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Estimated ultimate recovery (EUR) Prediction for Eagle Ford Shale using integrated datasets and artificial neural networks

The estimated ultimate recovery (EUR) is an important parameter for forecasting oil and gas production and informing decisions regarding field development strategies. In this study, we combined site-specific geologic, completion, and operational parameters with the predictive capabilities of machine learning (ML) models to predict EURs of the wells for the Eagle Ford Marl Continuous Oil Assessment Unit. We developed an extensive dataset of wells that have produced from the lower and upper Eagle Ford Shale intervals and reduced the model complexity using principal component analysis. We tested the ML models and estimated the sensitivities of ML-predicted EURs to changes in the values of different input variables. The results of applying the optimized ML model to the Eagle Ford suggest that the approach developed in this study could be promising. The ML estimates of the EURs fit the DCA-based values with an R 2 ~ 0.9 and a mean absolute error of ~36 × 10 3 bbl. In the lower Eagle Ford Shale, the EUR estimates were found to be most sensitive to changes in porosity, net thickness of the interval, clay volume, and the API gravity of the oil; and that in the upper Eagle Ford Shale they were most sensitive to changes in the total organic carbon and water saturation, which suggests that it could be important to consider these parameters in assessing these intervals or close analogs.

Louisiana, Mississippi, Texas

PFAS remediation in a bioelectrochemical system inoculated with the west branch consortium (WBC-2)

Groundwater contamination by per - and polyfluoroalkyl substances (PFAS) poses a persistent environmental and public health concern. This study evaluates a two-chambered bioelectrochemical system (BES) inoculated with the West Branch Consortium (WBC-2) for PFAS remediation. Under an applied cathodic potential of −450 mV (versus Ag/AgCl), the BES with active WBC-2 achieved >99.0% perfluorooctanesulfonic acid (PFOS) removal within 21 days in deionized water with culture medium and > 98.9% removal of PFOS, perfluorooctanoic acid (PFOA), perfluorohexanoic acid (PFHxA), and perfluorohexanesulfonic acid (PFHxS) in contaminated groundwater after 102 days. Intermediate formation (e.g., PFOA, 6:2 fluorotelomer sulfonate (6:2 FTS), perfluoropropionic acid (PFPrA), perfluorobutanoic acid (PFBA)) and background-corrected fluoride release were consistent with PFOS transformation under anaerobic reducing conditions potentially involving defluorination. Following repeated PFOS spikes (100 μg/L on Days 0, 50, and 399), PFOA, PFPrA, and PFBA accumulated over 664 days. Despite being the dominant accumulated compound, PFOA accounted for <1.8% of the total spiked PFOS mass. Minimal PFOS transformation occurred in controls without active WBC-2, highlighting the importance of microbial metabolism. Biofilm analysis revealed dense colonization of rod-shaped bacteria on carbon fiber brushes. Enrichment of Bacillus , Agrobacterium , and other low-abundance taxa suggests selective adaptation to BES and PFAS conditions. These findings highlight BES driven by electrochemically stimulated microbial activity as a promising strategy for PFAS remediation.

Journal of Water Process Engineering

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper

Deformation mechanisms in quartz veins and shear zones elucidate the origin of gold mineralization at Pogo, Alaska

Pogo is a quartz vein hosted, ca. 8 Moz gold deposit. Although it has similarities to orogenic and magmatic-hydrothermal deposits, its origin remains enigmatic. Observations from surface exposures, underground workings, and drill core provide new constraints on quartz vein origins with implications for mineralization. Abundant, largely barren metamorphic segregation quartz veins are found throughout interior Alaska and share characteristics with mineralized quartz veins at Pogo. Pogo quartz veins show crystal plastic deformation fabrics consistent with greenschist to amphibolite facies metamorphism and a lack of internal shear. In contrast, gold in Pogo quartz veins occurs in brittle microfaults and fractures with sulphides such as arsenopyrite and pyrrhotite. Major and minor cataclastic shear zones also exist at Pogo. Cataclastic shear zones commonly cut the mineralized quartz veins and porphyroclasts are dominated by quartz with the same plastic deformation fabrics found in the major Pogo quartz veins. The porphyroclasts, and the carbonaceous clay-rich matrix they sit in, also contain gold indicating that the shear zones postdate quartz and earliest gold deposition. These observations suggest that competency contrasts between the quartz veins and their phyllosilicate-rich host rocks controlled transient permeability formed by late, preferential brittle deformation events localizing sulphide ± gold deposition.

Alaska

Spatial differences in soil nutrients along a hydrographic gradient on floodplains in Dongting Lake

The spatial heterogeneity of soil nutrients is crucial for the water bird and whole floodplain wetland ecosystem in large lakes, and it is influenced by the dramatic water level changes and sedimentation progress in West Dongting Lake (WDL). Soil samples were collected at various soil depths along the Yuan River and Li River that feed into WDL. The concentrations of soil total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), and soil grain size were tested. The stoichiometric ratios of C, N, P, and the mean value of soil grain size ( Mz ) were calculated. The differences of soil TOC, TN, TP and the stoichiometric ratio at different sites and soil depths were compared. Linear regression was used to explore the relationships of Mz and nutrient concentrations, and relationships between TOC, TN, and TP. Redundancy analysis was used to explore the relationship between soil nutrients, heavy metal concentrations, and plant community diversity. The results showed that the distributions of soil TOC, TN, and TP concentrations differed across regions in west Dongting Lake along the Yuan and Li Rivers. Total organic carbon concentration differed at different sedimentation depths. Soil grain size showed negative effect with soil TOC, TN, and TP concentrations in this region. Plant community diversity correlated positively with soil TOC and negatively with Hg. West Dongting Lake was N limited despite the high wet deposition of N. It could potentially be attributed to the insufficient presence of aerobic environments for microbes during intermittent flooding of the floodplain, coupled with feeble mineralization. This study can provide valuable insights for the conservation of water bird habitats and wetland ecosystems.

West Dongting Lake

Rainfall thresholds for postfire debris-flow initiation vary with short-duration rainfall climatology

The size, frequency, and geographic scope of severe wildfires are expanding across the globe, including in the Western United States. Recently burned steeplands have an increased likelihood of debris flows, which pose hazards to downstream communities. The conditions for postfire debris-flow initiation are commonly expressed as rainfall intensity-duration thresholds, which can be estimated given sufficient observational history. However, the spread of wildfire across diverse climates poses a challenge for accurate threshold prediction in areas with limited observations. Studies of mass-movement processes in unburned areas indicate that thresholds vary with local climate, such that higher rainfall rates are required for initiation in climates characterized by frequent intense rainfall. Here, we use three independent methods to test whether initiation of postfire runoff-generated debris flows across the Western United States varies similarly with climate. Through the compilation of observed thresholds at various fires, analysis of the spatial density of observed debris flows, and quantification of feature importance at different spatial scales, we show that postfire debris-flow initiation thresholds vary systematically with short-duration rainfall-intensity climatology. The predictive power of climatological data sets that are readily available before a fire occurs offers a much-needed tool for hazard management in regions that are facing increased wildfire activity, have sparse observational history, and/or have limited resources for field-based hazard assessment. Furthermore, if the observed variation in thresholds reflects long-term adjustment of the landscape to local climate, rapid shifts in rainfall intensity related to climate change will likely induce spatially variable shifts in postfire debris-flow likelihood.

Arizona, California, Colorado, Nevada, New Mexico,

Cursed? Why one does not simply add new data sets to supervised geothermal machine learning models

Recent advances in machine learning (ML) identifying areas favorable to hydrothermal systems indicate that the resolution of feature data remains a subject of necessary improvement before ML can reliably produce better models. Herein, we consider the value of adding new features or replacing other, low-value features with new input features in existing ML pipelines. Our previous work identified stress and seismicity as having less value than the other feature types (i.e., heat flow, distance to faults, and distance to magmatic activity) for the 2008 USGS hydrothermal energy assessment; hence, a fundamental question regards if the addition of new but partially correlated features will improve resulting models for hydrothermal favorability. Therefore, we add new maps for shear strain rate and dilation strain rate to fit logistic regression and XGBoost models, resulting in new 7-feature models that are compared to the old 5-feature models. Because these new features share a degree of correlation with the original relatively uninformative stress and seismicity features, we also consider replacement of the two lower-value features with the two new features, creating new 5-feature models. Adding the new features improves the predictive skill of the new 7-feature model over that of the old 5-feature model; albeit, that improvement is not statistically significant because the new features are correlated with the old features and, consequently, the new features do not present considerable new information. However, the new 5-feature XGBoost model has a statistically significant increase in predictive skill for known positives over the old 5-feature model at p = 0.06. This improved performance is due to the lower-dimensional feature space of the former than that of the latter. In higher-dimensional feature space, relationships between features and the presence or absence of hydrothermal systems are harder to discern (i.e., the 7-feature model likely suffers from the “curse of dimensionality”).

Geothermal Resources Council Transactions

Recycling radiogenic osmium by crustal foundering in subduction zones: Evidence from pyroxenite xenoliths in the north Andean arc

Removal of mafic-ultramafic lower crust (e.g., via delamination) is fundamental to making andesitic continental crust, yet direct evidence of this process remains elusive. A unique suite of garnet clinopyroxenite and hornblendite (arclogite) xenoliths from the northern volcanic zone of the Andes, erupted to the surface in the mid-Pleistocene, have bulk-rock geochemistry and osmium (Os) isotopic compositions that demonstrate their crustal affinity, yet have equilibration pressures and temperatures below the arc Mohorovičić discontinuity (~53 km) and some as deep as within the sub-arc mantle wedge (~105 km). Garnet websterites from the same xenolith suite, sourced from depths approaching the Wadati-Benioff zone (~140 km), have elemental and isotopic compositions indicative of a mantle origin, likely formed as products of peridotite-liquid reactions above the subducting slab. Variability in bulk-rock 143 Nd/ 144 Nd values and garnet oxygen isotope ratios ( 𝛿 18 O) for these samples is attributed to minor assimilation of subducted components and/or older crustal material, but assimilation alone cannot account for the highly radiogenic Os isotopic compositions. These results provide direct petrologic evidence for modern arclogite formation and foundering in the Andean orogen, the archetypal active continental subduction system. Elevated 187 Os/ 188 Os values of Mercaderes arclogites imply that recycling of gravitationally unstable arc cumulates during continental crust formation introduces highly radiogenic Os into the convective mantle, which has implications for mass fluxes across the crust-mantle boundary as well as the sources and evolution of mantle heterogeneity as seen in orogenic peridotite massifs and in the sources of oceanic basalts

Earth and Planetary Science Letters

Rare earth elements on the Moon

Rare earth elements (REEs) are a scarce but vital resource for our modern economies and lifestyles. Since the late 1990s, China has supplied the vast majority of the world’s refined REEs. Increasing global demand has broadened the search for REE deposits to unconventional places, including the Moon. Although most lunar rocks have very low REE concentrations, Apollo samples showed that one type of lunar rock containing potassium (K), REEs, and phosphorus (P)—known by the acronym KREEP—has high concentrations of REEs. Data from orbiting satellites have identified locations where substantial deposits of KREEP are likely. The viability of mining these deposits depends on the evolution of REE economics, the development of the Earth-Moon infrastructure, and the findings from future lunar mineral exploration missions.

Fact Sheet

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York

Digitizer Suite: The Albuquerque Seismological Laboratory Digitizer Testing Suite

Laboratory testing of digitizers and seismometers helps ensure that prior to deployment the instrumentation can produce high quality data and is operating within specifications. In this work we detail the software package called: the Albuquerque Seismological Laboratory (ASL) Digitizer Test Suite. This Java software package provides several algorithms to verify various performance parameters of digitizers commonly used for recording analog seismic instruments. The goal of these tests is not to be exhaustive, but to identify common failures that could compromise the integrity of seismic data being recorded on the digitizer. For example, Sandia National Laboratories (e.g., Slad and Merchant, 2018) routinely do comprehensive testing of digitizers for various monitoring missions. While these tests reports are valuable for comprehensively characterizing a recording system, it would be resource intensive to conduct such tests on every seismic recorder used in a network. We focus on tests that include ways to estimate the sensitivity, timing, self-noise, and clip-level of the digitizer, as well as the fidelity of the signal being recorded. The software is publicly available and provides a way for the community to verify the integrity of a digitizer using a minimum amount of outside equipment.

Seismological Research Letters

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri River near Kansas City, Missouri, August 8–9, 2023

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near 8 bridge crossings of the Missouri River near Kansas City, Missouri, on August 8–9, 2023. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches that extended about 1,550 to 1,640 feet longitudinally and generally extended laterally across the active channel from bank to bank during low floodflow to nonflood conditions. These surveys provided the channel geometry and hydraulic conditions of the river at the time of the surveys and provided characteristics of scour holes, which may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. The data collected from the surveys may also be useful to the Missouri Department of Transportation as a record of low floodflow conditions in regards to the stability and integrity of the bridges with respect to bridge scour. Bathymetric data were collected around every in-channel pier. Scour holes were at most piers where bathymetry could be obtained, except for those piers on banks or surrounded by riprap. All the bridge sites in this study were surveyed and documented in previous studies. The average difference between the bathymetric surfaces ranged from 0.07 to 4.16 feet higher in 2023 than 2019, which indicates overall deposition between the survey dates, as might be expected based purely on streamflow at the time of the survey. However, the average difference between the bathymetric surfaces ranged from 1.44 feet higher to 1.88 feet lower in 2023 than 2015, which indicates a dynamic equilibrium of scour and deposition overall between those surveys, despite the lower flow conditions in 2023. Similarly, the average difference between the bathymetric surfaces ranged from 3.18 feet higher to 5.19 feet lower in 2023 than 2011, which indicates a relative equilibrium between scour and deposition overall, albeit the trend was toward scour as might be expected because of the substantial flood event in 2011. Riprap blankets and alignment to flow had a substantial effect on the size of the scour hole for a given pier. Piers that were partially or fully surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers with no rock or riprap and effectively mitigated the scour holes historically observed at these piers. Several of the structures had piers that were skewed to primary approach flow. At most of the structures, the scour hole was deeper and longer on the side of the pier with impinging flow than the leeward side, with some amount of deposition on the leeward side, as typically observed at piers skewed to approach flow.

Kansas, Missouri

Long‐period ground motions from dynamic rupture simulations of large earthquakes on the creeping Hayward–Calaveras–Rodgers Creek fault system

he Hayward, Calaveras, and Rodgers Creek faults in the San Francisco Bay region of California have a high probability of producing a large earthquake in the next decades. Although these faults creep, the creep is insufficient to keep up with their relatively rapid slip rates on their deepest sections, so they have been storing tectonic strain since their last large earthquakes, with the Hayward’s and Rodgers Creek’s more than 150 yr ago. We do not know what the next large Hayward–Calaveras–Rodgers Creek earthquakes will look like or how strongly they will shake the San Francisco Bay region. Harris et al. (2021) used the 3D dynamic (spontaneous) rupture method to simulate large earthquakes on these creeping faults. In this article, we examine the resulting simulated long‐period ( T > 1 s) ground shaking from 0 to 50 km distance, for earthquakes nucleating on the Hayward fault and earthquakes nucleating on the Rodgers Creek fault. We compare these simulated long‐period ground motions with the Boore et al. (2014) well‐established empirically based ground‐motion model suitable for the slowest material velocity in our 3D velocity structure. We find that the simulated long‐period ground motions from the creeping‐fault earthquake scenarios produce a reasonable agreement with the empirical expectations if frictional cohesion is included only where it is appropriate.

California

Teach me how to pycap: A high-capacity well decision support tool using analytical solutions in Python

Regulatory agencies in humid temperate environments rely on timely evaluations of streamflow depletion and drawdown to protect aquatic ecosystems and existing water users. Numerical models offer detailed insights, but their complexity and time demands often preclude their practical use in rapid decision-making. We present pycap-dss, an open-source Python package that implements a suite of analytical solutions for estimating streamflow depletion and drawdown. The tool supports superposition of multiple wells and time-varying pumping, enabling cumulative impact assessments in situations with multiple wells and streams. The software is modular and extensible, allowing users to interchange solutions or add new analytical methods. A YAML-based configuration supports batch processing of multiple wells, and an optional AnalysisProject class facilitates integration with regulatory workflows. Rigorous unit and regression testing ensures computational reliability, and continuous integration supports ongoing development. We demonstrate deterministic examples of drawdown where multiple solutions are readily compared and streamflow depletion with multiple wells in the Central Sands region of Wisconsin. We also show the value of Monte Carlo analyses of streamflow depletion in the same Central Sands example, leveraging computational efficiency to evaluate the uncertainty of individual and cumulative streamflow depletion calculations from over 200 high-capacity wells.

Wisconsin

Framework for mapping liquefaction hazard–Targeted design ground motions

Liquefaction-induced ground failure poses substantial challenges to geotechnical earthquake engineering design. Current approaches for designing against liquefaction hazards, as specified in most seismic provisions, focus on estimating a liquefaction factor of safety ( 𝐹⁢𝑆𝐿 ) and typically characterize earthquake loading using design parameters based on probabilistic or deterministic ground motion levels. Because 𝐹⁢𝑆𝐿 is estimated deterministically, this basis of design neglects considerable uncertainties for estimating liquefaction triggering and its consequences and results in a lack of liquefaction-specific design criteria, particularly as structural design has advanced toward risk-targeted performance objectives. This study presents a framework for developing liquefaction-targeted design criteria based on a minimum acceptable return period of liquefaction, informed by probabilistic liquefaction hazard analysis (PLHA). PLHA quantifies annualized rates of liquefaction by considering contributions from (1) the full ground-motion probability space, and (2) uncertainties in liquefaction triggering using probabilistic models. PLHA is used in this study to characterize the current, effective return periods of 𝐹⁢𝑆𝐿 ( 𝑇𝑅,𝐹⁢𝑆 ) obtained from conventional liquefaction hazard analysis (CLHA) using uniform-hazard ground motions. 𝑇𝑅,𝐹⁢𝑆 is evaluated in a parametric study of nearly 100 sites throughout the conterminous United States. The results indicate large geographic variations in acceptable liquefaction hazard levels, with implied 𝑇𝑅,𝐹⁢𝑆 ranging between approximately 1,000 to 3,000 years. To address these inconsistencies without the computational demands of full PLHA, a framework is proposed for developing a liquefaction-targeted design peak ground acceleration, 𝑃⁢𝐺⁢𝐴𝐿 , for use in liquefaction models that result in consistent liquefaction design levels across all geographic locations. The mapped 𝑃⁢𝐺⁢𝐴𝐿 is shown to be somewhat sensitive to site-specific properties, and adjustment factors are developed and presented. The proposed 𝑃⁢𝐺⁢𝐴𝐿 mapping procedure produces 𝐹⁢𝑆𝐿 estimates that are consistent with those obtained from full PLHA at a target 𝑇𝑅,𝐹⁢𝑆 , providing a promising roadmap to incorporating PLHA concepts into current liquefaction design methods.

Journal of Geotechnical and Geoenvironmental Engin

Ground magnetic and VLF studies at Midnite uranium mine, Stevens County, Washington

Ground magnetic and E-mode VLF measurements were made at more than 200 stations at the Midnite uranium Mine, Stevens County, Washington. The equipment was found to be light and foolproof, and each set of data was collected in one day, exclusive of surveying and marking the station points. The maps of contoured magnetic and VLF data resembled geologic maps of the area, showing many common features, as well as a few unique features on each map. Each showed some evidence of a small normal fault cutting the region; taken together, the evidence for this fault was judged to be much stronger, so that further structural details were inferred. Because of soil cover and inadequate outcrops, the presence of this fault had hitherto been unsuspected. A target area for further uranium mineralization north of the fault was indicated by this quick, inexpensive geophysical survey. The drilling program which Midnite Mine management had underway at that time had already outlined a mineralized zone in the indicated area.

Washington

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Mineralization processes at Escanaba Trough

Escanaba Trough off northern California is the southernmost and only sediment covered segment of the Gorda Ridge. Hydrothermal mineralization was first discovered in Escanaba Trough in 1985, and subsequent investigations included the delineation of the NESCA (northern Escanaba) and SESCA (southern Escanaba) sections of Escanaba Trough, as well as drilling by Ocean Drilling Program (ODP) Leg 169 in 1996. Preliminary research conducted in the 1980s distinguished two classes of sulfide mineral assemblages within the Escanaba Trough: one dominated by pyrrhotite (Fe 1-x S) and one containing ‘mixed sulfides’ including chalcopyrite (CuFeS 2 ) and sphalerite (ZnS). In 2022, we conducted a research expedition to the Escanaba Trough to more thoroughly characterize mineralization processes and consider preservation of precipitated minerals throughout hydrothermally active and inactive sections of Escanaba Trough, with the specific objective of characterizing the host minerals, and processes of enrichment for specific elements which are currently listed as critical elements and can also be toxic under certain conditions (Sb, As, Ba, Co, Ga, Ge, Te). The following will include initial results from that work.

California