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USGS2023

Recognizing political influences in participatory social-ecological systems modeling

Stakeholder participation in social-ecological systems (SES) modeling is increasingly considered a desirable way to elicit diverse sources of knowledge about SES behavior and to promote inclusive decision-making in SES. Understanding how participatory modeling processes function in the context of long-term adaptive management of SES may allow for better design of participatory processes to achieve the intended outcomes of inclusionary knowledge, representativeness, and social learning, while avoiding unintended outcomes. Long-term adaptive management contexts often include political influences -- attempts to shift or preserve power structures and authority, and efforts to represent the political and economic interests of stakeholders -- in the computer models that are used to shape policy making and implementation. In this research, we examine a period that included a major transition in the watershed model used for management of the Chesapeake Bay in the United States. The Chesapeake Bay watershed model has been in development since the 1980s, and is considered by many to be an exemplary case of participatory modeling. We use documentary analysis and interviews with participants involved in the model application and development transition to reveal a variety of ways in which participatory modeling may be subject to different kinds of political influences, some of which resulted in unintended outcomes, including: perceptions of difficulty updating the model in substantive ways, “gaming” of the model/participatory process by stakeholders, and increasing resistance against considering uncertainty in the system not captured by the model. This research suggests unintended or negative outcomes may be associated with both participatory decision-making and stakeholder learning even though they are so often touted as the benefits of participatory modeling. We end with a hypothesis that further development of a theory of computer model governance to bridge model impact and broader theories of environmental governance at the science-policy interface may result in improved SES modeling outcomes.

Maryland, Virginia↗

USGS2011

Unmarked: An R package for fitting hierarchical models of wildlife occurrence and abundance

Ecological research uses data collection techniques that are prone to substantial and unique types of measurement error to address scientific questions about species abundance and distribution. These data collection schemes include a number of survey methods in which unmarked individuals are counted, or determined to be present, at spatially- referenced sites. Examples include site occupancy sampling, repeated counts, distance sampling, removal sampling, and double observer sampling. To appropriately analyze these data, hierarchical models have been developed to separately model explanatory variables of both a latent abundance or occurrence process and a conditional detection process. Because these models have a straightforward interpretation paralleling mechanisms under which the data arose, they have recently gained immense popularity. The common hierarchical structure of these models is well-suited for a unified modeling interface. The R package unmarked provides such a unified modeling framework, including tools for data exploration, model fitting, model criticism, post-hoc analysis, and model comparison.

Journal of Statistical Software↗

USGS2013

Human and biophysical influences on fire occurrence in the United States

National-scale analyses of fire occurrence are needed to prioritize fire policy and management activities across the United States. However, the drivers of national-scale patterns of fire occurrence are not well understood, and how the relative importance of human or biophysical factors varies across the country is unclear. Our research goal was to model the drivers of fire occurrence within ecoregions across the conterminous United States. We used generalized linear models to compare the relative influence of human, vegetation, climate, and topographic variables on fire occurrence in the United States, as measured by MODIS active fire detections collected between 2000 and 2006. We constructed models for all fires and for large fires only and generated predictive maps to quantify fire occurrence probabilities. Areas with high fire occurrence probabilities were widespread in the Southeast, and localized in the Mountain West, particularly in southern California, Arizona, and New Mexico. Probabilities for large-fire occurrence were generally lower, but hot spots existed in the western and south-central United States The probability of fire occurrence is a critical component of fire risk assessments, in addition to vegetation type, fire behavior, and the values at risk. Many of the hot spots we identified have extensive development in the wildland–urban interface and are near large metropolitan areas. Our results demonstrated that human variables were important predictors of both all fires and large fires and frequently exhibited nonlinear relationships. However, vegetation, climate, and topography were also significant variables in most ecoregions. If recent housing growth trends and fire occurrence patterns continue, these areas will continue to challenge policies and management efforts seeking to balance the risks generated by wildfires with the ecological benefits of fire.

Ecological Applications↗

USGS2007

Lethal and sublethal effects of ammonia to juvenile Lampsilis mussels (Unionidae) in sediment and water-only exposures

We compared the sensitivity of two juvenile unionid mussels (Lampsilis cardium and Lampsilis higginsii) to ammonia in 96-h water-only and sediment tests by use of mortality and growth measurements. Twenty mussels were placed in chambers buried 2.5 cm into reference sediments to approximate pore-water exposure (sediment tests) or elevated above the bottom of the experimental units (water-only tests). In the sediment tests, a pH gradient existed between the overlying water (mean 8.0), sediment-water interface (mean 7.7), and 2.5 cm depth (mean 7.4). We assumed that mussels were exposed to ammonia in pore water and report effect concentrations in pore water, but if they were exposed to the higher pH water, more of the ammonia would be in the toxic un-ionized (NH 3) form. The only differences in toxicity and growth between mussel species occurred in some of the water-only tests. In sediment tests, median lethal concentrations (LC50s) ranged from 124 to 125 ??g NH3-N/L. In water-only tests, LC50s ranged from 157 to 372 ??g NH3-N/L. In sediment tests, median effective concentrations (EC50s based on growth) ranged from 30 to 32 ??g NH3-N/L. Juvenile mussels in the water-only tests grew poorly and did not exhibit a dose-response relation. These data demonstrate that growth is a sensitive and valuable endpoint for studies on ammonia toxicity with juvenile freshwater mussels and that growth should be measured via sediment tests. ?? 2007 SETAC.

Environmental Toxicology and Chemistry↗

USGS2007

Development of a mercury speciation, fate, and biotic uptake (BIOTRANSPEC) model: Application to Lahontan Reservoir (Nevada, USA)

A mathematically linked mercury transport, speciation, kinetic, and simple biotic uptake (BIOTRANSPEC) model has been developed. An extension of the metal transport and speciation (TRANSPEC) model, BIOTRANSPEC estimates the fate and biotic uptake of inorganic (Hg(II)), elemental (Hg(0)) and organic (MeHg) forms of mercury and their species in the dissolved, colloidal (e.g., dissolved organic matter [DOM]), and particulate phases of surface aquatic systems. A pseudo-steady state version of the model was used to describe mercury dynamics in Lahontan Reservoir (near Carson City, NV, USA), where internal loading of the historically deposited mercury is remobilized, thereby maintaining elevated water concentrations. The Carson River is the main source of total mercury (THg), of which more than 90% is tightly bound in a gold-silver-mercury amalgam, to the system through loadings in the spring, with negligible input from the atmospheric deposition. The speciation results suggest that aqueous species are dominated by Hg-DOM, Hg(OH)2, and HgClOH. Sediment-to-water diffusion of MeHg and Hg-DOM accounts for approximately 10% of total loadings to the water column. The water column acts as a net sink for MeHg by reducing its levels through two competitive processes: Uptake by fish, and net MeHg demethylation. Although reservoir sediments produce significant amounts of MeHg (4 g/d), its transport from sediment to water is limited (1.6 g/d), possibly because of its adsorption on metal oxides of iron and manganese at the sediment-water interface. Fish accumulate approximately 45% of the total MeHg mass in the water column, and 9% of total MeHg uptake by fish leaves the system because of fishing. Results from this new model reiterate the previous conclusion that more than 90% of THg input is retained in sediment, which perpetuates elevated water concentrations.

Nevada↗

USGS2008

Potential for 4- n -nonylphenol biodegradation in stream sediments

The potential for in situ biodegradation of 4-nonylphenol (4-NP) was investigated in three hydrologically distinct streams impacted by wastewater treatment plants (WWTPs) in the United States. Microcosms were prepared with sediments from each site and amended with [U-ring- 14 C]4- n -nonylphenol (4- n -NP) as a model test substrate. Microcosms prepared with sediment collected upstream of the WWTP outfalls and incubated under oxic conditions showed rapid and complete mineralization of [U-ring- 14 C]4- n -NP to 14 CO 2 in all three systems. In contrast, no mineralization of [U-ring- 14 C]4- n -NP was observed in these sediments under anoxic (methanogenic) conditions. The initial linear rate of [U-ring-14C]4-n-NP mineralization in sediments from upstream and downstream of the respective WWTP outfalls was inversely correlated with the biochemical oxygen demand (BOD) of the streambed sediments. These results suggest that the net supply of dissolved oxygen to streambed sediments is a key determinant of the rate and extent of 4-NP biodegradation in stream systems. In the stream systems considered by the present study, dissolved oxygen concentrations in the overlying water column (8–10 mg/L) and in the bed sediment pore water (1–3 mg/L at a depth of 10 cm below the sediment–water interface) were consistent with active in situ 4-NP biodegradation. These results suggest WWTP procedures that maximize the delivery of dissolved oxygen while minimizing the release of BOD to stream receptors favor efficient biodegradation of 4-NP contaminants in wastewater-impacted stream environments.

Colorado, Iowa↗

USGS2026

Identifying overwintering habitat of silver and bighead carp in the lower Mississippi River: Implications for harvesting and population reduction

A total of 41 sites along a 58 mi reach of the Lower Mississippi River (LMR) were surveyed during winter 2022 for invasive carp aggregation.* Sites consisting of scallops closest to the dike-vegetated bank interface with deeper, slow-moving water and consistent access back to the main channel were preferred. Carp avoided strong currents, and there was no trend in depth selection other than avoiding shallow (less than 20 ft) water. In January 2023, recreation-grade sonar (e.g., side-scan and down-imaging) surveys were conducted in the same reach of the LMR to demonstrate the technology and evaluate carp population size at sites with high abundances based on previous surveys. Fish density was estimated to be 32 fish/10,000 yd 3 (95% confidence interval [CI; 31–34]) using down-imaging software, which is the first estimate of assumed bigheaded carp density in the LMR. Additional fish collections are needed to confirm species composition and size abundance provided by sonar technology. Resurveying sites with high carp abundance over a range of river stages would be necessary to fully characterize habitat conditions, evaluate influence of river stage on occupancy duration, and continue to evaluate species composition and mass removal techniques as a management option in the Lower Mississippi River.

Louisiana, Mississippi↗

USGS2023

Getting Started with MODFLFOW

Numerical modeling of groundwater flow systems was once accessible only to modeling specialists in the hydrogeological community. Software such as MODFLOW—the most frequently used groundwater modeling program in the world—and associated graphical user interfaces (GUIs) have made modeling possible for most groundwater scientists. This book provides the bridge from understanding to implementing models by introducing the basics of MODFLOW version 6 and providing readers who have a working knowledge of groundwater flow with a guide through construction of their first groundwater model.

Book↗

USGS2010

Algal blooms and "Marine snow": Mechanisms that enhance preservation of organic carbon in ancient fine-grained sediments

Combined petrographic and geochemical methods are used to investigate the microfabrics present in thin sections prepared from representative organic carbon-rich mudstones collected from three successions (the Kimmeridge Clay Formation, the Jet Rock Member of the Whitby Mudstone Formation, and the pebble shale and Hue Shale). This study was initiated to determine how organic carbon-rich materials were being delivered to the sediment–water interface, and what happened to them after deposition, prior to deep burial. Analyses of the fabrics present shows that they exhibit many common attributes. In particular they are all: (1) highly heterogeneous on the scale of a thin section, (2) organized into thin beds (< 10 mm thick) composed mainly of mineral mixtures of fine-grained siliciclastic detritus and carbonate materials, and (3) contain significant concentrations of organic carbon, much of which is organized into laminasets that contain abundant organomineralic aggregates and pellets. In addition, framboidal pyrite (range of sizes from < 20 μm to < 1 μm) and abundant agglutinated foraminifers are present in some units. The individual beds are commonly sharp-based and overlain by thin, silt lags. The tops of many of the beds have been homogenized and some regions of the pelleted laminasets contain small horizontal burrows. The organomineralic aggregates present in these mudstones are interpreted to be ancient examples of marine snow. This marine snow likely formed in the water column, particularly during phytoplankton blooms, and was then transported rapidly to the seafloor. The existence of the thin beds with homogenized tops and an in-situ infauna indicates that between blooms there was sufficient oxygen and time for a mixed layer to develop as a result of sediment colonization by diminutive organisms using either aerobic or dysaerobic metabolic pathways. These textures suggest that the constituents of these mudstones were delivered neither as a continuous rain of sediment nor were the bottom waters persistently anoxic. In addition, the presence of thin lags and sharp-based beds suggests that the seafloor was being episodically reworked during deposition. These fabrics indicate that conditions in the water columns and at the seafloors while these rocks were being deposited were very dynamic, and episodic fluxes of high concentrations of organic carbon to the seafloor, during phytoplankton blooms, likely enhanced preservation of organic carbon.

Journal of Sedimentary Research↗

USGS2014

Distal facies variability within the Upper Triassic part of the Otuk Formation in northern Alaska

The Triassic-Jurassic Otuk Formation is a potentially important source rock in allochthonous structural positions in the northern foothills of the Brooks Range in the North Slope of Alaska. This study focuses on three localities of the Upper Triassic (Norian) limestone member, which form a present-day, 110-km-long, east-west transect in the central Brooks Range. All three sections are within the structurally lowest Endicott Mountain allochthon and are interpreted to have been deposited along a marine outer shelf with a ramp geometry. The uppermost limestone member of the Otuk was chosen for this study in order to better understand lateral and vertical variability within carbonate source rocks, to aid prediction of organic richness, and ultimately, to evaluate the potential for these units to act as continuous (or unconventional) reservoirs. At each locality, 1 to 4 m sections of the limestone member were measured and sampled in detail to capture fine-scale features. Hand sample and thin section descriptions reveal four major microfacies in the study area, and one diagenetically recrystallized microfacies. Microfacies 1 and 2 are interpreted to represent redeposition of material by downslope transport, whereas microfacies 3 and 4 have high total organic carbon (TOC) values and are classified as primary depositional organofacies. Microfacies 3 is interpreted to have been deposited under primarily high productivity conditions, with high concentrations of radiolarian tests. Microfacies 4 was deposited under the lowest relative-oxygen conditions, but abundant thin bivalve shells indicate that the sediment-water interface was probably not anoxic. The Otuk Formation is interpreted to have been deposited outboard of a southwest-facing ramp margin, with the location of the three limestone outcrops likely in relatively close proximity during deposition. All three sections have evidence of transported material, implying that the Triassic Alaskan Basin was not a low-energy, deep-water setting, but rather a dynamic system with intermittent, yet significant, downslope flow. Upwelling played an important role in the small-scale vertical variability in microfacies. The zone of upwelling and resultant oxygen-minimum zone may have migrated across the ramp during fourth- or fifth-order sea-level changes.

Alaska↗

USGS2004

Potential sources of hydrogel stabilization of Florida Bay lime mud sediments and implications for organic matter preservation

The fine grained carbonate mud sediments of central Florida Bay are resuspended quite easily. However, this disturbance is usually limited to the surficial ('floc') layer, as the underlying sediments appear to be stabilized by an hydrogelation involving the bulk organic matter. That gelation has occurred within these sediments is suggested from their physical behavior and an observed mathematical relationship between the percentages of organic carbon (C org) and water. Specifically, when extruded from a core barrel, the sediment maintains its integrity and has the consistency of a fine spackling compound. However, upon homogenization, as with a stirring rod prior to sieving, these sediments break into two distinct phases, 1/2-2/3 milky water and 1/3-1/2 sediment grains, by volume. The relationship observed between Corg and water was modeled as both linear (% water = (0.0777) Corg + 0.2984, R2 = 0.8664) and logarithmic (% water = 0.2489 Ln Corg + 0.2842, R2 = 0.9455) functions. As this relationship tends to be asymptotic at higher Corg (>3.5% dry)/water values (>60%) and given an higher correlation, the relationship appears better modeled as a logarithmic function. Values of C org from 1.2 to over 6.5%dry wt. and water contents from 30 to over 70%wt. were observed. The calculated intercept revealed that, without organic carbon (viz. hydrogel formation), these carbonates would likely contain only ???30% water by weight ('m' from linear model). This gelation is proposed to involve exopolymeric substances (EPS), likely polysaccharides, derived from diatoms and cyanobacteria of the microphytobenthos. A cyanobacterial-diatomaceous biofilm/mat underlain by purple sulfur bacteria was shown, by pigment based chemotaxonomy, to form the main components of the microphytobenthos. Additional water column detrital biomass, also mainly cyanobacteria and diatoms, is admixed with the living microphytobenthos in a flocculent/nephloid layer above the sediments prior to final incorporation into the gel-stabilized sediment column. Loss of seagrass cover appears to have allowed higher energy wave induced effects to reach the water-(nephloid)-sediment interface and increase overall turbidity in the bay. The effects of these gelatinized organics upon sediment stability, pore water chemistry and dissolved species flux in/out of the sediments are discussed as areas for future research which takes this (hydro-) gelation phenomenon into account.

Journal of Coastal Research↗

USGS2025

Multiscale framework for assessing land cover change on barrier islands from extreme storms and restoration

Often found along the estuarine-marine interface, barrier islands and mainland coastal zones are shaped by tides, currents, extreme storms, and relative sea-level rise. These systems provide ecosystem services such as storm surge and wave attenuation, erosion protection to inland areas, habitat for fish and wildlife, recreation, and tourism. Given the importance of these ecosystems coupled with their dynamic nature, information on how these coastal systems are changing can help to inform natural resource management. Remote sensing advancements have led to an abundance of data for monitoring change in coastal settings. This study developed a multiscale framework that can provide trajectory information from screening-level analyses by using existing or custom moderate spatial resolution land cover maps. Using the north-central Gulf Coast as a case study, the trajectory of land cover area for barrier islands and mainland coastal zones was assessed using several geospatial data sets, including: (1) long-term moderate-resolution remote sensing products with an annual (or more frequent) temporal frequency; (2) a restoration database ( e.g. , beach/dune restoration, sediment placement, and dune enhancement); and (3) a tropical storm database. Due to the coarser spatial resolution of data sets used for screening-level analyses, detailed or application-specific analyses are often needed to reduce uncertainty in smaller changes that may not be captured. These may include land cover change analyses ( i.e. this study), periodic land cover maps with higher spatial resolution and more detailed land cover classes, or elevation-related analyses ( e.g. , dune change or inundation change). Using this framework, abrupt changes in land cover on Dauphin Island, Alabama, resulting from extreme storms were detected using moderate spatial resolution screening-level data, while restoration impact analyses may require higher resolution data. Further, land cover change analyses that incorporate change allocation provide robust information for understanding land cover change in dynamic coastal settings.

Alabama, Florida↗

USGS2004

Ad Duwayhi, Saudi Arabia: Geology and geochronology of a neoproterozoic intrusion-related gold system in the Arabian shield

The Ad Duwayhi gold deposit, located in the east-central part of the Arabian shield, is the newest gold discovery in Saudi Arabia. Exploration to date has identified a gold resource of greater than 1 million ounces (oz) with significant potential for expansion. Gold mineralization was closely associated, in time and space, with emplacement of a late- to postorogenic, intracrustal, northwest-oriented granite body (659 ± 7 Ma) and comagmatic square quartz porphyry (646 ± 11 Ma), a hypabyssal and perhaps younger phase of the granite. Mineralization was largely confined to northeast-striking, southeast-dipping fault zones. Hydrothermal alteration consisted of early biotitic alteration overprinted by sericitic alteration. Sericitic alteration was coincident with gold mineralization and produced a quartz-sericite-carbonate-pyrite-rutile mineral assemblage, found both as vein fill and wall-rock alteration products. Mineralization styles, in the following general paragenetic sequence, include (1) quartz-molybdenite veins in and near the granite stock, (2) low-grade gold-bearing quartz vein breccia in and along the margins of the granite stock, (3) gold-bearing stockwork and sheeted quartz veins, and (4) massive to banded gold-rich tabular quartz veins. The gold-bearing stockwork, sheeted, and tabular veins are generally spatially associated with square quartz porphyry dikes and more distal to the granite stock. Mineralized zones at Ad Duwayhi are characterized by low sulfide and base metal content and gold/silver ratios of approximately 6/1. Gold shows no significant correlation with other metals, except lead, and moderate correlation with silver. Re-Os dating of molybdenite from a quartz-molybdenite vein and a tabular quartz vein with cogenetic gold produced robust ages of 655.6 ± 2.7 and 649.9 ± 2.3 Ma, respectively, documenting that gold mineralization and crystallization of granite and square quartz porphyry were, within uncertainty, coeval events. This age correlation combined with granite textural features, the presence of unidirectional solidification textures in granite and square quartz porphyry, and the nature and time-space distribution of mineralization styles, all indicate that mineralization evolved in and near the interface between a crystallizing magma and the surrounding rocks and, thus, is consistent with an intrusion-related genesis. In light of our findings at Ad Duwayhi, a reassessment of similar intrusion-hosted deposits in the Arabian shield is warranted, and areas of late- to postorogenic plutonism, particularly in the Afif composite terrane, should be considered prospective for intrusion-related gold systems.

Economic Geology↗

USGS2005

Foliation development and reaction softening by dissolution and precipitation in the transformation of granodiorite to orthogneiss, Glastonbury Complex, Connecticut, U.S.A

Textures, microstructures, and patterns of chemical zoning in minerals in a granodioritic orthogneiss in the Glastonbury Complex, Connecticut, lead to the interpretation that foliation development was facilitated by retrograde hydration reactions in the presence of an aqueous fluid. Incomplete replacement of the metastable magmatic minerals K-feldspar + hastingsite + magnetite produced foliation-defining biotite + epidote + quartz. These reaction products did not replace K-feldspar – hastingsite interfaces; rather, either biotite or epidote replaced the amphibole, and plagioclase replaced K-feldspar. Biotite and epidote precipitated syntectonically in discrete layers that define the foliation in the orthogneiss, whereas quartz precipitated primarily in ribbons, further enhancing the fabric. Metastable REE-rich igneous titanite also dissolved, and was incompletely replaced by REE-poor, Al-bearing metamorphic titanite. The similar concentrations of the REE in epidote and titanite show that the REE released by titanite dissolution were precipitated locally as the allanite component in adjacent grains of epidote. The entire process was syntectonic, with most grains showing multiple overgrowths in the direction of extension as defined by stretched xenoliths. Sufficient U was present in the titanite overgrowths to allow SHRIMP dating of cores, mantles, and rims. These results suggest at least three retrograde Alleghanian events of growth in a span of ~30 m.y. Thus the dissolution – transportation –precipitation process not only describes the reaction mechanism but also leads to the redistribution of reaction products into nearly monomineralic layers, thus contributing to metamorphic differentiation and to the development of the foliation. The resulting orthogneiss was much weaker that the granodiorite protolith, owing to this reaction and textural softening.

Connecticut↗

USGS1962

The origin of jasperoid in limestone

The name jasperoid has been applied to rocks that consist mainly of silica and that have formed by replacement. This paper considers only those jasperoids formed by replacement of limestone . Major problems involved in the origin of such jasperoid include: source of the silica; nature of solutions that dissolve, transport, and precipitate silica; and the mechanism of replacement of limestone by silica. The answers to these problems are of practical as well as scientific interest because many jasperoid bodies are closely related to mineralization. Silica may be derived from: juvenile silica of magmatic origin ; silica leached from underlying rocks by hydrothermal solutions; silica locally derived from enclosing rocks by circulating solutions; and silica carried downward in ground water from the weathering of overlying rocks. The nature and the concentration of other substances in solutions influence, in a complex manner, the ability of these solutions to dissolve, transport, and precipitate silica. Nevertheless, the following generalizations can be made. The solubility and rate of solution of silica in water at moderate pressure increase slowly with temperature up to 200 degrees C.; from 200 degrees to 360 degrees C. they increase rapidly; above 360 degrees C. solubility is pressure dependent, increasing steadily at high pressure and decreasing slightly at moderate pressure due to the formation of a vapor phase. The pH has slight effect on the ionic solubility of silica in the range from pH 1 to ph 9 at low temperature. The effect of other components on the solubility of silica is probably subordinate to that of temperature above 200 degrees C., but becomes increasingly important as the temperature falls below that point. Most jasperoid bodies form by both replacement and silica deposition in voids, with replacement dominant during the early phase, and precipitation dominant during later phases. Replacement of limestone by silica is favored by relatively low temperature acid solutions, and the presence of CO 2 . As limestone dissolves, Ca ions are released to promote the precipitation of colloidal silica. Acid solutions then diffuse through this gelatinous film to continue dissolving limestone behind it; the Ca ions diffusing outward cause the precipitation of more colloidal silica at the solution-gel interface. As the gel mass ages, it shrinks, hardens, and ruptures. More silica is then deposited in the fractures. Eventually the gel crystallizes to a dense mass of aphanitic quartz and chalcedony, with shrinkage cracks and vugs filled or coated with younger coarse-grained quartz and other minerals that have been deposited directly from solution. The theory that relatively low temperature favors the formation of jasperoid replacement bodies in carbonate rocks, and high temperature inhibits their formation, offers an explanation for the gap that is observed in some districts between contact metasomatic lime silicates and siliceous replacement of limestone . This gap is characterized by the lack of any reaction between limestone and silica-bearing solutions moving through it.

Economic Geology↗

USGS1978

Origin of a South Texas roll-type uranium deposit; I, Alteration of iron-titanium oxide minerals

The detrital Fe-Ti oxide minerals and their authigenic alteration products in samples from cores spanning 1.7 km across a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, south Texas, record important information on host-rock preparation and on development of the altered tongue of the deposit. In reduced rock, in front of and enveloping the altered tongue, iron disulfide minerals (pyrite and marcasite) have partially to completely replaced titanomagnetite and, to a lesser extent, titanohematite. Subsequent oxidation of these sulfidized Fe-Ti oxides, by processes that formed the altered tongue and uranium roll, produced ferric oxide and hydroxide phases (limonite) pseudomorphous after the sulfides. Fe-Ti oxides 1.0 km updip from the roll front were never sulfidized; titanomagnetite (partly replaced by hematite) and martite constitute nearly half of the heavy mineral fraction and limonite is absent. Oxidized rocks 210 m and closer to the nose of the roll front, however, are nearly devoid of titanomagnetite and contain abundant limonite. The redox interface that bounds the altered tongue, therefore, moved more than 210 m but less than 1.0 km. Detrital Fe-Ti oxide minerals are increasingly sulfidized in the downdip direction indicating that initial sulfidizaton was more intense in that direction. Organic carbon content is uniformly very low throughout the host sandstone, which implies that heterotrophic sulfate-reducing bacteria were not involved in the generation of sulfide. The H 2 S for the initial sulfidization may have been derived from oil and gas in formations that underlie the Catahoula Tuff. The H 2 S probably invaded the Catahoula along a fault that is 1.5 km downdip from the present roll front.

Texas↗

USGS1989

A reinterpretation of the δD H 2 O of inclusion fluids in contemporaneous quartz and sphalerite, Creede mining district, Colorodo: a generic problem for shallow orebodies?

Water extracted from fluid inclusions in quartz from shallow epithermal ore deposits often has a hydrogen isotope composition (δD) different from that of water extracted from inclusions in associated minerals. This difference is usually attributed to the involvement of primary fluids from multiple sources. Isotopic and homogenization and freezing temperature determinations on fluid inclusions from contemporaneous quartz and sphalerite from the epithermal, silver and base metal orebodies of the OH vein, Creede district, Colorado, suggest an alternative explanation. In near-surface deposits, differences between δD H 2 O of inclusion fluids in ore minerals and quartz may result, instead, from contamination during extraction of the fluids contained in primary inclusions by shallow ground water trapped in pseudosecondary inclusions in quartz. Quartz from the OH vein contains two principal petrographically distinct populations of fluid inclusions: primary and pseudosecondary. The primary inclusions have salinities ranging from 5 to 10 equiv wt percent NaCl, and the salinities of pseudosecondary inclusions cluster between 0 and 1 percent. Primary inclusions in quartz from one locality have a measured δD H 2 O value of -69 per mil, while pseudosecondary inclusions at the same locality have a δD H 2 O value of -102 per mil. Both salinity and isotopic values for primary inclusions in quartz are similar to those for primary inclusions in contemporaneous sphalerite. Homogenization temperatures for primary and pseudosecondary inclusions in quartz range from 191° to 280° C and from 199° to 278° C, respectively. The δD H 2 O value measured on fluid inclusions from bulk crystals ranges between -97 and -85 per mil and represents a mixture of fluids from both primary and pseudosecondary inclusions. We interpret the data to indicate that one or more episodes of abrupt incursion of cooler, overlying ground water into the ore zone caused thermal cracking of the quartz crystals during the time interval of mineralization. Subsequent healing of the fractures trapped heated, low-salinity ground water in pseudosecondary inclusions. The abrupt incursions of overlying ground water are speculated to have resulted from either collapse of a transient vapor-dominated region of the ore zone, or catastrophic venting of the system through hydrothermal eruption(s). The unusually high contrast between the salinities of the ore-depositing fluids and the ground water overlying the ore zone allowed recognition of this phenomenon at Creede. It is likely, however, that Creede is not unique. Similar phenomena may be common in shallow ore zones where rapid fluctuation of an interface between a deep, high-temperature thermal plume and an overlying, cooler ground water may be expected to occur. Careful study of the origins of fluid inclusions, particularly in quartz, is essential to characterize the primary ore fluids and to assess the role of ground water in the hydrology of shallow ore deposits.

Colorado↗

USGS1990

Genesis of the tabular-type vanadium-uranium deposits of the Henry Basin, Utah

Tabular-type vanadium-uranium deposits occur in fluvial sandstones of the Salt Wash Member of the Morrison Formation of Late Jurassic age The mineralized intervals and the weakly mineralized lateral extensions are bounded both above and below by zones rich in dolomite cement. Carbon isotope values of dolomite cements indicate that at least two sources of carbon existed. One source appears to be the same as that which formed the bedded carbonates in the evaporites in the Tidwell Member of the Morrison Formation stratigraphically below the mineralized interval. The second carbon source is typical of terrestrially deposited carbonates generally associated with meteoric water-dominated environments. Oxygen isotope values of these dolomites show the same trend of isotopically light values above the mineralized interval and isotopically heavier values in and below that interval; they indicate that two isotopically distinct fluids were involved in the mineralizing process. Some aspects of the origin of gangue and ore phases are explainable on the basis of processes which occurred solely within the saline fluid, but key aspects of ore genesis involved the interaction of the saline and meteoric waters. It is postulated that the solution interface migrated vertically within the stratigraphic section. -from Authors

Utah↗