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Geohydrology and water quality of Marine Corps Logistics Base, Nebo and Yermo annexes, near Barstow, California

Because ground water is the only dependable source of water in the Barstow area, a thorough understanding of the relationship between the geology and hydrology of this area is needed to make informed ground-water management andremediation decisions. This report summarizes geologic and hydrologic studies done during 1992-95 at the Marine Corps Logistics Base, Nebo and Yermo Annexes, near Barstow, California. The geologic investigation dealt with the stratigraphy and geologic history of the area and determined the location of faults that cross the Marine Corps Logistics Base, Nebo Annex. Two of these faultscoincide with significant ground-water barriers. Geologic and hydrologic data collected for this study were used to define two main aquifer systems in this area. The Mojave River aquifer is contained within the sand and gravel of the Mojave River alluvium, and the regional aquifer lies in the bordering alluvial-fan deposits and older alluvium. Water-level data showed that recharge occurs exten sively in the Mojave River aquifer but occurs only in small areas of the regional aquifer. Dissolved- solids concentrations showed that ground-water degradation exists in the Mojave River aquifer near the Nebo Annex and extends at least 1 mile downgradient of the Nebo golf course in the younger Mojave River alluvium. Nitrogen concentrations show that more than one source is causing the observed degradation in the Mojave River aquifer. Oxygen-18, deuterium, tritium, andcarbon-14 data indicate that the Mojave River and regional aquifers have different sources of recharge and that recent recharge occurs in the Mojave River aquifer but is more limited in the regional aquifer.

Water-Resources Investigations Report↗

Variation in the relation of rainfall to runoff from residential lawns in Madison, Wisconsin, July and August 1995

The quality of runoff from residential lawns is a concern for municipal stormwater management programs. Land-use based computer models are increasingly being used to assess the impact of lawn runoff on urban watersheds. To accurately model the runoff for residential lawns, the variation in the relation of rainfall to runoff from lawns must be understood. The study described in this report measures the runoff parameters from 20 residential lawns in Madison, Wisconsin, using a rainfall simulator. It was determined that the saturated hydraulic conductivity does not vary significantly within a single residential lawn, but does vary significantly from one lawn to another. This variation is recognized in the entire rainfall-runoff relation from one lawn to another. The age of a lawn, or the years since development and turf establishment, is used as a surrogate of several lawn and soil characteristics to describe the variability in lawn runoff volumes. Runoff volumes from newly developed lawns are significantly greater than runoff from older lawns. This is an important consideration when modeling runoff for new developments. For older lawns, the date since lawn establishment does not explain the variation in the rainfall-runoff relation. In order for simple land-use based computer models to adequately account for the volume of runoff from pervious landscapes, field data from individual lawns would be necessary. A more realistic, alternative method may be to consider a basin-scale analysis of runoff from pervious landscapes.

Wisconsin↗

Hydrology and geochemistry of a surface coal mine in northwestern Colorado

The hydrology and geochemistry of a reclaimed coal mine in northwestern Colorado were monitored during water years 1988 and 1989. Some data also were collected in water years 1987 and 1990. This report describes (1) the sources of hydrologic recharge to and discharge from reclaimed spoil, (2) the relative contributions of recharge to the reclaimed spoil aquifer from identified source waters and the rate of water movement from those sources to the reclaimed spoil, and (3) the geochemical reactions that control water quality in reclaimed spoil. The study area was at a dip-slope coal mine encompassing about 7 square miles with land slopes of varying aspect. The area was instrumented and monitored at five sites; two sites had unmined and reclaimed- spoil areas adjacent to each other and three sites were unmined. The mined areas had been reclaimed. Instrumentation at the study sites included 1 climate station, 3 rain gages, 19 soil-water access tubes, 2 lysimeters, 18 wells completed in bedrock, 7 wells completed in reclaimed spoil, and 2 surface- water gaging stations. The results of the study indicate that the reclaimed spoil is recharged from surface recharge and underburden aquifers. Discharge, as measured by lysimeters, was about 3 inches per year and occurred during and after snowmelt. Hydraulic-head measurements indicated a potential for ground-water movement from deeper to shallower aquifers. Water levels rose in the reclaimed-spoil aquifer and spring discharge at the toe of the spoil slopes increased rapidly in response to snowmelt. Water chemistry, stable isotopes, geochemical models, and mass-balance calculations indicate that surface recharge and the underburden aquifers each contribute about 50 percent of the water to the reclaimed-spoil aquifers. Geochemical information indicates that pyrite oxidation and dissolution of carbonate and efflorescent sulfate minerals control the water chemistry of the reclaimed-spoil aquifer.

Water-Resources Investigations Report↗

Analysis of ambient conditions and simulation of hydrodynamics, constituent transport, and water-quality characteristics in Lake Maumelle, Arkansas, 1991-92

Lake Maumelle is the major drinking-water source for the Little Rock metropolitan area in central Arkansas. Urban and agricultural development has increased in the Lake Maumelle Basin and information is needed related to constituent transport and water quality response to changes in constituent loading or hydrologic regime. This report characterizes ambient conditions in Lake Maumelle and its major tributary, Maumelle River; describes the calibration and verification of a numerical model of hydrodynamics and water quality; and provides several simulations that describe constituent transport and water quality response to changes in constituent loading and hydrologic regime. Ambient hydrologic and water-quality conditions demonstrate the relatively undisturbed nature of Lake Maumelle and the Maumelle River. Nitrogen and phosphorus concentrations were low, one to two orders of magnitude lower than estimates of national background nutrient concentrations. Phosphorus and chlorophyll a concentrations in Lake Maumelle demonstrate its oligotrophic/mesotrophic condition. However, concentrations of chlorophyll a appeared to increase since 1990 within the upper and middle reaches of the reservoir. A two-dimensional, laterally averaged hydrodynamic and water-quality model developed and calibrated for Lake Maumelle simulates water level, currents, heat transport and temperature distribution, conservative material transport, and the transport and transformation of 11 chemical constituents. Simulations included the movement and dispersion of spills or releases in the reservoir during stratified and unstratified conditions, release of the fish nursery pond off the southern shore of Lake Maumelle, and algal responses to changes in external loading. The model was calibrated using 1991 data and verified using 1992 data. Simulated temperature and dissolved oxygen concentrations related well when compared to measured values. Simulated nutrient and algal biomass also related reasonably well when compared to measured values. A simulated spill of conservative material at the upper end of Lake Maumelle during a major storm event took less than 102 hours to disperse the entire length of the reservoir. Simulation of a nursery pond release into a tributary to Lake Maumelle demonstrated how the released water plunges within the receiving embayment and enters the main stem of the reservoir at mid depths. Simulations of algal response to increases of nitrogen and phosphorus loads demonstrate the phosphorus limiting condition in Lake Maumelle. Results from this study will provide water-resource management with information to better understand how changes in hydrology and water quality in the basin affects water quality in the reservoir. With this information, managers will be able to more effectively manage their drinking-water source supply.

Arkansas↗

Cost-effectiveness of the U.S. Geological Survey's stream-gaging programs in Massachusetts and Rhode Island

The report documents the results of a study of the cost-effectiveness of the U.S. Geological Survey 's continuous-record stream-gaging programs in Massachusetts and Rhode Island. Data uses and funding sources were identified for 91 gaging stations being operated in Massachusetts are being operated to provide data for two special purpose hydrologic studies, and they are planned to be discontinued at the conclusion of the studies. Cost-effectiveness analyses were performed on 63 continuous-record gaging stations in Massachusetts and 15 stations in Rhode Island, at budgets of $353,000 and $60,500, respectively. Current operations policies result in average standard errors per station of 12.3% in Massachusetts and 9.7% in Rhode Island. Minimum possible budgets to maintain the present numbers of gaging stations in the two States are estimated to be $340,000 and $59,000, with average errors per station of 12.8% and 10.0%, respectively. If the present budget levels were doubled, average standards errors per station would decrease to 8.1% and 4.2%, respectively. Further budget increases would not improve the standard errors significantly. (USGS)

Water-Resources Investigations Report↗

Variations in sand storage measured at monumented cross sections in the Colorado River between Glen Canyon Dam and Lava Falls Rapid, northern Arizona, 1992-99

Bed elevations were measured at 131 monumented cross sections in the Colorado River between Glen Canyon Dam and Lava Falls Rapid from June 1992 to September 1999 to provide data on channel sand storage. This report documents the location of the 131 monumented cross sections, dates of measurements for all cross sections, methods of data collection and processing, and spatial and temporal variation and variability in changes in cross-sectional area for selected cross sections. Additionally, data were analyzed to determine if changes in sediment storage could be related to main channel flow conditions and tributary sediment inputs. Most of the cross sections showed a limited capacity, both in terms of amount and residence time, to store sediment. Data for 83 of the 131 cross sections were comprehensive and complete, and were used for analyses in this report. This data set is referred to as the primary data set. Of these 83 cross sections, 19 had a net gain in stored sediment, 61 had a net loss of stored sediment, and 3 had no change in stored sediment for the period of data collection, excluding data collected during the high release from Glen Canyon Dam in 1996. A subset of the primary data set consisting of the sections downstream from the Paria and Little Colorado Rivers with measurements made on or nearly on the same day, referred to as the matching-date data set, was used to explore the effects of controlled flows and tributary flows on the changes in cross-sectional area. The matching-date data set consists of data from 57 cross sections. Of these 57 cross sections, 1 had a net gain in stored sediment, 55 had a net loss of stored sediment, and 1 had no change in stored sediment. Results of the analysis did not show that changes in cross-sectional area were strongly related to main channel flow conditions or tributary sediment inputs.

Water-Resources Investigations Report↗

Peak-flow characteristics of small urban drainages along the Wasatch Front, Utah

Designers and planners for local, State, and Federal agencies need up-to- date methods for determining peak-flow characteristics for urban drainages along the Wasatch Front, Utah. This report summarizes methods used to develop equations that estimate peak-flows for small urban drainages along the Wasatch Front. Mathematical equations were developed that estimate peak flows for recurrence intervals of 2, 5, 10, 25, 50 and 100 years, for small urban drainages. Data entry to the equations requires measurements of basin slope, size and percent impervious area. Rainfall and runoff data collected from eight urban drainages along the Wasatch Front from 1984-86, were used to calibrate a rainfall-runoff model called DR3M-II. Rainfall data collected from 1948-83 at the National Weather Service Salt Lake City Airport station provided additional long-term data to the calibrated models. Log Pearson fits made to the peak flow data were used to estimate the recurrence interval peaks for each basin. Paired stations on Little Cottonwood Creek near Salt Lake City were used to help determine the effects of intervening urban drainage on peaks of larger streams. In general, peaks on larger streams caused by snowmelt and peaks caused by rainfall (where urban areas may have a significant effect) did not occur simultaneously. (USGS)

Water-Resources Investigations Report↗

Methods and guidelines for effective model calibration; with application to UCODE, a computer code for universal inverse modeling, and MODFLOWP, a computer code for inverse modeling with MODFLOW

This report documents methods and guidelines for model calibration using inverse modeling. The inverse modeling and statistical methods discussed are broadly applicable, but are presented as implemented in the computer programs UCODE, a universal inverse code that can be used with any application model, and MODFLOWP, an inverse code limited to one application model. UCODE and MODFLOWP perform inverse modeling, posed as a parameter-estimation problem, by calculating parameter values that minimize a weighted least-squares objective function using nonlinear regression. Minimization is accomplished using a modified Gauss-Newton method, and prior, or direct, information on estimated parameters can be included in the regression. Inverse modeling in many fields is plagued by problems of instability and nonuniqueness, and obtaining useful results depends on (1) defining a tractable inverse problem using simplifications appropriate to the system under investigation and (2) wise use of statistics generated using calculated sensitivities and the match between observed and simulated values, and associated graphical analyses. Fourteen guidelines presented in this work suggest ways of constructing and calibrating models of complex systems such that the resulting model is as accurate and useful as possible.

Water-Resources Investigations Report↗

Evaluating evapotranspiration for grasslands on the Arid Lands Ecology Reserve, Benton County, and Turnbull National Wildlife Refuge, Spokane County, Washington, May 1990 to September 1991

The report evaluates evapotranspiration at four grassland sites in eastern Washington: the Snively Basin and grass lysimeter sites on the Arid Lands Ecology Reserve, and the meadow and marsh sites on the Turnbull National Wildlife Refuge. A combination of the Bowen-ratio and Penman-Monteith methods were used to estimate evapotranspiration at the sites from May 30, 1990 to September 30, 1991. The Bowen-ratio method could be used to estimate latent-heat flux during only parts of the study period. Latent heat-flux values during these periods were used in the Penman-Monteith method to estimate canopy resistance. The daily average resistance values were used to recalculate latent-heat-flux with the Penman-Monteith method for all periods. Evapotranspiration estimates made with the two methods agreed within 3 percent over the period of study. However, for the grass lysimeter site, evapotranspiration estimates made with the Bowen-ratio method were only 41 percent of those made with weighing lysimeters. A water budget from August 20, 1990 to September 30, 1991 at the Snively Basin site estimated that 101 percent of the precipitation was returned to the atmosphere as evapotranspiration. Sixteen percent of the evapotranspiration occurred from October to February, while 76 percent occurred from March to July. April accounted for over 25 percent of the evapotranspiration for the water budget period.

Washington↗

Evaluation of Water Quality for Two St. Johns River Tributaries Receiving Septic Tank Effluent, Duval County, Florida

Tributary streamflow to the St. Johns River in Duval County is thought to be affected by septic tank leachate from residential areas adjacent to these tributaries. Water managers and the city of Jacksonville have committed to infrastructure improvements as part of a management plan to address the impairment of tributary water quality. In order to provide data to evaluate the effects of future remedial activities in selected tributaries, major ion and nutrient concentrations, fecal coliform concentrations, detection of wastewater compounds, and tracking of bacterial sources were used to document septic tank influences on the water quality of selected tributaries. The tributaries Fishing Creek and South Big Fishweir Creek were selected because they drain subdivisions identified as high priority locations for septic tank phase-out projects: the Pernecia and Murray Hill B subdivisions, respectively. Population, housing (number of residences), and septic tank densities for the Murray Hill B subdivision are greater than those for the Pernecia subdivision. Water-quality samples collected in the study basins indicate influences from ground water and septic tanks. Estimated concentrations of total nitrogen ranged from 0.33 to 2.86 milligrams per liter (mg/L), and ranged from less than laboratory reporting limit (0.02 mg/L) to 0.64 mg/L for total phosphorus. Major ion concentrations met the State of Florida Class III surface-water standards; total nitrogen and total phosphorus concentrations exceeded the U.S. Environmental Protection Agency Ecoregion XII nutrient criteria for rivers and streams 49 and 96 percent of the time, respectively. Organic wastewater compounds detected at study sites were categorized as detergents, antioxidants and flame retardants, manufactured polycarbonate resins, industrial solvents, and mosquito repellent. The most commonly detected compound was para-nonylphenol, a breakdown product of detergent. Results of wastewater sampling give evidence that stream water in the study basins is affected by septic tank effluent. Fecal coliform bacteria concentrations were measured on a monthly basis; of 115 samples, 63 percent exceeded the State of Florida fecal coliform bacteria standard for Class III surface waters of 800 colonies per 100 milliliters of water on any 1 day. Fecal coliform bacteria concentrations ranged from less than 20 colonies per 100 milliliters of sample to greater than or equal to 160,000 colonies per 100 milliliters of sample. Antibiotic resistance patterns of fecal coliform bacteria were used to identify the sources of fecal coliform bacteria. Significant sources of fecal coliform bacteria included wild animals, dogs, and humans. A majority of the fecal coliform bacteria were classified to be from human sources. Because the primary source of fecal coliform bacteria is from human sources, and most likely septic tank effluent, management of human sources may substantially improve microbiological water quality in both the Fishing Creek and South Branch Big Fishweir Creek basins.

Water-Resources Investigations Report↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Owyhee and Vale Projects, Oregon and Idaho, 1990-91

A reconnaissance investigation was conducted during 1990--91 in the Owyhee and Vale projects in eastern Oregon and southwestern Idaho, as well as at a number of sites in the Snake River and tributaries to the Snake River in the area of study. The objective of the study was to determine if agricultural drainwater entering the study area was causing, or had the potential to cause, significant harmful effects to human health, fish and wildlife, or may adversely affect the suitability of water for beneficial uses. Approximately 153,000 acres of land are irrigated annually within the areas of the Owyhee and Vale projects. Large quantities of water are required because of the semiarid climate and relatively high evaporation rates. Several reservoirs in the area are filled annually during the wet, nonirrigation season to sustain irrigation during the dry summer months. During the irrigation season, this impounded water, along with direct diversions from the Malheur, Owyhee, and Snake Rivers, is transported to the irrigated areas through a series of diversion tunnels, siphons, canals, aqueducts, ditches, and drains. Major crops grown in the area include sugar beets, alfalfa hay and other hay crops, onions, and winter wheat. Minor crops include corn, potatoes, mint, various seed crops, and fruit. In 1987, it was estimated that the following amounts of pesticides were used in the project areas: 2,4-D (21,000 lbs [pounds]), chlorpyrifos (1,000 lbs), dacthal (40,000 lbs), dicamba (320 lbs), endosulfan (2,500 lbs), ethion (11,000 lbs), malathion (24,000 lbs), parathion (5,000 lbs), and phorate (11,000 lbs). Median concentrations and values for total dissolved solids, alkalinity, sodium adsorption ratio, and hardness in the Vale project area were greater than 1.5 times those values observed in the Owyhee project area or at other Snake River locations. During irrigation (August 1990), total dissolved solids, alkalinity, sodium adsorption ratio, and hardness values increased in a downstream manner. Constituent values at drainwater sites generally were comparable to concentrations below the irrigated ureas in the Owyhee and Vale project areas. The trace elements arsenic, boron, copper, molybdenum, vanadium, and zinc were detected in most water samples; cadmium, chromium, lead, and selenium were detected in some samples at concentrations generally near the analytical reporting limit; mercury was not detected in any samples. In some water samples, concentrations of arsenic, boron, cadmium, copper, and lead exceeded State or Federal water-quality standards or criteria. Most trace elements in bottom sediment were detected at concentrations within the expected 95-percent baseline range for soils from the Western United States. Concentrations that exceeded the 95-percent baseline range for study area soils were: (1) arsenic and lead in one sample from a site in the Vale project area; (2) mercury, lead, and tin in one sample from a site in the Snake River system; (3) manganese in two samples from two sites in the Snake River system; and (4) manganese from one sample from a site in the Vale project area. Fifteen pesticides and metabolites were detected in whole-water samples collected from sites in the study area. DDT, plus its metabolites (DDE and DDD), dieldrin, endrin, 2,4-D, dicamba, and dacthal were detected in samples collected from seven or more sites. Other pesticides detected included chlorpyrifos, endosulfan, ethion, malathion, parathion, phorate, and lindane. Most of the detected pesticide concentrations generally were largest in drainwater and at the most downstream sampling locations in the Owyhee and Vale project areas. Concentrations exceeded water-quality criteria established for the protection of freshwater aquatic life in 86 percent of the whole-water samples analyzed for DDT plus its metabolites, 71 percent of the dieldrin samples, 14 percent of the endrin samples, and 10 percent of the parathion samples. Eight pesticides and

Water-Resources Investigations Report↗

Automatic dilution gaging of rapidly varying flow

It is often difficult to obtain discharge ratings at urban gaging stations. This report presents the results of using an automated constant-rate dyedilution technique to measure discharge at two sites in Madison, Wisconsin. The sites selected have well-defined stage-discharge ratings, developed during previous hydrologic studies. One site has a 60-inch diameter concrete storm sewer and the other a concrete-lined open trapezoidal channel. Equipment selected to automate the method included a portable automatic water sampler, a four-channel event recorder, and a variable-speed peristaltic pump for dye injection. An electrical switching circuit was designed to coordinate the operation of this equipment. During the data-collection period of 1 year, a total of 20 storms were monitored. The analysis showed that the discharges measured by dye-dilution techniques were generally within ± 10 percent of the discharges determined from ratings established by current-meter measurements. Larger differences were noted at the start of and on the rising limb of four hydrographs. Of the 20 storms monitored, dilution measurements on 17 were of acceptable accuracy. Peak discharges from the open-channel site ranged from 0 to 12 percent departures from the existing rating whereas the comparison of peak discharge at the storm sewer site ranged from 0 to 5 percent departures from the existing rating.

Water-Resources Investigations Report↗

Occurrence and Distribution of Organochlorine Compounds in Biological Tissue and Bed Sediment From Streams in the Trinity River Basin, Texas, 1992-93

This report describes the occurrence and distribution of organochlorine compounds in biological tissue and bed sediment from the Trinity River Basin study area of the National Water-Quality Assessment Program. Concentrations of organochlorine pesticides, polychlorinated biphenyls (PCBs), and other organochlorine compounds were determined in biological tissue and surficial bed sediment from 16 stream sites in the Trinity River Basin of east-central Texas. Asiatic clams (Corbicula fluminea) were collected at 10 sites, and fish, including blue catfish (Ictalurus furcatus), common carp (Cyprinus carpio), bluegill (Lepomis cyanellus), and yellow bullhead (Ameiurus natalis) were collected at all mainstem and two tributary sites. Thirty of the 36 compounds analyzed in biological tissue or surficial bed sediment were detected in one or both media. Overall, more organochlorine compounds were detected in bed sediment than in biological tissue; however, various chlordane isomers, DDT metabolites, and PCBs were detected more frequently in tissue than in sediment. The chlordane isomers and PCBs that were detected more frequently in biological tissue also were detected more frequently at urban sites than at agricultural sites. Organochlorine compound concentrations generally were highest in fish tissue from Trinity River mainstem sites. Fish tissue from the mainstem sites contained a higher percentage of lipids than did fish- and clam-tissue samples from the tributary sites.

Water-Resources Investigations Report↗

Evaluation of Diazinon and Chlorpyrifos Concentrations and Loads, and other Pesticide Concentrations, at Selected Sites in the San Joaquin Valley, California, April to August, 2001

Twelve sites in the San Joaquin Valley of California were monitored weekly during the growing and irrigation season of 2001 for a total of 51 pesticides and pesticide degradation products, with primary interest on the concentration, load, and basin yield of organophosphorus insecticides, especially diazinon and chlorpyrifos. Diazinon was detected frequently, up to 100 percent of the time, at many of the sampling sites, but with generally low concentrations. For all sites, 75 percent of all measured diazinon concentrations were less than 0.02 mg/L, and 90 percent of all measured diazinon concentrations were less than 0.06 mg/L. The highest diazinon concentrations were measured in samples from two west-side tributaries to the San Joaquin River, Orestimba Creek, and Del Puerto Creek. The median concentration of chlorpyrifos was at or less than the laboratory reporting limit (0.005 mg/L) for most sites with the exceptions of two tributaries to the San Joaquin River: Orestimba Creek and the Tuolumne River. For all sites, 75 percent of all measured chlorpyrifos concentrations were less than 0.03 mg/L and 90 percent of all measured chlorpyrifos concentrations were less than 0.07 mg/L. The total load of diazinon out of the basin was just over 7 kilograms, which accounted for about 0.17 percent of the total agricultural applications. The diazinon load from the monitored upstream tributaries accounted for about 50 percent of the load at the mouth of the San Joaquin River. The streamflow from the selected monitored tributaries accounted for about 83 percent of the streamflow at the mouth of the San Joaquin River. The total load of chlorpyrifos out of the basin was 3.75 kilograms, and this accounted for approximately 0.007 percent of the total amount applied. Other pesticides that were frequently detected during this study included herbicides such as metolachlor, simazine, and trifluralin, and insecticides such as carbaryl, carbofuran, and propargite. At Orestimba Creek, DDE, a degradation product of DDT, was detected at a frequency of 95 percent.

Water-Resources Investigations Report↗

Hydrogeologic framework and preliminary simulation of ground-water flow in the Mimbres Basin, southwestern New Mexico

The bolson-fill aquifer, the major water-yielding unit in the Mimbres Basin, southwestern New Mexico, ranges in thickness from 0 to about 3,700 feet. Recharge to the bolson-fill aquifer occurs by infiltration of ephemeral streams that cross the basin margin, infiltration from precipitation and streamflow, ground-water underflow from adjacent basins, and infiltration of springflow from adjacent bedrock units within the basin. Ground water generally flows southward from the northern highland areas of the basin. Ground-water discharge consists of pumpage from wells, transpiration by plants, outflow to playas and springs in the Los Muertos Basin in Mexico, discharge to the Mimbres River, and ground-water flow to the Mesilla Basin near Mason Draw. Before 1910, ground-water recharge and discharge were approximately equal; by 1975, however, about 75 percent of the 146,000 acre-feet withdrawn annually was ground water, most of it from aquifer storage. The transmissivity of the bolson-fill aquifer determined from aquifer tests and specific-capacity data ranges from 10 to 50,000 feet squared per day. Hydraulic conductivity, calculated from saturated thickness and transmissivity, ranges from 0.03 to 800 feet per day, with median values of about 18 feet per day in the Deming area and 6 feet per day elsewhere. Reported storage-coefficient values representing confined parts of the aquifer range from 0.00036 to 0.0036, and those representing unconfined parts of the aquifer range from 0.02 to 0.24. Water quality in the north and central parts of the Mimbres Basin is suitable for most uses. Due to its large salinity and alkalinity, some of the ground water in the south and southeastern areas of the bolson-fill aquifer may not be suitable for irrigation or domestic use. A preliminary two-dimensional digital model was constructed to evaluate ground-water flow in the bolson-fill aquifer. The model was divided into zones of uniform hydraulic conductivity corresponding to the major structural elements of the basin. For simulation purposes, hydraulic conductivity in the central part of the basin ranged from 2.2 to 4.4 feet per day, whereas locally along the edges of the aquifer less certain values ranged from 0.003 to 62 feet per day Analysis of the results of this predevelopment model indicated that use of the mountain-front recharge method overestimates total recharge and that evapotranspiration is substantial. The simulated total inflow was about 55 percent of that estimated in a water budget for the Mimbres Basin. Ground-water development between 1930 and 1985 was simulated using storage-coefficient values of 0.01 and 0.02 for the Gila Conglomerate, 0.04 to 0.17 for bolson-fill deposits, and 0.001 for bolson fill capped with lacustrine clay. The simulated transient water budget indicated that most of the water pumped by 1985 came from storage, and lesser but substantial amounts came from reductions in evapotranspiration.

New Mexico↗

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Ground-water quality in the Rio Grande flood plain, Cochiti Lake, New Mexico, to El Paso, Texas, 1995

From March to May of 1995, water samples were collected from 30 wells located in the flood plain of the Rio Grande between Cochiti Lake, New Mexico, and El Paso, Texas. These samples were analyzed for a broad host of constituents, including field parameters, major constituents, nutrients, dissolved organic carbon, trace elements, radiochemicals, pesticides, and volatile organic compounds. The main purpose of this study was to observe the quality of ground water in this part of the Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment program. The sampling effort was limited to the basin- fill aquifer beneath the above-defined reach of the Rio Grande flood plain because of the relative homogeneity of the hydrogeology, the large amount of ground-water use for public supply, and the potential for land-use activities to affect the quality of ground water. Most of the wells sampled for the study are used for domestic purposes, including drinking water. Depths to the tops of the sampling intervals in the 30 wells ranged from 10 to 345 feet below land surface, and the median was 161.5 feet; the sampling intervals in most of the wells spanned about 10 feet or less. Quality-control data were collected at three of the wells. A significant amount of variation was found in the chemical composition of ground water sampled throughout the study area, but the water generally was found to be of suitable chemical quality for use as drinking water, according to current enforceable standards established by the U.S. Environmental Protection Agency (EPA). Nutrients generally were measured at concentrations near or below their method reporting limits. The most dominant nutrient species was nitrite plus nitrate, at a maximum concentration of 1.9 milligrams per liter (as N). Only eight of the trace elements analyzed for had median concentrations greater than their respective minimum reporting levels. Water from one well exceeded the lifetime health advisory established by the EPA for molybdenum; water from a different well exceeded the proposed EPA maximum contaminant level for uranium. Gross alpha and gross beta particle activities generally appeared to strongly correlate with quantities of uranium and potassium, respectively, detected in ground water. However, water from one well exceeded the EPA maximum contaminant level for gross alpha particle activity and may exceed the EPA maximum contaminant level for beta particle and photon activity, although current data on gross beta particle activities are not conclusive on this point. Radon concentrations did not appear to directly correlate with uranium concentrations. The herbicide prometon was the only synthetic organic compound detected in ground water in the study area, and was detected in only one well, at a concentration of 0.038 microgram per liter. This well is shallow and is not used for drinking water. With the exception of the one detection of prometon, no strong evidence was found of effects on ground-water quality from human activities. Therefore, most of the water sampled probably recharged at the margins of the alluvial basins or recharged through the flood plain before human development began. With respect to major constituents, the concentrations of dissolved solids ranged from 209 to 3,380 milligrams per liter, and the median concentration was 409.5 milligrams per liter. There is evidence that the overall chemical composition of ground water in the study area may be affected by several processes, including cation exchange, feldspar weathering, calcite dissolution and precipitation, dissolution of volcanic glass, and microbial activity. Several chemical constituents in ground water showed relatively distinct spatial patterns that appear to be related to one or more of these processes.

Texas↗

Estimating hydraulic properties of the Floridan Aquifer System by analysis of earth-tide, ocean-tide, and barometric effects, Collier and Hendry Counties, Florida

Aquifers are subjected to mechanical stresses from natural, non-anthropogenic, processes such as pressure loading or mechanical forcing of the aquifer by ocean tides, earth tides, and pressure fluctuations in the atmosphere. The resulting head fluctuations are evident even in deep confined aquifers. The present study was conducted for the purpose of reviewing the research that has been done on the use of these phenomena for estimating the values of aquifer properties, and determining which of the analytical techniques might be useful for estimating hydraulic properties in the dissolved-carbonate hydrologic environment of southern Florida. Fifteen techniques are discussed in this report, of which four were applied. An analytical solution for head oscillations in a well near enough to the ocean to be influenced by ocean tides was applied to data from monitor zones in a well near Naples, Florida. The solution assumes a completely non-leaky confining unit of infinite extent. Resulting values of transmissivity are in general agreement with the results of aquifer performance tests performed by the South Florida Water Management District. There seems to be an inconsistency between results of the amplitude ratio analysis and independent estimates of loading efficiency. A more general analytical solution that takes leakage through the confining layer into account yielded estimates that were lower than those obtained using the non-leaky method, and closer to the South Florida Water Management District estimates. A numerical model with a cross-sectional grid design was applied to explore additional aspects of the problem. A relation between specific storage and the head oscillation observed in a well provided estimates of specific storage that were considered reasonable. Porosity estimates based on the specific storage estimates were consistent with values obtained from measurements on core samples. Methods are described for determining aquifer diffusivity by comparing the time-varying drawdown in an open well with periodic pressure-head oscillations in the aquifer, but the applicability of such methods might be limited in studies of the Floridan aquifer system.

Florida↗

Assessment of ground-water vulnerability to atrazine leaching in Kent County, Michigan; review, comparison of results of other studies and verification

Model assumptions and parameters used in an earlier study of the vulnerability of ground water in Kent County, Michigan, to atrazine contamination were reviewed and compared with other studies. The review indicated that model assumptions are consistent with those used in other models and that the parameters assigned in the Kent County model are within the broad range commonly found in the literature. Model assumptions most likely to limit the accuracy of the previous study include those of uniform transport and steady-state flow. Simulation results are more sensitive to parameter estimates for atrazine half life, organic-carbon content, and organic-carbon partition coefficient than to other model parameters. Potential atrazine detection probabilities and concentrations of atrazine reported in the previous Kent County Study were compared with data from other studies. Detection probabilities of 14 measurements of atrazine concentrations in ground water from shallow wells in the southern Lower Peninsula of Michigan were compared with detection probabilities based on potential atrazine concentrations computed for Kent County. Results indicate that the distribution of detection probabilities based on measured concentrations is similar to that based on adjusted potential concentrations. Potential concentrations were adjusted for effects of differences between sampling and modeling depths and for differences between the uniform application rate used for potential concentrations and the percentage of Kent County that is likely to be treated with atrazine. Potential concentrations of atrazine in the Kent County Study were within the wide range of concentrations measured in other states. A stratified random sampling strategy was developed to verify expected atrazine concentrations in ground water within Kent County. The strategy helps identify strata, determine the optimum allocation of ground-water samples within defined strata, and project the sampling error. Implementation of the strategy was illustrated by use of potential atrazine concentrations computed in the previous Kent County Study. Once detailed information on historical application rates of atrazine is developed, expected atrazine concentrations can be computed by use of the vulnerability model and used to implement the sampling strategy. Sampling results may be used to verify the effectiveness of the vulnerability model and local estimates of historical atrazine application rates by use of analysis of variance.

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