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Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Characterization and simulation of the quantity and quality of water in the Highland Lakes, Texas, 1983-92

The Highland Lakes, located in central Texas, are a series of seven reservoirs on the Colorado River (Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, Lake Marble Falls, Lake Travis, Lake Austin, and Town Lake). The reservoirs provide hydroelectric power for the area. In addition, Lake Austin and Town Lake also provide the public water supply for the Austin metropolitan area. Saline water released from Natural Dam Salt Lake during 1987–89 caused increased concern among water managers that high-salinity water entering the Highland Lakes could result in waterquality problems, necessitating additional treatment of the water. The maximum dissolved solids concentrations for the reservoirs after the saline inflow were about two to three times the average concentrations before the inflow. The maximum concentrations of chloride and sulfate after the inflow were about three to five times the average concentrations before the inflow. The concentrations of dissolved solids, chloride, and sulfate in Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, and Lake Marble Falls were less than the concentrations of the applicable water-quality standards by the end of 1990. Concentrations of these constituents in Lake Travis, Lake Austin, and Town Lake did not decrease to previous levels, which were less than the concentrations of the applicable waterquality standards, until the end of 1991. Constituent concentrations for Lake Buchanan and Inks Lake; for Lake Lyndon B. Johnson and Lake Marble Falls; and for Lake Travis, Lake Austin, and Town Lake were similar because of the relative storage capacities and location of tributary inflows. From the initial increase in constituent concentrations in Lake Buchanan (summer 1987) in response to the saline inflow, the high-salinity water passed through the entire Highland Lakes in about 3.5 years. A mathematical mass-balance model was used to simulate the input and movement of highsalinity water through the Highland Lakes and to estimate monthly mean concentrations of dissolved solids, chloride, and sulfate for wet, average, and dry hydrologic conditions. The simulated median monthly concentrations during the 10-year simulation period for each reservoir generally are larger for the average condition than for the wet condition and generally are larger for the dry condition than for the average condition. The simulated concentrations of dissolved solids, chloride, and sulfate decreased to levels less than the concentrations of the applicable water-quality standards in about 2 to 5 years after the saline water inflow of 1987–89 was simulated for the three hydrologic conditions. Results from the simulations indicate that saline inflows to the Highland Lakes similar to those of the releases from Natural Dam Salt Lake during 1987–89 are unlikely to cause large increases in future concentrations of dissolved solids, chloride, and sulfate in the Highland Lakes. The results also indicate that high-salinity water will continue to be diluted as it is transported downstream through the Highland Lakes, even during extended dry periods.

Texas

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology

Streamflow, ground-water recharge and discharge, and characteristics of surficial deposits in Buzzards Bay Basin, southeastern Massachusetts

Streamflow measurements at 14 low-flow partial-record stations and two discontinued streamflow-gaging stations were related to concurrent streamflows at six long-term streamflow-gaging stations to estimate streamflows at selected flow durations from 50 to 99 percent for water years 1967-91. At low flows, stream discharge per square mile generally increased with increasing percentage of subbasin underlain by stratified-drift deposits. At the 70-, 90-, and 99-percent flow durations, subbasins underlain primarily by stratified-drift deposits had stream discharges per square mile at least 2, 4, and 8 times greater, respectively, than subbasins underlain primarily by till and bedrock deposits. Streamflow measured three times at the Paskamanset River showed that streamflows downstream of municipal pumped wells increased at a lower rate per unit drainage area than streamflows upstream of the pumped wells. When pumpage from wells near the river was added to measured streamflow at the most downstream station, the sum was similar to the potential streamflow at the station if its streamflow per unit area was the same as that upstream from the pumped wells. Mean ground-water recharge and discharge rates were computed from continuous records of daily mean discharge during water years 1967-91 for six streamflow-gaging stations in southeastern Massachusetts and Rhode Island. Estimates of mean ground-water recharge were 19.7 to 22.6 inches per year for stations with drainage areas primarily underlain by till and bedrock deposits, and 23.8 to 25.2 inches per year for stations with drainage areas primarily underlain by stratified-drift deposits. During drought years, annual ground-water recharge can be less than 50 percent of the mean ground-water recharge rate for water years 1967-91. Estimates of ground-water discharge rates generally were 1 to 4 inches per year less than estimates of ground-water recharge rates. Ground-water discharge-duration curves were calculated from hydrograph separation of streamflow records at the six continuous streamflow-gaging stations for water years 1967-91. When streamflows were less than the median streamflow (50-percent duration), ground-water discharges averaged 85.7 percent of the total streamflow at the six streamflow-gaging stations. Ground-water discharges were estimated at the 14 low-flow partial-record stations and two discontinued streamflow-gaging stations by multiplying streamflows at the selected flow durations from 50 to 99 percent for water years 1967-91 by 85.7 percent. Data on surficial deposits in the basin were obtained by drilling 10 wells, by conducting 12 seismic-refraction surveys, and by collecting well log data for 313 wells from consulting firms and the Massachusetts Department of Environmental Management. These data indicated that a few minor corrections could be made to existing saturated thickness maps for stratified-drift deposits in Buzzards Bay Basin. Few well logs were detailed enough to estimate transmissivities; thus existing transmissivity maps were not updated for stratified-drift deposits in the basin.

Massachusetts

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Three-dimensional temperature maps of the Williston Basin, USA: Implications for deep hot sedimentary and enhanced geothermal resources

As part of U.S. Geological Survey's (USGS) efforts to identify and assess geothermal energy resources of the US, a three-dimensional (3D) geologic and thermal model has been constructed for the Williston Basin, USA. The geologic model consists of all sedimentary units above the Proterozoic and Archean crystalline rock (called basement herein), with a total sedimentary thickness of up to 5 km near the basin center. Twenty-nine geologic units were mapped from interpreted formation tops from 16,465 wells. A 3D temperature model was constructed to a depth of 7 km by constructing a 3D heat flow model for the sedimentary units, followed by estimating underlying temperature using a one-dimensional (1D) analytic solution for heat flow within the underlying crystalline basement. Using the sedimentary basin model, heat flow was simulated in 3D and was calibrated using three temperature datasets: 1) 24 high-confidence static temperature logs (equilibrium thermal profiles), 2) more than15,000 drill stem test (DST) measurements from >7,000 wells, and 3) more than 45,000 bottomhole temperature (BHT) measurements from >14,000 wells. The DST and BHT datasets provide broad spatial coverage, but are lower confidence, primarily because measurements were made prior to attaining thermal equilibrium. DST and BHT measurements were binned regionally to develop representative thermal profiles that generally agree with these lower quality data (hereafter called pseudowell temperature profiles). Layer properties (primarily thermal conductivity and compaction curves) were set to best estimate values, then the heat flow model was calibrated to fit pseudowell and static temperature logs primarily by adjusting basal heat flow to approximate the overall temperature profile. Minor adjustments to thermal conductivity allowed adjusting changes in slope at lithologic contacts. Resulting maps include 3D temperature and basal (bottom of sedimentary units) heat flow estimates, which are used as input for the temperature model of the basement. The crystalline basement temperature model uses an analytic 1D solution to the heat flow equation that requires estimates of heat flow and temperature at the upper boundary (i.e., the sediment/basement contact), radiogenic heat production within the crystalline basement, and reference thermal conductivity (i.e., uncorrected for temperature). Two regions of high heat flow are identified: 1) in western North Dakota along the North American Central Plains Conductivity Anomaly and 2) in eastern Montana near the Poplar dome. Within the sedimentary column in the center of the basin of the basin, an area of approximately 100,000 km2 is predicted to have moderate- to high-temperature geothermal resources (>90 °C) under the thickest sequences of sediments. Where thick insulation and high heat flow coincide, electric-grade resources can be less than 4 km deep. Assuming a maximum feasible drilling depth of 7 km, temperatures are predicted to be as high as 175 °C. The geologic model may be used to identify strata at sufficient temperatures that may have natural permeability or that may have conditions that favor development of enhanced/engineered geothermal systems resources.

Montana, North Dakota, South Dakota

Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington

Updating and recalibrating the integrated Santa Rosa Plain Hydrologic Model to assess stream depletion and to simulate future climate and management scenarios in Santa Rosa, Sonoma County, California

The Santa Rosa Plain Hydrologic Model (SRPHM) was developed and published in 2014 through a collaboration between the U.S. Geological Survey (USGS) and Sonoma Water to analyze the hydrologic system in the Santa Rosa Plain watershed, help meet the increasing demand for fresh water, and prepare for future uncertainties in water resources. The original model simulated hydrological conditions and water use from water years 1975 to 2010. Recently (2023), the USGS, in cooperation with Sonoma Water and the California State Water Resources Control Board, updated the SRPHM model to extend its simulation period to the end of the 2018 calendar year, incorporate new estimates of rural and agricultural water use, and use efficient input format for climate variables. The updated model was recalibrated, and evaluation of the new model calibration is included in this report. This report presents the results of comparing the hydraulic heads, streamflow, and groundwater budget simulated by the updated model with those generated by the original model and observed data. The main difference in the simulated budget between the original and updated SRPHM is the estimates of agricultural pumping, rural domestic pumping, and return flow generated from rural water use that was not simulated in the original model. The revised agricultural pumping is simulated using the agricultural package, which constrains pumping to available groundwater. The use of the agricultural package leads to a more realistic estimation of agricultural water use, with revised agricultural pumping being one-third less than that in the original model. The revised rural pumping is about half of the pumping in the original model because of using detailed parcel data to estimate population density in rural areas instead of coarse census tracts. Overall, average total inflows for water years 2006–10 simulated by the updated model were about 2 percent less than the original model, and the average total updated outflows were nearly 5 percent less than the original model. The updated model was then used to generate stream depletion maps, simulate climate change scenarios during 2019–99, and simulate water rights allocation using the Model for Decision Support in Integrated River Basin Management (MODSIM). The results from simulating eight future climate scenarios indicated either an increase in groundwater storage or no significant change in the next 80 years, along with an increase in recharge, an increase in actual evapotranspiration in six out of eight climate projections, and an increase in surface runoff. The increases in the simulated future groundwater storage, recharge, evapotranspiration, and runoff in most climate projections are mainly driven by the projected increase in precipitation in most of the future climate scenarios. The updated model also was used to test a pilot case study demonstrating water-resource allocation among different users with different water rights using the integrated MODSIM-Groundwater and Surface-Water Flow Model (GSFLOW) platform. The updated SRPHM serves as a valuable tool for analyzing historical and future hydrologic conditions in the Santa Rosa Plain watershed and preparing for future uncertainties.

California

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

California

Introduction and methods of analysis for peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods Report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. Flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done by the U.S. Geological Survey, in cooperation with the Departments of Transportation of Illinois, Iowa, Michigan, Minnesota, Missouri, South Dakota, and Wisconsin; the Montana Department of Natural Resources and Conservation; and the North Dakota Department of Water Resources, to assess potential nonstationarity in peak flows in the north-central United States. This chapter summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. A wide range of analyses and statistical approaches are applied to document the primary mechanisms controlling floods and characterize temporal changes in hydroclimatic variables and peak flow. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The climate data consist of monthly time series estimates of temperature, precipitation, potential evapotranspiration, actual evapotranspiration, snowfall, soil moisture storage, snow water equivalent, and runoff on a 3.1-mile by 3.1-mile grid for the conterminous United States. Statistical and graphical analyses were used to investigate potential changes in hydrology and climate. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. To examine potential causal drivers of changes, the climate data were analyzed graphically and statistically. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Iowa, Illinois, Michigan, Missouri, Minnesota, Mon

Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado

An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

Alluvial soils and fill materials in and near the floodplain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with various trace metals (primarily mercury), organic compounds, and radionuclides that were lost to the stream as a result of past operations at the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy’s Oak Ridge Reservation. Observation wells were installed in the shallow (above bedrock) aquifer in and near the floodplain of East Fork Poplar Creek and water-quality samples were collected to determine if contaminants found in the soils and fill are also present in the shallow ground water. The shallow aquifer in the East Fork Poplar Creek flood plain consists primarily of alluvial silt and clay with lesser amounts of sand and gravel. Thickness of the shallow aquifer ranges from essentially zero to as much as 20 feet. A silty-clay glei horizon is present between the base of the alluvium and the top of bedrock at most flood-plain locations and, where present, likely impedes downward ground-water movement. Water in the shallow aquifer near East Fork Poplar Creek occurs under water-table conditions. Recharge to the shallow aquifer is principally from precipitation, and discharge is through springs and seeps to East Fork Poplar Creek and its tributaries. During spring, summer; and fall, evapotranspiration also accounts for the removal of water in storage in the shallow aquifer. Water levels in the shallow aquifer fluctuate seasonally in response to variations in recharge and evapotranspiration. Generally, the depth to water in the observation wells ranged from about 1 to 4 feet below land surface in late winter, and from about 2 to 7 feet below land surface in late fall. During extremely dry periods, the water table recedes below the top of bedrock in some flood-plain areas, possibly causing East Fork Poplar Creek to lose water to the shallow aquifer along some reaches. Contaminants found in water samples collected from several of the observation wells in concentrations (total and (or) total-recoverable) which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, total phenols, and strontium-90. Total and dissolved uranium concentrations exceeded 1.0 microgram per liter in samples from nearly 70 percent of the wells in the East Fork Poplar Creek flood plain. Organic compounds that were identified in low concentrations in samples from a few wells in the flood plain are: Arochlor 1260, benzo(a)anthracene, benzo(b)fluoranthene, chrysene, 3,3-dichlorobenzidine, di-n-butylphthalate, N-nitrosodiphenylamine, and pyrene. Water from one well in the East Fork Poplar Creek flood plain at a contaminated fill site contained 37and 8 micrograms per liter of trichloroethene and trans-1,2-dichloroethene, respectively. Comparison of the results of total and (or) total-recoverable trace-metal determinations with those from dissolved determinations demonstrates that elevated concentrations of these substances in water collected from several of the wells in the East Fork Poplar Creek flood plain resulted from sorption of trace metals (and possibly organic compounds and radionuclides) by fine sediment suspended in the samples. The occurrence of contaminated sediment in these samples is suspected to be the result of borehole contamination during well installation.

Tennessee

Groundwater and surface-water interactions in the Lower Duwamish Waterway, Seattle, Washington

The U.S. Geological Survey (USGS), in cooperation with the Washington State Department of Ecology (Ecology), conducted a study to describe the current understanding of the regional groundwater system of the lower Duwamish River valley and groundwater and surface-water interactions in the lower Duwamish Waterway. The lower Duwamish Waterway is the final 5-mile (mi) reach of the Duwamish River before it empties into Elliott Bay in Puget Sound near Seattle, Washington. A nearshore site (hereinafter referred to as “Nearshore Site” to distinguish the particular site from general discussions of nearshore areas) along the western shoreline of the Duwamish River, about 1.5 mi upstream from the river mouth, was selected for focused groundwater data collection by USGS. Data loggers were deployed in seven groundwater wells and one stilling well in the Duwamish River to measure specific conductance, temperature, and depth at 15-minute intervals for a period of about 2 years. At the Nearshore Site during 2020–22, water levels in the shallow wells were 3–8 feet (ft) higher than water levels in the deep wells, providing evidence for a low-permeability layer between the shallow and deep aquifers in this area. The shallow wells had a pronounced seasonal variability, with high water levels in winter and low water levels in summer. Data from the deep wells showed far less seasonal variability, with slight increases in winter and a near-constant water level from spring to autumn. The deep wells had a strong hydraulic connection to the Duwamish River, as evidenced by the synchronous water-level variability during the tidal cycle, whereas the shallow wells had minimal to no tidal response. The potentiometric maps developed for the Nearshore Site and surrounding areas indicate large differences in groundwater-flow directions for the shallow and deep aquifers at low and high tides. For the shallow aquifer, flow is toward the lower Duwamish Waterway near the Nearshore Site, regardless of the tidal condition. For the deep aquifer, a potentiometric trough forms parallel to the shoreline during high tide, indicating that groundwater flow converges from the uplands to the west and the Duwamish River to the east. The geometry of the potentiometric surfaces between the nearshore-most well and the shoreline is complex and is further confounded by intermittent shoreline armoring and other buried infrastructure, which could serve as either a barrier or a conduit to flow. Groundwater and surface-water interactions in the lower Duwamish Waterway are inherently complex as a result of three overarching factors. First, water levels in the lower reaches of the Duwamish River vary daily by 11–16 ft because of tides from Puget Sound, which create large swings in the hydraulic gradient in the nearshore groundwater system. Second, the density and chemical composition of water in the Duwamish River change daily with the tides and seasonally, which constrains how river water entering the nearshore sediments interacts with discharging groundwater. Third, the nearshore subsurface and shoreline conditions are heterogenous because of extensive shoreline armoring over the past century, which governs the flow of groundwater and infiltrating river water. These unique features of groundwater and surface-water interactions in the lower Duwamish Waterway thus govern the transport of terrestrial contaminants to the lower Duwamish Waterway. Furthermore, the heterogenous aquifer properties in the lower Duwamish Waterway contribute to spatially and temporally dynamic contaminant-transport processes.

Washington

Timing and geometry of the Chemehuevi Formation reveal a late Pleistocene sediment pulse into the Lower Colorado River

The Chemehuevi Formation is a distinctive 50−150-m-thick wedge-shaped Pleistocene sedimentary unit deposited by the Colorado River. It lines the perimeters of the river’s floodplains and bedrock canyons for more than 600 km between the mouth of the Grand Canyon and the delta region in the Gulf of California. The formation is composed of a basal tan to light-yellowish-brown and pale-orange mud-dominated facies overlain and interbedded by a light-yellow-brown sand-dominated facies. The unit is one of two extensively exposed aggradational packages in the Lower Colorado River corridor, in addition to a series of other smaller alluvial terrace deposits. The Chemehuevi Formation appears to represent the response of a fully integrated Colorado River system to a significant perturbation, in contrast to the Bullhead Alluvium, which is likely a unique result of Pliocene river integration. The aggradation of the Chemehuevi Formation in the Lower Colorado River corridor may be similarly due to a unique event in the Colorado River system, or it may instead be a well-preserved sedimentary sequence recording typical behavior of the Colorado River below the Grand Canyon in the late Pleistocene. As such, multiple causal mechanisms have been proposed, but no study to date has conclusively explained the Chemehuevi Formation. To help resolve its timing, duration, and origin, we applied post-infrared infrared stimulated luminescence, carbonate U-Th series, and zircon sensitive high-resolution ion microprobe U-Th series geochronology to determine the ages of key exposures of the unit over a wide spatial area. These new data demonstrate that the Chemehuevi Formation was deposited ca. 110−90 ka. The depositional ages collectively overlap, suggesting that deposition occurred rapidly relative to the resolution of the geochronometers. The new depositional timing coincides with a shift from glacial to interglacial conditions after the marine isotope stage 5-6 transition. This observation is consistent with a climate-induced sediment pulse as a causal mechanism, yet correlations with similar deposits in the Colorado River headwaters or in neighboring catchments appear elusive. Potentially, climate transitions between glacial and interglacial periods induced a sediment pulse from hillslopes of the Colorado River system that resulted in the Chemehuevi Formation. An alternative or additional explanation is that the Chemehuevi Formation represents release of lava dam−impounded sediment in the Grand Canyon. The surface geometry of the Chemehuevi Formation projects upstream to the approximate location of lava dams, and the largest possible lava dam impoundment (the Upper Prospect dam) is comparable in volume to the formation. The lava dam hypothesis appears to be a possible explanation for the Chemehuevi Formation. However, tying deposition to a specific lava dam or series of lava dams remains challenging due to discrepancies in timing and volume. The combined effects of a series of lava dams may have led to the Chemehuevi Formation, as the last Pleistocene lava dam eruption coincides with the onset of deposition. Alternatively, the formation may result from the combined effects of both regional climate transitions and the lava dams that created a transient reservoir to compound a climate transition−driven sediment pulse. The geochronologic data presented here do not allow us to distinguish between the lava dam or climate transition hypotheses but will need to be reconciled with any future proposed depositional model.

Arizona, California, Nevada

Spatial distribution of API gravity and gas/oil ratios for petroleum accumulations in Upper Cretaceous strata of the San Miguel, Olmos, and Escondido Formations of the south Texas Maverick Basin—Implications for petroleum migration and charge history

The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.

Texas

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York