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Hydrogeology of the Valley-Fill Aquifer in the Onondaga Trough, Onondaga County, New York

Continuing efforts to improve water quality in Onondaga Lake, New York and its tributaries require an understanding of how the natural, brine-filled aquifer in the Onondaga Trough (valley) affects the freshwater in Onondaga Lake. The city of Syracuse, locally known as "The Salt City," was built around the salt springs, which issued from a valley-fill aquifer that contains a highly concentrated brine (up to six times as salty as sea water), but little is known about the source of the brine, its movement within the glacial sediments that partly fill the Onondaga Trough, and the interaction of the aquifer and the lake. This report summarizes initial data-collection and analysis efforts in the 25-mile long Onondaga Trough that extends from near Tully, N.Y., to the outlet of Onondaga Lake and presents results of some initial chemical and geographic analyses that will lead to the development of a mathematical ground-water-flow model of the valley-fill aquifer.

Scientific Investigations Report↗

Flood of May 2006 in York County, Maine

A stalled low-pressure system over coastal New England on Mother's Day weekend, May 13-15, 2006, released rainfall in excess of 15 inches. This flood (sometimes referred to as the 'Mother's Day flood') caused widespread damage to homes, businesses, roads, and structures in southern Maine. The damage to public property in York County was estimated to be $7.5 million. As a result of these damages, a presidential disaster declaration was enacted on May 25, 2006, for York County, Maine. Peak-flow recurrence intervals for eight of the nine streams studied were calculated to be greater than 500 years. The peak-flow recurrence interval of the remaining stream was calculated to be between a 100-year and a 500-year interval. This report provides a detailed description of the May 2006 flood in York County, Maine. Information is presented on peak streamflows and peak-flow recurrence intervals on nine streams, peak water-surface elevations for 80 high-water marks at 25 sites, hydrologic conditions before and after the flood, comparisons with published Flood Insurance Studies, and places the May 2006 flood in context with historical floods in York County. At sites on several streams, differences were observed between peak flows published in the Flood Insurance Studies and those calculated for this study. The differences in the peak flows from the published Flood Insurance Studies and the flows calculated for this report are within an acceptable range for flows calculated at ungaged locations, with the exception of those for the Great Works River and Merriland River. For sites on the Mousam River, Blacksmith Brook, Ogunquit River, and Cape Neddick River, water-surface elevations from Flood Insurance Studies differed with documented water-surface elevations from the 2006 flood.

Scientific Investigations Report↗

Update of the Accounting Surface Along the Lower Colorado River

The accounting-surface method was developed in the 1990s by the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, to identify wells outside the flood plain of the lower Colorado River that yield water that will be replaced by water from the river. This method was needed to identify which wells require an entitlement for diversion of water from the Colorado River and need to be included in accounting for consumptive use of Colorado River water as outlined in the Consolidated Decree of the United States Supreme Court in Arizona v. California. The method is based on the concept of a river aquifer and an accounting surface within the river aquifer. The study area includes the valley adjacent to the lower Colorado River and parts of some adjacent valleys in Arizona, California, Nevada, and Utah and extends from the east end of Lake Mead south to the southerly international boundary with Mexico. Contours for the original accounting surface were hand drawn based on the shape of the aquifer, water-surface elevations in the Colorado River and drainage ditches, and hydrologic judgment. This report documents an update of the original accounting surface based on updated water-surface elevations in the Colorado River and drainage ditches and the use of simple, physically based ground-water flow models to calculate the accounting surface in four areas adjacent to the free-flowing river.

Scientific Investigations Report↗

Aquifer chemistry and transport processes in the zone of contribution to a public-supply well in Woodbury, Connecticut, 2002-06

A glacial aquifer system in Woodbury, Connecticut, was studied to identify factors that affect the groundwater quality in the zone of contribution to a community public-supply well. Water samples were collected during 2002-06 from the public-supply well and from 35 monitoring wells in glacial stratified deposits, glacial till, and fractured bedrock. The glacial aquifer is vulnerable to contamination from a variety of sources due to the short groundwater residence times and the urban land use in the contributing recharge area to the public-supply well. The distribution and concentrations of pH, major and trace elements, stable isotope ratios, recharge temperatures, dissolved organic carbon (DOC), and volatile organic compounds (VOCs), and the oxidation-reduction (redox) conditions, were used to identify recharge source areas, aquifer source material, anthropogenic sources, chemical processes, and groundwater-flow paths from recharge areas to the public-supply well, PSW-1. The major chemical sources to groundwater and the tracers or conditions used to identify them and their processes throughout the aquifer system include (1) bedrock and glacial stratified deposits and till, characterized by high pH and concentrations of sulfate (SO42-), bicarbonate, uranium (U), radon-222, and arsenic (As) relative to those of other wells, reducing redox conditions, enriched delta sulfur-34 (d34S) and delta carbon-13 (d13C) values, depleted delta oxygen-18 (d18O) and delta deuterium (dD) values, calcite near saturation, low recharge temperatures, and groundwater ages of more than about 9 years; (2) natural organic matter, either in sediments or in an upgradient riparian zone, characterized by high concentrations of DOC or manganese (Mn), low concentrations of dissolved oxygen (DO) and nitrate (NO3-), enriched d34S values, and depleted d18O and dD values; (3) road salt (halite), characterized by high concentrations of sodium (Na), chloride (Cl-), and calcium (Ca), and indicative chloride/bromide (Cl:Br) mass concentration ratios; (4) septic-system leachate, characterized by high concentrations of NO3-, DOC, Na, Cl-, Ca, and boron (B), delta nitrogen-15 (d15N) and d18O values, and indicative Cl:Br ratios; (5) organic solvent spills, characterized by detections of perchloroethene (PCE), trichloroethene (TCE), and 1,1-dichloroethene (1,1-DCE); (6) gasoline station spills, characterized by detections of fuel oxygenates and occasionally benzene; and (7) surface-water leakage, characterized by enriched d18O and dD values and sometimes high DOC and Mn-reducing conditions. Evaluation of Cl- concentrations and Cl:Br ratios indicates that most samples were composed of mixtures of groundwater and some component of road salt or septic-system leachate. Leachate from septic-tank drainfields can cause locally anoxic conditions with NO3- concentrations of as much as 19 milligrams per liter (mg/L as N) and may provide up to 15 percent of the nitrogen in water from well PSW-1, based on mixing calculations with d15N of NO3-. Most of the water that contributes to PSW-1 is young (less than 7 years) and derived from the glacial stratified deposits. Typically, groundwater is oxic, but localized reducing zones that result from abundances of organic matter can affect the mobilization of trace elements and the degradation of VOCs. Groundwater from fractured bedrock beneath the valley bottom, which is old (more than 50 years), and reflects a Mn-reducing to methanic redox environment, constitutes as much as 6 percent of water samples collected from monitoring wells screened at the bottom of the glacial aquifer. Dissolved As and U concentrations generally are near the minimum reporting level (MRL) (0.2 micrograms per liter or ?g/L and 0.04 ?g/L, respectively), but water from a few wells screened in glacial deposits, likely derived from underlying organic-rich Mesozoic rocks, contain As concentrations up to 7 ?g/L. At one location, concentrations of As and U were high

Scientific Investigations Report↗

Volcanic Aquifers of Hawai‘i—Construction and calibration of numerical models for assessing groundwater availability on Kaua‘i, O‘ahu, and Maui

Steady-state numerical groundwater-flow models were constructed for the islands of Kaua‘i, O‘ahu, and Maui to enable quantification of the hydrologic consequences of withdrawals and other stresses that can place limits on groundwater availability. The volcanic aquifers of Hawai‘i supply nearly all drinking water for the islands’ residents, freshwater for diverse industries, and natural discharge to springs, streams, and nearshore areas that support ecosystems, cultural practices, aesthetics, and recreation. Increases in groundwater withdrawal and changes in climate can cause water-table depression, saltwater rise, and reduction of natural groundwater discharge—all of which can limit fresh groundwater availability. The numerical models described in this report are designed to quantify these consequences. Separate models were created for each island using MODFLOW-2005 with the Seawater Intrusion package, which allows simulation of freshwater and saltwater in ocean-island aquifers. Calibration resulted in models that generally replicate observed water-level, stream base-flow, and spring-flow data, and simulate groundwater-flow directions and fresh groundwater thicknesses that are consistent with conceptual models. The calibrated models use hydraulic properties that are consistent with the ranges reported in previous studies. The models show that the relative distribution of fresh groundwater discharge to the ocean, streams, and springs and withdrawals for human use differ substantially among the three islands studied here. These differences indicate that consequences that limit the availability of fresh groundwater for human use are likely to differ among the three islands.

Hawaii↗

Water, ice, and meteorological measurements at South Cascade Glacier, Washington, 1986-1991 balance years

Mass balance and climate variables are reported for South Cascade Glacier, Washington, for the years 1986-91. These variables include air temperature, precipitation, water runoff, snow accumulation, snow and ice melt terminus position, surface level, and ice speed. Data are reduced to daily and monthly values where appropriate. The glacier-averaged values of spring snow accumulation and fall net balance given in this report differ from previous results because amore complete analysis is made. Snow accumulation values for the1986-91 period ranged from 3.54 (water equivalent) meters in 1991 to2.04 meters in 1987. Net balance values ranged from 0.07 meters in1991 to -2.06 meters in 1987. The glacier became much smaller during the 1986-91 period and retreated a cumulative 50 meters.

Water-Resources Investigations Report↗

Klamath River Basin Hydrologic Conditions Prior to the September 2002 Die-Off of Salmon and Steelhead

More than 33,000 salmon and steelhead died in the lower Klamath River in late September 2002 on their way to spawning areas upstream. According to the California Department of Fish and Game, the cause of death was infection by protozoan and bacterial pathogens. Two factors that may have contributed to the disease incidence are low streamflow and high water temperature. September streamflows throughout the Klamath Basin were low, among the four lowest September flows recorded on the main stem since 1960. The low streamflows were caused by below-average snowpack and long-term drought, with resulting reduced ground-water discharge to streams. On the basis of historical climate data from the Klamath Basin and historical water temperature data from an adjacent basin, September 2002 water temperatures were above the long-term average. Temperatures in the Klamath River above the fish die-off reach exceeded 65 degrees Fahrenheit for nearly all of September; multiple days of exposure by fish to temperatures at or above that level can greatly increase disease incidence. This report characterizes streamflow and water temperature conditions during the period leading up to the die-off and compares them to historical conditions in the Klamath River. This report is not an exploration of the causative mechanism of the die-off; rather, it is intended to provide detailed documentation of these conditions to be used by those examining the cause(s) of the die-off and to provide information that can contribute to decisions about future water management in the Klamath Basin.

Water-Resources Investigations Report↗

U.S. Geological Survey National Computer Technology Meeting; Proceedings, Phoenix, Arizona, November 14-18, 1988

The U.S. Geological Survey National Computer Technology Meetings (NCTM) are sponsored by the Water Resources Division and provide a forum for the presentation of technical papers and the sharing of ideas or experiences related to computer technology. This report serves as a proceedings of the meeting held in November, 1988 at the Crescent Hotel in Phoenix, Arizona. The meeting was attended by more than 200 technical and managerial people representing all Divisions of the U.S. Geological Survey. Scientists in every Division of the U.S. Geological Survey rely heavily upon state-of-the-art computer technology (both hardware and sofnuare). Today the goals of each Division are pursued in an environment where high speed computers, distributed communications, distributed data bases, high technology input/output devices, and very sophisticated simulation tools are used regularly. Therefore, information transfer and the sharing of advances in technology are very important issues that must be addressed regularly. This report contains complete papers and abstracts of papers that were presented at the 1988 NCTM. The report is divided into topical sections that reflect common areas of interest and application. In each section, papers are presented first followed by abstracts. For these proceedings, the publication of a complete paper or only an abstract was at the discretion of the author, although complete papers were encouraged. Some papers presented at the 1988 NCTM are not published in these proceedings.

Water-Resources Investigations Report↗

Selected Streamflow Statistics and Regression Equations for Predicting Statistics at Stream Locations in Monroe County, Pennsylvania

A suite of 28 streamflow statistics, ranging from extreme low to high flows, was computed for 17 continuous-record streamflow-gaging stations and predicted for 20 partial-record stations in Monroe County and contiguous counties in north-eastern Pennsylvania. The predicted statistics for the partial-record stations were based on regression analyses relating inter-mittent flow measurements made at the partial-record stations indexed to concurrent daily mean flows at continuous-record stations during base-flow conditions. The same statistics also were predicted for 134 ungaged stream locations in Monroe County on the basis of regression analyses relating the statistics to GIS-determined basin characteristics for the continuous-record station drainage areas. The prediction methodology for developing the regression equations used to estimate statistics was developed for estimating low-flow frequencies. This study and a companion study found that the methodology also has application potential for predicting intermediate- and high-flow statistics. The statistics included mean monthly flows, mean annual flow, 7-day low flows for three recurrence intervals, nine flow durations, mean annual base flow, and annual mean base flows for two recurrence intervals. Low standard errors of prediction and high coefficients of determination (R2) indicated good results in using the regression equations to predict the statistics. Regression equations for the larger flow statistics tended to have lower standard errors of prediction and higher coefficients of determination (R2) than equations for the smaller flow statistics. The report discusses the methodologies used in determining the statistics and the limitations of the statistics and the equations used to predict the statistics. Caution is indicated in using the predicted statistics for small drainage area situations. Study results constitute input needed by water-resource managers in Monroe County for planning purposes and evaluation of water-resources availability.

Scientific Investigations Report↗

Porphyry copper assessment of the Central Asian Orogenic Belt and eastern Tethysides: China, Mongolia, Russia, Pakistan, Kazakhstan, Tajikistan, and India: Chapter X in Global mineral resource assessment

The U.S. Geological Survey collaborated with international colleagues to assess undiscovered resources in porphyry copper deposits in the Central Asian Orogenic Belt and eastern Tethysides. These areas host 20 known porphyry copper deposits, including the world class Oyu Tolgoi deposit in Mongolia that was discovered in the late 1990s. The study area covers major parts of the world’s largest orogenic systems. The Central Asian Orogenic Belt is a collage of amalgamated Precambrian through Mesozoic terranes that extends from the Ural Mountains in the west nearly to the Pacific Coast of Asia in the east and records the evolution and final closure of the Paleo-Asian Ocean in Permian time. The eastern Tethysides, the orogenic belt to the south of the Central Asian Orogenic Belt, records the evolution of another ancient ocean system, the Tethys Ocean. The evolution of these orogenic belts involved magmatism associated with a variety of geologic settings appropriate for formation of porphyry copper deposits, including subduction-related island arcs, continental arcs, and collisional and postconvergent settings. The original settings are difficult to trace because the arcs have been complexly deformed and dismembered by younger tectonic events. Twelve mineral resource assessment tracts were delineated to be permissive for the occurrence of porphyry copper deposits based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges and compositions. These include (1) nine Paleozoic tracts in the Central Asian Orogenic Belt, which range in area from about 60,000 to 800,000 square kilometers (km 2 ); (2) a complex area of about 400,000 km 2 on the northern margin of the Tethysides, the Qinling-Dabie tract, which spans central China and areas to the west, encompassing Paleozoic through Triassic igneous rocks that formed in diverse settings; and (3) assemblages of late Paleozoic and Mesozoic rocks that define two other tracts in the Tethysides, the 100,000 km 2 Jinsajiang tract and the 300,000 km 2 Tethyan-Gangdese tract. Assessment participants evaluated applicable grade and tonnage models and estimated numbers of undiscovered deposits at different confidence levels for each permissive tract. The estimates were then combined with the selected grade and tonnage models using Monte Carlo simulations to generate probabilistic estimates of undiscovered resources. Additional resources in extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show amounts of metal and rock in undiscovered deposits at selected quantile levels of probability (0.95, 0.9, 0.5, 0.1, and 0.05 confidence levels), as well as the arithmetic mean and associated standard deviations and variances for each tract. This assessment estimated a total of 97 undiscovered porphyry copper deposits within the assessed permissive tracts. This represents nearly five times the 20 known deposits. Predicted mean resources that could be associated with these undiscovered deposits are about 370,000,000 metric tons (t) of copper, 10,000 t of gold, 7,700,000 t of molybdenum, and 120,000 t of silver. The assessment area is estimated to contain about five times as much copper in undiscovered deposits as has been identified to date. This report includes a summary of the data used in the assessment, a brief overview of the geologic framework of the area, descriptions of permissive tracts and known deposits, maps, and tables. A geographic information system database that accompanies this report includes the tract boundaries and known porphyry copper deposits, significant prospects, and prospects. Assessments of overlapping younger rocks and adjacent areas are included in separate reports available on-line at http://minerals.usgs.gov/global/ .

Scientific Investigations Report↗

U.S. Geological Survey response to Hurricane Maria flooding in Puerto Rico and characterization of peak streamflows observed September 20–22, 2017

Hurricane Maria struck the island of Puerto Rico on September 20, 2017, as a Category 4 storm. The hurricane traversed the island from southeast to northwest and produced recorded 48-hour rainfall totals of up to 30.01 inches. Estimates of the human death toll range from 2,975 to 4,645, possibly more. The U.S. Geological Survey (USGS) hydrologic monitoring network sustained substantial wind and flood damage during the hurricane. Eighty-five of the 300 hydrologic monitoring stations operating in Puerto Rico and the U.S. Virgin Islands prior to the passage of Hurricane Maria were destroyed or damaged. During the weeks and months after the hurricane, USGS field crews in Puerto Rico prioritized repair of the hydrologic monitoring network and collected hydrologic information to characterize the magnitude of observed peak streamflows at 20 streamgage and to develop new theoretical stage-streamflow relations for 58 streamgages where stream channels were substantially altered; the theoretical stage-streamflow relations were used to estimate Hurricane Maria peak streamflows for 39 of those sites. As part of a pilot program, USGS field crews installed continuous slope-area monitoring equipment at two remote streamgages to automate the collection of high-streamflow stage data. Hurricane Maria peak streamflows and rankings were determined for 73 USGS streamgages in Puerto Rico. New rank 1 period-of-record peak streamflows occurred at 28 sites, rank 2 period-of-record peak streamflows occurred at 17 sites, and rank 3 period-of-record peak streamflows occurred at 9 sites; period-of-record peak streamflows at the remaining 19 sites either ranked from 4th to 20th or were not ranked. Annual exceedance probabilities for 53 unregulated peak streamflows ranged from greater than 50.0 percent (recurrence interval of less than 2 years) to 0.3 percent (recurrence interval of 333 years), with the majority (28 of 53) in the range of 10.0–2.1 percent (recurrence intervals of 10–48 years). A comparison of period-of-record ranks for the largest flood events that have occurred in Puerto Rico since the 1960s indicated that Hurricane Maria produced more record peak streamflows than either Hurricane Hortense in 1996 or Hurricane Georges in 1998. Limited pre-1960s hydrologic data preclude quantitative comparison with earlier storms. As part of this study, a maximum peak-streamflow envelope curve for Puerto Rico was developed using historical peak-streamflow information available through 2017. Other post-Hurricane Maria USGS activities summarized in this report include (1) Global Navigation Satellite System surveys at all stations in the USGS hydrologic monitoring network, used to tie the network to the Puerto Rico Vertical Datum of 2002; and (2) telemetered monitoring of the Lago Guajataca Dam in northwestern Puerto Rico, which was damaged and at risk of failure from October to December 2017.

Puerto Rico↗

Assessing natural recharge in Indian Wells Valley, California: A Basin Characterization Model case study

The communities in Indian Wells Valley (IWV), in the northern Mojave Desert in California, rely on groundwater for domestic and agricultural use. Mountain front recharge from the surrounding Sierra Nevada is the main source of natural recharge to the valley. Increased urbanization, agricultural development, and groundwater pumping during recent decades put IWV in a state of critical overdraft. The U.S. Geological Survey Basin Characterization Model, version 8 (BCMv8) was used to evaluate historical and future climate and hydrologic conditions in IWV. The BCMv8 estimated natural recharge in IWV at 10.7 million cubic meters (Mm 3 ) per year for the period from 1981 to 2010. Future patterns of water balance variables using three future climate scenarios, hot-wet, hot-dry, and warm-moderately wet, were calculated for mid-century (2040–69) and end-of-century (2070–99) periods. Results for both wet models projected an increase in recharge in both periods, whereas the hot-dry model projected a decrease in recharge in both periods. All models reported a large increase in seasonal variability in recharge, indicating more future availability and frequent occurrences of drought years. All climate scenarios projected an increase in climatic water deficit in both periods. These increases in irrigation demand and variability of water supply highlight the importance of strategic management planning for the sustainability of water resources in IWV.

California↗

Uranium content of ground and surface waters in western Kansas, eastern Colorado, and the Oklahoma Panhande

During 1954, 1955, and 1956, 324 water samples were collected in western Kansas, eastern Colorado, the Oklahoma Panhandle, and northeastern New Mexico, to determine the uranium content of water from the various rock units and geologic terranes in the region, and to locate areas in which, large amounts of uranium in the water might reflect the presence of nearby uranium accumulations. Three geologic terranes are present in the report area: the Tertiary-Quaternary tuff ace o us terrane, the Upper Cretaceous shale terrane, and the upper Permian through Lower Cretaceous sandstone terrane. The average uranium content of 179 water samples from the tuffaceous terrane, which is composed primarily of tuffaceous, fluviatile rocks ranging in age from Pliocene to Pleistocene, is 6.7 parts per billion. A total of 48 samples from the Upper Cretaceous shale terrane, which is composed almost entirely of shale and limestone of marine origin, contain an average of 20.4 parts per billion uranium , Sandstone, silt stone, and clay stone of terrestrial and near-shore marine origin are the predominant constituents of the upper Permian through Lower Cretaceous sandstone terrane, and the 83 water samples collected from, or related to, rock units of this terrane contain an average of 10.2 parts per billion uranium. The average uranium content figure derived for the tipper Cretaceous shale terrane may not be representative of the uranium content of waters from this terrane throughout the report area because more than half of the samples assigned to the terrane were collected in an area in which most water samples contain relatively large amounts of uranium. Compared to the shale terrane, the tuffaceous terrane and the sandstone terrane are both represented by a greater number of samples collected over a much larger area and the average uranium content figures derived for them are believed to be representative of the uranium content of waters from, or related to, rock units of the two terranes in the report area. The average uranium content figures derived for different rock units, or groups of rock units, subdivided by the source type from which the samples were collected (well, spring, stream, municipal water system, reservoir, or lake), and in some cases by geographic parts of the report area, are believed to be of more potential use in any future hydrogeochemical exploration in the area than are the average uranium content figures derived for the three geologic terranes. The average uranium content of ground-water samples from 12 individual rock units or groups of rock units ranges from less than 1. 0 to 38 parts per billion. Several rock units were sampled over large enough areas to indicate that waters from the same rock unit in different parts of the report area may range widely in average uranium content. Water samples from some of the rock units in the area, particularly those of Triassic and Permian age, contain large amounts of uranium, and in some parts of the report area, such as the Cimarron River area of westernmost Oklahoma and northeastern New Mexico, and the Rule Creek area in Bent and Las Animas Counties, Colo. , most, or all, of the water samples collected contain relatively large amounts of uranium. Further exploration to determine the source of the uranium in the water from these rock units and areas may be worthwhile.

Colorado;Kansas;New Mexico;Oklahoma↗

Saline contamination of soil and water on Pawnee tribal trust land, eastern Payne County, Oklahoma

The Bureau of Land Management reported evidence of saline contamination of soils and water in Payne County on Pawnee tribal trust land. Representatives of the Bureau of Land Management and U.S. Geological Survey inspected the site, in September 1997, and observed dead grass, small shrubs, and large trees near some abandoned oil production wells, a tank yard, an pit, and pipelines. Soil and bedrock slumps and large dead trees were observed near a repaired pipeline on the side of the steep slope dipping toward an unnamed tributary of Eagle Creek. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, initiated an investigation in March 1998 to examine soil conductance and water quality on 160 acres of Pawnee tribal trust land where there was evidence of saline contamination and concern about saline contamination of the Ada Group, the shallowest freshwater aquifer in the area. The proximity of high specific conductance in streams to areas containing pipeline spill, abandoned oil wells, the tank yard, and the pit indicates that surface-water quality is affected by production brines. Specific conductances measured in Eagle Creek and Eagle Creek tributary ranged from 1,187 to 10,230 microsiemens per centimeter, with the greatest specific conductance measured downgradient of a pipeline spill. Specific conductance in an unnamed tributary of Salt Creek ranged from 961 to 11,500 microsiemens per centimeter. Specific conductance in three ponds ranged from 295 to 967 microsiemens per centimeter, with the greatest specific conductance measured in a pond located downhill from the tank yard and the abandoned oil well. Specific conductance in water from two brine storage pits ranged from 9,840 to 100,000 microsiemens per centimeter, with water from the pit near a tank yard having the greater specific conductance. Bartlesville brine samples from the oil well and injection well have the greatest specific conductance, chloride concentration, and dissolved solids concentrations, and plot the furthest from meteoric water on a graph of 8 deuterium and d 18oxygen. Waterflooding of the Bartlesville sand in the study area started in 1957 and continued until 1998. Waterflooding is the process of injecting brine water under pressure to drive the remaining oil to the production wells. The high dissolved solids concentration samples from observation wells 1, 3B, 5,7, and 8 could result from mixing of the Bartlesville brine from the waterfiood with meteoric water.

Water-Resources Investigations Report↗

Plan of study for the regional aquifer-system analysis of the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

The San Juan structural basin is an 18,000 sq mi area that contains several extensive aquifers. The basin includes three surface drainage basins and parts of New Mexico, Colorado, Arizona, and Utah. Surface water in the area is fully appropriated, and the steadily increasing demand for groundwater has resulted in water supply concerns. Competition is great between mining and electric power companies, municipalities, and Indian communities for the limited groundwater supplies. This report outlines a 4-year plan for a study of the regional aquifer system in the San Juan structural basin. The purposes of the study are to define and understand the aquifer system; to assess the effects of groundwater use on the aquifers and streams; and to determine the availability and quality of groundwater in the basin. (Author 's abstract)

Water-Resources Investigations Report↗

Water and bed-material quality of selected streams and reservoirs in the Research Triangle area of North Carolina, 1988-94

The Triangle Area Water Supply Monitoring Project was formed by a consortium of local governments and governmental agencies in cooperation with the U.S. Geological Survey to supplement existing data on conventional pollutants, nutrients, and metals to enable eventual determination of long-term trends; to examine spatial differences among water supplies within the region, especially differences between smaller upland sources, large multipurpose reservoirs, and run-of-river supplies; to provide tributary loading inlake data for predictive modeling of Falls of the Neuse and B. Everett Jordan reservoirs; and to establish a database for synthetic organic compounds. Water-quality sampling began in October 1988 at 35 sites located on area run-of-river and reservoir water supplies and their tributaries. Sampling has continued through 1994. Samples were analyzed for major ions, nutrients, trace metals, pesticides, and semivolatile and volatile organic compounds. Monthly concentration data, high-flow concentration data, and data on daily mean streamflow at most stream sites were used to calculate loadings of nitrogen, phosphorus, suspended sediment, and trace metals to reservoirs. Stream and lake sites were assigned to one of five site categories-- (1) rivers, (2) large multipurpose reservoirs, (3) small water-supply reservoirs, (4) streams below urban areas and wastewater-treatment plants, and (5) headwater streams--according to general site characteristics. Concentrations of nitrogen species, phosphorus species, and selected trace metals were compared by site category using nonparametric analysis of variance techniques and qualitatively (trace metals). Wastewater-treatment plant effluents and urban runoff had a significant impact on water quality compared to reservoirs and headwater streams. Streams draining these areas had more mineralized water than streams draining undeveloped areas. Moreover, median nitrogen and nitrite plus nitrate concentrations were significantly greater than all other site categories. Phosphorus was significantly greater than for reservoir sites or headwater streams. Few concentrations of trace metals were greater than the minimum reporting limit, and U.S. Environmental Protection Agency drinking-water standards were rarely exceeded. Detections, when they occurred, were most frequent for sites below urban areas and wastewater-treatment plant effluents. A small number of samples for analysis of acetanilide, triazine, carbamate, and chlorophenoxy acid pesticides indicate that some of these compounds are generally present in area waters in small concentrations. Organochlorine and organophosphorus pesticides are ubiquitous in the study area in very small concentrations. Trihalomethanes were detected at sites below urban areas and wastewater-treatment plants. Otherwise, volatile organic compounds and semivolatile compounds were generally not detected. Suspended-sediment, nitrogen, phosphorus, lead, and zinc loads into Falls Lake, Jordan Lake, University Lake, Cane Creek Reservoir, Little River Reservoir, and Lake Michie were calculated. In general, reservoirs act as traps for suspended sediment and constituents associated with suspended sediments. During 1989-94, annual suspended-sediment load to Falls Lake ranged from 29,500 to 88,200 tons. Because Lake Michie trapped from 83 to 93 percent of the suspended sediment delivered by Flat River, Flat River is a minor contributor of suspended sediment to Falls Lake. Yields of suspended sediment from Little River, Little Lick Creek, and Flat River Basins were between 184 and 223 tons per square mile and appear to have increased increased slightly from yields reported in a study for the period 1970-79. Annual suspended-sediment load to Jordan Lake ranged from 271,000 to 622,000 tons from 1989 through 1994 water years. The Haw River contributed more than 75 percent of the tota load to Jordan Lake. The suspended-sediment yields for Haw River and Northeast Cree

North Carolina↗

Regional regression equations for estimation of natural streamflow statistics in Colorado

The U.S. Geological Survey (USGS), in cooperation with the Colorado Water Conservation Board and the Colorado Department of Transportation, developed regional regression equations for estimation of various streamflow statistics that are representative of natural streamflow conditions at ungaged sites in Colorado. The equations define the statistical relations between streamflow statistics (response variables) and basin and climatic characteristics (predictor variables). The equations were developed using generalized least-squares and weighted least-squares multilinear regression reliant on logarithmic variable transformation. Streamflow statistics were derived from at least 10 years of streamflow data through about 2007 from selected USGS streamflow-gaging stations in the study area that are representative of natural-flow conditions. Basin and climatic characteristics used for equation development are drainage area, mean watershed elevation, mean watershed slope, percentage of drainage area above 7,500 feet of elevation, mean annual precipitation, and 6-hour, 100-year precipitation. For each of five hydrologic regions in Colorado, peak-streamflow equations that are based on peak-streamflow data from selected stations are presented for the 2-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year instantaneous-peak streamflows. For four of the five hydrologic regions, equations based on daily-mean streamflow data from selected stations are presented for 7-day minimum 2-, 10-, and 50-year streamflows and for 7-day maximum 2-, 10-, and 50-year streamflows. Other equations presented for the same four hydrologic regions include those for estimation of annual- and monthly-mean streamflow and streamflow-duration statistics for exceedances of 10, 25, 50, 75, and 90 percent. All equations are reported along with salient diagnostic statistics, ranges of basin and climatic characteristics on which each equation is based, and commentary of potential bias, which is not otherwise removed by log-transformation of the variables of the equations from interpretation of residual plots. The predictor-variable ranges can be used to assess equation applicability for ungaged sites in Colorado.

Colorado↗

Simulation of groundwater flow, effects of artificial recharge, and storage volume changes in the Equus Beds aquifer near the city of Wichita, Kansas well field, 1935–2008

The Equus Beds aquifer is a primary water-supply source for Wichita, Kansas and the surrounding area because of shallow depth to water, large saturated thickness, and generally good water quality. Substantial water-level declines in the Equus Beds aquifer have resulted from pumping groundwater for agricultural and municipal needs, as well as periodic drought conditions. In March 2006, the city of Wichita began construction of the Equus Beds Aquifer Storage and Recovery project to store and later recover groundwater, and to form a hydraulic barrier to the known chloride-brine plume near Burrton, Kansas. In October 2009, the U.S. Geological Survey, in cooperation with the city of Wichita, began a study to determine groundwater flow in the area of the Wichita well field, and chloride transport from the Arkansas River and Burrton oilfield to the Wichita well field. Groundwater flow was simulated for the Equus Beds aquifer using the three-dimensional finite-difference groundwater-flow model MODFLOW-2000. The model simulates steady-state and transient conditions. The groundwater-flow model was calibrated by adjusting model input data and model geometry until model results matched field observations within an acceptable level of accuracy. The root mean square (RMS) error for water-level observations for the steady-state calibration simulation is 9.82 feet. The ratio of the RMS error to the total head loss in the model area is 0.049 and the mean error for water-level observations is 3.86 feet. The difference between flow into the model and flow out of the model across all model boundaries is -0.08 percent of total flow for the steady-state calibration. The RMS error for water-level observations for the transient calibration simulation is 2.48 feet, the ratio of the RMS error to the total head loss in the model area is 0.0124, and the mean error for water-level observations is 0.03 feet. The RMS error calculated for observed and simulated base flow gains or losses for the Arkansas River for the transient simulation is 7,916,564 cubic feet per day (91.6 cubic feet per second) and the RMS error divided by (/) the total range in streamflow (7,916,564/37,461,669 cubic feet per day) is 22 percent. The RMS error calculated for observed and simulated streamflow gains or losses for the Little Arkansas River for the transient simulation is 5,610,089 cubic feet per day(64.9 cubic feet per second) and the RMS error divided by the total range in streamflow (5,612,918/41,791,091 cubic feet per day) is 13 percent. The mean error between observed and simulated base flow gains or losses was 29,999 cubic feet per day (0.34 cubic feet per second) for the Arkansas River and -1,369,250 cubic feet per day (-15.8 cubic feet per second) for the Little Arkansas River. Cumulative streamflow gain and loss observations are similar to the cumulative simulated equivalents. Average percent mass balance difference for individual stress periods ranged from -0.46 to 0.51 percent. The cumulative mass balance for the transient calibration was 0.01 percent. Composite scaled sensitivities indicate the simulations are most sensitive to parameters with a large areal distribution. For the steady-state calibration, these parameters include recharge, hydraulic conductivity, and vertical conductance. For the transient simulation, these parameters include evapotranspiration, recharge, and hydraulic conductivity. The ability of the calibrated model to account for the additional groundwater recharged to the Equus Beds aquifer as part of the Aquifer Storage and Recovery project was assessed by using the U.S. Geological Survey subregional water budget program ZONEBUDGET and comparing those results to metered recharge for 2007 and 2008 and previous estimates of artificial recharge. The change in storage between simulations is the volume of water that estimates the recharge credit for the aquifer storage and recovery system. The estimated increase in storage of 1,607 acre-ft in the basin storage area compared to metered recharge of 1,796 acre-ft indicates some loss of metered recharge. Increased storage outside of the basin storage area of 183 acre-ft accounts for all but 6 acre-ft or 0.33 percent of the total. Previously estimated recharge credits for 2007 and 2008 are 1,018 and 600 acre-ft, respectively, and a total estimated recharge credit of 1,618 acre-ft. Storage changes calculated for this study are 4.42 percent less for 2007 and 5.67 percent more for 2008 than previous estimates. Total storage change for 2007 and 2008 is 0.68 percent less than previous estimates. The small difference between the increase in storage from artificial recharge estimated with the groundwater-flow model and metered recharge indicates the groundwater model correctly accounts for the additional water recharged to the Equus Beds aquifer as part of the Aquifer Storage and Recovery project. Small percent differences between inflows and outflows for all stress periods and all index cells in the basin storage area, improved calibration compared to the previous model, and a reasonable match between simulated and measured long-term base flow indicates the groundwater model accurately simulates groundwater flow in the study area. The change in groundwater level through recent years compared to the August 1940 groundwater level map has been documented and used to assess the change of storage volume of the Equus Beds aquifer in and near the Wichita well field for three different areas. Two methods were used to estimate changes in storage from simulation results using simulated change in groundwater levels in layer 1 between stress periods, and using ZONEBUDGET to calculate the change in storage in the same way the effects of artificial recharge were estimated within the basin storage area. The three methods indicate similar trends although the magnitude of storage changes differ. Information about the change in storage in response to hydrologic stresses is important for managing groundwater resources in the study area. The comparison between the three methods indicates similar storage change trends are estimated and each could be used to determine relative increases or decreases in storage. Use of groundwater level changes that do not include storage changes that occur in confined or semi-confined parts of the aquifer will slightly underestimate storage changes; however, use of specific yield and groundwater level changes to estimate storage change in confined or semi-confined parts of the aquifer will overestimate storage changes. Using only changes in shallow groundwater levels would provide more accurate storage change estimates for the measured groundwater levels method. The value used for specific yield is also an important consideration when estimating storage. For the Equus Beds aquifer the reported specific yield ranges between 0.08 and 0.35 and the storage coefficient (for confined conditions) ranges between 0.0004 and 0.16. Considering the importance of the value of specific yield and storage coefficient to estimates of storage change over time, and the wide range and substantial overlap for the reported values for specific yield and storage coefficient in the study area, further information on the distribution of specific yield and storage coefficient within the Equus Beds aquifer in the study area would greatly enhance the accuracy of estimated storage changes using both simulated groundwater level, simulated groundwater budget, or measured groundwater level methods.

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