamflow volume, (2) ±10 percent for low-flow volume, (3) ±15 percent for high-flow volume, (4) ±30 percent for summer volume, and (5) above 0.5 for the correlation coefficient (R 2 ). Seventy-one of the 90 calibration stations in the watershed models for the four major river basins within Alabama met the target calibration criteria. Variability in the model performance can be attributed to limitations in correctly representing certain hydrologic conditions that are characterized by some of the ecoregions in Alabama. Ecoregions consisting of predominantly clayey soils and (or) low topographic relief yield less successful calibration results, whereas ecoregions consisting of loamy and sandy soils and (or) high topographic relief yield more successful calibration results. Results indicate that the model does well in hilly regions with sandy soils because of rapid surface runoff and more direct interaction with subsurface flow.

Alabama↗
USGS1992

Seasonal dynamics of groundwater-lake interactions at Doñana National Park, Spain

The hydrologic and solute budgets of a lake can be strongly influenced by transient groundwater flow. Several shallow interdunal lakes in southwest Spain are in close hydraulic connection with the shallow ground water. Two permanent lakes and one intermittent lake have chloride concentrations that differ by almost an order of magnitude. A two-dimensional solute-transport model, modified to simulate transient groundwater-lake interaction, suggests that the rising water table during the wet season leads to local flow reversals toward the lakes. Response of the individual lakes, however, varies depending on the lake's position in the regional flow system. The most dilute lake is a flow-through lake during the entire year; the through flow is driven by regional groundwater flow. The other permanent lake, which has a higher solute concentration, undergoes seasonal groundwater flow reversals at its downgradient end, resulting in complex seepage patterns and higher solute concentrations in the ground water near the lake. The solute concentration of the intermittent lake is influenced more strongly by the seasonal wetting and drying cycle than by the regional flow system. Although evaporation is the major process affecting the concentration of conservative solutes in the lakes, geochemical and biochemical reactions influence the concentration of nonconservative solutes. Probable reactions in the lakes include biological uptake of solutes and calcite precipitation; probable reactions as lake water seeps into the aquifer are sulfate reduction and calcite dissolution. Seepage reversals can result in water composition that appears inconsistent with predictions based on head measurements because, under transient flow conditions, the flow direction at any instant may not satisfactorily depict the source of the water. Understanding the dynamic nature of groundwater-lake interaction aids in the interpretation of hydrologic and chemical relations between the lakes and the ground water.

Journal of Hydrology↗
USGS1993

Selenium source identification and biogeochemical processes controlling selenium in surface water and biota, Kendrick Reclamation Project, Wyoming, U.S.A.

The major tributaries draining the Kendrick Reclamation Project (KRP) account for an average of 52% of the total Se load measured in the North Platte River downstream from Casper, Wyoming. The Casper Creek drainage basin contributed the largest Se load of the five tributary sites to the North Platte River. The 4-d average Se concentration in water samples from one site in the part of the North Platte River that receives irrigation return flows exceeded the 5 μg/l U.S. Environmental Protection Agency's aquatic life criterion five time during a 50-d monitoring period in 1989. In agreement with the water-quality data, muscle and liver tissue rom rainbow trout collected from the same part of the North Platte River had Se concentrations exceeding levels known to cause reproductive failure and chronic Se poisoning. On the basis of Se: Cl, 18 O/ 16 O and D/H ratios in water from Goose and Rasmus Lee Lakes (closed-basin systems), the large Se concentrations in those lakes were derived by natural evaporation of irrigation water without leaching of soluble forms of Se from soil or rocks. Water samples from Thirtythree Mile Reservoir and Illco Pond (flow-through systems) showed considerable enrichment in Se over evaporative concentration, presumably due to leaching and desorption of Se from soil and rock. The Se: Cl ratios of irrigation drain water collected from the KRP indicate that leaching and desorption of soluble forms of Se from soils and rocks are the dominant processes in drain water. Results of a Wilcoxon matched-pairs test for 43 paired drain-water samples collected during June and August 1988, indicated there is a statistically larger concentration of Se (0.01 significance level) during the June sampling period. The larger concentrations of Se and other chemical constitutents during the early part of the irrigation season probably were due to dissolution of seleniferous salts that have accumulated in soils within the KRP since the last irrigation season. The large Se concentrations in water samples from wetland sites in the KRP were reflected in the aquatic-bird food chain. Most waterfowl and shorebirds nesting at the KRP showed Se concentrations in livers and eggs greater than levels suspected of causing adverse reproductive effects.

Wyoming↗
USGS2026

FluOil—A tool for estimating the transport and deposition of oil-particle aggregates in rivers

The FluOil tool was developed to help with planning and early response for oil spills in rivers where subsurface oil-sediment interactions result in the formation of oil-particle aggregates (OPA). The turbulence and variable velocity associated with water flowing within a natural stream channel creates the conditions needed for an oil slick to break up into small droplets and mix in the water column, collide with sediment or organic detritus, and form OPA. This process is similar to what occurs due to wave action along a shoreline. The FluOil tool estimates how fast OPA travel downstream in rivers as well as when and where they may deposit. The FluOil tool relies on pre-existing channel hydraulic data along with user-specified OPA characteristics of size, settling velocity and critical shear stress to compute OPA transport. It is important to know where OPA are transported and accumulated for understanding potential impacts on drinking water intakes, burial of sensitive habitat beds, potential toxicity to benthic organisms, and prolonged sheening from resuspension and breakup. OPA tend to accumulate with fine-grained (silt and clay) sediment deposits (“mud” or “muck”) in backwater areas, oxbows, side channels, pools, and other slow-moving reaches of rivers during low flows. Deposited OPA can be resuspended during high flows, driving continued environmental impact concerns that may extend beyond typical oil spill response timelines.

Fact Sheet↗
USGS1998

Glaciation and regional ground-water flow in the Fennoscandian Shield: Site 94

Results from a regional-scale ground-water flow model of the Fennoscandian shield suggest that ground-water flow is strongly affected by surface conditions associated with climatic change and glaciation. The model was used to run a series of numerical simulations of variable-density ground-water flow in a 1500-km-long and approximately 10-km-deep cross-section that passes through southern Sweden. Ground-water flow and shield brine transport in the cross-sectional model are controlled by an assumed time evolution of surface conditions over the next 140 ka. Simulations show that, under periglacial conditions, permafrost may locally or extensively impede the free recharge or discharge of ground water. Below cold-based glacial ice, no recharge or discharge of ground water occurs. Both of these conditions result in the settling of shield brine and consequent freshening of near-surface water in areas of natural discharge blocked by permafrost. The presence of warm-based ice with basal melting creates a potential for ground-water recharge rates much larger than under present, ice-free conditions. Recharging basal meltwater can reach depths of a few kilometers in a few thousand years. The vast majority of recharged water is accommodated through storage in the volume of bedrock below the local area of recharge; regional (lateral) redistribution of recharged water by subsurface flow is minor over the duration of a glacial advance (~10 ka). During glacial retreat, the weight of the ice overlying a given surface location decreases, and significant upward flow of ground water may occur below the ice sheet due to pressure release, despite the continued potential for recharge of basal meltwater. Excess meltwater must exit from below the glacier through subglacial cavities and channels. Subsurface penetration of meltwater during glacial advance and up-flow during glacial retreat are greatest if the loading efficiency of the shield rock is low. The maximum rate of ground-water discharge occurs at the receding ice margin, and some discharge occurs below incursive post-glacial seas. The simulation results suggest that vertical movement of deep shield brines induced by the next few glacial cycles should not increase the concentration of dissolved solids significantly above present-day levels. However, the concentration of dissolved solids should decrease significantly at depths of up to several kilometers during periods of glacial meltwater recharge. The meltwater may reside in the subsurface for periods exceeding 10 ka and may bring oxygenated conditions to an otherwise reducing chemical environment.

SKI Report↗
USGS2005

Trends in surface-water quality at selected National Stream Quality Accounting Network (NASQAN) stations, in Michigan

To demonstrate the value of long-term, water-quality monitoring, the Michigan Department of Environmental Quality (MDEQ), in cooperation with the U.S. Geological Survey (USGS), initiated a study to evaluate potential trends in water-quality constituents for selected National Stream Quality Accounting Network (NASQAN) stations in Michigan. The goal of this study is to assist the MDEQ in evaluating the effectiveness of water-pollution control efforts and the identification of water-quality concerns. The study included a total of nine NASQAN stations in Michigan. Approximately 28 constituents were analyzed for trend tests. Station selection was based on data availability, land-use characteristics, and station priority for the MDEQ Water Chemistry Monitoring Project. Trend analyses were completed using the uncensored Seasonal Kendall Test in the computer program Estimate Trend (ESTREND), a software program for the detection of trends in water-quality data. The parameters chosen for the trend test had (1) at least a 5-year period of record (2) about 5 percent of the observations censored at a single reporting limit, and (3) 40 percent of the values within the beginning one-fifth and ending one-fifth of the selected period. In this study, a negative trend indicates a decrease in concentration of a particular constituent, which generally means an improvement in water quality; whereas a positive trend means an increase in concentration and possible degradation of water quality. The results of the study show an overall improvement in water quality at the Clinton River at Mount Clemens, Manistee River at Manistee, and Pigeon River near Caseville. The detected trend for these stations show decreases in concentrations of various constituents such as nitrogen compounds, conductance, sulfate, fecal coliform bacteria, and fecal streptococci bacteria. The negative trend may indicate an overall improvement in agricultural practices, municipal and industrial wastewater-treatment processes, and effective regulations. Phosphorus data for most of the study stations could not be analyzed because of the data limitations for trend tests. The only station with a significant negative trend in total phosphorus concentration is the Clinton River at Mount Clemens. However, scatter-plot analyses of phosphorus data indicate decreasing concentrations with time for most of the study stations. Positive trends in concentration of nitrogen compounds were detected at the Kalamazoo River near Saugatuck and Muskegon River near Bridgeton. Positive trends in both fecal coliform and total fecal coliform were detected at the Tahquamenon River near Paradise. Various different point and nonpoint sources could produce such positive trends, but most commonly the increase in concentrations of nitrogen compounds and fecal coliform bacteria are associated with agricultural practices and sewage-plant discharges. The constituent with the most numerous and geographically widespread significant trend is pH. The pH levels increased at six out of nine stations on all the major rivers in Michigan, with no negative trend at any station. The cause of pH increase is difficult to determine, as it could be related to a combination of anthropogenic activities and natural processes occurring simultaneously in the environment. Trends in concentration of major ions, such as calcium, sodium, magnesium, sulfate, fluoride, chloride, and potassium, were detected at eight out of nine stations. A negative trend was detected only in sulfate and fluoride concentrations; a positive trend was detected only in calcium concentration. The major ions with the most widespread significant trends are sodium and chloride; three positive and two negative trends were detected for sodium, and three negative and two positive trends were detected for chloride. The negative trends in chloride concentrations outnumbered the positive trends. This result indicates a slight improvement in surface-water quality because chloride as a point source in natural water comes from deicing salt, sewage effluents, industrial wastes, and oil fields. For other major ions, such as magnesium and potassium, both positive and negative trends were detected. These changes in trends indicate changes in surface-water quality caused by a variety of point and non-point sources throughout Michigan, as well as natural changes in the environment.

Michigan↗
USGS1962

Data on uranium and radium in ground water in the United States, 1954 to 1957

This report is one of a series resulting from a study by the U.S. Geological Survey to determine the occurrence and distribution of naturally radioactive substances in water. From 1954-57 uranium and radium concentrations were determined in 561 samples, mainly of ground water, having wide geologic and geographic distribution. These concentrations, together with data on the hydrologic and geologic environment, the beta-gamma activity, and the chemical characteristics of each sample, are tabulated by States. The conterminous United States was subdivided into 10 geotectonic regions to facilitate statistical interpretation of the occurrence of uranium and radium in fresh water in approximately homogeneous geologic provinces. For each geotectonic region, the range and median were determined for the concentrations of radium and uranium; for regions from which sufficient data were available, log-normal frequency distribution curves were calculated and superimposed on histograms of radium and uranium concentrations in the samples. An "anomaly threshold" is suggested for both radioelements for each region analyzed statistically. The western stable region had the greatest median and highest "anomaly threshold" for uranium. This region also had the highest "anomaly threshold" for radium, but the largest median for radium was found for samples collected in the Ozark-Ouachita system. The median concentration for uranium was lowest for the Atlantic and Gulf Coastal Plain and the Pacific orogenic belt. This latter region also had the lowest median-radium content.

Professional Paper↗
USGS1989

Humic substances in the Suwannee River, Georgia; interactions, properties, and proposed structures

Humic substances as a collective term and humic and fulvic acids as specific terms are not household words. For about a century, these terms belonged to the domain of the soil scientist. Even^though their chemical structures remained elusive, they were recognized as important entities in soil. During the past decade or so, there has been a renewed interest in humic substances in soil and water. Such interest has been the result of improved analytical instrumentation, and by a need to understand the structure and function of natural organic substances in water. A responsibility of the U.S. Geological Survey is to assess the Nation's water resources; this includes water quality, which is the study of material in water. Such material may be suspended, colloidal, or in true solution. Because humic substances are a major carbon source in water, they have received attention by Geological Survey scientists. This attention has been a major focus by members of the Geological Survey's organic-chemistry group. For more than a decade, this group has collected samples, made analyses, and worked toward determining the structures and function of humic substances in water. Their work has brought worldwide recognition to the field, and in 1981, through Geological Survey support, they helped organize the International Humic Substances Society, which held its first meeting in Estes Park, Colorado, in August 1983. At the second meeting of the Society in Birmingham, England, in August 1984, it became apparent that Geological Survey scientists were rapidly advancing the study of the chemistry of humic substances. It seemed appropriate, therefore, to publish this Open-File report on humic and fulvic acids from the Suwannee River in Georgia. The results represent our most definitive findings to date (1986). Though this work is not conclusive, it is state-of-the-science. Hopefully, our reporting on this work will aid in moving the science of humic substances forward as others read of our progress, findings, and theories. If so, this Open-File report will have served its purpose.

Georgia↗
USGS1995

Water Budget for the Island of Kauai, Hawaii

A geographic information system model was created to calculate a monthly water budget for the island of Kauai. Ground-water recharge is the residual component of a monthly water budget calculated using long-term average rainfall, streamflow, and pan-evaporation data, applied irrigation-water estimates, and soil characteristics. The water-budget components are defined seasonally, through the use of the monthly water budget, and spatially by aquifer-system areas, through the use of the geographic information system model. The mean annual islandwide water-budget totals are 2,720 Mgal/d for rainfall plus irrigation; 1,157 Mgal/d for direct runoff; 911 Mgal/d for actual evapotranspiration; and 652 Mgal/d for ground-water recharge. Direct runoff is 43 percent, actual evapotranspiration is 33 percent, and ground-water recharge is 24 percent of rainfall plus irrigation. Ground-water recharge in the natural land-use areas is spatially distributed in a pattern similar to the rainfall distribution. Distinct seasonal variations in the water-budget components are apparent from the monthly water-budget calculations. Rainfall and ground-water recharge peak during the wet winter months with highs in January of 3,698 Mgal/d (million gallons per day) and 981 Mgal/d, respectively; a slight peak in July and August relative to June and September is caused by increased orographic rainfall. Recharge is lowest in June (454 Mgal/d) and November (461 Mgal/d).

Water-Resources Investigations Report↗
USGS2012

Effects of brush management on the hydrologic budget and water quality in and adjacent to Honey Creek State Natural Area, Comal County, Texas, 2001--10

Woody vegetation, including ashe juniper ( Juniperus ashei ), has encroached on some areas in central Texas that were historically oak grassland savannah. Encroachment of woody vegetation is generally attributed to overgrazing and fire suppression. Removing the ashe juniper and allowing native grasses to reestablish in the area as a brush management conservation practice (hereinafter referred to as "brush management") might change the hydrology in the watershed. These hydrologic changes might include changes to surface-water runoff, evapotranspiration, or groundwater recharge. The U.S. Geological Survey (USGS), in cooperation with Federal, State, and local partners, examined the hydrologic effects of brush management in two adjacent watersheds in Comal County, Tex. Hydrologic data were collected in the watersheds for 3-4 years (pre-treatment) depending on the type of data, after which brush management occurred on one watershed (treatment watershed) and the other was left in its original condition (reference watershed). Hydrologic data were collected in the study area for another 6 years (post-treatment). These hydrologic data included rainfall, streamflow, evapotranspiration, and water quality. Groundwater recharge was not directly measured, but potential groundwater recharge was calculated by using a simplified mass balance approach. This fact sheet summarizes highlights of the study from the USGS Scientific Investigations Report on which it is based.

Texas↗
USGS1998

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin— Ground-water quality in the Prairie du Chien-Jordan aquifer, 1996

The Prairie du Chien-Jordan (PDCJ) aquifer (Prairie du Chien-Trempealeau aquifer in Wisconsin), composed of dolomite and sandstone of Cambrian to Ordovician age, is the principal bedrock aquifer in the Upper Mississippi River study unit of the National Water-Quality Assessment (NAWQA) Program. The aquifer supplies approximately 75 percent of the ground water withdrawn in the area. In certain areas, the aquifer is overlain by bedrock or glacial deposits having low hydraulic conductivity (termed "confined portion" of the aquifer in this report). In other areas the aquifer is overlain by glacial sand and gravel deposits having greater hydraulic conductivity (termed "unconfined portion" of the aquifer in this report). Differences in the hydrogeologic characteristics of these overlying units have potential to affect the downward movement of water and of contaminants into the aquifer from the land surface. Ground-water samples were collected from 50 domestic wells completed in this aquifer in July, August, and September of 1996 as part of the U.S. Geological Survey's National WaterQuality Assessment Program. The purpose of this report is to describe the chemical characteristics of water in the PDCJ aquifer and to summarize the differences in water quality in confined and unconfined portions of the aquifer. Twenty-five wells were sampled in each portion of the aquifer. Water samples from the wells were measured for physical parameters and analyzed for concentrations of major ions, nutrients, dissolved organic carbon, trace metals, radon, tritium, pesticides, and volatile organic compounds. Differences in anthropogenic and naturally occurring materials in water between confined and unconfined portions of the PDCJ aquifer are small and frequently the differences are not statistically significant at the 95 percent confidence level. Dissolved oxygen concentrations were slightly less and specific conductances and alkalinities were slightly greater in water in the confined portion of the aquifer. Only the differences in specific conductance and alkalinity, however, were statistically significant at the 95 percent confidence level (two sample t-test). Concentrations of most major ions were generally greater in water from the confined portion of the aquifer. Nitrate (nitrite plus nitrate as N) and phosphorus were generally greater in the unconfined portion of the PDCJ aquifer although the differences were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). In the confined portion of the aquifer no samples exceeded the maximum contaminant level of 10 milligrams per liter for nitrate. In the unconfined portion of the aquifer nitrate in two samples exceeded the maximum contaminant level of 10 milligrams per liter. Phosphorus concentrations were generally about an order of magnitude less than nitrate concentrations. Iron and manganese concentrations commonly exceeded the secondary maximum contaminant levels set by the U.S. Environmental Protection Agency and were generally greater in the confined portion of the PDCJ aquifer, although the differences were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). Radon concentrations were greater in the confined portion of the aquifer than in the unconfined portion, although the difference was not statistically significant at the 95 percent confidence level (two sample t-test), with medians of 500 and 340 picoCuries per liter, respectively. Sixty-six percent of the radon concentrations were greater than the suspended maximum contaminant level of 300 picoCuries per liter. Tritium concentrations indicate that water in the unconfined portion of the PDCJ aquifer may have been recharged more recently than water in the confined portion of the aquifer, although differences in tritium concentrations between confined and unconfined portions of the aquifer were not statistically significant at the 95 percent confidence level (nonparametric MannWhitney test). Atrazine and its metabolite, deethylatrazine, were the most frequently detected pesticide compounds in water samples from the PDCJ aquifer. Volatile organic compounds were detected in 41 of the 50 water samples, but none of the concentrations exceeded 1 microgram per liter. Concentrations of volatile organic compounds were slightly greater in the unconfined portion, although the differences in detection rates were not statistically significant at the 95 percent confidence level (nonparametric Mann-Whitney test). Carbon disulfide and methyl chloride were the most frequently detected volatile organic compounds. Water in the unconfined portion of the PDCJ aquifer in Minnesota and Wisconsin appears to be affected to a greater degree by anthropogenic activities than water in the confined portion of the aquifer. Water in the confined portion has a longer residence time and greater concentrations of dissolution products of minerals. In general, however, differences in anthropogenic and naturally occurring materials among confined and unconfined portions of the aquifer are small and frequently not significantly different.

Minnesota, Wisconsin↗
USGS2003

Determination of sulfate in seawater and natural brines by 133Ba and membrane dialysis

Dissolved sulfate is determined by precipitation with the radioisotope 133 Ba and counting of the precipitate on a scintillation counter. Precipitation is carried out in dialysis bags; excess 133 Ba is removed via diffusion by soaking the bags in distilled water for 12 h, and the bags are then placed directly in the well of the scintillation counter. The procedure eliminates previous errors caused by washing and transferring of the precipitate and permits analysis of 0.5–3,000 µ g·ml −1 sulfate in a 1.0-ml sample. The detection limit is increased by simply increasing the sample volume up to 5.0 ml. The technique is interference-free in natural waters ranging from freshwater to brines of 1.5 times the salinity of seawater.

Limnology and Oceanography↗