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Hydrologic and Water-Quality Responses in Shallow Ground Water Receiving Stormwater Runoff and Potential Transport of Contaminants to Lake Tahoe, California and Nevada, 2005-07

Clarity of Lake Tahoe, California and Nevada has been decreasing due to inflows of sediment and nutrients associated with stormwater runoff. Detention basins are considered effective best management practices for mitigation of suspended sediment and nutrients associated with runoff, but effects of infiltrated stormwater on shallow ground water are not known. This report documents 2005-07 hydrogeologic conditions in a shallow aquifer and associated interactions between a stormwater-control system with nearby Lake Tahoe. Selected chemical qualities of stormwater, bottom sediment from a stormwater detention basin, ground water, and nearshore lake and interstitial water are characterized and coupled with results of a three-dimensional, finite-difference, mathematical model to evaluate responses of ground-water flow to stormwater-runoff accumulation in the stormwater-control system. The results of the ground-water flow model indicate mean ground-water discharge of 256 acre feet per year, contributing 27 pounds of phosphorus and 765 pounds of nitrogen to Lake Tahoe within the modeled area. Only 0.24 percent of this volume and nutrient load is attributed to stormwater infiltration from the detention basin. Settling of suspended nutrients and sediment, biological assimilation of dissolved nutrients, and sorption and detention of chemicals of potential concern in bottom sediment are the primary stormwater treatments achieved by the detention basins. Mean concentrations of unfiltered nitrogen and phosphorus in inflow stormwater samples compared to outflow samples show that 55 percent of nitrogen and 47 percent of phosphorus are trapped by the detention basin. Organic carbon, cadmium, copper, lead, mercury, nickel, phosphorus, and zinc in the uppermost 0.2 foot of bottom sediment from the detention basin were all at least twice as concentrated compared to sediment collected from 1.5 feet deeper. Similarly, concentrations of 28 polycyclic aromatic hydrocarbon compounds were all less than laboratory reporting limits in the deeper sediment sample, but 15 compounds were detected in the uppermost 0.2 foot of sediment. Published concentrations determined to affect benthic aquatic life also were exceeded for copper, zinc, benz[a]anthracene, phenanthrene, and pyrene in the shallow sediment sample. Isotopic composition of water (oxygen 18/16 and hydrogen 2/1 ratios) for samples of shallow ground water, lakewater, and interstitial water from Lake Tahoe indicate the lake was well mixed with a slight ground-water signature in samples collected near the lakebed. One interstitial sample from 0.8 foot beneath the lakebed was nearly all ground water and concentrations of nitrogen and phosphorus were comparable to concentrations in shallow ground-water samples. However, ammonium represented 65 percent of filtered nitrogen in this interstitial sample, but only 10 percent of the average nitrogen in ground-water samples. Nitrate was less than reporting limits in interstitial water, compared with mean nitrate concentration of 750 micrograms per liter in ground-water samples, indicating either active dissimilative nitrate reduction to ammonium by micro-organisms or hydrolysis of organic nitrogen to ammonium with concomitant nitrate reduction. The other interstitial sample falls along a mixing line between ground water and lake water and most of the nitrogen was organic nitrogen.

Scientific Investigations Report↗

Late Quaternary deposition in the inner basins of the California continental borderland — Part A. Santa Monica Basin

Radiocarbon dating of sediment core samples from Santa Monica Basin document Holocene (younger than approximately 11 ka) landslides and fault offsets along the basin margin. The new dates include 17 from six piston cores on the continental slope and 11 from Ocean Drilling Program Site 1015 on the basin floor. The dates, which are based on data from pelagic and benthic foraminifera in addition to several dates from mollusk shells, are used to provide chronostratigraphic control for a previously determined basin-wide seismic stratigraphy. The geologic setting at the core sites and a sediment log for each core are shown. In addition, each sediment log is accompanied by a color core photograph as well as P-wave velocity and gamma-ray density profiles. The primary purpose of the report is to make the radiocarbon dates available for other studies in the Santa Monica Basin. A comparison of sediment accumulation rates between the late Pleistocene and Holocene provides insight to the effects of sea-level change on sediment input to the basin. In addition, the results can be used to evaluate the effectiveness of wire-line piston coring in providing age control for earthquake hazard and sedimentologic studies.

California↗

Hydrostratigraphic Framework of the Raton, Vermejo, and Trinidad Aquifers in the Raton Basin, Las Animas County, Colorado

Exploration for and production of coalbed methane has increased substantially in the Rocky Mountain region of the United States since the 1990s. During 1999-2004, annual production of natural gas (coalbed methane) from the Raton Basin in Las Animas County, Colorado, increased from 28,129,515 to 80,224,130 thousand cubic feet, and the annual volume of ground water coproduced by coalbed methane wells increased from about 949 million gallons to about 2,879 million gallons. Better definition of the hydrostratigraphic framework of the Raton, Vermejo, and Trinidad aquifers in the Raton Basin of southern Colorado is needed to evaluate the long-term effects of coalbed methane development on the availability and sustainability of ground-water resources. In 2001, the U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, began a study to evaluate the hydrogeology of the Raton Basin in Huerfano and Las Animas Counties, Colorado. Geostatistical methods were used to map the altitude of and depths to the bottoms and tops (structure) and the apparent thicknesses of the Trinidad Sandstone, the Vermejo Formation, and the Raton Formation in Las Animas County, based on completion reports and drillers' logs from about 1,400 coalbed methane wells in the Raton Basin. There was not enough subsurface control to map the structural surfaces and apparent thicknesses of the aquifers in Huerfano County. Geostatistical methods also were used to map the regional water table in the northern part of Las Animas County, based on reported depth to water from completion reports of water-supply wells. Although these maps were developed to better define the hydrostratigraphic framework, they also can be used to determine the contributing aquifer(s) of existing water wells and to estimate drilling depths of proposed water wells. These maps of the hydrostratigraphic framework could be improved with the addition of measured sections and mapping of geologic contacts at outcrops along the eastern and western margins of the Raton Basin.

Scientific Investigations Report↗

Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-2011

Fish Creek, an approximately 25-kilometer-long tributary to Snake River, is located in Teton County in western Wyoming near the town of Wilson. Fish Creek is an important water body because it is used for irrigation, fishing, and recreation and adds scenic value to the Jackson Hole properties it runs through. Public concern about nuisance growths of aquatic plants in Fish Creek has been increasing since the early 2000s. To address these concerns, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the hydrology, water quality, and biologic communities of Fish Creek during 2007–11. The hydrology of Fish Creek is strongly affected by groundwater contributions from the area known as the Snake River west bank, which lies east of Fish Creek and west of Snake River. Because of this continuous groundwater discharge to the creek, land-use activities in the west bank area can affect the groundwater quality. Evaluation of nitrate isotopes and dissolved-nitrate concentrations in groundwater during the study indicated that nitrate was entering Fish Creek from groundwater, and that the source of nitrate was commonly a septic/sewage effluent or manure source, or multiple sources, potentially including artificial nitrogen fertilizers, natural soil organic matter, and mixtures of sources. Concentrations of dissolved nitrate and orthophosphate, which are key nutrients for growth of aquatic plants, generally were low in Fish Creek and occasionally were less than reporting levels (not detected). One potential reason for the low nutrient concentrations is that nutrients were being consumed by aquatic plant life that increases during the summer growing season, as a result of the seasonal increase in temperature and larger number of daylight hours. Several aspects of Fish Creek’s hydrology contribute to higher productivity and biovolume of aquatic plants in Fish Creek than typically observed in streams of its size in Wyoming. Especially in the winter, the proportionately large, continuous gain of groundwater into Fish Creek in the perennial section keeps most of the creek free of ice. Because sunlight can still reach the streambed in Fish Creek and the water is still flowing, aquatic plants continue to photosynthesize in the winter, albeit at a lower level of productivity. Additionally, the cobble and large gravel substrate in Fish Creek provides excellent attachment points for aquatic plants, and when combined with Fish Creek’s channel stability allows rapid growth of aquatic plants once conditions allow during the spring. The aquatic plant community of Fish Creek was different than most streams in Wyoming in that it contains many different macrophytes—including macroalgae such as long streamers of Cladophora , aquatic vascular plants, and moss; most other streams in the state contain predominantly algae. From the banks of Fish Creek, the bottom of the stream sometimes appeared to be a solid green carpet. A shift was observed from higher amounts of microalgae in April/May to higher amounts macrophytes in August and October, and differences in the relative abundance of microalgae and macrophytes were statistically significant between seasons. Differences in dissolved-nitrate concentrations and in the nitrogen-to-phosphorus ratio were significantly different between seasons, as concentrations of dissolved nitrate decreased from April/May to August and October. It is likely that dissolved-nitrate concentrations in Fish Creek were lower in August and October because macrophytes were quickly utilizing the nutrient, and a negative correlation between macro-phytes and nitrate was found. Macroinvertebrates also were sampled because of their role as indicators of water quality and their documented responses to perturbation such as degradation of water quality and habitat. Statistically significant seasonal differences were noted in the macroinvertebrate community. Taxa richness and relative abundance of Ephemeroptera, Plecoptera, and Trichoptera, which tend to be intolerant of water-quality degradation, decreased from April/May to August; the same time period saw a corresponding increase in Diptera and noninsects, particularly Oligochaeta (worms) that are more tolerant. Seasonal changes in macroinvertebrate functional feeding groups were significantly different. The relative abundance of gatherer-collector and scraper feeding groups decreased from April/May to August, accompanied by an increase in filterer-collector and shredders feeding groups. Seasonal changes in feeding groups might be due to the seasonal shift in aquatic plant communities, as indicated by comparison with other streams in the area that had fewer aquatic macrophytes than Fish Creek. Statistical tests of macroinvertebrate metrics indicated few differences between years or biological sampling sites on Fish Creek, although the site farthest upstream sometimes was different not only in terms of macroinvertebrates but also in streamflow, water quality, and aquatic plants. Potential effects of contributions of additional nutrients to the Fish Creek ecosystem beyond the conditions sampled during the study period are not known. However, because virtually all of the detectable dissolved nitrate commonly was consumed by aquatic plants in August (leaving dissolved nitrate less than the reporting level in water samples), it is possible that increased nutrient contributions could cause increased growth of aquatic plants. Additional long-term monitoring of the stream, with concurrent data analysis and interpretation would be needed to determine the effects of additional nutrients on the aquatic plant community and on higher levels of the food chain.

Wyoming↗

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2011-13

From 2011 to 2013, the U.S. Geological Survey’s Idaho National Laboratory (INL) Project Office, in cooperation with the U.S. Department of Energy, collected depth-discrete measurements of fluid pressure and temperature in 11 boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system (MLMS) consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the INL has been ongoing since 2006 and this report summarizes data collected from 2011 to 2013 in 11 multilevel monitoring wells. Hydraulic head (head) and groundwater temperature data were collected from 11 multilevel monitoring wells, including 177 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. One port (port 3) within borehole USGS 134 was not monitored because of a valve failure. Head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Twenty-two major head inflections were described for 9 of 11 MLMS boreholes and almost always coincided with low‑permeability sediment layers and occasionally thick layers of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within volcanic rift zones and near the southern boundary of the Idaho National Laboratory, indicate mostly convective heat transfer. Select boreholes along the southern boundary show a temperature reversal and cooler water deeper in the aquifer resulting from the vertical movement of groundwater. Vertical head and temperature change were quantified for each of the 11 multilevel monitoring systems. Vertical head gradients defined for the major inflections in the head profiles were as high as 2.9 feet per foot. In general, fractured basalt zones displayed relatively small vertical head differences and show a high occurrence within volcanic rift zones. Poor connectivity between fractures and higher vertical gradients were generally attributed to sediment layers and layers of dense basalt, or both. Groundwater temperatures in all boreholes ranged from 10.8 to 16.3 °C. Normalized mean head values were analyzed for all 11 multilevel monitoring wells for the period of record (2007–13). The mean head values suggest a moderately positive correlation among all boreholes and generally reflect regional fluctuations in water levels in response to seasonal climatic changes. Boreholes within volcanic rift zones and near the southern boundary (USGS 103, USGS 105, USGS 108, USGS 132, USGS 135, USGS 137A) display a temporal correlation that is strongly positive. Boreholes in the Big Lost Trough display some variations in temporal correlations that may result from proximity to the mountain front to the northwest and episodic flow in the Big Lost River drainage system. For example, during June 2012, boreholes MIDDLE 2050A and MIDDLE 2051 showed head buildup within the upper zones when compared to the June 2010 profile event, which correlates to years when surface water was reported for the Big Lost River several months preceding the measurement period. With the exception of borehole USGS 134, temporal correlation between MLMS wells completed within the Big Lost Trough is generally positive. Temporal correlation for borehole USGS 134 shows the least agreement with other MLMS boreholes located within the Big Lost Trough; however, borehole USGS 134 is close to the mountain front where tributary valley subsurface inflow is suspected.

Idaho↗

Evaluating drivers of hydrology, water quality, and benthic macroinvertebrates in streams of Fairfax County, Virginia, 2007–18

In 2007, the U.S. Geological Survey partnered with Fairfax County, Virginia, to establish a long-term water-resources monitoring program to evaluate the hydrology, water quality, and ecology of Fairfax County streams and the watershed-scale effects of management practices. Fairfax County uses a variety of management practices, policies, and programs to protect and restore its water resources, but the effects of such strategies are not well understood. This report used streamflow, water-quality, and ecological monitoring data collected from 20 Fairfax County watersheds from 2007 through 2018 to assess the effects of management practices, landscape factors, and climatic conditions on observed nutrient, sediment, salinity, and benthic-macroinvertebrate community responses. Urbanization, climatic variability, and an increase in management practices occurred within Fairfax County during the study period. Impervious cover, housing units, wastewater infrastructure, and (or) stormwater infrastructure increased in most study watersheds. Climatic conditions varied among study years; countywide estimates of average-annual air temperature differed by about 3 degrees Celsius, and total precipitation ranged from about 34 to 63 inches per year. The effects of the management practices, implemented to reduce nitrogen, phosphorus, and (or) sediment loads, are considered in this study. These management practices primarily consist of stormwater retrofits and stream restorations; however, stream restorations account for most of the financial investment and expected load reductions. Management practices were implemented in half of the study watersheds, and most practices were installed and reductions credited late in the study period. Changes in hydrologic response during storm events were evaluated over the study period because many management practices that were implemented were designed to achieve nutrient and sediment reductions by slowing or intercepting runoff. The average number and length of storm events was mostly unchanged throughout the monitoring network. Four watersheds with 10 years of streamflow data showed a mixture of trends in stormflow peak, volume, and rate-of-change. Event-mean nutrient and sediment concentrations from these watersheds were evaluated during storm events and generally showed increases in total phosphorus (TP) and suspended sediment and reductions or no changes in total nitrogen (TN). Landscape inputs of nitrogen and phosphorus and the percentage of inputs delivered to streams were estimated for the study watersheds. Estimated phosphorus from fertilizer and nitrogen from atmospheric deposition represented large nutrient inputs in most watersheds; amounts of other nonpoint sources varied based on land use. Estimated nitrogen inputs declined throughout Fairfax County and in most study watersheds from 2008 through 2018; in comparison, phosphorus input changes were relatively small. Most nonpoint-nutrient inputs were retained on the landscape and did not reach streams, with slightly more nitrogen retention than phosphorus, on average. Retention rates were lower for years with more precipitation and streamflow. After adjusting for streamflow, TN and TP loads were generally higher for years with more nutrient inputs. Calculated as a function of flow-adjusted loads, TP retention declined at most stations from 2009 through 2018, in comparison, TN retention was relatively unchanged. Landscape and climatic conditions affected spatial differences and changes in Fairfax County stream conditions from 2009 through 2018. TN concentrations were higher and increases over time were larger in watersheds with elevated septic-system density. TP concentrations were higher in watersheds with more turfgrass; concentrations were lower, but had larger increases over time, in watersheds with deeper soils. Suspended-sediment concentrations were higher in watersheds with greater stream densities. Specific conductance was higher in watersheds with more developed land use and shallower soils. Benthic-macroinvertebrate index of biotic integrity (IBI) scores were lower in watersheds with high road density and had larger increases over time in bigger, more developed watersheds. Annual variability in TN and TP concentrations and benthic-macroinvertebrate IBI scores was affected by precipitation; annual variability in suspended sediment concentrations and specific conductance was affected by air temperature. After accounting for influences from landscape and climatic conditions, expected management-practice effects were not consistently observed in monitored stream responses. These effects were assessed by comparing expected management-practice load reductions with the timing, direction, and magnitude of changes in storm-event hydrology, nutrient and sediment loads, median-annual water-quality conditions, and benthic-macroinvertebrate IBI scores. An important consideration for future investigations of management-practice effects is how to control for water-quality and ecological variability caused by geologic properties, the urban environment, precipitation, and (or) air temperature. The interpretation of management-practice effects in this report was likely influenced by a combination of factors, including (1) the amount, timing, and location of management-practice implementation; (2) unmeasured landscape and climatic factors; (3) uncertain management-practice expectations; (4) hydrologic variability; and (5) analytical assumptions. Through continued data-collection efforts, particularly after management practices have been completed, many of these factors may become less influential in the future.

Virginia↗

Simulation of the shallow groundwater-flow system near the Hayward Airport, Sawyer County, Wisconsin

There are concerns that removal and trimming of vegetation during expansion of the Hayward Airport in Sawyer County, Wisconsin, could appreciably change the character of a nearby cold-water stream and its adjacent environs. In cooperation with the Wisconsin Department of Transportation, a two-dimensional, steady-state groundwater-flow model of the shallow groundwater-flow system near the Hayward Airport was refined from a regional model of the area. The parameter-estimation code PEST was used to obtain a best fit of the model to additional field data collected in February 2007 as part of this study. The additional data were collected during an extended period of low runoff and consisted of water levels and streamflows near the Hayward Airport. Refinements to the regional model included one additional hydraulic-conductivity zone for the airport area, and three additional parameters for streambed resistance in a northern tributary to the Namekagon River and in the main stem of the Namekagon River. In the refined Hayward Airport area model, the calibrated hydraulic conductivity was 11.2 feet per day, which is within the 58.2 to 7.9 feet per day range reported for the regional glacial and sandstone aquifer, and is consistent with a silty soil texture for the area. The calibrated refined model had a best fit of 8.6 days for the streambed resistance of the Namekagon River and between 0.6 and 1.6 days for the northern tributary stream. The previously reported regional groundwater-recharge rate of 10.1 inches per year was adjusted during calibration of the refined model in order to match streamflows measured during the period of extended low runoff; this resulted in an optimal groundwater-recharge rate of 7.1 inches per year during this period. The refined model was then used to simulate the capture zone of the northern tributary to the Namekagon River.

Scientific Investigations Report↗

2013 volcanic activity in Alaska: summary of events and response of the Alaska Volcano Observatory

The Alaska Volcano Observatory (AVO) responded to eruptions, volcanic unrest or suspected unrest, and seismic events at 18 volcanic centers in Alaska during 2013. Beginning with the 2013 AVO Summary of Events, the annual description of the AVO seismograph network and activity, once a stand-alone publication, is now part of this report. Because of this change, the annual summary now contains an expanded description of seismic activity at Alaskan volcanoes. Eruptions occurred at three volcanic centers in 2013: Pavlof Volcano in May and June, Mount Veniaminof Volcano in June through December, and Cleveland Volcano throughout the year. None of these three eruptive events resulted in 24-hour staffing at AVO facilities in Anchorage or Fairbanks.

Alaska↗

The South Carolina bridge-scour envelope curves

The U.S. Geological Survey, in cooperation with the South Carolina Department of Transportation, conducted a series of three field investigations to evaluate historical, riverine bridge scour in the Piedmont and Coastal Plain regions of South Carolina. These investigations included data collected at 231 riverine bridges, which lead to the development of bridge-scour envelope curves for clear-water and live-bed components of scour. The application and limitations of the South Carolina bridge-scour envelope curves were documented in four reports, each report addressing selected components of bridge scour. The current investigation (2016) synthesizes the findings of these previous reports into a guidance manual providing an integrated procedure for applying the envelope curves. Additionally, the investigation provides limited verification for selected bridge-scour envelope curves by comparing them to field data collected outside of South Carolina from previously published sources. Although the bridge-scour envelope curves have limitations, they are useful supplementary tools for assessing the potential for scour at riverine bridges in South Carolina.

South Carolina↗

Hydrologic conditions and quality of rainfall and storm runoff for two agricultural areas of the Oso Creek Watershed, Nueces County, Texas, 2005-07

The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board, Coastal Bend Bays and Estuaries Program, and Texas AgriLife Research and Extension Center at Corpus Christi, studied hydrologic conditions and quality of rainfall and storm runoff of two (primarily) agricultural areas (subwatersheds) of the Oso Creek watershed in Nueces County, Texas. One area, the upper West Oso Creek subwatershed, is 5,145 acres. The other area, a subwatershed drained by an unnamed Oso Creek tributary (hereinafter, Oso Creek tributary), is 5,287 acres. Rainfall and runoff (streamflow) were continuously monitored at the outlets of the two subwatersheds during October 2005-September 2007. Fourteen rainfall samples were collected and analyzed for nutrients and major inorganic ions. Nineteen composite runoff samples (10 West Oso Creek, nine Oso Creek tributary) were collected and analyzed for nutrients, major inorganic ions, and pesticides. Twenty-two discrete suspended-sediment samples (10 West Oso Creek, 12 Oso Creek tributary) and 13 bacteria samples (eight West Oso Creek, five Oso Creek tributary) were collected and analyzed. These data were used to estimate, for selected constituents, rainfall deposition to and runoff loads and yields from the study subwatersheds. Quantities of fertilizers and pesticides applied in the subwatersheds were compared with quantities of nutrients and pesticides in rainfall and runoff. For the study period, total rainfall was greater than average. Most of the runoff at both subwatershed outlet sites occurred in response to a few specific storm periods. The West Oso Creek subwatershed produced more runoff during the study period than the Oso Creek tributary subwatershed, 10.83 inches compared with 7.28 inches. Runoff response was quicker and peak flows were higher in the West Oso Creek subwatershed than in the Oso Creek tributary subwatershed. Total nitrogen runoff yield for the 2-year study period averaged 2.61 pounds per acre per year from the West Oso Creek subwatershed and 0.966 pound per acre per year from the Oso Creek tributary subwatershed. Total phosphorus yields from the West Oso Creek and the Oso Creek tributary subwatersheds for the 2-year period were 0.776 and 0.498 pound per acre per year. Runoff yields of nitrogen and phosphorus were relatively small compared to inputs of nitrogen in fertilizer and rainfall deposition. Average annual runoff yield of total nitrogen (subwatersheds combined) represents about 2.4 percent of nitrogen applied as fertilizer and nitrogen entering the subwatersheds through rainfall deposition. Average annual runoff yield of total phosphorus (subwatersheds combined) represents about 4.4 percent of the phosphorus in applied fertilizer and rainfall deposition. Suspended-sediment yields from the West Oso Creek subwatershed were more than twice those from the Oso Creek tributary subwatershed. The average suspended-sediment yield from the West Oso Creek subwatershed was 582 pounds per acre per year. The average suspended-sediment yield from the Oso Creek tributary subwatershed was 257 pounds per acre per year. Twenty-two herbicides and eight insecticides were detected in runoff samples collected from the two subwatershed outlet sites. At the West Oso Creek site, 18 herbicides and four insecticides were detected, and at the Oso Creek tributary site, 17 herbicides and six insecticides. Seventeen pesticides were detected in only one sample at low concentrations (near the laboratory reporting level). Atrazine, atrazine degradation byproducts 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT) and 2-hydroxy-4-isopropylamino-6-ethylamino-s-triazine (OIET), glyphosate, and glyphosate byproduct aminomethylphosphonic acid (AMPA) were detected in all samples. Of all pesticides detected in runoff, the highest runoff yields were for glyphosate, 0.013 pound per acre per year for the West Oso Creek subwatershed and 0.001 pound per acre per year for the Oso Creek t

Scientific Investigations Report↗

Hydrogeologic Framework of Bedrock Units and Initial Salinity Distribution for a Simulation of Groundwater Flow for the Lake Michigan Basin

The U.S. Geological Survey is assessing groundwater availability in the Lake Michigan Basin. As part of the assessment, a variable-density groundwater-flow model is being developed to simulate the effects of groundwater use on water availability throughout the basin. The hydrogeologic framework for the Lake Michigan Basin model was developed by grouping the bedrock geology of the study area into hydrogeologic units on the basis of the functioning of each unit as an aquifer or confining layer within the basin. Available data were evaluated based on the areal extent of coverage within the study area, and procedures were established to characterize areas with sparse data coverage. Top and bottom altitudes for each hydrogeologic unit were interpolated in a geographic information system for input to the model and compared with existing maps of subsurface formations. Fourteen bedrock hydrogeologic units, making up 17 bedrock model layers, were defined, and they range in age from the Jurassic Period red beds of central Michigan to the Cambrian Period Mount Simon Sandstone. Information on groundwater salinity in the Lake Michigan Basin was compiled to create an input dataset for the variable-density groundwater-flow simulation. Data presented in this report are referred to as 'salinity data' and are reported in terms of total dissolved solids. Salinity data were not available for each hydrogeologic unit. Available datasets were assigned to a hydrogeologic unit, entered into a spatial database, and data quality was visually evaluated. A geographic information system was used to interpolate salinity distributions for each hydrogeologic unit with available data. Hydrogeologic units with no available data either were set equal to neighboring units or were vertically interpolated by use of values from units above and below.

Scientific Investigations Report↗

DayCent-Chem simulations of ecological and biogeochemical processes of eight mountain ecosystems in the United States

Atmospheric deposition of nitrogen (N) and sulfur (S) cause complex responses in ecosystems, from fertilization to forest ecosystem decline, freshwater eutrophication to acidification, loss of soil base cations, and alterations of disturbance regimes. DayCent-Chem, an ecosystem simulation model that combines ecosystem nutrient cycling and plant dynamics with aqueous geochemical equilibrium calculations, was developed to address ecosystem responses to combined atmospheric N and S deposition. It is unique among geochemically-based models in its dynamic biological cycling of N and its daily timestep for investigating ecosystem and surface water chemical response to episodic events. The model was applied to eight mountainous watersheds in the United States. The sites represent a gradient of N deposition across locales, from relatively pristine to N-saturated, and a variety of ecosystem types and climates. Overall, the model performed best in predicting stream chemistry for snowmelt-dominated sites. It was more difficult to predict daily stream chemistry for watersheds with deep soils, high amounts of atmospheric deposition, and a large degree of spatial heterogeneity. DayCent-Chem did well in representing plant and soil carbon and nitrogen pools and fluxes. Modeled stream nitrate (NO 3 - ) and ammonium (NH 4 + ) concentrations compared well with measurements at all sites, with few exceptions. Simulated daily stream sulfate (SO 4 2- ) concentrations compared well to measured values for sites where SO 4 2- deposition has been low and where SO 4 2- adsorption/desorption reactions did not seem to be important. The concentrations of base cations and silica in streams are highly dependent on the geochemistry and weathering rates of minerals in each catchment, yet these were rarely, if ever, known. Thus, DayCent-Chem could not accurately predict weathering products for some catchments. Additionally, few data were available for exchangeable soil cations or the magnitude of base cation deposition as a result of dry and fog inputs. The uncertainties related to weathering reactions, deposition, soil cation exchange capacity, and groundwater contributions influenced how well the simulated acid neutralizing capacity (ANC) and pH estimates compared to observed values. Daily discharge was well represented by the model for most sites. The chapters of this report describe the parameterization for each site and summarize model results for ecosystem variables, stream discharge, and stream chemistry. This intersite comparison exercise provided insight about important and possibly not well understood processes.

Scientific Investigations Report↗

Water-quality assessment and macroinvertebrate data for the Upper Yampa River watershed, Colorado, 1975 through 2009

A study was initiated in 2009 by the U.S. Geological Survey (USGS), in cooperation with Routt County, the Colorado Water Conservation Board, and the City of Steamboat Springs, to compile and analyze historic water-quality data and assess water-quality conditions in the Upper Yampa River watershed (UYRW) in northwestern Colorado. Water-quality data for samples collected by federal, state, and local agencies for various periods from 1975 through 2009 were compiled and assessed for streams, lakes, reservoirs, and groundwater in the UYRW, including the Elkhead Creek subwatershed and the Yampa River watershed that is upstream from Elkhead Creek. For selected physical-property and chemical-constituent data for samples collected from surface-water sites and groundwater wells in the UYRW, this report: (1) characterizes available data through statistical summaries, (2) analyzes the spatial and temporal distribution of water-quality conditions, (3) identifies temporal trends in water quality, where possible, (4) provides comparisons to federal and state water-quality standards and recommendations, and (5) identifies factors affecting the quality of water. In addition, the availability and characteristics of macroinvertebrate data collected in the UYRW are described.

Colorado↗

Hydrology of and Current Monitoring Issues for the Chicago Area Waterway System, Northeastern Illinois

The Chicago Area Waterway System (CAWS) consists of a combination of natural and manmade channels that form an interconnected navigable waterway of approximately 90-plus miles in the metropolitan Chicago area of northeastern Illinois. The CAWS serves the area as the primary drainage feature, a waterway transportation corridor, and recreational waterbody. The CAWS was constructed by the Metropolitan Water Reclamation District of Greater Chicago (MWRDGC). Completion of the Chicago Sanitary and Ship Canal (initial portion of the CAWS) in 1900 breached a low drainage divide and resulted in a diversion of water from the Lake Michigan Basin. A U.S. Supreme Court decree (Consent Decree 388 U.S. 426 [1967] Modified 449 U.S. 48 [1980]) limits the annual diversion from Lake Michigan. While the State of Illinois is responsible for the diversion, the MWRDGC regulates and maintains water level and water quality within the CAWS by using several waterway control structures. The operation and control of water levels in the CAWS results in a very complex hydraulic setting characterized by highly unsteady flows. The complexity leads to unique gaging requirements and monitoring issues. This report provides a general discussion of the complex hydraulic setting within the CAWS and quantifies this information with examples of data collected at a range of flow conditions from U.S. Geological Survey streamflow gaging stations and other locations within the CAWS. Monitoring to address longstanding issues of waterway operation, as well as current (2014) emerging issues such as wastewater disinfection and the threat from aquatic invasive species, is included in the discussion.

Illinois↗

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California↗

Water Quality of the Snake River and Five Eastern Tributaries in the Upper Snake River Basin, Grand Teton National Park, Wyoming, 1998-2002

To address water-resource management objectives of the National Park Service in Grand Teton National Park, the U.S. Geological Survey in cooperation with the National Park Service has conducted water-quality sampling in the upper Snake River Basin. Routine sampling of the Snake River was conducted during water years 1998-2002 to monitor the water quality of the Snake River through time. A synoptic study during 2002 was conducted to supplement the routine Snake River sampling and establish baseline water-quality conditions of five of its eastern tributaries?Pilgrim Creek, Pacific Creek, Buffalo Fork, Spread Creek, and Ditch Creek. Samples from the Snake River and the five tributaries were collected at 12 sites and analyzed for field measurements, major ions and dissolved solids, nutrients, selected trace metals, pesticides, and suspended sediment. In addition, the eastern tributaries were sampled for fecal-indicator bacteria by the National Park Service during the synoptic study. Major-ion chemistry of the Snake River varies between an upstream site above Jackson Lake near the northern boundary of Grand Teton National Park and a downstream site near the southern boundary of the Park, in part owing to the inputs from the eastern tributaries. Water type of the Snake River changes from sodium bicarbonate at the upstream site to calcium bicarbonate at the downstream site. The water type of the five eastern tributaries is calcium bicarbonate. Dissolved solids in samples collected from the Snake River were significantly higher at the upstream site (p-value<0.001), where concentrations in 43 samples ranged from 62 to 240 milligrams per liter, compared to the downstream site where concentrations in 33 samples ranged from 77 to 141 milligrams per liter. Major-ion chemistry of Pilgrim Creek, Pacific Creek, Buffalo Fork, Spread Creek, and Ditch Creek generally did not change substantially between the upstream sites near the National Park Service boundary with the National Forest and the downstream sites near the Snake River; however, variations in the major ions and dissolved solids existed between basins. Variations probably result from differences in geology between the tributary basins. Concentrations of dissolved ammonia, nitrite, and nitrate in all samples collected from the Snake River and the five eastern tributaries were less than water-quality criteria for surface waters in Wyoming. Concentrations of total nitrogen and total phosphorus in samples from the Snake River and the tributaries generally were less than median concentrations determined for undeveloped streams in the United States; however, concentrations in some samples did exceed ambient total-nitrogen and total-phosphorus criteria for forested mountain streams in the Middle Rockies ecoregion recommended by the U.S. Environmental Protection Agency to address cultural eutrophication. Sources for the excess nitrogen and phosphorus probably are natural because these basins have little development and cultivation. Concentrations of trace metals and pesticides were low and less than water-quality criteria for surface waters in Wyoming in samples collected from the Snake River and the five eastern tributaries. Atrazine, dieldrin, EPTC, or tebuthiuron were detected in estimated concentrations of 0.003 microgram per liter or less in 5 of 27 samples collected from the Snake River. An estimated concentration of 0.008 microgram per liter of metolachlor was detected in one sample from the Buffalo Fork. The estimated concentrations were less than the reporting levels for the pesticide analytical method. Suspended-sediment concentrations in 43 samples from the upstream site on the Snake River ranged from 1 to 604 milligrams per liter and were similar to suspended-sediment concentrations in 33 samples from the downstream site, which ranged from 1 to 648 milligrams per liter. Suspended-sediment concentrations in 38 samples collected from the tributary streams ranged from 1 t

Scientific Investigations Report↗

Ground-water flow and water quality in the Upper Floridan aquifer, southwestern Albany area, Georgia, 1998-2001

During 1997, the Dougherty County Health Department sampled more than 700 wells completed in the Upper Floridan aquifer in Dougherty County, Georgia, and determined that nitrate as nitrogen (hereinafter called nitrate) concentrations were above 10 milligrams per liter (mg/L) in 12 percent of the wells. Ten mg/L is the Georgia primary drinking-water standard. The ground-water flow system is complex and poorly understood in this predominantly agricultural area. Therefore, the U.S. Geological Survey (USGS) - in cooperation with Albany Water, Gas and Light Commission - conducted a study to better define ground-water flow and water quality in the Upper Florida aquifer in the southwestern Albany area, Georgia. Ground-water levels were measured in the southwestern Albany area, Georgia, during May 1998 and March 1999 (spring), and October 1998 and September 1999 (fall). Groundwater levels measured in 75 wells open only to the Upper Floridan aquifer were used to construct potentiometric-surface maps for those four time periods. These maps show that ground water generally flows from northwest to southeast at gradients ranging from about 2 to greater than 10 feet per mile. During spring and fall 1998, ground-water levels were high and mounding of the potentiometric surface occurred in the central part of the study area, indicating a local recharge area. Water levels declined from December through February, and by March 1999 the mound in the potentiometric surface had dissipated. Of the 75 wells in the potentiometric network, 24 were selected for a water-quality network. These 24 wells and 1 spring were sampled during fall 1998 and spring 1999. Samples were analyzed for major chemical constituents, selected minor constituents, selected nutrients, and chlorofluorocarbons (CFC). Water-quality field measurements - such as water temperature, pH, specific conductance (SC), and dissolved oxygen (DO) - were taken at each well. During August 2000, a ground-water sample was collected and analyzed for selected sewage tracers. During March 2001, water samples from selected wells were analyzed for nitrogen and oxygen isotopes. Age-dating analysis using CFCs yield apparent groundwater ages that range from modern to greater than 50 years. The chemistry of ground water in the Upper Floridan aquifer varies widely throughout the southwestern Albany area, Georgia, and in general represents the chemistry commonly found in recharge areas. From fall 1998 through spring 1999, median values of pH, SC, and DO concentration were 7.6 standard units, 266 microsiemens per centimeter at 25 degrees Celsius (uS/cm), and 5.6 mg/L, respectively. The SC is highest (350 - 400 uS/cm) where mounding of the potentiometric surface exists. Specific DO concentrations indicate an area of anoxic ground water in the north-central part of the study area. Water samples indicate that ground water in the study area is dominated by calcium and bicarbonate ions, which is consistent with the limestone lithology of the aquifer. About 25 percent of the samples contained sodium and chloride at ratios similar to those in rainfall, indicating a close proximity to recharge areas. The remaining water samples, however, had sodiumchloride ratios less than 0.90, the ratio in Tift County, Georgia, rainfall samples. These low sodium-chloride ratios are consistent with chloride enrichment. Minor constituent and nutrient concentrations typically are below laboratory reporting limits; however, the maximum nitrate concentration measured during the study period was 12.2 mg/L, and the median concentration for the study period was 3.0 mg/L. Samples collected during 1999 had a higher median nitrate concentration than the 1998 samples. Regression analysis indicated that nitrate concentrations are related exponentially to chloride concentrations. Four distinct groups of ground-water-quality samples, plus four unique samples, were identified using cluster analysis. Water-quality groups I and

Georgia↗

Estimation of monthly water yields and flows for 1951-2012 for the United States portion of the Great Lakes Basin with AFINCH

Monthly water yields from 105,829 catchments and corresponding flows in 107,691 stream segments were estimated for water years 1951&ndash;2012 in the Great Lakes Basin in the United States. Both sets of estimates were computed by using the Analysis of Flows In Networks of CHannels (AFINCH) application within the NHDPlus geospatial data framework. AFINCH provides an environment to develop constrained regression models to integrate monthly streamflow and water-use data with monthly climatic data and fixed basin characteristics data available within NHDPlus or supplied by the user. For this study, the U.S. Great Lakes Basin was partitioned into seven study areas by grouping selected hydrologic subregions and adjoining cataloguing units. This report documents the regression models and data used to estimate monthly water yields and flows in each study area. Estimates of monthly water yields and flows are presented in a Web-based mapper application. Monthly flow time series for individual stream segments can be retrieved from the Web application and used to approximate monthly flow-duration characteristics and to identify possible trends.

Great Lakes Basin↗