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Determination of Organic and Inorganic Percentages and Mass of Suspended Material at Four Sites in the Illinois River in Northwestern Arkansas and Northeastern Oklahoma, 2005-07

The Illinois River located in northwestern Arkansas and northeastern Oklahoma is influenced by point and nonpoint sources of nutrient enrichment. This has led to increased algal growth within the stream, reducing water clarity. Also, sediment runoff from fields, pastures, construction sites, and other disturbed areas, in addition to frequent streambank failure, has increased sedimentation within the stream and decreased water clarity. A study was conducted by the U.S. Geological Survey in cooperation with the Arkansas Department of Environmental Quality and the U.S. Environmental Protection Agency to characterize the increased turbidity by determining the organic and inorganic composition and mass of suspended material in the Illinois River from August 2005 through July 2007. Water-quality samples were collected at four sites on the Illinois River (listed in downstream order): near Viney Grove, Arkansas; at Savoy, Arkansas; south of Siloam Springs, Arkansas; and near Tahlequah, Oklahoma. In general, turbidity, total suspended solids, suspended-sediment concentration, organic material concentration (measured as volatile suspended solids and ash-free dry mass), and chlorophyll a concentration were the greatest in samples collected from the Illinois River at Savoy and the least in samples from the most upstream Illinois River site (near Viney Grove) and the most downstream site (near Tahlequah) from August 2005 through July 2007. For example, the suspended-sediment concentration at the Illinois River at Savoy had a median of 15 milligrams per liter, and the total suspended solids had a median of 12 milligrams per liter. The Illinois River near Tahlequah had the least suspended-sediment concentration with a median of 10 milligrams per liter and the least total suspended solids with a median of 6 milligrams per liter. The turbidity, total suspended solids, suspended-sediment concentration, organic material concentration, and chlorophyll a concentration in samples collected during high-flow events were greater than in samples collected during base-flow conditions at the Illinois River at Savoy, south of Siloam Springs, and near Tahlequah. For example, the median turbidity for the Illinois River at Savoy was 3 nephelometric turbidity ratio units during base-flow conditions and 52 nephelometric turbidity ratio units during high-flow conditions. Organic material in the Illinois River generally composed between 13 and 47 percent of the total suspended material in samples collected from August 2005 through July 2007. Therefore, most of the suspended material in samples collected from the sites was inorganic material. Overall, the highest percentage of organic material was found at the Illinois River near Viney Grove and at the Illinois River near Tahlequah. The Illinois River south of Siloam Springs had the lowest percentage of organic material among the four sites. In general, the percentage of organic material was greater in samples collected during base-flow conditions compared to samples collected during high-flow conditions. The mean seasonal concentrations and percentages of organic material were the least in the fall (September through November) in samples collected from August 2005 to July 2007 from the four Illinois River sites, while the greatest concentrations and percentages of organic material occurred at various times of the year depending on the site. The greatest concentrations of organic material occurred in the summer (June through August) in samples from sites on the Illinois River near Viney Grove, at Savoy and south of Siloam Springs, but in the spring (March through May) in samples from the Illinois River near Tahlequah. The greatest percentages of organic material (least percentages of inorganic material) occurred in the summer in samples from the site near Viney Grove, the winter and summer at the site at Savoy, in the spring, fall, and winter (December through February) at the site south of Siloam Springs, an

Scientific Investigations Report↗

Potential water-quality effects of coal-bed methane production water discharged along the upper Tongue River, Wyoming and Montana

Water quality in the upper Tongue River from Monarch, Wyoming, downstream to just upstream from the Tongue River Reservoir in Montana potentially could be affected by discharge of coal-bed methane (CBM) production water (hereinafter referred to as CBM discharge). CBM discharge typically contains high concentrations of sodium and other ions that could increase dissolved-solids (salt) concentrations, specific conductance (SC), and sodium-adsorption ratio (SAR) in the river. Increased inputs of sodium and other ions have the potential to alter the river's suitability for agricultural irrigation and aquatic ecosystems. Data from two large tributaries, Goose Creek and Prairie Dog Creek, indicate that these tributaries were large contributors to the increase in SC and SAR in the Tongue River. However, water-quality data were not available for most of the smaller inflows, such as small tributaries, irrigation-return flows, and CBM discharges. Thus, effects of these inflows on the water quality of the Tongue River were not well documented. Effects of these small inflows might be subtle and difficult to determine without more extensive data collection to describe spatial patterns. Therefore, synoptic water-quality sampling trips were conducted in September 2005 and April 2006 to provide a spatially detailed profile of the downstream changes in water quality in this reach of the Tongue River. The purpose of this report is to describe these downstream changes in water quality and to estimate the potential water-quality effects of CBM discharge in the upper Tongue River. Specific conductance of the Tongue River through the study reach increased from 420 to 625 microsiemens per centimeter (.μS/cm; or 49 percent) in the downstream direction in September 2005 and from 373 to 543 .μS/cm (46 percent) in April 2006. Large increases (12 to 24 percent) were measured immediately downstream from Goose Creek and Prairie Dog Creek during both sampling trips. Increases attributed to direct CBM discharges were smaller. In September 2005, the SC of 12 measured CBM discharges ranged from 1,750 to 2,440 .μS/cm, and the combined discharges increased SC in the river by an estimated 4.5 percent. In April 2006, the SC of eight measured CBM discharges ranged from 1,720 to 2,070 μS/cm; the largest of these discharges likely increased SC in the river by 5.8 percent. Estimates of potential effects of the CBM discharges on the SC of the Tongue River near the Tongue River Reservoir were calculated using a two-step process involving linear regression and mass-balance calculations for a range of streamflow and CBM-discharge conditions. Potential effects from CBM discharges are larger increases of SC and SAR at lower flows than at higher flows and relative increases that are substantially smaller for SC than for SAR. For example, if the streamflow was 100 cubic feet per second (ft 3 /s) in the Tongue River near the Tongue River Reservoir and CBM discharge ranged from 1,250 to 5,000 gallons per minute, the projected increases would range from 4.4 to 16 percent for SC and from 39 to 151 percent for SAR. In comparison, if the streamflow was 600 ft 3 /s, the projected increases would range from 2.2 to 8.4 percent for SC and from 21 to 79 percent for SAR. This analysis of potential water-quality effects on the SC and SAR of the Tongue River in the study area assumes that the quantity and quality of water flowing into the study reach at the time of this study was the same as during the period before CBM development (data from water years 1985-99).

Wyoming;Montana↗

Sediment loads in the Red River of the North and selected tributaries near Fargo, North Dakota, 2010--2011

Natural-resource agencies are concerned about possible geomorphic effects of a proposed diversion project to reduce the flood risk in the Fargo-Moorhead metropolitan area. The U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers collected data in the spring of 2010 and 2011, and from June to November 2011, during rainfall-runoff events and base-flow conditions to provide information on sediment transport. The data were used to examine sediment concentrations, loads, and particle-size distributions at nine selected sites in the Red River and its tributaries near the Fargo-Moorhead metropolitan area. Suspended-sediment concentration varied among sites in 2010 and 2011. The least suspended-sediment concentrations were measured at the Red River (site 1) and the Buffalo River (site 9), and the greatest concentrations were measured at the two Sheyenne River sites (sites 3 and 4). Estimated daily suspended-sediment loads were highly variable in 2010 and 2011 in the Red River and its tributaries, with the greatest loads occurring in the spring and the smallest loads occurring in the winter. For the Red River, daily suspended-sediment loads ranged from 26 to 3,500 tons per day at site 1 and from 30 to 9,010 tons per day at site 2. For the Sheyenne River, daily loads ranged from less than 10 to 10,200 tons per day at site 3 and from less than 10 to 4,530 tons per day at site 4. The mean daily load was 191 tons per day in 2010 and 377 tons per day in 2011 for the Maple River, and 610 tons per day in 2011 for the Wild Rice River (annual loads were not computed for 2010). For the three sites that were only sampled in 2011 (sites 7, 8 and 9), the mean daily suspended-sediment loads ranged from 40 tons per day at the Lower Branch Rush River (site 8) to 118 tons per day at the Buffalo River (site 9). For sites that had estimated loads in 2010 and 2011 (sites 1–5), estimated annual (March–November) suspended-sediment loads were greater in 2011 compared to 2010. In 2010, annual loads ranged from 68,650 tons per year at the Maple River (site 5) to 249,040 tons per year at the Sheyenne River (site 3). In 2011, when all nine sites were sampled, annual loads ranged from 8,716 tons per year at the Lower Branch Rush River (site 8) to 552,832 tons per year at the Sheyenne River (site 3). With the exception of the Sheyenne River (site 4), the greatest monthly loads occurred in March for 2010, with as little as 27 percent (site 1) and as much as 42 percent (site 3) of the annual load occurring in March. For 2011, the greatest monthly loads occurred in April, ranging from 33 percent (site 1) to 63 percent (site 7) of the 2011 annual load. A relatively small amount of sediment was transported past the nine sites as bedload in 2010 and 2011. For most of the samples collected at the nine sites, the bedload composed less than 1 percent of the calculated daily total sediment load.

North Dakota↗

Simulation of groundwater flow in the aquifer system of the Anacostia River and surrounding watersheds, Washington, D.C., Maryland, and Virginia

The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, Water Quality Division, is investigating the hydrogeology of the tidal Anacostia River watershed within Washington, D.C., with the goal of improving understanding of the groundwater-flow system and the interaction of groundwater and surface water in the watershed. To help meet this goal, a three-dimensional steady-state groundwater-flow model for the Anacostia River and surrounding watersheds in Washington, D.C., Maryland, and Virginia was constructed. The goal of the modeling study was to quantify the rate and pattern of groundwater flow to the tidal Anacostia River. The model domain includes weathered and unweathered rocks of the Piedmont Physiographic Province and the southeast-dipping sediments of the Atlantic Coastal Plain Physiographic Province. The model includes processes of recharge, evapotranspiration, withdrawals from wells, and base flow to streams, rivers, and tidal waters. Final model calibration was achieved by using the objective parameter estimation and sensitivity analysis capabilities of UCODE_2005. Simulated gradients in the surficial aquifer in the vicinity of the tidal Anacostia River indicate that flow is predominantly toward the river, with changes in the magnitude and direction of the gradients from the northeast, where the Anacostia River enters Washington, D.C., to the southwest, toward the confluence with the tidal Potomac River. Flow paths to the tidal Anacostia River from the north are largely horizontal through the surficial aquifer and Patuxent aquifer. From the south, the flow paths toward the river originate in the elevated topographic areas southeast of the river and pass through the surficial aquifer and Patapsco confining unit, lower Patapsco aquifer/Arundel Clay, and to some extent, the Patuxent aquifer. Groundwater-flow rates to and from the tidal rivers (Potomac and Anacostia) are generally greatest near the land-water boundary, where the gradient in the water table is greatest, and diminish toward the middle of the tidal river channels. The tidal rivers are predominantly areas of groundwater discharge, although there are areas where tidal waters are recharging the subsurface, typically where small variations or depressions in the topography produce small locally reversed gradients in the water table. Substantial recharge of tidal waters to the groundwater system is observed for the tidal Potomac where the upper Patapsco aquifer subcrops south of Washington, D.C. Water budget calculations indicate that inflows to the groundwater system beneath the tidal Anacostia River are predominantly from the land area of Washington, D.C., followed by tidal surface water and flows from lower layers. Outflows are largely to the tidal Anacostia River, with a smaller part going to the land area underlying Washington, D.C.

Delaware, Maryland, Washington D.C.↗

Simulation of the Lower Walker River Basin hydrologic system, west-central Nevada, using PRMS and MODFLOW models

Walker Lake is a terminal lake in west-central Nevada with almost all outflow occurring through evaporation. Diversions from Walker River since the early 1900s have contributed to a substantial reduction in flow entering Walker Lake. As a result, the lake is receding, and salt concentrations have increased to a level in which Oncorhynchus clarkii henshawi (Lahontan Cutthroat trout) are no longer present, and the lake ecosystem is threatened. Consequently, there is a concerted effort to restore the Walker Lake ecosystem and fishery to a level that is more sustainable. However, Walker Lake is interlinked with the lower Walker River and adjacent groundwater system which makes it difficult to understand the full effect of upstream water-management actions on the overall hydrologic system including the lake level, volume, and dissolved-solids concentrations of Walker Lake. To understand the effects of water-management actions on the lower Walker River Basin hydrologic system, a watershed model and groundwater flow model have been developed by the U.S. Geological Survey in cooperation with the Bureau of Reclamation and the National Fish and Wildlife Foundation. The watershed model was developed using the precipitation runoff modeling system (PRMS) and the groundwater flow model was constructed using the MODular groundwater FLOW model (MODFLOW) and both were calibrated for the lower Walker River Basin. These models can be incorporated in an integrated Groundwater and Surface-water FLOW (GSFLOW) model of the lower Walker River Basin. Additionally, the MODFLOW model developed for this study is useful for efficiently simulating long-term and large-scale effects of water-management actions on groundwater hydrology, streamflow, and Walker Lake level, volume, and dissolved-solids concentrations. The lower Walker River Basin PRMS model (LWR_PRMS) was constructed using a subbasin approach to aid in development and calibration, and simulates a 30-year period from 1978 to 2007 using daily time steps. The LWR_PRMS was used to estimate the distribution of groundwater recharge specified in the MODFLOW model. The highest rates of groundwater recharge occur in the Wassuk Range beneath perennial and ephemeral stream channels, whereas lower rates of recharge occur beneath alluvial fans along mountain fronts. The total groundwater recharge estimated using PRMS was about 25,000 acre-feet per year. The lower Walker River Basin MODFLOW (LWR_MF) model simulates an 89-year period using monthly time steps. The LWR_MF was constructed with an initial steady-state simulation to represent dynamic equilibrium conditions from 1908 to 1918 and then a transient simulation representing the period 1919–2007. The model was calibrated using a combination of manual and automated methods of adjusting model parameters to minimize errors between model simulated results and weighted observations of groundwater levels, streamflows, and lake level. Hydrologic conditions simulated with the LWR_MF include the movement and change in storage of groundwater, and the water budgets for Walker River, Walker Lake, and the groundwater system. The LWR_MF computed dissolved-solids concentrations for Walker Lake using simulated lake volume and an assumed constant internal salt mass of 37.2 million tons. Effects of potential changes in water management on future conditions (scenarios) of the lower Walker River Basin hydrologic system and Walker Lake from 2011 to 2070 were evaluated. Several water-management scenarios were considered, including a baseline scenario that represents no changes in system management, improved irrigation efficiencies for the Walker River Indian Irrigation Project (WRIIP), a range of increased streamflows entering the lower Walker River Basin, and, the fallowing of fields on the WRIIP. For the baseline scenario, it was assumed that streamflow conditions from 1981 to 2010 will be repeated in the future. Results indicate that Walker Lake level and volume continue to decline but at a slower rate as the surface area of the lake becomes smaller and lake evaporation decreases. Dissolved-solids concentrations in Walker Lake continue to increase and increase much more rapidly during periods when minimal flows reach the lake due to a diminished lake volume. Alternatively, in years with high runoff, lake level increases are greater and dissolved-solids decreases are greater, compared with equivalent runoffs experienced during 1981–2010. The simulated effects of improving WRIIP efficiencies on Walker River streamflows, Walker Lake inflow, level, and dissolved-solids concentrations, and crop consumptive use, are compared with the baseline reference scenario for a range of irrigation efficiency improvements from 0 to 25 percent over 60 years. Results indicate that water is conserved through a reduction in irrigation-induced groundwater recharge and subsequent groundwater discharge through evapotranspiration. The conserved water mostly goes to increased streamflow to Walker Lake, followed by increased crop consumptive use, then increased evaporation from Weber Reservoir. The simulated effects of increased streamflows at Walker River at Wabuska streamgage (10301500) on Walker Lake inflow, level, and dissolved-solids concentrations, and crop consumptive use, are compared with the baseline scenario after 60 years under two different management methods for Weber Reservoir. Results indicate Walker Lake level and dissolved-solids concentrations stabilized with increased irrigation-season streamflow of about 40,000 acre-feet per year at the Walker River at Wabuska streamgage. Walker Lake level increased, and dissolved-solids concentration decreased, with increased flows of 50,000 acre-feet per year or more. After 60 years with additional irrigation-season streamflows of 50,000 acre-feet per year, Walker Lake level increased by about 48 feet, and lake dissolved-solids concentrations decreased by about 3,000 milligrams per liter (mg/L). With 75,000 acre-feet per year of additional streamflow, Walker Lake level increased by 70 feet, and dissolved-solids concentration decreased by 7,600 milligrams per liter. The effects of fallowing of Walker River Indian Irrigation Project fields from 2007 to 2010 on Walker Lake inflow, level, and dissolved solids were evaluated. Fallowing resulted in a near doubling of Walker River inflow to Walker Lake during this period, an increase in Walker Lake level of about 1.4 feet, and a decrease in dissolved-solids concentration of about 540 mg/L.

Nevada↗

Flooding in the South Platte River and Fountain Creek Basins in eastern Colorado, September 9–18, 2013

On September 9, 2013, rain began to fall in eastern Colorado as a large low-pressure system pulled plumes of tropical moisture northward from the Pacific Ocean and the Gulf of Mexico. By September 16, 2013, as much as 12 to 20 inches of rain had fallen in the foothills of the Front Range of the Southern Rocky Mountains and adjacent plains near Colorado Springs, Colorado, north to the Colorado-Wyoming border. The rain caused major flooding during September 9–18, 2013, in a large part of the South Platte River Basin and in the Fountain Creek Basin. The floods resulted in several fatalities, more than 31,000 damaged or destroyed structures, and an estimated 3 billion dollars in damages. The U.S. Geological Survey (USGS) documented peak stage, streamflow, or both from the flood event for 80 sites located on selected rivers and streams in the South Platte River and Fountain Creek Basins and on the Platte River in Nebraska. The majority of flood-peak streamflows occurred on September 12 or 13, 2013, coinciding with the period of maximum rainfall. The flood resulted in new record peak streamflows at 17 streamgages having at least 10 years of record; 13 in the South Platte River Basin and 4 in the Fountain Creek Basin. Flooding in the South Platte River Basin was primarily contained to select streams in Aurora and the Denver metropolitan area, most of the mountain tributaries joining the main stem South Platte River from Denver to Greeley, and in the main stem South Platte River from Denver to the Colorado-Nebraska State line. In Aurora, where about 15 inches of rain fell, streamflow peaked at 5,470 cubic feet per second (ft 3 /s) in Toll Gate Creek, a tributary to Sand Creek. Downstream from Aurora near the confluence with the South Platte River, Sand Creek peaked at 14,900 ft 3 /s, which was the highest streamflow since at least 1992, but less than the peak of 25,500 ft 3 /s in 1957 that occurred 4 miles upstream from the mouth. Flood-peak streamflows in the Denver metropolitan area were generally below historic records. The peak of 3,930 ft 3 /s on September 12 at the State of Colorado streamgage South Platte River at Denver ranked 59 out of 116 peaks and was less than the 1965 peak of 40,300 ft 3 /s. Ten of the 13 streamgages in the South Platte River Basin with new record peak streamflows were located on the mountain tributaries; Bear Creek, Fourmile Creek, Boulder Creek, St. Vrain Creek, the Big Thompson River, and the Cache la Poudre River. A daily average streamflow of 8,910 ft 3 /s on September 13 in Boulder Creek at the confluence with St. Vrain Creek was more than twice the previous instantaneous peak of 4,410 ft 3 /s from 1938. The USGS calculated a peak streamflow of 23,800 ft 3 /s for the St. Vrain Creek at Lyons; the highest streamflow on record at this State of Colorado streamgage (122 years of record) is 10,500 ft 3 /s from 1941. A peak streamflow of 16,200 ft 3 /s was calculated for the Big Thompson River at mouth of canyon near Drake streamgage, which is the second highest peak in 90 years of record and about one-half the magnitude of the peak of 31,200 ft 3 /s from July 31, 1976. A streamflow of 60,000 ft 3 /s in the South Platte River at Fort Morgan (September 15, 2013) suggests that a new record streamflow occurred in the main stem in the Greeley area, about 45 miles upstream from Fort Morgan. The current peak of record at a State of Colorado streamgage at Kersey, about 6.5 miles downstream from Greeley, is 31,500 ft 3 /s from 1973. Given that there was minimal inflow between Kersey and Fort Morgan, the USGS estimates there was probably at least 60,000 ft 3 /s at Kersey, which would be almost double the peak streamflow of record from 1973. Flooding in the Fountain Creek Basin was primarily contained to Fountain Creek from southern Colorado Springs to its confluence with the Arkansas River in Pueblo, in lower Monument Creek, and in several mountain tributaries. New record peak streamflows occurred at four mountain tributary streamgages having at least 10 years of record; Bear Creek, Cheyenne Creek, Rock Creek, and Little Fountain Creek. Five streamgages with at least 10 years of record in a 32-mile reach of Fountain Creek extending from Colorado Springs to Piñon had peak streamflows in the top five for the period of record. A peak of 15,300 ft 3 /s at Fountain Creek near Fountain was the highest streamflow recorded in the Fountain Creek Basin during the September 2013 event and ranks the third highest peak in 46 years. Near the mouth of the basin, a peak of 11,800 ft 3 /s in Pueblo was only the thirteenth highest annual peak in 74 years. A new Colorado record for daily rainfall of 11.85 inches was recorded at a USGS rain gage in the Little Fountain Creek Basin on September 12, 2013.

Colorado↗

Aquatic biological communities and associated habitats at selected sites in the Big Wood River Watershed, south-central Idaho, 2014

Assessments of streamflow (discharge) parameters, water quality, physical habitat, and biological communities were completed between May and September 2014 as part of a monitoring program in the Big Wood River watershed of south-central Idaho. The sampling was conducted by the U.S. Geological Survey in cooperation with Blaine County, Trout Unlimited, the Nature Conservancy, and the Wood River Land Trust to help identify the status of aquatic resources at selected locations in the watershed. Information in this report provides a basis with which to evaluate and monitor the long-term health of the Big Wood River and its major tributaries. Sampling sites were co-located with existing U.S. Geological Survey streamgaging stations: three on the main stem Big Wood River and four on the North Fork Big Wood River (North Fork), Warm Springs Creek (Warm Sp), Trail Creek (Trail Ck), and East Fork Big Wood River (East Fork) tributaries. The analytical results and quality-assurance information for water quality, physical habitat, and biological community samples collected at study sites during 2 weeks in September 2014 are summarized. Water-quality data include concentrations of major nutrients, suspended sediment, dissolved oxygen, and fecal-coliform bacteria. To assess the potential effects of nutrient enrichment on algal growth, concentrations of periphyton biomass (chlorophyll- a and ash free dry weight) in riffle habitats were determined at each site. Physical habitat parameters include stream channel morphology, habitat volume, instream structure, substrate composition, and riparian vegetative cover. Biological data include taxa richness, abundance, and stream-health indicator metrics for macroinvertebrate and fish communities. Statistical summaries of the water-quality, habitat, and biological data are provided along with discussion of how these findings relate to the health of aquatic resources in the Big Wood River watershed. Seasonal discharge patterns using statistical summaries of daily discharge from selected sites are reported for water years 2012–15. Results showed that annual average daily mean discharge increased from the Big Wood River near Ketchum, ID (BW Ketchum) downstream to the Big Wood River at Hailey, ID (BW Hailey), but decreased by nearly 50 percent from BW Hailey downstream to Big Wood River at Stanton Crossing near Bellevue, ID (BW Stanton). Annual variability in daily mean discharge among main-stem sites was highest at BW Stanton, suggesting that this part of the river may be subject to some level of flow alteration. Hydrologic alterations resulting in flow reduction can contribute to higher water temperature, especially during the summer months when conditions are often most stressful to fish and other stream organisms. Daily water temperature and water temperature trends from June to September 2014 are reported for select tributary and main-stem sites on the Big Wood River and can be used to assess the potential for biological impairment based on aquatic life temperature criteria for cold-water streams. The State of Idaho maximum temperature criteria for protection of cold-water aquatic life of 22 °C was exceeded at Warm Sp and BW Stanton during summer 2014, but at none of the other main-stem or tributary sites. The 13 °C critical temperature criterion for salmonid spawning was exceeded in early July 2014 at BW Ketchum and BW Hailey near the end of the rainbow trout critical spawning and rearing period. Temperature exceedances were most frequent at BW Stanton, where exceedances for rainbow trout and brown trout occurred from May through early July 2014 during most of the critical spawning and rearing period. Water quality and habitat availability did not seem to be limiting for fish or other aquatic organisms at most sites in the Big Wood River watershed. Water quality assessments in September 2014 determined no exceedances of total maximum daily load target levels. The availability and quality of habitat was limited at BW Stanton, where shallow-water habitat conditions prevailed. Macroinvertebrate community diversity was high at all sites except for BW Stanton, where low community diversity was attributed to low species richness and high abundances of a few tolerant taxa. Presence of low species diversity and high macroinvertebrate tolerance values at BW Stanton indicates that benthic community condition and stream health were reduced at that location. Fish surveys done in September 2014 did not indicate any significant reductions in native fish communities in the Big Wood River or its tributaries. Native rainbow trout ( Oncorhynchus mykiss ) and Wood River sculpin ( Cottus leiopomus ) were the dominant fish species in the drainage and were found at all tributary and main-stem sites. Non-native brown ( Salmo trutta ) and brook trout ( Salvelinus fontinalis ) were limited to lower drainage sites on the Big Wood River (BW Hailey and BW Stanton), and occurred in relatively low numbers.

Idaho↗

Suspended sediment, turbidity, and stream water temperature in the Sauk River Basin, western Washington, water years 2012-16

The Sauk River is a federally designated Wild and Scenic River that drains a relatively undisturbed landscape along the western slope of the North Cascade Mountain Range, Washington, which includes the glaciated volcano, Glacier Peak. Naturally high sediment loads characteristic of basins draining volcanoes like Glacier Peak make the Sauk River a dominant contributor of sediment to the downstream main stem river, the Skagit River. Additionally, the Sauk River serves as important spawning and rearing habitat for several salmonid species in the greater Skagit River system. Because of the importance of sediment to morphology, flow-conveyance, and ecosystem condition, there is interest in understanding the magnitude and timing of suspended sediment and turbidity from the Sauk River system and its principal tributaries, the White Chuck and Suiattle Rivers, to the Skagit River. Suspended-sediment measurements, turbidity data, and water temperature data were collected at two U.S. Geological Survey streamgages in the upper and middle reaches of the Sauk River over a 4-year period extending from October 2011 to September 2015, and at a downstream location in the lower river for a 5-year period extending from October 2011 to September 2016. Over the collective 5-year study period, mean annual suspended-sediment loads at the three streamgages on the upper, middle, and lower Sauk River streamgages were 94,200 metric tons (t), 203,000 t, and 940,000 t streamgages, respectively. Fine (smaller than 0.0625 millimeter) total suspended-sediment load averaged 49 percent at the upper Sauk River streamgage, 42 percent at the middle Sauk River streamgage, and 34 percent at the lower Sauk River streamgage.

Washington↗

Transport of nitrogen and phosphorus in the Cedar River Basin, Iowa and Minnesota, 2000–15

Nitrate concentrations in the Cedar River in Iowa and Minnesota have increased from an average of less than 1.0 milligram per liter in the early 1900s to more than 5.0 milligrams per liter in the 2000s and have resulted in periodic water-quality impairment of the river. Spatial differences and temporal changes in nitrogen and phosphorus transport in the Cedar River Basin are described for the period from 2000 to 2015. Data used to estimate nitrogen and phosphorus transport were collected by the U.S. Geological Survey as part of six base-flow synoptic studies and by the Minnesota Pollution Control Agency and the Iowa Department of Natural Resources as part of their long-term stream and river monitoring programs. The Cedar River transported an annual average of 53,100 tons of total nitrogen and 2,510 tons of total phosphorus during 2000–15. Three subbasins yielded an annual average of more than 30 pounds per acre (lb/acre) of nitrogen to the Cedar River, whereas two subbasins yielded an annual average of less than 20 lb/acre of nitrogen. The average annual total phosphorus yield from the Little Cedar River subbasin (0.35 lb/acre) was only about 16 percent of the yield from the greatest total phosphorus yielding Lower Cedar River subbasin (more than 1.0 lb/acre). The annual total nitrogen and total phosphorus loads did not change significantly during the study. The relation between annual stream runoff and annual total nitrogen and total phosphorus yields was not spatially uniform across the Cedar River Basin. The Beaver Creek, Black Hawk Creek, and Wolf Creek subbasins yielded the most, and the Main Stem Middle Cedar River, the Lower Cedar River, and the Little Cedar River subbasins yielded the least amount of nitrogen for a given amount of runoff. The Lower Cedar River and Wolf Creek subbasins yielded the most and the West Fork Cedar River and the Little Cedar River subbasins yielded the least phosphorus for a given amount of runoff. The results of this study describe nutrient transport during 2000–15 that can be used to evaluate future progress of nutrient reduction strategies in the Cedar River Basin.

Iowa, Minnesota↗

Distribution of mining-related trace elements in streambed and flood-plain sediment along the middle Big River and tributaries in the Southeast Missouri Barite District, 2012–15

Lead mining first began in the Big River watershed during the 1700s. Lead was the primary metal mined throughout most of the 1700s and early 1800s and it continued to be mined until the mid-1900s. Barite mining began in the middle part of the watershed in the mid- to late 1800s. Although considerable attention has been given to concentrations of miningrelated trace elements (mostly cadmium, lead, and zinc) in the Big River and its tributaries draining the Old Lead Belt, there is less information regarding concentrations of mining-related trace elements in tributaries draining the Barite District in southeast Missouri, which is downstream from the Old Lead Belt, and the contribution of sediment transported from this district to trace elements in lower reaches of the Big River. The purpose of this report is to present results of an investigation of the distribution of mining-related trace elements in sediments in the middle reach of the Big River downstream from the Old Lead Belt and the Big River tributaries that drain a large part of the Barite District. In general, concentrations of cadmium and lead in streambed sediment were largest in samples from the Big River and smallest in Barite District tributary samples. Concentrations of zinc were somewhat similar in the Big River and Barite District tributaries; however, higher concentrations were present in upstream Big River site samples, as well as in samples from one site on Maddin Creek and at another site on Old Mines Creek that drains the Barite District. Barium concentrations were considerably larger in samples from Barite District tributaries compared to samples collected on the Big River. Samples collected downstream from the Barite District on the Big River had considerably larger barium concentrations than samples collected upstream from the Barite District. Flood-plain core samples were collected from 26 cores at 5 transect locations along tributaries in the Barite District. Of the individual 693 bulk (unsieved) samples from these cores analyzed by x-ray fluorescence, the probable effects concentration (PEC) values were exceeded for cadmium (PEC of 4.98 milligrams per kilogram [mg/kg], 218 samples), lead (PEC of 128 mg/kg, 91 samples), nickel (PEC of 48.6 mg/kg, 45 samples), and zinc (PEC of 459 mg/kg, 77 samples). Of the 693 samples, 21 exceeded the U.S. Environmental Protection Agency residential yard cleanup level of 400 mg/kg for lead; 19 of these were samples from a single transect near the mouth of Mineral Fork Creek where its flood plain joins the Big River flood plain. Shortly after the December 2015 flood on the Big River (the third largest flood along the river since the 1950s), 23 samples of fine sediment deposited from the flood were collected from the Big River flood plain upstream and downstream from the Barite District and several tributaries. Overall, the general pattern of barium, lead, and zinc concentrations in the 2015 flood sediment samples was similar to that observed in the streambed-sediment samples. Overall concentrations of barium were larger at Big River sites downstream from the Barite District, and cadmium, lead, and zinc concentrations were generally similar or smaller at sites downstream from the Barite District when compared to sites upstream from the Barite District. These data indicate a substantial influx of barium from the Barite District into the Big River but only a minimal influx of cadmium, lead, and zinc.

Missouri↗

Assessment of the presence of sewage in the Mill River under low-flow conditions, Springfield, Massachusetts, 2010–11

The U.S. Geological Survey, in cooperation with the Pioneer Valley Planning Commission, the U.S. Environmental Protection Agency, and the Massachusetts Department of Environmental Protection Senator William X. Wall Experiment Station, assessed the presence of 14 commonly used human-health pharmaceutical compounds, fecal indicator bacteria, and other man-made compounds indicative of the presence of human sewage in the lower reach of the Mill River near its confluence with the Connecticut River in Springfield, Massachusetts. The study was part of the Tri-State Connecticut River Targeted Watershed Initiative and involved the collection and analysis of raw river water at three sites along the reach, extending from Watershops Pond to the mouth, over the course of a low-flow period, July through November 2010. Previous studies in the region indicated that nonpoint or undocumented sources of wastewater contributed a variety of organic contaminants and potentially harmful bacteria to rivers under both high- and low-flow conditions. Additional samples, including a raw sewage sample collected near a Mill River combined sewer overflow during a non-overflow period, were collected in March 2011. The study was designed to determine if city sewage or other domestic sources of wastewater were entering the river within this reach during low-flow conditions. No definitive evidence of sewage was measured in Mill River water samples collected during the study period. Fecal indicator bacteria, including Escherichia coli ( E. coli ) and enterococci bacteria, were detected in all Mill River water samples. In the DNA analysis of enterococci cultures from the Mill River, samples generally tested negative for the Enterococcus faecium ( esp ) human-specific genetic marker, whereas the raw sewage sample tested positive. Samples also generally tested negative in the human-specific rDNA marker assay for the anaerobic bacterium Bacteroidetes . Samples tested negative in 2010 for two Bacteroidetes human-specific genetic markers, HF134 and HF183, except samples from near the mouth of the Mill River, which tested positive. Samples collected in March 2011 from all three measurement sites tested positive for both markers. The results of bacterial analyses suggest that the fecal bacteria in summer and fall months are most likely of animal origin rather than human. Despite the urban setting, long history of development, and many potential sources of man-made contamination in the Mill River, none of the 12 water samples collected during the study contained targeted pharmaceutical compounds at concentrations greater than the analytical reporting levels. Other man-made compounds, like fluorescent whitening agents, were measured and detected in samples at low concentrations 4 out of 5 times the samples were collected; however, the other lines of evidence do not support a sewer source but rather other nonpoint sources upstream in the watershed. The results of this study do not support the hypothesis that aging sewer lines or combined sewer overflow infrastructure leak into the Mill River as tested during the low-flow conditions during sampling for this study. None of the results from Mill River samples offer conclusive evidence of the presence of sewage. Some low-level detections of pharmaceutical compounds, other man-made chemicals, and bacteria suggest an upstream, nonpoint source. A single raw sewage sample was collected, diluted, and examined for comparison with Mill River water samples and to ensure that the analytical methods could detect typical wastewater constituents. High levels of bacteria were measured, and low levels of three anthropogenic pharmaceutical compounds were detected, confirming the effectiveness of the sub-part-per-million method. The concentration of fluorescent whitening agent-1 in the sewage sample was 90,000 times greater than the median concentration in the Mill River samples.

Massachusetts↗

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

Colorado↗

Streamflow, water quality, and contaminant loads in the lower Charles River Watershed, Massachusetts, 1999-2000

Streamflow data and dry-weather and stormwater water-quality samples were collected from the main stem of the Charles River upstream of the lower Charles River (or the Basin) and from four partially culverted urban streams that drain tributary subbasins in the lower Charles River Watershed. Samples were collected between June 1999 and September 2000 and analyzed for a number of potential contaminants including nitrate (plus nitrite), ammonia, total Kjeldahl nitrogen, phosphorus, cadmium, chromium, copper, lead, and zinc; and water-quality properties including specific conductance, turbidity, biochemical oxygen demand, fecal coliform bacteria, Entero-coccus bacteria, total dissolved solids, and total suspended sediment. These data were used to identify the major pathways and to determine the magnitudes of contaminants loads that contribute to the poor water quality of the lower Charles River. Water-quality and streamflow data, for one small urban stream and two storm drains that drain subbasins with uniform (greater than 73 percent) land use (including single-family residential, multifamily residential, and commercial), also were collected. These data were used to elucidate relations among streamflow, water quality, and subbasin characteristics. Streamflow in the lower Charles River Watershed can be characterized as being unsettled and flashy. These characteristics result from the impervious character of the land and the complex infrastructure of pipes, pumps, diversionary canals, and detention ponds throughout the watershed. The water quality of the lower Charles River can be considered good?meeting water-quality standards and guidelines?during dry weather. After rainstorms, however, the water quality of the river becomes impaired, as in other urban areas. The poor quality of stormwater and its large quantity, delivered over short periods (hours and days), together with illicit sanitary cross connections, and combined sewer overflows, results in large contaminant loads that appear to exceed the river?s assimilative capacity. Annual contaminant loads from stormwater discharges directly to the lower Charles River are large, but most dry-weather and stormwater contaminant loads measured in this study originate from upstream of the Watertown Dam and are delivered to the lower Charles River in mainstem flows. An exception is fecal coliform bacteria. Stony Brook, a large tributary influenced by combined sewer overflow, contributed almost half of the annual fecal coliform load to the lower Charles River for Water Year 2000. Much of this fecal coliform bacteria load is discharged from Stony Brook to the lower Charles River during rain-storms. Estimated stormwater loads for future conditions suggest that sewer separation in the Stony Brook Subbasin might reduce loads of constituents associated with sewage but increase loads of constituents associated with street runoff. The unique environment offered by the lower Charles River must be considered when the environmental implications of large contaminant loads are interpreted. In particular, the lower Charles River has low hydraulic gradients, a lack of tidal flushing, a lack of natural uncontaminated sediment from erosion of upstream uncontaminated soils, and an anoxic, sulfide-rich bottom layer that forms a non-tidal salt wedge in the downstream part of the lower Charles River. Individually and in combination, these characteristics may increase the likelihood of adverse effects of some contaminants on the water, biota, and sediment of the lower Charles River.

Water-Resources Investigations Report↗

Surface-Water Quality of the Skokomish, Nooksack, and Green-Duwamish Rivers and Thornton Creek, Puget Sound Basin, Washington, 1995-98

Streamflow and surface-water-quality data were collected from November 1995 through April 1998 (water years 1996-98) from a surface-water network in the Puget Sound Basin study unit of the U.S. Geological Survey National Water-Quality Assessment program. Water samples collected monthly and during storm runoff events were analyzed for nutrients, major ions, organic carbon, and suspended sediment, and at selected sites, samples were analyzed for pesticides and volatile organic compounds. Eleven sites were established in three major watersheds--two in the Skokomish River Basin, three in the Nooksack River Basin, five in the Green-Duwamish River Basin, and one site in Thornton Creek Basin, a small tributary to Lake Washington. The Skokomish River near Potlatch, Nooksack River at Brennan, and Duwamish River at Tukwila are integrators of mixed land uses with the sampling sites locally influenced by forestry practices, agriculture, and urbanization, respectively. The remaining eight sites are indicators of relatively homogeneous land use/land cover in their basins. The site on the North Fork Skokomish River is an indicator site chosen to measure reference or background conditions in the study unit. In the Nooksack River Basin, the site on Fishtrap Creek is an indicator of agriculture, and the Nooksack River at North Cedarville is an indicator site of forestry practices in the upper watershed. In the Green-Duwamish River Basin, Springbrook Creek is an urban indicator, Big Soos Creek is an indicator of a rapidly developing suburban basin; Newaukum Creek is an indicator of agriculture; and the Green River above Twin Camp Creek is an indicator of forestry practices. Thornton Creek is an indicator of high-density urban residential and commercial development. Conditions during the first 18 months of sampling were dominated by above-normal precipitation. For the Seattle-Tacoma area, water year 1997 was the wettest of the 3 years during the sample-collection period. Nearly 52 inches fell (about 14 inches above average) and monthly precipitation was often 200 percent of normal. The wet years kept streamflows generally above normal and contributed to high concentrations of pesticides, nutrients, suspended sediment, and organic carbon in samples. On the basis of chemical concentrations, dissolved oxygen concentrations, and water temperature, the relative quality of water among the 11 study sites ranged from exceptionally high in the North Fork Skokomish and the Green to fair in Springbrook and Thornton. Water in the large rivers (Skokomish, Nooksack, Green-Duwamish) and in two of the small streams in the Puget Sound Lowlands (Big Soos and Newaukum) was characterized by dilute water chemistry with dissolved solids concentrations less than 130 milligrams per liter. Water in three other small streams in the Lowlands (Fishtrap, Springbrook, and Thornton) had dissolved solids concentrations as high as 320 milligrams per liter. Nutrient and pesticide concentrations mostly were higher in the small streams than in the large rivers. Suspended-sediment concentrations, however, were highest in the large rivers, with averages ranging from 85 to 443 milligrams per liter. During storm and flood events, suspended-sediment concentrations in samples from the Nooksack were as much as 2,800 milligrams per liter, and from the Skokomish, 1,500 milligrams per liter. Out of 86 pesticides and 86 volatile organic compounds analyzed, a total of 35 pesticides and 11 volatile organic compounds were detected at concentrations above laboratory reporting levels in samples collected from the four intensively studied sites, the lower Nooksack River, Duwamish River, Fishtrap Creek, and Thornton Creek. Herbicides were detected more frequently than insecticides. The herbicide prometon was detected in 66 percent of all 124 samples collected, followed by simazine (65 percent), atrazine (64 percent), and the insecticide diazinon (50 percent). The detected volatile organic c

Water-Resources Investigations Report↗

Ground-water levels in an alluvial plain between the Tanana and Chena Rivers near Fairbanks, Alaska 1986-93

The aquifer of an alluvial plain between the Tanana and Chena Rivers near Fairbanks, Alaska, generally consists of highly transmissive sands and gravels under water-table conditions. During 1986-88, the U.S. Geological Survey studied the distribution of ground-water levels in the alluvial plain between Moose Creek Dam and the confluence of the Tanana and Chena Rivers. Moose Creek Dam is a flood-control structure on the Chena River that impounds water only during high flows in the Chena River or during tests of the dam's control gates. Ground-water-level information is needed to help design and place septic systems, buildings, and drainage structures. Using 38 existing wells and 83 wells drilled for this study during 1986 and 1987, ground-water levels were measured to determine the depth to the water table, its seasonal variation, and its relation to changes in river and reservoir stages. Water levels were continuously measured in 10 wells and periodically measured in 110 other wells until August 1988. During 1989, water levels were measured at least once in 59 wells. Three wells were equipped with water-level recorders through 1993. River stages were measured continuously at one gaging station on the Tanana River and at two stations on the Chena River. During summer months of 1986-88, stages and discharges in the Chena River were generally less than long-term mean monthly values, whereas mean monthly stages and discharges in the Tanana River fluctuated above and below long-term mean monthly values. Depths to water in monitoring wells ranged from slightly above land surface to about 21 feet below land surface. Depths to water in the alluvial plain were within 10 feet of land surface in most areas, but were within 5 feet of land surface in many low-lying areas. In general, the water table sloped to the northwest, from the Tanana River to the Chena River, at a gradient of about 4 feet per mile. Water levels in wells within about half a mile of either river responded rapidly to changes in river stage. During summer months of 1989-93, stages and discharges in the Chena River were generally higher than those during 1986-88, whereas stages and discharges in the Tanana River were similar to those during 1986-88. During 1989, peak water levels were higher in more than half the wells measured than during peak levels observed during 1986-88. Peak water levels were also 1.9 to 3.3 feet higher in 1991 or 1992 than peak values during 1986-88 in three wells equipped with water-level recorders. Water levels in wells near Moose Creek Dam responded rapidly to changes in water levels behind the dam. During one impoundment, water levels in a well 0.1 mile from the dam rose approximately 7 feet, to 4.8 feet below land surface.

Alaska↗

Surface-water-quality assessment of the Yakima River basin, Washington: Overview of major findings, 1987-91

Surface-water-quality conditions were assessed in the Yakima River Basin, which drains 6,155 square miles of mostly forested, range, and agricultural land in Washington. The Yakima River Basin is one of the most intensively farmed and irrigated areas in the United States, and is often referred to as the “Nation’s Fruitbowl.” Natural and anthropogenic sources of contaminants and flow regulation control water-quality conditions throughout the basin. This report summarizes the spatial and temporal distribution, sources, and implications of the dissolved oxygen, water temperature, pH, suspended sediment, nutrient, organic compound (pesticide), trace element, fecal indicator bacteria, radionuclide, and aquatic ecology data collected during the 1987–91 water years. The Yakima River descends from a water surface altitude of 2,449 feet at the foot of Keechelus Dam to 340 feet at its mouth downstream from Horn Rapids Dam near Richland. The basin can be divided into three distinct river reaches on the basis of its physical characteristics. The upper reach, which drains the Kittitas Valley, has a high gradient, with an average streambed slope of 14 feet per mile (ft/mi) over the 74 miles from the foot of Keechelus Dam (river mile [RM] 214.5) to just upstream from Umtanum. The middle reach, which drains the Mid Valley, extends a distance of 33 miles from Umtanum (RM 140.4) to just upstream from Union Gap and also has a high gradient, with an average streambed slope of 11 ft/mi. The lower reach of the Yakima River drains the Lower Valley and has an average streambed slope of 7 ft/mi over the 107 miles from Union Gap (RM 107.2) to the mouth of the Yakima River. These reaches exhibited differences in water-quality conditions related to the differences in geologic sources of contaminants and land use. Compared with the rest of the basin, the Kittitas Valley and headwaters of the Naches River Subbasin had relatively low concentrations and loads of suspended sediment, nutrients, organic compounds, and fecal indicator bacteria. There were very few failures to meet the Washington State dissolved oxygen standard or exceedances of the water temperature and pH standards in this reach. In general, these areas are considered to be areas of lessdegraded water quality in the basin. The preTertiary metamorphic and intrusive rocks of the Cle Elum and Teanaway River Subbasins, however, were found to be significant geologic sources of antimony, arsenic, chromium, copper, mercury, nickel, selenium, and zinc. As a result, the arsenic, chromium, and nickel concentrations measured in the streambed sediment of the Kittitas Valley were 13 to 74 times higher than those measured in the Lower Valley. The Mid and Lower Valleys had similar water-quality conditions, governed by the intensive agricultural and irrigation activities, highly erosive landscapes, and flow regulation. Most of the failures to meet the Washington State standards for dissolved oxygen and exceedances of the standards for water temperature and pH occurred in the Mid and Lower Valleys. Agricultural drains in the Mid and Lower Valleys were found to be significant sources of nutrients, suspended sediment, pesticides, and fecal indicator bacteria. Downstream from the irrigation diversions near Union Gap, summertime streamflow in the Yakima River was drastically reduced to only a few hundred cubic feet per second. In the lower Yakima River, agricultural return flow typically accounts for as much as 80 percent of the main stem summertime flow near the downstream terminus of the basin. Therefore, the water-quality characteristics of the lower Yakima River resemble those of the agricultural drains. The highest fecal bacteria concentrations (35,000 colonies of Escherichia coli per 100 milliliters of water) were measured in the Granger/Sunnyside area, the location of most of the livestock in the basin. The east side area of the Lower Valley (area east of the Yakima River) was the predominant source area for suspended sediment and pesticides in the basin. This area had the largest acreage of irrigated land and generally received the largest application of pesticides. Owing to the highly erosive soils of the area, the suspended sediment load from the east side in June 1989 (320 kilograms per day) was five or more times larger than from any other area, and the loads of several of the more hydrophobic organic compounds were four or more times larger. An ecological assessment of the Yakima River Basin ranked physical, chemical, and biological conditions at impaired (degraded) sites against reference sites in an effort to understand how land use changes physical and chemical site characteristics and how biota respond to these changes. For this assessment, the basin was divided into four natural ecological categories: (1) Cascades ecoregion, (2) Eastern Cascades Slopes and Foothills ecoregion, (3) Columbia Basin ecoregion, and (4) large rivers. Each of these categories has a unique combination of climate and landscape features that produces a distinctive terrestrial vegetation assemblage. In the combined Cascades and Eastern Cascades site group, which had the fewest impaired sites, the metals index was the only physical and chemical index that indicated any impairment. The moderate levels of impairment noted in the invertebrate and algal communities were not, however, associated with metals, and may have been related to the effects of logging, although the intensity of logging was not directly quantified in this study. Sites in the Columbia Basin site group were all moderately or severely impaired with the exception of the two reference sites (Umtanum Creek and Satus Creek below Dry Creek), which showed no physical, chemical, or biological impairment. Three sites were heavily affected by agriculture (Granger Drain, Moxee Drain, and Spring Creek) and were listed as severely impaired by most of the physical, chemical, and biological condition indices. Agriculture was the primary cause of the impairment of biological communities in this site group. The primary physical and chemical indicators of agricultural effects were nutrients, pesticides, dissolved solids, and substrate embeddedness, which all tended to increase with agricultural intensity. The biological effects of agriculture were manifested by a decrease in the abundance and number of native species of fish and invertebrates, a shift in algal communities to species indicative of eutrophic conditions, and higher abundances. There was also an increase in the abundance and number of nonnative fish species due to the prevalence of fish that are largely tolerant of nutrient-rich conditions. Main stem (large river) sites downstream from the city of Yakima exhibited severe impairment of fish communities associated with high levels of pesticides in fish tissues and the presence of external anomalies on fish.

Washington↗

Stream water quality in coal mined areas of the lower Cheat River Basin, West Virginia and Pennsylvania, during low-flow conditions, July 1997

Introduction The Cheat River Basin is in the Allegheny Plateau and Allegheny Mountain Sections of the Appalachian Plateau Physiographic Province (Fenneman, 1946) and is almost entirely within the state of West Virginia. The Cheat River drains an area of 1,422 square miles in Randolph, Tucker, Preston, and Monongalia Counties in West Virginia and Fayette County in Pennsylvania. From its headwaters in Randolph County, W.Va., the Cheat River flows 157 miles north to the Pennsylvania state line, where it enters the Monongahela River. The Cheat River drainage comprises approximately 19 percent of the total Monongahela River Basin. The Cheat River and streams within the Cheat River Basin are characterized by steep gradients, rock channels, and high flow velocities that have created a thriving white-water rafting industry for the area. The headwaters of the Cheat River contain some of the most pristine and aesthetic streams in West Virginia. The attraction to the area, particularly the lower part of the Cheat River Basin (the lower 412 square miles of the basin), has been suppressed because of poor water quality. The economy of the Lower Cheat River Basin has been dominated by coal mining over many decades. As a result, many abandoned deep and surface mines discharge untreated acid mine drainage (AMD), which degrades water quality, into the Cheat River and many of its tributary streams. Approximately 60 regulated mine-related discharges (West Virginia Department of Environmental Protection, 1996) and 185 abandoned mine sites (U.S. Office of Surface Mining, 1998) discharge treated and untreated AMD into the Cheat River and its tributaries. The West Virginia Department of Environmental Protection (WVDEP) Office of Abandoned Mine Lands and Reclamation (AML&R) has recently completed several AMD reclamation projects throughout the Cheat River Basin that have collectively improved the mainstem water quality. The AML&R office is currently involved in acquiring grant funds and designing treatment facilities for several additional AMD sites that adversely affect the Cheat River and its tributaries. To obtain the baseline water-quality information necessary to evaluate instream treatment and alternative methods for remediating AMD and its effects, the U.S. Geological Survey (USGS), in cooperation with the WVDEP, collected stream water samples at 111 sites throughout the Lower Cheat River Basin during low-flow conditions from July 16-18, 1997. The data also will provide information on stream water quality in areas affected by AMD and thus would point to priority areas of focus, such as the sources of the AMD. This report presents the results of analyses of the samples collected in July 1997 and describes a process for ranking of stream water-quality degradation as a guide to water-resource managers considering AMD remediation activities.

Pennsylvania, West Virginia↗

Nutrients and Suspended Solids in Surface Waters of the Upper Illinois River Basin in Illinois, Indiana, and Wisconsin, 1978-97

A retrospective analysis of selected data on nutrients and suspended solids in surface waters of the upper Illinois River Basin was done as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program. Approximately 91 percent of the upper Illinois River Basin is drained by three principal rivers: the Kankakee (and its major tributary, the Iroquois), the Des Plaines, and the Fox. The data analyzed were collected by the Illinois Environmental Protection Agency (IEPA), which operates 39 monitoring sites in the study area as part of its Ambient Water-Quality Monitoring Network, and included analyses for total ammonia nitrogen, total nitriteplus- nitrate nitrogen, total ammonia-plus-organic (total Kjeldahl) nitrogen, dissolved and total phosphorus, and total suspended solids and volatile solids. Nutrient and suspended-sediment data collected by the USGS as part of the upper Illinois River Basin NAWQA pilot study from 1987-90 were compared to IEPA data. For the 1978-97 period, in general, nutrient concentrations, with the exception of nitrate, were highest at streams in the urban areas of the Des Plaines River Basin. Streams in the Kankakee and Fox River Basins generally had lower concentrations, although the data indicate that concentrations increased in a downstream direction in these basins. These spatial patterns in nutrient concentrations correspond closely with land use in the respective basins. The elevated concentrations of ammonia and phosphorus in the urbanized Des Plaines River Basin, with respect to other sites in the study area, indicate that municipal- and industrial- waste discharges into streams of the basin increase concentrations of these nutrients in the receiving streams. In contrast, nitrate concentrations were highest in agricultural areas. Relatively large ratios of nitrogen to phosphorus and nitrate to ammonia are characteristic of agricultural drainage. On the other hand, urban tributaries were characterized by smaller ratios of nitrogen to phosphorus and nitrate to ammonia. The apparent, but nonuniform, correspondence of nutrient concentrations to urban and agricultural land use in the upper Illinois River Basin was generally consistent with findings in other river basins. A seasonal pattern of nutrient concentrations characterized by high concentrations in the winter months, depletion during the spring and summer, and minimum levels in the late summer or early fall was observed in some of the data from the upper Illinois River Basin. Monthly median concentrations of total ammonia nitrogen and nitrite plus nitrate nitrogen were at minimum levels from July through October, whereas phosphorus concentrations did not display a strong seasonal trend. The net result of nutrient inputs and transport through the river system were elevated nutrient concentrations at the most-downstream site in the study area on the Illinois River. At this site, the median concentrations of nitrate, total phosphorus, and orthophosphate were among the highest in the Mississippi River Basin, and the concentration of ammonia was the highest. Suspended-solids concentrations do not indicate any particularly strong spatial patterns among major river basins in the study area. Instead, higher suspended-solids concentrations are observed at sites draining areas of low-permeability, easily eroded soils in agricultural and urban areas alike. Seasonal variation of suspended solids were consistent at sites across the study area. In general, suspended- solids concentrations were highest in the summer and lowest in the winter. The increase during the summer can be attributed to higher streamflow and the associated increase in runoff and transport, as well as increased phytoplankton growth. Because of the high nutrient concentrations in the upper Illinois River Basin, annual loads and yields also were relatively large; however, yields of phosphorus from the Fox and Kankakee River Basins were not unusually high. The ma

Water-Resources Investigations Report↗