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Mercury on a landscape scale—Balancing regional export with wildlife health

The Cosumnes River watershed requires a 57–64 percent reduction in loads to meet the new Delta methylmercury (MeHg) total maximum daily load allocation, established by the Central Valley Regional Water Quality Control Board. Because there are no large point sources of MeHg in the watershed, the focus of MeHg load reductions will fall upon non-point sources, particularly the expansive wetlands considered to be a primary source of MeHg in the region. Few management practices have been implemented and tested in order to meet load reductions in managed wetlands, but recent efforts have shown promise. This project examines a treatment approach to reduce MeHg loads to the Sacramento-San Joaquin River Delta by creating open-water deep cells with a small footprint at the downstream end of wetlands to promote net demethylation of MeHg and to minimize MeHg and Hg loads exiting wetlands at the Cosumnes River Preserve. Specifically, the deep cells were were located immediately up gradient of the wetland’s outflow weir and were deep enough (75–91 centimeter depth) to be vegetation-free. The topographic and hydrologic structure of each treatment wetland was modified to include open-water deep cells so that the removal of aqueous MeHg might be enhanced through (1) particle settling, (2) photo-degradation, and (3) benthic microbial demethylation. These deep cells were, therefore, expected to clean MeHg from surface water prior to its discharge to the Cosumnes River and the downstream Delta. Our goal was to test whether the implementation of the deep cells within wetlands would minimize MeHg and total Hg export. Further, we sought to test whether continuous flow-through hydrology, would lower MeHg concentrations in resident biota, compared to traditional wetland management operations. The dominant practice in seasonal wetlands management is the “fill-and-maintain” approach, in which wetlands are filled with water and the water levels maintained without substantial draining until drawdown. Our approach was to create and characterize replicate treatment wetland complexes, in conjunction with monitoring of hydrologic, biologic, and chemical indicators of MeHg exposure for two full annual cycles within winter-spring flooded seasonal wetlands. In addition to the creation of deep cells within treatment wetlands, hydrology was manipulated so that there was a constant flow-through of water, while the control wetlands utilized the fill-and-maintain approach. Specifically, the treatment wetlands were maintained in a flow-through manner, while the control wetlands were maintained in a fill-and-maintain manner from September through May, to test the hypothesis that the flow of water through the seasonal wetland can lower fish bioaccumulation through dilution of MeHg-concentrated water within the wetland by constant inflows of water into the wetland. The major tasks of this study included: (1) field design and implementation, (2) water and wetland management, (3) hydrologic monitoring and water quality sampling, (4) MeHg export and load estimates, (5) caged fish experiments for examining MeHg bioaccumulation, (6) site and process characterization to improve understanding and transferability of results, (7) adaptive management, transferability, and outreach, and (8) reporting of results and conclusions. This report summarizes the key findings of this study, which focuses on MeHg load estimates from control and treatment wetlands, quantification of three MeHg removal mechanisms (particulate settling, benthic demethylation, and photo-demethylation) in the deep cells within the treatment wetlands, and MeHg bioaccumulation in wetland fishes. Key findings include: Over two years of study, mean whole-water MeHg load decreased 37 percent in deep cells, when comparing inlet of check weir flows to outlet. Of the 37 percent MeHg load removed within the deep cell, photodegradation accounted for 7 percent and particle flux to the benthos accounted for 24 percent of the mass removed, with the remaining 6 percent apparent MeHg loss unexplained. Benthic MeHg degradation did not appear to be a major MeHg removal process in the deep cells, as changes in the ambient MeHg pool over 7-day bottle incubations showed that the surface sediment exhibited net MeHg production in the majority (87 percent) of incubation experiments. In only 13 percent of the incubations (3 out of 24) was net MeHg degradation observed. Estimates of benthic diffusive flux of MeHg across the sediment/water interface were small relative to particulate flux and variable (positive or negative), suggesting this is likely a minor term in the overall MeHg budget within the deep cells. Although the deep cells served as net MeHg sink overall, MeHg export from the flow-through treatment wetlands (shallow and deep combined) exceeded export from the fill-and-maintain managed control wetlands, because of the differences in hydrologic management between the two wetland types. Shallow wetlands under flow-through conditions generated a net export of MeHg. Most of the annual MeHg export from the treatment wetlands occurred within the first 3 months of flood up (September to November), shortly after hydrologic management began. Despite the effectiveness of the deep cell in lowering MeHg export concentrations, total mercury (THg) concentration did not decrease in biosentinel fish ( Gambusia affinis , Mosquitofish) between the deep cell inlet and outlet. Mosquitofish THg concentrations were higher in treatment wetlands than in control wetlands during the first year of study, likely because of an associated increase in MeHg availability immediately following wetland construction activities. Mosquitofish THg concentrations declined in the treatment wetlands during the second year of study, and fish THg concentrations in treatment wetlands were no different from those in the control. Similarly, the increased hydrologic flow rates in the treatment wetlands did not lower fish THg concentrations nor aqueous MeHg concentrations in the shallow cells, suggesting that MeHg flux from the sediment to water column exceeded the flow-through flushing rate in the shallow portion of the treatment wetlands. Reductions in MeHg concentrations of surface water and fish may require higher flow rates than used in the study to achieve the region’s regulatory goals. However, the flow rates necessary may not be feasible for these managed wetlands because of limited water supply and the associated costs for water and pumping. The use of deep cells in seasonal wetlands were effective in lowering MeHg exports under continuous water flow-through hydrology. However, fill-and-maintain hydrology had lower exports overall, because of a single major drainage event at the end of the flood season. Future studies focused on limiting MeHg export should consider combining deep cells with the fill-and-maintain or fill-and-trickle hydrologic management approach.

California↗

Landscape change associated with the upper Scenic Drive landslide, La Honda, California, January 10–June 28, 2017

La Honda, California, is a small town in unincorporated San Mateo County, located on the west edge of the San Francisco Peninsula in the Santa Cruz Mountains, between San Francisco and San Jose. The Scenic Drive area of La Honda has experienced several past episodes of landslide motion, which were documented in 1998, 2005, and 2006. This report documents the movement of the upper Scenic Drive landslide that occurred between January 10 and June 28, 2017. Our mapping provides a snapshot of the 2017 upper Scenic Drive landslide, as imaged from high-resolution terrestrial laser scanner (TLS) survey data (also referred to as terrestrial lidar) that we collected January 27–28, 2017; we mapped the landforms associated with the 2017 upper Scenic Drive landslide motion using a bare-earth TLS shaded-relief base map, in addition to field observations. Our mapping is supplemented by photographs of the mapped landforms, which were taken between January 11 and 31, 2017; these photographs illustrate the development of selected landslide features. The purpose of this report is to make available the maps constructed from three-dimensional TLS data and the photographs that show the landslide morphology of the 2017 upper Scenic Drive landslide. The scope of this report is limited to the motion of the upper Scenic Drive landslide that occurred between January 10 and June 28, 2017.

California↗

Documenting the multiple facets of a subsiding landscape from coastal cities and wetlands to the continental shelf

Land subsidence is a settling, sinking, or collapse of the land surface. In the southeastern United States, subsidence is frequently observed as sinkhole collapse in karst environments, wetland degradation and loss in coastal and other low-lying areas, and inundation of coastal urban communities. Human activities such as fluid extraction, mining, and overburden alteration can cause or exacerbate subsidence, which can result in damage to infrastructure and resources. Subsidence is a hazard that takes place throughout the United States; however, a systematic approach to recognize and develop informed responses to the drivers of subsidence has not yet been fully established. To address this problem, the U.S. Geological Survey (USGS) Southeast Region (SER) funded the gathering of a team of interdisciplinary USGS scientists to promote scientific collaboration. Southeast Region scientists welcomed scientists from other regions (see table 1.1 in Appendix 1) in September 2018 at the St. Petersburg Coastal and Marine Science Center (SPCMSC) in Florida for the first workshop of the Subsidence Flex Team (SFT) (see Appendix 2 for agenda). The SFT set out to review subsidence-related research and technology and develop a unifying framework for describing the processes and hazards associated with land subsidence. A more comprehensive understanding of subsidence hazards could help to inform regional vulnerability assessments that would prove invaluable to the public, community developers, policy makers, and resource managers in both inland and coastal states. The SFT analyzed USGS strengths and weaknesses to identify existing infrastructure and capabilities that could be leveraged to create a comprehensive and far-reaching subsidence-monitoring and mitigation program. Over the course of the 2-day workshop, interdisciplinary understandings of the processes and hazards related to subsidence were explored through individual presentations and group discussion. With all perspectives considered, the SFT recommended that subsidence-related research develop scientific approaches and metrics by which the subsidence component can be isolated and quantified in order to protect both the environment and human infrastructure from harm.

Alabama, Florida, Louisiana, Mississippi↗

Geochemical landscapes of the conterminous United States — New map presentations for 22 elements

Geochemical maps of the conterminous United States have been prepared for seven major elements (Al, Ca, Fe, K, Mg, Na, and Ti) and 15 trace elements (As, Ba, Cr, Cu, Hg, Li, Mn, Ni, Pb, Se, Sr, V, Y, Zn, and Zr). The maps are based on an ultra low-density geochemical survey consisting of 1,323 samples of soils and other surficial materials collected from approximately 1960-1975. The data were published by Boerngen and Shacklette (1981) and black-and-white point-symbol geochemical maps were published by Shacklette and Boerngen (1984). The data have been reprocessed using weighted-median and Bootstrap procedures for interpolation and smoothing.

Conterminous United States↗

Organic-carbon sequestration in soil/sediment of the Mississippi River deltaic plain — Data; landscape distribution, storage, and inventory; accumulation rates; and recent loss, including a post-Katrina preliminary analysis

Soil/sediment of the Mississippi River deltaic plain (MRDP) in southeastern Louisiana is rich in organic carbon (OC). The MRDP contains about 2 percent of all OC in the surface meter of soil/sediment in the Mississippi River Basin (MRB). Environments within the MRDP differ in soil/sediment organic carbon (SOC) accumulation rate, storage, and inventory. The focus of this study was twofold: (1) develop a database for OC and bulk density for MRDP soil/sediment; and (2) estimate SOC storage, inventory, and accumulation rates for the dominant environments (brackish, intermediate, and fresh marsh; natural levee; distributary; backswamp; and swamp) in the MRDP. Comparative studies were conducted to determine which field and laboratory methods result in the most accurate and reproducible bulk-density values for each marsh environment. Sampling methods included push-core, vibracore, peat borer, and Hargis1 sampler. Bulk-density data for cores taken by the "short push-core method" proved to be more internally consistent than data for samples collected by other methods. Laboratory methods to estimate OC concentration and inorganic-constituent concentration included mass spectrometry, coulometry, and loss-on-ignition. For the sampled MRDP environments, these methods were comparable. SOC storage was calculated for each core with adequate OC and bulk-density data. SOC inventory was calculated using core-specific data from this study and available published and unpublished pedon data linked to SSURGO2 map units. Sample age was estimated using isotopic cesium ( 37 Cs), lead ( 210 Pb), and carbon ( 14 C), elemental Pb, palynomorphs, other stratigraphic markers, and written history. SOC accumulation rates were estimated for each core with adequate age data. Cesium-137 profiles for marsh soil/sediment are the least ambiguous. Levee and distributary 137 Cs profiles show the effects of intermittent allochthonous input and/or sediment resuspension. Cesium-137 and 210 Pb data gave the most consistent and interpretable information for age estimations of soil/sediment deposited during the 1900s. For several cores, isotopic 14 C and 137 Cs data allowed the 1963-64 nuclear weapons testing (NWT) peak-activity datum to be placed within a few-centimeter depth interval. In some cores, a too old 14 C age (when compared to 137 Cs and microstratigraphic-marker data) is the probable result of old carbon bound to clay minerals incorporated into the organic soil/sediment. Elemental Pb coupled with Pb source-function data allowed age estimation for soil/sediment that accumulated during the late 1920s through the 1980s. Exotic pollen (for example, Vigna unguiculata and Alternanthera philoxeroides ) and other microstratigraphic indicators (for example, carbon spherules) allowed age estimations for marsh soil/sediment deposited during the settlement of New Orleans (1717-20) through the early 1900s. For this study, MRDP distributary and swamp environments were each represented by only one core, backswamp environment by two cores, all other environments by three or more cores. MRDP core data for the surface meter soil/sediment indicate that (1) coastal marshes, abandoned distributaries, and swamps have regional SOC-storage values >16 kg m -2 ; (2) swamps and abandoned distributaries have the highest SOC storage values (swamp, 44.8 kg m -2 ; abandoned distributary, 50.9 kg m -2 ); (3) fresh-to-brackish marsh environments have the second highest site-specific SOC-storage values; and (4) site-specific marsh SOC storage values decrease as the salinity of the environment increases (fresh-marsh, 36.2 kg m -2 ; intermediate marsh, 26.2 kg m -2 ; brackish marsh, 21.5 kg m -2 ). This inverse relation between salinity and SOC storage is opposite the regional systematic increase in SOC storage with increasing salinity that is evident when SOC storage is mapped by linking pedon data to SSURGO map units (fresh marsh, 47 kg m -2 ; intermediate marsh, 67 kg m -2 ; brackish marsh, 75 kg m -2 ; and salt marsh, 80 kg m -2 ). MRDP core data for this study also indicate that levees and backswamp have regional SOC-storage values <16 kg m -2 . Group-mean SOC storage for cores from these environments are natural levee (17.0 kg m -2 ) and backswamp (14.1 kg m -2 ). An estimate for the SOC inventory in the surface meter of soil/sediment in the MRDP can be made using the SSURGO mapped portion of the coastal-marsh vegetative-type map (13,236 km 2 , land-only area) published by the Louisiana Department of Wildlife and Fisheries and U.S. Geological Survey (1997). This area has a SOC inventory (surface meter) of 677 Tg (slightly more than 2 percent of the 30,289 Tg SOC inventory for the MRB). The MRDP (6,180 km2, land-only area) has an estimated SOC inventory of 397 Tg. Most of the MRDP is located within the SSURGO mapped coastal marshlands. The entire MRDP, including water, has an area of about 10,800 km 2 . Using the ratio of total MRDP area to SSURGO mapped MRDP area as an adjustment, the MRDP SOC inventory is estimated at 694 Tg. This larger estimate of 694 Tg for the SOC inventory is probably more realistic, because it is reasonable to assume that the marsh sediments overlain by shallow water have comparable SOC storage to that of the adjacent land areas. MRDP core data for this study indicate that there is some variability in long-term SOC mass-accumulation rates for centuries and millennia and that this variability may indicate important geologic changes or changes in land use. However, the consistency of the range in rates of SOC accumulation through time suggests a remarkable degree of marsh sustainability throughout the Holocene, including the recent period of significant marsh modification/channelization for human use. One example of marsh sustainability is its present ability to function as a SOC sink even with Louisiana's large-scale coastal land loss during the last several decades. With coastal-marsh restoration efforts, this sink potential will increase. Looking to the future, a total of 1,101 g m -2 yr -1 SOC is projected to be lost from all of coastal Louisiana (U.S. Army Corps of Engineers, Louisiana Coastal Area (LCA) subprovinces 1-4; not just the MRDP) through coastal erosion from year 2000 to 2050. This translates to a projected SOC-loss rate of about 0.20 percent per year. The recent Hurricanes Katrina and Rita, which devastated the Louisiana coast during late August and late September 2005, transformed about 259 km 2 (100 mi 2 ) of marsh to open water (U.S. Geological Survey, 2005). To the extent that some or all of this land loss is permanent, this result equates to a SOC loss of about 15 Tg. This estimate is based on the year-2000 15,153-km 2 land area for the LCA study area that includes LCA subprovince 4. Using the year-2000 land area, the LCA study area had an estimated SOC inventory of 858 Tg. The estimated 15 Tg SOC loss attributable to Hurricanes Katrina and Rita is 1.7 percent of the year-2000 LCA inventory and 2.3 percent of the year-2000 MRDP inventory. If this SOC loss is included in the projection for the year 2050, then the MRDP would either remain a source with a net SOC loss of 3 Tg or become a weak sink with a net SOC gain of 4 Tg. These estimates are lower bounds for potential SOC flux because they are only for the surface meter of landmass.

Louisiana↗

Physiography, geology, and land cover of four watersheds in eastern Puerto Rico: Chapter A in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Four watersheds with differing geology and land cover in eastern Puerto Rico have been studied on a long-term basis by the U.S. Geological Survey to evaluate water, energy, and biogeochemical budgets. These watersheds are typical of tropical, island-arc settings found in many parts of the world. Two watersheds are located on coarse-grained granitic rocks that weather to quartz- and clay-rich, sandy soils, and two are located on fine-grained volcanic rocks and volcaniclastic sedimentary rocks that weather to quartz-poor, fine-grained soils. For each bedrock type, one watershed is covered with mature forest, and the other watershed, like most of Puerto Rico, has transformed from relatively undisturbed pre-European forest to intensive agriculture in the 19th and early 20th centuries, and further to ongoing reforestation that began in the middle of the 20th century. The comparison of water chemistry and hydrology in these watersheds allows an evaluation of the effects of land-use history and geology on hydrologic regimes and erosion rates. This chapter describes the physiography, geology, and land cover of the four watersheds and provides background information for the remaining chapters in this volume.

Professional Paper↗

Hydrology and climate of four watersheds in eastern Puerto Rico: Chapter C in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Puerto Rico lies directly in the path of the easterly trade winds, which deliver steady rainfall to the mountains and steer tropical wave systems toward the island. Hurricanes and tropical storms derived from these tropical waves differ in frequency and intensity, contributing to substantial interannual variation in precipitation and stream discharge. Puerto Rico's steep topography and small water-storage capacity leave the island's water supply and developed flood plains vulnerable to extreme weather events, such as hurricanes, floods, and droughts. This vulnerability may increase in the future owing to ongoing change, both local (such as land-cover shifts, water-supply projects, and construction of roads and other infrastructure) and regional (climate variability and change). Climate change, which could lead to more intense and prolonged droughts as well as an increase in the magnitude and frequency of destructive storms in the Caribbean, may alter temperature and affect the availability of water for human and ecosystem needs. Accurate assessment of hydrologic regimes and water budgets is therefore crucial for effective management of water resources. As part of the U.S. Geological Survey's Water, Energy, and Biogeochemical Budgets program, hydrologic and geomorphologic processes and stream chemistry of four small watersheds in eastern Puerto Rico, which differ in geology and land cover, have been studied since 1991. Spatial and temporal characteristics of precipitation and stream discharge, along with water budgets, were determined for the watersheds for the period 1991 to 2005. The locations of the watersheds relative to the Luquillo Mountains and the range's associated rain shadow dominate hydrological processes, dwarfing influences of land cover. The influence of geology is reflected in recession characteristics of the rivers (recession is faster in soils overlying volcaniclastic bedrock) and in hillslope geomorphic processes (sediment is delivered at higher rates from soils overlying granitic bedrock).

Professional Paper↗

Atmospheric inputs to watersheds of the Luquillo Mountains in eastern Puerto Rico: Chapter D in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Twenty years of precipitation-chemistry data from the National Atmospheric Deposition Program site at El Verde, Puerto Rico, demonstrate that three major sources control the composition of solutes in rain in eastern Puerto Rico. In order of importance, these sources are marine salts, temperate contamination from the Northern Hemisphere, and Sahara Desert dust. Marine salts are a source of roughly 82 percent of the ionic charge in precipitation; marine salt inputs are greatest in January. Evaluation of 15 years of U.S. Geological Survey data for four watersheds in eastern Puerto Rico suggests that large storms, including hurricanes, are associated with exceptionally high chloride concentrations in stream waters. Some of these storms were missed in sampling by the National Atmospheric Deposition Program, and therefore its data on the marine contribution likely underestimate chloride. The marine contribution is a weak source of acidity. Temperate contamination contributes about 10 percent of the ionic charge in precipitation; contaminants are primarily nitrate, ammonia, and sulfate derived from various manmade and natural sources. Peak deposition of temperate contaminants is during January, April, and May, months in which strong weather fronts arrive from the north. Temperate contamination, a strong source of acidity, is the only component that is increasing through time. Sahara Desert dust provides 5 percent of the ionic charge in precipitation; it is strongly seasonal, peaking in June and July during times of maximum dust transport from the Sahara and sub-Saharan regions. This dust contributes, on average, enough alkalinity to neutralize the acidity in June and July rains.

Professional Paper↗

Water quality and mass transport in four watersheds in eastern Puerto Rico: Chapter E in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Water quality of four small watersheds in eastern Puerto Rico has been monitored since 1991 as part of the U.S. Geological Survey's Water, Energy, and Biogeochemical Budgets program. These watersheds represent a montane, humid-tropical environment and differ in geology and land cover. Two watersheds are located on granitic rocks, and two are located on volcaniclastic rock. For each bedrock type, one watershed is covered with mature rainforest in the Luquillo Mountains, and the other watershed is undergoing reforestation after being affected by agricultural practices typical of eastern Puerto Rico. A subwatershed of the Icacos watershed, the Guab&aacute;, was also monitored to examine scaling effects. The water quality of the rivers draining forest, in the Icacos and Guab&aacute; (granitic watersheds) and Mameyes (a volcaniclastic watershed), show little contamination by human activities. The water is well oxygenated and has a nearly neutral pH, and nutrient concentrations are low. Concentrations of nutrients in the disturbed watersheds, the Cayagu&aacute;s (granitic rock) and Can&oacute;vanas (volcaniclastic rock), are greater than in the forested watersheds, indicating some inputs from human activities. High in-stream productivity in the Can&oacute;vanas watershed leads to occasional oxygen and calcite supersaturation and carbon dioxide undersaturation. Suspended sediment concentrations in all watersheds are low, except during major storms. Most dissolved constituents derived from bedrock weathering or atmospheric deposition (including sodium, magnesium, calcium, silica, alkalinity, and chloride) decrease in concentration with increasing runoff, reflecting dilution from increased proportions of overland or near-surface flow. Strongly bioactive constituents (dissolved organic carbon, potassium, nitrate, ammonium ion, and phosphate) commonly display increasing concentration with increasing runoff, regardless of their ultimate origin (bedrock or atmosphere). The concentrations of many of the bioactive constituents eventually decrease at runoff rates greater than 3 to 10 millimeters per hour, presumably reflecting an increased relative contribution from overland flow. Sulfate behaves like the nonbioactive constituents in the Can&oacute;vanas, Cayagu&aacute;s, and Mameyes watersheds but like a bioactive constituent in the Icacos and Guab&aacute; watersheds. Storms resulted in several anomalous sample compositions. Runoff waters from a number of storms - mostly hurricanes, but also other storms - have exceptionally high chloride concentrations, presumably resulting from windborne seasalt from the ocean, and low nitrate concentrations, reflecting a dominance of maritime air masses contributing moisture to the storms. High-potassium samples, without high chloride, are also associated with some smaller storms that followed Hurricane Georges in 1998; they are likely related to the breakdown of fallen vegetation. Finally, occasional low-silica events are observed in the Icacos and Guab&aacute; watersheds in the years prior to Hurricane Georges, but not after; this difference may be related to a change in hydrologic flow paths.

Professional Paper↗

Effects of earthworms on slopewash, surface runoff, and fine-litter transport on a humid-tropical forested hillslope in eastern Puerto Rico: Chapter G in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Rainfall, slopewash (the erosion of soil particles), surface runoff, and fine-litter transport were measured in tropical wet forest on a hillslope in the Luquillo Experimental Forest, Puerto Rico, from February 1998 until April 2000. Slopewash data were collected using Gerlach troughs at eight plots, each 2 square meters in area. Earthworms were excluded by electroshocking from four randomly selected plots. The other four (control) plots were undisturbed. During the experiment, earthworm population in the electroshocked plots was reduced by 91 percent. At the end of the experiment, the electroshocked plots had 13 percent of earthworms by count and 6 percent by biomass as compared with the control plots. Rainfall during the sampling period (793 days) was 9,143 millimeters. Mean and maximum rainfall by sampling period (mean of 16 days) were 189 and 563 millimeters, respectively. Surface runoff averaged 0.6 millimeters and 1.2 millimeters by sampling period for the control and experimental plots, equal to 0.25 and 0.48 percent of mean rainfall, respectively. Disturbance of the soil environment by removal of earthworms doubled runoff and increased the transport (erosion) of soil and organic material by a factor of 4.4. When earthworms were removed, the erosion of mineral soil (soil mass left after ashing) and the transport of fine litter were increased by a factor of 5.3 and 3.4, respectively. It is assumed that increased runoff is a function of reduced soil porosity, resulting from decreased burrowing and reworking of the soil in the absence of earthworms. The background, or undisturbed, downslope transport of soil, as determined from the control plots, was 51 kilograms per hectare and the "disturbance" rate, determined from the experimental plots, was 261 kilograms per hectare. The background rate for downslope transport of fine litter was 71 kilograms per hectare and the disturbance rate was 246 kilograms per hectare. Data from this study indicate that the reduction in soil macrofauna population, in this case, earthworms, plays a key role in increasing runoff and soil erosion and, therefore, has important implications for forest and water management.

Luquillo Experimental Forest↗

Weathering processes in the Rio Icacos and Rio Mameyes watersheds in Eastern Puerto Rico: Chapter I in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Streams draining watersheds of the two dominant lithologies (quartz diorite and volcaniclastic rock) in the Luquillo Experimental Forest of eastern Puerto Rico have very high fluxes of bedrock weathering products. The R&iacute;o Blanco quartz diorite in the Icacos watershed and the Fajardo volcaniclastic rocks in the Mameyes watershed have some of the fastest documented rates of chemical weathering of siliceous rocks in the world. Rapid weathering produces thick, highly leached saprolites in both watersheds that lie just below the soil and largely isolate subsurface biogeochemical and hydrologic processes from those in the soil. The quartz diorite bedrock in the Icacos watershed weathers spheroidally, leaving large, relatively unweathered corestones that are enveloped by slightly weathered rock layers called rindlets. The rindlets wrap around the corestones like an onionskin. Within the corestones, biotite oxidation is thought to induce the spheroidal fracturing that leads to development of rindlets; plagioclase in the rindlets dissolves, creating additional pore spaces. Near the rindlet-saprolite interface, the remaining plagioclase dissolves, hornblende dissolves to completion, and precipitation of kaolinite, gibbsite, and goethite becomes pervasive. In the saprolite, biotite weathers to kaolinite and quartz begins to dissolve. In the soil layer, both quartz and kaolinite dissolve. The volcaniclastic bedrock of the Mameyes watershed weathers even faster than the quartz diorite bedrock of the Icacos watershed, leaving thicker saprolites that are devoid of all primary minerals except quartz. The quartz content of volcaniclastic bedrock may help to control watershed geomorphology; high-quartz rocks form thick saprolites that blanket ridges. Hydrologic flow paths within the weathering profiles vary with total fluid flux, and they influence the chemistry of streams. Under low-flow conditions, the R&iacute;o Icacos and its tributaries are fed by rainfall and by groundwater from the fracture zones; during storm events, intense rainfall rapidly raises stream levels and water is flushed through the soil as shallow flow. As a result, weathering constituents that shed into streamwaters are dominated by rindlet-zone weathering processes during base flow and by soil weathering processes during stormflow. The upper reaches of the Mameyes watershed are characterized by regolith more than 35 meters thick in places that contains highly fractured rock embedded in its matrix. Weathering contributions to stream chemistry at base flow are predicted to be more spatially variable in the Mameyes watershed than in the Icacos watershed owing to the more complex subsurface weathering profile of the volcaniclastic bedrocks of the Mameyes watershed.

Professional Paper↗

The concept of entropy in landscape evolution

The concept of entropy is expressed in terms of probability of various states. Entropy treats of the distribution of energy. The principle is introduced that the most probable condition exists when energy in a river system is as uniformly distributed as may be permitted by physical constraints. From these general considerations equations for the longitudinal profiles of rivers are derived that are mathematically comparable to those observed in the field. The most probable river profiles approach the condition in which the downstream rate of production of entropy per unit mass is constant. Hydraulic equations are insufficient to determine the velocity, depths, and slopes of rivers that are themselves authors of their own hydraulic geometries. A solution becomes possible by introducing the concept that the distribution of energy tends toward the most probable. This solution leads to a theoretical definition of the hydraulic geometry of river channels that agrees closely with field observations. The most probable state for certain physical systems can also be illustrated by random-walk models. Average longitudinal profiles and drainage networks were so derived and these have the properties implied by the theory. The drainage networks derived from random walks have some of the principal properties demonstrated by the Horton analysis; specifically, the logarithms of stream length and stream numbers are proportional to stream order.

Professional Paper↗