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Characteristics of the fault damage zone From high-resolution seismic imaging along the Palos Verdes Fault, California

The distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in-situ distribution of fault damage remain limited and along-strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub-bottom profiles. The combination of high-resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi-trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

California

Near-fault amplification and ground motion variability during the 2019 Ridgecrest, California sequence

We estimate ground-motion variability near the 2019 M 7.1 Ridgecrest earthquake sequence. Accurate seismic hazard estimation requires understanding ground-motion spatial correlations, yet many studies lack the dense station coverage needed to resolve small-scale variability. The 2019 M 7.1 Ridgecrest earthquake sequence presents a unique opportunity to examine ground motions and their spatial correlations at a range of interstation distances. The permanent seismic network was augmented with hundreds of temporary stations including several fault-crossing nodal arrays. We compute the event ( δE i ) and within-event ( δW ij ) residuals from the observed peak ground velocity and peak ground acceleration data to isolate potential sources of ground-motion variability. We then compare δW ij between station pairs that record an event to understand the semivariance of the ground motion versus interstation distance. By fitting an exponential model to the semivariances, we determine a correlation range of 25 km for the Ridgecrest region. Although the exponential model fits the broad-scale increase of semivariance with interstation distance, we also observe smaller-scale trends. We find that ground motions are less correlated for station pairs that are near or across faults that ruptured during the 2019 Ridgecrest sequence. We also find large, positive median δW ij with relative values 2–3 times larger than nearby stations for individual stations’ near-fault traces. Near-fault amplification and greater ground-motion variability can delineate fault zones and may locally increase the seismic hazard.

California

Widespread anhydrite saturation in Laramide-age arc magmas of southwestern USA

Anhydrite is considered a rare mineral phase in magmas, with only ∼33 documented occurrences worldwide. However, anhydrite readily decomposes in the near-surface environment, making it difficult to recognize its former presence in rocks collected at or near Earth’s surface. In such samples, only small anhydrite inclusions fully shielded within other minerals can have survived. During a recent field trip to the southwestern USA, we sampled 17 Laramide-age (ca. 40−80 Ma) magma systems, most of which are associated with porphyry copper deposits. A systematic search for anhydrite inclusions preserved within apatite, amphibole, plagioclase, and quartz phenocrysts in ∼100 rock samples by optical microscopy and Raman spectroscopy revealed that each of these 17 magma systems was at least temporarily anhydrite-saturated. Also, most previously identified magmatic anhydrite-bearing intrusions are associated with porphyry copper deposits, and both intrusive and volcanic rocks containing magmatic anhydrite show high Sr/Y ratios. These observations suggest that anhydrite saturation and porphyry copper formation are linked via magma fractionation at high pressure. Compared to average arc magmas, anhydrite-bearing magmas are unusually oxidized and sulfur-rich and seem to also be unusually water-rich. Hence, our preferred interpretation is that magma generation and/or fractionation at high pressure promotes the formation of superhydrous and oxidized magmas, which in turn promotes high sulfur contents and ultimately the precipitation of anhydrite. The high mineralization potential of these magmas does not need to result from their high sulfur content but could be caused by other properties of high-pressure magmas.

Arizona, New Mexico

Rapid characterization of the 2025 Mw 8.8 Kamchatka, Russia earthquake

The 29 July 2025 M w 8.8 Kamchatka, Russia, earthquake was the sixth largest instrumentally recorded earthquake. This event was seismically well observed at regional and teleseismic distances, but publicly available near‐source data were sparse at the time of the event, presenting unique challenges for rapid source and impact characterization. The U.S. Geological Survey (USGS) National Earthquake Information Center provides global real‐time monitoring for earthquakes, including rapid response information products that estimate source characteristics, shaking, and the resulting impacts. We describe the USGS rapid response earthquake information products following the Kamchatka event and discuss their implications for ongoing hazards in the region. We describe potential improvements to our response workflows motivated by this event, including more rapid constraints on source geometries and the automated selection of fault geometries for finite‐fault inversions. The rapid response products together support the interpretation of a unilateral southwestward rupture with significant slip on the southwestern end of the rupture extent. The M w 8.8–9.0 event in 1952, which ruptured a comparable extent of the Kuril–Kamchatka subduction interface, has many similarities to the 2025 rupture. This illustrates that slip deficits may remain following great earthquakes and highlights the usefulness of comparative studies between historic and modern events.

Kuril-Kamchatka subduction zone

StreamStats—A quarter century of delivering web-based geospatial and hydrologic information to the public, and lessons learned

StreamStats is a U.S. Geological Survey (USGS) web application that provides streamflow statistics, such as the 1-percent annual exceedance probability peak flow, the mean flow, and the 7-day, 10-year low flow, to the public through a map-based user interface. These statistics are used in many ways, such as in the design of roads, bridges, and other structures; in delineation of floodplains for land-use zoning and setting of insurance rates; for regulatory purposes, such as the permitting of wastewater discharges; and for hydrologic and climate change studies. StreamStats was first developed for Massachusetts and released in 2001. The application provided users with the ability to obtain streamflow statistics computed from data collected at USGS streamgages and to obtain estimates of streamflow statistics for user-selected ungaged sites. Massachusetts StreamStats used geographic information system software and digital mapping to compute drainage-basin characteristics, which were then used in statistical models to estimate streamflow statistics for the user-selected sites. The statistical models were in the form of equations that were developed through a process known as regression analysis. StreamStats was the first known web application with the ability to do interactive geoprocessing. The utility of Massachusetts StreamStats was instantly apparent, leading the USGS to develop a version of StreamStats that could be implemented nationally. USGS State offices normally were required to develop custom regression equations and prepare local digital mapping data needed for implementing StreamStats for their States. Funding needed to complete this work usually was provided through cooperative agreements between the USGS and State agencies. In 2004, Idaho became the first to be released in the national version of StreamStats. By 2023, 44 States were fully implemented and six were undergoing implementation. StreamStats has undergone many modifications over the years to keep up with changes to the underlying software and to add functionality. Customized functionality and separate linked StreamStats applications were developed for several States. Meeting the high demand for additions and improvements to StreamStats while also adhering to budgetary constraints has, at times, been challenging. The StreamStats development team has identified numerous additional improvements that could be made to provide better performance and more functionality. The lessons learned from the experience of building and operating StreamStats for nearly 25 years could be relevant to others interested in pursuing efforts of a similar scale.

Circular

Three-dimensional temperature maps of the Williston Basin, USA: Implications for deep hot sedimentary and enhanced geothermal resources

As part of U.S. Geological Survey's (USGS) efforts to identify and assess geothermal energy resources of the US, a three-dimensional (3D) geologic and thermal model has been constructed for the Williston Basin, USA. The geologic model consists of all sedimentary units above the Proterozoic and Archean crystalline rock (called basement herein), with a total sedimentary thickness of up to 5 km near the basin center. Twenty-nine geologic units were mapped from interpreted formation tops from 16,465 wells. A 3D temperature model was constructed to a depth of 7 km by constructing a 3D heat flow model for the sedimentary units, followed by estimating underlying temperature using a one-dimensional (1D) analytic solution for heat flow within the underlying crystalline basement. Using the sedimentary basin model, heat flow was simulated in 3D and was calibrated using three temperature datasets: 1) 24 high-confidence static temperature logs (equilibrium thermal profiles), 2) more than15,000 drill stem test (DST) measurements from >7,000 wells, and 3) more than 45,000 bottomhole temperature (BHT) measurements from >14,000 wells. The DST and BHT datasets provide broad spatial coverage, but are lower confidence, primarily because measurements were made prior to attaining thermal equilibrium. DST and BHT measurements were binned regionally to develop representative thermal profiles that generally agree with these lower quality data (hereafter called pseudowell temperature profiles). Layer properties (primarily thermal conductivity and compaction curves) were set to best estimate values, then the heat flow model was calibrated to fit pseudowell and static temperature logs primarily by adjusting basal heat flow to approximate the overall temperature profile. Minor adjustments to thermal conductivity allowed adjusting changes in slope at lithologic contacts. Resulting maps include 3D temperature and basal (bottom of sedimentary units) heat flow estimates, which are used as input for the temperature model of the basement. The crystalline basement temperature model uses an analytic 1D solution to the heat flow equation that requires estimates of heat flow and temperature at the upper boundary (i.e., the sediment/basement contact), radiogenic heat production within the crystalline basement, and reference thermal conductivity (i.e., uncorrected for temperature). Two regions of high heat flow are identified: 1) in western North Dakota along the North American Central Plains Conductivity Anomaly and 2) in eastern Montana near the Poplar dome. Within the sedimentary column in the center of the basin of the basin, an area of approximately 100,000 km2 is predicted to have moderate- to high-temperature geothermal resources (>90 °C) under the thickest sequences of sediments. Where thick insulation and high heat flow coincide, electric-grade resources can be less than 4 km deep. Assuming a maximum feasible drilling depth of 7 km, temperatures are predicted to be as high as 175 °C. The geologic model may be used to identify strata at sufficient temperatures that may have natural permeability or that may have conditions that favor development of enhanced/engineered geothermal systems resources.

Montana, North Dakota, South Dakota

Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

Washington

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California

Landsliding follows signatures of wildfire history and vegetative regrowth in a steep coastal shrubland

Five years after the deadly and destructive 9 January 2018 Montecito debris flows (Santa Barbara County, California, USA), an atmospheric river storm on 9 January 2023 triggered widespread landsliding that affected many of the same drainages in the Santa Ynez Mountains. Using high-resolution aerial imagery, we identified >10,000 landslides over an ∼160 km 2 area. Most of the landslides were shallow (<1 m in depth) translational debris slides that initiated on steep (∼40°), south-facing hillslopes, with the highest incidence of landsliding in a sandstone-dominated bedrock unit. The landslides mobilized into debris flows and delivered substantial quantities of sediment downstream, which contributed to costly infrastructure impairments. We detected order-of-magnitude differences in landslide density across the study area that could not be attributed to variations in geomorphology (topographic aspect and slope), geology (bedrock type), or hydrology (seasonal antecedent rainfall, peak hourly storm rainfall intensity, total storm rainfall), which are usually considered relevant factors for shallow landsliding. Rather, we found that vegetation regrowth following wildfire was likely a relevant factor associated with the highly variable landslide densities. Hillslopes with less and different types of vegetation regrowth after fire appear to have been more susceptible to shallow landslides. We identify a possible vegetation control on postfire landsliding, which highlights an opportunity for hypothesis testing using more advanced techniques to track the evolution of vegetation cover and vegetation type in steep shrubland environments following wildfire.

California

Site response and wave propagation effects in the eastern United States

Fourier amplitude spectra from regional earthquakes in the eastern United States are used in a parametric inversion for source, path, and site effects. Five earthquakes are selected for analysis during the installation of the United States National Seismic Network (US), Earthscope’s USArray Transportable Array (TA), and other temporary arrays to maximize station coverage. A global search algorithm is used to solve for site response from 0.1 to 15 Hz, corner frequency, geometrical spreading ( r - γ ), and frequency dependent anelastic attenuation in the form Q(f) = Q o f α . Tradeoff between moment and geometric spreading is handled by fixing the moment. The tradeoff between corner frequency and Q(f) is solved by selecting the value of corner frequency that minimizes an objective function defined over all stations. Values of site response and attenuation parameters show a strong spatial correlation with the physiographic provinces of the eastern United States. Site response for the Atlantic Coastal Plain is consistent with previous work using spectral ratios relative to a reference site, defined by strong resonance peaks correlated with the thickness of sediments. Site response for the other physiographic provinces is markedly different from the coastal plain, with a lack of distinct resonance peaks and a broad moderate high at frequences from 0.1 to 0.5 Hz consistent with the hard-rock geology of the regions. Like site response, Q(f) has a strong correlation with physiographic province, showing lower values on the coastal plain and higher values inland. Geometric spreading exponent, γ, decreases with increasing hypocenter distance from just above 1 at a few tens of kilometers to 0.9 at 500 km. The limited range in geometric spreading values is attributed to starting the Fourier transform window at the S ‐wave arrival for all distances and averaging over multiple wave types.

eastern United States

Development of liquefaction-targeted design basis in U.S. seismic provisions

Seismic design criteria for new buildings in the United States have historically focused on life safety performance objectives through minimizing the potential for structural collapse. Development of design criteria to meet this performance objective has evolved over time, leading to the current, risk-targeted maximum considered earthquake (MCE R ) design basis. Corresponding MCE R seismic design loads incorporate the full range of probabilistic ground motion hazard information available from U.S. Geological Survey National Seismic Hazard Models, as well as a representation of the uncertainty in structural collapse capacity. Despite these considerable advances in structural design criteria, guidelines for geotechnical hazards such as liquefaction-induced damage, which continue to be based on uniform ground-shaking hazard (i.e., MCE ground motions), are not well-connected with risk-based, collapse prevention performance objectives. This study, undertaken as part of Building Seismic Safety Council efforts to update recommended seismic provisions through the National Earthquake Hazards Reduction Program, presents probabilistic, liquefaction-targeted design objectives and corresponding ground motion parameters, with a focus on improving consistency in first-level screening criteria for liquefaction hazard assessment. This study identifies a potential maximum acceptable annualized probability of liquefaction triggering ( P L,max ) of 2.5% in 50 years, above which liquefaction consequences and potential mitigation measures would be considered. The P L,max -based design basis is calibrated to effective probabilistic liquefaction hazard levels obtained in practice using current MCE peak ground accelerations, and could be implemented via a new liquefaction-targeted maximum considered earthquake (MCE L ) peak ground acceleration ( PGA L ). The proposed PGA L is derived from probabilistic liquefaction hazard curves and includes uncertainties inherent to liquefaction hazard modeling. The potential design effects of the proposed PGA L are demonstrated via comparison with current MCE PGA levels, effects on first-level liquefaction screening analyses, and improvements in the consistency of P L,max levels across the United States, and for a wide range of site conditions.

conterminous United States

Geology and geochemistry of Jurassic plutonic rocks, Baboquivari Mountains, south-central Arizona

Among the plutons of the Jurassic magmatic arc segment in southern Arizona, northern Sonora, and southern California, two distinctive rock types dominate, occurring together in numerous mountain ranges: porphyritic, titanite-bearing hornblende-biotite granodiorite; and biotite leucogranite. These characteristic rocks are particularly well preserved and well exposed around Kitt Peak, in the Baboquivari Mountains, southern Arizona. The Middle to early Late Jurassic Kitt Peak Plutonic Suite (KPPS) comprises three units: Aguirre Peak Quartz Diorite (APQD;<170 Ma, >=165 Ma, U-Pb), chiefly hornblende mesodiorite; Kitt Peak Granodiorite (KPGD; 165 Ma), hornblende-biotite granodiorite and monzogranite; and Pavo Kug Granite (PKG; 159 Ma), equigranular biotite leucogranite. This range also hosts a fourth, regionally unusual, Jurassic plutonic unit: the Baboquivari Peak Perthite Granite, related to post-arc, Late Jurassic crustal extension. Binary variation diagrams, incompatible element patterns, and REE spectra indicate APQD and KPGD are consanguineous. APQD basaltic mesodiorite evidently approximates the parental magma for the APQD–KPGD series. More evolved rocks of this series evidently formed by combinations of fractional crystallization and mixing with or assimilation of crustal material. PKG is less directly related to APQD and KPGD than these two are to one another.

Arizona, Sonora

Numerical modeling of Late Pleistocene to Holocene earthquake-induced progressive rock slope damage in the paraglacial Serpentine valley, Prince William Sound, Alaska

Landslides in deglaciating fjords pose a potential tsunami threat to nearby communities; however, processes contributing to long-term progressive rock damage and landslide conditioning remain poorly constrained in paraglacial settings. Here, we analyse the role of earthquake-induced rock mass damage over late Pleistocene to Holocene time scales, as a conditioning factor for modern landslides, using distinct element numerical modelling to assess spatial and temporal patterns of fracture propagation influenced by varying glacier thickness. Conceptualised numerical models were parameterised by in situ rock mass, glacial and topographic conditions in Serpentine valley, located in Prince William Sound, Alaska, where several large landslides are actively developing along the western valley wall. Results show that although rigid glacier buttressing reduces co-seismic rock mass damage, it does not suppress it completely, and damage occurs both above and below the glacier surface elevation. We demonstrate that topography, and especially steep slopes with topographic convexity, as well as preexisting damage of joint networks and faults inherited from tectonic and exhumation induced stresses, exert primary control on the location of new co-seismic damage. Simulations representing a simplified deglaciation sequence over the past 25 ka, with a series of 10 evenly spaced earthquakes, generated rock mass damage patterns that qualitatively match in situ landslide structural and kinematic observations at one instability in Serpentine valley. Our conceptual study helps clarify the role of repeated seismicity over glacial timescales as a long-term conditioning process for paraglacial rock slope failure, highlighting spatial and temporal patterns of progressive damage accumulation, with outcomes relevant for modern landslide hazard assessment.

Alaska

Sand provenance boundary in the Mu Us Sandy Land of northern China

Desert dunes are often assumed to have uniform mineral compositions due to extensive mixing during lateral transport, which complicates provenance studies. The Mu Us Sandy Land in north-central China, near the East Asian summer monsoon precipitation boundary, experiences a wetter climate than most deserts. Climate wetting as a result of a warming climate, and the ‘Sand Control Project’ implemented by the Chinese government to decrease the lateral movement of sand dunes in this area provide an opportunity to study surface processes of sand production and transport. Previous studies using zircon U Pb geochronology and heavy mineral composition indicate distinct sand sources for the Mu Us Sandy Land: local basement-derived middle Yellow River sediments and recycled dried-up lacustrine sediments for the eastern part, and northeastern Tibetan Plateau-derived upper Yellow River sediments for the western part. However, zircons and heavy minerals only represent trace amounts of the bulk mineralogy within a sand dune, so broader provenance analysis targeting common minerals is essential. We focus on the area near the proposed provenance difference boundary between the western and eastern Mu Us Sandy Land, using comprehensive sampling and provenance techniques to confirm distinct provenance characteristics and delineate the provenance boundary. Our findings reveal that sand from most of the Mu Us Sandy Land originated from the erosion of local basement by the middle Yellow River and recycled local dried-up lacustrine sediments, whereas the southwestern corner and the neighboring western-central Chinese Loess Plateau received sediments from the distal northeastern Tibetan Plateau.

Mu Us Sandy Land

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho

Critical minerals in orogenic (gold) and Coeur d’Alene-type mineral systems of the United States

Orogenic and Coeur d’Alene-type mineral systems are produced by metamorphic devolatilization of thick volcanic or siliciclastic sedimentary rock sequences and the focused flow of hydrothermal fluids upwards along crustal-scale faults. Most orogenic systems are found along the Cordilleran orogen, stretching from California northwards into Alaska, whereas most Coeur d’Alene-type systems occur in the Proterozoic Belt Basin in Idaho and Montana. Although the deposit types in these systems are exploited for precious and base metals, potential exists for the production of critical minerals necessary for current (2025) societal needs in the United States. Publicly available geochemical data compiled for these mineral systems, coupled with mineralogical characteristics, indicate that several critical minerals could potentially be recovered from unmined resources and processed mine waste: arsenic, antimony, tellurium, cobalt, and tungsten from orogenic gold deposits and zinc, antimony, arsenic, and manganese from Coeur d’Alene-type systems. These critical minerals reside primarily in arsenopyrite (arsenic), scheelite (tungsten), siderite (manganese), sphalerite (zinc), tetrahedrite (antimony and arsenic), stibnite (antimony), and telluride (tellurium) minerals.

continental United States