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At least 1,207 records · Page 67Linked to original sources
USGS2007

Experimental analysis of the auditory detection process on avian point counts

We have developed a system for simulating the conditions of avian surveys in which birds are identified by sound. The system uses a laptop computer to control a set of amplified MP3 players placed at known locations around a survey point. The system can realistically simulate a known population of songbirds under a range of factors that affect detection probabilities. The goals of our research are to describe the sources and range of variability affecting point-count estimates and to find applications of sampling theory and methodologies that produce practical improvements in the quality of bird-census data. Initial experiments in an open field showed that, on average, observers tend to undercount birds on unlimited-radius counts, though the proportion of birds counted by individual observers ranged from 81% to 132% of the actual total. In contrast to the unlimited-radius counts, when data were truncated at a 50-m radius around the point, observers overestimated the total population by 17% to 122%. Results also illustrate how detection distances decline and identification errors increase with increasing levels of ambient noise. Overall, the proportion of birds heard by observers decreased by 28 ± 4.7% under breezy conditions, 41 ± 5.2% with the presence of additional background birds, and 42 ± 3.4% with the addition of 10 dB of white noise. These findings illustrate some of the inherent difficulties in interpreting avian abundance estimates based on auditory detections, and why estimates that do not account for variations in detection probability will not withstand critical scrutiny.

The Auk↗
USGS2016

Using spatial capture–recapture to elucidate population processes and space-use in herpetological studies

The cryptic behavior and ecology of herpetofauna make estimating the impacts of environmental change on demography difficult; yet, the ability to measure demographic relationships is essential for elucidating mechanisms leading to the population declines reported for herpetofauna worldwide. Recently developed spatial capture–recapture (SCR) methods are well suited to standard herpetofauna monitoring approaches. Individually identifying animals and their locations allows accurate estimates of population densities and survival. Spatial capture–recapture methods also allow estimation of parameters describing space-use and movement, which generally are expensive or difficult to obtain using other methods. In this paper, we discuss the basic components of SCR models, the available software for conducting analyses, and the experimental designs based on common herpetological survey methods. We then apply SCR models to Red-backed Salamander ( Plethodon cinereus ), to determine differences in density, survival, dispersal, and space-use between adult male and female salamanders. By highlighting the capabilities of SCR, and its advantages compared to traditional methods, we hope to give herpetologists the resource they need to apply SCR in their own systems.

Journal of Herpetology↗
USGS2022

High‐frequency rupture processes of the 2014 Mw 8.2 Iquique and 2015 Mw 8.3 Illapel, Chile, earthquakes determined from strong‐motion recordings

Strong‐motion recordings of the 2014 M w "> M w Mw 8.2 Iquique and 2015 M w "> M w Mw 8.3 Illapel, Chile, earthquakes were analyzed to determine rupture propagation and the location, timing, and strength of subevents that produce most of the high‐frequency (≥1 Hz) ground motions. A moving window,cross‐correlation analysis of recordings from a local dense array, band‐pass filtered at 1 Hz, directly shows that the Iquique earthquake ruptured to the southeast over a distance of about 60 km. Array analysis of lower frequency energy (0.03–0.1 Hz) indicates that it occurred updip of the high‐frequency rupture. A methodology was developed for inverting the envelopes of acceleration records (1–5 Hz) to map high‐frequency source factors on the rupture zone and was applied to the two earthquakes. Waveforms of M w "> M w Mw 6 earthquakes were used as empirical Green’s functions in the inversions. High‐frequency subevents within the two M w "> M w Mw 8 earthquakes were located at depths ranging from 25 to 55 km and mostly occurred downdip of the peak slip of these earthquakes. Fourier spectral ratios of the Iquique mainshock with respect to M w "> M w Mw 5–6 aftershocks were fit to determine their stress drops. The stress drops were roughly constant from M w "> M w Mw 5 to 8 at 10–20 MPa. A compound rupture model is described in which subevents occur in areas of spatially heterogeneous strength and stress on the rupture, and produce the high‐frequency radiated energy of the overall earthquake, but are not located in the areas of peak slip. The stress drop of the overall earthquake is shown to equal the root mean square stress drop of subevents averaged over the rupture area.

Iquique, Illapel↗
USGS2020

Rupture process of the M6.5 Stanley, Idaho, earthquake inferred from seismic waveform and geodetic data

The 2020 M 6.5 Stanley, Idaho, earthquake produced rupture in the north of the active Sawtooth fault in the northern basin and range at depth, without any observable surface rupture. Global Positioning System (GPS) and Interferometric Synthetic Aperture Radar (InSAR) data yield several millimeters of static offsets out to ∼100 km from the rupture and up to ∼0.1 m of near‐field crustal deformation. We combine the GPS and InSAR data with long‐period regional seismic waveforms to derive models of kinematic slip and afterslip. We find that the coseismic rupture is complex, likely involving up to 2 m combined left‐lateral strike slip and normal slip on a previously unidentified ∼south‐southeast‐striking fault. This slip is predominantly left‐lateral strike slip, different from the dominant east‐northeast–west‐northwest normal faulting of the region. At least one ∼northeast‐trending fault, likely associated with the Trans‐Challis fault system, is inferred to have accommodated a few decimeters of right‐lateral afterslip, consistent with vigorous aftershock activity at depth along northeast‐trending lineations.

Idaho↗
USGS2026

The digital archivist: Automating legacy macroseismic data processing using large language models

Macroseismic data are a key resource to investigate shaking and damage from preinstrumental and early instrumental eras. However, data are often stored as inconsistently formatted reports describing observed shaking and damage, making manually parsing and interpreting accounts labor‐intensive. We introduce a novel workflow using Google’s Gemini 2.5 Pro large language model (LLM) to automate the extraction and structuring of macroseismic observations from summary reports. We apply this workflow to the 22 March 1957 M 5.3 Daly City, California, earthquake as a case study. We used Gemini to extract addresses, originally assigned modified Mercalli intensity values, and descriptions from each report. To address coordinate precision limits, addresses were geocoded via Google’s Geocoding application programming interface. This workflow yielded over 2300 geocoded intensity reports for the Daly City earthquake. We use the geocoded accounts, with the original report intensity assignments, to develop a shaking intensity map that in some respects rivals modern Did You Feel It? Maps. We also extract and present data for the 9 February 1971 M L 6.7 Sylmar, California, earthquake. Our results demonstrate the potential of LLMs for reliably extracting and analyzing large, unstructured macroseismic datasets. LLMs offer a scalable solution for rapidly digitizing macroseismic archives, enabling their broader use to constrain ground‐motion models in modern seismic hazard analysis and to improve our understanding of site effects in urban areas. The concepts explored here may also be applied to the handling of other legacy seismological and earth science data.

Seismological Research Letters↗
USGS1989

Rupture process of the Ms 6.6 Superstition Hills, California, earthquake determined from strong-motion recordings: application of tomographic source inversion

We analyze strong-motion recordings of the M s 6.6 Superstition Hills earthquake to determine the timing, location, spatial extent, and rupture velocity of the subevents that produced the bulk of the high-frequency (0.5 to 4 Hz) seismic energy radiated by this shock. The earthquake can be characterized by three principal subevents, the largest ones occurring about 3 and 10 sec after initiation of rupture. Timing relationships between pulses on the seismograms indicate that the three subevents are located within 8 km of each other along the northern portion of the Superstition Hills fault. The two largest subevents display different directivity effects. We apply a tomographic source inversion to the integrated accelerograms to determine the slip acceleration on the fault as a function of time and distance, based on a one-dimensional fault model. The azimuthal distribution of amplitudes for the second subevent can be largely explained by a rupture that propagated about 2 km to the southeast along the Superstition Hills fault at a velocity about equal to the P -wave velocity. An alternative model with rupture propagating to the northeast along a conjugate fault plane can also account for the observed directivity of this subevent, but it is not supported by the aftershock distribution. The third subevent ruptured to the southeast along an 8-km long portion of the Superstition Hills fault at about the shear-wave velocity. This rupture propagation caused the relatively large accelerations and velocities observed in strong-motion records for stations southeast of the hypocenter. The long time intervals between the subevents and their relative proximity to each other indicate a very slow component to the rupture development. The southern half of the Superstition Hills fault did not generate significant high-frequency strong ground motion, although it showed substantial co-seismic surface displacement. The subevents are situated along the same northern portion of the fault where most of the aftershocks are located. The locations of the subevents appear to be controlled by bends in the fault mapped at the surface and by changes in basement structure at depth.

California↗
USGS1994

Wide-band analysis of the 3 March 1985 central Chile earthquake: Overall source process and rupture history

We apply a linear, finite-fault waveform inversion scheme to the near-source strong-motion records, the teleseismic body waves, and the long-period Rayleigh waves recorded for the 3 March 1985 Chile earthquake to recover the mainshock rupture history. The data contain periods between about 2 and 350 sec and are inverted by allowing a variable dislocation rise time at each point on the fault. The results indicate that the mainshock had a seismic moment of 1.5 × 10 28 dyne-cm ( M w 8.0) and ruptured mainly updip and to the south of the hypocenter for a distance of about 150 km along the Nazca-South America plate boundary. A smaller northward component of propagation is also evident, giving a total rupture length of about 200 km. The total source duration of the mainshock is 70 sec, with the majority of the slip occurring within the first 40 sec in a broad 100-km-wide zone in the northern half of the rupture area. Slip in this region extends from a depth of 55 km to within about 10 km of the surface and contains two areas of maximum slip (2.3 and 2.9 m) with rise times of approximately 14 sec. Slip in the southern portion of the fault reaches lower peak values (1.8 m) and extends downdip to depths no greater than 30 km. An independent variable rise-time inversion of the teleseismic body waves alone yields similar results, indicating that a significant component of slow fault motion is not required for this earthquake. The mainshock was preceded by several smaller precursors, the largest of which is an M w ∼ 6.6 thrust earthquake occurring at a depth of 22 km in the shallow 15° dipping portion of the plate interface.

Bulletin of the Seismological Society of America↗
USGS2001

Physiography and late Quaternary-Holocene processes of Northeastern Gulf of Mexico outer continental shelf off Mississippi and Alabama

High-resolution multibeam mapping of the mid- and outer continental shelf and upper slope off Mississippi and Alabama reveals a complex bathymetry that reflects conditions during the last eustatic rise and the present high stand of sea level. The most prominent bathymetric features are pinnacles and hardgrounds that are scattered throughout the area. These features generally stand <10 m above the surrounding seafloor, cover large areas, and display a variety of morphologies. Almost all the reef pinnacles and hardgrounds have zones of high acoustic backscatter on their summits and on the seafloor immediately adjacent to their southwest walls. In addition, they also have erosional moats on the seafloor to the southwest. Large fields of bedforms are scattered throughout the mapped area. The asymmetries and orientations of the bedforms suggest that they were formed by excursions of the northeast-flowing Loop Current. In contrast, the pervasive ponding of sediment on the northeast sides of bathymetric highs indicates that one of the predominant directions of sediment transport has been to the south and southwest. The shelf break is a zone of numerous landslides of various sizes and complexities. The morphology of several landslide scars indicates that some of the failures occurred recently. One large reef-capped salt dome was mapped in the area, surrounded by a large field of pock-marks. Fields of pockmarks are also scattered on the shelf. The growth and demise of the reefs are related to the fluctuating transgression of eustatic sea level during the last deglaciation. Two episodes of reef drowning are correlated with the increased rates of sea-level rise during documented melt-water pulses; the first occurred from 14.8 to 14.2 ka and the second from 11.8 to 11.2 ka. Rates of sea-level rise exceeded the maximum growth rate of hermatypic corals only during these two intervals since the last glacial maximum and thus drowned the coral communities.

Alabama, Mississippi↗
USGS2013

Relating hyporheic fluxes, residence times, and redox-sensitive biogeochemical processes upstream of beaver dams

Abstract. Small dams enhance the development of patchy microenvironments along stream corridors by trapping sediment and creating complex streambed morphologies. This patchiness drives intricate hyporheic flux patterns that govern the exchange of O 2 and redox-sensitive solutes between the water column and the stream bed. We used multiple tracer techniques, naturally occurring and injected, to evaluate hyporheic flow dynamics and associated biogeochemical cycling and microbial reactivity around 2 beaver dams in Wyoming (USA). High-resolution fiber-optic distributed temperature sensing was used to collect temperature data over 9 vertical streambed profiles and to generate comprehensive vertical flux maps using 1-dimensional (1-D) heat-transport modeling. Coincident with these locations, vertical profiles of hyporheic water were collected every week and analyzed for dissolved O 2 , pH, dissolved organic C, and several conservative and redox-sensitive solutes. In addition, hyporheic and net stream aerobic microbial reactivity were analyzed with a constant-rate injection of the biologically sensitive resazurin (Raz) smart tracer. The combined results revealed a heterogeneous system with rates of downwelling hyporheic flow organized by morphologic unit and tightly coupled to the redox conditions of the subsurface. Principal component analysis was used to summarize the variability of all redox-sensitive species, and results indicated that hyporheic water varied from oxic-stream-like to anoxic-reduced in direct response to the hydrodynamic conditions and associated residence times. The anaerobic transition threshold predicted by the mean O 2 Damko ¨hler number seemed to overestimate the actual transition as indicated by multiple secondary electron acceptors, illustrating the gradient nature of anaerobic transition. Temporal flux variability in low-flux morphologies generated a much greater range in hyporheic redox conditions compared to high-flux zones, and chemical responses to changing flux rates were consistent with those predicted from the empirical relationship between redox condition and residence time. The Raz tracer revealed that hyporheic flow paths have strong net aerobic respiration, particularly at higher residence time, but this reactive exchange did not affect the net stream signal at the reach scale.

Freshwater Science↗
USGS2021

Miocene neritic benthic foraminiferal community dynamics, Calvert Cliffs, Maryland, USA: Species pool, patterns and processes

The presence/absence and abundance of benthic foraminifera in successive discrete beds (Shattuck “zones”) of the Miocene Calvert and Choptank formations, exposed at the Calvert Cliffs, Maryland, USA, allows for investigation of community dynamics over space and time. The stratigraphic distribution of benthic foraminifera is documented and interpreted in the context of sea-level change, sequence stratigraphy, and the previously published distribution of mollusks. Neritic benthic foraminiferal communities of four sea-level cycles over ∼4 million years of the middle Miocene, encompassing the Miocene Climatic Optimum and the succeeding middle Miocene Climate Transition, are dominated by the same abundant species. They differ in the varying abundance of common species that occur throughout most of the studied section and in the different rare species that appear and disappear. Transgressive systems tracts (TSTs) have higher species diversity than highstand systems tracts (HSTs) but much lower density of specimens. In contrast to some previous research, all beds in the studied section are interpreted as being from the inner part of a broad, low gradient shelf and were deposited at water depths of less than ∼50 m. It is suggested that species are recruited from a regional species pool of propagules throughout the duration of TSTs. Recruitment is curtailed during highstands leading to lower diversity in the HSTs.

Maryland↗
USGS1991

Wave processes and geologic responses on the floor of the Yellow Sea

The floor of the Yellow Sea is a geologically mundane surface: it is nearly horizontal, lacks relief, and, with few exceptions, is devoid of conspicuous geomorphologic features. However, it is the principal repository for the prodigious sediment load of the Huanghe (Yellow River); and, due to its inherent shallowness (average depth is 40 m), it is frequently stressed by waves generated by winter storms and typhoons. Analyses of mass physical properties of cores representing the upper few meters of sediment in the central and north-central Yellow Sea (near the Shandong Peninsula), in conjunction with analyses of slope stability, failure modes, and erodibility, permit an assessment of the likelihood and effect of dynamic, transient geologic events on the seabed. Vane shear-strength profiles along with consolidation test data indicate that the present surface of the seabed is in a depositional mode and is compacting normally. in addition, liquid-limit profiles imply that in the study area these neritic sediments have been accumulating in an environment that probably has not been modified significantly since sea level reached its current level. There is no geotechnical evidence in the nine cores recovered that slope failures have occurred, and clasts, sand lenses or other manifestations of mass movements, including flows, also are absent. These observations support previous interpretations of seismic records. Moreover, slope stability analysis for static conditions shows that the sea floor is quite stable. Regardless, shear-stress levels generated by cyclic loading during major storms may approach the sediment shear strengths, and, when coupled with concomitant excess pore pressures, could cause slope failure. Unless the failed beds collapsed or flowed, however, there probably would be little conspicuous evidence of such a failure. in fact, evaluation of the potential of these sediments for disintegrative behavior suggests that they are not prone to either collapse or flow. Storm waves also generate oscillatory bottom currents that may erode the seabed. Whether the sediment is considered as cohesionless or cohesive, typhoons could have the potential to erode at all water depths within the Yellow Sea (i.e., to 90 m), and winter storms to water depths of 60 m or more. However, in the case of cohesive behavior, it could be that the effect of winter storms and most typhoons is generally less extreme. If the sea floor is repeatedly scoured, it is likely limited to the top few centimeters. Despite the fact that storm waves may cause slope failure and are certainly responsible for frequent scouring, they probably leave only a subtle sedimentologic imprint on the seabed.

Yellow Sea↗
USGS2004

Hydrothermal alteration, ore fluid characteristics, and gold depositional processes along a trondhjemite-komatiite contact at Tarmoola, Western Australia

Tarmoola is a structurally controlled Archean orogenic gold deposit hosted in greenschist facies metamorphosed komatiite and trondhjemite in the Leonora district of the Eastern Goldfields province, Yilgarn craton. High-grade (>1 g/t Au) orebodies are located in komatiite wall rock adjacent to the eastern and northeastern margins of the asymmetrical, north-south-striking, Tarmoola trondhjemite intrusion. Gold-bearing veins post-date trondhjemite emplacement (ca. 2700 Ma), quartz diorite dikes (ca. 2667 Ma), and regional greenschist facies metamorphism. Textures and crosscutting relationships in gold-bearing veins indicate two stages of hydrothermal fluid infiltration associated with a single gold-related hydrothermal event: a volumetrically dominant, but gold-poor, stage I fluid and a gold-rich stage II fluid. Gold-bearing veins contain stage I milky quartz and pyrite that are overprinted by stage II quartz-ankerite-muscovite-chalcopyrite-sphalerite-galena-gold-tellurides ?? albite ?? chlorite ?? fuchsite ?? epidote ?? scheelite. Stage I hydrothermal alteration assemblages are different in trondhjemite and komatiite due to contrasting reactions between a common ore fluid and disparate wall-rock chemistry. Stage II fluid-wall rock interaction was minor compared to stage I and is indicated by the overprinting of stage I mineral assemblages by stage II microveins. Wall-rock alteration proximal to veins in trondhjemite is characterized by replacement of igneous plagioclase, amphibole, biotite, and metamorphic chlorite by hydrothermal quartz, muscovite, ankerite, calcite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold, whereas in proximal alteration in komatiite, metamorphic chlorite and talc are replaced by ankerite, quartz, muscovite, albite, chlorite, fuchsite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold. The stage II fluid was enriched in H2O, CO2, Si, Ca, K, Na, S, Au, Ag, Cu, Pb, W, Bi, As, Mo, Zn, and Te. Based on fluid inclusion studies and stage II mineral equilibria, gold deposited from a homogeneous, neutral to slightly alkaline (pH 5.1-5.5), reduced, low-salinity (<5.5 wt % NaCl equiv) fluid that had a bulk composition of 78 mole percent H2O and 21 mole percent CO2, and trace amounts of CH4, C2H6, H2, Ar, H2S, and He. Gold deposition occurred at 300?? ?? 50??C and 0.5 to 3.0 kbars. Assuming lithostatic fluid pressures, gold precipitated at a 2- to 10-km depth. Stage II gray quartz ??18Ofluid values range from 5.9 to 7.5 per mil, whereas ??Dfluid values calculated from the dehydration of muscovite grains and measured directly from bulk fluid inclusion analyses of stage II gray quartz have ranges of -9 to -35 and -27 to -28 per mil, respectively. Hydrothermal ore fluids were transported from greater crustal depths to the site of gold deposition during the district-scale D3 event by shallowly W dipping, reverse brittle-ductile shear zones in supracrustal rock and along the steeply east dipping trondhjemite contact. Associated subhorizontal east-west shortening caused the reactivation of the eastern trondhjemite margin and subparallel foliation, which facilitated the transport of hydrothermal fluids and the generation of gold-bearing veins and hydrothermal alteration zones in komatiite. East-west-striking fractures in trondhjemite aided the lateral migration of ore fluids away from trondhjemite margins and the formation of east-west-striking gold-bearing veins and broad alteration zones. Gold was most likely transported in the stage II fluid as bisulfide complexes. The sulfidation of trondhjemite and komatiite wall rock by the stage II fluid caused the destabilization of An bisulfide complexes and gold deposition. Potassium, Ca, and CO2 metasomatism of komatiite wall rock may have enhanced gold deposition via the acidification of the stage II fluid. The physicochemical characteristics of the Tarmoola ore fluid and relative timing of gold mineralization are consistent with the Yilgarn-wide,

Economic Geology↗
USGS2001

Olivine-liquid relations of lava erupted by Kilauea volcano from 1994 to 1998: Implications for shallow magmatic processes associated with the ongoing east-rift-zone eruption

From 1994 through 1998, the eruption of Kîlauea, in Hawai’i, was dominated by steady-state effusion at Pu‘u ‘Ô‘ô that was briefly disrupted by an eruption 4 km uprift at Nāpau Crater on January 30, 1997. In this paper, I describe the systematic relations of whole-rock, glass, olivine, and olivine-inclusion compositions of lava samples collected throughout this interval. This suite comprises vent samples and tube-contained flows collected at variable distances from the vent. The glass composition of tube lava varies systematically with distance and allows for the “vent-correction” of glass thermometry and olivine–liquid K D as a function of tube-transport distance. Combined olivine–liquid data for vent samples and “vent-corrected” lava-tube samples are used to document pre-eruptive magmatic conditions. K D values determined for matrix glasses and forsterite cores define three types of olivine phenocrysts: type A (in equilibrium with host glass), type B (Mg-rich relative to host glass) and type C (Mg-poor relative to host glass). All three types of olivine have a cognate association with melts that are present within the shallow magmatic plumbing system during this interval. During steady-state eruptive activity, the compositions of whole-rock, glass and most olivine phenocrysts (type A) all vary sympathetically over time and as influenced by changes of magmatic pressure within the summit-rift-zone plumbing system. Type-A olivine is interpreted as having grown during passage from the summit magma-chamber along the east-rift-zone conduit. Type-B olivine (high Fo) is consistent with equilibrium crystallization from bulk-rock compositions and is likely to have grown within the summit magma-chamber. Lower-temperature, fractionated lava was erupted during non-steady-state activity of the Nāpau Crater eruption. Type-A and type-B olivine–liquid relations indicate that this lava is a mixture of rift-stored and summit-derived magmas. Post- Nāpau lava (at Pu‘u ‘Ô‘ô) gradually increases in temperature and MgO content, and contains type-C olivine with complex zoning, indicating magma hybridization associated with the flushing of rift-stored components through the eruption conduit.

Hawaii↗
USGS1982

Biogenic and nonbiogenic ore-forming processes in the south Texas uranium district; evidence from the Panna Maria deposit

Geochemical and petrographic studies of core samples from the Panna Maria uranium deposit, a roll-type orebody in the Eocene Jackson Group in Karnes County, Texas, yield important information on the origin of the deposit. Organic carbon content averages about 0.42 weight percent in reduced rock and correlates postively with sulfur content. Pyrite is the dominant iron disulfide (FeS 2 ) mineral in most of the ore zone and throughout a surrounding zone of reduced barren ground, and it is commonly associated with organic debris. Marcasite is sparse except in ore adjacent to the altered tongue in one core and locally in mineralized lignite. Sulfur isotopic compositions (delta 34 S) of FeS 2 minerals range broadly from -1 to -34 per mil; the lightest delta 34 S values (less than -20 per mil) were measured in samples from mineralized lignite and from the nose of the ore roll. Petrographic and geochemical characteristics of the Panna Maria deposit contrast greatly with those of three other south Texas roll-type uranium deposits (the Benavides, Felder, and Lamprecht deposits), which are devoid of organic carbon and which contain more sulfide than does the Panna Maria. These three deposits are characterized by abundant isotopically light ore-stage marcasite and by isotopically heavy preore (in the Benavides) or postore (in the Felder and Lamprecht) pyrite. We have concluded previously that sulfide-bearing fault-leaked solutions from underlying hydrocarbon accumulations were important in the formation of the Benavides, Felder, and Lamprecht deposits. Although the Panna Maria deposit shows an apparent alignment along a fault zone, and although underlying formations in the Karnes County area contain sour gas (delta 34 S [asymp] + 14 per mil) and produce oil, the deposit lacks characteristics indicating that its formation or preservation involved extrinsically derived reductants such as fault-leaked aqueous sulfide. Mineralization of the Panna Maria, rather, appears to have been controlled by intrinsically derived reductants related either directly or indirectly to the presence of organic matter.

Texas↗
USGS1992

Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: I. Iron-copper-zinc-lead sulfide solubility relations

Experimental studies, using cold-seal and extraction vessel techniques, were conducted on Fe, Pb, Zn, and Cu sulfide solubilities in chloride solutions at temperatures from 300 degrees to 700 degrees C and pressures from 0.5 to 2 kbars. The solutions were buffered in pH by a quartz monzonite and the pure potassium feldspar-muscovite-quartz assemblage and in f (sub S 2 ) - f (sub O 2 ) largely by the assemblage pyrite-pyrrhotite-magnetite. Solubilities increase with increasing temperature and total chloride, and decrease with increasing pressure. The rise in solubility is particularly steep between 300 degrees and 500 degrees C and between 1,000 and 500 bars. With increasing temperature at any given pressure, or with decreasing pressure at any given temperature, metal solubility eventually passes through a maximum due to increasing competition for chloride by the alkali, hydrogen, and base metal ions and because intersection with a two-fluid region eventually occurs. In that portion of the two-fluid region encountered in the study, metal solubilities in the brine were very high, but solubilities in the gas phase also were significant. In a system controlled by the potassium feldspar-muscovite-quartz buffer, 1-m total Cl (super -) , and the assemblage pyrite-pyrrhotite-magnetite-sphalerite-galena-chalcopyrite, solubilities in ppm at 1 kbar and 300 degrees , 400 degrees , and 500 degrees C were 237, 1,216, and 5,636, for Fe; 51, 613, and 3,105 for Pb; 36, 423, and 2,649 for Zn; and 11, 40, and 113 for Cu, respectively. At 400 degrees C, 0.5 and 2 kbars, the values were 2,627 and 500 for Fe; 1,262 and 194 for Pb; 983 and 120 for Zn; and 60 and 29 for Cu, respectively. All of the above were in the single-fluid region. Single-metal solubilities also were investigated to assess the influence of iron on the solubility of the other metals and to corroborate preliminary dissociation constants for the metal chloride complexes involved. The effect of increasing chloride concentration on solubility reflects primarily a shift to lower pH via the silicate buffer reactions. The effect of decreasing pressure reflects primarily the relative change in the dissociation constants of the chloride complexes involved. Increasing sulfur fugacity lowers solubility, but in systems controlled at relatively low values by an f (sub S 2 ) buffer or wall-rock sulfidation reactions, solutions of high metal content relative to reduced sulfur will tend to develop at high chloride concentrations. Similarity in behavior with respect to the temperature and pressure of Fe, Zn, and Pb sulfide solubilities points to similarity in chloride speciation, and the neutral species appear to be dominant in the high-temperature region. At 500 degrees C and 1 kbar, the log K D values for FeCl degrees 2 , PbCl degrees 2 , ZnCl degrees 2 , and CuCl degrees are, respectively, -8.76, -9.14, -10.86, and -6.22.

Economic Geology↗
USGS2005

Transport and fate of nitrate and pesticides: Hydrogeology and riparian zone processes

There is continuing concern over potential impacts of widespread application of nutrients and pesticides on ground- and surface-water quality. Transport and fate of nitrate and pesticides were investigated in a shallow aquifer and adjacent stream, Cow Castle Creek, in Orangeburg County, South Carolina. Pesticide and pesticide degradate concentrations were detected in ground water with greatest frequency and largest concentrations directly beneath and downgradient from the corn (Zea mays L.) field where they were applied. In almost all samples in which they were detected, concentrations of pesticide degradates greatly exceeded those of parent compounds, and were still present in ground waters that were recharged during the previous 18 yr. The absence of both parent and degradate compounds in samples collected from deeper in the aquifer suggests that this persistence is limited or that the ground water had recharged before use of the pesticide. Concentrations of NO3- in ground water decreased with increasing depth and age, but denitrification was not a dominant controlling factor. Hydrologic and chemical data indicated that ground water discharges to the creek and chemical exchange takes place within the upper 0.7 m of the streambed. Ground water had its greatest influence on surface-water chemistry during low-flow periods, causing a decrease in concentrations of Cl-, NO3-, pesticides, and pesticide degradates. Conversely, shallow subsurface drainage dominates stream chemistry during high-flow periods, increasing stream concentrations of Cl-, NO3-, pesticides, and pesticide degradates. These results point out the importance of understanding the hydrogeologic setting when investigating transport and fate of contaminants in ground water and surface water. ?? ASA, CSSA, SSSA.

Journal of Environmental Quality↗
USGS2008

Comparative study of transport processes of nitrogen, phosphorus, and herbicides to streams in five agricultural basins, USA

Agricultural chemical transport to surface water and the linkage to other hydrological compartments, principally ground water, was investigated at five watersheds in semiarid to humid climatic settings. Chemical transport was affected by storm water runoff, soil drainage, irrigation, and how streams were linked to shallow ground water systems. Irrigation practices and timing of chemical use greatly affected nutrient and pesticide transport in the semiarid basins. Irrigation with imported water tended to increase ground water and chemical transport, whereas the use of locally pumped irrigation water may eliminate connections between streams and ground water, resulting in lower annual loads. Drainage pathways in humid environments are important because the loads may be transported in tile drains, or through varying combinations of ground water discharge, and overland flow. In most cases, overland flow contributed the greatest loads, but a significant portion of the annual load of nitrate and some pesticide degradates can be transported under base-flow conditions. The highest basin yields for nitrate were measured in a semiarid irrigated system that used imported water and in a stream dominated by tile drainage in a humid environment. Pesticide loads, as a percent of actual use (LAPU), showed the effects of climate and geohydrologic conditions. The LAPU values in the semiarid study basin in Washington were generally low because most of the load was transported in ground water discharge to the stream. When herbicides are applied during the rainy season in a semiarid setting, such as simazine in the California basin, LAPU values are similar to those in the Midwest basins. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗