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Constraining the earthquake recording threshold of intraslab earthquakes with turbidites in southcentral Alaska’s lakes and fjords

Strong ground motion from intraslab earthquakes, which do not produce primary paleoseismic evidence, may initiate gravity-driven turbidity flows in subaqueous basins. The resulting deposits (turbidites) can provide a paleoseismic proxy if the conditions that initiate these flows are known. To better constrain the initiating conditions, we use two recent intraslab earthquakes in southcentral Alaska, the M w 7.1 30 November 2018 Anchorage earthquake and the M w 7.1 24 January 2016 Iniskin earthquake, as calibration events. Through a multilake investigation, we document the occurrence, or the absence, of earthquake-generated turbidity flows from these two events. Both earthquakes are recorded by centimeter-scale turbidites that can be differentiated from climatically generated deposits, as well as other seismic sources based on deposit thickness, sedimentological properties, and deposit age. We show that a Modified Mercalli Intensity (MMI) of ∼V–V1/2 is the minimum shaking intensity required to generate localized sediment remobilization from deltaic slopes, and an MMI of ∼V1/2 is required to produce a deposit of sufficient thickness that a seismic origin can be confidently assigned. The documentation of seismically generated deposits in quick succession (∼2 years) with diagnostic features highlights the utility of using recent earthquakes as calibration events to investigate the subaqueous response to strong ground motion.

Alaska

Oligocene–Miocene northward growth of the Tibetan Plateau: Insights from intermontane basins in the West Qinling Belt, NW China

Growth of the Tibetan Plateau, Earth’s broadest and highest elevation collisional system, shapes orographic barriers, reorganizes drainage networks, and influences surface erosion and sediment delivery, whose changes in space and provenance feed back to intracontinental tectonic processes. Studies of interior basins within the northern Tibetan Plateau provide new sediment accumulation, provenance, paleodrainage, and deformation timing data that enable a reconstruction of the far-field tectono-geomorphic evolution of the rising Tibetan Plateau. Along the northern plateau margin, topographic growth in the West Qinling Belt is inferred to have initiated in the Eocene, nearly coeval with the India-Asia collision, as well as in the late Miocene. However, geological knowledge about the intervening period remains at present enigmatic, and the kinematics and dynamics are uncertain. This study presents a multidisciplinary data set from the intermontane Anhua-Huicheng Basin (AHB; Gansu Province, China) to fill this gap. Magnetostratigraphic dating, regional mapping, and sedimentological analysis imply that contractional deformation and thrust-top basin systems formed within the West Qinling Belt in the Oligocene (not later than ca. 24 Ma). A combination of observations including paleocurrent changes, detrital zircon U-Pb age variations, and appearance of growth strata along the Anhua-Huicheng Basin reveal the rapid uplift of the West Qinling Belt at ca. 15 Ma. Sedimentation in the intermontane basins ended after the late Miocene (ca. 8 Ma), when the region experienced intrabasinal deformation, uplift, and erosion with the establishment of an external drainage system. Since the late Miocene, the growth of the West Qinling Belt reached a climax with the lack of substantial contractional deformation in Cenozoic sequences heralding the onset of the modern kinematic regime and attainment of high elevation. Observed transitions in the tectonostratigraphy and paleodrainage define different phases of deformation and plateau-wide shifts in stress reorganization, which led to the northward growth and later lateral expansion of the Tibetan Plateau.

GSA Bulletin

Case study of deep learning image segmentation for the purposes of rapid 2D petrographic analysis in volcanic rocks

Automation using deep learning methods is a useful alternative to manual methods of petrographic segmentation, but often requires user familiarity with coding and/or algorithms. We examine the Dragonfly TM program's deep learning tools for application by users with a variety of skill levels as a method for petrographic image segmentation. An image processing methodology, bimodal image stacking, was created for low-input-data, high-efficacy training of models which can then be applied to varied samples. Using backscatter electron images we show that the resulting model segmentations agree with manual segmentation total and modal crystallinity values within 5%, and calculated plagioclase crystal size distribution (CSD) values within 2σ, despite limitations in discriminating mafic phases. Model creation and training takes <24 hours, 1–3 hours of which are supervised, and the resultant model can then be applied to new uncharacterized samples in <15 minutes per image. This allows for non-experts to create and utilize deep learning models to segment images of variable brightness and texture, at low user-time cost and resulting in size and shape data which are within uncertainty of manual segmentation. While some limitations are noted (for example, sieve-textured phases may need manual correction, and different minerals with similar BSE intensity may not be resolved as separate phases), this methodology can be utilized for general application of models to wide ranges of volcanic crystalline and bubble textures, and to create a library of models for rapid petrological analysis during volcanic eruptions.

Alaska

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Late Pleistocene kinematics of the Great Southern Puerto Rico Fault Zone, Puerto Rico

Several onshore faults in southern Puerto Rico have recently been recognized as Quaternary active. However, the kinematics of these faults, particularly any lateral component, remain largely unconstrained. It is difficult to characterize low strain‐rate faults, partially due to extensive erosional and anthropogenic landscape modification, steep relief, and frequent landsliding, limiting the preservation of geomorphic features that could serve as recorders of fault motion. Here, we constrain the kinematics along sections of the Great Southern Puerto Rico Fault Zone (GSPRFZ) on the southern coastal plain of Puerto Rico. We integrate ∼1‐m‐resolution light detection and ranging (lidar)‐derived topography, historical air photos, and field mapping to identify a series of ∼50–1200‐m‐long fault scarps and lineaments that trend northwest–southeast and extend for ≥25 km across the southern coastal plain. Fault scarps are primarily south facing, cut across topography, and displace Quaternary deposits and landforms. We document multiple offset geomorphic markers, including channel thalwegs and interfluves formed in deposits previously mapped as Quaternary piedmont alluvial plain. We observe both vertical (south‐side‐down) and right‐lateral meter‐scale displacements, which indicate that the GSPRFZ accommodates right‐lateral oblique motion in the late Pleistocene, consistent with northeast motion of the Puerto Rico and the Virgin Islands microplate away from the Hispaniola block.

Puerto Rico

A methods framework for evaluating measurement consistency across spectrometers for multispectral uncrewed aerial system vegetation mapping applications

The U.S. Geological Survey collects remote sensing data to support national scientific assessments of natural resources, hazards, and landscape change. Spectrometers and spectroradiometers are essential for gathering point-based spectral measurements used in applications such as uncrewed aerial systems (UAS) multispectral image calibration, validation, and analysis. Evaluating how different instruments perform in laboratory and field environments helps determine whether they provide consistent, interoperable measurements. Such verification can expand access to spectral ground data during UAS operations by allowing scientists to use alternative instruments when budgets, logistics, or field conditions limit options. We propose and test a methodological framework for evaluating spectrometers for measurement consistency during UAS multispectral vegetation mapping applications. There are three central evaluation components to the framework: laboratory, field, and relative to UAS multispectral imagery. By evaluating the instruments in both relatively controlled and uncontrolled environments, we thoroughly examine measurement consistency and when/why measurements may differ. We opportunistically selected two instruments for a case study in a coastal marsh setting: a compact laboratory spectrometer we modified for field use and a field-ready spectroradiometer. The instruments produced consistent measurements in both environments. We found differences between the field spectra and UAS spectra that likely reflect the perspectives of ground vs. aerial data and indicate that further radiometric calibration may be needed.

Massachusetts

Regional variations in sea ice and primary productivity in the Bering Sea during Marine Isotope Stage 11

Marine Isotope Stage (MIS) 11 (424-374 ka) has long been an analog for Holocene climate, because it is the most recent interglacial period with similar orbital conditions. However, there is significant global and regional variability in the climate response to MIS 11 warmth. Here, we review sediment core records from across the Bering Sea to investigate changes in paleoceanographic conditions during Marine Isotope Stages 12-10. Sea ice was present over much of the Bering Sea during MIS 11, but today, none of the sites investigated are ever ice-covered. This suggests that sea ice regimes in the Bering Sea during MIS 11 were different to those of the Holocene. There are also regional differences in the response of sea ice to MIS 11 warming. At the Umnak Plateau, Southeastern Bering Sea, sea ice concentrations decline during deglaciation, but they remain high at the slope sites until Peak MIS 11. Sea ice re-advances over the Umnak Plateau during peak interglacial warmth, at the same time that it declines over the slope sites. Late MIS 11 is characterized by high concentrations of seasonal sea ice at the Umnak Plateau, whilst sea ice at the slope sites fluctuates between consolidated and unconsolidated ice cover. This east-west dichotomy may be explained by changes in the behavior of the Aleutian Low. Productivity increases dramatically during deglaciation due to increased upwelling and sea level rise bringing fresh nutrients into the oceans. This is characterized by increased diatom productivity, increased terrestrial carbon deposition, and laminations at all sites.

Alaska

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Hydraulic properties of the Madison aquifer system in the western Rapid City area, South Dakota

Available information on hydrogeology, data from borehole geophysical logs, and aquifer tests were used to determine the hydraulic properties of the Madison aquifer. From aquifer-test analysis, transmissivity and storage coefficient were determined for the Minnelusa and Madison aquifers, and vertical hydraulic conductivity (K v ') along with specific storage (Ss') for the Minnelusa confining bed. Borehole geophysical well logs were used to determine the thickness and location of the Minnelusa aquifer, the lower Minnelusa confining bed, and the Madison aquifer within the Madison Limestone. Porosity values determined from quantitative analysis of borehole geophysical well logs were used in analyzing the aquifer-test data. The average porosity at the two aquifer-test sites is about 10 percent in the Minnelusa aquifer, 5 percent in the lower Minnelusa confining bed, and 35 percent in the Madison aquifer. The first aquifer test, which was conducted at Rapid City production well #6, produced measured drawdown in the Minnelusa and Madison aquifers. Neuman and Witherspoon's method of determining the hydraulic properties of leaky two-aquifer systems was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. Analysis of the aquifer test for the Minnelusa aquifer yielded a transmissivity value of 12,000 feet squared per day and a storage coefficient of 3 x 10 -3 . The specific storage of the Minnelusa confining bed was 2 x 10 -7 per foot, and its vertical hydraulic conductivity was 0.3 foot per day. The transmissivity of the Madison aquifer at this site was 17,000 feet squared per day, and the storage coefficient was 2 x 10 -3 . The second aquifer test, which was conducted at Rapid City production well #5 (RC-5) produced measured drawdown only in the Madison aquifer. Hantush and Jacob's method of determining the hydraulic properties of leaky confined aquifers with no storage in the confining bed was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. The analysis of data from the RC-5 aquifer test showed that transmissivity was not equal in all directions. Hantush's method was used to determine the direction of radial anisotropy and magnitude of the major and minor axes of transmissivity. The major axis of transmissivity is at an angle of 42° east of north, and the transmissivity along this axis is about 56,000 feet squared per day. The minor axis of transmissivity is at an angle of 48° west of north, and the transmissivity along this axis is about 1,300 feet squared per day. The major axis of transmissivity intersects Cleghorn Springs, a large resurgent spring on the west edge of Rapid City. The shape of the potentiometric contours of the Madison aquifer near RC-5 agree with the orientation of the transmissivity ellipse. The average value of the storage coefficient from the isotropic analysis of the aquifer-test data was 3.5 x 10 -4 , and the average vertical hydraulic conductivity of the lower Minnelusa confining bed was 9.6 x 10 -3 foot per day.

South Dakota

Ground-motion simulations for the 2024 Mw 4.8 Tewksbury, New Jersey, earthquake

Ground-motion simulations of notable earthquakes in the central and eastern United States are limited and typically assume one-dimensional (1D) Earth structure. In this study, we use a three-dimensional (3D) seismic velocity model to better constrain the depth and focal mechanism of the April 5th, 2024, moment magnitude 4.8 Tewksbury earthquake and investigate the spatial variability of earthquake ground motions and the effects of nearby sedimentary basins. We perform earthquake ground-motion simulations up to 0.5 Hz using the 3D spectral-element wave-propagation solver SPECFEM3D over a region 280-km wide by 260-km long by 77-km deep. Topography and subsurface geophysical structure are assigned using the U.S. Geological Survey National Crustal Model with a minimum shear-wave velocity of 200 m/s. We use earthquake time series from 13 broadband seismic stations in the region that have a uniform azimuthal distribution and epicentral distances ranging from 76 to 131 km to compare with synthetics and explore the effects of 1D versus 3D seismic structure on focal mechanism and depth solutions. Ground-motion intensity metrics are also presented relative to the NGA-East ground-motion models (GMMs) currently used in seismic hazard assessments for the region. We find that the 3D model, which reveals a wide spatial variability of period-dependent ground motions, yields better predictions of earthquake ground motions relative to the 1D model and the NGA-East ergodic ground-motion model, with 76 percent reduction of residual variance in observed ground motions averaged over 3-, 5-, 7-, and 10-second periods. Use of the 3D model to solve for a focal mechanism yields a shallower focal depth at 4 km and a shallower east-dipping focal plane relative to the U.S. Geological Survey regional moment tensor and Global Centroid Moment Tensor. Our study demonstrates that use of 3D seismic velocity models can improve estimates of earthquake focal mechanisms, ground motions, and seismic hazard.

New Jersey

Developments in African industrial minerals for renewable energy

Introduction Africa is emerging as a leading source for minerals used in the manufacture of batteries for electric vehicles and in other renewable energy applications. New graphite, lithium, and rare-earth mines have or could be opened in African countries from 2017 through 2026. Estimates of production capacities for graphite, lithium, and rare-earth mines for 2023 and beyond are based upon supply-side assumptions, such as announced plans for new capacity construction and bankable feasibility studies, as well as projected trends that could affect current producing facilities in 2023 and planned new facilities projected to come online by 2026. Forward-looking information, including estimates of future production capacities, graphite flake distributions, and timing of the start of operations, are subject to risk factors and uncertainties that could cause actual events or results to differ significantly from expected outcomes. Projects listed in this report are presented as an indication of industry plans and are not a U.S. Geological Survey (USGS) prediction of what will take place. Only projects with planned startup dates are included in this report; ther graphite, lithium, and rare-earth projects in Africa without startup dates were known to be in various stages of development but are not included in this fact sheet.

Fact Sheet

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy

Treatability study to evaluate bioremediation of trichloroethene at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, 2020–22

Executive Summary Chlorinated solvents, including trichloroethene (TCE) and other chlorinated volatile organic compounds (cVOCs), are widespread contaminants that can be treated by bioremediation approaches that enhance anaerobic reductive dechlorination. Reductive dechlorination can be enhanced either through the addition of an electron donor (biostimulation) or the addition of a known dechlorinating culture (bioaugmentation) along with an electron donor. Although bioremediation has been applied at many TCE-contaminated groundwater sites, application in source zones at sites where residual dense nonaqueous phase liquid (DNAPL) is present is more limited. In this study, laboratory and field treatability tests were completed to evaluate the potential application of anaerobic bioremediation for a shallow groundwater plume containing TCE in a perched alluvial aquifer at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, which was on the National Priorities List as the New Brighton/Arden Hills Superfund site until 2019. In addition to the presence of residual DNAPL at the site, temporal variability in groundwater flow directions and input of oxygenated recharge were possible complicating factors for the application of enhanced anaerobic biodegradation in the shallow plume. The Site K plume extends beneath the footprint of Building 103, which was demolished in 2006, and soil excavations to a maximum depth of 6 feet (ft) below ground surface in 2014 were known to leave some deeper contaminated soil in place in the TCE source area. Groundwater treatment at the site, formalized as part of the 1997 Record of Decision, has been in operation since 1986 and consists of an extraction trench at the downgradient edge of the plume to collect groundwater, which is then pumped to an on-site air stripper. Groundwater concentrations in the plume have been relatively stable since treatment began, indicating a continued source of TCE in the aquifer. The desire for a destructive remedy that would enhance the removal of cVOCs in the aquifer at Site K and shorten the remediation timeframe led the U.S. Army to request that the U.S. Geological Survey conduct a groundwater treatability study to assess bioremediation. This report describes the U.S. Geological Survey bioremediation treatability study conducted during 2020–22, including pre-design site characterization to assist in formulating the bioremediation approach, laboratory experiments to support the design of the field pilot test, and implementation and 1-year performance monitoring results for the pilot test. Pre-design site characterization included the collection of soil cores for cVOC analysis and lithologic descriptions and the re-installment of three wells to obtain hydrologic measurements and initial groundwater chemistry. Relatively flat head gradients were measured at the site, and substantial decreases in water-level elevations occurred from spring to summer (May–July 2021). Continuous water-level monitoring indicated a rapid response to precipitation. Groundwater flow velocities were consistently less than 0.5 foot per day, and the pilot bioremediation test was therefore designed with short lateral distances (about 5 ft) between injection and individual monitoring points. Soil analyses confirmed that high volatile organic compound contamination was left in place in the source area. The highest concentrations were near or in clay at the base of the perched aquifer. Concentrations of cVOCs measured in the replaced wells were consistent with historical data and had a maximum TCE concentration of 57,700 micrograms per liter (μg/L), indicative of nearby residual DNAPL based on the general rule of observed concentrations exceeding 1 percent of solubility. The primary TCE daughter product detected was 1,2-cis-dichloroethene (cisDCE), which indicated limited reductive dechlorination in the plume. Groundwater in both the source and downgradient areas was relatively reducing during the pre-design characterization, particularly in the source area where methane concentrations greater than 400 μg/L were measured. Initial laboratory tests conducted using native aquifer microorganisms from the three replacement wells showed that anaerobic TCE biodegradation rates were low when biostimulated with the addition of sodium lactate as an electron donor, also known as a carbon donor, and resulted in the production of only cisDCE. Addition of a known dechlorinating culture, WBC-2, however, resulted in rapid biodegradation and production of ethene, verifying complete reductive dechlorination of TCE. Microcosms constructed with aquifer soil collected from the site were used to evaluate other electron donors besides lactate to support reductive dechlorination by WBC-2, including corn syrup as an alternative fast-release compound and whey, soy-based vegetable oil, and 3-D Microemulsion (Regenesis, San Clemente, California) as slow-release compounds. First-order rate constants for total organic chlorine removal in these WBC-2 amended microcosms were greatest with either lactate or vegetable oil as the donor, ranging between 0.061 and 0.047 per day or corresponding half-lives of 11–15 days. Testing of commercial products in other WBC-2-bioaugmented microcosms led to selection for the field pilot test of an emulsified vegetable oil product that also contained some sodium lactate as a fast-release donor. Delaying the addition of WBC-2 relative to the donor in the microcosms resulted in the most rapid overall biodegradation rates. The selected design for the pilot test utilized three separate test plots, each about 30-ft wide and 60-ft long: plots GS1 and GS2 in the source area of the plume and plot GS3 in the downgradient area of the plume near the excavation trench. Each test plot had one injection well, one monitoring well upgradient from the injection point, and 12 surrounding monitoring wells in a grid to capture variable groundwater flow directions. Donor injections, which included a bromide tracer, were completed in October 2021, immediately following baseline sampling, and the WBC-2 culture was injected about 40 days later, between November 30 and December 2, 2021. Performance monitoring conducted until December 2022 included hydrologic measurements and analyses of cVOCs, redox-sensitive constituents, dissolved organic carbon, bromide, volatile fatty acids, compound-specific carbon isotopes, and microbial communities. The biogeochemical data collected during the pilot tests in the three treatment plots showed that enhanced, complete reductive dechlorination of cVOCs in the groundwater was achieved in the GS1 and GS3 plots. In contrast, evidence of distribution of the injected amendments and subsequent biodegradation was limited in GS2, which was in an area of more heterogeneous soil lithology and low water table elevations. The molar composition of volatile organic compounds in the GS1 and GS3 plots was dominated by ethene in wells that were reached by the injected amendments by the end of the monitoring period. In the GS1 and GS3 plots, similar patterns were observed of cVOC concentrations decreasing to near detection levels, or below, at some wells sampled in July and October 2022, whereas ethene became dominant and indicated sustained complete reductive dechlorination. Baseline cVOC concentrations were more than a factor of 10 higher in the groundwater in the GS1 plot than in GS3, but no apparent inhibition of complete dechlorination occurred. As expected from the initial pre-design site data and the laboratory experiments, enhanced dissolution of residual DNAPL coupled to biodegradation was evident in the GS1 plot, where a marked increase in dichloroethene (DCE) above the initial baseline and upgradient TCE and DCE concentrations occurred. DCE concentrations subsequently declined where DNAPL dissolution was evident, concurrent with production of vinyl chloride and then predominantly ethene. Thus, overall biodegradation rates outpaced the DNAPL dissolution and desorption and DCE production in the source area. This success in complete degradation to predominantly ethene was achieved even in areas where the DCE concentrations reached a maximum of about 30,000 μg/L. Compound specific isotope analysis of carbon in TCE, cisDCE, trans-1,2-dichloroethene, and vinyl chloride was conducted to provide another line of evidence of the occurrence and extent of anaerobic biodegradation. Along a flow path in each plot that was affected by the injected amendments, carbon isotopes in the TCE and daughter cVOCs in the groundwater became isotopically heavier, indicating biodegradation. Enhanced biodegradation rates calculated from the field tests in GS1 and GS3 showed half-lives of 36.9–75.3 days for DCE degradation and 9.48–38.5 days for ethene production. Notably, these ethene production rates calculated from the field tests are consistent with the results of WBC-2-bioaugmented microcosms amended with either lactate or vegetable oil, which had half-lives for total organic chlorine removal that ranged from 11 to 15 days. These rates indicated rapid enhanced biodegradation, which is promising for application of a full-scale bioremediation remedy. Ultimately, however, the mass of residual or sorbed TCE in the aquifer that remains accessible for dissolution and biodegradation would likely control the time required for a full-scale bioremediation effort to achieve performance goals for TCE and cisDCE specified in the Record of Decision for Site K. The field pilot tests showed that the relatively low hydraulic head gradients and temporal changes in groundwater flow directions in the shallow aquifer would add complexity to a full-scale bioremediation effort. The radius of influence (ROI) at GS1 and GS3 (16.3 ft and 12.7 ft, respectively) were close to the design ROI of 15 ft. The estimated ROI at GS2 was about four times the design ROI, but may be less reliable at this location owing to groundwater flow direction. In addition, the low temperatures following WBC-2 injection in late November to early December 2021, in combination with the low hydraulic head gradients, were probably major factors in the delay observed before the onset of enhanced biodegradation following injection of the culture. Additional test injections could be beneficial to optimize the timing of donor and culture injections with the variable temperatures and hydraulic head in the shallow aquifer.

Minnesota

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon

Do Graviquakes exist?

The “Graviquake” model, proposed in 2015 as an alternative to the elastic dislocation model, posits that normal faults are passive features dominated by coseismic gravitational collapse into a dilated crustal wedge, and that normal faulting is fundamentally distinct from strike‐slip and reverse faulting. Developed using finite‐element modeling before the 2016 central Apennines earthquake sequence, the model was revamped based on interpreted Differential Interferometric Synthetic Aperture Radar data from these events and used as evidence for a gravitational collapse episode. However, this interpretation relies on miscalculated elevation changes and is not corroborated by independent geophysical and seismological observations. Our analysis exposes fundamental flaws in the Graviquake model. By assuming that faults are passive players, it underrepresents the dynamic role of strain accumulation and release in rocks adjacent to faults. The hypothesized rapid expulsion of overpressurized fluids appears inconsistent with observed diffusion rates and lacks supporting seismological evidence. Part of the uplifted–subsided volume imbalance is likely an artifact arising from data processing, and in part is a transient effect due to the delayed response of the lower crust. Moment tensor analyses detect no isotropic components indicative of gravitational collapse, and observed ground motion and stress‐drop levels remain fully consistent with elastic dislocation theory. In addition, finite‐element modeling of normal faulting replicates observed surface deformation without invoking a collapsing wedge. The Graviquake model proposes a representation of normal‐faulting mechanics that differs significantly from established models and observations. Gravity does play a role in normal faulting, but the elastic dislocation theory remains the definitive framework of fault mechanics. Reinterpreting the 2016 earthquakes as a cascade of gravitational episodes, based on incorrect data processing and modeling, fails to substantiate the Graviquake hypothesis. Persistence in advocating this model could mislead seismic hazard assessment and undermine our understanding of normal faulting.

Bulletin of the Seismological Society of America

Landslide volume estimation from seismic waveform features using a global catalog of seismogenic events

Seismic waves generated by large, rapid landslides encode information about the source and can be analyzed rapidly following an event. Even remote landslides can pose hazards to downstream communities, so rapid detection and characterization using existing seismic monitoring networks could be beneficial. In this study, we expand on past regionally limited work by presenting a globally applicable method for estimating landslide volume from seismic features that could be integrated into future landslide seismic monitoring frameworks. We train the model using multivariable linear regression and five seismic features derived from recordings of 129 landslide events of a range of styles and locations with independently estimated volumes. We present two preferred models, one that combines long‐period (LP) and high‐frequency (HF) features and one for use on smaller landslides without observed long‐period signals. We find that our best‐performing model, applicable to landslides larger than 100,000 m 3 with signals containing observable long‐period energy, requires only two features: LP (20–100 s) absolute maximum amplitude and HF (1–5 Hz) rise time (time between the signal start and the maximum envelope amplitude) and has an R 2 score of 0.79. This model predicted volumes within one order of magnitude for 55 out of 58 events. We find that this combination mitigates the trade‐off between mass and acceleration and other variations of landslide style that limit methods based on amplitude alone.

Seismological Research Letters