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At least 1,189 records · Page 66Linked to original sources

Discriminating assimilants and decoupling deep- vs. shallow-level crystal records at Mount Adams using 238U-230Th disequilibria and Os isotopes

A suite of 23 basaltic to dacitic lavas erupted over the last 350 kyr from the Mount Adams volcanic field has been analyzed for U–Th isotope compositions to evaluate the roles of mantle versus crustal components during magma genesis. All of the lavas have ( 230 Th/ 238 U) > 1 and span a large range in ( 230 Th/ 232 Th) ratios, and most basalts have higher ( 230 Th/ 232 Th) ratios than andesites and dacites. Several of the lavas contain antecrysts (crystals of pre-existing material), yet internal U–Th mineral isochrons from six of seven lavas are indistinguishable from their eruption ages. This indicates a relatively brief period of time between crystal growth and eruption for most of the phenocrysts (olivine, clinopyroxene, plagioclase, magnetite) prior to eruption. One isochron gave a crystallization age that is ~ 20–25 ka older than its corresponding eruptive age, and is interpreted to reflect mixing of older and juvenile crystals or a protracted period of magma storage in the crust. Much of the eruptive volume since 350 ka consists of lavas that have small to moderate 230 Th excesses (2–16%), which are likely inherited from melting of a garnet-bearing intraplate (“OIB-like”) mantle source. Following melt generation and subsequent migration through the upper mantle, most Mt. Adams magmas interacted with young, mafic lower crust, as indicated by 187 Os/ 188 Os ratios that are substantially more radiogenic than the mantle or those expected via mixing of subducted material and the mantle wedge. Moreover, Os–Th isotope variations suggest that unusually large 230 Th excesses (25–48%) and high 187 Os/ 188 Os ratios in some peripheral lavas reflect assimilation of small degree partial melts of pre-Quaternary basement that had residual garnet or Al-rich clinopyroxene. Despite the isotopic evidence for lower crustal assimilation, these processes are not generally recorded in the erupted phenocrysts, indicating that the crystal record of the deep-level ‘cryptic’ processes has been decoupled from shallow-level crystallization.

Washington↗

On the causes of mid-Pliocene warmth and polar amplification

The mid-Pliocene (~ 3 to 3.3 Ma ago), is a period of sustained global warmth in comparison to the late Quaternary (0 to ~ 1 Ma ago), and has potential to inform predictions of long-term future climate change. However, given that several processes potentially contributed, relatively little is understood about the reasons for the observed warmth, or the associated polar amplification. Here, using a modelling approach and a novel factorisation method, we assess the relative contributions to mid-Pliocene warmth from: elevated CO 2 , lowered orography, and vegetation and ice sheet changes. The results show that on a global scale, the largest contributor to mid-Pliocene warmth is elevated CO 2 . However, in terms of polar amplification, changes to ice sheets contribute significantly in the Southern Hemisphere, and orographic changes contribute significantly in the Northern Hemisphere. We also carry out an energy balance analysis which indicates that that on a global scale, surface albedo and atmospheric emmissivity changes dominate over cloud changes. We investigate the sensitivity of our results to uncertainties in the prescribed CO 2 and orographic changes, to derive uncertainty ranges for the various contributing processes.

Earth and Planetary Science Letters↗

Refining fault slip rates using multiple displaced terrace risers-An example from the Honey Lake fault, NE California, USA

Faulted terrace risers are semi-planar features commonly used to constrain Quaternary slip rates along strike-slip faults . These landforms are difficult to date directly and therefore their ages are commonly bracketed by age estimates of the adjacent upper and lower terrace surfaces. However, substantial differences in the ages of the upper and lower terrace surfaces (a factor of 2.4 difference observed globally) produce large uncertainties in the slip-rate estimate. In this investigation, we explore how the full range of displacements and bounding ages from multiple faulted terrace risers can be combined to yield a more accurate fault slip rate. We use 0.25-m cell size digital terrain models derived from airborne lidar data to analyze three sites where terrace risers are offset right-laterally by the Honey Lake fault in NE California, USA. We use ages for locally extensive subhorizontal surfaces to bracket the time of riser formation: an upper surface is the bed of abandoned Lake Lahontan having an age of 15.8 ± 0.6 ka and a lower surface is a fluvial terrace abandoned at 4.7 ± 0.1 ka. We estimate lateral offsets of the risers ranging between 6.6 and 28.3 m (median values), a greater than fourfold difference in values. The amount of offset corresponds to the riser's position relative to modern stream meanders: the smallest offset is in a meander cutbank position, whereas the larger offsets are in straight channel or meander point-bar positions. Taken in isolation, the individual terrace-riser offsets yield slip rates ranging from 0.3 to 7.1 mm/a. However, when the offset values are collectively assessed in a probabilistic framework, we find that a uniform (linear) slip rate of 1.6 mm/a (1.4–1.9 mm/a at 95% confidence) can satisfy the data, within their respective uncertainties. This investigation demonstrates that integrating observations of multiple offset elements (crest, midpoint, and base) from numerous faulted and dated terrace risers at closely spaced sites can refine slip-rate estimates on strike-slip faults.

California↗

A Bayesian age from dispersed plagioclase and zircon dates in the Los Chocoyos ash, Central America

The eruption that produced the modern Atitlán caldera in Guatemala has a Volcanic Explosivity Index (VEI) greater than 8, making it the largest of the Quaternary in the Central American Volcanic Arc (CAVA). It generated ∼1220 km 3 (730 km 3 dense rock equivalent) of dispersed rhyolitic ash and unwelded pyroclastic flow deposits known as the Los Chocoyos ash. Despite its scale, the age of the Los Chocoyos ash has been difficult to constrain. Its inferred position in marine sediment off the coast of Ecuador suggests an oxygen isotope-based age of 84 ± 5 thousand years (ka) that has been used for decades. A recent effort to determine the eruption age of the Los Chocoyos ash used U-Th/He and U/Th disequilibrium methods that both yield overdispersed sets of dates from zircon. Using U/Th disequilibrium corrected U-Th/He dates, which include some that are up to 19 ± 8 kyr younger than the youngest U/Th disequilibrium dates, an eruption age of 75 ± 4 ka has been proposed, which overlaps the eruption age of the Youngest Toba Tuff, 40 Ar/ 39 Ar dated at 73.9 ± 0.6 ka. Critically, the above findings have led to the hypothesis that this pair of sulfate-rich supereruptions may be responsible for a global cooling event ∼74 ka. To further test this supereruption doublet hypothesis we present new 40 Ar/ 39 Ar and U-Th disequilibrium data from plagioclase and zircon rim surfaces, respectively, to quantify the timing of the Los Chocoyos eruption. We apply Bayesian estimation to the overdispersed sets of 40 Ar/ 39 Ar plagioclase and U-Th disequilibrium zircon dates. This approach accounts for retention of radiogenic 40 Ar in plagioclase in a subset of crystals and for crystallization of zircon that may precede the time of eruption and yields remarkably consistent ages from two independent chronometers. The Bayesian estimate of 98 ± 6 ka calculated from 308 individual dates identifies the population nearest to the time of the Los Chocoyos eruption. Interpreted as an eruption age, this finding precludes a link between the Los Chocoyos eruption and global cooling ∼74 ka and rules out the supereruption doublet trigger.

Earth and Planetary Science Letters↗

Dynamic drainage reorganization in Eastern Tibet: Insights from the Yangtze River first bend

The modern drainage network of eastern Tibet is widely believed to have developed through a series of river capture and flow reversal events; however, the timing and mechanisms driving this reorganization remain contentious. Among these events, the river capture that formed the First Bend of the Yangtze River (YFB) stands out as both iconic and particularly debated. Here we present sedimentary provenance data from the Late Miocene–Quaternary Dali Basin, located south of the YFB, which indicate that a southward-flowing Jinsha River (i.e., the present-day upper Yangtze River) sourced sediment to the Dali basin at ∼7.4–6.4 Ma in a drainage configuration different from that of today. Because this interval postdates the initial establishment of a near-modern Jinsha River system prior to the Miocene, our results imply at least two discrete fluvial reorganizations occurred at the YFB—one preceding ∼7.4 Ma and another following ∼6.4 Ma. By integrating these findings with landscape evolution modeling, we infer that the initiation of rapid uplift of the Yulong-Haba Mountains and the Diancang Shan may have been responsible for these drainage reorganizations. These results underscore that Cenozoic drainage systems on the eastern Tibetan Plateau have evolved dynamically on a short timescale of ∼10 5 –10 6 -year, rather than remaining in a long-term stationary configuration on ∼10 7 -year timescales.

eastern Tibetan Plateau, first bend of the Yangtze↗

Anaerobic methane oxidation in low-organic content methane seep sediments

Sulfate-dependent anaerobic oxidation of methane (AOM) is the key sedimentary microbial process limiting methane emissions from marine sediments and methane seeps. In this study, we investigate how the presence of low-organic content sediment influences the capacity and efficiency of AOM at Bullseye vent, a gas hydrate-bearing cold seep offshore of Vancouver Island, Canada. The upper 8 m of sediment contains < 0.4 wt% total organic carbon (OC) and primarily consists of glacially-derived material that was deposited 14,900 to 15,900 yrs BP during the retreat of the late Quaternary Cordilleran Ice Sheet. We hypothesize this aged and exceptionally low-OC content sedimentary OM is biologically refractory, thereby limiting degradation of non-methane OM by sulfate reduction and maximizing methane consumption by sulfate-dependent AOM. A radiocarbon-based dissolved inorganic carbon (DIC) isotope mass balance model demonstrates that respired DIC in sediment pore fluids is derived from a fossil carbon source that is devoid of 14 C. A fossil origin for the DIC precludes remineralization of non-fossil OM present within the sulfate zone as a significant contributor to pore water DIC, suggesting that nearly all sulfate is available for anaerobic oxidation of fossil seep methane. Methane flux from the SMT to the sediment water interface in a diffusion-dominated flux region of Bullseye vent was, on average, 96% less than at an OM-rich seep in the Gulf of Mexico with a similar methane flux regime. Evidence for enhanced methane oxidation capacity within OM-poor sediments has implications for assessing how climate-sensitive reservoirs of sedimentary methane (e.g., gas hydrate) will respond to ocean warming, particularly along glacially-influenced mid and high latitude continental margins.

Geochimica et Cosmochimica Acta↗

Novel insights from NMR spectroscopy into seasonal changes in the composition of dissolved organic matter exported to the Bering Sea by the Yukon River

Seasonal (spring freshet, summer&ndash;autumn, and winter) variability in the chemical composition of dissolved organic matter (DOM) from the Yukon River was determined using advanced one- and two-dimensional (2D) solid-state NMR spectroscopy, coupled with isotopic measurements and UV&ndash;visible spectroscopy. Analyses were performed on two major DOM fractions, the hydrophobic organic acid (HPOA) and transphilic organic acid (TPIA) fractions obtained using XAD resins. Together these two fractions comprised 64&ndash;74% of the total DOM. Carboxyl-rich alicyclic molecules (CRAM) accounted for the majority of carbon atoms in the HPOA (63&ndash;77%) and TPIA (54&ndash;78%) samples, and more so in winter and summer than in spring samples. 2D and selective NMR data revealed association of abundant nonprotonated O-alkyl and quaternary alkyl C (OC np , OC np O and C q , 13&ndash;17% of HPOA and 15&ndash;20% of TPIA) and isolated O&ndash;CH structures with CRAM, which were not recognized in previous studies. Spectral editing and 2D NMR allowed for the discrimination of carbohydrate-like O-alkyl C from non-carbohydrate O-alkyl C. Whereas two spring freshet TPIA samples contained carbohydrate clusters such as carboxylated carbohydrates (16% and 26%), TPIA samples from other seasons or HPOA samples mostly had small amounts (<8%) of sugar rings dispersed in a nonpolar alkyl environment. Though nonprotonated aromatic C represented the largest fraction of aromatic C in all HPOA/TPIA isolates, only a small fraction (&sim;5% in HPOA and 3% in TPIA) was possibly associated with dissolved black carbon. Our results imply a relatively stable portion of DOM exported by the Yukon River across different seasons, due to the predominance of CRAM and their associated nonprotonated C&ndash;O and O&ndash;C&ndash;O structures, and elevated reactivity (bio- and photo-lability) of spring DOM due to the presence of terrestrial inputs enriched in carbohydrates and aromatic structures.

Alaska, Yukon↗

Strontium isotopes and nutrient sourcing in a semi-arid woodland

Sr isotopes are widely used as a tracer of Sr and Ca in surficial systems. Basalt flows ranging in age from 3 ka (kiloyears ago) to > 200 ka from El Malpais National Monument (EMNM), New Mexico provide an ideal setting to examine strontium, and hence calcium cycling by plants in a semi-arid woodland. To gauge plant dependence on atmospheric dust versus local weathering products for strontium and calcium, we measured 87 Sr/ 86 Sr ratios in local bedrock and soils, and compared them to leaf/wood cellulose of four different conifers, a deciduous tree, three shrubs, an annual C 4 grass, and a lichen. Sampling sites varied by parent material (limestone, sandstone, granite, and basalt) and age (Quaternary to Precambrian), providing a wide range in end-member 87 Sr/ 86 Sr ratios, whereas the target plant species varied in physiognomy, life history, and rooting depth. On non-basalt parent material, the contribution from dust changed with the supply of weatherable Sr-bearing minerals in local bedrock. Soils developed on Paleozoic limestone showed significant bedrock contributions. On basalts, the Sr budget of soils at EMNM is dominated by atmospheric dust on young, 3 ka flows, incorporates a mixture of basalt-dust in 9 ka flows, and is basalt-dominated in 120 ka flows. This is unlike the pattern observed in tropical soils developed on basalt in Hawaii, where basalt weathering dominates the Sr inventory of the youngest soils and aerosols dominate in older, deeply weathered soils. This contrast is mainly due to different water/rock (W/R) ratios: bedrock subjected to high W/R over short periods is quickly ( < 10 ka) depleted in Sr (and Ca), except for the ongoing replenishment from aerosols. In arid settings where W/R are lower, soil Sr is still abundantly available first from dust, and increasingly from bedrock even after 120 ka. For plants, 87 Sr/ 86 Sr variations within and across sites at EMNP showed that evergreen trees varied most in 87 Sr/ 86 Sr ratios, shrubs were least dependent on eolian input of Sr, and both foliage density and rooting depths influence soil Sr pools.

New Mexico↗

Landslides triggered by the 8 October 2005 Kashmir earthquake

The 8 October 2005 Kashmir earthquake triggered several thousand landslides. These were mainly rock falls and debris falls, although translational rock and debris slides also occurred. In addition, a sturzstrom (debris avalanche) comprising ??? 80??million m3 buried four villages and blocked streams to create two lakes. Although landsliding occurred throughout the region, covering an area of > 7500??km2, the failures were highly concentrated, associated with six geomorphic-geologic-anthropogenic settings, including natural failures in (1) highly fractured carbonate rocks comprising the lowest beds in the hanging wall of the likely earthquake fault; (2) Tertiary siliciclastic rocks along antecedent drainages that traverse the Hazara-Kashmir Syntaxis; (3) steep (> 50??) slopes comprising Precambrian and Lower Paleozoic rocks; (4) very steep (?? 50??) lower slopes of fluvially undercut Quaternary valley fills; and (5) ridges and spur crests. The sixth setting was associated with road construction. Extensive fissuring in many of the valley slopes together with the freshly mobilized landslide debris constitutes a potential hazard in the coming snowmelt and monsoon seasons. This study supports the view that earthquake-triggered landslides are highly concentrated in specific zones associated with the lithology, structure, geomorphology, topography, and human presence. ?? 2007 Elsevier B.V. All rights reserved.

Geomorphology↗

Buried paleoindian-age landscapes in stream valleys of the central plains, USA

A systematic study of late-Quaternary landscape evolution in the Central Plains documented widespread, deeply buried paleosols that represent Paleoindian-age landscapes in terrace fills of large streams (> 5th order), in alluvial fans, and in draws in areas of western Kansas with a thick loess mantle. Alluvial stratigraphic sections were investigated along a steep bio-climatic gradient extending from the moist-subhumid forest-prairie border of the east-central Plains to the dry-subhumid and semi-arid shortgrass prairie of the west-central Plains. Radiocarbon ages indicate that most large streams were characterized by slow aggradation accompanied by cumulic soil development from ca. 11,500 to 10,000??14C yr B.P. In the valleys of some large streams, such as the Ninnescah and Saline rivers, these processes continued into the early Holocene. The soil-stratigraphic record in the draws of western Kansas indicates slow aggradation punctuated by episodes of landscape stability and pedogenesis beginning as early as ca. 13,300??14C yr B.P. and spanning the Pleistocene-Holocene boundary. The development record of alluvial fans in western Kansas is similar to the record in the draws; slow aggradation was punctuated by multiple episodes of soil development between ca. 13,000 and 9000??14C yr B.P. In eastern Kansas and Nebraska, development of alluvial fans was common during the early and middle Holocene, but evidence shows fan development as early as ca. 11,300??14C yr B.P. Buried soils dating between ca. 12,600 and 9000??14C yr B.P. were documented in fans throughout the region. In stream valleys across the Central Plains, rapid alluviation after ca. 9000??14C yr B.P. resulted in deeply buried soils that may harbor Paleoindian cultural deposits. Hence, the paucity of recorded stratified Paleoindian sites in the Central Plains is probably related to poor visibility (i.e., deep burial in alluvial deposits) instead of limited human occupation in the region during the terminal Pleistocene and early Holocene. The thick, dark, cumulic A horizons of soils, representing buried Paleoindian-age landscapes, are targets for future archaeological surveys. ?? 2008 Elsevier B.V. All rights reserved.

Geomorphology↗

From deposition to erosion: Spatial and temporal variability of sediment sources, storage, and transport in a small agricultural watershed

The spatial and temporal variability of sediment sources, storage, and transport were investigated in a small agricultural watershed draining the Coast Ranges and Sacramento Valley in central California. Results of field, laboratory, and historical data analysis in the Willow Slough fluvial system document changes that transformed a transport-limited depositional system to an effective erosion and transport system, despite a large sediment supply. These changes were caused by a combination of factors: (i) an increase in transport capacity, and (ii) hydrologic alteration. Alteration of the riparian zone and drainage network pattern during the past ~ 150 years included a twofold increase in straightened channel segments along with a baselevel change from excavation that increased slope, and increased sediment transport capacity by ~ 7%. Hydrologic alteration from irrigation water contributions also increased transport capacity, by extending the period with potential for sediment transport and erosion by ~ 6 months/year. Field measurements document Quaternary Alluvium as a modern source of fine sediment with grain size distributions characterized by 5 to 40% fine material. About 60% of an upland and 30% of a lowland study reach incised into this deposit exhibit bank erosion. During this study, the wet 2006 and relatively dry 2007 water years exhibited a range of total annual suspended sediment load spanning two orders of magnitude: ~ 108,500 kg/km 2 /year during 2006 and 5,950 kg/km 2 /year during 2007, only 5% of that during the previous year. Regional implications of this work are illustrated by the potential for a small tributary such as Willow Slough to contribute sediment – whereas large dams limit sediment supply from larger tributaries – to the Sacramento River and San Francisco Bay Delta and Estuary. This work is relevant to lowland agricultural river–floodplain systems globally in efforts to restore aquatic and riparian functions and where water quality management includes reducing fine sediment contributions that can couple with other pollutants.

California↗

Dating of river terraces along Lefthand Creek, western High Plains, Colorado, reveals punctuated incision

The response of erosional landscapes to Quaternary climate oscillations is recorded in fluvial terraces whose quantitative interpretation requires numerical ages. We investigate gravel-capped strath terraces along the western edge of Colorado's High Plains to constrain the incision history of this shale-dominated landscape. We use ¹⁰Be and ²⁶Al cosmogenic radionuclides (CRNs), optically stimulated luminescence (OSL), and thermally transferred OSL (TT-OSL) to date three strath terraces, all beveled in shale bedrock and then deposited upon by Lefthand Creek, which drains the crystalline core of the Front Range. Our study reveals: (i) a long history (hundreds of thousands of years) of fluvial occupation of the second highest terrace, T2 (Table Mountain), with fluvial abandonment at 92 ± 3 ka; (ii) a brief occupation of a narrow and spatially confined terrace, T3, at 98 ± 7 ka; and (iii) a 10–25 thousand year period of cutting and fluvial occupation of a lower terrace, T4, marked by the deposition of a lower alluvial unit between 59 and 68 ka, followed by deposition of an upper alluvial package at 40 ± 3 ka. In conjunction with other recent CRN studies of strath terraces along the Colorado Front Range (Riihimaki et al., 2006; Dühnforth et al., 2012), our data reveal that long periods of lateral planation and fluvial occupation of strath terraces, sometimes lasting several glacial-interglacial cycles, are punctuated by brief episodes of rapid vertical bedrock incision. These data call into question what a singular terrace age represents, as the strath may be cut at one time (its cutting-age) and the terrace surface may be abandoned at a much later time (its abandonment age), and challenge models of strath terraces that appeal to simple pacing by the glacial-interglacial cycles.

Colorado↗

Preface to historic and paleoflood analyses: New perspectives on climate, extreme flood risk, and the geomorphic effects of large floods

Paleofloods are flood events that occurred prior to instrumented records that are discerned from sedimentary evidence. Historic floods are flood events that predate the instrumented record that have been reconstructed based on evidence provided by historical sources. This special issue presents papers on historic and paleoflood analyses that stemmed from the 5th International Paleoflood Symposium held in 2016 and a technical paper session convened during the 2016 Annual Meeting of the Geological Society of America (GSA) in Denver, Colorado, titled ‘Paleofloods and Related Fluvial Processes during the Late Quaternary: Reconstructions and Causes.’ The papers included in this special issue address a wide variety of flood science questions, including hydrologic hazard and risk assessments, the examination of prehistoric human migration patterns, understanding relationships between large floods and climate, and the investigation of cataclysmic flood processes.

Geomorphology↗

Cenozoic stratigraphy of the Sahara, Northern Africa

This paper presents an overview of the Cenozoic stratigraphic record in the Sahara, and shows that the strata display some remarkably similar characteristics across much of the region. In fact, some lithologies of certain ages are exceptionally widespread and persistent, and many of the changes from one lithology to another appear to have been relatively synchronous across the Sahara. The general stratigraphic succession is that of a transition from early Cenozoic carbonate strata to late Cenozoic siliciclastic strata. This transition in lithology coincides with a long-term eustatic fall in sea level since the middle Cretaceous and with a global climate transition from a Late Cretaceous–Early Eocene “warm mode” to a Late Eocene–Quaternary “cool mode”. Much of the shorter-term stratigraphic variability in the Sahara (and even the regional unconformities) also can be correlated with specific changes in sea level, climate, and tectonic activity during the Cenozoic. Specifically, Paleocene and Eocene carbonate strata and phosphate are suggestive of a warm and humid climate, whereas latest Eocene evaporitic strata (and an end-Eocene regional unconformity) are correlated with a eustatic fall in sea level, the build-up of ice in Antarctica, and the appearance of relatively arid climates in the Sahara. The absence of Oligocene strata throughout much of the Sahara is attributed to the effects of generally low eustatic sea level during the Oligocene and tectonic uplift in certain areas during the Late Eocene and Oligocene. Miocene sandstone and conglomerate are attributed to the effects of continued tectonic uplift around the Sahara, generally low eustatic sea level, and enough rainfall to support the development of extensive fluvial systems. Middle–Upper Miocene carbonate strata accumulated in northern Libya in response to a eustatic rise in sea level, whereas Upper Miocene mudstone accumulated along the south side of the Atlas Mountains because uplift of the mountains blocked fluvial access to the Mediterranean Sea. Uppermost Miocene evaporites (and an end-Miocene regional unconformity) in the northern Sahara are correlated with the Messinian desiccation of the Mediterranean Sea. Abundant and widespread Pliocene paleosols are attributed to the onset of relatively arid climate conditions and (or) greater variability of climate conditions, and the appearance of persistent and widespread eolian sediments in the Sahara is coincident with the major glaciation in the northern hemisphere during the Pliocene.

Journal of African Earth Sciences↗

Postglacial eruptive history of Laguna del Maule volcanic field and constraints on its magmatic system

The Laguna del Maule (LdM) volcanic field has produced >100 explosive and extrusive events over the past 17 ka. More than two-thirds of these have been silicic, with most being postglacial rhyolites (72–78 % SiO 2 ) concentrated near the eponymous lake (LdM), an extraordinary anomaly in the Quaternary Andes and unprecedented in this 1.5–Ma-old volcanic field as a whole. The postglacial field includes >70 separate vents distributed over ∼360 km 2 that together produced the many distinct eruptive events, of which 55 are rhyolitic (73 %−77 % SiO 2 ), 18 are rhyodacitic (68 %−72 % SiO 2 ), 4 are dacitic (63 %–66 % SiO 2 ), 26 are intermediate (54–62 % SiO 2 ), and 2 are true basalts (50 %–53 % SiO 2 ). Of these, most originated from single-vent domes, cones, or craters that erupted effusive and/or explosive products, each with relatively short lifespans. Some originated from multi-vent centers, the largest one being the Barrancas complex southeast of the lake, which has as many as 18 vents that erupted over as much as 10 kyr. The LdM basin itself is ringed by 13 separate silicic centers, many of which are also multi-vent and built over time by multiple explosive and extrusive events. These surround the lake, near the middle of which is the vent for the high-silica rhyolite Plinian eruption that produced the “ Rhyolite of Laguna del Maule ”, which was the first and largest silicic event from the postglacial field. Explosive and effusive products from all these events have been put in a time-stratigraphic framework supported by radiocarbon dating and chemical analyses to reconstruct the postglacial eruptive history. Correlations of pyroclastics to eruptive vents have provided a spatial-temporal framework that helps characterize the magmatic system beneath the LdM field. Distribution of both silicic and mafic vents support the likelihood that two separate magmatic systems produced the postglacial eruptions in the volcanic field—one in the Laguna del Maule basin and the other at the Barrancas complex—with a cluster of silicic vents at each and mafic vents situated between the two. Vent distributions, compositions of eruptive products, and temporal and spatial trends of eruptive units suggest that the abundant rhyodacitic and mafic units in the LdM basin have no common magma reservoir, but instead each had its own evolutionary trend. In contrast, there is enough affinity among some of the rhyolitic units in the Basin to imply magmatic connections and/or continuity that span both time and space, although neither geographic proximity nor temporal similarity have singular control on LdM-basin rhyolite compositions. Compositional trends through time at the Barrancas center suggest the rhyolitic eruptions at West and East Barrancas were derived from separate, zoned reservoirs that were tapped in batches, not permitting development of a large high-silica reservoir such as that beneath the LdM basin.

Laguna del Maule lake basin↗

The geochemistry of loess: Asian and North American deposits compared

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the bulk of loess deposits are found on both continents. Although loess has been considered to be representative of the average upper continental crust, there are regionally distinctive compositions of loess in both Asia and North America. Loess deposits in Asia from Yakutia, Tajikistan, and China have compositionally distinct major element compositions, due to varying abundances of silicate minerals, carbonate minerals, and clay minerals. In North America, loess in the Mississippi River valley, the Great Plains, and Alaska are also distinguishable with regard to major element composition that reflects highly diverse source sediments. Trace element geochemistry (Sc-Th-Zr and the rare earth elements) also shows regional diversity of loess bodies, in both Asia and North America. On both continents, most loess bodies show significant contributions from later-cycle, altered sedimentary rocks, as opposed to direct derivation from igneous rocks. Further, some loess bodies have detectable contributions from mafic igneous rocks as well as major contributions from average, upper-crustal, felsic rocks. Intercalated paleosols in loess sections show geochemical compositions that differ significantly from the underlying loess parent materials. Ratios of soluble-to-insoluble elements show depletions in paleosols due to chemical weathering losses of calcite, dolomite, plagioclase, mica, apatite, and smectite. In Asia and North America, the last interglacial paleosol is more weathered than equivalent modern soils, which could be due either to a climate that was warmer and more humid, a longer period of pedogenesis, or both. In Asia, early Pleistocene loess and paleosols are both more weathered than those from the middle and late Pleistocene, forming prior to a mid-Pleistocene aridification of Asia from uplift of the Tibetan Plateau. Understanding the geochemistry of loess and paleosols can tell us much about past atmospheric circulation, past temperature and moisture regimes, and even tectonic processes.

Journal of Asian Earth Sciences↗

Eruptive history of South Sister, Oregon Cascades

South Sister is southernmost and highest of the Three Sisters, three geologically dissimilar stratovolcanoes that together form a spectacular 20km reach along the Cascade crest in Oregon. North Sister is a monotonously mafic edifice as old as middle Pleistocene, Middle Sister a basalt-andesite-dacite cone built between 48 and 14ka, and South Sister is a basalt-free edifice that alternated rhyolitic and intermediate modes from 50ka to 2ka (largely contemporaneous with Middle Sister). Detailed mapping, 330 chemical analyses, and 42 radioisotopic ages show that the oldest exposed South Sister lavas were initially rhyolitic ~50ka. By ~37ka, rhyolitic lava flows and domes (72-74% SiO 2 ) began alternating with radially emplaced dacite (63-68% SiO 2 ) and andesite (59-63% SiO 2 ) lava flows. Construction of a broad cone of silicic andesite-dacite (61-64% SiO 2 ) culminated ~30ka in a dominantly explosive sequence that began with crater-forming andesitic eruptions that left fragmental deposits at least 200m thick. This was followed at ~27ka by growth of a steeply dipping summit cone of agglutinate-dominated andesite (56-60.5% SiO 2 ) and formation of a summit crater ~800m wide. This crater was soon filled and overtopped by a thick dacite lava flow and then by >150m of dacitic pyroclastic ejecta. Small-volume dacite lavas (63-67% SiO 2 ) locally cap the pyroclastic pile. A final sheet of mafic agglutinate (54-56% SiO 2 ) - the most mafic product of South Sister - erupted from and drapes the small (300-m-wide) present-day summit crater, ending a summit-building sequence that lasted until ~22ka. A 20kyr-long-hiatus was broken by rhyolite eruptions that produced (1) the Rock Mesa coulee, tephra, and satellite domelets (73.5% SiO 2 ) and (2) the Devils Chain of ~20 domes and short coulees (72.3-72.8% SiO 2 ) from N-S vent alignments on South Sister's flanks. The compositional reversal from mafic summit agglutinate to recent rhyolites epitomizes the frequently changing compositional modes of the South Sister locus throughout its lifetime. South Sister is part of a reach of the Cascades unusually active in the last 50kyr, characterized by high vent density, N-S vent alignments, and numerous eruptive units of true rhyolite (≥ 72% SiO 2 ) that distinguishes it from much of the Quaternary Cascade arc; these are eruptive expressions of the complex confluence of arc and intraplate magmatic-tectonic regimes.

Journal of Volcanology and Geothermal Research↗

Dynamic deformation of Seguam Island, Alaska, 1992--2008, from multi-interferogram InSAR processing

We generated a time-series of ERS-1/2 and ENVISAT interferometric synthetic aperture radar (InSAR) images to study ground surface deformation at Seguam Island from 1992 to 2008. We used the small baseline subset (SBAS) technique to reduce artifacts associated with baseline uncertainties and atmospheric delay anomalies, and processed images from two adjacent tracks to validate our results. Seguam Island comprises the remnants of two late Quaternary calderas, one in the western caldera of the island and one in the eastern part of the island. The western caldera subsided at a constant rate of ~ 1.6 cm/yr throughout the study period, while the eastern caldera experienced alternating periods of subsidence and uplift: ~ 5 cm/year uplift during January 1993–October 1993 (stage 1), ~ 1.6 cm/year subsidence during October 1993–November 1998 (stage 2), ~ 2.0 cm/year uplift during November 1998–September 2000 (stage 3), ~ 1.4 cm/year subsidence during September 2000–November 2005 (stage 4), and ~ 0.8 cm/year uplift during November 2005– July 2007 (stage 5). Source modeling indicates a deflationary source less than 2 km below sea level (BSL) beneath the western caldera and two sources beneath the eastern caldera: an inflationary source 2.5–6.0 km BSL and a deflationary source less than 2 km BSL. We suggest that uplift of the eastern caldera is driven by episodic intrusions of basaltic magma into a poroelastic reservoir 2.5–6.0 km BSL beneath the caldera. Cooling and degassing of the reservoir between intrusions results in steady subsidence of the overlying surface. Although we found no evidence of magma intrusion beneath the western caldera during the study period, it is the site (Pyre Peak) of all historical eruptions on the island and therefore cooling and degassing of intrusions presumably contributes to subsidence there as well. Another likely subsidence mechanism in the western caldera is thermoelastic contraction of lava flows emplaced near Pyre Peak during several historical eruptions, most recently in 1977 and 1992–93.

Alaska↗