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Water-quality and ground-water hydrology of the Columbia/Eagle Bluffs Wetland Complex, Columbia, Missouri— 1992-99

In an effort to restore riverine wetlands along the Missouri River, the Missouri Department of Conservation constructed the 2,700-acre Eagle Bluffs Conservation Area. The primary water source for managing 1,200 wetland acres on the Eagle Bluffs Conservation Area is treated effluent received from a 91-acre constructed wastewater-treatment wetland operated by the city of Columbia, Missouri. The combined areas of the Eagle Bluffs Conservation Area and the wastewater-treatment wetland are termed the Columbia/Eagle Bluffs Wetland Complex. The U.S. Geological Survey, in cooperation with the Missouri Department of Conservation and the city of Columbia, Missouri, collected samples quarterly from August 1992 to March 1999 from a monitoring network that included 33 ground-water sites and 4 surface-water sites to establish a baseline pre-effluent data set and to provide post-effluent data for trend analysis. Changes in major chemical constituent concentrations have been observed at several sampling locations between pre- and post-effluent data. Analysis of post-effluent time-series water-quality data indicates changes occurred in sodium, potassium, calcium, sulfate, and chloride concentrations at 13 sites. These changes can be correlated to the beginning of the operation of the wastewater-treatment wetland. The concentrations of these major chemical constituents plot on the mixing continuum between pre-effluent ground water as one end member and the treated effluent as the other end member. At ground water sites that had changes in concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 11 to more than 100 percent. At ground-water sites, few changes were noted in fecal indicator bacteria, nutrients, trace constituents, total and dissolved organic carbon, and organic constituents. Other than changes in boron concentrations at one ground-water site, these changes could not be directly correlated to the operation of the treatment wetland or the management of the Eagle Bluffs Conservation Area. After the treatment wetland began operation, improvement in the water quality in Perche Creek was observed. With respect to fecal indicator bacteria and nutrient concentrations, the water quality of water discharging from the Eagle Bluffs Conservation Area was improved relative to the water entering the area. Persistent ground-water highs have been observed beneath the Eagle Bluffs Conservation Area and wastewater-treatment unit 1 following the flooding of the wetland areas. These ground-water highs occur during the fall and winter months when ground- and surface-water levels are high and during the spring and summer months when the water levels are lower. The Missouri River stage had a strong effect on the water levels in the aquifer during pre-effluent conditions, but the effect has been lessened by the ground-water high.

Missouri↗

Quality of shallow ground water in areas of recent residential and commercial development, Wichita, Kansas, 2000

Water samples from 30 randomly distributed monitoring wells in areas of recent residential and commercial development (1960–96), Wichita, Kansas, were collected in 2000 as part of the High Plains Regional Ground-Water Study conducted by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The samples were analyzed for about 170 water-quality constituents that included chlorofluorocarbons, physical properties, dissolved solids and major ions, nutrients and dissolved organic carbon, trace elements, pesticide compounds, and volatile organic compounds. The purpose of this report is to provide an assessment of water quality in recharge to shallow ground water underlying areas of recent residential and commercial development and to determine the relation of ground-water quality to overlying urban land use. Analyses of water from the 30 monitoring wells for chlorofluorocarbons were used to estimate apparent dates of recharge. Water from 18 wells with nondegraded and uncontaminated chlorofluorocarbon concentrations had calculated apparent recharge dates that ranged from 1979 to 1990 with an average date of 1986. Water from 14 monitoring wells (47 percent) exceeded the 500-milligrams-per-liter Secondary Maximum Contaminant Level established by the U.S. Environmental Protection Agency for dissolved solids in drinking water. The Secondary Maximum Contaminant Levels of 250 milligrams per liter for chloride and sulfate were exceeded in water from one well. The source of the largest concentrations of dissolved solids and associated ions, such as chloride and sulfate, in shallow ground water in the study area probably is highly mineralized water moving out of the Arkansas River into the adjacent, unconsolidated deposits and mixing with the dominant calcium bicarbonate water in the deposits. Concentrations of most nutrients in water from the sampled wells were small, with the exception of nitrate. Although water from the sampled wells did not have nitrate concentrations larger than the 10-milligram-per-liter Maximum Contaminant Level for drinking water, water from 50 percent of the sampled wells showed nitrate enrichment (concentrations greater than 2.0 milligrams per liter). Most trace elements in water from the sampled wells were detected only in small concentrations, and few exceeded respective water-quality standards. Twenty percent of iron concentrations, 40 percent of manganese concentrations, 3 percent of arsenic concentrations, and 13 percent of uranium concentrations exceeded respective Maximum Contaminant Levels or Secondary Maximum Contaminant Levels. A total of 47 pesticide compounds were analyzed in ground-water samples during this study. Water from 73 percent of the wells sampled had detectable concentrations of one or more of 8 of these 47 compounds. The herbicide atrazine or its degradation product deethylatrazine were detected most frequently (in water from 70 percent of the sampled wells). Metolachlor was detected in water from 10 percent of the wells, and simazine was detected in water from 30 percent of the wells sampled. Other pesticides detected included dieldrin, pendimethalin, prometon, and tebuthiuron (each in water from 3 percent of the wells). All concentrations of these compounds were less than established Maximum Contaminant Levels. A total of 85 volatile organic compounds (VOCs) were analyzed in ground-water samples during this study. Water from 43 percent of the wells had a detectable concentration of one or more VOCs. Chloroform was the most frequently detected VOC (23 percent of the wells sampled).Seven other VOCs were detected in water at frequencies of 13 percent or less in the wells sampled. Concentrations of VOCs were less than respective Maximum Contaminant Levels, except one sample with a concentration of 9.0 micrograms per liter for tetrachloroethylene (Maximum Contaminant Level of 5.0 micrograms per liter). An analysis of hydraulic gradient, flow velocity, and residence time of the ground water indicated potential recharge areas that ranged from 0.8 to 2.8 miles upgradient of monitoring-well locations. Nineteen (63 percent) of these potential recharge areas were in agricultural areas or areas in transition from agricultural to residential and (or) commercial land use at the time water sampled from the monitoring wells was recharged to the shallow ground water. The occurrence of atrazine or deethylatrazine in water from 70 percent of the monitoring wells may indicate a historical agricultural land-use relation. This agricultural relation also may affect concentrations of other water-quality constituents of possible agricultural origin such as nitrate, which generally were in excess of background concentrations in shallow ground water.

Kansas↗

Using water-quality profiles to characterize seasonal water quality and loading in the upper Animas River basin, southwestern Colorado

One of the important types of information needed to characterize water quality in streams affected by historical mining is the seasonal pattern of toxic trace-metal concentrations and loads. Seasonal patterns in water quality are estimated in this report using a technique called water-quality profiling. Water-quality profiling allows land managers and scientists to assess priority areas to be targeted for characterization and(or) remediation by quantifying the timing and magnitude of contaminant occurrence. Streamflow and water-quality data collected at 15 sites in the upper Animas River Basin during water years 1991?99 were used to develop water-quality profiles. Data collected at each sampling site were used to develop ordinary least-squares regression models for streamflow and constituent concentrations. Streamflow was estimated by correlating instantaneous streamflow measured at ungaged sites with continuous streamflow records from streamflow-gaging stations in the subbasin. Water-quality regression models were developed to estimate hardness and dissolved cadmium, copper, and zinc concentrations based on streamflow and seasonal terms. Results from the regression models were used to calculate water-quality profiles for streamflow, constituent concentrations, and loads. Quantification of cadmium, copper, and zinc loads in a stream segment in Mineral Creek (sites M27 to M34) was presented as an example application of water-quality profiling. The application used a method of mass accounting to quantify the portion of metal loading in the segment derived from uncharacterized sources during different seasonal periods. During May, uncharacterized sources contributed nearly 95 percent of the cadmium load, 0 percent of the copper load (or uncharacterized sources also are attenuated), and about 85 percent of the zinc load at M34. During September, uncharacterized sources contributed about 86 percent of the cadmium load, 0 percent of the copper load (or uncharacterized sources also are attenuated), and about 52 percent of the zinc load at M34. Characterized sources accounted for more of the loading gains estimated in the example reach during September, possibly indicating the presence of diffuse inputs during snowmelt runoff. The results indicate that metal sources in the upper Animas River Basin may change substantially with season, regardless of the source.

Colorado↗

SUTRA: A model for 2D or 3D saturated-unsaturated, variable-density ground-water flow with solute or energy transport

SUTRA (Saturated-Unsaturated Transport) is a computer program that simulates fluid movement and the transport of either energy or dissolved substances in a subsurface environment. This upgraded version of SUTRA adds the capability for three-dimensional simulation to the former code (Voss, 1984), which allowed only two-dimensional simulation. The code employs a two- or three-dimensional finite-element and finite-difference method to approximate the governing equations that describe the two interdependent processes that are simulated: 1) fluid density-dependent saturated or unsaturated ground-water flow; and 2) either (a) transport of a solute in the ground water, in which the solute may be subject to: equilibrium adsorption on the porous matrix, and both first-order and zero-order production or decay; or (b) transport of thermal energy in the ground water and solid matrix of the aquifer. SUTRA may also be used to simulate simpler subsets of the above processes. A flow-direction-dependent dispersion process for anisotropic media is also provided by the code and is introduced in this report. As the primary calculated result, SUTRA provides fluid pressures and either solute concentrations or temperatures, as they vary with time, everywhere in the simulated subsurface system. SUTRA flow simulation may be employed for two-dimensional (2D) areal, cross sectional and three-dimensional (3D) modeling of saturated ground-water flow systems, and for cross sectional and 3D modeling of unsaturated zone flow. Solute-transport simulation using SUTRA may be employed to model natural or man-induced chemical-species transport including processes of solute sorption, production, and decay. For example, it may be applied to analyze ground-water contaminant transport problems and aquifer restoration designs. In addition, solute-transport simulation with SUTRA may be used for modeling of variable-density leachate movement, and for cross sectional modeling of saltwater intrusion in aquifers at near-well or regional scales, with either dispersed or relatively sharp transition zones between freshwater and saltwater. SUTRA energy-transport simulation may be employed to model thermal regimes in aquifers, subsurface heat conduction, aquifer thermal-energy storage systems, geothermal reservoirs, thermal pollution of aquifers, and natural hydrogeologic convection systems. Mesh construction, which is quite flexible for arbitrary geometries, employs quadrilateral finite elements in 2D Cartesian or radial-cylindrical coordinate systems, and hexahedral finite elements in 3D systems. 3D meshes are currently restricted to be logically rectangular; in other words, they are similar to deformable finite-difference-style grids. Permeabilities may be anisotropic and may vary in both direction and magnitude throughout the system, as may most other aquifer and fluid properties. Boundary conditions, sources and sinks may be time dependent. A number of input data checks are made to verify the input data set. An option is available for storing intermediate results and restarting a simulation at the intermediate time. Output options include fluid velocities, fluid mass and solute mass or energy budgets, and time-varying observations at points in the system. Both the mathematical basis for SUTRA and the program structure are highly general, and are modularized to allow for straightforward addition of new methods or processes to the simulation. The FORTRAN-90 coding stresses clarity and modularity rather than efficiency, providing easy access for later modifications.

Water-Resources Investigations Report↗

Estimated water-level declines in the Santa Fe Group aquifer system in the Albuquerque area, central New Mexico, predevelopment to 2002

In the Albuquerque metropolitan area of central New Mexico, residential water-supply requirements have historically been met almost exclusively by ground-water withdrawal from the Santa Fe Group aquifer system. The rapid population growth of the metropolitan area from about 262,200 residents in 1960 (Karen D. Thompson, U.S. Census Bureau, written commun., 2002) to about 712,700 residents in 2000 (U.S. Census Bureau, 2001) has resulted in a large increase in the number of municipal-supply wells operated in the region and the total quantity of water they withdraw per year. The largest municipal supplier is the City of Albuquerque, which delivered about 35.8 billion gallons of water to approximately 450,000 people during 1997 (files of the City of Albuquerque) and operates more than 90 municipal-supply wells. Other nearby important suppliers include the City of Rio Rancho and the Town of Bernalillo. The large quantity of ground-water withdrawal in the Albuquerque metropolitan area relative to ground-water recharge has resulted in water-level declines in the Santa Fe Group aquifer system across much of the region. Analysis of the magnitude of and patterns in water-level declines can improve understanding of how the ground-water system responds to withdrawals and how the system might be managed in the future to minimize water-level declines and operating costs of water suppliers.

Water-Resources Investigations Report↗

Simulation of ground-water flow and evaluation of water-management alternatives in the upper Charles River basin, eastern Massachusetts

Ground water is the primary source of drinking water for towns in the upper Charles River Basin, an area of 105 square miles in eastern Massachusetts that is undergoing rapid growth. The stratified-glacial aquifers in the basin are high yield, but also are thin, discontinuous, and in close hydraulic connection with streams, ponds, and wetlands. Water withdrawals averaged 10.1 million gallons per day in 1989?98 and are likely to increase in response to rapid growth. These withdrawals deplete streamflow and lower pond levels. A study was conducted to develop tools for evaluating water-management alternatives at the regional scale in the basin. Geologic and hydrologic data were compiled and collected to characterize the ground- and surface-water systems. Numerical flow modeling techniques were applied to evaluate the effects of increased withdrawals and altered recharge on ground-water levels, pond levels, and stream base flow. Simulation-optimization methods also were applied to test their efficacy for management of multiple water-supply and water-resource needs. Steady-state and transient ground-water-flow models were developed using the numerical modeling code MODFLOW-2000. The models were calibrated to 1989?98 average annual conditions of water withdrawals, water levels, and stream base flow. Model recharge rates were varied spatially, by land use, surficial geology, and septic-tank return flow. Recharge was changed during model calibration by means of parameter-estimation techniques to better match the estimated average annual base flow; area-weighted rates averaged 22.5 inches per year for the basin. Water withdrawals accounted for about 7 percent of total simulated flows through the stream-aquifer system and were about equal in magnitude to model-calculated rates of ground-water evapotranspiration from wetlands and ponds in aquifer areas. Water withdrawals as percentages of total flow varied spatially and temporally within an average year; maximum values were 12 to 13 percent of total annual flow in some subbasins and of total monthly flow throughout the basin in summer and early fall. Water-management alternatives were evaluated by simulating hypothetical scenarios of increased withdrawals and altered recharge for average 1989?98 conditions with the flow models. Increased withdrawals to maximum State-permitted levels would result in withdrawals of about 15 million gallons per day, or about 50 percent more than current withdrawals. Model-calculated effects of these increased withdrawals included reductions in stream base flow that were greatest (as a percentage of total flow) in late summer and early fall. These reductions ranged from less than 5 percent to more than 60 percent of model-calculated 1989?98 base flow along reaches of the Charles River and major tributaries during low-flow periods. Reductions in base flow generally were comparable to upstream increases in withdrawals, but were slightly less than upstream withdrawals in areas where septic-system return flow was simulated. Increased withdrawals also increased the proportion of wastewater in the Charles River downstream of treatment facilities. The wastewater component increased downstream from a treatment facility in Milford from 80 percent of September base flow under 1989?98 conditions to 90 percent of base flow, and from 18 to 27 percent of September base flow downstream of a treatment facility in Medway. In another set of hypothetical scenarios, additional recharge equal to the transfer of water out of a typical subbasin by sewers was found to increase model-calculated base flows by about 12 percent of model-calculated base flows. Addition of recharge equal to that available from artificial recharge of residential rooftop runoff had smaller effects, augmenting simulated September base flow by about 3 percent. Simulation-optimization methods were applied to an area near Populatic Pond and the confluence of the Mill and Charles Rivers in Franklin,

Massachusetts↗

Ground displacements caused by aquifer-system water-level variations observed using interferometric synthetic aperture radar near Albuquerque, New Mexico

Six synthetic aperture radar (SAR) images were processed to form five unwrapped interferometric (InSAR) images of the greater metropolitan area in the Albuquerque Basin. Most interference patterns in the images were caused by range displacements resulting from changes in land-surface elevation. Loci of land- surface elevation changes correlate with changes in aquifer-system water levels and largely result from the elastic response of the aquifer-system skeletal material to changes in pore-fluid pressure. The magnitude of the observed land-surface subsidence and rebound suggests that aquifer-system deformation resulting from ground-water withdrawals in the Albuquerque area has probably remained in the elastic (recoverable) range from July 1993 through September 1999. Evidence of inelastic (permanent) land subsidence in the Rio Rancho area exists, but its relation to compaction of the aquifer system is inconclusive because of insufficient water-level data. Patterns of elastic deformation in both Albuquerque and Rio Rancho suggest that intrabasin faults impede ground- water-pressure diffusion at seasonal time scales and that these faults are probably important in controlling patterns of regional ground-water flow.

Water-Resources Investigations Report↗

Classification of irrigated land using satellite imagery, the High Plains aquifer, nominal date 1992

Satellite imagery from the Landsat Thematic Mapper (nominal date 1992) was used to classify and map the location of irrigated land across the High Plains aquifer. The High Plains aquifer underlies 174,000 square miles in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. The U.S. Geological Survey is conducting a waterquality study of the High Plains aquifer as part of the National Water-Quality Assessment Program. To help interpret data and select sites for the study, it is helpful to know the location of irrigated land within the study area. To date, the only information available for the entire area is 20 years old. To update the data on irrigated land, 40 summer and 40 spring images (nominal date 1992) were acquired from the National Land Cover Data set and processed using a band-ratio method (Landsat Thematic Mapper band 4 divided by band 3) to enhance the vegetation signatures. The study area was divided into nine subregions with similar environmental characteristics, and a band-ratio threshold was selected from imagery in each subregion that differentiated the cutoff between irrigated and nonirrigated land. The classified images for each subregion were mosaicked to produce an irrigated land map for the study area. The total amount of irrigated land classified from the 1992 imagery was 13.1 million acres, or about 12 percent of the total land in the High Plains. This estimate is approximately 1.5 percent greater than the amount of irrigated land reported in the 1992 Census of Agriculture (12.8 millions acres). This information was also compared to a similar data set based on 1980 imagery. The 1980 data classified 13.7 million acres as irrigated. Although the change in the amount of irrigated land between the two times was not substantial, the location of the irrigated land did shift from areas where there were large ground-water-level declines to other areas where ground-water levels were static or rising.

Water-Resources Investigations Report↗

Chemistry and age of ground water in the southwestern Hueco Bolson, New Mexico and Texas

This report, prepared in cooperation with El Paso Water Utilities, presents the results of an investigation to determine the chemistry and age of ground water on the southwestern side of the Hueco Bolson. The radioactive isotope carbon-14 was used to estimate the length of time that water from wells has been isolated from the atmosphere, which is the modern carbon-14 reservoir. Nine wells on the southwestern side of the Hueco Bolson were sampled for analysis of common constituents, nutrients, total organic carbon, trace elements, stable isotopes, and radioactive isotopes. Dissolved-solids concentrations in water from the wells sampled ranged from 269 to 2,630 milligrams per liter. Sodium concentrations generally increased linearly with chloride concentrations, possibly indicating mixing of dilute recharge water with sodium chloride brine. Concentrations of nutrients and trace elements generally were small. The deuterium and oxygen-18 composition in all samples except those from wells adjacent to the Rio Grande indicates that infiltration of precipitation is the main source of water to these wells and that evaporation has not affected the isotopic composition of the water. The source of water from wells adjacent to the Rio Grande is probably not the same source as the water from wells adjacent to the Franklin Mountains. The calculated apparent carbon-14 ages ranged from 12,100 to 25,500 years.

Water-Resources Investigations Report↗

Flow-frequency characteristics of Vermont streams

The safe and economical design of infrastructure in and near waterways and the effective management of flood-hazard areas require information on streamflow that may not be readily available. This report provides estimates of flow-frequency characteristics for gaged streams in Vermont and describes methods for estimating flow-frequency characteristics for ungaged streams. The flow-frequency characteristics investigated are the magnitude of peak discharges at recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years, and the magnitude of daily-mean discharges exceeded 25, 50, and 75 percent of the time. Peak-flow frequency characteristics for gaged streams were computed following the guidelines in Bulletin 17B of the U.S. Interagency Advisory Committee on Water Data. To determine the peak-flow exceedance probabilities at stream-gaging stations in Vermont, a new generalized skew coefficient map for the State was developed. This new map has greater resolution and more current data than the existing National map. The standard error of the new map is 0.269. Two methods of extending streamflow record were applied to improve estimates of peak-flow frequency for streams with short flow records (10 to 15 years) in small drainage areas (sites less than 15 square miles). In the first method, a two-station comparison, data from a long-record site was used to adjust the frequency characteristics at the short-record site. This method was applied to 31 crest-stage gages--stations at which only instantaneous peak discharges are determined--in Vermont. The second method used rainfall-runoff modeling. Precipitation and evapotranspiration data from 1948 to 1999 for numerous climate data-collection sites were used as input to a model to simulate flows at 10 stream-gaging stations in Vermont. Also, methods are described to estimate flow-frequency characteristics for ungaged and unregulated rural streams in Vermont. The peak-flow estimating methods were developed by generalized-least-squares regression procedures with data from 138 U.S. Geological Survey stream-gaging stations in Vermont and in adjacent areas of New York, New Hampshire, Massachusetts, and Quebec. The flow-duration (daily flow exceeded a given percentage of the time) estimating methods were developed by ordinary-least-squares regression procedures with data from 81 stream-gaging stations in Vermont and adjacent states.

Vermont↗

Detection and measurement of land subsidence using global positioning system and Interferometric Synthetic Aperture Radar, Coachella Valley, California, 1998-2000

Land subsidence associated with ground-water-level declines has been recognized as a potential problem in Coachella Valley, California. Since the early 1920s, ground water has been a major source of agricultural, municipal, and domestic supply in the valley. Pumping of ground water resulted in water-level declines as large as 15 meters (50 feet) through the late 1940s. In 1949, the importation of Colorado River water to the lower Coachella Valley began, resulting in a reduction in ground-water pumping and a recovery of water levels during the 1950s through the 1970s. Since the late 1970s, demand for water in the valley has exceeded deliveries of imported surface water, resulting in increased pumping and associated ground-water-level declines and, consequently, an increase in the potential for land subsidence caused by aquifer-system compaction. The location, extent, and magnitude of the vertical land-surface changes in Coachella Valley between 1998 and 2000 were determined using Global Positioning System (GPS) and interferometric synthetic aperture radar (InSAR) methods. GPS measurements made at 15 geodetic monuments in the lower Coachella Valley indicate that -34 to +60 millimeters ± 45 millimeters (-0.11 to +0.20 foot ± 0.15 foot) of vertical change in the land surface occurred during the 2-year period. Changes at three of the monuments exceeded the maximum uncertainty of ± 45 millimeters (± 0.15 foot) at the 95-percent confidence level, which indicates that small amounts of uplift occurred at these monuments between October 1998 and August 2000. Water-level measurements made at wells near the three uplifted monuments during this 2-year period indicate that the water levels fluctuate seasonally; water-level measurements made at these wells in September 1998 and September 2000 indicate that the water levels rose slightly near two monuments and declined slightly near the third. The relation between the seasonally fluctuating, but fairly stable, water levels between September 1998 and September 2000 and the slight uplift at the monuments may indicate that the water levels are fluctuating in the elastic range of stress and that the preconsolidation stress of the aquifer system was not exceeded during the 2-year period. Results of the InSAR measurements made between June 17, 1998, and October 4, 2000, indicate that land subsidence, ranging from about 40 to 80 millimeters (0.13 to 0.26 foot), occurred in three areas of the Coachella Valley; near Palm Desert, Indian Wells, and La Quinta. Measurements made between June 17, 1998, and June 2, 1999, indicate that about 15 millimeters (0.05 foot) occurred southeast of Lake Cahuilla. All the subsiding areas coincide with or are near areas where ground-water levels declined between 1998 and 2000; some water levels in 2000 were at the lowest levels in their recorded histories. The coincident areas of subsidence and declining water levels suggest that aquifer-system compaction may be causing subsidence. If the stresses imposed by the historically lowest water levels exceeded the preconsolidation stress, the aquifer-system compaction and associated land subsidence may be permanent. Although the localized character of the subsidence signals look typical of the type of subsidence characteristically caused by localized pumping, the subsidence also may be related to tectonic activity in the valley.

California↗

Simulation of runoff and recharge and estimation of constituent loads in runoff, Edwards aquifer recharge zone (outcrop) and catchment area, Bexar County, Texas, 1997-2000

The U.S. Geological Survey developed a watershed model (Hydrological Simulation Program—FORTRAN) to simulate runoff and recharge and to estimate constituent loads in surface-water runoff in the Edwards aquifer recharge zone (outcrop) and catchment area in Bexar County, Texas. Rainfall and runoff data collected during 1970–98 from four gaged basins in the outcrop and catchment area were used to calibrate and test the model. The calibration parameters were applied in simulations of the four calibration basins and six ungaged basins that compose the study area to obtain runoff and recharge volumes for 4 years, 1997–2000. In 1997, simulated runoff from the study area was 5.62 inches. Simulated recharge in the study area was 7.85 inches (20 percent of rainfall). In 1998, simulated runoff was 11.05 inches; simulated recharge was 10.99 inches (25 percent of rainfall). In 1999, simulated runoff was 0.66 inch; simulated recharge was 3.03 inches (19 percent of rainfall). In 2000, simulated runoff was 5.29 inches; simulated recharge was 7.19 inches (21 percent of rainfall). During 1997– 2000, direct infiltration of rainfall accounted for about 56 percent of the total Edwards aquifer recharge in Bexar County. Streamflow losses contributed about 37 percent of the recharge; flood impoundment contributed 7 percent. The simulated runoff volumes were used with event-mean-concentration data from basins in the study area and from other Bexar County basins to compute constituent loads and yields for various land uses. Annual loads for suspended solids, dissolved solids, dissolved nitrite plus nitrate nitrogen, and total lead were consistently largest from undeveloped land and smallest from commercial land or transportation corridors. Annual loads and yields varied with rainfall, with the maximum loads produced in the wettest year (1998) and the minimum loads produced in the driest year (1999).

Texas↗

Assessment of stream conditions and trends in biological and water-chemistry data from selected streams in Chester County, Pennsylvania, 1981-97

Biological, chemical, and physical data were collected from a network of 43 sites in Chester County, Pa., from 1981 to 1997. The goal of the network is to assess stream conditions and determine trends in benthic-macroinvertebrate and water-chemistry data. Most sites in the network were assessed as nonimpacted or slightly impacted on the basis of biological metric analysis of benthic-macroinvertebrate data. Sites assessed as impacted were affected by habitat degradation, organic pollution, or toxins. Analysis of calculated biological metrics indicates that most sites were assessed as nonimpacted or slightly impacted between 1981 and 1997. Sites in the Pigeon, French, Pickering, and upper East Branch Brandywine Creek Basins generally were assessed as nonimpacted with stable physical and chemical data through the 17-year period. Sites in the Darby, Crum, Ridley, Valley, and lower East Branch Brandywine Creek Basins are being degraded from the reference conditions, primarily because of habitat alteration. The areas with the poorest stream quality were sites with greater than 50 percent agricultural land use, sites with greater than 10 percent impervious surface, and sites affected by wastewater-treatment plant discharges. These sites are being degraded by erosion, sedimentation, and nutrient enrichment. Trend analysis indicates that calculated biological metrics at most sites improved or remained unchanged between 1981 and 1997. Trend analysis on chemical constituents indicated that concentrations of nitrate and chloride were increasing, and concentrations of phosphorus and ammonia were unchanged or declining across Chester County from 1981 to 1997. The highest concentrations of ammonia and chloride were at locations affected by wastewater-treatment plant discharges. Concentrations of pesticides and other organic compounds in stream-bottom sediments decreased between 1983 and 1997 but these compounds still are present at low concentrations throughout Chester County.

Water-Resources Investigations Report↗

Water and bed-sediment quality in the vicinity of Berlin Lake, Ohio, 2001

Berlin Lake, in northeast Ohio, was created by the U.S. Army Corps of Engineers in 1943 and is used primarily for flood control for the upper reaches of the Mahoning River. The area surrounding and under the lake has been tapped for oil and natural gas production. One of the by-products of oil and gas production is concentrated salt water or brine, which might have an effect on the chemical quality of area potable-water sources. This report presents the results of a U.S. Geological Survey baseline study to collect current (2001) water and sediment-quality data and to characterize water quality in the Berlin Lake watershed. Chloride-to-bromide ratios were used to detect the presence of brine in water samples and to indicate possible adverse effects on water quality. Analyses of ground-water samples from domestic wells in the area indicate a source of chloride and bromide, but defining the source would require more data collection. Analyses of specific conductance and dissolved solids indicate that 78 percent (14 of 18) of the ground-water samples exceeded the Secondary Maximum Contaminant Level for dissolved solids in public water supplies of 500 milligrams per liter (mg/L), compared to 6 percent of samples exceeding 500 mg/L in two nearby studies. Surface water was analyzed twice, once each during low-flow and surface runoff conditions. A comparison of the 2001 data to historical chloride concentrations, accounting for seasonal changes, does not indicate an increase in chloride loads for surface water in the area of Berlin Lake. Polycyclic aromatic hydrocarbons were found in bed-sediment samples collected from the mouths of major tributaries to Berlin Lake. Polycyclic aromatic hydrocarbons are produced during the incomplete combustion of organic carbon materials such as wood and fossil fuels, and they are components of petroleum products.

Water-Resources Investigations Report↗

Ground-water-quality assessment of shallow aquifers in the Front Range Urban Corridor, Colorado, 1954-98

Historical (1954-98) water-quality data for major ions, trace elements, major plant nutrients, and organic constituents collected in 3,870 sampling events at 2,138 shallow wells represent ground-water quality in shallow aquifers that underlie the Front Range Urban Corridor in Colorado. Nonparametric summary statistics and maps of concentrations across the study area indicate that ground water in the study area included fresh to saline water. Sulfate concentrations were elevated in the north and northeast parts of the study area, possibly due to Pierre Shale and Laramie Formation shale outcrops in those areas. Apart from isolated areas of known contamination, chloride concentrations were generally less than 100 milligrams per liter across the study area. Wells with elevated nitrate concentrations usually were located near rivers and streams downgradient from metropolitan areas. Elevated nitrate concentrations in wells that were not along the South Platte River were possibly from individual sewage disposal system usage or from fertilizer application to land. Spatial distribution for organic compounds for which more than 40 percent of the data were above the detection limit (atrazine, methyl-tert-butylether, and prometon) is not widespread across the study area, but this may reflect limitations of data availability. Summary statistics calculated or estimated by decade are influenced by the temporal variability of data across the study area. The median values of specific conductance, chloride, and nitrate from the 1970?s are less than values from the 1980?s and 1990?s, which, because most samples from the l970?s were collected in the western part of the study area, indicates that water quality in the western part of the study area is generally different than the rest of the study area. Chloride may be introduced to ground water from runoff of road deicers or chlorinated organics in transportation/transitional areas, where the median concentration is the greatest (85.0 milligrams per liter). Nitrate median concentrations are several times greater where the land is cultivated or used for agricultural business, which may reflect use of nitrogen fertilizers and the presence of animal feeding operations. Most inorganic and organic constituents exceeded drinking-water standards in only a small percentage of samples. Exceptions to this include sulfate; nitrate; trace elements aluminum, cadmium, iron, and manganese; and organic compounds 1,1-dichloroethylene, tetrachloroethylene, trichloroethylene, benzene, and dichloromethane.

Water-Resources Investigations Report↗

Subsurface evaluation of the west parking lot and landfill 3 areas of Air Force Plant 4, Fort Worth, Texas, using two-dimensional direct-current resistivity profiling

During September 1999, the U.S. Geological Survey made 10 two-dimensional direct-current resistivity profile surveys in the west parking lot and landfill 3 areas of Air Force Plant 4, Fort Worth, Texas, to identify subsurface areas of anomalously high or low resistivity that could indicate potential contamination, contaminant pathways, or anthropogenic structures. Six of the 10 surveys (transects) were in the west parking lot. Each of the inverted sections of these transects had anomalously high resistivities in the terrace alluvium/fill (the surficial subsurface layer) that probably were caused by highly resistive fill material. In addition, each of these transects had anomalously low resistivities in the Walnut Formation (a bedrock layer immediately beneath the alluvium/fill) that could have been caused by saturation of fractures within the Walnut Formation. A high-resistivity anomaly in the central part of the study area probably is associated with pea gravel fill used in construction of a French drain. Another high resistivity anomaly in the west parking lot, slightly southeast of the French drain, could be caused by dense nonaqueous-phase liquid in the Walnut Formation. The inverted sections of the four transects in the landfill 3 area tended to have slightly higher resistivities in both the alluvium/fill and the Walnut Formation than the transects in the west parking lot. The higher resistivities in the alluvium/fill could have been caused by drier conditions in grassy areas relative to conditions in the west parking lot. Higher resistivities in parts of the Walnut Formation also could be a function of drier conditions or variations in the lithology of the Walnut Formation. In addition to the 10 vertical sections, four horizontal sections at 2-meteraltitude intervals show generally increasing resistivity with decreasing altitude that most likely results from the increased influence of the Walnut Formation, which has a higher resistivity than the terrace alluvium/fill.

Texas↗

Simulation of flow and effects of best-management practices in the upper Seco Creek basin, south-central Texas, 1991-98

The Hydrological Simulation Program— FORTRAN model was used to assess the effects of two best-management practices—brush management (removal of woody species locally known as cedar) and weather modification (rainfall enhancement)—on selected hydrologic processes in six subbasins that compose the upper Seco Creek Basin in south-central Texas. A parameter set for use with the model was developed to simulate surface-water-budget components for the six gaged subbasins. Simulation of brush management, represented by decreases in simulated evapotranspiration of 5 to 6 percent, resulted in increases of 1 to 47 percent in annual runoff and increases of 14 to 48 percent in surface runoff for the six subbasins. Simulation of weather modification, represented by a 10-percent increase in rainfall totals and intensities, resulted in increases of 5 to 6 percent in evapotranspiration, increases of 2 to 92 percent in annual runoff, and increases of 36 to 101 percent in surface runoff. Rainfall and runoff data for the study were collected during January 1, 1991–September 30, 1998. Data from 60 storms were used for the simulations. The model was calibrated with data from 33 storms (in two subbasins) and tested with data from 27 storms (in four subbasins). Twenty-one pervious land segments were defined for the study on the basis of geology and land cover. An error analysis and a sensitivity analysis were done on each subbasin, and the results were used to develop the final parameter set.

Texas↗