USGS Science⌕ Search

SEARCH · USGS Science

Results for “Complexity”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,189 records · Page 66Linked to original sources

Acoustical deterrence of Silver Carp ( Hypophthalmichthys molitrix )

The invasive Silver Carp ( Hypophthalmichthys molitrix ) dominate large regions of the Mississippi River drainage and continue to expand their range northward threatening the Laurentian Great Lakes. This study found that complex broadband sound (0–10 kHz) is effective in altering the behavior of Silver Carp with implications for deterrent barriers or potential control measures (e.g., herding fish into nets). The phonotaxic response of Silver Carp was investigated using controlled experiments in outdoor concrete ponds (10 × 4.9 × 1.2 m). Pure tones (500–2000 Hz) and complex sound (underwater field recordings of outboard motors) were broadcast using underwater speakers. Silver Carp always reacted to the complex sounds by exhibiting negative phonotaxis to the sound source and by alternating speaker location, Silver Carp could be directed consistently, up to 37 consecutive times, to opposite ends of the large outdoor pond. However, fish habituated quickly to pure tones, reacting to only approximately 5 % of these presentations and never showed more than two consecutive responses. Previous studies have demonstrated the success of sound barriers in preventing Silver Carp movement using pure tones and this research suggests that a complex sound stimulus would be an even more effective deterrent.

Biological Invasions↗

Rearing environment influences boldness and prey acquisition behavior, and brain and lens development of bull trout

Animals reared in barren captive environments exhibit different developmental trajectories and behaviors than wild counterparts. Hence, the captive phenotypes may influence the success of reintroduction and recovery programs for threatened and endangered species. We collected wild bull trout embryos from the Metolius River Basin, Oregon and reared them in differing environments to better understand how captivity affects the bull trout Salvelinus confluentus phenotype. We compared the boldness and prey acquisition behaviors and development of the brain and eye lens of bull trout reared in conventional barren and more structurally complex captive environments with that of wild fish. Wild fish and captive reared fish from complex habitats exhibited a greater level of boldness and prey acquisition ability, than fish reared in conventional captive environments. In addition, the eye lens of conventionally reared bull trout was larger than complex reared captive fish or same age wild fish. Interestingly, we detected wild fish had a smaller relative cerebellum than either captive reared treatment. Our results suggest that rearing fish in more complex captive environments can create a more wild-like phenotype than conventional rearing practices. A better understanding of the effects of captivity on the development and behavior of bull trout can inform rearing and reintroduction programs though prediction of the performance of released individuals.

Environmental Biology of Fishes↗

Salt marsh habitats and diamondback terrapins in a rapidly changing climate: A review

The impacts associated with global climate change (e.g., sea-level rise, tropical storms, and warming temperatures) are expected to alter predator–prey interactions, foundation species, and plant community structure in coastal ecosystems. While the complex dynamics of these habitats have been examined under future climate predictions, few ecosystem models incorporate influences from fauna, such as the diamondback terrapin, the only estuarine turtle native to North America. This review examines the impacts of climate change on diamondback terrapins ( Malaclemys terrapin ) and the role that terrapins play as higher trophic level predators and keystone species in driving the dynamics of these ecosystems. We also review the potential implications of changes to terrapin populations on coastal ecosystems as a conservation challenge and suggest solutions to advance our understanding of those complex systems. Because of their role as a keystone and area-sensitive species that helps maintain healthy coastal habitats by foraging on herbivorous periwinkle snails, alterations to terrapin life history from climate change are expected, which could have significant impacts to the conservation of coastal habitats. Life history alterations could occur due to individual stressors, such as warming temperatures altering terrapin sex ratios. However, because of the complexity of these coastal systems, these stressors could also act additively or synergistically. Inclusion of faunal taxa such as the diamondback terrapin in modeling efforts examining climate change impacts to coastal ecosystems would better represent the complexity of these habitats thereby providing a more comprehensive evaluation of the entire ecosystem, resulting in more effective conservation strategies.

Estuaries and Coasts↗

Effect of surface area and chemisorbed oxygen on the SO2 adsorption capacity of activated char

The objective of this study was to determine whether activated char produced from Illinois coal could be used effectively to remove sulfur dioxide from coal combustion flue gas. Chars were prepared from a high-volatile Illinois bituminous coal under a wide range of pyrolysis and activation conditions. A novel char preparation technique was developed to prepare chars with SO2 adsorption capacities significantly greater than that of a commercial activated carbon. In general, there was no correlation between SO2 adsorption capacity and surface area. Temperature-programmed desorption (TPD) was used to determine the nature and extent of carbon-oxygen (C-O) complexes formed on the char surface. TPD data revealed that SO2 adsorption was inversely proportional to the amount of C-O complex. The formation of a stable C-O complex during char preparation may have served only to occupy carbon sites that were otherwise reactive towards SO2 adsorption. A fleeting C(O) complex formed during SO2 adsorption is postulated to be the reaction intermediate necessary for conversion of SO2 to H2SO4. Copyright ?? 1996 Elsevier Science Ltd.

Fuel↗

Interactions between ground water and wetlands, southern shore of Lake Michigan, USA

Wetlands between, and within, dune-beach complexes along the south shore of Lake Michigan are strongly affected by ground water. The hydrogeology of the glacial drift aquifer system in a 26 km 2 area was investigated to determine the effects of ground water on the hydrology and hydrochemistry of Cowles Bog and its adjacent wetlands. The investigation showed that ground water from intermediate- and regional-scale flow systems discharges to Cowles Bog from confined aquifers that underlie the wetland. These flow systems are recharged in moraines south of the dune-beach complexes. Water from the confined aquifers discharges into the surficial aquifer mainly by upward leakage through a buried till sheet that serves as the confining layer. However, the till sheet is breached below a raised peat mound in Cowles Bog, allowing direct upward discharge from the confinef aquifer into the surficial sand, marl, and peat. The shallow ground and wetland water in the area influenced by this leakage is a calcium magnesium bicarbonate type, with low tritium concentrations consistent with mixing of older ground water and more recent precipitation. Ground water and wetland water from surrounding areas are less mineralized and have higher tritium concentrations characteristic of precipitation in the late 1970s. The results of this study suggest that wetlands in complex hydrogeologic settings may be influenced by multiple ground-water flow systems that are affected by geomorphic features, stratigraphic discontinuities, and changes in sediment types. Discharge and recharge zones may both occur in the same wetland. Multidisciplinary studies incorporating hydrological, hydrochemical, geophysical, and sedimentological data are necessary to identify such complexities in wetland hydrology.

Journal of Hydrology↗

Role of heat and detachment in continental extension as viewed from the eastern basin and range province in Arizona

The Bill Williams River area of west-central Arizona includes not only the Rawhide-Buckskin metamorphic core complex, which is part of the lower Colorado River highly extended terrane (HET), but also the boundary between the extended terranes of the Basin and Range Province and the less deformed Arizona Transition Zone/Colorado Plateau. This provides important constraints on models that address the mechanisms for the mid- to late Tertiary deformation. Three phases of extension are present. The oldest is the extension associated with core-complex tectonism, which characteristically shows a lower plate composed of lineated mylonitic gneiss overlain by a detachment fault that is regionally nearly horizontal but undulates at the local scale. The fault in turn is overlain by an upper plate that includes Precambrian basement rocks, recrystallized Paleozoic sedimentary rocks, Mesozoic(?) metasedimentary and metavolcanic rocks of greenschist facies, and unaltered to hydrothermally altered syntectonic sedimentary and volcanic rocks of Miocene age. The upper plate is cut by closely spaced faults of modest structural relief that strike northwest and strongly rotate intervening blocks to face southwest. Most of these faults do not penetrate below the detachment fault. Fault spacing increases, and rotation decreases, to the northeast, away from the trace of the detachment. The second phase consists of “classic” Basin-Range high-angle normal faults that strike about north and have wide spacing, high structural relief, and modest rotation of blocks. These faults have no consistent direction of displacement and so produced horst and graben that form the ranges and basins visible today. This phase is locally superposed on Phase I, and also extends in more subdued form into the Transition Zone/Colorado Plateau. The third phase consists of tectonic quiescence and is present everywhere except parts of the Transition Zone that are still active seismically. The first phase occurred in the early and middle Miocene and was accompanied by deposition of syntectonic fluviolacustrine rocks (Suite I); the second (middle to late Miocene) was marked by interior-basin deposits (Suite II); the third (latest Miocene through Quaternary) is characterized by deposits related to through-flowing drainage. The phases grade into each other and thus are likely to be genetically related. Tectonic models must take into account not only the geographic distribution of deformation at any one time but also the time-dependent succession of deformation at any one place. A model proposed in this paper attempts to do this. The model is thermotectonic. A heating event in the lower crust, (basaltic intrusion, asthenospheric upwelling) combined with stretching, causes a sharp thermal front to rise within the crust. Embedded within the front is an “isotherm” that marks the brittle-ductile transition. As the front rises, it leaves behind a trail of shear zones, each marking a locus of preferred failure defined by mechanical or physical properties, or combinations thereof. The highest shear zone, now preserved in fossil form as the “detachment”, occurs where the front impinges on the meteoric groundwater, a few km below the topographic surface. The water steepens the thermal gradient at the front, which it stabilizes. A convective hydrothermal circulation system is established, causing alteration and mineralization above the ductile-brittle transition, as well as pore overpressure that results in hydrofracturing (producing monolithologic breccias) and the sliding of gravity-glide sheets. During these events, extension is taking place by brittle failure in the upper plate and ductile deformation below the detachment. Simultaneously, the hottest areas (core complexes) are updomed, promoting drainage reversals and the sliding of breccias and glide sheets. All this occurred only in the hottest areas or “blisters”, now marked by the core complexes. Distal areas showed less or no deformation at the surface. With time and the waning of the thermal event, the thermal front, and thus the brittle-ductile transition, smoothed out and sank, again leaving a trail of shear zones. Phase 1 deformation ceased and was replaced by Phase 2 deformation that occurred over a much wider area. Eventually, the front sank so deep that surface deformation ceased. This illustrates how the style of deformation at the surface may be a measure of the depth to the brittle-ductile transition. According to the thermotectonic model, extensional strain does not need to be constant along the detachment, in contrast to models involving simple shear through crustal-scale normal faults. On the contrary, one would expect strain to vary geographically as a function of maximum temperature attained, because of the well known relation between temperature and lithospheric strength. The thermotectonic model is also in good accord with geophysical characteristics of the Basin and Range Province, which suggests that extension was accompanied by intrusion of basalt into the lower crust, with consequent heating and anatexis. Many studies in the U.S. and elsewhere support the model by showing that continental extension commonly is accompanied by near-surface temperatures corresponding to the brittle-ductile transition, by steep thermal gradients, and by hydrothemal convective systems. A possible driving mechanism from the thermotectonic processes described by the model is the rise of asthenospheric domes or welts, which thin the lithosphere by subcrustal transfer while heating and stretching it. An asthenospheric welt that migrates northeastward while dying out might explain the encroachment of relatively subdued extension onto the Colorado Plateau, as well as the juxtaposition of compressive stress on the plateau with extensional stress in the adjacent Transition Zone and Basin and Range Province.

Arizona↗

Proton and metal ion binding to natural organic polyelectrolytes—I. Studies with synthetic model compounds

A unified physico-chemical model, based on a modified Henderson-Hasselbalch equation, for the analysis of ion complexation reactions involving charged polymeric systems is presented and verified. In this model pH = p K a +p( ΔK a ) + log( α /1 − α ) where K a is the intrinsic acid dissociation constant of the ionizable functional groups on the polymer, ΔK a is the deviation of the intrinsic constant due to electrostatic interaction between the hydrogen ion and the polyanion, and alpha (α) is the polyacid degree of ionization. Using this approach p K a values for repeating acidic units of polyacrylic (PAA) and polymethacrylic (PMA) acids were found to be 4.25 ± 0.03 and 4.8 ± 0.1, respectively. The polyion electrostatic deviation term derived from the potentiometric titration data (i.e. p( ΔK a )) is used to calculate metal ion concentration at the complexation site on the surface of the polyanion. Intrinsic cobalt-polycarboxylate binding constants (7.5 for PAA and 5.6 for PMA), obtained using this procedure, are consistent with the range of published binding constants for cobalt-monomer carboxylate complexes. In two phase systems incorporation of a Donnan membrane potential term allows determination of the intrinsic p K a of a cross-linked PMA gel, p K a = 4.83, in excellent agreement with the value obtained for the linear polyelectrolyte and the monomer. Similarly, the intrinsic stability constant for cobalt ion binding to a PMA-gel ( β CoPMA+ = 11) was found to be in agreement with the linear polyelectrolyte analogue and the published data for cobalt-carboxylate monodentate complexes.

Organic Geochemistry↗

Precambrian ophiolites of Arabia: Geologic settings, U Pb geochronology, Pb-isotope characteristics, and implications for continental accretion

Disrupted ophiolites occur in linear belts up to 900 km long between microplates that collided during the late Proterozoic to form the Arabian Shield. UPb zircon ages and Pb-isotope data from these ophiolitic rocks help constrain the history of accretion of the Arabian Shield and thereby contribute to the definition of its microplates and terranes. Terranes of the central and western Arabian Shield are generally thought to represent intraoceanic island arcs that range in age from about 900 to 640 Ma; however, a region of the eastern Arabian Shield contains rocks of Early Proterozoic age and may represent an exotic continental fragment entrained between the arc complexes. Ophiolites of the Yanbu suture (northwestern shield), dated by UPb (zircon) and SmNd (mineral isochron) methods, yield model ages of 740–780 Ma. These are among the oldest well-dated rocks in the northwestern Arabian Shield. Ages from the Jabal al Wask complex overlap with ages of adjacent arc rocks. This overlap in age supports geologic and geochemical evidence that the Wask complex represents a fragment of back-arc oceanic lithosphere formed during arc magmatism. Older ages of about 780 Ma for gabbro from the Jabal Ess ophiolite suggest that the ophiolite is either a fragment of fore-arc oceanic crust or oceanic basement on which an arc was built. Gabbro samples from ophiolites of the Bir Umq suture (west-central Arabian Shield) yield zircons with ages of 820–870 Ma and $ ̆ 1250 Ma "> 1250Ma . The 820–870 Ma dates overlap with ages of the oldest nearby arc rocks; this favors an intra-arc or near-arc paleotectonic setting. The older zircons suggest that middle or early Proterozoic crustal material, possibly derived from the Mozambique belt of Africa, was present during back- or intra-arc magmatism. Plagiogranite from the Bir Tuluhah ophiolitic complex at the northern end of the 900 km-long Nabitah mobile belt was dated by the zircon U Pb method at ∼ 830 Ma. This date is in the range of the oldest dated arc rocks along the northern and central parts of the Nabitah suture, but is ∼ 100 Ma older than the oldest arc plutons (tonalites) associated with the southern part of the belt. These age relations suggest that the northern part of the Nabitah belt contains an extension of the Bir Umq suture that was transposed parallel to the Nabitah trend during collision of the arc terranes of the northwest Arabian Shield with the Afif plate to the east. Feldspar lead-isotope data from the ophiolites are of three types: (1) lead from the ophiolitic rocks and arc tonalites of the northwestern Shield and ophiolitic rocks of the Nabitah suture is similar to lead in modern mid-ocean ridge basalt, (2) anomalous radiogenic data from the Thurwah ophiolite are from rocks that contain zircons from pre-late Proterozoic continental crust, and (3) feldspar from the Urd ophiolite shows retarded uranogenic lead growth and is related either to an anomalous and perhaps primitive oceanic mantle source, or in an unknown manner to ancient continental mantle or lower crust of the eastern Arabian Shield.

Precambrian Research↗

Extended history of a 3.5 Ga trondhjemitic gneiss, Wyoming Province, USA: Evidence from U-Pb systematics in zircon

The Beartooth-Bighorn magmatic zone (BBMZ) and the Montana metasedimentary province (MMP) are two major subprovinces of the Archean Wyoming province. In the northwestern Beartooth Mountains, these subprovinces are separated by a structurally, lithologically and metamorphically complex assemblage of lithotectonic units that include: (1) a strongly deformed complex of trondhjemitic gneiss and interlayered amphibolites; and (2) an amphibolite facies mafic unit that occurs in a nappe that structurally overlies the gneiss complex. Zircons from a trondhjemitic blastomylonite in the gneiss complex yield concordant U-Pb ages of 3.5 Ga, establishing it as the oldest rock yet documented in the Wyoming province. Two younger events are also recorded by zircons in this rock: (1) an apparently protracted period of high-grade metamorphism and/or intrusion of additional magmas at ∼ 3.25 Ga; and (2) growth of hydrothermal zircon at ∼ 2.55 Ga, apparently associated with ductile deformation that immediately preceded structural emplacement of the gneiss. Although this latter event appears confined to areas along the BBMZ-MMP boundary, evidence of ∼ 3.25 Ga igneous activity is found in the overlying amphibolite (3.24 Ga) and throughout the MMP. These data suggest that this boundary first developed as a major intracratonic zone of displacement at or before 3.25 Ga. The limited occurrences of 2.8 Ga magmatic activity in the MMP suggest that it had a controlling influence on late Archean magmatism as well.

Precambrian Research↗

Enhancing the Simplified Surface Energy Balance (SSEB) Approach for Estimating Landscape ET: Validation with the METRIC model

Evapotranspiration (ET) can be derived from satellite data using surface energy balance principles. METRIC (Mapping EvapoTranspiration at high Resolution with Internalized Calibration) is one of the most widely used models available in the literature to estimate ET from satellite imagery. The Simplified Surface Energy Balance (SSEB) model is much easier and less expensive to implement. The main purpose of this research was to present an enhanced version of the Simplified Surface Energy Balance (SSEB) model and to evaluate its performance using the established METRIC model. In this study, SSEB and METRIC ET fractions were compared using 7 Landsat images acquired for south central Idaho during the 2003 growing season. The enhanced SSEB model compared well with the METRIC model output exhibiting an r2 improvement from 0.83 to 0.90 in less complex topography (elevation less than 2000 m) and with an improvement of r2 from 0.27 to 0.38 in more complex (mountain) areas with elevation greater than 2000 m. Independent evaluation showed that both models exhibited higher variation in complex topographic regions, although more with SSEB than with METRIC. The higher ET fraction variation in the complex mountainous regions highlighted the difficulty of capturing the radiation and heat transfer physics on steep slopes having variable aspect with the simple index model, and the need to conduct more research. However, the temporal consistency of the results suggests that the SSEB model can be used on a wide range of elevation (more successfully up 2000 m) to detect anomalies in space and time for water resources management and monitoring such as for drought early warning systems in data scarce regions. SSEB has a potential for operational agro-hydrologic applications to estimate ET with inputs of surface temperature, NDVI, DEM and reference ET.

Agricultural Water Management↗

Modules based on the geochemical model PHREEQC for use in scripting and programming languages

The geochemical model PHREEQC is capable of simulating a wide range of equilibrium reactions between water and minerals, ion exchangers, surface complexes, solid solutions, and gases. It also has a general kinetic formulation that allows modeling of nonequilibrium mineral dissolution and precipitation, microbial reactions, decomposition of organic compounds, and other kinetic reactions. To facilitate use of these reaction capabilities in scripting languages and other models, PHREEQC has been implemented in modules that easily interface with other software. A Microsoft COM (component object model) has been implemented, which allows PHREEQC to be used by any software that can interface with a COM server—for example, Excel®, Visual Basic®, Python, or MATLAB". PHREEQC has been converted to a C++ class, which can be included in programs written in C++. The class also has been compiled in libraries for Linux and Windows that allow PHREEQC to be called from C++, C, and Fortran. A limited set of methods implements the full reaction capabilities of PHREEQC for each module. Input methods use strings or files to define reaction calculations in exactly the same formats used by PHREEQC. Output methods provide a table of user-selected model results, such as concentrations, activities, saturation indices, and densities. The PHREEQC module can add geochemical reaction capabilities to surface-water, groundwater, and watershed transport models. It is possible to store and manipulate solution compositions and reaction information for many cells within the module. In addition, the object-oriented nature of the PHREEQC modules simplifies implementation of parallel processing for reactive-transport models. The PHREEQC COM module may be used in scripting languages to fit parameters; to plot PHREEQC results for field, laboratory, or theoretical investigations; or to develop new models that include simple or complex geochemical calculations.

Computers & Geosciences↗

Fluoride geochemistry of thermal waters in Yellowstone National Park: I. Aqueous fluoride speciation

Thermal water samples from Yellowstone National Park (YNP) have a wide range of pH (1–10), temperature, and high concentrations of fluoride (up to 50 mg/l). High fluoride concentrations are found in waters with field pH higher than 6 (except those in Crater Hills) and temperatures higher than 50 °C based on data from more than 750 water samples covering most thermal areas in YNP from 1975 to 2008. In this study, more than 140 water samples from YNP collected in 2006–2009 were analyzed for free-fluoride activity by ion-selective electrode (ISE) method as an independent check on the reliability of fluoride speciation calculations. The free to total fluoride concentration ratio ranged from <1% at low pH values to >99% at high pH. The wide range in fluoride activity can be explained by strong complexing with H + and Al 3+ under acidic conditions and lack of complexing under basic conditions. Differences between the free-fluoride activities calculated with the WATEQ4F code and those measured by ISE were within 0.3–30% for more than 90% of samples at or above 10 −6 molar, providing corroboration for chemical speciation models for a wide range of pH and chemistry of YNP thermal waters. Calculated speciation results show that free fluoride, F − , and major complexes ( HF ( aq ) 0 "> HF(aq)0 , AlF 2+ , AlF 2 + "> AlF2+ and AlF 3 0 "> AlF30 ) account for more than 95% of total fluoride. Occasionally, some complex species like AlF 4 - "> AlF4- , FeF 2+ , FeF 2 + "> FeF2+ , MgF + and BF 2 ( OH ) 2 - "> BF2(OH)2- may comprise 1–10% when the concentrations of the appropriate components are high. According to the simulation results by PHREEQC and calculated results, the ratio of main fluoride species to total fluoride varies as a function of pH and the concentrations and ratios of F and Al.

Yellowstone National Park↗

Geochemistry of glacial sediments in the area of the Bend massive sulfide deposit, north-central Wisconsin

Geochemical exploration in northern Wisconsin has been problematic because of thick glacial overburden and complex stratigraphic record of glacial history. To assess till geochemical exploration in an area of thick glacial cover and complex stratigraphy samples of glacial materials were collected from cores from five rotasonic boreholes near a known massive sulfide deposit, the Bend deposit in north-central Wisconsin. Diamond drilling in the Bend area has defined a long, thin zone of mineralization at least partly intersected at the bedrock surface beneath 30-40 m of unconsolidated glacial sediments. The bedrock surface has remnant regolith and saprolite resulting from pre-Pleistocene weathering. Massive sulfide and mineralized rock collected from diamond drill core from the deposit contain high (10s to 10,000s ppm) concentrations of Ag, As, Au, Bi, Cu, Hg, Se, Te, and Tl. Geochemical properties of the glacial stratigraphic units helped clarify the sequence and source areas of several glacial ice advances preserved in the section. At least two till sheets are recognized. Over the zone of mineralization, saprolite and preglacial alluvial and lacustrine samples are preserved on the bedrock surface in a paleoriver valley. The overlying till sheet is a gray, silty carbonate till with a source hundreds of kilometers to the northwest of the study area. This gray till is overlain by red, sandy till with a source to the north in Proterozoic rocks of the Lake Superior area. The complex glacial stratigraphy confounds down-ice geochemical till exploration. The presence of remnant saprolite, preglacial sediment, and far-traveled carbonate till minimized glacial erosion of mineralized material. As a result, little evidence of down-ice glacial dispersion of lithologic or mineralogic indicators of Bend massive sulfide mineralization was found in the samples from the rotasonic cores. This study points out the importance of determining glacial stratigraphy and history, and identifying favorable lithologies required for geochemical exploration. Drift prospecting in Wisconsin and other areas near the outer limits of the Pleistocene ice sheets may not be unsuccessful, in part, because of complex stratigraphic sequences of multiple glaciations where deposition dominates over erosion. ?? 2004 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

Forecasting water levels using the ConvLSTM algorithm in the Everglades, USA

Forecasting water levels in complex ecosystems like wetlands can support effective water resource management, ecological conservation, and understanding surface and groundwater hydrology. Predictive models can be used to simulate the complex interactions among natural processes, hydrometeorological factors, and human activities. The Greater Everglades in the USA is a well-known example of an ecosystem where complexity has motivated adoption of machine learning algorithms in water level prediction studies. This paper aims to contribute to extending existing machine learning algorithms by integrating spatiotemporal data with deep-learning algorithms in the forecasting process. In this study, a deep-learning model is developed to predict water levels on a regional scale, covering a large area of approximately 9,138 square kilometers in the Everglades ecosystem. This model has the architecture of Convolutional Long Short-Term Memory which can deal with spatiotemporal data by capturing both spatial and temporal dependencies in the training data. The forecasting capabilities of this model (referred to as the global model) are assessed by comparing the global model to two Artificial Neural Networks developed at two different gaging stations, referred to here as local models. One local model is developed at a gaging station directly influenced by nearby water control structures, whereas the other is developed at a gaging station located farther away from these structures. By leveraging data from the Everglades Depth Estimation Network spanning from January 2002 to May 2023, the global and local models were trained to forecast water levels with a two-day lead time. Our findings suggest that both the global and local models perform with approximately the same level of accuracy, with Mean Absolute Relative Error values ranging from 0.38% to 1.4% at the selected stations. The developed global model has demonstrated strong potential as a standalone forecasting tool for the entire study area in the Everglades and could eliminate the need for developing multiple local models. This finding also highlights how machine learning can capture complex spatial and temporal relationships to generate accurate water level predictions on a regional scale.

Florida↗

Nonexplosive and explosive magma/wet-sediment interaction during emplacement of Eocene intrusions into Cretaceous to Eocene strata, Trans-Pecos igneous province, West Texas

Eocene intrusion of alkaline basaltic to trachyandesitic magmas into unlithified, Upper Cretaceous (Maastrichtian) to Eocene fluvial strata in part of the Trans-Pecos igneous province in West Texas produced an array of features recording both nonexplosive and explosive magma/wet-sediment interaction. Intrusive complexes with 40 Ar/ 39 Ar dates of ~ 47-46??Ma consist of coherent basalt, peperite, and disrupted sediment. Two of the complexes cutting Cretaceous strata contain masses of conglomerate derived from Eocene fluvial deposits that, at the onset of intrusive activity, would have been > 400-500??m above the present level of exposure. These intrusive complexes are inferred to be remnants of diatremes that fed maar volcanoes during an early stage of magmatism in this part of the Trans-Pecos province. Disrupted Cretaceous strata along diatreme margins record collapse of conduit walls during and after subsurface phreatomagmatic explosions. Eocene conglomerate slumped downward from higher levels during vent excavation. Coherent to pillowed basaltic intrusions emplaced at the close of explosive activity formed peperite within the conglomerate, within disrupted Cretaceous strata in the conduit walls, and within inferred remnants of the phreatomagmatic slurry that filled the vents during explosive volcanism. A younger series of intrusions with 40 Ar/ 39 Ar dates of ~ 42??Ma underwent nonexplosive interaction with Upper Cretaceous to Paleocene mud and sand. Dikes and sills show fluidal, billowed, quenched margins against the host strata, recording development of surface instabilities between magma and groundwater-rich sediment. Accentuation of billowed margins resulted in propagation of intrusive pillows into the adjacent sediment. More intense disruption and mingling of quenched magma with sediment locally produced fluidal and blocky peperite, but sufficient volumes of pore fluid were not heated rapidly enough to generate phreatomagmatic explosions. This work suggests that Trans-Pecos Texas may be an important locale for the study of subvolcanic phreatomagmatic processes and associated phenomena. Eocene intrusions in the study area underwent complex interactions with wet sediment at shallow levels beneath the surface in strata as old as Maastrichtian, which must have remained unlithified and rich in pore water for ~ 20-25??Ma. ?? 2009 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

Refining the link between the Holocene development of the Mississippi River Delta and the geologic evolution of Cat Island, MS: implications for delta-associated barrier islands

The geologic evolution of barrier islands is profoundly influenced by the nature of the deposits underlying them. Many researchers have speculated on the origin and evolution of Cat Island in Mississippi, but uncertainty remains about whether or not the island is underlain completely or in part by deposits associated with the past growth of the Mississippi River delta. In part, this is due to a lack of comprehensive geological information offshore of the island that could augment previous stratigraphic interpretations based on terrestrial borings. An extensive survey of Cat Island and its surrounding waters was conducted, including shallow-water geophysics (e.g., high-resolution chirp seismic, side-scan sonar, and swath and single-beam bathymetry) and both terrestrial and marine vibracoring. High-resolution seismic data and vibracores from south and east of the island show two horizontally laminated silt units; marine radiocarbon dates indicate that they are St. Bernard delta complex (SBDC) deposits. Furthermore, seismic data reveal that the SBDC deposits taper off toward the southern shoreline of Cat Island and to the west, morphology consistent with the distal edge of a delta complex. The sedimentology and extent of each unit suggest that the lower unit may have been deposited during an earlier period of continuous river flow while the upper unit may represent reduced or sporadic river flow. OSL dates from the island platform (beneath beach ridge complexes) indicate three stages of terrestrial evolution: island emergence resulting from relative sea-level rise (~ 5400 ybp) island aggradation via littoral transport (~ 2500–4000 ybp) and island degradation due to delta-mediated changes in wave direction (present– ~ 3600 ybp). Finally, the combination of terrestrial and marine data shows that portions of Cat Island that are lower in elevation than the central part of the island are younger and are likely underlain by a thin layer of deltaic sediments. This underscores the potential for increased future vulnerability of barrier islands that develop adjacent to major river delta complexes.

Mississippi↗

Composition, distribution, and potential toxicity of organochlorine mixtures in bed sediments of streams

Mixtures of organochlorine compounds have the potential for additive or interactive toxicity to organisms exposed in the stream. This study uses a variety of methods to identify mixtures and a modified concentration-addition approach to estimate their potential toxicity at 845 stream sites across the United States sampled between 1992 and 2001 for organochlorine pesticides and polychlorinated biphenyls (PCBs) in bed sediment. Principal-component (PC) analysis identified five PCs that account for 77% of the total variance in 14 organochlorine compounds in the original dataset. The five PCs represent: (1) chlordane-related compounds and dieldrin; (2) p,p′ -DDT and its degradates; (3) o,p′ -DDT and its degradates; (4) the pesticide degradates oxychlordane and heptachlor epoxide; and (5) PCBs. The PC analysis grouped compounds that have similar chemical structure (such as parent compound and degradate), common origin (in the same technical pesticide mixture), and(or) similar relation of concentrations to land use. For example, the highest concentrations of chlordane compounds and dieldrin occurred at urban sites, reflecting past use of parent pesticides for termite control. Two approaches to characterizing mixtures—PC-based mixtures and unique mixtures—were applied to all 299 samples with a detection of two or more organochlorine compounds. PC-based mixtures are defined by the presence (in the sample) of one or more compounds associated with that PC. Unique mixtures are defined as a specific combination of two or more compounds detected in a sample, regardless of how many other compounds were also detected in that sample. The simplest PC-based mixtures (containing compounds from 1 or 2 PCs) commonly occurred in a variety of land use settings. Complex mixtures (containing compounds from 3 or more PCs) were most common in samples from urban and mixed/urban sites, especially in the Northeast, reflecting high concentrations of multiple chlordane, dieldrin, DDT-related compounds, and(or) PCBs. The most commonly occurring unique mixture ( p,p′ -DDE, p,p′ -DDD) occurred in both simple and complex PC-based mixtures, and at both urban and agricultural sites. Mean Probable Effect Concentration Quotients (PEC-Q) values, which estimate the potential toxicity of organochlorine contaminant mixtures, were highest for complex mixtures. Mean PEC-Q values were highest for urban sites in the Northeast, followed by mixed/urban sites in the Northeast and agricultural sites in cotton growing areas. These results demonstrate that the PEC-Q approach can be used in combination with PC-based and unique mixture analyses to relate potential aquatic toxicity of contaminant mixtures to mixture complexity, land use, and other surrogates for contaminant sources.

Science of the Total Environment↗

Evaluation of conditions along the grounding line of temperate marine glaciers: An example from Muir Inlet, Glacier Bay, Alaska

In the marine environment, stability of the glacier terminus and the location of subglacial streams are the dominant controls on the distribution of grounding-line deposits within morainal banks. A morainal bank complex in Muir Inlet, Glacier Bay, SE Alaska, is used to develop a model of terminus stability and location of subglacial streams along the grounding line of temperate marine glaciers. This model can be used to interpret former grounding-line conditions in other glacimarine settings from the facies architecture within morainal bank deposits. The Muir Inlet morainal bank complex was deposited between 1860 A.D. and 1899 A.D., and historical observations provide a record of terminus positions, glacial retreat rates and sedimentary sources. These data are used to reconstruct the depositional environment and to develop a correlation between sedimentary facies and conditions along the grounding line. Four seismic facies identified on the high-resolution seismic-reflection profiles are used to interpret sedimentary facies within the morainal bank complex. Terminus stability is interpreted from the distribution of sedimentary facies within three distinct submarine geomorphic features, a grounding-line fan; stratified ridges, and a field of push ridges. The grounding-line fan was deposited along a stable terminus and is represented on seismic-reflection profiles by two distinct seismic facies, a proximal and a distal fan facies. The proximal fan facies was deposited at the efflux of subglacial streams and indicates the location of former glacifluvial discharges into the sea. Stratified ridges formed as a result of the influence of a quasi-stable terminus on the distribution of sedimentary facies along the grounding line. A field of push ridges formed along the grounding line of an unstable terminus that completely reworked the grounding-line deposits through glacitectonic deformation. Between 1860 A.D. and 1899 A.D. (39 years), 8.96 x 108 m3 of sediment were deposited within the Muir Inlet morainal bank complex at an average annual sediment accumulation rate of 2.3 x 107 m3/a. This rate represents the annual sediment production capacity of the glacier when the Muir Inlet drainage basin is filled with glacial ice.

Marine Geology↗