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Optical maturity variation in lunar spectra as measured by Moon Mineralogy Mapper data

High spectral and spatial resolution data from the Moon Mineralogy Mapper (M3) instrument on Chandrayaan-1 are used to investigate in detail changes in the optical properties of lunar materials accompanying space weathering. Three spectral parameters were developed and used to quantify spectral effects commonly thought to be associated with increasing optical maturity: an increase in spectral slope ("reddening"), a decrease in albedo ("darkening"), and loss of spectral contrast (decrease in absorption band depth). Small regions of study were defined that sample the ejecta deposits of small fresh craters that contain relatively crystalline (immature) material that grade into local background (mature) soils. Selected craters are small enough that they can be assumed to be of constant composition and thus are useful for evaluating trends in optical maturity. Color composites were also used to identify the most immature material in a region and show that maturity trends can also be identified using regional soil trends. The high resolution M3 data are well suited to quantifying the spectral changes that accompany space weathering and are able to capture subtle spectral variations in maturity trends. However, the spectral changes that occur as a function of maturity were observed to be dependent on local composition. Given the complexity of space weathering processes, this was not unexpected but poses challenges for absolute measures of optical maturity across diverse lunar terrains. Copyright 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Wetland losses related to fault movement and hydrocarbon production, southeastern Texas coast

Time series analyses of surface fault activity and nearby hydrocarbon production from the southeastern Texas coast show a high correlation among volume of produced fluids, timing of fault activation, rates of subsidence, and rates of wetland loss. Greater subsidence on the downthrown sides of faults contributes to more frequent flooding and generally wetter conditions, which are commonly reflected by changes in plant communities {e.g., Spartina patens to Spartina alterniflora) or progressive transformation of emergent vegetation to open water. Since the 1930s and 1950s, approximately 5,000 hectares of marsh habitat has been lost as a result of subsidence associated with faulting. Marsh- es have expanded locally along faults where hydrophytic vegetation has spread into former upland areas. Fault traces are linear to curvilinear and are visible because elevation differences across faults alter soil hydrology and vegetation. Fault lengths range from 1 to 13.4 km and average 3.8 km. Seventy-five percent of the faults visible on recent aerial photographs are not visible on photographs taken in the 1930's, indicating relatively recent fault movement. At least 80% of the surface faults correlate with extrapolated subsurface faults; the correlation increases to more than 90% when certain assumptions are made to compensate for mismatches in direction of displacement. Coastal wetlands loss in Texas associated with hydrocarbon extraction will likely increase where production in mature fields is prolonged without fiuid reinjection.

Texas↗

Practical guide to measuring wetland carbon pools and fluxes

Wetlands cover a small portion of the world, but have disproportionate influence on global carbon (C) sequestration, carbon dioxide and methane emissions, and aquatic C fluxes. However, the underlying biogeochemical processes that affect wetland C pools and fluxes are complex and dynamic, making measurements of wetland C challenging. Over decades of research, many observational, experimental, and analytical approaches have been developed to understand and quantify pools and fluxes of wetland C. Sampling approaches range in their representation of wetland C from short to long timeframes and local to landscape spatial scales. This review summarizes common and cutting-edge methodological approaches for quantifying wetland C pools and fluxes. We first define each of the major C pools and fluxes and provide rationale for their importance to wetland C dynamics. For each approach, we clarify what component of wetland C is measured and its spatial and temporal representativeness and constraints. We describe practical considerations for each approach, such as where and when an approach is typically used, who can conduct the measurements (expertise, training requirements), and how approaches are conducted, including considerations on equipment complexity and costs. Finally, we review key covariates and ancillary measurements that enhance the interpretation of findings and facilitate model development. The protocols that we describe to measure soil, water, vegetation, and gases are also relevant for related disciplines such as ecology. Improved quality and consistency of data collection and reporting across studies will help reduce global uncertainties and develop management strategies to use wetlands as nature-based climate solutions.

Wetlands↗

Isotopic Approach to Soil Carbonate Dynamics and Implications for Paleoclimatic Interpretations

The radiocarbon content and stable isotope composition of soil carbonate are best described by a dynamic system in which isotopic reequilibration occurs as a result of recurrent dissolution and reprecipitation. Depth of water penetration into the soil profile, as well as soil age, determines the degree of carbonate isotope reequilibration. We measured ??13C, ??18O and radiocarbon content of gravel rinds and fine (<2 mm) carbonate in soils of 3 .different ages (1000, 3800, and 6300 14 C yr B.P.) to assess the degree to which they record and preserve a climatic signal. In soils developing in deposits independently dated at 3800 and 6300 radiocarbon yr B.P., carbonate radiocarbon content above 40 cm depth suggests continual dissolution and reprecipitation, presumably due to frequent wetting events. Between 40 and 90 cm depth, fine carbonate is dissolved and precipitated as rinds that are not redissolved subsequently. Below 90 cm depth in these soils, radiocarbon content indicates that inherited, fine carbonate undergoes little dissolution and reprecipitation. In the 3800- and 6300-yr-old soils, ??13C in rind and fine carbonate follows a decreasing trend with depth, apparently in equilibrium with modern soil gas, as predicted by a diffusive model for soil CO2. ??18O also decreases with depth due to greater evaporative enrichment above 50 cm depth. In contrast, carbonate isotopes in a 1000-yr-old deposit do not reflect modern conditions even in surficial horizons; this soil has not undergone significant pedogenesis. There appears to be a lag of at least 1000 but less than 3800 yr before carbonate inherited with parent material is modified by ambient climatic conditions. Although small amounts of carbonate are inherited with the parent material, the rate of pedogenic carbonate accumulation indicates that Ca is derived primarily from eolian and rainfall sources. A model describing carbonate input and radiocarbon decay suggests that fine carbonate below 90 cm is mostly detrital (inherited) and that carbonate rinds have been forming pedogenically at a constant rate since alluvial fans were deposited.

Quaternary Research↗

Pleistocene glaciation of volcano Ajusco, central Mexico, and comparison with the standard Mexican glacial sequence

Three Pleistocene glaciations and two Holocene Neoglacial advances occurred on volcano Ajusco in central Mexico. Lateral moraines of the oldest glaciation, the Marqués, above 3250 m are made of light-gray indurated till and are extensively modified by erosion. Below 3200 m the till is dark red, decomposed, and buried beneath volcanic colluvium and tephra. Very strongly to strongly developed soil profiles (Inceptisols) have formed in the Marqués till and in overlying colluvia and tephra. Large sharp-crested moraines of the second glaciation, the Santo Tomás, above 3300 m are composed of pale-brown firm till and are somewhat eroded by gullies. Below 3250 m the till is light reddish brown, cemented, and weathered. Less-strongly developed soil profiles (Inceptisols) have formed in the Santo Tomás till and in overlying colluvia and tephra. Narrow-crested moraines of yellowish-brown loose till of the third glaciation, the Albergue, are uneroded. Weakly developed soil profiles (Inceptisols) in the Albergue till have black ash in the upper horizon. Two small Neoglacial moraines of yellowish-brown bouldery till on the cirque floor of the largest valley support weakly developed soil profiles with only A and Cox horizons and no ash in the upper soil horizons. Radiocarbon dating of organic matter of the B horizons developed in tills, volcanic ash, and colluvial volcanic sand includes ages for both the soil-organic residue and the humic-acid fraction, with differences from 140 to 660 yr. The dating provides minimum ages of about 27,000 yr for the Marqués glaciation and about 25,000 yr for the Santo Tomás glaciation. Dates for the overlying tephra indicate a complex volcanic history for at least another 15,000 yr. Comparison of the Ajusco glacial sequence with that on Iztaccíhuatl to the east suggests that the Marqués and Santo Tomás glaciations may be equivalent to the Diamantes glaciation First and Second advances, the Albergue to the Alcalican glaciations, and the Neoglacial to the Ayolotepito advances.

Quaternary Research↗

Regional interpretation of water-quality monitoring data

We describe a method for using spatially referenced regressions of contaminant transport on watershed attributes (SPARROW) in regional water-quality assessment. The method is designed to reduce the problems of data interpretation caused by sparse sampling, network bias, and basin heterogeneity. The regression equation relates measured transport rates in streams to spatially referenced descriptors of pollution sources and land-surface and stream-channel characteristics. Regression models of total phosphorus (TP) and total nitrogen (TN) transport are constructed for a region defined as the nontidal conterminous United States. Observed TN and TP transport rates are derived from water-quality records for 414 stations in the National Stream Quality Accounting Network. Nutrient sources identified in the equations include point sources, applied fertilizer, livestock waste, nonagricultural land, and atmospheric deposition (TN only). Surface characteristics found to be significant predictors of land-water delivery include soil permeability, stream density, and temperature (TN only). Estimated instream decay coefficients for the two contaminants decrease monotonically with increasing stream size. TP transport is found to be significantly reduced by reservoir retention. Spatial referencing of basin attributes in relation to the stream channel network greatly increases their statistical significance and model accuracy. The method is used to estimate the proportion of watersheds in the conterminous United States (i.e., hydrologic cataloging units) with outflow TP concentrations less than the criterion of 0.1 mg/L, and to classify cataloging units according to local TN yield (kg/km 2 /yr).

Water Resources Research↗

Phenology, growth, and fecundity as determinants of distribution in closely related nonnative taxa

Invasive species researchers often ask: Why do some species invade certain habitats while others do not? Ecological theories predict that taxonomically related species may invade similar habitats, but some related species exhibit contrasting invasion patterns. Brassica nigra , Brassica tournefortii , and Hirschfeldia incana are dominant, closely related nonnative species that have overlapping, but dissimilar, distributions. Brassica tournefortii is rapidly spreading in warm deserts of the southwestern United States, whereas B. nigra and H. incana are primarily limited to semiarid and mesic regions. We compared traits of B. tournefortii that might confer invasiveness in deserts with those of related species that have not invaded desert ecosystems. Brassica tournefortii , B. nigra and H. incana were compared in controlled experiments conducted outdoors in a mesic site (Riverside, CA) and a desert site (Blue Diamond, NV), and in greenhouses, over 3 yr. Desert and mesic B. tournefortii populations were also compared to determine whether locally adapted ecotypes contribute to desert invasion. Experimental variables included common garden sites and soil water availability. Response variables included emergence, growth, phenology, and reproduction. There was no evidence for B. tournefortii ecotypes, but B. tournefortii had a more rapid phenology than B. nigra or H. incana . Brassica tournefortii was less affected by site and water availability than B. nigra and H. incana , but was smaller and less fecund regardless of experimental conditions. Rapid phenology allows B. tournefortii to reproduce consistently under variable, stressful conditions such as those found in Southwestern deserts. Although more successful in milder, mesic ecosystems, B. nigra and H. incana may be limited by their ability to reproduce under desert conditions. Rapid phenology and drought response partition invasion patterns of nonnative mustards along a gradient of aridity in the southwestern United States, and may serve as a predictive trait for other potential invaders of arid and highly variable ecosystems.

California;Nevada↗

Interdisciplinary science approach for harmful algal blooms (HABs) and algal toxins—A strategic science vision for the U.S. Geological Survey

Executive Summary Algal blooms in water, soils, dusts, and the environment have captured national attention because of concerns associated with exposure to algal toxins for humans and animals. Algal blooms naturally occur in all surface-water types and are important primary producers for aquatic ecosystems. However, excessive algae growth can be associated with many harmful effects ranging from aesthetic to toxicity concerns, so this excessive growth is commonly called a harmful algal bloom (HAB). Ecological imbalances that can lead to excessive algal growth, such as increased nutrient availability to waterbodies from natural and anthropogenic sources, are well documented in scientific literature. On the other hand, fundamental scientific understandings of environmental causes and controls leading to algal toxin production, environmental exposures, and adverse health outcomes for humans and animals could benefit from more attention by U.S. Geological Survey (USGS) scientists. Understanding when, why, and how the toxin is produced by individual algal cells or communities and why the toxin is released to the surrounding waterbody requires fundamental research to determine a toxin’s role, whether it provides competitive advantage or if other potential reasons exist for toxin production and release, such as secretions from otherwise benign biological processes. This research will require groundbreaking scientific discovery about underlying biologic and abiotic (non-living) processes commonly complicated by local variation in land use, microbial species composition, and ecosystem structure of the surrounding watershed. Although underlying processes by which HABs form may be similar from one waterbody to another, individual waterbodies may be controlled by local factors for HAB development and toxin production that are unique to the watershed. Consequently, many fundamental science gaps exist that prevent informed mitigation and prevention of toxic HAB events. There are also gaps in understanding local conditions that control algal growth unique to specific watersheds. Addressing these science gaps is needed to inform evidence-based decisions that protect human and animal health and that reduce recreational and socioeconomic losses.

Circular↗

Sediment transport and capacity change in three reservoirs, Lower Susquehanna River Basin, Pennsylvania and Maryland, 1900-2012

The U.S. Geological Survey (USGS) has conducted numerous sediment transport studies in the Susquehanna River and in particular in three reservoirs in the Lower Susquehanna River Basin to determine sediment transport rates over the past century and to document changes in storage capacity. The Susquehanna River is the largest tributary to Chesapeake Bay and transports about one-half of the total freshwater input and substantial amounts of sediment and nutrients to the bay. The transported loads are affected by deposition in reservoirs (Lake Clarke, Lake Aldred, and Conowingo Reservoir) behind three hydropower dams. The geometry and texture of the deposited sediments in each reservoir upstream from the three dams has been a subject of research in recent decades. Particle size deposition and sediment scouring processes are part of the reservoir dynamics. A Total Maximum Daily Load (TMDL) for nitrogen, phosphorus, and sediment was established for Chesapeake Bay to attain water-quality standards. Six states and the District of Columbia agreed to reduce loads to the bay and to meet load allocation goals for the TMDL. The USGS has been estimating annual sediment loads at the Susquehanna River at Marietta, Pennsylvania (above Lake Clarke), and Susquehanna River at Conowingo, Maryland (below Conowingo Reservoir), since the mid-1980s to predict the mass balance of sediment transport through the reservoir system. Using streamflow and sediment data from the Susquehanna River at Harrisburg, Pennsylvania (upstream from the reservoirs), from 1900 to 1981, sediment loads were greatest in the early to mid-1900s when land disturbance activities from coal production and agriculture were at their peak. Sediment loads declined in the 1950s with the introduction of agricultural soil conservation practices. Loads were dominated by climatic factors in the 1960s (drought) and 1970s (very wet) and have been declining since the 1980s through 2012. The USGS developed a regression equation to predict the sediment scour load for daily mean streamflows greater than 300,000 cubic feet per second for the Lower Susquehanna River reservoirs. A compilation of data from various sources produced a range in total sediment transported through the reservoir system and allowed for apportioning to source (watershed or scour) for various streamflows. In 2011, Conowingo Reservoir was estimated to be about 92 percent of sediment storage capacity. Since construction of Conowingo Dam in 1929 through 2012, approximately 470 million tons of sediment was transported down the Susquehanna River into the reservoir system, approximately 290 million tons were trapped, and approximately 180 million tons were transported to Chesapeake Bay. Spatial and estimated total sand deposition in Conowingo Reservoir based on historical sediment cores indicated continued migration of sand downgradient toward the dam and the winnowing of silts and clays near the dam due to scour.

Maryland, Pennsylvania↗

Climate variability and extremes, interacting with nitrogen storage, amplify eutrophication risk

Despite 30 years of basin-wide nutrient-reduction efforts, severe hypoxia continues to be observed in the Chesapeake Bay. Here we demonstrate the critical influence of climate variability, interacting with accumulated nitrogen (N) over multidecades, on Susquehanna River dissolved nitrogen (DN) loads, known precursors of the hypoxia in the Bay. We used the process model LM3-TAN (Terrestrial and Aquatic Nitrogen), which is capable of capturing both seasonal and decadal-to-century changes in vegetation-soil-river N storage, and produced nine scenarios of DN-load distributions under different short-term scenarios of climate variability and extremes. We illustrate that after 1 to 3 yearlong dry spells, the likelihood of exceeding a threshold DN load (56 kt yr −1 ) increases by 40 to 65% due to flushing of N accumulated throughout the dry spells and altered microbial processes. Our analyses suggest that possible future increases in climate variability/extremes—specifically, high precipitation occurring after multiyear dry spells—could likely lead to high DN-load anomalies and hypoxia.

Chesapeake Bay↗

Seasonal variation in nutrient retention during inundation of a short-hydroperiod floodplain

Floodplains are generally considered to be important locations for nutrient retention or inorganic-to-organic nutrient conversions in riverine ecosystems. However, little is known about nutrient processing in short-hydroperiod floodplains or seasonal variation in floodplain nutrient retention. Therefore, we quantified the net uptake, release or transformation of nitrogen (N), phosphorus (P) and suspended sediment species during brief periods (1-2 days) of overbank flooding through a 250-m floodplain flowpath on the fourth-order Mattawoman Creek, Maryland U.S.A. Sampling occurred during a winter, two spring and a summer flood in this largely forested watershed with low nutrient and sediment loading. Concentrations of NO3- increased significantly in surface water flowing over the floodplain in three of the four floods, suggesting the floodplain was a source of NO3-. The upper portion of the floodplain flowpath consistently exported NH4+, most likely due to the hyporheic: flushing of floodplain soil NH4+, which was then likely nitrified to NO3- in floodwaters. The floodplain was a sink for particulate organic P (POP) during two floods and particulate organic N and inorganic suspended sediment (ISS) during one flood. Large releases of all dissolved inorganic N and P species occurred following a snowmelt and subsequent cold winter flood. Although there was little consistency in most patterns of nutrient processing among the different floods, this floodplain, characterized by brief inundation, low residence time and low nutrient loading, behaved oppositely from the conceptual model for most floodplains in that it generally exported inorganic nutrients and imported organic nutrients.

River Research and Applications↗

Spatial and temporal geochemical trends in the hydrothermal system of Yellowstone National Park: Inferences from river solute fluxes

We present and analyze a chemical dataset that includes the concentrations and fluxes of HCO 3 − , SO 4 2− , Cl − , and F − in the major rivers draining Yellowstone National Park (YNP) for the 2002–2004 water years (1 October 2001 – 30 September 2004). The total (molar) flux in all rivers decreases in the following order, HCO 3 − > Cl − > SO 4 2− > F − , but each river is characterized by a distinct chemical composition, implying large-scale spatial heterogeneity in the inputs of the various solutes. The data also display non-uniform temporal trends; whereas solute concentrations and fluxes are nearly constant during base-flow conditions, concentrations decrease, solute fluxes increase, and HCO 3 − /Cl − , and SO 4 2− /Cl − increase during the late-spring high-flow period. HCO 3 − /SO 4 2− decreases with increasing discharge in the Madison and Falls Rivers, but increases with discharge in the Yellowstone and Snake Rivers. The non-linear relations between solute concentrations and river discharge and the change in anion ratios associated with spring runoff are explained by mixing between two components: (1) a component that is discharged during base-flow conditions and (2) a component associated with snow–melt runoff characterized by higher HCO 3 − /Cl − and SO 4 2− /Cl − . The fraction of the second component is greater in the Yellowstone and Snake Rivers, which host lakes in their drainage basins and where a large fraction of the solute flux follows thaw of ice cover in the spring months. Although the total river HCO 3 − flux is larger than the flux of other solutes (HCO 3 − /Cl − ≈ 3), the CO 2 equivalent flux is only ∼ 1% of the estimated emission of magmatic CO 2 soil emissions from Yellowstone. No anomalous solute flux in response to perturbations in the hydrothermal system was observed, possibly because gage locations are too distant from areas of disturbance, or because of the relatively low sampling frequency. In order to detect changes in river hydrothermal solute fluxes, sampling at higher frequencies with better spatial coverage would be required. Our analysis also suggests that it might be more feasible to detect large-scale heating or cooling of the hydrothermal system by tracking changes in gas and steam flux than by tracking changes in river solute flux.

Journal of Volcanology and Geothermal Research↗

Hydrologic connectivity between landscapes and streams: Transferring reach‐ and plot‐scale understanding to the catchment scale

The relationship between catchment structure and runoff characteristics is poorly understood. In steep headwater catchments with shallow soils the accumulation of hillslope area (upslope accumulated area (UAA)) is a hypothesized first‐order control on the distribution of soil water and groundwater. Hillslope‐riparian water table connectivity represents the linkage between the dominant catchment landscape elements (hillslopes and riparian zones) and the channel network. Hydrologic connectivity between hillslope‐riparian‐stream (HRS) landscape elements is heterogeneous in space and often temporally transient. We sought to test the relationship between UAA and the existence and longevity of HRS shallow groundwater connectivity. We quantified water table connectivity based on 84 recording wells distributed across 24 HRS transects within the Tenderfoot Creek Experimental Forest (U.S. Forest Service), northern Rocky Mountains, Montana. Correlations were observed between the longevity of HRS water table connectivity and the size of each transect's UAA ( r 2 = 0.91). We applied this relationship to the entire stream network to quantify landscape‐scale connectivity through time and ascertain its relationship to catchment‐scale runoff dynamics. We found that the shape of the estimated annual landscape connectivity duration curve was highly related to the catchment flow duration curve ( r 2 = 0.95). This research suggests internal catchment landscape structure (topography and topology) as a first‐order control on runoff source area and whole catchment response characteristics.

Water Resources Research↗

Sensitivity of headwater streamflow to thawing permafrost and vegetation change in a warming Arctic

Climate change has the potential to impact headwater streams in the Arctic by thawing permafrost and subsequently altering hydrologic regimes and vegetation distribution, physiognomy and productivity. Permafrost thaw and increased subsurface flow have been inferred from the chemistry of large rivers, but there is limited empirical evidence of the impacts to headwater streams. Here we demonstrate how changing vegetation cover and soil thaw may alter headwater catchment hydrology using water budgets, stream discharge trends, and chemistry across a gradient of ground temperature in northwestern Alaska. Colder, tundra-dominated catchments shed precipitation through stream discharge, whereas in warmer catchments with greater forest extent, evapotranspiration and infiltration are substantial fluxes. Forest soils thaw earlier, remain thawed longer, and display seasonal water content declines, consistent with greater evapotranspiration and infiltration. Streambed infiltration and water chemistry indicate that even minor warming can lead to increased infiltration and subsurface flow. Additional warming, permafrost loss, and vegetation shifts in the Arctic will deliver water back to the atmosphere and to subsurface aquifers in many regions, with the potential to substantially reduce discharge in headwater streams, if not compensated by increasing precipitation. Decreasing discharge in headwater streamflow will have important implications for aquatic and riparian ecosystems.

Alaska↗

Trace-metal variation in soils and sagebrush in the Powder River Basin, Wyoming and Montana

A reconnaissance study of 28 trace metals in samples of surface soil (0-2.5 cm deep), subsurface soil (15-20 cm deep), and big sagebrush ( Artemisia tridentata ) that were collected from the Powder River Basin in Wyoming and Montana indicates that little variation occurs in nature at scales greater than about 35 km. This general lack of broadscale variation suggests that simple summary statistics for these materials could provide basinwide geochemical baselines for use in monitoring secular changes in the local geochemical environment. Samples of big sagebrush near the Dave Johnston Power Plant at the southern edge of the basin exhibit statistically significant reductions of strontium, vanadium, uranium, and selenium eastward from the plant.

Montana, Wyoming↗

Evidence from Lake Baikal for Siberian glaciation during oxygen-isotope substage 5d

The paleoclimatic record from bottom sediments of Lake Baikal (eastern Siberia) reveals new evidence for an abrupt and intense glaciation during the initial part of the last interglacial period (isotope substage 5d). This glaciation lasted about 12 000 yr from 117 000 to 105 000 yr BP according to correlation with the SPEC-MAP isotope chronology. Lithological and biogeochemical evidence of glaciation from Lake Baikal agrees with evidence for the advance of ice sheet in northwestern Siberia during this time period and also with cryogenic features within the strata of Kazantzevo soils in Southern Siberia. The severe 5d glaciation in Siberia was caused by dramatic cooling due to the decrease in solar insolation (as predicted by the model of insulation changes for northern Asia according to Milankovich theory) coupled with western atmospheric transport of moisture from the opea areas of Northern Atlantic and Arctic seas (which became ice-free due to the intense warming during preceeding isotope substage 5e). Other marine and continental records show evidence for cooling during 5d, but not for intense glaciation. Late Pleistocene glaciations in the Northern Hemisphere may have begun in northwestern Siberia.

Lake Baikal↗

Instrumental record of debris flow initiation during natural rainfall: Implications for modeling slope stability

The middle of a hillslope hollow in the Oregon Coast Range failed and mobilized as a debris flow during heavy rainfall in November 1996. Automated pressure transducers recorded high spatial variability of pore water pressure within the area that mobilized as a debris flow, which initiated where local upward flow from bedrock developed into overlying colluvium. Postfailure observations of the bedrock surface exposed in the debris flow scar reveal a strong spatial correspondence between elevated piezometric response and water discharging from bedrock fractures. Measurements of apparent root cohesion on the basal ( C b ) and lateral ( C l ) scarp demonstrate substantial local variability, with areally weighted values of C b = 0.1 and C l = 4.6 kPa. Using measured soil properties and basal root strength, the widely used infinite slope model, employed assuming slope parallel groundwater flow, provides a poor prediction of hydrologic conditions at failure. In contrast, a model including lateral root strength (but neglecting lateral frictional strength) gave a predicted critical value of relative soil saturation that fell within the range defined by the arithmetic and geometric mean values at the time of failure. The 3‐D slope stability model CLARA‐W, used with locally observed pore water pressure, predicted small areas with lower factors of safety within the overall slide mass at sites consistent with field observations of where the failure initiated. This highly variable and localized nature of small areas of high pore pressure that can trigger slope failure means, however, that substantial uncertainty appears inevitable for estimating hydrologic conditions within incipient debris flows under natural conditions.

Oregon↗

Machine learning predicted redox conditions in the glacial aquifer system, northern continental United States

Groundwater supplies 50% of drinking water worldwide and 30% in the United States. Geogenic and anthropogenic contaminants can, however, compromise water quality, thus limiting groundwater availability. Reduction/oxidation (redox) processes and redox conditions affect groundwater quality by influencing the mobility and transport of common geogenic and anthropogenic contaminants. In the glacial aquifer system, northern United States (GLAC, 1.87 million km 2 ), groundwater with high arsenic or manganese concentration is associated with reducing conditions and high nitrate with oxidizing conditions. This study uses machine learning to identify the relative influence of drivers of redox conditions (e.g., residence time vs. reactivity) across the glacial landscape. We developed three‐dimensional boosted regression tree models to predict redox conditions using the likelihood of low dissolved oxygen or high iron as indicators of anoxic conditions. Results indicate that variation in redox condition is controlled primarily by residence time (e.g., groundwater age and relative depth) and to a lesser extent by geochemical reactivity (e.g., subsurface contact time, soil carbon). Older water and deeper wells, along with more water storage or slower water movement was associated with higher probability of anoxic conditions. Mapped model results illustrate regions where anoxic redox conditions may mobilize geogenic contaminants or oxic conditions may limit denitrification potential. Results may also provide simplified redox input for process or predictive models of, for example, arsenic, manganese, or nitrate. Machine learning modeling methods can lead to improved understanding of contaminant occurrence and what drives redox conditions, and the methods may be transferable to other settings.

Northern Continental United States↗