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At least 1,189 records · Page 66Linked to original sources
USGS2002

Denitrification in the recharge area and discharge area of a transient agricultural nitrate plume in a glacial outwash sand aquifer, Minnesota

Recharge rates of nitrate (NO 3 − ) to groundwater beneath agricultural land commonly are greater than discharge rates of NO 3 − in nearby streams, but local controls of NO 3 − distribution in the subsurface generally are poorly known. Groundwater dating (CFC, 3 H) was combined with chemical (ions and gases) and stable isotope (N, S, and C) analyses to resolve the effects of land use changes, flow patterns, and water‐aquifer reactions on the distributions of O 2 , NO 3 − , SO 4 = , and other constituents in a two‐dimensional vertical section leading from upland cultivated fields to a riparian wetland and stream in a glacial outwash sand aquifer near Princeton, Minnesota. Within this section a “plume” of oxic NO 3 − ‐rich groundwater was present at shallow depths beneath the fields and part of the wetland but terminated before reaching the stream or the wetland surface. Groundwater dating and hydraulic measurements indicate travel times in the local flow system of 0 to >40 years, with stratified recharge beneath the fields, downward diversion of the shallow NO 3 − ‐bearing plume by semiconfining organic‐rich valley‐filling sediments under the wetland and upward discharge across the valley and stream bottom. The concentrations and δ 15 N values of NO 3 − and N 2 indicate that the NO 3 − plume section was bounded in three directions by a curvilinear zone of active denitrification that limited its progress; however, when recalculated to remove the effects of denitrification, the data also indicate changes in both the concentrations and δ 15 N values of NO 3 − that was recharged in the past. Isotope data and mass balance calculations indicate that FeS 2 and other ferrous Fe phases were the major electron donors for denitrification in at least two settings: (1) within the glacial‐fluvial aquifer sediments beneath the recharge and discharge areas and (2) along the bottom of the valley‐filling sediments in the discharge area. Combined results indicate that the shape and progress of the oxic NO 3 − plume termination were controlled by a combination of (1) historical and spatial variations in land use practices, (2) contrast in groundwater flow patterns between the agricultural recharge area and riparian wetland discharge area, and (3) distribution and abundance of electron donors in both the sand aquifer and valley‐filling sediments. The data are consistent with slow migration of redox zones through the aquifer in response to recharging oxic groundwater during Holocene time, then an order‐of‐magnitude increase in the flux of electron acceptors as a result of agricultural NO 3 − contamination in the late twentieth century, to which the redox zone configuration still may be adjusting. The importance of denitrification for NO 3 − movement through formerly glaciated terrains should depend on the source areas and depositional environments of the glacial sediments, as well as geomorphology and recent stream‐valley sediment history.

Water Resources Research↗
USGS2014

On the effects of scale for ecosystem services mapping

Ecosystems provide life-sustaining services upon which human civilization depends, but their degradation largely continues unabated. Spatially explicit information on ecosystem services (ES) provision is required to better guide decision making, particularly for mountain systems, which are characterized by vertical gradients and isolation with high topographic complexity, making them particularly sensitive to global change. But while spatially explicit ES quantification and valuation allows the identification of areas of abundant or limited supply of and demand for ES, the accuracy and usefulness of the information varies considerably depending on the scale and methods used. Using four case studies from mountainous regions in Europe and the U.S., we quantify information gains and losses when mapping five ES - carbon sequestration, flood regulation, agricultural production, timber harvest, and scenic beauty - at coarse and fine resolution (250 m vs. 25 m in Europe and 300 m vs. 30 m in the U.S.). We analyze the effects of scale on ES estimates and their spatial pattern and show how these effects are related to different ES, terrain structure and model properties. ES estimates differ substantially between the fine and coarse resolution analyses in all case studies and across all services. This scale effect is not equally strong for all ES. We show that spatially explicit information about non-clustered, isolated ES tends to be lost at coarse resolution and against expectation, mainly in less rugged terrain, which calls for finer resolution assessments in such contexts. The effect of terrain ruggedness is also related to model properties such as dependency on land use-land cover data. We close with recommendations for mapping ES to make the resulting maps more comparable, and suggest a four-step approach to address the issue of scale when mapping ES that can deliver information to support ES-based decision making with greater accuracy and reliability.

PLoS ONE↗
USGS2007

Factors Affecting Spatial and Temporal Variability in Nutrient and Pesticide Concentrations in the Surficial Aquifer on the Delmarva Peninsula

Water quality in the unconfined, unconsolidated surficial aquifer on the Delmarva Peninsula is influenced by the availability of soluble ions from natural and human sources, and by geochemical factors that affect the mobility and fate of these ions within the aquifer. Ground-water samples were collected from 60 wells completed in the surficial aquifer of the peninsula in 2001 and analyzed for major ions, nutrients, and selected pesticides and degradation products. Analytical results were compared to similar data from a subset of sampled wells in 1988, as well as to land use, soils, geology, depth, and other potential explanatory variables to demonstrate the effects of natural and human factors on water quality in the unconfined surficial aquifer. This study was conducted as part of the National Water-Quality Assessment Program of the U.S. Geological Survey, which is designed (in part) to describe the status and trends in ground-water quality and to provide an understanding of natural and human factors that affect ground-water chemistry in different parts of the United States. Results of this study may be useful for water-resources managers tasked with addressing water-quality issues of local and regional importance because the surficial aquifer on the Delmarva Peninsula is a major source of water for domestic and public supply and provides the majority of flow in local streams. Human impacts are apparent in ground-water quality throughout the surficial aquifer. The surficial aquifer on the Delmarva Peninsula is generally sandy and very permeable with well-oxygenated ground water. Dissolved constituents found throughout various depths of the unconfined aquifer are likely derived from the predominantly agricultural practices on the peninsula, although effects of road salt, mineral dissolution, and other natural and human influences are also apparent in some areas. Nitrate occurred at concentrations exceeding natural levels in many areas, and commonly exceeded 10 milligrams per liter (as nitrogen). In addition to land use in the aquifer recharge area, concentrations of nitrate in ground water are related to regional patterns in soil drainage that affect underlying aquifer redox conditions. Over the peninsula, nitrate concentrations are not related to recharge date of the water, but are positively correlated with depth in shallow wells screened beneath agricultural areas. Nitrate concentrations increased in oxic areas (dissolved oxygen greater than 1 milligram per liter) of the deeper part of the surficial aquifer used for domestic supply by an average of about 2 milligrams per liter between 1988 and 2001, although no changes were apparent in shallower parts of the aquifer over that same period. Water in the surficial aquifer generally flows from land-surface recharge to surface-water discharge areas in less than 30 years. As a result, the entire flow system in the surficial aquifer has likely been affected by human activities on and near the land surface over the past several decades. Pesticide compounds occurred widely at low levels throughout the surficial aquifer. The most commonly used herbicides (metolachlor, alachlor, and atrazine) were the most commonly detected. These pesticides primarily occurred in ground water in the form of degradation products. The widespread occurrence of these and other pesticide compounds reflects their abundant use as well as chemical properties and aquifer characteristics that allow their movement into ground water. Mixtures of pesticides are common. Most samples contained at least 3 different compounds; several samples contained as many as 11. Pesticide concentrations in the surficial aquifer are relatively high beneath recharge areas with well-drained soils in the shallow part of the aquifer and in oxic environments throughout the surficial aquifer. Concentrations are generally below existing drinking-water standards, although standards are not available for all of the pesticide compound

Scientific Investigations Report↗
USGS2017

Electrical resistivity investigation of fluvial geomorphology to evaluate potential seepage conduits to agricultural lands along the San Joaquin River, Merced County, California, 2012–13

Increased flows in the San Joaquin River, part of the San Joaquin River Restoration Program, are designed to help restore fish populations. However, increased seepage losses could result from these higher restoration flows, which could exacerbate existing drainage problems in neighboring agricultural lands and potentially damage crops. Channel deposits of abandoned river meanders that are hydraulically connected to the river could act as seepage conduits, allowing rapid and widespread water-table rise during restoration flows. There is a need to identify the geometry and properties of these channel deposits to assess their role in potential increased seepage effects and to evaluate management alternatives for reducing seepage. Electrical and electromagnetic surface geophysical methods have provided a reliable proxy for lithology in studies of fluvial and hyporheic systems where a sufficient electrical contrast exists between deposits of differing grain size. In this study, direct-current (DC) resistivity was used to measure subsurface resistivity to identify channel deposits and to map their subsurface geometry. The efficacy of this method was assessed by using DC resistivity surveys collected along a reach of the San Joaquin River in Merced County, California, during the summers of 2012 and 2013, in conjunction with borings and associated measurements from a hydraulic profiling tool. Modeled DC resistivity data corresponded with data from cores, hand-auger samples, a hydraulic profiling tool, and aerial photographs, confirming that DC resistivity is effective for differentiating between silt and sand deposits in this setting. Modeled DC resistivity data provided detailed two-dimensional cross-sectional resistivity profiles to a depth of about 20 meters. The distribution of high-resistivity units in these profiles was used as a proxy for identifying areas of high hydraulic conductivity. These data were used subsequently to guide the location and depth of wells installed onsite for monitoring flow in the channel deposits. Estimates of the cross-sectional area of channel deposits from DC resistivity pseudosections can provide critical input for groundwater-flow models designed to simulate river seepage and evaluate seepage-management alternatives.

California↗
USGS2022

Anthropogenic stressors compound climate impacts on inland lake dynamics: The case of Hamun Lakes

Inland lakes face unprecedented pressures from climatic and anthropogenic stresses, causing their recession and desiccation globally. Climate change is increasingly blamed for such environmental degradation, but in many regions, direct anthropogenic pressures compound, and sometimes supersede, climatic factors. This study examined a human-environmental system – the terminal Hamun Lakes on the Iran-Afghanistan border – that embodies amplified challenges of inland waters. Satellite and climatic data from 1984 to 2019 were fused, which documented that the Hamun Lakes lost 89% of their surface area between 1999 and 2001 (3809 km 2 versus 410 km 2 ), coincident with a basin-wide, multi-year meteorological drought. The lakes continued to shrink afterwards and desiccated in 2012, despite the above-average precipitation in the upstream basin. Rapid growth in irrigated agricultural lands occurred in upstream Afghanistan in the recent decade, consuming water that otherwise would have fed the Hamun Lakes. Compounding upstream anthropogenic stressors, Iran began storing flood water that would have otherwise drained to the lakes, for urban and agricultural consumption in 2009. Results from a deep Learning model of Hamun Lakes' dynamics indicate that the average lakes' surface area from 2010 to 2019 would have been 2.5 times larger without increasing anthropogenic stresses across the basin. The Hamun Lakes' desiccation had major socio-environmental consequences, including loss of livelihood, out-migration, dust-storms, and loss of important species in the region.

Science of the Total Envionrment↗
USGS2014

Habitat prioritization across large landscapes, multiple seasons, and novel areas: an example using greater sage-grouse in Wyoming

Animal habitat selection is an important and expansive area of research in ecology. In particular, the study of habitat selection is critical in habitat prioritization efforts for species of conservation concern. Landscape planning for species is happening at ever-increasing extents because of the appreciation for the role of landscape-scale patterns in species persistence coupled to improved datasets for species and habitats, and the expanding and intensifying footprint of human land uses on the landscape. We present a large-scale collaborative effort to develop habitat selection models across large landscapes and multiple seasons for prioritizing habitat for a species of conservation concern. Greater sage-grouse ( Centrocercus urophasianus , hereafter sage-grouse) occur in western semi-arid landscapes in North America. Range-wide population declines of this species have been documented, and it is currently considered as “warranted but precluded” from listing under the United States Endangered Species Act. Wyoming is predicted to remain a stronghold for sage-grouse populations and contains approximately 37% of remaining birds. We compiled location data from 14 unique radiotelemetry studies (data collected 1994–2010) and habitat data from high-quality, biologically relevant, geographic information system (GIS) layers across Wyoming. We developed habitat selection models for greater sage-grouse across Wyoming for 3 distinct life stages: 1) nesting, 2) summer, and 3) winter. We developed patch and landscape models across 4 extents, producing statewide and regional (southwest, central, northeast) models for Wyoming. Habitat selection varied among regions and seasons, yet preferred habitat attributes generally matched the extensive literature on sage-grouse seasonal habitat requirements. Across seasons and regions, birds preferred areas with greater percentage sagebrush cover and avoided paved roads, agriculture, and forested areas. Birds consistently preferred areas with higher precipitation in the summer and avoided rugged terrain in the winter. Selection for sagebrush cover varied regionally with stronger selection in the Northeast region, likely because of limited availability, whereas avoidance of paved roads was fairly consistent across regions. We chose resource selection function (RSF) thresholds for each model set (seasonal × regional combination) that delineated important seasonal habitats for sage-grouse. Each model set showed good validation and discriminatory capabilities within study-site boundaries. We applied the nesting-season models to a novel area not included in model development. The percentage of independent nest locations that fell directly within identified important habitat was not overly impressive in the novel area (49%); however, including a 500-m buffer around important habitat captured 98% of independent nest locations within the novel area. We also used leks and associated peak male counts as a proxy for nesting habitat outside of the study sites used to develop the models. A 1.5-km buffer around the important nesting habitat boundaries included 77% of males counted at leks in Wyoming outside of the study sites. Data were not available to quantitatively test the performance of the summer and winter models outside our study sites. The collection of models presented here represents large-scale resource-management planning tools that are a significant advancement to previous tools in terms of spatial and temporal resolution.

Wyoming↗
USGS2026

Evaluating evidence of changing regional occupancy of four bat species in response to forest management practices

Coordinated, regional strategies to guide effective management and conservation of forests can be used to balance conservation with management for other objectives such as timber, scenic viewsheds, and fire. A key part of these regional strategies is incorporating knowledge of how management actions may affect certain species, especially those that are sensitive or are of concern. However, knowledge of how management actions may affect species is inferred from studies conducted across small areas where the species’ behavior and forest conditions are easily assessed. Here, we examine how occupancy of four bat species responds to forest management across the eastern United States at regional scales. We used range-wide capture and stationary acoustic surveys from the North American Bat Monitoring Program from 2010 to 2020 to estimate yearly summer occupancy for four bat species of conservation concern identified in the U.S. Department of Agriculture Forest Service (USFS) Southern and Eastern Regions Bat Conservation Strategy: little brown bat ( Myotis lucifugus ), northern long-eared bat ( Myotis septentrionalis ), Indiana bat ( Myotis sodalis ), and tricolored bat ( Perimyotis subflavus ), and assessed the degree to which occupancy of each species changed after different vegetation management actions were implemented on USFS lands. We identified 78 different management actions that were hypothesized to influence summer bat occupancy at two spatial scales (5-km and 10-km) across the eastern United States from the Forest Service Activity Tracking System and grouped these management actions into four vegetation management types: clear-cutting, fire, thinning, and ground vegetation management. To evaluate potential effects of these vegetation management types on bat occupancy, we created a yearly management metric representing the average number of years that had passed since any one of the included management actions in each management type had been implemented in each 5-km or 10-km grid cell, weighted by the proportion of the grid cell covered by the management treatment history. We chose these metrics to ask if more management or management done recently had a larger effect on bat occupancy than less management or management done long-ago. We then fit Bayesian hierarchical multi-scale occupancy models for each species to assess how occupancy changed in response to the amount and time since implementation of each vegetation management type. Using the estimated relationships between the yearly metrics of management and bat occupancy, we created predictions for how bat occupancy responded at 1- and 5- years after implementation. We found substantial differences in the response of the four species to the four vegetation management types. Ground vegetation management provided the greatest increase in expected occupancy at 1 year after implementation for little brown bat, long-eared bat, and tricolored bat, while fire provided the greatest increase in expected occupancy for Indiana bat. Thinning provided increases for all species at 1 year after implementation, but even greater increases at 5 years after implementation. Clear-cutting, on the other hand, tended to result in decreased occupancy at both 1- and 5-years after implementation for each species and had the greatest effect on tricolored bat at 1 year after implementation. Clear evidence for how management types like these may be affecting bat populations can be used at regional scales to help private and public forest managers achieve their strategic goals.

eastern United States↗
USGS1995

Evaluation of a monitoring program for assessing the effects of management practices on the quantity and quality of drainwater from the Panoche Water District, western San Joaquin Valley, California

An evaluation was made of an existing monitoring program in the Panoche Water District for 1986-93. The Panoche Water District is an agricultural area located in the western San Joaquin Valley of California. Because irrigation drainage from this area has high concentrations of dissolved solids and selenium, management strategies have been developed to improve the quality of drainwater discharge. The purpose of the Panoche Water District's monitoring program is to assess the effects of water- and land-use practices on local ground water and drain flow from the district. Drainflow from the district consists of the discharge from 50 separate on-farm underground tile-drainage systems. The Panoche Water District maintains information on water deliveries, planned and actual crop types, and planned and actual acreages planted each year. In addition, the water district monitors ground-water and drainage-system discharges using a variety of data-collection methods. A total of 62 observation well sites are used to monitor ground-water level and quality. A total of 42 sites were monitored for drainflow quantity, and drain flow quality samples were collected from the outlets of each of the 50 drainage systems. However, these data were collected inconsistently and (or) intermittently during the period studied. All data obtained from the water district were compiled and stored in a geographic information system database. Water delivered for irrigation by the Panoche Water District is a mix of imported water and local ground water pumped directly into delivery canals. Although delivered water is a mix, information on the proportion of water from the two sources is not reported. Also, individual growers pump directly to their crops unknown quantities of ground water, the total of which could be greater than 60 percent of total applications during years when water district deliveries are greatly reduced (for example, the years during and following a drought). To evaluate the effects of irrigation on ground-water and drainflow quality, data on the combined chemical characteristics and the volume of water applied to crops are needed as part of the district's monitoring program. For example, without these data, this study could estimate only the effects of irrigation on ground-water recharge for 1986 (60.4 106 m3/y), 1987 (74.2 106 m3/y), and 1988 (56.0 106 m3/y) in the Panoche Water District water years when the amount of ground water pumped by individual growers was probably small. Water-level data show a significant decline of the water table in the upslope, undrained parts of the study area, and little or no significant change in the down slope, drained parts of the study area. Pumping from productions wells, most of which are located in the upslope part of the study area, may have contributed to the decline of the water table in the upslope area. The quantities of drainflow, dissolved solids, and selenium discharged from the study area decreased during the study period. However, drainflow, dissolved solids, and selenium discharged from individual on-farm drainage systems did not decrease. These data also illustrate the need for consistent and regular monitoring of the factors that affect drainage in the western San Joaquin Valley.

Open-File Report↗
USGS1988

Water use in Kentucky, 1985

Water use information for 1985 was collected and reported by county for eight major categories of use. Seven of the categories were offstream uses, which included (1) public supply , (2) commercial, (3) domestic, (4) industrial, (5) mining, (6) thermoelectric, and (7) agricultural uses. The agricultural uses category was separated into irrigation and livestock water use. Instream water-use data also were collected for hydroelectric power generation. Water use in Kentucky was estimated to average 4,200 million gallons per day (M gal/d) during 1985 for all offstream uses. About 95% of this amount was from surface water sources, and about 5% was from groundwater sources. Per capita use for all offstream uses was about 1,100 gal/day. About 260 M gal/d was consumed (not returned to the surface--or groundwater system). Instream water use for hydroelectric power generation was estimated to be 91,000 M gal/d. Almost 97% of the offstream water withdrawals in 1985 were withdrawn for thermoelectric, public supply, and industrial use. Cooling water used in the production of thermoelectric power accounted for about 81% of the total offstream water use in 1985. Water withdrawn for public supplies was the second largest offstream use at about 10 % of the total, and industrial water use was almost 6%. Thermoelectric, domestic, and livestock uses accounted for almost 90% of the consumptive use in 1985. Consumptive use in the thermoelectric category was almost one-half of the total amount consumed in the State for all uses. (USGS)

Water-Resources Investigations Report↗
USGS2021

Developing a strategy for the national coordinated soil moisture monitoring network

Soil moisture is a critical land surface variable, affecting a wide variety of climatological, agricultural, and hydrological processes. Determining the current soil moisture status is possible via a variety of methods, including in situ monitoring, remote sensing, and numerical modeling. Although all of these approaches are rapidly evolving, there is no cohesive strategy or framework to integrate these diverse information sources to develop and disseminate coordinated national soil moisture products that will improve our ability to understand climate variability. The National Coordinated Soil Moisture Monitoring Network initiative has developed a national strategy for network coordination with NOAA's National Integrated Drought Information System. The strategy is currently in review within NOAA, and work is underway to implement the initial milestones of the strategy. This update reviews the goals and steps being taken to establish this national-scale coordination for soil moisture monitoring in the United States.

Vadose Zone Journal↗
USGS2005

Groundwater recharge and sustainability in the High Plains aquifer in Kansas, USA

Sustainable use of groundwater must ensure not only that the future resource is not threatened by overuse, but also that natural environments that depend on the resource, such as stream baseflows, riparian vegetation, aquatic ecosystems, and wetlands are protected. To properly manage groundwater resources, accurate information about the inputs (recharge) and outputs (pumpage and natural discharge) within each groundwater basin is needed so that the long-term behavior of the aquifer and its sustainable yield can be estimated or reassessed. As a first step towards this effort, this work highlights some key groundwater recharge studies in the Kansas High Plains at different scales, such as regional soil-water budget and groundwater modeling studies, county-scale groundwater recharge studies, as well as field-experimental local studies, including some original new findings, with an emphasis on assumptions and limitations as well as on environmental factors affecting recharge processes. The general impact of irrigation and cultivation on recharge is to appreciably increase the amount of recharge, and in many cases to exceed precipitation as the predominant source of recharge. The imbalance between the water input (recharge) to the High Plains aquifer and the output (pumpage and stream baseflows primarily) is shown to be severe, and responses to stabilize the system by reducing water use, increasing irrigation efficiency, adopting water-saving land-use practices, and other measures are outlined. Finally, the basic steps necessary to move towards sustainable use of groundwater in the High Plains are delineated, such as improving the knowledge base, reporting and providing access to information, furthering public education, as well as promoting better understanding of the public's attitudinal motivations; adopting the ecosystem and adaptive management approaches to managing groundwater; further improving water efficiency; exploiting the full potential of dryland and biosaline agriculture; and adopting a goal of long-term sustainable use. ?? Springer-Verlag 2005.

Hydrogeology Journal↗
USGS2001

Mercury and methylmercury in water and sediment of the Sacramento River Basin, California

Mercury (Hg) and methylmercury (CH3Hg+) concentrations in streambed sediment and water were determined at 27 locations throughout the Sacramento River Basin, CA. Mercury in sediment was elevated at locations downstream of either Hg mining or Au mining activities where Hg was used in the recovery of Au. Methylmercury in sediment was highest (2.84 ng/g) at a location with the greatest wetland land cover, in spite of lower total Hg at that site relative to other river sites. Mercury in unfiltered water was measured at 4 locations on the Sacramento River and at tributaries draining the mining regions, as well as agricultural regions. The highest levels of Hg in unfiltered water (2248 ng/l) were measured at a site downstream of a historic Hg mining area, and the highest levels at all sites were measured in samples collected during high streamflow when the levels of suspended sediment were also elevated. Mercury in unfiltered water exceeded the current federal and state recommended criterion for protection of aquatic life (50 ng/l as total Hg in unfiltered water) only during high streamflow conditions. The highest loading of Hg to the San Francisco Bay system was attributed to sources within the Cache Creek watershed, which are downstream of historic Hg mines, and to an unknown source or sources to the mainstem of the Sacramento River upstream of historic Au mining regions. That unknown source is possibly associated with a volcanic deposit. Methylmercury concentrations also were dependent on season and hydrologic conditions. The highest levels (1.98 ng/l) in the Sacramento River, during the period of study, were measured during a major flood event. The reactivity of Hg in unfiltered water was assessed by measuring the amount available for reaction by a strong reducing agent. Although most Hg was found to be nonreactive, the highest reactivity (7.8% of the total Hg in water) was measured in the sample collected from the same site with high CH3Hg+ in sediment, and during the time of year when that site was under continual flooded conditions. Although Hg concentrations in water downstream of the Hg mining operations were measured as high as 2248 ng/l during stormwater runoff events, the transported Hg was found to have a low potential for geochemical transformations, as indicated by the low reactivity to the reducing agent (0.0001% of the total), probably because most of the Hg in the unfiltered water sample was in the mercury sulfide form.

Applied Geochemistry↗
USGS2022

Evaluation of salinity and nutrient conditions in the Heart River Basin, North Dakota, 1970–2020

The Heart River Basin is predominantly an agricultural basin in western North Dakota and is approximately 3,350 square miles. The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Natural Resources Conservation Service and the Grant County Soil Conservation District, completed a study to assess spatial and temporal patterns of water quality in the Heart River Basin. The purpose of this report is to describe the methods and results of a study to evaluate salinity and nutrients in the Heart River Basin in western North Dakota. Water-quality and streamflow data used in the study were compiled from 1970 to 2020 using the National Water Quality Monitoring Council Water Quality Portal and National Water Information System. Changes in streamflow characteristics were investigated at three sites from 1970 to 2020, and changes in water quality were investigated at four sites from 1974 to 2019. Streamflow analysis indicated decreasing streamflow from 1970 until the late 1990s followed by increasing streamflow through 2020, with the largest increase in the 7-day minimum streamflow or base flow. For the historical water-quality trend period (1974–2019), total dissolved solids, sulfate, sodium, chloride, and sodium adsorption ratio concentrations have increased since the mid-1970s through 2019. Potassium concentrations during the historical period remained mostly constant with some small fluctuations. Calcium and magnesium concentrations increased since the mid-1970s at all sites, except for a decrease at one site between 1974 and 1999. During the recent trend period (1999–2019), increasing concentrations in total dissolved solids, sulfate, sodium, chloride, calcium, magnesium, and sodium adsorption ratios were observed across the Heart River Basin. The magnitude of the increases was smaller at tributary sites compared to main-stem sites. During the recent period, potassium was mostly constant, although small (−0.9 milligram per liter or less) decreases on tributaries and minor (1.3 milligrams per liter) increases on the main-stem sites were detected. Unlike dissolved ion concentrations, significant increases in nutrient concentrations were not detected from 1999 to 2019, but nitrate plus nitrite concentrations most likely decreased upstream from Lake Tschida. Inverse modeling for period 1 (1974–99) in model zone 1 (Heart River reach from site 5 to site 6) had eight reasonable models that indicated the clay mineral-water interactions and dissolution of evaporites control the geochemistry. Results of the inverse modeling for period 2 (1999–2019) in model zone 1 also had eight reasonable models that indicated that the dissolution of evaporites was the major geochemical control. Results of the geochemical modeling for period 1 (1974–99) in model zone 2 (Heart River and Sweetbriar Creek reach from sites 20 and 21 to site 22) produced seven reasonable models, and the geochemical control of the system was the dissolution of sulfate evaporite minerals. Geochemical modeling results for period 2 (1999–2019) in model zone 2 produced 11 reasonable models and was also controlled by the dissolution of sulfate evaporite minerals. Differences between the two model zones indicated that geology controls some of the water-quality changes in the Heart River Basin. Loads were estimated for total dissolved solids, sulfate, sodium, and chloride and total phosphorus. Annual loads estimated for the Heart River from 2013 through 2020 at the Heart River site upstream from Lake Tschida (site 5) and near Mandan (site 22) were generally greatest in 2014 and least in 2016 for total dissolved solids, sulfate, sodium, and chloride. Most of the annual loads of total dissolved solids, sulfate, sodium, and chloride are delivered in March through July in the Heart River at these sites and are likely from snowmelt and spring and summer rains. The mean annual yields of total dissolved solids and sodium from 2013 to 2020 generally were largest in Big Muddy Creek (site 18), whereas yields of sulfate and chloride were largest at Sweetbriar Creek (site 21) compared to the other selected sites in the Heart River Basin. Larger yields of total dissolved solids, sulfate, sodium, and chloride at sites located on Big Muddy Creek and Sweet Briar Creek in the lower Heart River Basin were likely a result of differences in geology and soils upstream from the selected sites. A mass balance of total dissolved solids, sulfate, sodium, and chloride was estimated for the lower Heart River Basin, specifically the reach below Lake Tschida to Mandan (site 7 to site 22). Intervening flow was the largest contributor to the dissolved ion loads in the lower Heart River Basin and is an important part of understanding the transport of dissolved ions in the basin. The intervening load can include groundwater discharge, irrigation return flow, local runoff, and input from smaller ephemeral tributaries. Tributaries in the lower Heart River Basin contributed portions of the total dissolved solids, sulfate, sodium, and chloride loads at the Heart River near Mandan (site 22) that generally were proportional to the streamflow contributions. Annual loads for total phosphorus between 2013 and 2020 at the Heart River site upstream from Lake Tschida (site 5) and near Mandan (site 22) generally were largest in 2019 and smallest in 2016. Most of the total phosphorus loads for main-stem sites 5 and 22 were transported in March, April, and June, likely from snowmelt and early summer rains. The mean annual yields of total phosphorus for 2013–20 were largest on the main-stem site upstream from Lake Tschida (site 5) and Sweetbriar Creek (site 21), whereas the smallest yields were in Big Muddy Creek (site 18). Much of the phosphorus that enters Lake Tschida from the upper basin does not get transported downstream to the lower basin, and much of the phosphorus in the lower basin was attributed to intervening flow.

North Dakota↗
USGS1998

Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate (NO2+NO3-N) in ground water in the Idaho part of the upper Snake River basin

Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, cyanazine, metolachlor, and simazine. This study developed maps that the Idaho State Department of Agriculture might use to predict the probability of detecting atrazine and desethyl-atrazine (a breakdown product of atrazine) in ground water in the Idaho part of the upper Snake River Basin. These maps can be incorporated in the State Pesticide Management Plan and help provide a sound hydrogeologic basis for atrazine management in the study area. Maps showing the probability of detecting atrazine/desethyl-atrazine in ground water were developed as follows: (1) Ground-water monitoring data were overlaid with hydrogeologic and anthropogenic data using a geographic information system to produce a data set in which each well had corresponding data on atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Individual (univariate) relations between atrazine/desethyl-atrazine in ground water and atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth data were evaluated to identify those independent variables significantly related to atrazine/ desethyl-atrazine detections. (3) Several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected. (5) The multivariate models were entered into the geographic information system and the probability maps were constructed. Two models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected; one with and one without atrazine use. Correlations of the predicted probabilities of atrazine/desethyl-atrazine in ground water with the percent of actual detections were good; r-squared values were 0.91 and 0.96, respectively. Models were verified using a second set of groundwater quality data. Verification showed that wells with water containing atrazine/desethyl-atrazine had significantly higher probability ratings than wells with water containing no atrazine/desethylatrazine (p <0.002). Logistic regression also was used to develop a preliminary model to predict the probability of nitrite plus nitrate as nitrogen concentrations greater than background levels of 2 milligrams per liter. A direct comparison between the atrazine/ desethyl-atrazine and nitrite plus nitrate as nitrogen probability maps was possible because the same ground-water monitoring, hydrogeologic, and anthropogenic data were used to develop both maps. Land use, precipitation, soil hydrologic group, and well depth were significantly related with atrazine/desethyl-atrazine detections. Depth to water, land use, and soil drainage were signifi- cantly related with elevated nitrite plus nitrate as nitrogen concentrations. The differences between atrazine/desethyl-atrazine and nitrite plus nitrate as nitrogen relations were attributed to differences in chemical behavior of these compounds in the environment and possibly to differences in the extent of use and rates of their application.

Idaho↗
USGS1995

Organophosphorus and carbamate pesticides

Organophosphorus and carbamate pesticides are used throughout the world to control a large variety of insects and other invertebrates, fungi, birds, mammals, and herbaceous plants. Over 100 different organophosphorus and carbamate chemicals are registered in the U.S. alone for use in thousands of products applied to widely diverse habitats including agricultural crops, forests, rangelands, wetlands, towns, and cities. These applications are estimated to be nearly 200 million acre-treatments (i.e., number of acres treated corrected for number of treatments) per year to control nuisance, depradating, and disease-bearing invertebrates and vertebrates, and to maintain landscape aesthetics. Except for mosquito control, most applications target terrestrial habitat. Due to drift or run-off, pesticide and degrades are inevitably detected in soils and water that are fundamental to the primary productivity of ecosystems. Thus, critical life-giving systems are frequently contaminated with organophosphorus and carbamate pesticides, however briefly, each year.

Book chapter↗
USGS1979

Uranium transport in the Walker River Basin, California and Nevada

During the summer of 1976 waters from tributaries, rivers, springs and wells were sampled in the Walker River Basin. Snow and sediments from selected sites were also sampled. All samples were analyzed for uranium and other elements. The resulting data provide an understanding of the transport of uranium within a closed hydrologic basin as well as providing a basis for the design of geochemical reconnaissance studies for the Basin and Range Province of the Western United States. Spring and tributary data are useful in locating areas containing anomalous concentrations of uranium. However, agricultural practices obscure the presence of known uranium deposits and render impossible the detection of other known deposits. Uranium is extremely mobile in stream waters and does not appear to sorb or precipitate. Uranium has a long residence time (2500 years) in the open waters of Walker Lake; however, once it crosses the sediment-water interface, it is reduced to the U(IV) state and is lost from solution. Over the past two million years the amount of uranium transported to the terminal point of the Walker River system may have been on the order of 4 × 10 8 kg . This suggests that closed basin termini are sites for significant uranium accumulations and are, therefore, potential sites of uranium ore deposits.

Journal of Geochemical Exploration↗
USGS2005

Effects of iron on arsenic speciation and redox chemistry in acid mine water

Concern about arsenic is increasing throughout the world, including areas of the United States. Elevated levels of arsenic above current drinking-water regulations in ground and surface water can be the result of purely natural phenomena, but often are due to anthropogenic activities, such as mining and agriculture. The current study correlates arsenic speciation in acid mine drainage and mining-influenced water with the important water-chemistry properties Eh, pH, and iron(III) concentration. The results show that arsenic speciation is generally in equilibrium with iron chemistry in low pH AMD, which is often not the case in other natural-water matrices. High pH mine waters and groundwater do not always hold to the redox predictions as well as low pH AMD samples. The oxidation and precipitation of oxyhydroxides deplete iron from some systems, and also affect arsenite and arsenate concentrations through sorption processes. ?? 2004 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗
USGS2012

Modeling of land use and reservoir effects on nonpoint source pollution in a highly agricultural basin

Nonpoint source (NPS) pollution is tightly linked to land use activities that determine the sources and magnitudes of pollutant loadings to stream water. The pollutant loads may also be alleviated within reservoirs because of the physical interception resulting from changed hydrological regimes and other biochemical processes. It is important but challenging to assess the NPS pollution processes with human effects due to the measurement limitations. The objective of this study is to evaluate the effects of human activities such as land uses and reservoir operation on the hydrological and NPS pollution processes in a highly agricultural area-the Iowa River Basin-using the Soil and Water Assessment Tool (SWAT). The evaluation of model performance at multiple sites reveals that SWAT can consistently simulate the daily streamflow, and monthly/annual sediment and nutrient loads (nitrate nitrogen and mineral phosphorus) in the basin. We also used the calibrated model to estimate the trap efficiencies of sediment (~78%) and nutrients (~30%) in the Coralville Reservoir within the basin. These non-negligible effects emphasize the significance of incorporating the sediment and nutrient removal mechanisms into watershed system studies. The spatial quantification of the critical NPS pollution loads can help identify hot-spot areas that are likely locations for the best management practices.

Iowa↗