SEARCH · USGS Science

Results for “Human Organization”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,185 records · Page 66Linked to original sources

USGS2010

Antibiotic, pharmaceutical, and wastewater-compound data for Michigan, 1998-2005

Beginning in the late 1990's, the U.S. Geological Survey began to develop analytical methods to detect, at concentrations less than 1 microgram per liter (ug/L), emerging water contaminants such as pharmaceuticals, personal-care chemicals, and a variety of other chemicals associated with various human and animal sources. During 1998-2005, the U.S. Geological Survey analyzed the following Michigan water samples: 41 samples for antibiotic compounds, 28 samples for pharmaceutical compounds, 46 unfiltered samples for wastewater compounds (dissolved and suspended compounds), and 113 filtered samples for wastewater compounds (dissolved constituents only). The purpose of this report is to summarize the status of emerging contaminants in Michigan waters based on data from several different project-specific sample-collection efforts in Michigan during an 8-year period. During the course of the 8-year sampling effort, antibiotics were determined at 20 surface-water sites and 2 groundwater sites, pharmaceuticals were determined at 11 surface-water sites, wastewater compounds in unfiltered water were determined at 31 surface-water sites, and wastewater compounds in filtered water were determined at 40 surface-water and 4 groundwater sites. Some sites were visited only once, but others were visited multiple times. A variety of quality-assurance samples also were collected. This report describes the analytical methods used, describes the variations in analytical methods and reporting levels during the 8-year period, and summarizes all data using current (2009) reporting criteria. Very few chemicals were detected at concentrations greater than current laboratory reporting levels, which currently vary from a low of 0.005 ug/L for some antibiotics to 5 ug/L for some wastewater compounds. Nevertheless, 10 of 51 chemicals in the antibiotics analysis, 9 of 14 chemicals in the pharmaceuticals analysis, 34 of 67 chemicals in the unfiltered-wastewater analysis, and 56 of 62 chemicals in the filtered-wastewater analysis were detected. Antibiotics were detected at 7 of 20 tested surface-water sites, but none were detected in 2 groundwater samples. Pharmaceuticals were detected at 7 of 11 surface-water sites. Wastewater compounds were detected at 25 of 31 sites for which unfiltered water samples were analyzed and at least once at all 40 surface-water sites and all 4 groundwater sites for which filtered water samples were analyzed. Overall, the chemicals detected most frequently in Michigan waters were similar to those reported frequently in other studies nationwide. Patterns of chemical detections were site specific and appear to be related to local sources, overall land use, and hydrologic conditions at the time of sampling. Field-blank results provide important information for the design of future sampling programs in Michigan and demonstrate the need for careful field-study design. Field-replicate results indicated substantial confidence regarding the presence or absence of the many chemicals tested. Overall, data reported herein indicate that a wide array of antibiotic, pharmaceutical, and organic wastewater compounds occur in Michigan waters. Patterns of occurrence, with respect to hydrologic, land use, and source variables, generally appear to be similar for Michigan as for other sampled waters across the United States. The data reported herein can serve as a basis for future studies in Michigan.

Michigan↗

USGS1966

Geologic effects of the March 1964 earthquake and associated seismic sea waves on Kodiak and nearby islands, Alaska

Kodiak Island and the nearby islands constitute a mountainous landmass with an aggregate area of 4,900 square miles that lies at the western border of the Gulf of Alaska and from 20 to 40 miles off the Alaskan mainland. Igneous and metamorphic rocks underlie most of the area except for a narrow belt of moderately to poorly indurated rocks bordering the Gulf of Alaska coast and local accumulations of unconsolidated alluvial and marine deposits along the streams and coast. The area is relatively undeveloped and is sparsely inhabited. About 4,800 of the 5,700 permanent residents in the area live in the city of Kodiak or at the Kodiak Naval Station. The great earthquake, which occurred on March 27, 1964, at 5:36 p.m. Alaska standard time (March 28,1964, 0336 Greenwich mean time), and had a Richter magnitude of 8.4-8.5, was the most severe earthquake felt on Kodiak Island and its nearby islands in modern times. Although the epicenter lies in Prince William Sound 250 miles northeast of Kodiak—the principal city of the area—the areal distribution of the thousands of aftershocks that followed it, the local tectonic deformation, and the estimated source area of the subsequent seismic sea wave, all suggest that the Kodiak group of islands lay immediately adjacent to, and northwest of, the focal region from which the elastic seismic energy was radiated. The duration of strong ground motion in the area was estimated at 2½ minutes. Locally, the tremors were preceded by sounds audible to the human ear and were reportedly accompanied in several places by visible ground waves. Intensity and felt duration of the shocks during the main earthquake and aftershock sequence varied markedly within the area and were strongly influenced by the local geologic environment. Estimated Mercalli intensities in most areas underlain by unconsolidated Quaternary deposits ranged from VIII to as high as IX. In contrast, intensities in areas of upper Tertiary rock ranged from VII to VIII, and in areas of relatively well indurated lower Tertiary and Mesozoic rocks, from VI to VII. Local subsidence of as much as 10 feet was widespread in noncohesive granular deposits through compaction, flow, and sliding that resulted from vibratory loading during the earthquake. This phenomenon, which was largely restricted to saturated beach and alluvial deposits or artificial fill, was locally accompanied by extensive cracking of the ground and attendant ejection of water and water-sediment mixtures. Numerous landslides, including a wide variety of rockfalls, rockslides, and flows along steep slopes, were triggered by the long-duration horizontal and vertical accelerations during the earthquake. The landslides are most numerous in a narrow belt along the southeast coast of Kodiak Island and the nearby offshore islands. Their abundance appears to be related to an area underlain predominantly by Tertiary rocks. Temporary and permanent changes of level occurred after the earthquake in some wells, lakes, and streams throughout the area; ice was cracked, and the salinity of a few wells increased. Permanent change of water level at some localities appears to be related to readjustments of fracture porosity by earthquake-induced movements of bedrock blocks. Increased salinity of wells in coastal areas resulted from encroachment of seawater into aquifiers after subsidence during the earthquake, and to flooding of watersheds by seismic sea waves. Vertical displacements, both downward and upward, occurred throughout the area as a result of crustal warping along a northeast-trending axis. Most of Kodiak and all of Afognak, Shuyak, and adjacent islands are within a regional zone of subsidence whose trough plunges gently northeastward and approximately coincides with the mountainous backbone of Kodiak Island. Subsidence in excess of 6 feet occurred throughout the northern part of the zone-a maximum subsidence of 6½ feet having occurred on Marmot and, eastern Afognak Islands. Southeast of the axis of tectonic tilting, uplift of at least 2lh feet occurred in a narrow zone that includes most of the southeasterly capes of Kodiak Island, the southeastern half of Sitkalidak Island, and Sitkinak Island. The uplift is inferred to extend offshore over much or all of the continental shelf adjacent to the Kodiak group of islands. Within the affected area, tectonic subsidence, which was locally augmented by surficial subsidence of unconsolidated. deposits, caused widespread inundation of shorelines and attendant damage to intertidal organisms, nearshore terrestrial vegetation, and salmon-spawning areas. The most devastating effect of the earthquake on Kodiak Island and nearby islands resulted from seismic sea waves that probably originated along a linear zone of differential uplift in the Gulf of Alaska. A train of at least seven seismic sea waves, having initial periods of 50–55 minutes, struck along all the southeast coast of the island group from 38 to 63 minutes after the earthquake. The southeast shores were repeatedly washed by destructive waves having runup heights along exposed coasts of perhaps as much as 40 feet above existing tide level, and of 8–20 feet along protected shores. Runup heights of the waves were much less on the northwest and southwest sides of the islands, and no wave damage was incurred there. Locally, high-velocity currents that accompanied the waves caused intense erosion and redistribution of unconsolidated natural and artificial shore deposits and of shallow sea-floor deposits. The Alaska earthquake was the greatest natural catastrophe to befall the Kodiak Island area in historic time. The combination of seismic shock and the earthquake-related tectonic deformation and seismic sea waves took 18 lives, destroyed property worth about $45 million, and resulted in estimated losses of income to the fishing industry of an additional $5 million. Most of the damage and all of the loss of life were directly attributable to the seismic sea waves that crippled the city of Kodiak, wiped out the village of Kaguyak, and destroyed most of the village of Old Harbor and parts of the villages of Afognak and Uzinki. Bridges and segments of the highways in the vicinity of the city of Kodiak were washed out, and parts of the Kodiak Naval Station were inundated and damaged. Especially serious to all the damaged communities was the loss of fishing boats, seafood processing plants, and other waterfront installations, which had been the mainstay of the economy. Additional heavy losses resulted from the combined regional tectonic and local surficial subsidence that occurred during the earthquake. Widespread shoreline flooding by high tides necessitated raising, protecting, or removing many installations otherwise undamaged by the earthquake or waves. Structural damage attributable to seismic shock during the earthquake was relatively light and was restricted to areas underlain by saturated unconsolidated deposits. The chief structural failure in the area as a result of shaking was the collapse of part of a cannery built on saturated beach deposits that were partially liquefied during the earthquake. Minor structural damage resulted from differential settlement and cracking of the ground on natural granular deposits and artificial fills. The overwhelming majority of structures are constructed on indurated bedrock; none of these sustained damage other than small losses resulting from shifting about and breakage of their contents.

Alaska↗

USGS2022

Contaminants of emerging concern in the Great Lakes: Science to inform management practices for protecting the health and integrity of wildlife populations from adverse effects: GLRI action plan I, focus area 1, goal 5

Executive Summary: Under Action Plan I (2010-2014) of the Great Lakes Restoration Initiative (GLRI), Federal and Academic partners began an investigation of the presence and distribution of contaminants of emerging concern (CECs) in the Great Lakes and potential impacts on fish and wildlife. The term CECs is applied to a broad range of chemicals that are currently in use but for which we currently lack good understanding of whether fish, wildlife, or humans are being exposed and/or whether negative health or environmental effects are expected if exposure occurs. Pharmaceuticals, personal care products, flame retardants, many current use pesticides, and poly- and perfluorinated chemicals are some well-known groups of CECs, but there is no definitive or comprehensive list that can be used to support the management of CECs to reduce impacts on the Great Lakes ecosystem. Four overarching goals were identified for this collaborative investigation: 1. Evaluate the sources, occurrence, and distribution of CECs across the Great Lakes Basin. 2. Examine associations between the distribution of CECs and land-use patterns. 3. Review both scientific literature and field-generated data to determine the potential for CECs to cause adverse effects on Great Lakes fish and wildlife populations. 4. Develop efficient strategies to survey and/or monitor for threats that CECs may pose in order to take effective management actions before those threats evolve into large scale impacts on Great Lakes ecosystems or the services they provide. Achievement of these goals ensures progress towards Focus Area 1: Toxic Substances and Areas of Concern from GLRI Action Plan I, Goal 5: “ The health and integrity of wildlife populations and habitat are protected from adverse chemical and biological effects associated with the presence of toxic substances in the Great Lakes Basin ”. This large-scale research effort was comprised of individual and collaborative projects from multiple federal agencies and academic institutions, involving over 85 investigators, and overseen by the U.S. Environmental Protection Agency (EPA) Region 5, Great Lakes National Program Office. Partners include the United States Geological Survey, the National Oceanic and Atmospheric Administration, U.S. Fish and Wildlife Service, Saint Cloud State University, the U.S. EPA Office of Research and Development, and the U.S. Army Corps of Engineers. Key findings: 1. Contaminants of emerging concern were found throughout the monitored Great Lakes tributaries, but types and concentrations vary in association with regional land use. CECs were detected in nearly all samples collected. The type and concentration of the specific contaminants detected varied considerably among field sites and in association with land use type, such as urban, agricultural, wetland, 2 or forest. Contaminants were detected in the water column, sediment, and tissues of all species surveyed in the current work (mussels, aquatic insects, fish, and insect-eating birds). 2. There were over 20 contaminants for which CEC concentrations approached or exceeded those reported to cause toxicity in laboratory experiments. This was based on detection in water, sediments and or biota at one or more field sites. These contaminants represent compounds that warrant further investigation and monitoring with respect to potential impacts in certain areas of the Great Lakes basin. Based on the present investigation, compounds of greatest concern include: polycyclic aromatic hydrocarbons, associated with oil-based products and combustion of organic matter; atrazine, an herbicide; dichlorvos, an insecticide; and ibuprofen and venlafaxine, both pharmaceuticals. 3. Results suggest that mixtures of CECs presently found in most Great Lakes tributary locations surveyed may elicit subtle biological effects, but likely are not, alone, causing obvious detriment to current communities of fish and wildlife. CECs detected in the Great Lakes were associated with subtle biological effects like changes in gene expression, altered circulating glucose, etc. in both wild-caught and laboratory-reared organisms. These effects were generally not indicative of reproductive failure or mortality. However, the effects may have more serious implications when combined with other sources of stress like habitat degradation, changing climate conditions, and competition with invasive species. Due to limited historical data, it is unknown whether severe CEC-related impacts have already affected aquatic communities in waterbodies that have received long-term inputs of these contaminants. Likewise, under Action Plan I, biological effects were not necessarily evaluated at the sites where CEC concentrations exceeding laboratory toxicity thresholds were detected. As a result, strategic, ongoing surveillance and monitoring of CECs is warranted. This collaborative investigation resulted in new tools, approaches, and data that can be used to inform and support the management of CECs to reduce their impacts on Great Lakes natural resources. The following products of this research effort are available through https://communities.geoplatform.gov/glri/ or by contacting the investigators (see technical chapters found in Appendices A-F): 1. Database of CEC occurrence and concentrations in US tributary streams. The database includes CEC detections in water, sediment, and fish and wildlife tissues, and represents the most comprehensive survey of CECs in the Great Lakes Region. 2. Synopses of results and key findings. Integrated summaries of results, conclusions, and management implications of the CEC research are available through reports, topical fact sheets, and presentations. 3. Technical publications: This collaborative research effort has resulted in over 50 peer-reviewed publications, agency reports, and data releases that can be of use to resource managers, the scientific community, and members of the public. 4. Innovative tools. Innovative monitoring devices, sampling equipment, conceptual frameworks, and software applications were developed over the course of this 3 research. These tools are transferable to stakeholders via internet accessibility or via specifications, instructions, and demonstration detailed in technical publications. Hypotheses to guide CECs research under Action Plan II. Findings from 2010-2014 were used to guide further research in 2015-2018 for basin-wide surveillance of CECs and for sites warranting further study of potential biological impacts of CECs. Additional surveillance included both evaluation of additional classes of contaminants and expanded lists for chemical classes shown to be of greatest concern. Mixtures of some of the most frequently detected contaminants were also tested in laboratory studies to understand whether long term exposures to multiple contaminants may result in effects not evident from uncontrolled, short-term field experiments.

Great Lakes↗

USGS1979

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report↗

USGS2009

Character and Trends of Water Quality in the Blue River Basin, Kansas City Metropolitan Area, Missouri and Kansas, 1998 through 2007

Water-quality and ecological character and trends in the metropolitan Blue River Basin were evaluated from 1998 through 2007 to provide spatial and temporal resolution to factors that affect the quality of water and biota in the basin and provide a basis for assessing the efficacy of long-term combined sewer control and basin management plans. Assessments included measurements of stream discharge, pH, dissolved oxygen, specific conductance, turbidity, nutrients (dissolved and total nitrogen and phosphorus species), fecal-indicator bacteria (Escherichia coli and fecal coliform), suspended sediment, organic wastewater and pharmaceutical compounds, and sources of these compounds as well as the quality of stream biota in the basin. Because of the nature and myriad of factors that affect basin water quality, multiple strategies are needed to decrease constituent loads in streams. Strategies designed to decrease or eliminate combined sewer overflows (CSOs) would substantially reduce the annual loads of nutrients and fecal-indicator bacteria in Brush Creek, but have little effect on Blue River loadings. Nonpoint source reductions to Brush Creek could potentially have an equivalent, if not greater, effect on water quality than would CSO reductions. Nonpoint source reductions could also substantially decrease annual nutrient and bacteria loadings to the Blue River and Indian Creek. Methods designed to decrease nutrient loads originating from Blue River and Indian Creek wastewater treatment plants (WWTPs) could substantially reduce the overall nutrient load in these streams. For the main stem of the Blue River and Indian Creek, primary sources of nutrients were nonpoint source runoff and WWTPs discharges; however, the relative contribution of each source varied depending on how wet or dry the year was and the number of upstream WWTPs. On Brush Creek, approximately two-thirds of the nutrients originated from nonpoint sources and the remainder from CSOs. Nutrient assimilation processes, which reduced total nitrogen loads by approximately 13 percent and total phosphorus loads by double that amount in a 20-kilometer reach of the Blue River during three synoptic base-flow sampling events between August through September 2004 and September 2005, likely are limited to selected periods during any given year and may not substantially reduce annual nutrient loads. Bacteria densities typically increased with increasing urbanization, and bacteria loadings to the Blue River and Indian Creek were almost entirely the result of nonpoint source runoff. WWTPs contributed, on average, less than 1 percent of the bacteria to these reaches, and in areas of the Blue River that had combined sewers, CSOs contributed only minor amounts (less than 2 percent) of the total annual load in 2005. The bulk of the fecal-indicator bacteria load in Brush Creek also originated from nonpoint sources with the remainder from CSOs. From October 2002 through September 2007, estimated daily mean Escherichia coli bacteria density in upper reaches of the Blue River met the State of Missouri secondary contact criterion standard approximately 85 percent of the time. However, in lower Blue River reaches, the same threshold was exceeded approximately 45 percent of the time. The tributary with the greatest number of CSO discharge points, Brush Creek, contributed approximately 10 percent of the bacteria loads to downstream reaches. The tributary Town Fork Creek had median base-flow Escherichia coli densities that were double that of other basin sites and stormflow densities 10 times greater than those in other parts of the basin largely because approximately one-fourth of the runoff in the Town Fork Creek Basin is believed to originate in combined sewers. Genotypic source typing of bacteria indicated that more than half of the bacteria in this tributary originated from human sources with two storms contributing the bulk of all bacteria sourced as human. However, areas outsid

Scientific Investigations Report↗

USGS1995

Presence, distribution, and potential sources of nitrate and selected pesticides in the surficial aquifer along the Straight River in north-central Minnesota, 1992-93

The presence and distribution of nitrate and selected pesticides in ground water in the surficial aquifer along the Straight River in north-central Minnesota were studied. Local residents and public officials are concerned that these substances may pose a health hazard to humans and livestock. Nitrate and pesticides may move downward from cultivated croplands, livestock feedlots and manured fields, waste-water lagoons, and residential development to the ground water. Ground water near the water table ranged in nitrate-nitrogen concentration (based on median values determined for sampled monitoring wells) from less than 5 to a little greater than 20 mg/L (milligrams per liter) except for one concentration of 50 mg/L downgradient from a feedlot and manured field. Increased nitrate-nitrogen concentrations generally were coincident with cultivated croplands. Decreased nitrate-nitrogen concentrations generally were coincident with forests. Trace amounts of atrazine were detected in 4 of 8 ground-water samples collected from 8 monitoring wells screened near the water table. Detections were more frequent in cultivated croplands (detections at 3 of 5 monitoring wells) than in forests (detections at 1 of 3 monitoring wells). Atrazine concentrations ranged from 0.01 to 0.11 ( μ g/L (micrograms per liter), which are well below the MCL (Maximum Contaminant Level) of 3 μ g/L established by the USEPA (U.S. Environmental Protection Agency). Trace amounts of metolachlor and alachlor were detected in one of the samples in which atrazine was detected. MCLs for metolachlor and alachlor have not been established by the USEPA. The median nitrate-nitrogen concentration determined from sampled monitoring wells along the direction of ground-water flow through five land-use settings: (1) increased from slightly greater than 0 to 50 mg/L near the water table at a feedlot and an adjacent manured field; animal waste was a nitrate source; (2) increased from 8.0 to 16 mg/L near the water table at cultivated croplands irrigated with municipal treated waste water; fertilizer probably was a nitrate source; (3) increased from slightly greater than 0 to 14 mg/L near the bottom of the aquifer at cultivated croplands irrigated with ground water; fertilizer probably was a nitrate source; (4) increased from 1.6 to 3.7 mg/L near the water table and from slightly greater than 0 to 2.8 mg/L near the bottom of the aquifer at a residential development; septic-system leachates, and possibly lawn fertilizer, may have been nitrate sources; and (5) decreased from 14 to 2.6 mg/L near the water table at three waste-water treatment lagoons; waste water was not a nitrate source. Upgradient to downgradient mean or individual nitrogen isotope δ 15 N values in % o (delta units in parts per thousand) determined for sampled monitoring wells along the direction of ground-water flow through the five land-use settings were: (1) 5.1 % o and 4.0 % o for the feedlot and adjacent manured field; (2) 1.1 % o and 0.9 % o for the cultivated croplands irrigated with waste water; (3) 3.8 % o and 2.7 % o for the cultivated croplands irrigated with ground water; (4) 3.4 % o and 4.9 % o for the residential development; and (5) 1.7 % o and 3.0 % o for the three waste-water lagoons. Nitrate from fertilizer appeared to have been present in ground water at the waste-water lagoons, cultivated croplands irrigated with waste water, and cultivated croplands irrigated with ground water. Nitrate from soil organic matter rather than from animal waste appeared to have been present in ground water at the feedlot and adjacent manured field.

Minnesota↗

USGS1996

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Vermejo Project area and the Maxwell National Wildlife Refuge, Colfax County, northeastern New Mexico, 1993

Based on findings of limited studies during 1989-92, a reconnaissance investigation was conducted in 1993 to assess the effects of the Vermejo Irrigation Project on water quality in the area of the project, including the Maxwell National Wildlife Refuge. This project was part of a U.S. Department of the Interior National Irrigation Water-Quality Program to determine whether irrigation drainage has caused or has the potential to cause significant harmful effects on human health, fish, and wildlife and whether irrigation drainage may adversely affect the suitability of water for other beneficial uses. For this study, samples of water, sediment, and biota were collected from 16 sites in and around the Vermejo Irrigation Project prior to, during the latter part of, and after the 1993 irrigation season (April, August-September, and November, respectively). No inorganic constituents exceeded U.S. Environmental Protection Agency drinking-water standards. The State of New Mexico standard of 750 micrograms per liter for boron in irrigation water was exceeded at three sites (five samples), though none exceeded the livestock water standard of 5,000 micrograms per liter. Selenium concentrations exceeded the State of New Mexico chronic standard of 2 micrograms per liter for wildlife and fisheries water in at least eight samples from five sites. Bottom-sediment samples were collected and analyzed for trace elements and compared to concentrations of trace elements in soils of the Western United States. Concentrations of three trace elements at eight sites exceeded the upper values of the expected 95-percent ranges for Western U.S. soils. These included molybdenum at one site, selenium at seven sites, and uranium at four sites. Cadmium and copper concentrations exceeded the National Contaminant Biomonitoring Program 85th percentile in fish from six sites. Average concentrations of selenium in adult brine flies (33.7 μ g/g dry weight) were elevated above concentrations in other invertebrates. Concentrations of other elements were below their respective toxicity levels. Plants, invertebrates, fish, and fish fillets were collected and analyzed. These analyses were compared to diagnostic criteria and to each other to determine the extent of bioaccumulation of trace elements. Plants contained larger dry weight concentrations of aluminum, arsenic, boron, chromium, iron, lead, magnesium, manganese, nickel, and vanadium than invertebrates and fish. Adult brine flies, gathered from playas, contained larger geometric mean dry weight concentrations of boron, magnesium, and selenium than other invertebrates. Of all samples collected, the largest mercury concentrations were found in fish fillets, although these concentrations were below levels of concern. Mercury and selenium bioaccumulation was evident in various habitats of the study area. Biological samples from Natural playa, an endemic wetland, and Half playa, a playa that receives additional water through seepage and irrigation delivery canals, generally had elevated concentrations of boron, iron, magnesium, and selenium than samples from reservoir and river sites. Selenium concentrations were lowest in biota from the two reservoir sites, although a wetland immediately downstream from the dam impounding Lake No. 13 (created by seepage from the reservoir) had elevated concentrations of selenium in biota. The geometric mean selenium concentration of whole-fish samples, except those from Lakes No. 13 and No. 14, exceeded the 5- μ g/g dry weight selenium concentration that demarcates the approximate lower limit of the threshold range of concentrations that have freen associated with adverse effects on piscine reproduction. Biota collected on and in the area around Maxwell National Wildlife Refuge contained concentrations of selenium that are in the lower range of threshold values that have been associated (dietarily) with risks of avian reproductive abnormalities. Bottom-sediment samples from two sites downstream from the irrigation project were collected and analyzed for 23 organic compounds (principally organochlorine pesticide residues). Three compounds were detected at the two sites: DDD was found at 0.2 microgram per kilogram, DDE was detected at 0.1 microgram per kilogram at both sites, and chlordane was detected at 1 microgram per kilogram. None of the 28 whole-fish and fillet samples analyzed for PCB and organochlorine pesticide residues contained any of the 23 organic compounds tested for at concentrations higher than the analytical reporting limit (less than 0.01 μ g/g wet weight). Concentrations of inorganic analytes were generally within established guidelines or expected concentrations for water, sediment, and biota. lirigation-return flows were found to be unrelated to adverse effects in biota.

New Mexico↗

USGS2015

Chemicals of emerging concern in water and bottom sediment in the Great Lakes Basin, 2012: collection methods, analytical methods, quality assurance, and study data

In synoptic surveys of surface-water quality across the United States, a large group of organic chemicals associated with agricultural, household, and industrial waste have been detected. These chemicals are referred to collectively as chemicals of emerging concern (CECs) and include prescription drugs and antibiotics, over-the-counter medications, reproductive hormones, personal-care products, detergent metabolites, and flame retardants. The U.S. Geological Survey (USGS) collaborated with the U.S. Fish and Wildlife Service and the U.S. Environmental Protection Agency on a study to identify the presence of CECs in water and bottom-sediment samples collected during 2012 at 66 sites throughout the Great Lakes Basin. The 2012 effort is part of a long-term study that was initiated in 2010. The purposes of this report are to document the collection and analytical methods, provide the quality-assurance data and analyses, and provide the water and bottom-sediment data for this study of CECs in the Great Lakes Basin for 2012. A previous report documents data collected during 2010 and 2011. The methods used for chemical analyses were identical between the 2010–11 and 2012 studies, with the exception that a method to determine nontarget chemicals was used during 2010–11. The data from this study are published as a USGS Data Series Report to ensure adequate documentation of the original methods and provide a citable source for study data. This report contains no interpretations of the study data. The chemical data are as reported by the laboratory and have not been censored or adjusted unless otherwise noted. Field measurements were recorded and samples were collected in April and May and in September 2012, by U.S. Geological Survey, U.S. Fish and Wildlife Service, and U.S. Environmental Protection Agency personnel. Study sites included tributaries to the Great Lakes located near Duluth, Minnesota; King, Wisconsin; Green Bay, Wis.; Detroit, Michigan; Monroe, Mich.; Toledo, Ohio, and Rochester, New York. Water and bottom-sediment samples were analyzed at the USGS National Water Quality Laboratory in Denver, Colorado, for a broad suite of CECs. During this 2012 study, 140 environmental and 8 field duplicate samples of surface water and wastewater effluent, 1 field blank water sample, and 5 field spike water samples were collected or prepared. Water samples were analyzed at the USGS National Water Quality Laboratory using laboratory schedule 4433 for wastewater indicators, research method 8244 for pharmaceuticals, and laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A. For wastewater indicators in unfiltered water, 61 of the 68 chemicals analyzed using laboratory schedule 4433 had detectable concentrations ranging from 0.002 to 64.4 micrograms per liter. Thirty-eight of the 48 chemicals analyzed using research method 8244 for pharmaceuticals in unfiltered water had detectable concentrations ranging from 0.002 to 3.32 micrograms per liter. Twelve of the 20 chemicals analyzed using laboratory schedule 4434 for steroid hormones, sterols, and bisphenol A in unfiltered water had detectable concentrations ranging from 0.43 to 120,000 nanograms per liter. During this study, 53 environmental samples, 4 field duplicate samples, and 8 field spike samples of bottom sediment and laboratory matrix-spike samples were analyzed for a wide variety of CECs at the USGS National Water Quality Laboratory using laboratory schedule 5433 for wastewater indicators; research method 6434 for steroid hormones, sterols, and bisphenol A; and research method 9008 for human-use pharmaceuticals and antidepressants. Forty of the 57 chemicals analyzed using laboratory schedule 5433 had detectable concentrations ranging from 1 to 49,000 micrograms per kilogram. Fourteen of the 20 chemicals analyzed using research method 6434 had detectable concentrations ranging from 0.04 to 24,940 nanograms per gram. Ten of the 20 chemicals analyzed using research method 9008 had detectable concentrations ranging from 0.59 to 197.5 micrograms per kilogram. Five of the 11 chemicals analyzed using research method 9008 had detectable concentrations ranging from 1.16 to 25.0 micrograms per kilogram.

Great Lakes Basin↗

USGS2003

Sediment deposition and occurrence of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Perry Lake, northeast Kansas, 1969–2001

A combination of bathymetric surveying and bottom-sediment coring was used to investigate sediment deposition and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 26 metals and trace elements, 15 organochlorine compounds, 1 radionuclide, and diatoms in bottom sediment of Perry Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1969 through 2001 in the original conservation-pool area of the lake was 2,470 million cubic feet (56,700 acre-feet) and 97,200 million pounds (44,100 million kilograms), respectively. The estimated sediment volume occupied about 23 percent of the original conservation-pool, water-storage capacity of the lake. Mean annual net sediment deposition since 1969 was estimated to be 3,040 million pounds (1,379 million kilograms). Mean annual sediment yield from the Perry Lake Basin was estimated to be 2,740,000 pounds per square mile (4,798 kilograms per hectare). The estimated mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Perry Lake were 7,610,000 pounds per year (3,450,000 kilograms per year) and 3,350,000 pounds per year (1,520,000 kilograms per year), respectively. The estimated mean annual yields of total nitrogen and total phosphorus from the Perry Lake Basin were 6,850 pounds per square mile per year (12.0 kilograms per hectare per year) and 3,020 pounds per square mile per year (5.29 kilograms per hectare per year), respectively. A statistically significant positive trend for total nitrogen deposition in the bottom sediment of Perry Lake was indicated. However, the trend may be due solely to analytical variance. No statistically significant trend for total phosphorus deposition was indicated. Overall, the transport and deposition of these constituents have been relatively uniform throughout the history of Perry Lake. On the basis of nonenforceable sediment-quality guidelines established by the U.S. Environmental Protection Agency, concentrations of arsenic, chromium, copper, and nickel in the bottom sediment of Perry Lake typically exceeded the threshold-effects levels, which represent the concentrations above which toxic biological effects occasionally occur. Most nickel concentrations also exceeded the probable-effects level, which represents the concentration above which toxic biological effects usually or frequently occur. Sediment concentrations of metals and trace elements were relatively uniform over time. Statistically significant positive depositional trends for arsenic and manganese and statistically significant negative depositional trends for beryllium, chromium, titanium, and vanadium were indicated. However, the trends may be due solely to analytical variance. Organochlorine compounds either were not detected or were detected at concentrations less than the threshold-effects levels. Evidence of a negative depositional trend for DDE (degradation product of DDT) was consistent with the history of DDT use. Other organochlorine compounds detected were DDD and dieldrin. Diatom occurrence in the bottom sediment of Perry Lake was dominated by species that are indicators of eutrophic (nutrient-rich) conditions. Thus, it was concluded that eutrophic conditions have existed during much of the history of Perry Lake. However, an increase in the relative percentage abundance of the oligotrophic (nutrient-poor) species, combined with the significant positive depositional trends for two oligotrophic species ( Aulacoseira islandica and Cyclotella radiosa ) and the significant negative depositional trend for one eutrophic species ( Stephanodiscus niagarae ), indicated that conditions in Perry Lake may have become less eutrophic in recent years. Notable changes in human activity within the basin included a substantial decrease in alfalfa production and a substantial increase in soybean production from 1965 to 2000. These and other changes in human activity may have had some effect on the deposition of chemical constituents and diatoms in the bottom sediment of Perry Lake. It is uncertain whether changes in human activity may account, in part, for the possibility of Perry Lake becoming less eutrophic over time as indicated by trends in the deposition of several diatom species in the lake-bed sediment.

Kansas↗

USGS2007

Organic-carbon sequestration in soil/sediment of the Mississippi River deltaic plain — Data; landscape distribution, storage, and inventory; accumulation rates; and recent loss, including a post-Katrina preliminary analysis

Soil/sediment of the Mississippi River deltaic plain (MRDP) in southeastern Louisiana is rich in organic carbon (OC). The MRDP contains about 2 percent of all OC in the surface meter of soil/sediment in the Mississippi River Basin (MRB). Environments within the MRDP differ in soil/sediment organic carbon (SOC) accumulation rate, storage, and inventory. The focus of this study was twofold: (1) develop a database for OC and bulk density for MRDP soil/sediment; and (2) estimate SOC storage, inventory, and accumulation rates for the dominant environments (brackish, intermediate, and fresh marsh; natural levee; distributary; backswamp; and swamp) in the MRDP. Comparative studies were conducted to determine which field and laboratory methods result in the most accurate and reproducible bulk-density values for each marsh environment. Sampling methods included push-core, vibracore, peat borer, and Hargis1 sampler. Bulk-density data for cores taken by the "short push-core method" proved to be more internally consistent than data for samples collected by other methods. Laboratory methods to estimate OC concentration and inorganic-constituent concentration included mass spectrometry, coulometry, and loss-on-ignition. For the sampled MRDP environments, these methods were comparable. SOC storage was calculated for each core with adequate OC and bulk-density data. SOC inventory was calculated using core-specific data from this study and available published and unpublished pedon data linked to SSURGO2 map units. Sample age was estimated using isotopic cesium ( 37 Cs), lead ( 210 Pb), and carbon ( 14 C), elemental Pb, palynomorphs, other stratigraphic markers, and written history. SOC accumulation rates were estimated for each core with adequate age data. Cesium-137 profiles for marsh soil/sediment are the least ambiguous. Levee and distributary 137 Cs profiles show the effects of intermittent allochthonous input and/or sediment resuspension. Cesium-137 and 210 Pb data gave the most consistent and interpretable information for age estimations of soil/sediment deposited during the 1900s. For several cores, isotopic 14 C and 137 Cs data allowed the 1963-64 nuclear weapons testing (NWT) peak-activity datum to be placed within a few-centimeter depth interval. In some cores, a too old 14 C age (when compared to 137 Cs and microstratigraphic-marker data) is the probable result of old carbon bound to clay minerals incorporated into the organic soil/sediment. Elemental Pb coupled with Pb source-function data allowed age estimation for soil/sediment that accumulated during the late 1920s through the 1980s. Exotic pollen (for example, Vigna unguiculata and Alternanthera philoxeroides ) and other microstratigraphic indicators (for example, carbon spherules) allowed age estimations for marsh soil/sediment deposited during the settlement of New Orleans (1717-20) through the early 1900s. For this study, MRDP distributary and swamp environments were each represented by only one core, backswamp environment by two cores, all other environments by three or more cores. MRDP core data for the surface meter soil/sediment indicate that (1) coastal marshes, abandoned distributaries, and swamps have regional SOC-storage values >16 kg m -2 ; (2) swamps and abandoned distributaries have the highest SOC storage values (swamp, 44.8 kg m -2 ; abandoned distributary, 50.9 kg m -2 ); (3) fresh-to-brackish marsh environments have the second highest site-specific SOC-storage values; and (4) site-specific marsh SOC storage values decrease as the salinity of the environment increases (fresh-marsh, 36.2 kg m -2 ; intermediate marsh, 26.2 kg m -2 ; brackish marsh, 21.5 kg m -2 ). This inverse relation between salinity and SOC storage is opposite the regional systematic increase in SOC storage with increasing salinity that is evident when SOC storage is mapped by linking pedon data to SSURGO map units (fresh marsh, 47 kg m -2 ; intermediate marsh, 67 kg m -2 ; brackish marsh, 75 kg m -2 ; and salt marsh, 80 kg m -2 ). MRDP core data for this study also indicate that levees and backswamp have regional SOC-storage values <16 kg m -2 . Group-mean SOC storage for cores from these environments are natural levee (17.0 kg m -2 ) and backswamp (14.1 kg m -2 ). An estimate for the SOC inventory in the surface meter of soil/sediment in the MRDP can be made using the SSURGO mapped portion of the coastal-marsh vegetative-type map (13,236 km 2 , land-only area) published by the Louisiana Department of Wildlife and Fisheries and U.S. Geological Survey (1997). This area has a SOC inventory (surface meter) of 677 Tg (slightly more than 2 percent of the 30,289 Tg SOC inventory for the MRB). The MRDP (6,180 km2, land-only area) has an estimated SOC inventory of 397 Tg. Most of the MRDP is located within the SSURGO mapped coastal marshlands. The entire MRDP, including water, has an area of about 10,800 km 2 . Using the ratio of total MRDP area to SSURGO mapped MRDP area as an adjustment, the MRDP SOC inventory is estimated at 694 Tg. This larger estimate of 694 Tg for the SOC inventory is probably more realistic, because it is reasonable to assume that the marsh sediments overlain by shallow water have comparable SOC storage to that of the adjacent land areas. MRDP core data for this study indicate that there is some variability in long-term SOC mass-accumulation rates for centuries and millennia and that this variability may indicate important geologic changes or changes in land use. However, the consistency of the range in rates of SOC accumulation through time suggests a remarkable degree of marsh sustainability throughout the Holocene, including the recent period of significant marsh modification/channelization for human use. One example of marsh sustainability is its present ability to function as a SOC sink even with Louisiana's large-scale coastal land loss during the last several decades. With coastal-marsh restoration efforts, this sink potential will increase. Looking to the future, a total of 1,101 g m -2 yr -1 SOC is projected to be lost from all of coastal Louisiana (U.S. Army Corps of Engineers, Louisiana Coastal Area (LCA) subprovinces 1-4; not just the MRDP) through coastal erosion from year 2000 to 2050. This translates to a projected SOC-loss rate of about 0.20 percent per year. The recent Hurricanes Katrina and Rita, which devastated the Louisiana coast during late August and late September 2005, transformed about 259 km 2 (100 mi 2 ) of marsh to open water (U.S. Geological Survey, 2005). To the extent that some or all of this land loss is permanent, this result equates to a SOC loss of about 15 Tg. This estimate is based on the year-2000 15,153-km 2 land area for the LCA study area that includes LCA subprovince 4. Using the year-2000 land area, the LCA study area had an estimated SOC inventory of 858 Tg. The estimated 15 Tg SOC loss attributable to Hurricanes Katrina and Rita is 1.7 percent of the year-2000 LCA inventory and 2.3 percent of the year-2000 MRDP inventory. If this SOC loss is included in the projection for the year 2050, then the MRDP would either remain a source with a net SOC loss of 3 Tg or become a weak sink with a net SOC gain of 4 Tg. These estimates are lower bounds for potential SOC flux because they are only for the surface meter of landmass.

Louisiana↗

USGS2009

Factors affecting water quality in selected carbonate aquifers in the United States, 1993-2005

Carbonate aquifers are an important source of water in the United States; however, these aquifers can be particularly susceptible to contamination from the land surface. The U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program collected samples from wells and springs in 12 carbonate aquifers across the country during 1993–2005; water-quality results for 1,042 samples were available to assess the factors affecting ground-water quality. These aquifers represent a wide range of climate, land-use types, degrees of confinement, and other characteristics that were compared and evaluated to assess the effect of those factors on water quality. Differences and similarities among the aquifers were also identified. Samples were analyzed for major ions, radon, nutrients, 47 pesticides, and 54 volatile organic compounds (VOCs). Geochemical analysis helped to identify dominant processes that may contribute to the differences in aquifer susceptibility to anthropogenic contamination. Differences in concentrations of dissolved oxygen and dissolved organic carbon and in ground-water age were directly related to the occurrence of anthropogenic contaminants. Other geochemical indicators, such as mineral saturation indexes and calcium-magnesium molar ratio, were used to infer residence time, an indirect indicator of potential for anthropogenic contamination. Radon exceeded the U.S. Environmental Protection Agency proposed Maximum Contaminant Level (MCL) of 300 picocuries per liter in 423 of 735 wells sampled, of which 309 were drinking-water wells. In general, land use, oxidation-reduction (redox) status, and degree of aquifer confinement were the most important factors affecting the occurrence of anthropogenic contaminants. Although none of these factors individually accounts for all the variation in water quality among the aquifers, a combination of these characteristics accounts for the majority of the variation. Unconfined carbonate aquifers that had high percentages of urban or agricultural land, or a combination of both, had higher concentrations and higher frequency of detections for most of the anthropogenic contaminants than areas with other combinations of land use and degree of aquifer confinement. Redox status is an indicator of more recently recharged water and affects the fate of some contaminants. Median concentrations of nitrate were highest in the Valley and Ridge and Piedmont aquifers and lowest in the Biscayne and Silurian-Devonian/Upper carbonate aquifers. Nitrate concentrations were significantly higher in unconfined aquifers than in confined aquifers and semiconfined/mixed confined aquifers (wells in aquifers with breached confining layers or wells open to both a confined and an unconfined aquifer). Water recharged after 1953 had significantly higher concentrations of nitrate than water recharged prior to 1953. Redox status was also a key factor affecting nitrate concentrations; in recently recharged waters, samples in oxic waters had significantly higher concentrations of nitrate than anoxic waters, regardless of land use in the area around the well. Samples from 54 wells (5 percent) exceeded the U.S. Environmental Protection Agency MCL of 10 mg/L for nitrate in drinking water. Most of the samples exceeding the drinking-water standard (52 samples, or 5 percent) were in domestic supply wells in agricultural areas. The Piedmont and Valley and Ridge aquifers had the largest number of samples (45) exceeding the MCL; in the remaining aquifers only 9 samples had concentrations of nitrate that exceeded the MCL (about 1 percent). None of the water recharged prior to 1953 and only a single sample from a confined aquifer had nitrate concentrations that exceeded 10 mg/L as N. Wells were sampled for a minimum of 47 pesticides. Detection frequencies and comparisons varied depending on the assessment level used. At least 1 of the 47 pesticides was detected at 510 (50 percent) of the 1,027 sites where pesticide data were available using the ‘all detections’ assessment level—that is, including any quantified detection as well as any estimated values where the compound was definitively detected. Multiple pesticides were frequently detected in a sample of water from a site; 34 percent of the samples had two to five pesticides detected in the same sample, and 4 percent of the samples had six or more pesticides detected. Dieldrin was detected at 20 sites, 9 of which were from either domestic or public supply wells, at a concentration above the Health-Based Screening Level (HBSL) of 0.002 µg/L. Diazinon was detected at a concentration greater than the HBSL of 1 µg/L at a single site, which was also a domestic supply well. These are the only samples where a pesticide exceeded a human-health benchmark. The most frequently occurring pesticide compounds were four herbicides—atrazine, simazine, metolachlor, and prometon—and deethylatrazine, a degradate of atrazine. These pesticides typically were detected at concentrations that were less than 10 percent of a human-health benchmark. Of the four frequently occurring pesticides, only samples for atrazine (3 percent) and simazine (0.1 percent) had concentrations that exceeded 10 percent of the human-health benchmark; most of these cases were in agricultural areas. It is important to note, however, that the most frequently occurring pesticide degradate compound—deethylatrazine—has no human-health benchmark. Using a common assessment level of 0.01 µg/L, four of the aquifers—Biscayne, Mississippian, Piedmont, and Valley and Ridge—had at least one of these five compounds detected in more than 30 percent of the wells sampled. These four aquifers, along with the Ordovician, Ozark Plateaus, and Prairie du Chien aquifers were the aquifers or aquifer systems that had concentrations of pesticides that exceeded 10 percent of a human-health benchmark. Water recharged after 1953 had a significantly higher percentage of detections of pesticides than water recharged before 1953, and water from unconfined aquifers had a significantly higher percentage of detections of pesticides than water from confined or semiconfined/mixed confined aquifers. Water from sites in unconfined aquifers, where land use was agricultural or urban, accounted for the vast majority of detections of pesticides. Dissolved oxygen concentration was positively related to pesticide occurrence, which likely reflects the positive association between dissolved oxygen concentration and recently recharged water. Water samples were collected for analysis of VOCs at 793 sites—154 samples were analyzed for 54 VOCs from 1993 through 1995 and 639 samples were analyzed for 86 VOCs from 1996 through 2005. Twenty percent of samples contained one or more VOCs at concentrations greater than or equal to 0.2 µg/L (159 of 793 samples). The aquifers with the highest percentage of samples containing one or more VOCs were the Castle Hayne (about 41 percent of samples) and Biscayne aquifers (34 percent). The most frequently detected VOCs were chloroform, tetrahydrofuran, tetrachloroethene (PCE), toluene, acetone, ethylmethylketone, methyl tert-butyl ether (MTBE), and trichloroethene (TCE). Low-level concentrations of VOCs occurred in a much larger percentage of a subset of the data (the 639 samples analyzed using a low-level analytical method). In these samples, 69 percent of the 639 samples contained 1 or more VOCs, indicating the vulnerability of the carbonate aquifers to low-level VOC contamination. Four VOCs were detected at concentrations exceeding their respective MCLs in five samples, all of which were from drinking-water wells. Vinyl chloride concentrations exceeded the MCL of 2 µg/L in two samples from urban areas in the unconfined Biscayne aquifer. PCE, TCE, and 1,2-dichloropropane each had one sample with a concentration greater than their MCLs of 5 µg/L; these samples were from agricultural and urban areas in the unconfined Mississippian aquifer. Water quality in the 12 carbonate aquifers was highly variable. Most of the samples met drinking-water standards. The occurrence of anthropogenic contaminants was related to contaminant sources but also was affected by degree of aquifer confinement, ground-water age, and redox status. Areas with higher amounts of agricultural or urban land in unconfined aquifers were the most likely to have elevated concentrations of anthropogenic contaminants.

Scientific Investigations Report↗

USGS2001

Quality of water in alluvial aquifers in eastern Iowa

The goal of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is to assess the status and trends in the quality of the Nation's surface and ground water, and to better understand the natural and human factors affecting water quality. The Eastern Iowa Basins study unit encompasses an area of about 50,500 square kilometers (19,500 square miles) in eastern Iowa and southern Minnesota and is one of 59 study units in the NAWQA program. Land-use studies are an important component of the NAWQA program, and are designed to assess the concentration and distribution of water-quality constituents in recently recharged ground water associated with the most significant land use and hydrogeologic settings within a study unit. The focus of the land-use study in the Eastern Iowa Basins study unit is agricultural and urban land uses and alluvial aquifers. Agriculture is the dominant land use in the study unit. Urban areas, although not extensive, represent important potential source areas of contaminants associated with residential, commercial, and industrial activities. Alluvial aquifers are present throughout much of the study unit, and constitute a major ground-water supply that is susceptible to contamination from land-use activities. Ground-water samples were collected from monitoring wells at 31 agricultural and 30 urban sites in the Eastern Iowa Basins study unit during June-August 1997 to evaluate the effects of land use and hydrogeology on the water quality of alluvial aquifers. Calcium, magnesium, and bicarbonate were the dominant ions in most samples and were likely derived from solution of carbonate minerals (calcite and dolomite) present in alluvial detrital deposits. Tritium-based ages indicate ground water was most likely recharged after the 1950's at all but one sampling site. Agricultural and urban land-use areas have remained relatively stable in the study area since the 1950's, therefore the effects of current land use should be reflected in ground water sampled during this study. Sodium and chloride concentrations were significantly higher in samples from urban areas, where roads are more numerous and road salts may be more frequently applied, than in agricultural areas. Nitrate was detected in 94 percent of samples from agricultural areas and 77 percent of samples from urban areas. Nitrate concentrations were significantly higher in agricultural areas than in urban areas and exceeded the U.S. Environmental Protection Agency maximum contaminant level for drinking water (10 milligrams per liter as N) in 39 percent of samples from agricultural areas. Nitrate concentrations in samples from urban areas did not exceed the maximum contaminant level. Greater usage of fertilizers in agricultural areas most likely contributes to higher nitrate concentrations in samples from those areas. Pesticides were detected in 84 percent of samples from agricultural areas and 70 percent from urban areas. Atrazine and metolachlor were the most frequently detected pesticides in samples from agricultural areas; atrazine and prometon were the most frequently detected pesticides in samples from urban areas. None of the pesticide concentrations exceeded U.S. Environmental Protection Agency maximum contaminant levels or lifetime health advisories for drinking water. Pesticide degradates were detected in 94 percent of samples from agricultural areas and 53 percent from urban areas. Metolachlor ethane sulfonic acid and deethylatrazine were the most frequently detected metabolites in samples from agricultural areas; metolachlor ethane sulfonic acid and alachlor ethane sulfonic acid were the most frequently detected degradates in samples from urban areas. Total degradate concentrations were significantly higher in samples from agricultural areas than in samples from urban areas. Total pesticide concentrations (parent compounds) tended to be higher in samples from agricultural areas; however, this difference was not statistically significant. Degradates constituted the major portion of the total residue concentration in the alluvial aquifer. Volatile organic compounds were detected in 40 percent of samples from urban areas and 10 percent from agricultural areas. Methyl tert-butyl ether was the most commonly detected volatile organic compound and was present in 23 percent of samples from urban areas. Elevated concentrations (greater than 30 micrograms per liter) of methyl tert-butyl ether and BTEX compounds (benzene, toluene, ethylbenzene, and xylene) in two samples from urban areas suggest the possible presence of point-source gasoline leaks or spills. Factors other than land use may contribute to observed differences in water quality between and within agricultural and urban areas. Nitrate, atrazine, deethylatrazine, and deisopropylatrazine concentrations were significantly higher in shallow wells with sample intervals nearer the water table and in wells with thinner cumulative clay thickness above the sample intervals, suggesting that longer flow paths allow for greater residence time and increase opportunities for sorbtion, degradation, and dispersion which may contribute to decreases in nutrient and pesticide concentrations with depth. Nitrogen speciation was influenced by redox conditions. Nitrate concentrations were significantly higher in ground water with dissolved-oxygen concentrations in excess of 0.5 milligrams per liter. Ammonia concentrations were higher in ground water with dissolved-oxygen concentrations of 0.5 milligrams per liter or less, however, this relation was not statistically significant. The amount of available organic matter may limit denitrification rates. Elevated nitrate concentrations (greater than 2.0 mg/L) were significantly related to lower dissolved organic carbon concentrations in water samples from both agricultural and urban areas. A similar relation between nitrate concentrations (in water) and organic carbon concentrations (in aquifer material) also was observed but was not statistically significant.

Iowa↗

USGS2018

Public views of wetlands and waterfowl conservation in the United States—Results of a survey to inform the 2018 update of the North American Waterfowl Management Plan

Executive Summary This report provides information from a general public survey conducted in early 2017 to help inform the North American Waterfowl Management Plan (NAWMP) 2018 update. This report is intended for use by the NAWMP advisory committees and anyone interested in the human dimensions of wetlands and waterfowl management. A mail-out survey was sent to 5,000 addresses in the United States, which were selected randomly in proportion to the population of each State. A total of 1,030 completed surveys representing 49 States were returned, resulting in a 23 percent overall response rate. When comparing the demographics of the respondents to the U.S. census data, this sample overrepresented people who are male, older, highly educated, and white. Data were weighted on gender and age to make the results more representative of the overall U.S. population. Additionally, this sample had higher participation rates in all wildlife-related recreation activities than has been found in previous studies; this indicates there may have been selection bias, with people interested in nature-related topics more likely to complete the survey. Therefore, results likely represent a segment of the U.S. public that is more oriented toward and aware of wildlife and conservation issues than the general public as a whole. Because of this bias, responses for each question were also broken down by recreationist type (hunters, anglers, wildlife viewers, and no wildlife-related recreation). Additionally, responses for each question were split by administrative flyway (Atlantic, Central, Mississippi, Pacific) and residency (urban, urban cluster, rural) to better understand the different groups. Most respondents knew of wetlands in their local area or community, and more than half had visited wetlands in the previous 12 months. Of those who had visited wetlands, the most common reasons were for walking/hiking/biking and enjoying nature/picnicking. In addition, this sample was very concerned about the reduction or loss of ecosystem services resulting from wetlands degradation or loss. A majority of respondents were somewhat or very concerned about 9 out of 10 wetlands benefits, with hunting opportunities being the only benefit the majority of people were not concerned about. People were the most concerned about clean water, clean air, and providing a home for wildlife. In contrast, people were least concerned about hunting opportunities and wetlands providing scenic places for inspiration or spiritual renewal. Communication about wetlands that focuses on habitat, clean air, and clean water may resonate with the widest variety of people. However, if communication is targeted toward wildlife-related recreationists, including more information about the recreation benefits of wetlands and emphasizing habitat benefits may be the most effective. Many people reported having participated in conservation behaviors in the last year. The most popular activity was making the yard more desirable to wildlife, with more than three-fourths of respondents participating, followed by donating money to support wildlife/habitat conservation and talking to others in their community about conservation issues. There was lower participation in conservation behavior specifically related to wetlands and waterfowl, with two-fifths of respondents voting for candidates or ballot issues to support wetlands/waterfowl conservation and one-third advocating for political action to conserve wetlands/waterfowl. In order to better understand how to reach out to the public on nature-related topics, preferences in information channels and trust in information sources were explored. Respondents were mostly likely to want to receive their information through personal experience, by reading or accessing online content, and through watching visual media online. People were least likely to want to receive information through listening to recorded audio media, attending educational opportunities, and listening to live audio media. These results emphasize the importance of having content available online in an easily accessible and appealing format. Visual media in particular seems to be preferred across a wide variety of people. Additionally, people had the highest trust in scientific organizations, universities/educational organizations, and friends/family/neighbors/colleagues. The least trusted sources were national media/news, religious organizations, and local media/news. Urban respondents had higher trust levels overall, particularly for the government. Hunters and those in rural areas had lower levels of trust in the government but higher trust in family/friends. In this sample, few respondents reported hunting waterfowl (5 percent) or hunting other game (16 percent) in the last year. Additionally, few respondents said they were very or somewhat likely to hunt waterfowl in the following 12 months. Even after considering that self-selection bias would make it more likely for hunters to respond to the survey, the relatively small number of respondents who identified as hunters reinforces that engagement of other wildlife-related recreationists is critical to meeting the third goal of the NAWMP 2012 revision—to increase numbers of wetlands/waterfowl conservationists. Many people also had negative perceptions of hunting. Half of the respondents stated that hunting would be unpleasant, and two-fifths believed hunting would be boring. In contrast, people had more favorable attitudes toward birdwatching, with only one-sixth saying it would be unpleasant and less than one-third saying it would be boring. A majority of respondents thought they could easily go hunting or birdwatching in the following 12 months. Overall, people had much more positive views toward birdwatching and expressed fewer barriers to participating in it. When asked what would prevent them from hunting, the most frequently stated reasons were moral opposition, no interest, personal health, and time constraints; for birdwatching, the most popular responses were nothing, no interest, and time constraints. These responses indicate it may be beneficial to move beyond hunting and find ways for other groups, such as birdwatchers, to play a more active role in conservation. Although not many people hunted and many people tended to have negative attitudes toward hunting, over three-fourths of people said they knew a hunter. Given that wildlife viewers, those who did not participate in wildlife-related recreation, and urban residents tended to have negative attitudes toward hunting and (or) were not interested in participating, attempting to recruit them to participate in hunting may not be effective. However, given how many people across all groups knew a hunter and the relatively high levels of trust people had in their friends/family, hunters may be effective ambassadors for promoting waterfowl and wetlands conservation among nonhunters. Additionally, because people had less preference for viewing waterfowl and other game birds compared to their preference for seeing hummingbirds and birds of prey, conservation efforts that extend beyond waterfowl and include other species that benefit from wetlands may have more appeal to a broader range of people.

Open-File Report↗

USGS2010

The potential influence of changing climate on the persistence of salmonids of the inland west

The Earth's climate warmed steadily during the 20th century, and mean annual air temperatures are estimated to have increased by 0.6°C (Intergovernmental Panel on Climate Change, 2007). Although many cycles of warming and cooling have occurred in the past, the most recent warming period is unique in its rate and magnitude of change (Siegenthaler and others, 2005) and in its association with anthropogenic emissions of greenhouse gases (Intergovernmental Panel on Climate Change , 2007). The climate in the western United States warmed in concert with the global trend but at an accelerated rate (+0.8°C during the 20th century; Saunders and others, 2008). The region could also prove especially sensitive to future changes because the relatively small human population is growing rapidly, as are demands on limited water supplies. Regional hydrological patterns are dominated by seasonal snow accumulation at upper elevations. Most of the region is relatively dry, and both terrestrial and aquatic ecosystems are strongly constrained b y water availability (Barnett and others, 2008; Brown and others, 2008). Stream environments are dynamic and climatically extreme, and salmonid fishes are the dominant elements of the native biodiversity (McPhail and Lindsey, 1986; Waples and others, 2008). Salmonids have broad economic and ecologic importance, but a century of intensive water resource development, nonnative fish stocking, and land use has significantly reduced many populations and several taxa are now protected under the Endangered Species Act (Thurow and others, 1997; Trotter, 2008). Because salmonids require relatively pristine, cold water environments and are often isolated in headwater habitats, members of this group may be especially vulnerable to the effects of a warming climate (Keleher and Rahel, 1996; Rieman and others, 2007; Williams and others, 2009). Warming during the 20th century drove a series of environmental trends that have profound implications for many aspects of salmonid habitat, including disturbance regimes such as wildfire, and unfavorable changes to thermal and hydrologic properties of aquatic systems. Warmer air temperatures have been associated with decreased winter snow accumulations, have accelerated snowmelt, and have advanced the timing of peak runoff by several days to weeks across most of western North America (Stewart and others, 2005; Barnett and others, 2008). Less snow and earlier runoff decrease aquifer recharge, make less water available for groundwater inputs to streams, and are contributing to widespread decreases in summer low flows (Stewart and others, 2005; Rood and others, 2008; Luce and Holden 2009). Interannual variability in stream flow is increasing, as is the persistence of multi-year extreme conditions (McCabe and others, 2004; Pagano and Garen 2005). In many areas of western North America, flood risks have increased in association with warmer temperatures during the 20th century (Hamlet and Lettenmaier, 2005). Streams where midwinter temperatures are near freezing have proven especially sensitive to increased flooding because of associated transitional hydrological patterns (mixtures of rainfall and snowmelt) and propensity for occasional rain-on-snow events to rapidly melt winter snowpack and generate large floods (Hamlet and Lettenmaier, 2005). Stream temperatures in many areas are increasing (Peterson and Kitchell, 2001; Morrison and others, 2002; Bartholow, 2005; Kaushal and others, 2010), due to both air temperature increases and reduced summer flows that make streams more sensitive to warmer air temperatures (Isaak and others, 2010). In recent decades, wildfires have become more common across much of the western United States during periods of more frequent droughts (Westerling and others, 2006; Hoerling and Eischeid, 2007), and local stream temperature can increase in postfire environments (Gresswell, 1999; Dunham and others, 2007). Fire-related temperature increase within streams is commonly a transient phenomenon, lasting only until riparian vegetation has recovered (Gresswell, 1999); however, ongoing climate change could preclude recovery to higher stature, prefire vegetation types in some areas (McKenzie and others, 2004; van Mantgem and Stephenson, 2007), resulting in a loss of critical riparian shading. Additionally, when wildfires occur in steep mountain topographies, the vegetation that stabilize s soils on hillslopes is often killed and landslides become more prevalent (Gresswell, 1999). Landslides int o stream channels form debris flows composed of sediment slurries and dead trees that can scour channels to bedrock and further exacerbate stream heating, delay recovery of riparian areas, or extirpate fish populations (Gresswell, 1999; May and Gresswell, 2003; Dunham and others, 2007). Changes in stream environments will shift habitat distributions, sometimes unpredictably, in both time and space for many salmonid fishes. Water temperature fundamentally influences aquatic ecosystem health because distribution, reproduction, fitness, and survival of ectothermic organisms are inextricably linked to the thermal regime of the environment. Historically, research has focused on defining lethal thermal limits of salmonids (Eaton and others, 1995; Selong and others, 2001; Todd and others, 2008); however, water temperature is known to be important in biological processes at a variety of spatial scales and levels of biological organization (Rahel and Olden, 2008; McCullough and others, 2009). For instance, trout are affected directly by water temperature through feeding, metabolism, and growth rates, and indirectly by factors such as prey availability and species interactions (Wehrly and others, 2007; Rahel and Olden, 2008). Where cold water temperatures currently limit habitat suitability and distributions of some species (for example, at the highest and most northerly distributional extents; Nakano and others, 1996; Coleman and Fausch, 2007), a warming climate may gradually increase the quality and extent of suitable habitat. Over time, previously constrained populations are expected to expand into these new habitats and increase in number. Some evidence suggests this may already be happening in Alaska, where streams in recently deglaciated areas are being colonized by emigrants from nearby salmon and char populations (Milner and others, 2000). Unfortunately, many of the sensitive salmonid species that are often the focus of western managers are unlikely to benefit from future water temperature increases. Warmer stream temperatures will facilitate invasion by nonnative species that are broadly established in downstream areas into upstream areas where they will compete with native species (Rieman and others, 2006; Rahel and Olden, 2008; Fausch and others, 2009). In other cases, warmer stream temperatures will render thermally suitable habitats unsuitable in downstream areas and effect net losses of habitat because upstream distributions are often constrained by streams that are too small or steep (Hari and others, 2006; Isaak and others, 2010). Both scenarios are realistic for fish species like bull trout ( Salvelinus confluentus ) (Rieman and others, 2006; Rieman and others, 2007), the various subspecies of cutthroat trout ( Oncorhynchus clarkii ) (Williams and others, 2009), Gila trout ( Oncorhynchus gilae gilae ) (Kennedy and others, 2008), and Apache trout ( Oncorhynchus gilae apache ) (Rinne and Minckley, 1985; Carmichael and others, 1993). As native species are increasingly confined to smaller and more isolated habitats by a gradually warming climate, the effects of wildfires (whether related to lethal changes in water quality during a fire, channel debris flows, or chronic postfire warming ) could have greater proportional effects on remaining habitats (for example, Brown and others, 2001; Rieman and others, 2007). If these changes were accompanied by additional hydrologic alterations associated with changes to the magnitude, frequency, duration, timing, and rate of change of discharge patterns (Jager and others, 1999; Henderson and others, 2000), populations may begin to lose some of their historic resilience and become ever more susceptible to local extirpations. As dramatic and extensive as climatic and environmental trends are for salmonid habitats, global climate models (GCMs) project that many of these trends will continue and even accelerate until at least the middle of the 21st century (Intergovernmental Panel on Climate Change, 2007). Current projections suggest mean annual air temperatures will increase by an additional 1–3°C, and early indications are that climate trajectory is at the higher end of this range (Pittock, 2006; Raupach and others, 2007). Although predicted changes vary considerably, even the most conservative estimates suggest a warming rate that will be twice that observed during the 20th century. Projections for the midcentury are most certainly due to the effects of greenhouse gases already emitted or predicted in the short term, uncertainties of the effects of longer-term greenhouse gas emissions, short-term climate cycles, and process errors associated with climate models (Cox and Stephenson, 2007). Projections of changes in total precipitation are less certain than those for air temperatures, but most GCMs project relatively small changes in the Northwest, with the exception of slightly drier summer periods (Mote and others, 2008; Karl and others, 2009). In the Southwest, however, significant decreases (such as 15–30 percent ) are projected during most periods of the year, and this area is one of the few for which Intergovernmental Panel on Climate Change (2007) precipitation projections have a high level of certainty (Hoerling and Eischeid, 2007; Karl and others, 2009). Clearly, managers of native salmonids in the wester n United States should consider adjusting management strategies to accommodate a warmer and possibly drier future (Williams and others, 2009). Tools are needed to forecast where important changes may occur and how conservation efforts should be prioritized. In this Open-File Report, we document our initial efforts in this regard for 10 species and subspecies of inland trout and Montana Arctic grayling ( Thymallus arcticus ) across the western United States.

Arizona, California, Colorado, Idaho, Montana, Nev↗

USGS2012

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222 radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium ( 226 radium plus 228 radium), gross alpha-particle radioactivity, and methyl tert -butyl ether (M t BE). Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and metaluminous granite lithology groups than from samples in the other lithology groups. Water samples from 1.4 percent of 2,167 studied wells had fluoride concentrations that were equal to or greater than the maximum contaminant level (MCL) of 4 milligrams per liter (mg/L) and 7.5 percent of the wells had fluoride concentrations that were equal to or greater than the secondary MCL of 2 mg/L. For arsenic, groundwater samples from the calcareous metasedimentary rocks in the New Hampshire-Maine geologic province, peraluminous granite, and pelitic rocks lithology groups had higher concentrations than did samples from the other lithology groups. Water samples from 13.3 percent of 2,054 studied wells had arsenic concentrations that were equal to or greater than the MCL of 10 micrograms per liter (μg/L), about double the national rate of occurrence in community-supply systems and in domestic wells of the United States. Uranium concentrations were significantly higher in groundwater samples from the peraluminous granite, alkali granite, and calcareous metasedimentary rocks in the New Hampshire-Maine geologic province lithology groups than from samples in the other lithology groups. Water samples from 14.2 percent of 556 studied wells had uranium concentrations equal to or greater than the MCL of 30 μg/L. Radon activities were equal to or greater than the proposed MCL of 300 picocuries per liter (pCi/L) in 95 percent of 943 studied wells, and 33 percent of the wells had radon activities were equal to or greater than the proposed alternative maximum contaminant level (AMCL) of 4,000 pCi/L. Radon activities exceeded the proposed AMCL in 20 percent or more of groundwater samples in each of the studied lithology groups with a minimum of 9 samples, but radon activities were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and Narragansett basin metasedimentary rocks lithology groups. Water samples from 3.2 percent of 564 studied wells had combined radium activities equal to or greater than the MCL of 5 pCi/L; however, combined radium activities were not significantly different among the studied lithology groups. Land use and population density also were evaluated to explain patterns in water quality. Concentrations of nitrate, sodium, chloride, and MtBE from the studied wells were significantly greater in areas of high population density (≥50 persons per square kilometer) than in areas of low population density (<50 persons per square kilometer). Concentrations of sodium, chloride, and M t BE from the studied wells were significantly greater in areas classified as developed (urban lands) than in areas classified as undeveloped (forested), agricultural, or mixed (no dominant land use). Nitrate concentrations from the public-supply wells were not significantly different among the four land use categories, but nitrate concentrations from the domestic wells were significantly greater in areas classified as developed than in areas classified as undeveloped, agricultural, or mixed. Chloride to bromide mass ratios in the domestic well samples indicate that the groundwater was probably affected by at least three halogen sources: local precipitation and recharge waters, remnant seawater and connate waters evolved from seawater, and recharge waters affected by road salt. The groundwater in the NECR aquifers generally contained low concentrations of nitrate, VOCs, and pesticides. Less than 1 percent of water samples from 4,781 studied wells had concentrations of nitrate greater than the MCL of 10 mg/L. Less than 1 percent of water samples from 1,299 studied wells exceeded the USEPA advisory level of 20 to 40 μg/L for M t BE. None of the other studied VOCs exceeded a human health benchmark. M t BE (36 percent frequency detection) and chloroform (32.9 percent frequency detection) were the most frequently detected (>0.02 μg/L) VOCs in the domestic wells. M t BE was detected more often in water samples with apparent ages of less than 25 years than in water samples with apparent ages greater than 25 years. This finding is consistent with the time period of high M t BE use in areas in the United States where reformulated gasoline was mandated. The largest pesticide concentration was an estimated concentration of 0.06 μg/L for the herbicide metolachlor. Deethylatrazine, a degradate of atrazine, (18 percent frequency detection) and atrazine (8 percent frequency detection) were the only pesticide compounds detected (>0.001 μg/L) in more than 3 percent of the domestic wells. None of the detected pesticide compounds exceeded human health benchmarks. Concentrations of nitrate and gross alpha-particle activities were significantly greater in the water samples from the domestic wells than in samples from the public-supply wells. Concentrations of sodium, chloride, iron, manganese, and uranium were significantly greater in the water samples from the public-supply wells than in the samples from the domestic wells. One possible explanation may be related to differences in field processing (filtered samples from the domestic wells compared to unfiltered samples from the public-supply wells). The high frequency of detections for a wide variety of manmade and naturally occurring contaminants in both domestic and public-supply wells shows the vulnerability of NECR aquifers to contamination. The highly variable water quality and the association with highly variable lithology of crystalline bedrock underscores the importance of testing individual wells to determine if concentrations for the most commonly detected contaminants exceed human health benchmarks.

Connecticut, Maine, Massachusetts, New Hampshire, ↗