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At least 1,171 records · Page 65Linked to original sources

Prevalence and potential for biological effects of several chemicals of interest in Lake Superior tributaries

Lake Superior is typically assumed to have excellent water quality, but its tributaries have been understudied for contaminants relative to other Great Lakes. This study monitored polycyclic aromatic hydrocarbons (PAHs), alkylphenols (AP) and alkylphenol ethoxylates (APEs), bisphenols, and neonicotinoid pesticides in 18 sites on 17 United States tributaries to Lake Superior in 2022. Contaminants were analyzed from 54 surface water and 17 stream bed sediment samples. PAHs were the most prevalent contaminant class. Among 17 PAHs in 17 samples (289 instances), 71 % were positive detections. Surface water samples were not analyzed for PAHs. Next, among 4 APs and APEs analyzed, 35 % of sediment sample instances and 21 % of instances in 54 water samples were positive detections. Bisphenol analogues were detected in 2 % of sediment sample instances and 4 % of water sample instances. Bisphenol A (BPA) was not quantified due to field blank contamination, but bisphenol AF (BPAF), bisphenol E (BPE), bisphenol F (BPF), and bisphenol S (BPS) were detected in environmental samples. Neonicotinoids were detected in 0.5 % of sediment sample instances and 0.4% of water samples instances. Low detection frequencies for contaminants precluded analyses with watershed land use characteristics, but four sites (Tischer Creek, Miller Creek, Carp River and Iron River) emerged as locations with relatively elevated contaminant concentrations. Comparison of concentrations with ToxCast and other water quality guidelines suggested potential for biological effects from some samples. This study provides a baseline of low contaminant prevalence in Lake Superior tributaries while identifying a few locations that may warrant further monitoring.

Michigan, Minnesota, Wisconsin↗

Drainage effects on stream nitrate-N and hydrology in south-central Minnesota (USA)

Excessive nitrate-N in south-central Minnesota ditches and streams is related to land-use change, and may be contributing to the development of the zone of hypoxia in the Gulf of Mexico. Intensive land-use (agricultural management) has progressively increased as subsurface drainage has improved crop productivity over the past 25 years. We have examined water at varying scales for ??18O and, nitrate-N concentrations. Additionally, analysis of annual peak flows, and channel geomorphic features provided a measure of hydrologic change. Laboratory and field results indicate that agricultural drainage has influenced riverine source waters, concentrations of nitrate-N, channel dimensions and hydrology in the Blue Earth River (BER) Basin. At the mouth of the BER shallow ground water comprises the largest source water component. The highest nitrate-N concentrations in the BER and tributaries typically occurred in May and June and ranged from 7-34 mg L-1. Peak flows for the 1.01-2-yr recurrence intervals increased by 20-to-206% over the past 25 years. Geomorphic data suggest that small channels (ditches) were entrenched by design, whereas, natural channels incised. Increased frequent peak flows in the BER have created laterally confined channels that are disconnected from an accessible riparian corridor. Frequent access to a functioning riparian zone is important for denitrification.

Environmental Monitoring and Assessment↗

Water-resources investigations in Wisconsin: Programs and activities of the U.S. Geological Survey, 1991-92

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for: regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for water-quality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in "Water Resources Data Wisconsin."

Wisconsin↗

Water-resources investigations in Wisconsin, 1993

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development. An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for: regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for water-quality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in "Water Resources Data Wisconsin."

Wisconsin↗

Water-resources investigations in Wisconsin

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development. An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also LOCATION: Statewide PROJECT CHIEF: Barry K. Holmstrom PERIOD OF PROJECT: July 1913-Continuing designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for waterquality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in the report "Water Resources Data-Wisconsin."

Wisconsin↗

Using CO 2 Prophet to estimate recovery factors for carbon dioxide enhanced oil recovery

Introduction The Oil and Gas Journal’s enhanced oil recovery (EOR) survey for 2014 (Koottungal, 2014) showed that gas injection is the most frequently applied method of EOR in the United States and that carbon dioxide (CO 2 ) is the most commonly used injection fluid for miscible operations. The CO 2 -EOR process typically follows primary and secondary (waterflood) phases of oil reservoir development. The common objective of implementing a CO 2 -EOR program is to produce oil that remains after the economic limit of waterflood recovery is reached. Under conditions of miscibility or multicontact miscibility, the injected CO 2 partitions between the gas and liquid CO2 phases, swells the oil, and reduces the viscosity of the residual oil so that the lighter fractions of the oil vaporize and mix with the CO 2 gas phase (Teletzke and others, 2005). Miscibility occurs when the reservoir pressure is at least at the minimum miscibility pressure (MMP). The MMP depends, in turn, on oil composition, impurities of the CO 2 injection stream, and reservoir temperature. At pressures below the MMP, component partitioning, oil swelling, and viscosity reduction occur, but the efficiency is increasingly reduced as the pressure falls farther below the MMP. CO 2 -EOR processes are applied at the reservoir level, where a reservoir is defined as an underground formation containing an individual and separate pool of producible hydrocarbons that is confined by impermeable rock or water barriers and is characterized by a single natural pressure system. A field may consist of a single reservoir or multiple reservoirs that are not in communication but which may be associated with or related to a single structural or stratigraphic feature (U.S. Energy Information Administration [EIA], 2000). The purpose of modeling the CO 2 -EOR process is discussed along with the potential CO 2 -EOR predictive models. The data demands of models and the scope of the assessments require tradeoffs between reservoir-specific data that can be assembled and simplifying assumptions that allow assignment of default values for some reservoir parameters. These issues are discussed in the context of the CO 2 Prophet EOR model, and their resolution is demonstrated with the computation of recovery-factor estimates for CO 2 -EOR of 143 reservoirs in the Powder River Basin Province in southeastern Montana and northeastern Wyoming.

Scientific Investigations Report↗

Flow of variably fluidized granular masses across three-dimensional terrain 2. Numerical predictions and experimental tests

Numerical solutions of the equations describing flow of variably fluidized Coulomb mixtures predict key features of dry granular avalanches and water-saturated debris flows measured in physical experiments. These features include time-dependent speeds, depths, and widths of flows as well as the geometry of resulting deposits. Threedimensional (3-D) boundary surfaces strongly influence flow dynamics because transverse shearing and cross-stream momentum transport occur where topography obstructs or redirects motion. Consequent energy dissipation can cause local deceleration and deposition, even on steep slopes. Velocities of surge fronts and other discontinuities that develop as flows cross 3-D terrain are predicted accurately by using a Riemann solution algorithm. The algorithm employs a gravity wave speed that accounts for different intensities of lateral stress transfer in regions of extending and compressing flow and in regions with different degrees of fluidization. Field observations and experiments indicate that flows in which fluid plays a significant role typically have high-friction margins with weaker interiors partly fluidized by pore pressure. Interaction of the strong perimeter and weak interior produces relatively steep-sided, flat-topped deposits. To simulate these effects, we compute pore pressure distributions using an advection-diffusion model with enhanced diffusivity near flow margins. Although challenges remain in evaluating pore pressure distributions in diverse geophysical flows, Riemann solutions of the depthaveraged 3-D Coulomb mixture equations provide a powerful tool for interpreting and predicting flow behavior. They provide a means of modeling debris flows, rock avalanches, pyroclastic flows, and related phenomena without invoking and calibrating Theological parameters that have questionable physical significance.

Journal of Geophysical Research B: Solid Earth↗

Geology and ground-water resources of Laramie County, Wyoming

Laramie County, an area of 2,709 square miles, is in the southeast corner of Wyoming. Rocks exposed there range in age from Precambrian to Recent. The most extensive aquifers in the county are the White River Formation of Oligocene age, which is as much as 500 feet thick and consists predominantly of siltstone ; the Arikaree Formation of Miocene age, which consists of as much as 450 feet of very fine grained to fine-grained sandstone; and the Ogallala Formation of Miocene and Pliocene age, which consists ,of as much as 330 feet of gravel, sand, silt, and some cobbles and boulders. These formations are capable of yielding large ,supplies of water locally. Terrace deposits of Quaternary age yield moderate .to large supplies of water in the southeastern and northeastern parts of the county. In the Federal well field, large yields of water from the White River Formation are obtained from gravel lenses. In the eastern part of the county near Pine Bluffs, large yields are obtained from openings in .the siltstone of the White River. Previous investigators reported that the large yields were obtained in areas where the formation is fractured and fissured. The authors of this report believe that .the large yields from siltstone in the White River Formation are from pipes, sometimes called natural tunnels, rather than from fractures ,or fissures. Little is known about the water-bearing properties of the pro-Tertiary aquifers in the county, but water derived from the pro-Tertiary formations would probably be of poor quality, except in the vicinity of the outcrop near the western edge of the county. Precipitation is the principal source of recharge to the ground-water reservoirs. About 5 percent of the annual precipitation, or about 108,400 acre-feet per year, is estimated to be recharged. Only a small amount of additional recharge is from streams. The general movement of ground water is eastward, and the average gradient of the water table is about 40 feet per mile. The total amount ,of ground water pumped from wells in Laramie County during 1964 is estimated to be 28,000 acre-feet; about 6,000 acre-feet was used for municipal and industrial supplies, about 17,000 acre-feet was used for irrigation in the Pine Bluffs-Carpenter area, and about 5,000 acre-feet was used for other purposes. The balance of the recharge (80,400 acre-feet) is estimated to be discharged by the following means: 20 percent by underflow, 20 percent by streamflow, and 60 percent by evapotranspiration. The coefficient of transmissibility of the Ogallala Formation, determined by averaging data from 28 pumping tests made in the Cheyenne municipal well field, is about 16,000 gallons per day per foot. However, this figure is an average of the more permeable zones, and the average coefficient of transmissibility of the Ogallala in the county is probably much less because of the heterogeneous character of the formation. A coefficient of transmissibility of 3,800 gallons per day per foot was calculated for the Ogallala, in the same vicinity that the pumping tests were made, by using a regional method of analysis. Although the average transmissibility of the Ogallala is considered to be low, large yields are obtained from gravel stringers and lenses in the formation. The maximum perennial yield from the Cheyenne well field is estimated to be about 1.6 billion gallons per year. Moderate to large yields of water can be obtained in the north-central part of the county where the saturated thickness of the Arikaree Formation, or combined Arikaree and Ogallala Formations, is 200 feet or more. Ground water has been developed throughout the county, but development has been intensive only in the Cheyenne municipal well fields near Cheyenne and Federal and in the Pine Bluffs lowland. The water level has been lowered as much as 40 feet in the Cheyenne well field and somewhat less in the Federal well field.

Wyoming↗

The gap between experts, farmers and non-farmers on perceived environmental vulnerability and the influence of values and beliefs

Science has played a mixed role in guiding conservation and sustainability-oriented decision-making by individuals, policymakers, institutions, and governments. Not all science-based conservation and sustainability initiatives that address issues facing humanity and ecosystems and global problems have gained public support. Conservation decisions and policy prescriptions are and may be based on perceptions about and experiences with the environment, local land use, and ecosystems that may not align with or be grounded in science or evidence from experts in the field. Values, beliefs, and perceptions associated with nature play a critical role in how individuals view biodiversity conservation, sustainability, and natural resource management . This study first examines the gap between experts (scientists and other field experts) and the public (farmers and non-farmers) about the state of water and land resources, wildlife and associated habitats, and aquatic biodiversity in the Smoky Hill River Watershed in western Kansas. Second, the study examines the role that values and beliefs play in shaping environmental perceptions for farmers and non-farmers. Analysis confirms that a gap between experts and farmers/non-farmers does exist, especially with respect to the state of the Ogallala Aquifer, playas, rivers and streams, lakes and reservoirs, native grasslands, wildlife habitats, farmland, native fish populations, and wildlife species. Ordered-logistic regression analyses, meanwhile, indicate that farmer and non-farmer perceptions about the state of the local environment are influenced by traditional and self-interested values, as well as environmental values and beliefs, but less so by religiosity and political ideology. Despite broad takeaways, results exhibited heterogeneity across the farmer and non-farmer subpopulations. If environmental professionals cannot align ecological data, stakeholders’ values/perceptions, and policies, then the existing body of technical research and management on sustainability in natural and social sciences may be of little value.

Journal of Environmental Management↗

Simulation of ground-water flow in coastal Georgia and adjacent parts of South Carolina and Florida-predevelopment, 1980, and 2000

A digital model was developed to simulate steady-state ground-water flow in a 42,155-square-mile area of coastal Georgia and adjacent parts of South Carolina and Florida. The model was developed to (1) understand and refine the conceptual model of regional ground-water flow, (2) serve as a framework for the development of digital subregional ground-water flow and solute-transport models, and (3) serve as a tool for future evaluations of hypothetical pumping scenarios used to facilitate water management in the coastal area. Single-density ground-water flow was simulated using the U.S. Geological Survey finite-difference code MODFLOW-2000 for mean-annual conditions during predevelopment (pre?1900) and the years 1980 and 2000. The model comprises seven layers: the surficial aquifer system, the Brunswick aquifer system, the Upper Floridan aquifer, the Lower Floridan aquifer, and the intervening confining units. A combination of boundary conditions was applied, including a general-head boundary condition on the top active cells of the model and a time-variable fixed-head boundary condition along part of the southern lateral boundary. Simulated heads for 1980 and 2000 conditions indicate a good match to observed values, based on a plus-or-minus 10-foot (ft) calibration target and calibration statistics. The root-mean square of residual water levels for the Upper Floridan aquifer was 13.0 ft for the 1980 calibration and 9.94 ft for the 2000 calibration. Some spatial patterns of residuals were indicated for the 1980 and 2000 simulations, and are likely a result of model-grid cell size and insufficiently detailed hydraulic-property and pumpage data in some areas. Simulated potentiometric surfaces for predevelopment, 1980, and 2000 conditions all show major flow system features that are indicated by estimated peotentiometric maps. During 1980?2000, simulated water levels at the centers of pumping at Savannah and Brunswick rose more than 20 ft and 8 ft, respectively, in response to decreased pumping. Simulated drawdown exceeded 10 ft in the Upper Floridan aquifer across much of the western half of the model area, with drawdown exceeding 20 ft along parts of the western, northern, and southern boundaries where irrigation pumping increased during this period. From predevelopment to 2000 conditions, the simulated water budget showed an increase in inflow from, and decrease in outflow to, the general-head boundaries, and a reversal from net seaward flow to net landward flow across the coastline. Simulated changes in recharge and discharge distribution from predevelopment to 2000 conditions showed an increase in extent and magnitude of net recharge cells in the northern part of the model area, and a decrease in discharge or change to recharge in cells containing major streams and beneath major pumping centers. The model is relatively sensitive to pumping and the controlling head at the fixed-head boundary and less sensitive to the distribution of aquifer properties in general. Model limitations include: (1) its spatial scale and discretization, (2) the extent to which data are available to physically define the flow system, (3) the type of boundary conditions and controlling parameters used, (4) uncertainty in the distribution of pumping, and (5) uncertainty in field-scale hydraulic properties. The model could be improved with more accurate estimates of ground-water pumpage and better characterization of recharge and discharge.

Florida, Georgia, South Carolina↗

Use of Doppler velocity radars to monitor and predict debris and flood wave velocities and travel times in post-wildfire basins

The magnitude and timing of extreme events such as debris and floodflows (collectively referred to as floodflows) in post-wildfire basins are difficult to measure and are even more difficult to predict. To address this challenge, a sensor ensemble consisting of noncontact, ground-based (near-field), Doppler velocity (velocity) and pulsed (stage or gage height) radars, rain gages, and a redundant radio communication network was leveraged to monitor flood wave velocities, to validate travel times, and to compliment observations from NEXRAD weather radar. The sensor ensemble (DEbris and Floodflow Early warNing System, DEFENS) was deployed in Waldo Canyon, Pike National Forest, Colorado, USA, which was burned entirely (100 percent burned) by the Waldo Canyon fire during the summer of 2012 ( MTBS, 2020 ). Surface velocity, stage, and precipitation time series collected during the DEFENS deployment on 10 August 2015 were used to monitor and predict flood wave velocities and travel times as a function of stream discharge (discharge; streamflow). The 10 August 2015 event exhibited spatial and temporal variations in rainfall intensity and duration that resulted in a discharge equal to 5.01 cubic meters per second (m 3 /s). Discharge was estimated post-event using a slope-conveyance indirect discharge method and was verified using velocity radars and the probability concept algorithm. Mean flood wave velocities – represented by the kinematic celerity ( c k = 2.619 m e t e r s p e r s e c o n d , m / s ± 0.556 p e r c e n t "> 𝑐 𝑘 = 2.619 𝑚𝑒𝑡𝑒𝑟𝑠 𝑝𝑒𝑟 𝑠𝑒𝑐𝑜𝑛𝑑, m/s ± 0.556 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and dynamic celerity ( c d = 3.533 m / s ± 0.181 p e r c e n t a n d t h e i r u n c e r t a i n t i e s "> 𝑐 𝑑 = 3.533 m/s ± 0.181 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and their uncertainties were computed. L-moments were computed to establish probability density functions (PDFs) and associated statistics for each of the at-a-section hydraulic parameters to serve as a workflow for implementing alert networks in hydrologically similar basins that lack data. Measured flood wave velocities and travel times agreed well with predicted values. Absolute percent differences between predicted and measured flood wave velocities ranged from 1.6 percent to 49 percent and varied with water slope, hydraulic radius, and depth. The kinematic celerity was a better predictor for steep slopes and wide flood plains associated with the Upper Waldo and Middle Waldo radar streamgages; whereas, the dynamic celerity was a better surrogate for shallow slopes and incised channels such as the Lower Waldo radar streamgage. The method demonstrates the potential extensibility of a post-wildfire warning system by (1) leveraging multiple systems (i.e., weather radar, near-field velocity and stage radars, and rain gages) for accurate and timely warnings of debris and floodflows, (2) establishing an order of operations to site, install, and operate near-field radars and conventional rain gages to record floodflows, forecast travel times, and document geomorphic change in this basin and hydrologically similar basins that lack data, and (3) communicating data operationally with the Colorado Department of Transportation engineering staff, National Weather Service forecasters, and emergency managers.

Colorado↗

Validating morphometrics as a nonlethal tool to determine Arctic Grayling sex

Objective Some graylings Thymallus spp. possess an elongated dorsal fin and other morphological traits that can be sexually dimorphic, as demonstrated in the European Grayling T. thymallu s. North American Arctic Grayling T. arcticus are assumed to follow these trends, but decisive evidence is lacking. This study aimed to determine whether sexually dimorphic characteristics, including posterior dorsal height, can be used to accurately predict the sex of Arctic Grayling in Interior Alaska. Methods We used computer imaging software to measure 22 morphometrics on 97 Arctic Grayling of known sex from streams in Interior Alaska, and we developed a set of binomial models to evaluate the validity of morphometrics as predictors of Arctic Grayling sex. Result Posterior dorsal height was a reasonably accurate predictor of sex (~90% accurate at fork lengths ≥300 mm), although models containing additional morphometrics were more accurate (100% accuracy at fork lengths ≥250 mm). Conclusion This study presents an affordable, noninvasive, and replicable method for nonlethal determination of Arctic Grayling sex by using digital images from the field, with potential application to other salmonids.

North American Journal of Fisheries Management↗

New insights on scale-dependent surface-groundwater exchange from a floating self-potential Dipole

In south-central Texas the lower Guadalupe River has incised into the outcrop of the Carrizo-Wilcox aquifer. The river and the aquifer are hydraulically connected across the outcrop, although the connectivity is obscured at the surface by alluvium and surface-water and groundwater exchange dynamics are currently poorly understood. To investigate surface-water and groundwater exchange dynamics between the lower Guadalupe River and the Carrizo-Wilcox aquifer, a geophysical study was completed along a 14.86 km reach of the river by using water-borne gradient self-potential (SP) profiling and two-dimensional direct-current electric resistivity tomography. This paper explores the applicability of these water-borne geoelectric methods in delineating gaining and losing channel reaches, and demonstrates that geoelectric signals in the form of total electric field strength can be logged with an electric dipole and decomposed into component SP signals depicting regional and local groundwater flow patterns attributable to regional and localized hydraulic gradients. Localized SP anomalies of several tens of millivolts, indicative of hyporheic exchange flows, are observed and superimposed upon a 124 mV regional SP anomaly indicative of ambient groundwater exchange flows between the river and the aquifer. The observed SP signals are interpreted through two-dimensional finite-element modeling of streaming potentials attributable to ambient groundwater exchange and hyporheic exchange flow patterns. Variables of the channel environment such as temperature and concentration gradients, depth, and velocity are considered and subsequently eliminated as alternative sources of the SP signals that are presented.

Texas↗

Field and Laboratory Data From an Earthquake History Study of Scarps in the Hanging Wall of the Tacoma Fault, Mason and Pierce Counties, Washington

As part of the effort to assess seismic hazard in the Puget Sound region, we map fault scarps on Airborne Laser Swath Mapping (ALSM, an application of LiDAR) imagery (with 2.5-m elevation contours on 1:4,000-scale maps) and show field and laboratory data from backhoe trenches across the scarps that are being used to develop a latest Pleistocene and Holocene history of large earthquakes on the Tacoma fault. We supplement previous Tacoma fault paleoseismic studies with data from five trenches on the hanging wall of the fault. In a new trench across the Catfish Lake scarp, broad folding of more tightly folded glacial sediment does not predate 4.3 ka because detrital charcoal of this age was found in stream-channel sand in the trench beneath the crest of the scarp. A post-4.3-ka age for scarp folding is consistent with previously identified uplift across the fault during AD 770-1160. In the trench across the younger of the two Stansberry Lake scarps, six maximum 14C ages on detrital charcoal in pre-faulting B and C soil horizons and three minimum ages on a tree root in post-faulting colluvium, limit a single oblique-slip (right-lateral) surface faulting event to AD 410-990. Stratigraphy and sedimentary structures in the trench across the older scarp at the same site show eroded glacial sediments, probably cut by a meltwater channel, with no evidence of post-glacial deformation. At the northeast end of the Sunset Beach scarps, charcoal ages in two trenches across graben-forming scarps give a close maximum age of 1.3 ka for graben formation. The ages that best limit the time of faulting and folding in each of the trenches are consistent with the time of the large regional earthquake in southern Puget Sound about AD 900-930.

Scientific Investigations Map↗

Occurrence of Agricultural Chemicals in Shallow Ground Water and the Unsaturated Zone, Northeast Nebraska Glacial Till, 2002-04

Agricultural chemicals applied at the land surface in northeast Nebraska can move downward, past the crop root zone, to ground water. Because agricultural chemicals applied at the land surface are more likely to be observed in the shallowest part of an aquifer, an assessment of shallow ground-water and unsaturated zone quality in the northeast Nebraska glacial till was completed between 2002 and 2004. Ground-water samples were collected at the first occurrence of ground water or just below the water table at 32 sites located in areas likely affected by agriculture. Four of the 32 sites were situated along a ground-water flow path with its downgradient end next to Maple Creek. Twenty-eight sites were installed immediately adjacent to agricultural fields throughout the glacial-till area. In addition to those 32 sites, two sites were installed in pastures to represent ground-water conditions in a non-cropland setting. Ground-water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, selected pesticides and pesticide degradates, dissolved solids, major ions, trace elements, and dissolved organic carbon. Chlorofluorocarbons (CFCs) or sulfur hexafluoride (SF6) concentrations were analyzed at about 70 percent of the monitoring wells to estimate the residence time of ground water. Borehole-core samples were collected from 28 of the well boreholes. Sediment in the unsaturated zone was analyzed for nitrate, chloride, and ammonia concentrations. Analytical results indicated that the agricultural chemicals most often detected during this study were nitrates and herbicides. Nitrate as nitrogen (nitrate-N) concentrations (2003 median 9.53 milligrams per liter) indicated that human activity has affected the water quality of recently recharged ground water in approximately two-thirds of the wells near corn and soybean fields. The principal pesticide compounds that were detected reflect the most-used pesticides in the area and included parent or degradate compounds of acetochlor, alachlor, atrazine, and metolachlor. Overall, pesticide concentrations in ground-water samples collected in 2003 and 2004 were small and did not exceed public drinking-water standards where established. On average, more pesticides were detected in the flow-path wells than in the glacial-till network wells. The presence of a perennial stream within 1,640 feet of a well was correlated to smaller nitrate-N concentrations in the well water, and the presence of a road ditch within 164 feet of the well was correlated to the presence of detectable pesticides in the well water. All other variables tested showed no significant correlations to nitrate-N concentrations or pesticide detections. Unsaturated zone soil cores collected in 2002 from well boreholes indicated that nitrogen in the forms of nitrate-N and ammonia as nitrogen (ammonia-N) was available in the unsaturated zone for transport to ground water. Concentrations of nitrate-N and ammonia-N in these soil cores were inversely correlated to depth, and nitrate-N concentrations were correlated to chloride concentrations.

Scientific Investigations Report↗

Heterozygosity and fitness: No strong association in Great Lakes populations of the zebra mussel, Dreissena Polymorpha (Pallas)

A number of studies have found positive associations between allozyme heterozygosity and fitness surrogates (e.g., body size and growth rate) for marine molluscs. We investigated whether similar relationships exist for freshwater populations of the zebra mussel, Dreissena polymorpha. Only one significant correlation between multi-locus heterozygosity and shell length was observed for a total of 22 D. polymorpha populations surveyed from midwestern U.S.A. lakes and streams, and the result was not significant on a table-wide basis. Meta-analysis revealed a significant common correlation coefficient (effect magnitude) between multi-locus heterozygosity and shell length across all 22 sites (rc = 0.052, P = 0.019, 1557 df). However, the variance in shell length explained by multi-locus heterozygosity was small (rc2 = 0.0027), implying a weak causal relationship if any. Also, we saw no relationship between heterozygosity and growth rate in a one-year field enclosure experiment. A significant heterozygosity-shell length correlation previously reported for a zebra mussel population at Put-in-Bay, Lake Erie, Ohio, may have been the product of unique population dynamics, rather than natural selection. Similar demographic considerations may contribute to inconsistencies in heterozygosity-fitness correlations seen for other molluscs.

Malacologia↗

Influence of light and temperature on Prochlorococcus ecotype distributions in the Atlantic Ocean

In a focused analysis of Prochlorococcus population structure in the western North Atlantic, we found that the relative abundances of ecotypes varied significantly with depth and, at seasonally stratified locations, with degree of vertical mixing. More limited regional variation was observed (e.g., Sargasso Sea, Gulf Stream, continental slope, and equatorial current), and local patchiness was minimal. Modeling of a combined North and South Atlantic data set revealed significant, independent effects of light and temperature on ecotype abundances, suggesting that they are key ecological determinants that establish the different habitat ranges of the physiologically and genetically distinct ecotypes. This was in sharp contrast with the genus Synechococcus, whose total abundance was related to light but did not vary in a predictable way with temperature. Comparisons of field abundances with growth characteristics of cultured isolates of Prochlorococcus suggested the presence of ecotype-specific thermal and light adaptations that could be responsible for the distinct distribution patterns of the four dominant ecotypes. Significantly, we discovered that one "low-light-adapted" ecotype, eNATL2A, can thrive in deeply mixed surface layers, whereas another, eMIT9313, cannot, even though they have the same growth optimum for (low) light. ?? 2007, by the American Society of Limnology and Oceanography, Inc.

Limnology and Oceanography↗

A novel approach to assessing natural resource injury with Bayesian networks

Quantifying the effects of environmental stressors on natural resources is problematic because of complex interactions among environmental factors that influence endpoints of interest. This complexity, coupled with data limitations, propagates uncertainty that can make it difficult to causally associate specific environmental stressors with injury endpoints. The Natural Resource Damage Assessment and Restoration (NRDAR) regulations under the Comprehensive Environmental Response, Compensation, and Liability Act and Oil Pollution Act aim to restore natural resources injured by oil spills and hazardous substances released into the environment; exploration of alternative statistical methods to evaluate effects could help address NRDAR legal claims. Bayesian networks (BNs) are statistical tools that can be used to estimate the influence and interrelatedness of abiotic and biotic environmental variables on environmental endpoints of interest. We investigated the application of a BN for injury assessment using a hypothetical case study by simulating data of acid mine drainage (AMD) affecting a fictional stream-dwelling bird species. We compared the BN-generated probability estimates for injury with a more traditional approach using toxicity thresholds for water and sediment chemistry. Bayesian networks offered several distinct advantages over traditional approaches, including formalizing the use of expert knowledge, probabilistic estimates of injury using intermediate direct and indirect effects, and the incorporation of a more nuanced and ecologically relevant representation of effects. Given the potential that BNs have for natural resource injury assessment, more research and field-based application are needed to determine their efficacy in NRDAR. We expect the resulting methods will be of interest to many US federal, state, and tribal programs devoted to the evaluation, mitigation, remediation, and/or restoration of natural resources injured by releases or spills of contaminants

Integrated Environmental Assessment and Management↗