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Flow of variably fluidized granular masses across three-dimensional terrain 2. Numerical predictions and experimental tests

Numerical solutions of the equations describing flow of variably fluidized Coulomb mixtures predict key features of dry granular avalanches and water-saturated debris flows measured in physical experiments. These features include time-dependent speeds, depths, and widths of flows as well as the geometry of resulting deposits. Threedimensional (3-D) boundary surfaces strongly influence flow dynamics because transverse shearing and cross-stream momentum transport occur where topography obstructs or redirects motion. Consequent energy dissipation can cause local deceleration and deposition, even on steep slopes. Velocities of surge fronts and other discontinuities that develop as flows cross 3-D terrain are predicted accurately by using a Riemann solution algorithm. The algorithm employs a gravity wave speed that accounts for different intensities of lateral stress transfer in regions of extending and compressing flow and in regions with different degrees of fluidization. Field observations and experiments indicate that flows in which fluid plays a significant role typically have high-friction margins with weaker interiors partly fluidized by pore pressure. Interaction of the strong perimeter and weak interior produces relatively steep-sided, flat-topped deposits. To simulate these effects, we compute pore pressure distributions using an advection-diffusion model with enhanced diffusivity near flow margins. Although challenges remain in evaluating pore pressure distributions in diverse geophysical flows, Riemann solutions of the depthaveraged 3-D Coulomb mixture equations provide a powerful tool for interpreting and predicting flow behavior. They provide a means of modeling debris flows, rock avalanches, pyroclastic flows, and related phenomena without invoking and calibrating Theological parameters that have questionable physical significance.

Journal of Geophysical Research B: Solid Earth↗

Geology and ground-water resources of Laramie County, Wyoming

Laramie County, an area of 2,709 square miles, is in the southeast corner of Wyoming. Rocks exposed there range in age from Precambrian to Recent. The most extensive aquifers in the county are the White River Formation of Oligocene age, which is as much as 500 feet thick and consists predominantly of siltstone ; the Arikaree Formation of Miocene age, which consists of as much as 450 feet of very fine grained to fine-grained sandstone; and the Ogallala Formation of Miocene and Pliocene age, which consists ,of as much as 330 feet of gravel, sand, silt, and some cobbles and boulders. These formations are capable of yielding large ,supplies of water locally. Terrace deposits of Quaternary age yield moderate .to large supplies of water in the southeastern and northeastern parts of the county. In the Federal well field, large yields of water from the White River Formation are obtained from gravel lenses. In the eastern part of the county near Pine Bluffs, large yields are obtained from openings in .the siltstone of the White River. Previous investigators reported that the large yields were obtained in areas where the formation is fractured and fissured. The authors of this report believe that .the large yields from siltstone in the White River Formation are from pipes, sometimes called natural tunnels, rather than from fractures ,or fissures. Little is known about the water-bearing properties of the pro-Tertiary aquifers in the county, but water derived from the pro-Tertiary formations would probably be of poor quality, except in the vicinity of the outcrop near the western edge of the county. Precipitation is the principal source of recharge to the ground-water reservoirs. About 5 percent of the annual precipitation, or about 108,400 acre-feet per year, is estimated to be recharged. Only a small amount of additional recharge is from streams. The general movement of ground water is eastward, and the average gradient of the water table is about 40 feet per mile. The total amount ,of ground water pumped from wells in Laramie County during 1964 is estimated to be 28,000 acre-feet; about 6,000 acre-feet was used for municipal and industrial supplies, about 17,000 acre-feet was used for irrigation in the Pine Bluffs-Carpenter area, and about 5,000 acre-feet was used for other purposes. The balance of the recharge (80,400 acre-feet) is estimated to be discharged by the following means: 20 percent by underflow, 20 percent by streamflow, and 60 percent by evapotranspiration. The coefficient of transmissibility of the Ogallala Formation, determined by averaging data from 28 pumping tests made in the Cheyenne municipal well field, is about 16,000 gallons per day per foot. However, this figure is an average of the more permeable zones, and the average coefficient of transmissibility of the Ogallala in the county is probably much less because of the heterogeneous character of the formation. A coefficient of transmissibility of 3,800 gallons per day per foot was calculated for the Ogallala, in the same vicinity that the pumping tests were made, by using a regional method of analysis. Although the average transmissibility of the Ogallala is considered to be low, large yields are obtained from gravel stringers and lenses in the formation. The maximum perennial yield from the Cheyenne well field is estimated to be about 1.6 billion gallons per year. Moderate to large yields of water can be obtained in the north-central part of the county where the saturated thickness of the Arikaree Formation, or combined Arikaree and Ogallala Formations, is 200 feet or more. Ground water has been developed throughout the county, but development has been intensive only in the Cheyenne municipal well fields near Cheyenne and Federal and in the Pine Bluffs lowland. The water level has been lowered as much as 40 feet in the Cheyenne well field and somewhat less in the Federal well field.

Wyoming↗

The gap between experts, farmers and non-farmers on perceived environmental vulnerability and the influence of values and beliefs

Science has played a mixed role in guiding conservation and sustainability-oriented decision-making by individuals, policymakers, institutions, and governments. Not all science-based conservation and sustainability initiatives that address issues facing humanity and ecosystems and global problems have gained public support. Conservation decisions and policy prescriptions are and may be based on perceptions about and experiences with the environment, local land use, and ecosystems that may not align with or be grounded in science or evidence from experts in the field. Values, beliefs, and perceptions associated with nature play a critical role in how individuals view biodiversity conservation, sustainability, and natural resource management . This study first examines the gap between experts (scientists and other field experts) and the public (farmers and non-farmers) about the state of water and land resources, wildlife and associated habitats, and aquatic biodiversity in the Smoky Hill River Watershed in western Kansas. Second, the study examines the role that values and beliefs play in shaping environmental perceptions for farmers and non-farmers. Analysis confirms that a gap between experts and farmers/non-farmers does exist, especially with respect to the state of the Ogallala Aquifer, playas, rivers and streams, lakes and reservoirs, native grasslands, wildlife habitats, farmland, native fish populations, and wildlife species. Ordered-logistic regression analyses, meanwhile, indicate that farmer and non-farmer perceptions about the state of the local environment are influenced by traditional and self-interested values, as well as environmental values and beliefs, but less so by religiosity and political ideology. Despite broad takeaways, results exhibited heterogeneity across the farmer and non-farmer subpopulations. If environmental professionals cannot align ecological data, stakeholders’ values/perceptions, and policies, then the existing body of technical research and management on sustainability in natural and social sciences may be of little value.

Journal of Environmental Management↗

Simulation of ground-water flow in coastal Georgia and adjacent parts of South Carolina and Florida-predevelopment, 1980, and 2000

A digital model was developed to simulate steady-state ground-water flow in a 42,155-square-mile area of coastal Georgia and adjacent parts of South Carolina and Florida. The model was developed to (1) understand and refine the conceptual model of regional ground-water flow, (2) serve as a framework for the development of digital subregional ground-water flow and solute-transport models, and (3) serve as a tool for future evaluations of hypothetical pumping scenarios used to facilitate water management in the coastal area. Single-density ground-water flow was simulated using the U.S. Geological Survey finite-difference code MODFLOW-2000 for mean-annual conditions during predevelopment (pre?1900) and the years 1980 and 2000. The model comprises seven layers: the surficial aquifer system, the Brunswick aquifer system, the Upper Floridan aquifer, the Lower Floridan aquifer, and the intervening confining units. A combination of boundary conditions was applied, including a general-head boundary condition on the top active cells of the model and a time-variable fixed-head boundary condition along part of the southern lateral boundary. Simulated heads for 1980 and 2000 conditions indicate a good match to observed values, based on a plus-or-minus 10-foot (ft) calibration target and calibration statistics. The root-mean square of residual water levels for the Upper Floridan aquifer was 13.0 ft for the 1980 calibration and 9.94 ft for the 2000 calibration. Some spatial patterns of residuals were indicated for the 1980 and 2000 simulations, and are likely a result of model-grid cell size and insufficiently detailed hydraulic-property and pumpage data in some areas. Simulated potentiometric surfaces for predevelopment, 1980, and 2000 conditions all show major flow system features that are indicated by estimated peotentiometric maps. During 1980?2000, simulated water levels at the centers of pumping at Savannah and Brunswick rose more than 20 ft and 8 ft, respectively, in response to decreased pumping. Simulated drawdown exceeded 10 ft in the Upper Floridan aquifer across much of the western half of the model area, with drawdown exceeding 20 ft along parts of the western, northern, and southern boundaries where irrigation pumping increased during this period. From predevelopment to 2000 conditions, the simulated water budget showed an increase in inflow from, and decrease in outflow to, the general-head boundaries, and a reversal from net seaward flow to net landward flow across the coastline. Simulated changes in recharge and discharge distribution from predevelopment to 2000 conditions showed an increase in extent and magnitude of net recharge cells in the northern part of the model area, and a decrease in discharge or change to recharge in cells containing major streams and beneath major pumping centers. The model is relatively sensitive to pumping and the controlling head at the fixed-head boundary and less sensitive to the distribution of aquifer properties in general. Model limitations include: (1) its spatial scale and discretization, (2) the extent to which data are available to physically define the flow system, (3) the type of boundary conditions and controlling parameters used, (4) uncertainty in the distribution of pumping, and (5) uncertainty in field-scale hydraulic properties. The model could be improved with more accurate estimates of ground-water pumpage and better characterization of recharge and discharge.

Florida, Georgia, South Carolina↗

Use of Doppler velocity radars to monitor and predict debris and flood wave velocities and travel times in post-wildfire basins

The magnitude and timing of extreme events such as debris and floodflows (collectively referred to as floodflows) in post-wildfire basins are difficult to measure and are even more difficult to predict. To address this challenge, a sensor ensemble consisting of noncontact, ground-based (near-field), Doppler velocity (velocity) and pulsed (stage or gage height) radars, rain gages, and a redundant radio communication network was leveraged to monitor flood wave velocities, to validate travel times, and to compliment observations from NEXRAD weather radar. The sensor ensemble (DEbris and Floodflow Early warNing System, DEFENS) was deployed in Waldo Canyon, Pike National Forest, Colorado, USA, which was burned entirely (100 percent burned) by the Waldo Canyon fire during the summer of 2012 ( MTBS, 2020 ). Surface velocity, stage, and precipitation time series collected during the DEFENS deployment on 10 August 2015 were used to monitor and predict flood wave velocities and travel times as a function of stream discharge (discharge; streamflow). The 10 August 2015 event exhibited spatial and temporal variations in rainfall intensity and duration that resulted in a discharge equal to 5.01 cubic meters per second (m 3 /s). Discharge was estimated post-event using a slope-conveyance indirect discharge method and was verified using velocity radars and the probability concept algorithm. Mean flood wave velocities – represented by the kinematic celerity ( c k = 2.619 m e t e r s p e r s e c o n d , m / s ± 0.556 p e r c e n t "> 𝑐 𝑘 = 2.619 𝑚𝑒𝑡𝑒𝑟𝑠 𝑝𝑒𝑟 𝑠𝑒𝑐𝑜𝑛𝑑, m/s ± 0.556 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and dynamic celerity ( c d = 3.533 m / s ± 0.181 p e r c e n t a n d t h e i r u n c e r t a i n t i e s "> 𝑐 𝑑 = 3.533 m/s ± 0.181 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and their uncertainties were computed. L-moments were computed to establish probability density functions (PDFs) and associated statistics for each of the at-a-section hydraulic parameters to serve as a workflow for implementing alert networks in hydrologically similar basins that lack data. Measured flood wave velocities and travel times agreed well with predicted values. Absolute percent differences between predicted and measured flood wave velocities ranged from 1.6 percent to 49 percent and varied with water slope, hydraulic radius, and depth. The kinematic celerity was a better predictor for steep slopes and wide flood plains associated with the Upper Waldo and Middle Waldo radar streamgages; whereas, the dynamic celerity was a better surrogate for shallow slopes and incised channels such as the Lower Waldo radar streamgage. The method demonstrates the potential extensibility of a post-wildfire warning system by (1) leveraging multiple systems (i.e., weather radar, near-field velocity and stage radars, and rain gages) for accurate and timely warnings of debris and floodflows, (2) establishing an order of operations to site, install, and operate near-field radars and conventional rain gages to record floodflows, forecast travel times, and document geomorphic change in this basin and hydrologically similar basins that lack data, and (3) communicating data operationally with the Colorado Department of Transportation engineering staff, National Weather Service forecasters, and emergency managers.

Colorado↗

Validating morphometrics as a nonlethal tool to determine Arctic Grayling sex

Objective Some graylings Thymallus spp. possess an elongated dorsal fin and other morphological traits that can be sexually dimorphic, as demonstrated in the European Grayling T. thymallu s. North American Arctic Grayling T. arcticus are assumed to follow these trends, but decisive evidence is lacking. This study aimed to determine whether sexually dimorphic characteristics, including posterior dorsal height, can be used to accurately predict the sex of Arctic Grayling in Interior Alaska. Methods We used computer imaging software to measure 22 morphometrics on 97 Arctic Grayling of known sex from streams in Interior Alaska, and we developed a set of binomial models to evaluate the validity of morphometrics as predictors of Arctic Grayling sex. Result Posterior dorsal height was a reasonably accurate predictor of sex (~90% accurate at fork lengths ≥300 mm), although models containing additional morphometrics were more accurate (100% accuracy at fork lengths ≥250 mm). Conclusion This study presents an affordable, noninvasive, and replicable method for nonlethal determination of Arctic Grayling sex by using digital images from the field, with potential application to other salmonids.

North American Journal of Fisheries Management↗

New insights on scale-dependent surface-groundwater exchange from a floating self-potential Dipole

In south-central Texas the lower Guadalupe River has incised into the outcrop of the Carrizo-Wilcox aquifer. The river and the aquifer are hydraulically connected across the outcrop, although the connectivity is obscured at the surface by alluvium and surface-water and groundwater exchange dynamics are currently poorly understood. To investigate surface-water and groundwater exchange dynamics between the lower Guadalupe River and the Carrizo-Wilcox aquifer, a geophysical study was completed along a 14.86 km reach of the river by using water-borne gradient self-potential (SP) profiling and two-dimensional direct-current electric resistivity tomography. This paper explores the applicability of these water-borne geoelectric methods in delineating gaining and losing channel reaches, and demonstrates that geoelectric signals in the form of total electric field strength can be logged with an electric dipole and decomposed into component SP signals depicting regional and local groundwater flow patterns attributable to regional and localized hydraulic gradients. Localized SP anomalies of several tens of millivolts, indicative of hyporheic exchange flows, are observed and superimposed upon a 124 mV regional SP anomaly indicative of ambient groundwater exchange flows between the river and the aquifer. The observed SP signals are interpreted through two-dimensional finite-element modeling of streaming potentials attributable to ambient groundwater exchange and hyporheic exchange flow patterns. Variables of the channel environment such as temperature and concentration gradients, depth, and velocity are considered and subsequently eliminated as alternative sources of the SP signals that are presented.

Texas↗

Field and Laboratory Data From an Earthquake History Study of Scarps in the Hanging Wall of the Tacoma Fault, Mason and Pierce Counties, Washington

As part of the effort to assess seismic hazard in the Puget Sound region, we map fault scarps on Airborne Laser Swath Mapping (ALSM, an application of LiDAR) imagery (with 2.5-m elevation contours on 1:4,000-scale maps) and show field and laboratory data from backhoe trenches across the scarps that are being used to develop a latest Pleistocene and Holocene history of large earthquakes on the Tacoma fault. We supplement previous Tacoma fault paleoseismic studies with data from five trenches on the hanging wall of the fault. In a new trench across the Catfish Lake scarp, broad folding of more tightly folded glacial sediment does not predate 4.3 ka because detrital charcoal of this age was found in stream-channel sand in the trench beneath the crest of the scarp. A post-4.3-ka age for scarp folding is consistent with previously identified uplift across the fault during AD 770-1160. In the trench across the younger of the two Stansberry Lake scarps, six maximum 14C ages on detrital charcoal in pre-faulting B and C soil horizons and three minimum ages on a tree root in post-faulting colluvium, limit a single oblique-slip (right-lateral) surface faulting event to AD 410-990. Stratigraphy and sedimentary structures in the trench across the older scarp at the same site show eroded glacial sediments, probably cut by a meltwater channel, with no evidence of post-glacial deformation. At the northeast end of the Sunset Beach scarps, charcoal ages in two trenches across graben-forming scarps give a close maximum age of 1.3 ka for graben formation. The ages that best limit the time of faulting and folding in each of the trenches are consistent with the time of the large regional earthquake in southern Puget Sound about AD 900-930.

Scientific Investigations Map↗

Occurrence of Agricultural Chemicals in Shallow Ground Water and the Unsaturated Zone, Northeast Nebraska Glacial Till, 2002-04

Agricultural chemicals applied at the land surface in northeast Nebraska can move downward, past the crop root zone, to ground water. Because agricultural chemicals applied at the land surface are more likely to be observed in the shallowest part of an aquifer, an assessment of shallow ground-water and unsaturated zone quality in the northeast Nebraska glacial till was completed between 2002 and 2004. Ground-water samples were collected at the first occurrence of ground water or just below the water table at 32 sites located in areas likely affected by agriculture. Four of the 32 sites were situated along a ground-water flow path with its downgradient end next to Maple Creek. Twenty-eight sites were installed immediately adjacent to agricultural fields throughout the glacial-till area. In addition to those 32 sites, two sites were installed in pastures to represent ground-water conditions in a non-cropland setting. Ground-water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, selected pesticides and pesticide degradates, dissolved solids, major ions, trace elements, and dissolved organic carbon. Chlorofluorocarbons (CFCs) or sulfur hexafluoride (SF6) concentrations were analyzed at about 70 percent of the monitoring wells to estimate the residence time of ground water. Borehole-core samples were collected from 28 of the well boreholes. Sediment in the unsaturated zone was analyzed for nitrate, chloride, and ammonia concentrations. Analytical results indicated that the agricultural chemicals most often detected during this study were nitrates and herbicides. Nitrate as nitrogen (nitrate-N) concentrations (2003 median 9.53 milligrams per liter) indicated that human activity has affected the water quality of recently recharged ground water in approximately two-thirds of the wells near corn and soybean fields. The principal pesticide compounds that were detected reflect the most-used pesticides in the area and included parent or degradate compounds of acetochlor, alachlor, atrazine, and metolachlor. Overall, pesticide concentrations in ground-water samples collected in 2003 and 2004 were small and did not exceed public drinking-water standards where established. On average, more pesticides were detected in the flow-path wells than in the glacial-till network wells. The presence of a perennial stream within 1,640 feet of a well was correlated to smaller nitrate-N concentrations in the well water, and the presence of a road ditch within 164 feet of the well was correlated to the presence of detectable pesticides in the well water. All other variables tested showed no significant correlations to nitrate-N concentrations or pesticide detections. Unsaturated zone soil cores collected in 2002 from well boreholes indicated that nitrogen in the forms of nitrate-N and ammonia as nitrogen (ammonia-N) was available in the unsaturated zone for transport to ground water. Concentrations of nitrate-N and ammonia-N in these soil cores were inversely correlated to depth, and nitrate-N concentrations were correlated to chloride concentrations.

Scientific Investigations Report↗

Heterozygosity and fitness: No strong association in Great Lakes populations of the zebra mussel, Dreissena Polymorpha (Pallas)

A number of studies have found positive associations between allozyme heterozygosity and fitness surrogates (e.g., body size and growth rate) for marine molluscs. We investigated whether similar relationships exist for freshwater populations of the zebra mussel, Dreissena polymorpha. Only one significant correlation between multi-locus heterozygosity and shell length was observed for a total of 22 D. polymorpha populations surveyed from midwestern U.S.A. lakes and streams, and the result was not significant on a table-wide basis. Meta-analysis revealed a significant common correlation coefficient (effect magnitude) between multi-locus heterozygosity and shell length across all 22 sites (rc = 0.052, P = 0.019, 1557 df). However, the variance in shell length explained by multi-locus heterozygosity was small (rc2 = 0.0027), implying a weak causal relationship if any. Also, we saw no relationship between heterozygosity and growth rate in a one-year field enclosure experiment. A significant heterozygosity-shell length correlation previously reported for a zebra mussel population at Put-in-Bay, Lake Erie, Ohio, may have been the product of unique population dynamics, rather than natural selection. Similar demographic considerations may contribute to inconsistencies in heterozygosity-fitness correlations seen for other molluscs.

Malacologia↗

Influence of light and temperature on Prochlorococcus ecotype distributions in the Atlantic Ocean

In a focused analysis of Prochlorococcus population structure in the western North Atlantic, we found that the relative abundances of ecotypes varied significantly with depth and, at seasonally stratified locations, with degree of vertical mixing. More limited regional variation was observed (e.g., Sargasso Sea, Gulf Stream, continental slope, and equatorial current), and local patchiness was minimal. Modeling of a combined North and South Atlantic data set revealed significant, independent effects of light and temperature on ecotype abundances, suggesting that they are key ecological determinants that establish the different habitat ranges of the physiologically and genetically distinct ecotypes. This was in sharp contrast with the genus Synechococcus, whose total abundance was related to light but did not vary in a predictable way with temperature. Comparisons of field abundances with growth characteristics of cultured isolates of Prochlorococcus suggested the presence of ecotype-specific thermal and light adaptations that could be responsible for the distinct distribution patterns of the four dominant ecotypes. Significantly, we discovered that one "low-light-adapted" ecotype, eNATL2A, can thrive in deeply mixed surface layers, whereas another, eMIT9313, cannot, even though they have the same growth optimum for (low) light. ?? 2007, by the American Society of Limnology and Oceanography, Inc.

Limnology and Oceanography↗

A novel approach to assessing natural resource injury with Bayesian networks

Quantifying the effects of environmental stressors on natural resources is problematic because of complex interactions among environmental factors that influence endpoints of interest. This complexity, coupled with data limitations, propagates uncertainty that can make it difficult to causally associate specific environmental stressors with injury endpoints. The Natural Resource Damage Assessment and Restoration (NRDAR) regulations under the Comprehensive Environmental Response, Compensation, and Liability Act and Oil Pollution Act aim to restore natural resources injured by oil spills and hazardous substances released into the environment; exploration of alternative statistical methods to evaluate effects could help address NRDAR legal claims. Bayesian networks (BNs) are statistical tools that can be used to estimate the influence and interrelatedness of abiotic and biotic environmental variables on environmental endpoints of interest. We investigated the application of a BN for injury assessment using a hypothetical case study by simulating data of acid mine drainage (AMD) affecting a fictional stream-dwelling bird species. We compared the BN-generated probability estimates for injury with a more traditional approach using toxicity thresholds for water and sediment chemistry. Bayesian networks offered several distinct advantages over traditional approaches, including formalizing the use of expert knowledge, probabilistic estimates of injury using intermediate direct and indirect effects, and the incorporation of a more nuanced and ecologically relevant representation of effects. Given the potential that BNs have for natural resource injury assessment, more research and field-based application are needed to determine their efficacy in NRDAR. We expect the resulting methods will be of interest to many US federal, state, and tribal programs devoted to the evaluation, mitigation, remediation, and/or restoration of natural resources injured by releases or spills of contaminants

Integrated Environmental Assessment and Management↗

Velocity bias induced by flow patterns around ADCPs and associated deployment platforms

Velocity measurements near the Acoustic Doppler Current Profiler (ADCP) are important for mapping surface currents, measuring velocity and discharge in shallow streams, and providing accurate estimates of discharge in the top unmeasured portion of the water column. Improvements to ADCP performance permit measurement of velocities much closer (5 cm) to the transducer than has been possible in the past (25 cm). Velocity profiles collected by the U.S. Geological Survey (USGS) with a 1200 kHz Rio Grande Zedhead ADCP in 2002 showed a negative bias in measured velocities near the transducers. On the basis of these results, the USGS initiated a study combining field, laboratory, and numerical modeling data to assess the effect of flow patterns caused by flow around the ADCP and deployment platforms on velocities measured near the transducers. This ongoing study has shown that the negative bias observed in the field is due to the flow pattern around the ADCP. The flow pattern around an ADCP violates the basic assumption of flow homogeneity required for an accurate three-dimensional velocity solution. Results, to date (2014), have indicated velocity biases within the measurable profile, due to flow disturbance, for the TRDI 1200 kHz Rio Grande Zedhead and the SonTek RiverSurveyor M9 ADCPs. The flow speed past the ADCP, the mount and the deployment platform have also been shown to play an important role in the magnitude and extent of the velocity bias.

Conference Paper↗

Water quality and landscape processes of four watersheds in eastern Puerto Rico

Humid tropical regions occupy about a quarter of Earth's land surface, yet they contribute a substantially higher fraction of the water, solutes, and sediment discharged to the world's oceans. Nearly half of Earth's population lives in the tropics, and development stresses can potentially harm soil resources, water quality, and water supply and in addition increase landslide and flood hazards. Owing to Puerto Rico's steep topography, low water storage capacity, and dependence on trade-wind precipitation, the island's people, ecosystems, and water supply are vulnerable to extreme weather such as hurricanes, floods, and droughts. Eastern Puerto Rico offers a natural laboratory for separating geologic and land-cover influences from regional- and global-scale influences because of its various bedrock types and the changing land cover surrounding intact, mature forest of the Luquillo Experimental Forest. Accordingly, a multiyear assessment of hydrological and biogeochemical processes was designed to develop an understanding of the effects of these differences on local climate, streamflow, water quality, and ecosystems, and to form the basis for a long-term and event-based program of climate and hydrologic monitoring. Because infrequent, large storms play a major role in this landscape, we focused on high-runoff events, sampling 263 storms, including all major hurricanes from 1991 through 2005. The largest storms have profound geomorphic consequences, such as landslides, debris flows, deep gullying on deforested lands, excavation and suspension of sediment in stream channels, and delivery of a substantial fraction of annual stream sediment load. Large storms sometimes entrain ocean foam and spray causing high concentrations of seasalt-derived constituents in stream waters during the storm. Past deforestation and agricultural activities in the Cayaguás and Canóvanas watersheds accelerated erosion and soil loss, and this material continues to be remobilized during large storms. Nearly 5,000 routine and event samples were analyzed for parameters that allow determination of denudation rates based on suspended and dissolved loads; 860 of these samples were analyzed for a comprehensive suite of chemical constituents. The rivers studied are generally similar in water-quality characteristics, and windward or leeward aspect appears to exert a stronger influence on water quality than geology or land cover. Of samples analyzed for comprehensive chemistry and for sediment, 543 were collected at runoff rates greater than 1 millimeter per hour, 256 at rates exceeding 10 millimeters per hour, and 3 at rates exceeding 90 millimeters per hour. Streams have rarely been sampled during events with such high runoff rates. Rates of physical and chemical weathering are especially high, and physical denudation rates, forested watersheds included, are considerably greater than is expected for a steady-state system. The elevated physical erosion drives an increased particulate organic carbon flux, one that is large, important to the carbon cycle, and sustainable, because soil-carbon regeneration is rapid. The 15-year Water, Energy, and Biogeochemical Budget dataset, which includes discharge, field parameters, suspended sediment, major cations and anions, and nutrients, is available from the U.S. Geological Survey's National Water Information System (http://waterdata.usgs.gov/nwis). The dataset provides a baseline for characterizing future environmental change and will improve our understanding of the interdependencies of land, water, and biological resources and their responses to changes in climate and land use. Because eastern Puerto Rico resembles many tropical regions in terms of geology and patterns of development, implications from this study are transferable to other tropical regions facing deforestation, rapid land-use change, and climate change.

Professional Paper↗

Assessment of hydrogeologic terrains, well-construction characteristics, groundwater hydraulics, and water-quality and microbial data for determination of surface-water-influenced groundwater supplies in West Virginia

In January 2014, a storage tank leaked, spilling a large quantity of 4-methylcyclohexane methanol into the Elk River in West Virginia and contaminating the water supply for more than 300,000 people. In response, the West Virginia Legislature passed Senate Bill 373, which requires the West Virginia Department of Health and Human Resources (WVDHHR) to assess the susceptibility and vulnerability of public surface-water-influenced groundwater supply sources (SWIGS) and surface-water intakes statewide. In response to this mandate for reassessing SWIGS statewide, the U.S. Geological Survey (USGS), in cooperation with the WVDHHR, Bureau of Public Health, Office of Environmental Health Services, compiled available data and summarized the results of previous groundwater studies to provide the WVDHHR with data that could be used as part of the process for assessing and determining SWIGS. Existing geologic, hydrologic, well-construction, water-quality, and other related data and information from previous U.S. Geological Survey (USGS) hydrogeologic studies and the USGS National Water Information System (NWIS) database, in conjunction with data from the West Virginia Bureau for Public Health (WVBPH) Department of Health and Human Resources (WVDHHR) and the West Virginia Department of Environmental Protection database and files, were collected, compiled, and analyzed to help the WVDHHR to better assess public groundwater supply wells that may meet the definition of a surface-water-influenced- groundwater supply (SWIGS). In this study, measures of intrinsic susceptibility, which are characterized by the physical properties that affect the ease with which water moves through the unsaturated zone and, subsequently, into the saturated zone within an aquifer, showed that karst limestone aquifers are the aquifers most intrinsically susceptible to contamination within the State of West Virginia. Karst limestone aquifers are present within Cambrian- and Ordovician-age formations within West Virginia’s eastern panhandle and in Mississippian-age limestones within the Greenbrier River valley. Solution development within these limestone aquifers allows rapid recharge and flow of groundwater within the aquifer, both of which allow surface contaminants to easily enter the aquifer and travel long distances in a short period of time. Alluvial aquifers bordering the Ohio River in western West Virginia are also potentially highly susceptible to contamination because these alluvial aquifers can receive significant recharge from the adjacent Ohio River. Any potential contaminants that may be present in the river have the potential to enter the aquifer and contaminate wells completed within the sand and gravel alluvial sediments within which the wells are completed. These same alluvial sediments, however, help to retard the movement of bacteria and other potentially pathogenic organisms, such as Cryptosporidia and Giardia lamblia , into the aquifer. As a result, samples from alluvial aquifers bordering the Ohio River and elsewhere within the State do not commonly test positive for indicator bacteria, such as total coliform, fecal coliform, or Escherichia coli ( E. coli ). The alluvial sediments do not, however, provide assimilative capacity with respect to water soluble compounds such as nitrate and certain volatile and semi-volatile organic compounds. Therefore, the Ohio River alluvial aquifers are highly susceptible to organic compounds present in the river or on the land surface near a well. These aquifers are also susceptible to nitrate contamination from fertilizers, pesticides, and manure, which are commonly used on the fertile agricultural soils present on terraces along the Ohio River. Abandoned-coal-mine aquifers, which are typically used as a source of groundwater in southern West Virginia, are moderately susceptible to contamination. The vast network of voids from mine entries provide vast storage for groundwater in abandoned mine aquifers, and fracturing of overburden strata, which is common in areas of past or current mining, can allow rapid infiltration of contaminants to the aquifer. Where streams cross over below-drainage underground coal mines, there is an increased potential for contamination of coal-mine aquifers. As a result, above-drainage underground coal mines, those mines that are present at an elevation above local tributary drainage, are probably less susceptible to contamination than are below-drainage underground coal mines. Public groundwater supplies in abandoned coal mines need to be evaluated on a case-by-case basis to assess the potential for recharge of contaminated surface water to enter below-drainage underground coal-mine aquifers and to assess potential hydraulic conductivity to nearby surface-water bodies, such as lakes, ponds, rivers, or streams. Fractured-rock aquifers compose an additional major type of aquifer within the State of West Virginia. Owing to their low permeability and their typically small groundwater capture areas, fractured-rock aquifers within the State of West Virginia typically have low susceptibility to contamination. However, there are exceptions, and wells completed in fractured-rock aquifers that are in close proximity to streams may be adversely affected by induced recharge from the stream. Where such systems are present, frequent bacterial testing of the source water can be used to ascertain the potential for microbial contamination of the aquifer. Intrinsic susceptibility alone does not fully predict whether or not a well is vulnerable to contamination, only that the hydrogeologic terrain is suitable for rapid transport of pathogenic organisms or chemical compounds to and within the aquifer. However, contaminants may or may not be present in the recharge water to an individual well or well field. Therefore, an assessment of potential contaminant sources, such as nearby gas wells, landfills, underground storage tanks, above ground storage tanks, major transportation corridors, surface or underground coal mines, and flood plains, is needed to assess vulnerability. The assessments need to be conducted on a case-by-case basis or, as has been done in this study, by collecting and compiling the number of potential contaminant sources that may be present in the source-water-protection area for an individual public groundwater supply source. Groundwater public-supply systems in areas of high intrinsic susceptibility and with a large number of potential contaminant sources within the recharge or source-water-protection area of individual wells or well fields are potentially vulnerable to contamination and probably warrant further evaluation as potential SWIGS. However, measures can be taken to educate the local population and initiate safety protocols and protective strategies to appropriately manage contaminant sources to prevent release of contaminants to the aquifer, therefore, reducing vulnerability of these systems to contamination. However, each public groundwater supply source needs to be assessed on an individual basis. Data presented in this report can be used to categorize and prioritize wells and springs that have a high potential for intrinsic susceptibility or vulnerability to contamination.

West Virginia↗

Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons, have been included in the CCAP Geochemical Database and are planned to be added to the NGDB.

Colorado↗

Using OTIS to model solute transport in streams and rivers

Solute transport in streams and rivers is governed by a suite of hydrologic and geochemical processes. Knowledge of these processes is needed when assessing the fate of contaminants that are released into surface waters. The study of solute fate and transport often is aided by solute transport models that mathematically describe the underlying processes. This fact sheet describes a model that considers One-Dimensional Transport with Inflow and Storage (OTIS). As shown by several example applications, OTIS may be used in conjunction with field-scale data to quantify hydrologic processes (advection, dispersion, and transient storage) and certain chemical reactions (sorption and first-order decay).

Fact Sheet↗