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Strontium 87/strontium 86 as a tracer of mineral weathering reactions and calcium sources in an alpine/subalpine watershed, Loch Vale, Colorado

Sr isotopic ratios of atmospheric deposition, surface and subsurface water, and geologic materials were measured in an alpine/subalpine watershed to characterize weathering reactions and identify sources of dissolved Ca in stream water. Previous studies have noted an excess of Ca in stream water above that expected from stoichiometric weathering of the dominant bedrock minerals. Mixing calculations based on 87 Sr/ 86 Sr indicate that on an annual basis, 26 ± 7% of Ca export in streams is atmospherically derived, 23 ± 1% is from weathering of plagioclase, and the remainder is from weathering of calcite present in trace amounts in the bedrock. A potential source of error when applying Sr isotopes in catchment studies is determination of the 87 Sr/ 86 Sr of Sr released by mineral weathering, which is complicated by the wide range of mineral isotopic compositions, particularly in older rocks, and the variable rates at which the minerals weather. In this study, base-flow stream chemistry was used to represent the 87 Sr/ 86 Sr of Sr derived from mineral weathering because it effectively integrates the potentially variable isotopic composition of Sr released by weathering in the alpine environment.

Colorado↗

Methane hydrates and global climate

Methane hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. The amount of methane sequestered in gas hydrates is probably enormous, but estimates of the amounts are speculative and range over three orders of magnitude (about 10 3 to 10 6 GT (gigatons = 10 15 g)). A question of current interest concerns the possible consequences of an addition of methane to the atmosphere from destabilized methane hydrates due to global warming. Models of greenhouse warming predict that climatic change will be greatest in the Arctic. Thus, if methane from destabilized gas hydrates contributes to greenhouse warming, this destabilization will most likely take place first in the Arctic, particularly in the shallow nearshore regions of the Arctic Ocean where offshore permafrost is found. The process of permafrost warming and release of methane from gas hydrates may already be in progress, but the amount being released now and to be released in the 21st century is probably small. The positive feedback of this atmospheric methane on global climates will likely be minimal.

Global Biogeochemical Cycles↗

Television observations from Surveyor 3

A total of 6315 pictures were taken by the television camera on Surveyor 3 after the lunar landing. These pictures have provided much new information about the location of the landing site on the moon, the detailed topographic and geologic characteristics of the lunar surface, and the appearance of the earth as seen from the moon, both during eclipse of the sun and during partial direct illumination by the sun. Surveyor 3 landed in a subdued crater slightly more than 200 meters in diameter, which has a low rounded rim and is about 15 meters deep. The spacecraft is situated on the east wall of the crater, about half way between the center of the crater and the rim crest. The spacecraft is inclined 14.7° ± 1.0° toward the west. The selenographic coordinates of the landing site are 2.94°S latitude, 23.34°W longitude, relative to selenodetic control adopted by the Aeronautical Chart and Information Center. Small morphologic elements of the landing site include small craters, linear ridges and troughs, and fragmental debris. The craters and fragmental debris resemble those observed at the Surveyor 1 landing site, both in distribution of shape and in distribution of size. Most of the craters in Surveyor 1 and 3 pictures are inferred to be of impact origin. Their size-frequency distribution corresponds to the distribution that would be produced by repetitive bombardment by meteoroids, a bombardment sufficiently prolonged that the crater population has reached a steady state or has come to equilibrium. Some of the craters observed at the Surveyor 3 landing site are inferred to be of secondary impact origin, and some probably have been formed either by subsidence or by drainage of fragmental debris into cracks or fissures in the subsurface. Fragmental debris at the landing site is inferred to have been derived primarily by the same process of repetitive bombardment that produced the majority of craters. The inferred volumetric size-frequency distribution of fragments, derived from the observed size distribution of fragments on the surface, is similar to the distribution that would be produced by repetitive bombardment of coherent rocks by meteoroids with a mass-frequency distribution like that found from observed meteors and recovered meteorites on earth. Two prominent strewn fields of blocky debris were observed around two craters, 13 and 15 meters across, at the Surveyor 3 site. The 13-meter crater has a sharp raised rim, and the 15-meter crater has a more subdued rounded rim. The blocks associated with the subdued crater have twice as high a mean roundness as the blocks associated with the raised-rim crater, and they are much more deeply buried. The size-frequency distribution function for the fragments in each of the strewn fields of blocks resembles the size-frequency distribution for fragments ejected by impacts in strong rock, such as Meteor Crater, Arizona. Most of the fragments at the surface of the Surveyor 3 landing site are evidently part of a layer of fragmental material of low cohesion that is at least 1 meter thick along the upper parts of the wall of the crater in which Surveyor 3 landed and may be much thicker near the center of the crater. The evidence from the Surveyor 3 pictures suggests that this layer of debris, or regolith, is subject to downslope creep or mass movement. Creep is probably caused by seismic shaking, due mainly to near and far impact events and perhaps due partly to internal lunar seismicity. Disturbances of the lunar surface produced by Surveyor 3, like those produced by Surveyor 1, exposed material at depths of a few centimeters or less that was darker than the material at the surface. The albedo of the fine-grained fragmental debris is probably 20 to 30% lower at depths of only a fraction of a millimeter than it is at the optically observed surface. All coarse fragments protruding above the general level of the surface have a higher albedo than the fine-grained matrix of the surface. These general photometric relationships can be explained if it is assumed that the surfaces of the particles in the shallow lunar subsurface tend to become coated with a dark substance; the term proposed for this hypothetical substance is ‘lunar varnish’ On the protruding surface of blocks and coarse fragments the lunar varnish is scrubbed off by the processes that cause rounding. The exposed surfaces of fine particles on the lunar surface are similarly affected, but, because they are mixed relatively rapidly with particles just beneath the surface, the process is incomplete and the fine-grained material exposed at the lunar surface, therefore, has a lower albedo than blocks and other large fragments. Coating of particles by lunar varnish evidently takes place just beneath the surface. The estimated normal luminance factor (normal albedo) of an undisturbed part of the lunar surface next to footpad 2 of the Surveyor 3 spacecraft is 8.5%. An area of the lunar surface disturbed by the surface sampler has an estimated normal luminance factor of 6.6%, and fine-grained material placed on footpad 2 by the surface sampler has an estimated normal luminance factor of 7.6%. The errors in all these estimates may be as high as 25% because of uncertainties of correction required for light scattered from the camera mirror. Preliminary search for color differences, by color reconstitution methods, revealed no determinable differences in color among various coarse blocks, the fine-grained matrix of the surface, or fine-grained material disturbed by the surface sampler. Surveyor 3 pictures of the eclipse of the sun by the earth revealed a bright region in the refraction halo surrounding the earth, which was correlated with the position of the sun, and a series of bright beads that occurred over regions of the earth largely clear of clouds. Clouds tend to occult the refracted rays of the sun, most of which pass through the lower part of the atmosphere at the limb; the beads occurred in the depressions in the optical silhouette of the earth. Preliminary reduction of the color of the refracted light showed that the brightest region, near the position of the sun, exhibited a correlated color temperature close to 4800°K. The color temperature tended to be lower for light that followed paths of greater atmospheric absorption. Preliminary analysis of Surveyor 3 pictures of the partly illuminated earth revealed colors similar to the colors recorded from orbit by the Mercury and Gemini astronauts.

Journal of Geophysical Research↗

Origin and distribution of carbon dioxide in the unsaturated zone of the southern High Plains of Texas

Partial pressures of CO 2 , O 2 , N 2 , and Ar were monitored at two locations in the Ogallala aquifer system on the Southern High Plains of Texas. Samples were collected monthly during parts of 1980–1981 from nine depths ranging from 0.6 to 36 meters below land surface. P CO 2 was observed to be greater at depth than in the active soil zone and thus appears to contradict the normal process in which CO 2 is generated in the soil zone and diffuses upward to the atmosphere and downward to the water table. The δ 13 C of the CO 2 gas was quite uniform and averaged −17.9 per mil. P O 2 declined with depth, suggesting in situ generation of CO 2 by the oxidation of carbon. Several hypotheses were considered to explain the origin of the CO 2 at depth. It was concluded that the most probable hypothesis was that dissolved and particulate organic carbon introduced by recharging water was oxidized to CO 2 by the aerobic microbial community that utilized oxygen diffusing in from the atmosphere. This hypothesis is consistent with the CO 2 concentration profile, calculated production profile of CO 2 , δ 13 C values of CO 2 gas, caliche, soil humic acid fraction, and dissolved carbonate in groundwater. The abundance of CO 2 , its concentration profile, and its probable origin provide information for evaluating the observed complex sequence of caliche dissolution and precipitation known to occur in the aquifer.

Texas↗

Possible precipitation of ice at low latitudes of Mars during periods of high obliquity

Most of the old cratered highlands of Mars are dissected by branching river valleys that appear to have been cut by running water1,2 yet liquid water is unstable everywhere on the martian surface. In the equatorial region, where most of the valleys are observed, even ice is unstable3,4. It has been suggested, therefore, that Mars had an early denser atmosphere with sufficient greenhouse warming to allow the existence of liquid water 5. Here, we suggest instead that during periods of very high obliquities, ice could accumulate at low latitudes as a result of sustained sublimation of ice from the poles and transport of the water vapour equatorwards. At low latitudes, the water vapour would saturate the atmosphere and condense onto the surface where it would accumulate until lower obliquities prevailed. The mechanism is efficient only at the very high obliquities that occurred before formation of Tharsis very early in the planet's history, but limited equatorial ice accumulation could also have occurred at the highest obliquities during the rest of the planet's history. Partial melting of the ice could have provided runoff to form the channels or replenish the groundwater system. ?? 1985 Nature Publishing Group.

Nature↗

Water on Mars

Estimates of the amount of water outgassed from Mars, based on the composition of the atmosphere, range from 6 to 160 m, as compared with 3 km for the Earth. In contrast, large flood features, valley networks, and several indicators of ground ice suggest that at least 500 m of water have outgassed. The two sets of estimates may be reconciled if early in its history, Mars lost part of its atmosphere by impact erosion and hydrodynamic escape.

Nature↗

Permafrost collapse is accelerating carbon release

This much is clear: the Arctic is warming fast, and frozen soils are starting to thaw, often for the first time in thousands of years. But how this happens is as murky as the mud that oozes from permafrost when ice melts. As the temperature of the ground rises above freezing, microorganisms break down organic matter in the soil. Greenhouse gases — including carbon dioxide, methane and nitrous oxide — are released into the atmosphere, accelerating global warming. Soils in the permafrost region hold twice as much carbon as the atmosphere does — almost 1,600 billion tonnes 1 . What fraction of that will decompose? Will it be released suddenly, or seep out slowly? We need to find out. Current models of greenhouse-gas release and climate assume that permafrost thaws gradually from the surface downwards. Deeper layers of organic matter are exposed over decades or even centuries, and some models are beginning to track these slow changes. But models are ignoring an even more troubling problem. Frozen soil doesn’t just lock up carbon — it physically holds the landscape together. Across the Arctic and Boreal regions, permafrost is collapsing suddenly as pockets of ice within it melt. Instead of a few centimetres of soil thawing each year, several metres of soil can become destabilized within days or weeks. The land can sink and be inundated by swelling lakes and wetlands. Abrupt thawing of permafrost is dramatic to watch. Returning to field sites in Alaska, for example, we often find that lands that were forested a year ago are now covered with lakes 2 . Rivers that once ran clear are thick with sediment. Hillsides can liquefy, sometimes taking sensitive scientific equipment with them. This type of thawing is a serious problem for communities living around the Arctic (see ‘Arctic permafrost’). Roads buckle, houses become unstable. Access to traditional foods is changing, because it is becoming dangerous to travel across the land to hunt. Families cannot reach lines of game traps that have supported them for generations.

Nature↗

Diversity of active aerobic methanotrophs along depth profiles of arctic and subarctic lake water column and sediments

Methane (CH 4 ) emitted from high-latitude lakes accounts for 2–6% of the global atmospheric CH 4 budget. Methanotrophs in lake sediments and water columns mitigate the amount of CH 4 that enters the atmosphere, yet their identity and activity in arctic and subarctic lakes are poorly understood. We used stable isotope probing (SIP), quantitative PCR (Q-PCR), pyrosequencing and enrichment cultures to determine the identity and diversity of active aerobic methanotrophs in the water columns and sediments (0–25 cm) from an arctic tundra lake (Lake Qalluuraq) on the north slope of Alaska and a subarctic taiga lake (Lake Killarney) in Alaska's interior. The water column CH 4 oxidation potential for these shallow (~2m deep) lakes was greatest in hypoxic bottom water from the subarctic lake. The type II methanotroph, Methylocystis, was prevalent in enrichment cultures of planktonic methanotrophs from the water columns. In the sediments, type I methanotrophs (Methylobacter, Methylosoma and Methylomonas) at the sediment-water interface (0–1 cm) were most active in assimilating CH 4 , whereas the type I methanotroph Methylobacter and/or type II methanotroph Methylocystis contributed substantially to carbon acquisition in the deeper (15–20 cm) sediments. In addition to methanotrophs, an unexpectedly high abundance of methylotrophs also actively utilized CH 4 -derived carbon. This study provides new insight into the identity and activity of methanotrophs in the sediments and water from high-latitude lakes.

Alaska↗

Rain, winds and haze during the Huygens probe's descent to Titan's surface

The irreversible conversion of methane into higher hydrocarbons in Titan's stratosphere implies a surface or subsurface methane reservoir. Recent measurements from the cameras aboard the Cassini orbiter fail to see a global reservoir, but the methane and smog in Titan's atmosphere impedes the search for hydrocarbons on the surface. Here we report spectra and high-resolution images obtained by the Huygens Probe Descent Imager/Spectral Radiometer instrument in Titan's atmosphere. Although these images do not show liquid hydrocarbon pools on the surface, they do reveal the traces of once flowing liquid. Surprisingly like Earth, the brighter highland regions show complex systems draining into flat, dark lowlands. Images taken after landing are of a dry riverbed. The infrared reflectance spectrum measured for the surface is unlike any other in the Solar System; there is a red slope in the optical range that is consistent with an organic material such as tholins, and absorption from water ice is seen. However, a blue slope in the near-infrared suggests another, unknown constituent. The number density of haze particles increases by a factor of just a few from an altitude of 150 km to the surface, with no clear space below the tropopause. The methane relative humidity near the surface is 50 per cent.

Nature↗

Global circulation as the main source of cloud activity on Titan

Clouds on Titan result from the condensation of methane and ethane and, as on other planets, are primarily structured by circulation of the atmosphere. At present, cloud activity mainly occurs in the southern (summer) hemisphere, arising near the pole and at mid-latitudes from cumulus updrafts triggered by surface heating and/or local methane sources, and at the north (winter) pole, resulting from the subsidence and condensation of ethane-rich air into the colder troposphere. General circulation models predict that this distribution should change with the seasons on a 15-year timescale, and that clouds should develop under certain circumstances at temperate latitudes (40??) in the winter hemisphere. The models, however, have hitherto been poorly constrained and their long-term predictions have not yet been observationally verified. Here we report that the global spatial cloud coverage on Titan is in general agreement with the models, confirming that cloud activity is mainly controlled by the global circulation. The non-detection of clouds at latitude 40??N and the persistence of the southern clouds while the southern summer is ending are, however, both contrary to predictions. This suggests that Titans equator-to-pole thermal contrast is overestimated in the models and that its atmosphere responds to the seasonal forcing with a greater inertia than expected. ?? 2009 Macmillan Publishers Limited. All rights reserved.

Nature↗

A shift of thermokarst lakes from carbon sources to sinks during the Holocene epoch

Thermokarst lakes formed across vast regions of Siberia and Alaska during the last deglaciation and are thought to be a net source of atmospheric methane and carbon dioxide during the Holocene epoch 1,2,3,4 . However, the same thermokarst lakes can also sequester carbon 5 , and it remains uncertain whether carbon uptake by thermokarst lakes can offset their greenhouse gas emissions. Here we use field observations of Siberian permafrost exposures, radiocarbon dating and spatial analyses to quantify Holocene carbon stocks and fluxes in lake sediments overlying thawed Pleistocene-aged permafrost. We find that carbon accumulation in deep thermokarst-lake sediments since the last deglaciation is about 1.6 times larger than the mass of Pleistocene-aged permafrost carbon released as greenhouse gases when the lakes first formed. Although methane and carbon dioxide emissions following thaw lead to immediate radiative warming, carbon uptake in peat-rich sediments occurs over millennial timescales. We assess thermokarst-lake carbon feedbacks to climate with an atmospheric perturbation model and find that thermokarst basins switched from a net radiative warming to a net cooling climate effect about 5,000   years ago. High rates of Holocene carbon accumulation in 20 lake sediments (47±10 grams of carbon per square metre per year; mean±standard error) were driven by thermokarst erosion and deposition of terrestrial organic matter, by nutrient release from thawing permafrost that stimulated lake productivity and by slow decomposition in cold, anoxic lake bottoms. When lakes eventually drained, permafrost formation rapidly sequestered sediment carbon. Our estimate of about 160petagrams of Holocene organic carbon in deep lake basins of Siberia and Alaska increases the circumpolar peat carbon pool estimate for permafrost regions by over 50 per cent (ref. 6). The carbon in perennially frozen drained lake sediments may become vulnerable to mineralization as permafrost disappears 7,8,9 , potentially negating the climate stabilization provided by thermokarst lakes during the late Holocene.

Nature↗

The impact of lower sea-ice extent on Arctic greenhouse-gas exchange

In September 2012, Arctic sea-ice extent plummeted to a new record low: two times lower than the 1979–2000 average. Often, record lows in sea-ice cover are hailed as an example of climate change impacts in the Arctic. Less apparent, however, are the implications of reduced sea-ice cover in the Arctic Ocean for marine–atmosphere CO 2 exchange. Sea-ice decline has been connected to increasing air temperatures at high latitudes. Temperature is a key controlling factor in the terrestrial exchange of CO 2 and methane, and therefore the greenhouse-gas balance of the Arctic. Despite the large potential for feedbacks, many studies do not connect the diminishing sea-ice extent with changes in the interaction of the marine and terrestrial Arctic with the atmosphere. In this Review, we assess how current understanding of the Arctic Ocean and high-latitude ecosystems can be used to predict the impact of a lower sea-ice cover on Arctic greenhouse-gas exchange.

Nature Climate Change↗

Potential evapotranspiration and continental drying

By various measures (drought area and intensity , climatic aridity index , and climatic water deficits ), some observational analyses have suggested that much of the Earth ’ s land has been drying during recent decades, but such drying seems inconsistent with observations of dryland greening and decreasing pan evaporation . ‘Offline ’ analyses of climate-model outputs from anthropogenic climate change (ACC) experiments portend continuation of putative drying through the twenty-first century , despite an expected increase in global land precipitation . A ubiquitous increase in estimates of potential evapotranspiration (PET), driven by atmospheric warming , underlies the drying trends , but may be a methodological artefact . Here we show that the PET estimator commonly used (the Penman–Monteith PET for either an open-water surface or a reference crop ) severely overpredicts the changes in non-water-stressed evapotranspiration computed in the climate models themselves in ACC experiments. This overprediction is partially due to neglect of stomatal conductance reductions commonly induced by increasing atmospheric CO 2 concentrations in climate models . Our findings imply that historical and future tendencies towards continental drying, as characterized by offline-computed runoff, as well as other PET-dependent metrics, may be considerably weaker and less extensive than previously thought.

Nature Climate Change↗

Global and Arctic climate sensitivity enhanced by changes in North Pacific heat flux

Arctic amplification is a consequence of surface albedo, cloud, and temperature feedbacks, as well as poleward oceanic and atmospheric heat transport. However, the relative impact of changes in sea surface temperature (SST) patterns and ocean heat flux sourced from different regions on Arctic temperatures are not well constrained. We modify ocean-to-atmosphere heat fluxes in the North Pacific and North Atlantic in a climate model to determine the sensitivity of Arctic temperatures to zonal heterogeneities in northern hemisphere SST patterns. Both positive and negative ocean heat flux perturbations from the North Pacific result in greater global and Arctic surface air temperature anomalies than equivalent magnitude perturbations from the North Atlantic; a response we primarily attribute to greater moisture flux from the subpolar extratropics to Arctic. Enhanced poleward latent heat and moisture transport drive sea-ice retreat and low-cloud formation in the Arctic, amplifying Arctic surface warming through the ice-albedo feedback and infrared warming effect of low clouds. Our results imply that global climate sensitivity may be dependent on patterns of ocean heat flux in the northern hemisphere.

Nature Communications↗

Continental-scale analysis of shallow and deep groundwater contributions to streams

Groundwater discharge generates streamflow and influences stream thermal regimes. However, the water quality and thermal buffering capacity of groundwater depends on the aquifer source-depth. Here, we pair multi-year air and stream temperature signals to categorize 1729 sites across the continental United States as having major dam influence, shallow or deep groundwater signatures, or lack of pronounced groundwater (atmospheric) signatures. Approximately 40% of non-dam stream sites have substantial groundwater contributions as indicated by characteristic paired air and stream temperature signal metrics. Streams with shallow groundwater signatures account for half of all groundwater signature sites and show reduced baseflow and a higher proportion of warming trends compared to sites with deep groundwater signatures. These findings align with theory that shallow groundwater is more vulnerable to temperature increase and depletion. Streams with atmospheric signatures tend to drain watersheds with low slope and greater human disturbance, indicating reduced stream-groundwater connectivity in populated valley settings.

Nature Communications↗

Boreal conifers maintain carbon uptake with warming despite failure to track optimal temperatures

Warming shifts the thermal optimum of net photosynthesis ( T optA ) to higher temperatures. However, our knowledge of this shift is mainly derived from seedlings grown in greenhouses under ambient atmospheric carbon dioxide (CO 2 ) conditions. It is unclear whether shifts in T optA of field-grown trees will keep pace with the temperatures predicted for the 21 st century under elevated atmospheric CO 2 concentrations. Here, using a whole-ecosystem warming controlled experiment under either ambient or elevated CO 2 levels, we show that T optA of mature boreal conifers increased with warming. However, shifts in T optA did not keep pace with warming as T optA only increased by 0.26–0.35 °C per 1 °C of warming. Net photosynthetic rates estimated at the mean growth temperature increased with warming in elevated CO 2 spruce, while remaining constant in ambient CO 2 spruce and in both ambient CO 2 and elevated CO 2 tamarack with warming. Although shifts in T optA of these two species are insufficient to keep pace with warming, these boreal conifers can thermally acclimate photosynthesis to maintain carbon uptake in future air temperatures.

Nature Communciations↗

Nanoscale silicate melt textures determine volcanic ash surface chemistry

Explosive volcanic eruptions produce vast quantities of silicate ash, whose surfaces are subsequently altered during atmospheric transit. These altered surfaces mediate environmental interactions, including atmospheric ice nucleation, and toxic effects in biota. A lack of knowledge of the initial, pre-altered ash surface has required previous studies to assume that the ash surface composition created during magmatic fragmentation is equivalent to the bulk particle assemblage. Here we examine ash particles generated by controlled fragmentation of andesite and find that fragmentation generates ash particles with substantial differences in surface chemistry. We attribute this disparity to observations of nanoscale melt heterogeneities, in which Fe-rich nanophases in the magmatic melt deflect and blunt fractures, thereby focusing fracture propagation within aureoles of single-phase melt formed during diffusion-limited growth of crystals. In this manner, we argue that commonly observed pre-eruptive microtextures caused by disequilibrium crystallisation and/or melt unmixing can modify fracture propagation and generate primary discrepancies in ash surface chemistry, an essential consideration for understanding the cascading consequences of reactive ash surfaces in various environments.

Nature Communications↗

Isotopic evidence against North Pacific Deep Water formation during late Pliocene warmth

Several modelling and observational studies suggest deep water formation in the subpolar North Pacific as a possible alternative mode of thermohaline circulation that occurred in the warm Pliocene, a time when global atmospheric partial pressure of carbon dioxide was like the modern atmosphere (~400 ppm). We test this hypothesis by measuring the δ 13 C of the benthic foraminifer Cibicidoides wuellerstorfi collected from northernmost Pacific mid-Piacenzian Warm Period (3.264–3.025 Myr ago) sediments. The data reveal progressively more isotopically negative dissolved inorganic carbon along a northward Equator-to-pole transect, the opposite of the expected Pliocene Pacific meridional overturning circulation signal. C. wuellerstorfi δ 13 C is also often more positive at the deeper Ocean Drilling Program (ODP) site 887 compared with the shallower ODP site 883, suggesting ‘bottom-up’ ventilation of the deep Pacific Ocean. We then present alkenone sea surface temperature and export-productivity data from ODP site 883, which suggest that late Pliocene subarctic North Pacific carbonate sedimentation was, at least in part, probably due to higher coccolithophore export production, rather than North Pacific Deep Water formation as previously argued. Therefore, we suggest it is unlikely that North Pacific Deep Water formation occurred in the mid-Piacenzian Warm Period, although a shallower overturning cell cannot be ruled out.

Nature Geoscience↗