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Deep critical zone controls on shallow landslides

The deep critical zone (CZ) has long been recognized for its importance in influencing shallow landslides but was not considered feasible to include in slope stability models at the watershed scale. In this study, we demonstrate that simple approximations of the CZ in a fully coupled hydrologic and soil slope stability model can effectively capture the location, timing, and likely size of shallow landslides. To achieve this, we use coupled, process-based models that incorporate the effects of 1) deep CZ structures, 2) three-dimensional transient hydrology, and 3) multidimensional slope stability, calibrated with data from an intensively monitored field site. Our results show that the hydrologically active deep CZ guides groundwater flow, influencing where it drains from or exfiltrates to the soil mantle, producing distinct patterns of soil saturation and seepage forces at the soil-bedrock boundary. Deep conductive weathered critical zone drains the soil mantle, reducing the likelihood of destabilizing pore pressures, while the downslope thinning of the CZ forces groundwater to the surface. This creates localized instability and a tendency for similar-sized landslides across the landscape. In contrast, the absence of conductive weathered bedrock results in more widespread destabilizing pore pressures, leading to larger landslides and the likelihood of landslides earlier in a storm than in landscapes underlain by a deep CZ. Our findings suggest that first-order variations of deep CZ can provide physical explanations for variations observed in the susceptibility, magnitude, and timing of shallow landslides, and that CZ structure may be inferred from patterns and timing of landsliding.

Proceedings of the National Academy of Sciences

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2021–22

Between the 1950s and 1980s, wastewater generated at the Idaho National Laboratory contained Iodine-129 ( 129 I); this wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well, unlined infiltration ponds, or leaked from distribution systems below industrial facilities. During 2021–22, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy and the Idaho Department of Environmental Quality Idaho National Laboratory Oversight Program, collected groundwater samples from 64 monitoring wells in the ESRP aquifer, 6 of which are part of a multilevel monitoring system, to determine the concentration of 129 I in the groundwater. These samples were analyzed by accelerator mass spectrometry as part of a long-term ongoing study to track trends and occurrences of this carcinogenic, long-lived radionuclide in the environment. Concentrations ranged from slightly above the locally determined background concentration of 5.4×10 −6 picocuries per liter, to just below the U.S. Environmental Protection Agency’s maximum contaminant level of 1 picocurie per liter. Discharge of wastewater containing 129 I has been discontinued to the aquifer, and long-term trends from a subset (n=15) of sampled wells show decreasing 129 I concentrations over the last three decades. Concentrations of 129 I in groundwater from monitoring wells near facilities at the Idaho National Laboratory are affected by episodic recharge from an ephemeral surface-water source and by the fracture-flow dominated hydrologic regime in the ESRP aquifer. The spatially focused sampling effort has also identified a low-level 129 I plume that affects long-term water quality near and downgradient from the Advanced Test Reactor Complex in the southwestern part of the facility that had not been clearly defined in previous sampling efforts, although the definition of the plume is somewhat limited by available data.

Idaho

Bathymetric contour maps, surface area and capacity tables, and bathymetric change maps for selected water-supply lakes in Missouri, 2022–23

Bathymetric data were collected at 13 water-supply lakes around the periphery of Missouri by the U.S. Geological Survey in cooperation with the Missouri Department of Natural Resources and various local agencies, as part of a multiyear effort to establish or update the surface area and capacity tables for the surveyed lakes. Surveys were carried out during the months of April and May in 2022 and 2023. All but two of the lakes had been surveyed previously by the U.S. Geological Survey, and the recent surveys were compared to the earlier surveys to document the changes in the bathymetric surface and capacity of the lake. Bathymetric data were collected using a high-resolution multibeam mapping system mounted on a boat. Supplemental depth data at three of the lakes were collected in shallow areas with an acoustic Doppler current profiler on a remote-controlled boat. Data points from the various sources were exported at a gridded data resolution appropriate to each lake, either 0.82 foot, 1.64 feet, or 3.28 feet. Data outside the multibeam survey extent and greater than the surveyed water-surface elevation were obtained from data collected using aerial light detection and ranging (lidar) point cloud data. A linear enforcement technique was used to add points to the dataset in areas of sparse data (the upper ends of coves where the water was shallow or aquatic vegetation precluded data acquisition) based on surrounding multibeam and upland data values. The various point datasets were used to produce a three-dimensional triangulated irregular network surface of the lake-bottom elevations for each lake. A surface area and capacity table was produced from the three-dimensional surface for each lake showing surface area and capacity at specified lake water-surface elevations. Various quality-assurance tests were conducted to ensure quality data were collected with the multibeam, including beam angle checks and patch tests. Additional quality-assurance tests were conducted on the gridded bathymetric data from the survey, the bathymetric surface created from the gridded data, and the contours created from the bathymetric survey.

Missouri

Peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. This work is part of that reexamination. The stationarity assumption is a concern because flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done to assess potential nonstationarity in peak flows in the north-central United States. This report summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Scientific Investigations Report

Recycling radiogenic osmium by crustal foundering in subduction zones: Evidence from pyroxenite xenoliths in the north Andean arc

Removal of mafic-ultramafic lower crust (e.g., via delamination) is fundamental to making andesitic continental crust, yet direct evidence of this process remains elusive. A unique suite of garnet clinopyroxenite and hornblendite (arclogite) xenoliths from the northern volcanic zone of the Andes, erupted to the surface in the mid-Pleistocene, have bulk-rock geochemistry and osmium (Os) isotopic compositions that demonstrate their crustal affinity, yet have equilibration pressures and temperatures below the arc Mohorovičić discontinuity (~53 km) and some as deep as within the sub-arc mantle wedge (~105 km). Garnet websterites from the same xenolith suite, sourced from depths approaching the Wadati-Benioff zone (~140 km), have elemental and isotopic compositions indicative of a mantle origin, likely formed as products of peridotite-liquid reactions above the subducting slab. Variability in bulk-rock 143 Nd/ 144 Nd values and garnet oxygen isotope ratios ( 𝛿 18 O) for these samples is attributed to minor assimilation of subducted components and/or older crustal material, but assimilation alone cannot account for the highly radiogenic Os isotopic compositions. These results provide direct petrologic evidence for modern arclogite formation and foundering in the Andean orogen, the archetypal active continental subduction system. Elevated 187 Os/ 188 Os values of Mercaderes arclogites imply that recycling of gravitationally unstable arc cumulates during continental crust formation introduces highly radiogenic Os into the convective mantle, which has implications for mass fluxes across the crust-mantle boundary as well as the sources and evolution of mantle heterogeneity as seen in orogenic peridotite massifs and in the sources of oceanic basalts

Earth and Planetary Science Letters

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper

Simulation of groundwater flow in the Silurian aquifer, eastern Iowa, 2020–45

The Silurian aquifer is an important water source for municipalities, industry, and rural households and communities in eastern Iowa, including Johnson County. Increasing demand for groundwater from the aquifer indicated that analytical tools may be beneficial to quantify groundwater resources and inform water-management decisions for the aquifer. The U.S. Geological Survey, in cooperation with the Johnson County Board of Supervisors, developed conceptual and numerical groundwater models to simulate water levels in the Silurian aquifer, determine groundwater budgets, and forecast changes in groundwater levels through 2045. A MODFLOW numerical model was constructed to match water levels for 2020 through 2022. Model performance was assessed by comparing simulated and observed water-level hydrographs at several pumping and monitoring wells. Hydrograph comparison indicates that the model simulates water levels accurately at monitoring wells that are not near areas of pumping and generally overpredicts water levels near pumping wells, while accurately simulating the drawdown trend over time at pumping wells. This transient model framework was then used to predict water levels through 2045 in a scenario of moderate drought and increased groundwater withdrawals. Results from the predictive model indicate as much as 13 meters of additional drawdown in 2045 from 2020 water levels in the area of pumping wells.

Iowa

Application of Hydrologic Simulation Program—FORTRAN (HSPF) as part of an integrated hydrologic model for the Salinas Valley, California

The U.S. Geological Survey (USGS), in cooperation with the Monterey County Water Resources Agency, conducted studies to help evaluate the surface-water and groundwater resources of the Salinas Valley study area, consisting of the entire Salinas River watershed and several smaller, adjacent coastal watersheds draining into Monterey Bay. The Salinas Valley study area is a highly productive agricultural region that depends on the coordinated use of surface water and groundwater to meet demand for irrigation and public water supply. To continue to meet these demands, a better understanding of the historical water balance and the effects of water-resource development on the long-term sustainability of water resources in the Salinas Valley study area is needed.

California

The Long Island Sound and Watershed Metadata map application

The Long Island Sound and its watershed encompass an area of about 17,000 square miles and include the Connecticut, Housatonic, and Thames Rivers, which all drain to the sound. Dozens of organizations from government agencies, nonprofits, and Tribal Nations have developed projects and monitoring programs to analyze and protect the water resources of the watershed and sound. The abundance of data and lack of an existing searchable index require a centralized metadata repository to allow users to find water resources data more efficiently. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Long Island Sound Study, has created an interactive map application to visualize and search for metadata information across organizations working to monitor and protect the Long Island Sound.

Connecticut, Massachusetts, New Hampshire, New Yor

Streamflow, base-flow, and precipitation trends and simulated effects of groundwater withdrawals from the North Fork Red River aquifer on base flows upgradient from Lake Altus, western Oklahoma, 1980–2022

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used five scenarios created from a previously published numerical groundwater-flow model (1980–2013) and historical streamflow records (1980–2022) to investigate the relation between groundwater withdrawals from the North Fork Red River aquifer and inflows to Lake Altus from the North Fork Red River in western Oklahoma. The five scenarios were (1) a scaled-equal-proportionate-share (EPS) groundwater-withdrawal scenario, (2) a study-area-scaled-reported groundwater-withdrawal scenario, (3) a zonal-scaled-reported groundwater-withdrawal scenario, (4) a historical drought-threshold scenario, and (5) a base-flow and evapotranspiration depletion scenario. For the scaled-EPS groundwater-withdrawal scenario, EPS groundwater withdrawals were often much higher than reported groundwater withdrawals and greatly decreased base flows for most scale factors. For the study-area-scaled-reported groundwater-withdrawal scenario, base flows were reduced more but by smaller percentages during wet periods than during dry periods when scaling simulated reported groundwater withdrawals. For the zonal-scaled-reported groundwater-withdrawal scenario, scaling simulated reported groundwater withdrawals within selected zones with more groundwater withdrawals did not always affect base flows more than scaling reported groundwater withdrawals within zones with less groundwater withdrawals. For the historical drought-threshold scenario, curtailing groundwater withdrawals at the drought thresholds increased annual base flows to Lake Altus by about 1,169 to 3,665 acre-feet. For the base-flow and evapotranspiration depletion scenario, the distance between a groundwater well and a stream was a major factor affecting base flow to the North Fork Red River when increasing groundwater withdrawals; however, spatially variable hydrologic properties and saturated-zone evapotranspiration could also affect the relation between base flows and groundwater withdrawals.

Oklahoma

Water-resources inventory and assessment at Katahdin Woods and Waters National Monument

The U.S. Geological Survey, in cooperation with the National Park Service, prepared a water-resources inventory and assessment for Katahdin Woods and Waters National Monument (KAWW). This compilation includes published and publicly accessible hydrologic data and resource assessments of streams, rivers, ponds, lakes, wetlands, vernal pools, and groundwater in and near KAWW. It also includes reports and datasets summarizing attributes of KAWW’s hydrologic infrastructure, such as stream crossings, dams, wastewater discharge plants, groundwater monitoring wells, and U.S. Geological Survey streamflow-gaging stations. Descriptions of data and details of current limitations in available datasets are included. Wetland, groundwater, streamflow, and water-quality information are all limited. Hydrography data are available; however, there are limited ground-truth data. Accurate streamlines within KAWW were developed from light detection and ranging (lidar) as a part of this work. Hydrologic infrastructure information is available from multiple sources; however, differences exist among the datasets. Datasets are summarized in appendix 1.

Maine

Nitrogen deposition weakens soil carbon control of nitrogen dynamics across the contiguous United States

Anthropogenic nitrogen (N) deposition is unequally distributed across space and time, with inputs to terrestrial ecosystems impacted by industry regulations and variations in human activity. Soil carbon (C) content normally controls the fraction of mineralized N that is nitrified ( ƒ nitrified ), affecting N bioavailability for plants and microbes. However, it is unknown whether N deposition has modified the relationships among soil C, net N mineralization, and net nitrification. To test whether N deposition alters the relationship between soil C and net N transformations, we collected soils from coniferous and deciduous forests, grasslands, and residential yards in 14 regions across the contiguous United States that vary in N deposition rates. We quantified rates of net nitrification and N mineralization, soil chemistry (soil C, N, and pH), and microbial biomass and function (as beta-glucosidase (BG) and N -acetylglucosaminidase (NAG) activity) across these regions. Following expectations, soil C was a driver of ƒ nitrified across regions, whereby increasing soil C resulted in a decline in net nitrification and ƒ nitrified . The ƒ nitrified value increased with lower microbial enzymatic investment in N acquisition (increasing BG:NAG ratio) and lower active microbial biomass, providing some evidence that heterotrophic microbial N demand controls the ammonium pool for nitrifiers. However, higher total N deposition increased ƒ nitrified , including for high soil C sites predicted to have low ƒ nitrified , which decreased the role of soil C as a predictor of ƒ nitrified . Notably, the drop in contemporary atmospheric N deposition rates during the 2020 COVID-19 pandemic did not weaken the effect of N deposition on relationships between soil C and ƒ nitrified . Our results suggest that N deposition can disrupt the relationship between soil C and net N transformations, with this change potentially explained by weaker microbial competition for N. Therefore, past N inputs and soil C should be used together to predict N dynamics across terrestrial ecosystems.

contiguous United States

Estimating the importance of floating surface material to the total phosphorus transport in Silver Creek, Wisconsin using Particle Image Velocimetry

Various techniques are used to estimate nutrient delivery in streams that combine flow and water-quality data. However, the transport of surface floating material is difficult to measure, and is therefore typically neglected when stream sampling and in the estimated nutrient delivery. Here, we describe an approach to estimate the amount of material (duckweed ( Lemna genus), filamentous algae, and other macrophyte fragments) and associated nutrients (in this case, phosphorus, P) transported on the surface of Silver Creek, Wisconsin, to determine if this material is an important transport mechanism and if historical P loads were underestimated. This approach includes estimating the transport of surface material using 10 s videos collected every 15 min from a downward-looking camera installed beneath a bridge. The average velocity of the surface material was first determined using Large-Scale Particle Image Velocimetry (LSPIV), which uses short videos to analyze surface particle movement. The amount of surface material in each video was then computed using computer-vision techniques. The P load associated with the transported surface material was then estimated by combining surface velocities, coverage of floating material, and laboratory-measured P content. Surface material transported ~9–11% of the total summer P load and ~4–7% of the annual load in Silver Creek.

Wisconsin

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California

A high-resolution 3-D P-wave velocity structure of the south-central Cascadia subduction zone from wide-angle shore-crossing seismic refraction data

This study addresses a significant gap in understanding the features of the south-central Cascadia subduction zone, a region characterized by complex geologic, tectonic, and seismic transitions both offshore and onshore. Unlike other segments along this margin, this area lacks a 3-D velocity model to delineate its structural and geological features on a fine scale. To address this void, we developed a high-resolution 3-D P-wave velocity model using active source seismic data from ship-borne seismic shots recorded on temporary and permanent onshore seismic stations and ocean-bottom seismometers. Our model shows velocity variations across the region with distinct velocity-depth profiles for the Siletz, Franciscan, and Klamath terranes in the overlying plate. We identified seaward dipping high-velocity static backstops associated with the Siletz and Klamath terranes, situated near the shoreline and further inland, respectively. Regions of reduced crustal velocity are associated with crustal faults. Moreover, there is significant along-strike depth variation in the subducting slab, which is about 4 km deeper near the thick, dense Siletz terrane and becomes shallower near the predominantly less-dense Franciscan terrane. This highlights a sudden tectonic and geologic transition at the southern boundary of the Siletz terrane. Our velocity model also indicates slightly increased hydration, though still minimal, in both the oceanic crust and the upper mantle of the subducting plate compared to other parts of the margin.

British Columbia, California, Oregon, Washington

Probabilistic assessment of postfire debris-flow inundation in response to forecast rainfall

Communities downstream of burned steep lands face increases in debris-flow hazards due to fire effects on soil and vegetation. Rapid postfire hazard assessments have traditionally focused on quantifying spatial variations in debris-flow likelihood and volume in response to design rainstorms. However, a methodology that provides estimates of debris-flow inundation downstream of burned areas based on forecast rainfall would provide decision-makers with information that directly addresses the potential for downstream impacts. We introduce a framework that integrates a 24 h lead-time ensemble precipitation forecast with debris-flow likelihood, volume, and runout models to produce probabilistic maps of debris-flow inundation. We applied this framework to simulate debris-flow inundation associated with the 9 January 2018 debris-flow event in Montecito, California, USA. When the observed debris-flow volumes were used to drive the probabilistic forecast model, analysis of the simulated inundation probabilities demonstrates that the model is both reliable and sharp. In the fully predictive model, however, in which debris-flow likelihood and volume were computed from the atmospheric model ensemble's predictions of peak 15 min rainfall intensity, I 15 , the model generally under-forecasted the inundation area. The observed peak I 15 lies in the upper tail of the atmospheric model ensemble spread; thus a large fraction of ensemble members forecast lower I 15 than observed. Using these I 15 values as input to the inundation model resulted in lower-than-observed flow volumes which translated into under-forecasting of the inundation area. Even so, approximately 94 % of the observed inundated area was forecast to have an inundation probability greater than 1 %, demonstrating that the observed extent of inundation was generally captured within the range of outcomes predicted by the model. Sensitivity analyses indicate that debris-flow volume and two parameters associated with debris-flow mobility exert significant influence on inundation predictions, but reducing uncertainty in postfire debris-flow volume predictions will have the largest impact on reducing inundation outcome uncertainty. This study represents a first step toward a near-real-time hazard assessment product that includes probabilistic estimates of debris-flow inundation and provides guidance for future improvements to this and similar model frameworks by identifying key sources of uncertainty.

California

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida