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Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis

Tectonic controls on volcanism and associated hydrothermal activity in a sediment-dominated mid-ocean ridge; Escanaba Trough

Mid-ocean ridges, the Earth's most extensive volcanic system, exhibit unique characteristics in sediment-dominant environments. Thick sediment cover insulates the crust and channels fluid along pathways that can lead to the formation of distinct crustal alteration patterns, exceptionally large mineral deposits, and specialized chemosynthetic ecosystems. This study presents an interdisciplinary investigation into the tectonics of the Escanaba Trough, a heavily sedimented axial valley at the southern Gorda Ridge in the Northeast Pacific Ocean. A primary challenge in such environments is overcoming the masking effect of thick sediments on basement structures that control magmatic and hydrothermal activity. We address this by employing three-dimensional (3D) magnetic modeling of high-resolution near-seafloor magnetic data collected by an autonomous underwater vehicle (AUV). The 2022 surveys with AUV Sentry provided data for 3D magnetic susceptibility models, refining our understanding of the geometry of sub-sediment laccoliths/saucer-shaped sills and hydrothermal alteration. In conjunction with a new 1:100,000 scale lithostratigraphic map, we outline the tectonic controls on the emplacement of Escanaba Trough's three main volcanic centers, characterize the geometry of its spreading segments, and provide volumetric data on the distribution of sub-sediment volcanism in the southern Gorda Ridge.

Escanaba Trough, Pacific Ocean

Mesoproterozoic to Paleozoic tectonics, Pleistocene landforms, and Holocene seismicity in the Blue Ridge: Results from integrated studies of the 9 August 2020, Mw 5.1 earthquake area near Sparta, North Carolina, USA

This field trip examines the results of integrated geologic studies of the 9 August 2020, M w 5.1 earthquake near Sparta, North Carolina, USA. The earthquake generated ~4 km of coseismic surface rupture of the Little River fault and uplifted a surface area of ~11 km 2 . The Little River fault is a thrust fault oriented 110–130°/45–70°SW, and mapped fault segments are en echelon with scarp heights from <5–30 cm. The epicenter is in polydeformed rocks of the Ashe and Alligator Back Metamorphic Suites in the eastern Blue Ridge. Bedrock structure formed during multiple Paleozoic orogenies; the regional foliation strikes NE-SW and dips SE (mean orientation 063°/52°SE). Mapping identified late Paleozoic veins and shear zones, a regional joint set striking 330–340° and 250–240°, and brittle faults that cut the Paleozoic foliation. Brittle faults oriented similar to the Little River fault are mapped up to 4 km along strike from the coseismic rupture along Bledsoe Creek valley, and the combined length of the Little River fault system is ~8 km. Paleoseismic trenches across the Little River fault corroborate the reactivation of an older fault by the 2020 earthquake and reveal two events during late Pleistocene (<50 ka). Surficial mapping identified several terrace deposits, including a deposit along Bledsoe Creek that yielded a 26 Al/ 10 Be isochron burial age of 0.46 ± 0.13 Ma and overlies a brittle fault, thus constraining the timing of movement of the fault at that location. Paleoliquefaction studies document soft-sediment deformation features in alluvium that may represent paleoseismic events. Collectively, these results highlight long-lived paleoseismicity of the Blue Ridge and that the 9 August 2020 earthquake reactivated an older, suitably oriented brittle fault in the bedrock. The Little River fault is an example of a previously unknown but active fault lying outside of known seismic zones with demonstrated recurrence of paleo-ruptures, raising questions about the assumption that damaging earthquakes are limited to areas of ongoing background seismicity, which is counter to seismic hazard assessments in the eastern United States. Bedrock mapping separates eastern Blue Ridge lithostratigraphy of the Lynchburg Group and Ashe and Alligator Back Metamorphic Suites into separate fault-bound packages juxtaposed over various 1.3–1.0 Ga basement rocks of the northern French Broad massif by the Gossan Lead fault.

North Carolina

Estimation of the accessible and useful resource base for electric-grade enhanced geothermal systems (EGS) resources of the Great Basin, USA

Scientists with the U.S. Geological Survey (USGS) recently completed a provisional assessment of the electric-grade geothermal resources associated with the low-permeability geologic formations of the Great Basin, USA, where resources are assumed to be accessible using enhanced geothermal systems (EGS) technologies (i.e., the engineering of sufficient permeability to facilitate efficient heat extraction). This assessment required estimation of the accessible resource base (electric-grade heat [>90ºC] at depths where drilling and stimulation are deemed achievable using current technology) and useful resource (heat that can be extracted from the accessible region). Electric-grade heat can be estimated from existing temperature models. The accessible resource base can be estimated as the electric-grade heat that exists at depths shallower than 6 km based on the limitations of current drilling and stimulation technologies, along with evidence for sustained natural fracture conductivity at depth. The useful part of the accessible heat can be estimated as the product of three efficiencies and factors: the heat extraction efficiency, the viable geology factor, and the reservoir spacing efficiency. The accessible and useful parts of the resource can be estimated in units of heat, or in units of electric power using an electrical conversion efficiency, which is a function of resource temperature. We also estimate the ranges for each of the efficiencies and describe the motivations behind the choice of best estimates used for the recent assessment. An analytic solution is provided for the useful resource above any depth (in units of electric power), where efficiency estimation assumes nearly steady heat extraction rates that cool reservoirs to 90ºC over 30 years of power generation.

Great Basin

Shallow storage of the explosive Earthquake Flat Pyroclastics magma body, Okataina Volcanic Center, Taupo Volcanic Zone, New Zealand: Evidence from phase-equilibria experiments

Rhyolitic tuffs range widely in their crystal contents from nearly aphyric to crystal-rich, and their crystal cargoes inform concepts of upper crustal magma reservoirs. The Earthquake Flat pyroclastics (Okataina Volcanic Center, Taupo Volcanic Zone, New Zealand) are 10 km 3 of rhyolitic tuffs with abundant (~ 40 vol.%) plagioclase and quartz, minor biotite, hornblende, and orthopyroxene, and accessory Fe-Ti oxides, apatite, and zircon, set in high-silica rhyolitic glass. Major minerals form large, euhedral phenocrysts and abundant glomerocrysts with few disequilibrium textures excepting some faintly resorbed quartz. Plagioclase phenocrysts have thick rims of nearly constant composition near An 30 , and hornblende is weakly zoned or unzoned. The abundant and texturally complex mineral assemblage contrasts with the nearby (~ 25 km), nearly synchronous, but more voluminous and crystal-moderate rhyolite tuffs from Rotoiti caldera. New H 2 O-saturated phase-equilibria results on the erupted Earthquake Flat melt (glass) determine its co-saturation with the partial phenocryst assemblage of plagioclase, quartz, biotite, and Fe-Ti oxides at: 140 MPa, 755 ºC. These closely approximate the conditions of the pre-eruptive magma body assuming it was saturated with nearly pure H 2 O and at an f O 2 of ~ Ni–NiO. Absence of hornblende and orthopyroxene from the synthesized assemblages may result from those minerals being in a peritectic reaction relation with melt to produce biotite, so they would not grow from the liquid used as starting material. Experimental results on Rotoiti rhyolite (Nicholls et al. 1992) show that the two bodies resided at similar pressures, temperatures, and f O 2 s. Lower crystal abundance of the Rotoiti tuffs may result from slight compositional differences. We interpret that the Earthquake Flat pyroclastics were sourced from the crystal-rich periphery of a mushy reservoir system with the Rotoiti occupying a more melt-rich central location. Uncertain is whether this was a single intrusion zoned continuously in crystallinity, or discrete adjacent intrusions, but our results illustrate and quantify complexities of magma storage across relatively short distances.

North Island, Taupo Volcanic Zone

Avak Creek oil occurrence, North Slope, Alaska: Newly discovered oil seep on Native lands, near village of Utqiagvik

An unknown occurrence of oil was detected near Avak Creek on Native lands on the North Slope of Alaska. Determining the source of oil was imperative for allowing stakeholders (Federal, State, and local government agencies and the landowner, an Alaska Native corporation) to make timely and informed decisions and mount a mitigation response, if required. The regional and local geological framework of the Avak Creek site was constructed using seismic surveys, well data, and basin modeling results, to identify local petroleum systems, map structural geometry and faults, define source rock thermal maturity distributions, and infer likely oil-migration pathways. Molecular hydrocarbon fingerprints (biomarkers, diamondoids, compound-specific isotopes) of the oil were compared to those of local and regional oil seeps, exploration well tests, and produced oils. Biomarker acid distributions characterized the history and extent of petroleum biodegradation. Integrating subsurface and geochemical parameters, the oil is interpreted to be a natural seep generated locally, predominantly from the Brookian Lower Cretaceous Hue Shale/gamma-ray zone, rather than an anthropogenic source of pollution. Results highlight sophisticated analytical technologies used to characterize complex, compositionally altered hydrocarbons. Results also advance our understanding of Brookian source rock distribution, subsurface petroleum migration pathways, and Arctic Alaska petroleum systems.

Alaska

Predictive regressive models of recent marsh sediment thickness improve the quantification of coastal marsh sediment budgets

Coastal marsh wetlands experience variations in vertical gains and losses through time, which have allowed them to infill relict topography and record variations in drivers. The stratigraphic unit associated with the development of the marsh also reflects the long-term importance of key ecosystem services supplied by the marsh environment, including carbon storage and storm mitigation. Mapping these coastal wetland sediments and the marsh unit thickness is challenging as traditional coastal geophysical tools are not easily deployable (acoustic methods) or are unreliable in saline-soil environments (e.g., ground-penetrating radar), leaving core-based methods the most viable mapping method. In the present study, we utilized prior information on the geologic architecture of the region to select spatial and physical metrics that likely persisted throughout evolution of the marsh during the late Holocene. We then assessed the individual and collective power of these metrics to predict marsh thickness observed from cores. Employing regressive predictive models powered by these data, we improve the quantification of marsh thickness for a coastal fringing marsh within the Grand Bay estuary in Mississippi and Alabama (USA). The information gained from this approach yields improved estimates of the carbon stocks in this environment. Additionally, the stored sediment masses reflect the past, and potential future, persistence of the Grand Bay marsh under historical and present marsh-estuarine sediment exchange fluxes. Such improvements to both the sediment budget of recent marsh stratigraphic units and the spatial extent provide new resources for comparison with large-scale landscape models, the latter of which may be used, when validated, to predict future change and ecosystem transformations.

Alabama. Mississippi

Recycling radiogenic osmium by crustal foundering in subduction zones: Evidence from pyroxenite xenoliths in the north Andean arc

Removal of mafic-ultramafic lower crust (e.g., via delamination) is fundamental to making andesitic continental crust, yet direct evidence of this process remains elusive. A unique suite of garnet clinopyroxenite and hornblendite (arclogite) xenoliths from the northern volcanic zone of the Andes, erupted to the surface in the mid-Pleistocene, have bulk-rock geochemistry and osmium (Os) isotopic compositions that demonstrate their crustal affinity, yet have equilibration pressures and temperatures below the arc Mohorovičić discontinuity (~53 km) and some as deep as within the sub-arc mantle wedge (~105 km). Garnet websterites from the same xenolith suite, sourced from depths approaching the Wadati-Benioff zone (~140 km), have elemental and isotopic compositions indicative of a mantle origin, likely formed as products of peridotite-liquid reactions above the subducting slab. Variability in bulk-rock 143 Nd/ 144 Nd values and garnet oxygen isotope ratios ( 𝛿 18 O) for these samples is attributed to minor assimilation of subducted components and/or older crustal material, but assimilation alone cannot account for the highly radiogenic Os isotopic compositions. These results provide direct petrologic evidence for modern arclogite formation and foundering in the Andean orogen, the archetypal active continental subduction system. Elevated 187 Os/ 188 Os values of Mercaderes arclogites imply that recycling of gravitationally unstable arc cumulates during continental crust formation introduces highly radiogenic Os into the convective mantle, which has implications for mass fluxes across the crust-mantle boundary as well as the sources and evolution of mantle heterogeneity as seen in orogenic peridotite massifs and in the sources of oceanic basalts

Earth and Planetary Science Letters

Constraining source and path effects of large magnitude earthquakes using ground motion simulations

The purpose of this study is to use ground‐motion simulations to investigate ways in which source and path effects for large‐magnitude earthquakes can be represented in nonergodic ground‐motion models (GMMs). To achieve this, we designed a ground‐motion study in the San Francisco Bay Area that includes earthquakes with a broad range of magnitudes distributed uniformly on a fault plane, and sites covering a large range of rupture distances and azimuths. After running a large suite of kinematic simulations (magnitude 4–7), we then develop a nonergodic GMM with the simulated data. We find that trends in the within‐site residuals are affected significantly by the earthquake radiation pattern, rupture directivity, and slip patterns. Next, we modify an existing rupture directivity model to fit and remove the observed radiation pattern and rupture directivity from the residuals. We also minimize the contributions of slip patterns by averaging the within‐site residuals among multiple source realizations. Finally, after removing the source effects from the within‐site residuals, we compare the path effects computed with different magnitude groups using two approaches. The first approach only considers the small events that have the same shortest path to a site as the large events, whereas the second approach considers all small events on the fault plane. The results indicate that it is difficult to satisfactorily approximate the path effects of large events with those of small events using either approach, at least in the case of simulations.

California

Extending the Boore and Abrahamson (2023) modified square-root-impedance method for the development of site amplifications consistent with the full-resonance approach to a range of VS30 values

The square-root-impedance (SRI) method is commonly used to approximate the seismic site amplifications computed using the full-resonance (FR) method for gradient shear-wave velocity ( V S ) profiles that are smoothly varying with depth. The SRI site amplifications have been observed to systematically underpredict the FR site amplifications by a ratio of FR/SRI amplifications around 1.05 to 1.3 across a wide frequency range (Boore, 2013). Recently, Boore and Abrahamson (2023; hereafter, BA23) related this difference in the SRI and FR methods to differences in the exponent η of the ratio of seismic impedances between the two methods. They proposed the implementation of a modified frequency-dependent η in the SRI method to improve its match to the FR site amplifications. This modified η was derived using only five V S profiles. We investigate the performance of the BA23 η for a wide range of realistic gradient V S profiles with V S30 ranging from 180 to 1500 m/s. These gradient V S profiles are constructed using two power-law functions of depth and are constrained by the assigned VS30 value, the depth and velocity of the half-space, and depths to shear-wave velocity horizons of 1.0 and 2.5 km/s ( Z 1.0 and Z 2.5 ) based on western United States sites. Despite observing a V S30 dependence of η, we find that the BA23 η generally works reasonably well for the range of V S profiles analyzed. Using the VS30 -dependent η derived in this study results in improvements in matching the FR site amplification compared to using the BA23 η. These improvements are more pronounced for the soft-site conditions and become modest to negligible for the stiff site conditions

Bulletin of the Seismological Society of America

Mitigating climate change by abating coal mine methane: A critical review of status and opportunities

Methane has a short atmospheric lifetime compared to carbon dioxide (CO 2 ), ∼decade versus ∼centuries, but it has a much higher global warming potential (GWP), highlighting how reducing methane emissions can slow the rate of climate change. When considering the contribution of greenhouse gas (GHG) emissions to current global warming (2010–2019) relative to the industrial revolution (1850–1900) levels, methane contributes 0.5 °C or ∼ a third of the total. The most recent post-2023 global estimates of methane emissions by bottom-up (BU) and top-down (TD) approaches for the coal mining sector are in the range of ∼41 ± 3 Tg yr −1 and 33 ± 5 Tg yr −1 , respectively. This divergence, notwithstanding overlapping confidence intervals, is a result of differences between applied TD global inversion models and BU emission inventories. Further research can help to better refine emissions from the various contributing coal mine methane (CMM) emissions sources. The coal mining sector accounts for over 10 % of global anthropogenic methane emissions. The contribution of CMM emissions to the global budget have increased since 2000, although upward and downward regional trends have been observed.

International Journal of Coal Geology

Permafrost–wildfire interactions: active layer thickness estimates for paired burned and unburned sites in northern high latitudes

As the northern high-latitude permafrost zone experiences accelerated warming, permafrost has become vulnerable to widespread thaw. Simultaneously, wildfire activity across northern boreal forest and Arctic/subarctic tundra regions impacts permafrost stability through the combustion of insulating organic matter, vegetation, and post-fire changes in albedo. Efforts to synthesis the impacts of wildfire on permafrost are limited and are typically reliant on antecedent pre-fire conditions. To address this, we created the FireALT dataset by soliciting data contributions that included thaw depth measurements, site conditions, and fire event details with paired measurements at environmentally comparable burned and unburned sites. The solicitation resulted in 52 466 thaw depth measurements from 18 contributors across North America and Russia. Because thaw depths were taken at various times throughout the thawing season, we also estimated end-of-season active layer thickness (ALT) for each measurement using a modified version of the Stefan equation. Here, we describe our methods for collecting and quality-checking the data, estimating ALT, the data structure, strengths and limitations, and future research opportunities. The final dataset includes 48 669 ALT estimates with 32 attributes across 9446 plots and 157 burned–unburned pairs spanning Canada, Russia, and the United States. The data span fire events from 1900 to 2022 with measurements collected from 2001 to 2023. The time since fire ranges from 0 to 114 years. The FireALT dataset addresses a key challenge: the ability to assess impacts of wildfire on ALT when measurements are taken at various times throughout the thaw season depending on the time of field campaigns (typically June through August) by estimating ALT at the end-of-season maximum. This dataset can be used to address understudied research areas, particularly algorithm development, calibration, and validation for evolving process-based models as well as extrapolating across space and time, which could elucidate permafrost–wildfire interactions under accelerated warming across the high-northern-latitude permafrost zone. The FireALT dataset is available through the Arctic Data Center ( https://doi.org/10.18739/A2RN3092P , Talucci et al., 2024).

Arctic

Preliminary field report of landslide hazards following Hurricane Helene

Executive Summary This report reflects our knowledge regarding the widespread landslide activity associated with Hurricane Helene observed during the U.S. Geological Survey’s (USGS) mission assignment to North Carolina in October 2024. The material in this report was originally prepared for the Federal Emergency Management Agency under mission assignment DR-4827-NC. The data and commentary in this report are reflective of a report provided to the Federal Emergency Management Agency (FEMA) on October 18, 2024, as well as information provided in briefings at the Buncombe County Emergency Operations Center. The report has been modified for public dissemination. This assessment was based on systematic visual examination and mapping of landslide locations from aerial and satellite imagery, visual and photographic observations from low-level helicopter overflights and conversations with local landslide experts from the North Carolina Geological Survey and Appalachian Landslide Consultants PLLC, and more than 50 years of combined landslide hazard professional experience of the mission-assigned field team. No systematic field investigations were done by the USGS. While responding to the event, the USGS did not identify any landslides that posed an immediate major threat to recovery personnel in parts of nine counties in North Carolina (Avery, Buncombe, Henderson, McDowell, Mitchell, Polk, Rutherford, Watauga, and Yancey); however, threats from renewed landslide activity may remain heightened in localized areas for months or even years. Known areas of the most abundant landslide occurrence include Bat Cave, Lake Lure, Chimney Rock, Swannanoa, Black Mountain, Fairview, steep areas in Asheville, and the Blue Ridge Parkway. The USGS shared detailed locations of known landslides with the Emergency Operations Centers. The thousands of landslide scars on hillsides and landslide deposits on flatter ground may present some threat to recovery activities. Soil and rocks will continue to erode from newly exposed landslide scars and may pose a threat to people and infrastructure who are immediately nearby. In general, the steeper and taller the landslide scar, the greater the potential threat. This threat is heightened during periods of rainfall and increases with the duration and intensity of rainstorms. Very heavy rainfall, or repeated rainfall events during short periods, could also initiate new landslides on steep slopes. Excavation of landslide deposits, particularly excavation of those deposits directly adjacent to steep slopes, may also pose a threat to nearby people and equipment. An interagency collaborative mapping effort led by the USGS that informed this assessment identified 1,155 landslide locations by the October 2024 briefings, but that number increased to 2,217 in a final reviewed version of the locations published in January 2025. Locations were mapped from satellite imagery, fixed-wing and helicopter surveys, media and social media, and field reports in the 3 weeks following the passage of the remnants of Hurricane Helene. USGS products outlined in this report are publicly available and include geotagged photographs from aerial reconnaissance, hazard models, an interactive view of mapped landslide locations, and landslide safety and education resources.

North Carolina, South Carolina, Tennessee, Virgini

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California

A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan

Sensitivity of Alabama freshwater gastropod species to nickel exposure

Snails are effective bioindicators due to their prolific distribution, high level of endemism, and capacity to accumulate contaminants. Freshwater snails have unique ecological niches which are imperiled by land‐use change and the introduction of hazardous chemicals. To assess how environmental alterations affect gastropods, lab‐based studies are needed to characterize the toxicity of specific stressors. This can help guide policy decisions and remediation efforts. The aim of this research was to characterize acute toxicity of nickel (Ni) on endemic snails ( Somatogyrus georgianus [Walker, 1904], Elimia cahawbensis [Lea, 1861], and Elimia spp.) and measure the accumulation of Ni and mineral elements including calcium (Ca), magnesium, potassium, and sodium (Na). Snails were exposed to six concentrations (25–800 µg/L) of Ni for 96 h. Among the studied snail species, E. cahawbensis was the most sensitive to Ni, with the lowest lethal concentration where 50% of the organisms died (LC50) at 88.88 µg/L Ni after 96 h. The LC50 at 96 h for S. georgianus was 167.78 µg/L Ni, and 393.13 μg/L Ni for Elimia spp. Except for Elimia spp., mortality of the other two snail species corresponded to the whole‐body uptake of Ni. Nickel exposure also influenced Ca and Na uptake for Elimia spp. All three endemic species are potential candidate species for evaluating localized effects of human activities, and the present study provides a first step in characterizing how snails would be affected by environmental alterations. More research could further characterize potential effects of other human stressors on these endemic snail species. Future research into subindividual responses and routes of exposure can further elucidate variations in species sensitivity.

Alabama

Nanometer-scale relationships between sedimentary organic matter molecular composition, fluorescence, cathodoluminescence, and reflectance: The importance of oxygen content at low thermal maturities

Molecular characterization of sedimentary organic matter (SOM), termed macerals, is a common goal when seeking to understand petroleum generation as well as other geologic processes in deep time. However, unambiguous measurement of discrete macerals is challenging due to the small size of organic particles in sedimentary rocks, the proximity of different organic matter types to one another, mineral-organic matter interactions, and maceral mixing that occurs during SOM isolation prior to ex situ analysis. The recent advent of infrared spectrometers capable of nanometer-scale resolution and the application of these technologies to geologic samples has enabled advances in rapid, in situ molecular characterization of SOM allowing for insights into paleoenvironmental processes, such as organic matter productivity and preservation, among others. Here we employ one such technology, optical photothermal infrared (OPTIR) spectroscopy, to map SOM functional group distributions at 500-nm resolution in a sample from the Lower Cretaceous Sunniland Limestone of the South Florida Basin. Examined fields of view include occurrences of amorphous organic matter (AOM), inertinite, micrinite, solid bitumen, telalginite, and vitrinite. OPTIR data from these macerals are compared against traditional organic petrographic data from the same organic grains including fluorescence intensity and white light reflectance as well as against cathodoluminescence response, an emerging organic petrographic approach. Maceral oxygen content (using carbonyl functional group abundance as a proxy) is observed to vary widely between maceral types but correlates strongly with fluorescence and cathodoluminescence intensity as well as against reflectance. These findings highlight the important role that oxygen content plays in determining the optical properties of SOM and further demonstrate the ability of OPTIR to discriminate subtle molecular differences between SOM types.

Organic Geochemistry

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper