On the need for a national (US) research program to elucidate the potential risks to human health and the environment posed by contaminants of emerging concern
No abstract available.
Environmental Science & Technology↗
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Landscape pattern metrics and regional assessment
The combination of remote imagery data, geographic information systems software, and landscape ecology theory provides a unique basis for monitoring and assessing large-scale ecological systems. The unique feature of the work has been the need to develop and interpret quantitative measures of spatial pattern-the landscape indices. This article reviews what is known about the statistical properties of these pattern metrics and suggests some additional metrics based on island biogeography, percolation theory, hierarchy theory, and economic geography. Assessment applications of this approach have required interpreting the pattern metrics in terms of specific environmental endpoints, such as wildlife and water quality, and research into how to represent synergystic effects of many overlapping sources of stress.
Ecosystem Health↗
Reproductive health of bass in the potomac, USA, drainage: Part 1. exploring the effects of proximity to wastewater treatment plant discharge
Intersex (specifically, testicular oocytes) has been observed in male smallmouth bass (SMB; Micropterus dolomieu ) and other centrarchids in the South Branch of the Potomac River, USA, and forks of the Shenandoah River, USA, during the past five years. This condition often is associated with exposure to estrogenic endocrine‐disrupting chemicals in some fish species, but such chemicals and their sources have yet to be identified in the Potomac. In an attempt to better understand the plausible causes of this condition, we investigated the reproductive health of bass sampled up‐ and downstream of wastewater treatment plant (WWTP) effluent point sources on the Potomac River in Maryland, USA. Smallmouth bass were sampled from the Conococheague Creek and the Monocacy River, and largemouth bass (LMB; Micropterus salmoides ) were collected near the Blue Plains WWTP on the mainstem of the Potomac River. Chemical analyses of compounds captured in passive samplers at these locations also were conducted. A high prevalence of intersex (82–100%) was identified in male SMB at all sites regardless of collection area. A lower prevalence of intersex (23%) was identified in male LMB collected at the Blue Plains site. When up‐ and downstream fish were compared, significant differences were noted only in fish from the Conococheague. Differences included condition factor, gonadosomatic index, plasma vitellogenin concentration, and estrogen to testosterone ratio. In general, chemicals associated with waste‐water effluent, storm‐water runoff, and agriculture were more prevalent at the downstream sampling sites. An exception was atrazine and its associated metabolites, which were present in greater concentrations at the upstream sites. It appears that proximity to effluent from WWTPs may influence the reproductive health of bass in the Potomac watershed, but inputs from other sources likely contribute to the widespread, high incidence of testicular oocytes.
Environmental Toxicology and Chemistry↗
The importance of U.S. Geological Survey water-quality super gages
Super gages are an important tool providing real-time, continuous water-quality data at streamgages or groundwater wells. They are designed to address specific water-resource threats such as water-related human health issues including harmful algal blooms, floods, droughts, and hazardous substance spills. In addition, super gages improve our understanding of the effects land-use practices have on critical water resources. Super gage data allow the development of surrogates, a continuous in-stream sensor measurement used to estimate something of greater interest to environmental managers, to be modeled and reported in near real-time concentrations and loads. This fact sheet presents some of the ways water-quality data from a USGS super gage network benefits all of us.
Fact Sheet↗
Updates to the Madison Lake (Minnesota) CE–QUAL–W2 water-quality model for assessing algal community dynamics
A previously developed CE–QUAL–W2 model for Madison Lake, Minnesota, simulated the algal community dynamics, water quality, and fish habitat suitability of Madison Lake under recent (2014) meteorological conditions. Additionally, this previously developed model simulated the complex interplay between external nutrient loading, internal nutrient loading from sediment release of phosphorus, and the organic matter decomposition of the algal biomass. However, the partitioning of Cyanophyta within the modeling framework was simplified to one group and did not account for how different Cyanophyta populations are affected by light conditions, use of nitrogen, temperature growth ranges, and differences in settling rates. Properly capturing Cyanophyta dynamics is important given the potential risks posed by potential large algal blooms. For example, when Cyanophyta form large blooms, recreational activities can become restricted in certain areas because of thick algal scums or algal mats, in addition to the possible production of a class of toxins, known as cyanotoxins, capable of threatening human health, domestic animals, and wildlife. Therefore, we updated the model to partition the Cyanophyta into a group that fixed nitrogen and a second, more buoyant Cyanophyta group that did not independently fix nitrogen. The U.S. Geological Survey, in cooperation with the St. Croix Watershed Research Station (Science Museum of Minnesota) with support from the Environmental and Natural Resources Trust Fund of Minnesota (Legislative-Citizen Commission on Minnesota Resources), updated the Madison Lake CE–QUAL–W2 model to address the shortcomings of simulating Cyanophyta in the previously developed model and better characterize Cyanophyta into two groups. In addition to updating the Cyanophyta group differentiation, the part of the model that handles the simulation of algal community dynamics was updated while preserving model predictive capabilities for nutrients, water temperature, and dissolved oxygen. The calibration and validation of the model was done under recent meteorological conditions with large and persistent Cyanophyta blooms (2014 and 2016). Overall, the model simulations predicted the persistently large total phosphorus concentrations in the hypolimnion of Madison Lake and key differences in nutrient concentrations between 2014 and 2016. The Cyanophyta bloom persistence throughout the summer was also simulated by the model in 2014 and 2016, a critical goal of the model update. Finally, monthly total phosphorus budgets were calculated for the updated Madison Lake model for 2014 and 2016.
Minnesota↗
Water quality of the lower Columbia River Basin: Analysis of current and historical water-quality data through 1994
The lower Columbia River Basin includes the river basins draining into the Columbia River below Bonneville Dam—the largest of which is the Willamette River. This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Lower Columbia River Bi-State Water- Quality Program, to describe the water-quality conditions in the lower Columbia River Basin by interpreting historical data collected and data collected in 1994. Historical water-quality data spanning more than 50 years and comprising more than 200 parameters were collated for interpretation in this report. The U.S. Geological Survey, the Oregon Department of Environmental Quality, and the Washington Department of Ecology collected water-quality data at 10 sites in the lower Columbia River Basin from January to December of 1994. Water-quality constituents measured in 1994 were screened against U.S. Environmental Protection Agency (EPA) and State guidelines. Arsenic, a human carcinogen, was detected in 15 of 16 samples in the lower Columbia River, but was not detected in any of the sampled tributaries. All 15 arsenic detections had concentrations that exceeded both the EPA ambient water-quality criteria for the protection of human health and the EPA human-health advisories for drinking water. Chromium was detected at all four Columbia River sites—most frequently in the Columbia River at Hayden Island. None of the chromium concentrations detected, however, exceeded water-quality criteria or guidelines. Measurements of suspended trace-element concentrations (trace-element concentrations associated with the suspended-sediment fraction) showed that the suspended form is the dominant transport phase for aluminum, iron, and manganese, whereas the dissolved form is the dominant transport phase for arsenic, barium, chromium, and copper. On the basis of tributary loads during summer low-flow months, sources of suspended silver, nickel, aluminum, and antimony exist in the lower Columbia River Basin, whereas the sources of suspended zinc and arsenic exist outside of the lower basin. Twenty organic compounds were detected of the 47 compounds analyzed for this study. None of the organic compounds measured exceeded EPA’s ambient water-quality criteria or drinking-water guidelines. The Willamette River at Portland had the largest number of detections, and all 20 compounds were detected at one time or another at that site. The largest concentrations of the agricultural pesticides, atrazine, metolachlor, and simazine were detected in the Willamette River, where they were detected in 93, 86, 93 percent, respectively, of the samples collected. The highest concentrations of atrazine in the Willamette River were associated with the spring application and fall runoff periods. Both historical and current data showed that the highest water temperatures in the lower Columbia River Basin are present during August. For water years 1977–81 in the Columbia River at Bradwood (river mile 38.9), 75 percent of the daily mean water temperatures during August exceeded 20 degrees Celsius, a “special condition” criterion for the State of Washington. The special condition criterion was exceeded at four sites on the lower Columbia River during July and August, 1994—a period coinciding with season-high air temperatures and low streamflow. Trend tests using data from 1974 to 1994 showed significant (r < 0.05) upward trends for water temperature at the Columbia River at Warrendale and the Willamette River at Portland. Concentrations of dissolved oxygen and total dissolved gas were above saturation levels during high stormflows in the lower Columbia River and the Willamette River during 1994. The high concentrations of total dissolved gas in the Columbia River exceeded Oregon and Washington State standards of 110 percent of saturation and were caused by spilling water at the Columbia River dams. Aquatic life in the lower Columbia River Basin was not subjected to low dissolved-oxygen concentrations. Comparison of dissolved-oxygen concentrations in the Willamette River from 1949–58 to 1972–94 showed a significant increase in dissolved-oxygen concentrations during the low-streamflow months of summer. Trend tests showed significant (r < 0.05) downward trends from 1973 to 1994 for three constituents at the Columbia River at Warrendale: phosphorus in unfiltered water, total dissolved solids, and specific conductance. These trends may be a consequence of more conservative agricultural practices in the area upstream from Warrendale.
Oregon↗
Reconnaissance of the chemical quality of surface waters of the Neches River basin, Texas
The kinds and quantities of minerals dissolved in the surface water of the Neches River basin result from such environmental factors as geology, streamflow patterns and characteristics, and industrial influences. As a result of high rainfall in the basin, much of the readily soluble material has been leached from the surface rocks and soils. Consequently, the water in the streams is usually low in concentrations of dissolved minerals and meets the U.S. Public Health Service drinking-water standards. In most streams the concentration of dissolved solids is less than 250 ppm (parts per million). The Neches River drains an area of about 10,000 square miles in eastern Texas. From its source in southeast Van Zandt County the river flows in a general southeasterly direction and empties into Sabine Lake, an arm of the Gulf of Mexico. In the basin the climate ranges from moist subhumid to humid, and the average annual rainfall ranges from 46 inches is the northwest to more than 52 inches in the southeast. Annual runoff from the basin has averaged 11 inches; however, runoff rates vary widely from year to year. The yearly mean discharge of the Neches River at Evadale has ranged from 994 to 12,720 cubic feet per second. The rocks exposed in the Neches River basin are of the Quaternary and Tertiary Systems and range in age from Eocene to Recent. Throughout most of the basin the geologic formations dip generally south and southeast toward the gulf coast. The rate of dip is greater than that of the land surface; and as a result, the older formations crop out to the north of the younger formations. Water from the outcrop areas of the Wilcox Group and from the older formations of the Claiborne Group generally has dissolved-solids concentrations ranging from 100 to 250 ppm; water from the younger formations has concentrations less than 100 ppm. The northern half of the basin has soft water, with less than 60 ppm hardness. The southern half of .the basin has very soft water, usually with less than 30 ppm hardness. The chloride concentrations are less than 20 ppm in surface water in the southern half of the basin and usually range from 20 to 100 ppm in the northern half of the basin. Concentrations greater than 100 ppm are found only where pollution is occurring. The Neches River basin has an abundance of surface water, but uneven distribution of runoff makes storage projects necessary to provide dependable water supplies. The principal existing reservoirs, with the exception of Striker Creek Reservoir, contain water of excellent quality. Chemical-quality data for the Striker Creek drainage area indicate that its streams are affected by .the disposal of brines associated with oil production. Sam Rayburn Reservoir began impounding water in 1965. The water impounded should prove of acceptable quality for most uses, but municipal and industrial wastes released into the Angelina River near Lufkin may have a degrading effect on the quality of the water, especially during extended periods of low flows. Water available for storage at the many potential reservoir sites will be of good quality; but, if the proposed salt-water barrier is to impound acceptable water, the disposal of oilfield brine into Pine Island Bayou should be discontinued.
Water Supply Paper↗
The US EPA’s National Nutrient Inventory: Critical shifts in US nutrient pollution sources from 1987 to 2017
Efforts to constrain the negative environmental impacts of excess nitrogen (N) and phosphorus (P) are costly and challenging, due in part to inconsistent reporting of nutrient sources at temporal and spatial scales relevant for local decision making. To meet this challenge, the U.S. Environmental Protection Agency’s National Nutrient Inventory provides estimates of major agricultural, urban, atmospheric, and natural nutrient fluxes for the contiguous United States at county and HUC12 scales annually from 1987 (from 1950 for agriculture) to 2017. Since the late 1980s, total N emissions and atmospheric N deposition have declined 22% and 15%, respectively, despite increased agricultural emissions. Over the same period, municipal wastewater N and P loads remained largely stable, despite population increases, through wastewater treatment upgrades and the phaseout of phosphorus-containing detergents. Improved agricultural efficiency allowed for dramatic increases in agricultural production and crop harvest since 1987 (∼25% for N and P), with little change in surplus nutrients left on fields. Overall, a combination of innovative technologies and management has stemmed or even decreased major sources of nutrient pollution to the environment over the last several decades, representing an important shift that, if continued, may contribute to improved air, land, and water quality and human health.
contiguous United States↗
Metal accumulation varies with life history, size, and development of larval amphibians
Amphibian larvae are commonly used as indicators of aquatic ecosystem health because they are susceptible to contaminants. However, there is limited information on how species characteristics and trophic position influence contaminant loads in larval amphibians. Importantly, there remains a need to understand whether grazers (frogs and toads [anurans]) and predators (salamanders) provide comparable information on contaminant accumulation or if they are each indicative of unique environmental processes and risks. To better understand the role of trophic position in contaminant accumulation, we analyzed composite tissues for 10 metals from larvae of multiple co-occurring anuran and salamander species from 20 wetlands across the United States. We examined how metal concentrations varied with body size (anurans and salamanders) and developmental stage (anurans) and how the digestive tract (gut) influenced observed metal concentrations. Across all wetlands, metal concentrations were greater in anurans than salamanders for all metals tested except mercury (Hg), selenium (Se), and zinc (Zn). Concentrations of individual metals in anurans decreased with increasing weight and developmental stage. In salamanders, metal concentrations were less correlated with weight, indicating diet played a role in contaminant accumulation. Based on batches of similarly sized whole-body larvae compared to larvae with their digestive tracts removed, our results indicated that tissue type strongly affected perceived concentrations, especially for anurans (gut represented an estimated 46–97% of all metals except Se and Zn). This suggests the reliability of results based on whole-body sampling could be biased by metal, larval size, and development. Overall, our data shows that metal concentrations differs between anurans and salamanders, which suggests that metal accumulation is unique to feeding behavior and potentially trophic position. To truly characterize exposure risk in wetlands, species of different life histories, sizes and developmental stages should be included in biomonitoring efforts.
Environmental Pollution↗
Use of DNA markers for investigating sources of bacteria in contaminated ground water: Wooster Township, Wayne County, Ohio
In 2004, a public-health nuisance was declared by the Wayne County Board of Health in the Scenic Heights Drive-Batdorf Road area of Wooster Township, Wayne County, Ohio, because of concerns about the safety of water from local wells. Repeated sampling had detected the presence of fecal-indicator bacteria and elevated nitrate concentrations. In June 2006, the U.S. Geological Survey (USGS), in cooperation with the Ohio Environmental Protection Agency (Ohio EPA), collected and analyzed samples from some of the affected wells to help investigate the possibility of human-origin bacterial contamination. Water samples from 12 wells and 5 home sewage-treatment systems (HSTS) were collected. Bromide concentrations were determined in samples from the 12 wells. Samples from 5 of the 12 wells were analyzed for wastewater compounds. Total coliform, enterococci and Escherichia coli (E. coli) bacteria concentrations were determined for samples from 8 of the 12 wells. In addition, two microbial source-tracking tools that employ DNA markers were used on samples from several wells and a composite sample of water from five septic tanks. The DNA markers from the Enterococcus faecium species and the order Bacteroidales are associated with specific sources, either human or ruminant sources. Bromide concentrations ranged from 0.04 to 0.18 milligrams per liter (mg/L). No wastewater compounds were detected at concentrations above the reporting limits. Samples from the 12 wells also were collected by Ohio EPA and analyzed for chloride and nitrate. Chloride concentrations ranged from 12.6 to 61.6 mg/L and nitrate concentrations ranged from 2.34 to 11.9 mg/L (as N). Total coliforms and enterococci were detected in samples from 8 wells, at concentrations from 2 to 200 colony-forming units per 100 milliliters (CFU/100 mL) and 0.5 to 17 CFU/100 mL, respectively. E. coli were detected in samples from three of the eight wells, at concentrations of 1 or 2 CFU/100 mL. Tests for the human-specific marker of enterococci, the esp gene, were negative in the seven samples tested, including the composite sample of HSTS water. DNA with the general Bacteroidales marker was detected in samples from four wells, but the tests for both the human- and ruminant-associated markers were negative. The presence of the PCR (polymerase chain reaction) -detectable DNA for the general fecal Bacteroidales marker is indicative of fecal contamination and recently recharged water.
Ohio↗
Prevalence, environmental loading, and molecular characterization of Cryptosporidium and Giardia</i isolates from domestic and wild animals along the Central California Coast
The risk of disease transmission from waterborne protozoa is often dependent on the origin (e.g., domestic animals versus wildlife), overall parasite load in contaminated waterways, and parasite genotype, with infections being linked to runoff or direct deposition of domestic animal and wildlife feces. Fecal samples collected from domestic animals and wildlife along the central California coast were screened to (i) compare the prevalence and associated risk factors for fecal shedding of Cryptosporidium and Giardia species parasites, (ii) evaluate the relative importance of animal host groups that contribute to pathogen loading in coastal ecosystems, and (iii) characterize zoonotic and host-specific genotypes. Overall, 6% of fecal samples tested during 2007 to 2010 were positive for Cryptosporidium oocysts and 15% were positive for Giardia cysts. Animal host group and age class were significantly associated with detection of Cryptosporidium and Giardia parasites in animal feces. Fecal loading analysis revealed that infected beef cattle potentially contribute the greatest parasite load relative to other host groups, followed by wild canids. Beef cattle, however, shed host-specific, minimally zoonotic Cryptosporidium and Giardia duodenalis genotypes, whereas wild canids shed potentially zoonotic genotypes, including G. duodenalis assemblages A and B. Given that the parasite genotypes detected in cattle were not zoonotic, the public health risk posed by protozoan parasite shedding in cattle feces may be lower than that posed by other animals, such as wild canids, that routinely shed zoonotic genotypes.
California↗
Biomarker response and health of polychlorinated biphenyl- and chlordane-contaminated paddlefish from the Ohio River Basin, USA
Fifty paddlefish ( Polyodon spathula ) collected from two sites on the Ohio River and from one site on the Cumberland River, USA, were examined to determine gonad polychlorinated biphenyl (PCB) and chlordane concentrations, amounts of plasma sex steroids (testosterone and estradiol), hepatic microsomal ethoxyresorufin- O -deethylase (EROD) activity, and the presence of immunoreactive cytochrome P450 1A (CYP1A) protein. Percent hatch and liver, spleen, and kidney histology were also determined. Gonad PCB and chlordane concentrations were significantly higher in Ohio River paddlefish than in Cumberland River paddlefish. Gonad PCB and chlordane concentration and gonad percent lipid were correlated in Ohio River paddlefish. Five of 10 Ohio River egg samples exceeded the Food and Drug Administration's action limit for chlordane (0.30 μg/g). Polychlorinated biphenyl congener-specific analysis detected predominantly the tetra-, penta-, and hexachlorobiphenyls in paddlefish testes. Plasma testosterone levels were significantly lower in males collected from the upper Ohio River site than those collected from the lower part of the river. There was no measurable hepatic microsomal EROD activity in any of the 50 paddlefish collected from the three sites. Western blotting analysis confirmed that a rabbit antitrout CYP1A1 IgG antibody did not recognize a CYP1A protein in paddlefish liver microsomes. Percent hatch was not significantly different in eggs collected from the Cumberland (88–96%) and Ohio Rivers (90–95%). Histological analysis of liver, spleen, and kidney detected the presence of hepatic steatosis and hemosiderosis, splenic lymphoid cell depletion, and hyperplasia of interrenal and chromaffin tissues. Immunosuppression, hepatic metabolic disorders, and altered neuroendocrine function may be occurring in Ohio River paddlefish. Results presented here suggest that organochlorine exposure may be jeopardizing the long-term health of Ohio River paddlefish and that additional investigation of contaminant effects on immune system function and hormone levels in paddlefish is warranted.
Alabama, Georgia, Illinois, Indiana, Kentucky, Mar↗
Pesticides in U.S. streams and groundwater
A 10-year study by the U.S. Geological Survey’s (USGS’s) National Water-Quality Assessment (NAWQA) Program provides a national-scale view of pesticide occurrence in streams and groundwater. The 1992-2001 study builds upon a preliminary analysis from NAWQA’s first phase of studies during 1992-1996 (1, 2). Pesticide data available from various studies prior to 1992 did not allow national assessment because of limited and variable geographic coverage (usually focusing on individual states or regions), sparse and inconsistent inclusion of pesticides in use, and variable sampling designs (3-5). The expanded geographic coverage and improved data following 10 years of study (Figure 1) confirm and reinforce previously reported findings and enable more detailed analyses of each topic. This article summarizes selected findings from a comprehensive report (6), with a focus on the nature of pesticide occurrence and potential significance to human health and stream ecosystems. Information on study design and methods as well as additional analysis of geographic patterns and trends in relation to use and management practices are available in the full report (6).
Environmental Science & Technology↗
The social, economic, and environmental importance of inland fish and fisheries
Though reported capture fisheries are dominated by marine production, inland fish and fisheries make substantial contributions to meeting the challenges faced by individuals, society, and the environment in a changing global landscape. Inland capture fisheries and aquaculture contribute over 40% to the world’s reported finfish production from less than 0.01% of the total volume of water on earth. These fisheries provide food for billions and livelihoods for millions of people worldwide. Herein, using supporting evidence from the literature, we review 10 reasons why inland fish and fisheries are important to the individual (food security, economic security, empowerment), to society (cultural services, recreational services, human health and well-being, knowledge transfer and capacity building), and to the environment (ecosystem function and biodiversity, as aquatic “canaries”, the “green food” movement). However, the current limitations to valuing the services provided by inland fish and fisheries make comparison with other water resource users extremely difficult. This list can serve to demonstrate the importance of inland fish and fisheries, a necessary first step to better incorporating them into agriculture, land-use, and water resource planning, where they are currently often underappreciated or ignored.
Environmental Reviews↗
Ecotoxicology of organochlorine chemicals in birds of the Great Lakes
Silent Spring was fulfilled in the United States with passage of environmental legislation such as the Clean Water Act, the Federal Insecticide, Fungicide, and Rodenticide Act, and the Toxic Substance Control Act in the 1970s. Carson's writings, television interviews, and testimony before Congress alerted a nation and the world to the unintended effects of persistent, bioaccumulative chemicals on populations of fish, wildlife, and possibly humans. Her writings in the popular press brought attention to scientific findings that declines in populations of a variety of birds were directly linked to the widespread use of dichlorodiphenyltrichloroethane (DDT) in agriculture, public health, and horticulture. By the 1970s, DDT and other persistent organic pollutants (POPs) were being banned or phased out, and the intent of these regulatory acts became apparent in a number of locations across the United States, including the Great Lakes. Concentrations of DDT and its major product of transformation, dichlorodiphenylchloroethane (DDE), were decreasing in top predators, such as bald eagles (Haliaeetus leucocephalus), osprey (Pandion haliaetus), colonial waterbirds, and other fish-eating wildlife. Eggshell thinning and the associated mortality of bird embryos caused by DDE had decreased in the Great Lakes and elsewhere by the early 1980s.
Environmental Toxicology and Chemistry↗
Environmental contaminants in blood, hair, and tissues of ocelots from the Lower Rio Grande Valley, Texas, 1986-1997
The ocelot (Felis pardalis) is an endangered neotropical cat distributed within a small range in the Lower Rio Grande Valley (LRGV), in Texas, U.S.A. Studies of the impacts of environmental contaminants in wild cats are few. Approximately one fourth of the estimated population (about 100) of ocelots in the LRGV was sampled to evaluate the impacts of chlorinated pesticides, polychlorinated biphenyls, and trace elements on the population. Hair was collected from 32 ocelots trapped between 1986-1992, and blood was collected from 20 ocelots trapped between 1993-1997. A few blood samples were obtained from individuals recaptured two or three times. Tissue samples from 4 road-killed ocelots were also analyzed. DDE, PCBs, and Hg were some of the most common contaminants detected in hair and blood. Mean Hg levels in hair ranged from 0.5 to 1.25 ??g g-1 dw, Se from 1.5 to 3.48 ??g g-1 dw, and Pb from 0.56 to 26.8 ??g g-1 dw. Mean DDE concentrations in plasma ranged from 0.005 ??g g-1 ww to 0.153 ??g g-1 ww, and PCBs ranged from 0.006 ??g g-1 ww to 0.092 ??g g-1 ww. Mean Hg levels in red blood cells ranged from 0.056 ??g g-1 dw to 0.25 ??g g-1 dw. Concentrations of DDE, PCBs, or Hg, did not increase significantly with age, although the highest concentrations of DDE and Hg were found in older animals. Overall, concentrations of DDE, PCBs, and Hg were low and at levels that currently do not pose any threat to health or survival of the ocelot. This is further supported by good reproduction of the ocelot in the LRGV, where adult females averaged about 1.5 kittens/litter. Thus, it seems that the current major threat to recovery of the ocelot in the LRGV may be habitat loss, although potential impacts of new generation pesticides, such as organophosphorus and carbamate insecticides need further study.The ocelot (Felis pardalis) is an endangered neotropical cat distributed within a small range in the Lower Rio Grande Valley (LRGV), in Texas, U.S.A. Studies of the impacts of environmental contaminants in wild cats are few. Approximately one fourth of the estimated population (about 100) of ocelots in the LRGV was sampled to evaluate the impacts of chlorinated pesticides, polychlorinated biphenyls, and trace elements on the population. Hair was collected from 32 ocelots trapped between 1986-1992, and blood was collected from 20 ocelots trapped between 1993-1997. A few blood samples were obtained from individuals recaptured two or three times. Tissue samples from 4 road-killed ocelots were also analyzed. DDE, PCBs, and Hg were some of the most common contaminants detected in hair and blood. Mean Hg levels in hair ranged from 0.5 to 1.25 ??g g-1 dw, Se from 1.5 to 3.48 ??g g-1 dw, and Pb from 0.56 to 26.8 ??g g-1 dw. Mean DDE concentrations in plasma ranged from 0.005 ??g g-1 ww to 0.153 ??g g-1 ww, and PCBs ranged from 0.006 ??g g-1 ww to 0.092 ??g g-1 ww. Mean Hg levels in red blood cells ranged from 0.056 ??g g-1 dw to 0.25 ??g g-1 dw. Concentrations of DDE, PCBs, or Hg, did not increase significantly with age, although the highest concentrations of DDE and Hg were found in older animals. Overall, concentrations of DDE, PCBs, and Hg were low and at levels that currently do not pose any threat to health or survival of the ocelot. This is further supported by good reproduction of the ocelot in the LRGV, where adult females averaged about 1.5 kittens/litter. Thus, it seems that the current major threat to recovery of the ocelot in the LRGV may be habitat loss, although potential impacts of new generation pesticides, such as organophosphorus and carbamate insecticides need further study.The impacts of PCBs, trace elements, and chlorinated pesticides on the endangered ocelot population in the Lower Rio Grande Valley, TX, was studied. Hair was sampled from 32 animals trapped during 1986-92 and blood was collected from 20 ocelots trapped during 1993-97. Mean mercury, selenium, and lead levels in hair were in the 0.5-1.25, 1.5-3.48, and 0.56-26.8 ??g/g
Environmental Monitoring and Assessment↗
Predicting recreational water quality advisories: A comparison of statistical methods
Epidemiological studies indicate that fecal indicator bacteria (FIB) in beach water are associated with illnesses among people having contact with the water. In order to mitigate public health impacts, many beaches are posted with an advisory when the concentration of FIB exceeds a beach action value. The most commonly used method of measuring FIB concentration takes 18–24 h before returning a result. In order to avoid the 24 h lag, it has become common to ”nowcast” the FIB concentration using statistical regressions on environmental surrogate variables. Most commonly, nowcast models are estimated using ordinary least squares regression, but other regression methods from the statistical and machine learning literature are sometimes used. This study compares 14 regression methods across 7 Wisconsin beaches to identify which consistently produces the most accurate predictions. A random forest model is identified as the most accurate, followed by multiple regression fit using the adaptive LASSO.
Environmental Modelling and Software↗
Bioactive contaminants of emerging concern in National Park waters of the northern Colorado Plateau, USA
Pharmaceuticals and personal care products (PPCPs), wastewater indicators (WWIs), and pesticides (herein, Contaminants of Emerging Concern [CECs]) have been documented in surface waters throughout the world and have associated risks to aquatic life. While much research has focused on temperate and urbanized watersheds, less is known about CEC presence in semi-arid landscapes, where water availability is limited and populations are low. CEC presence in water and sediment is reported for 21 sites in eight U.S. national parks in the northern Colorado Plateau region. From 2012 to 2016, at least one PPCP and/or WWI was detected at most sites on over half of sampling visits, indicating that CECs are not uncommon even in isolated areas. CEC detections were generally fewer and at lower concentrations than in urbanized or agricultural watersheds. Consistent with studies from other U.S. regions, the most frequently detected CECs in this study include DEET, caffeine, organophosphorus flame retardants, and bisphenol A in water and fecal indicators and polycyclic aromatic hydrocarbons in sediment. Maximum concentrations in this study were generally below available water quality benchmarks, sediment quality guidelines, and risk assessment thresholds associated with vertebrates. Additional work is needed to assess the potential activity of hormones, which had high reporting limits in our study, and potential bioactivity of environmental concentrations for invertebrates, microbial communities, and algae. Potential sources of CEC contamination include upstream wastewater effluent discharges and National Park Service invasive-plant-control herbicide applications. CEC occurrence patterns and similarities between continuous and isolated flow locations suggest that direct contamination from individual visitors may also occur. While our data indicate there is little aquatic health risk associated with CECs at our sites, our results demonstrate the ubiquity of CECs on the landscape and a continued need for public outreach concerning resource-use ethics and the potential effects of upstream development.
Colorado Plateau↗