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Long-term intermittent connection between the western Snake River Plain and Columbia basin: A two-phased incision history of Hells Canyon

For more than a century, researchers have debated the route of the Snake River across the northern Cordillera and U.S. Pacific Northwest, including the associated incision history of Hells Canyon. Here, we use detrital zircon U-Pb provenance analysis of Miocene strata upstream and downstream of Hells Canyon to constrain the evolution in fluvial pathways over time. Downstream of Hells Canyon, we show that the ca. 10−6 Ma Clarkston Heights gravel was dominantly sourced from the nearby Salmon and Clearwater rivers but also with substantial input from drainages that now flow into the western Snake River Plain. These same western Snake River Plain drainages were contributing to time-equivalent Lake Idaho strata, upstream of Hells Canyon, indicating a Hells Canyon fluvial connection between the western Snake River Plain and Columbia basin before 6 Ma. Results from Lake Idaho strata suggest a two-phased lacustrine history in the western Snake River Plain: Before ca. 6.0 Ma, lake strata were derived from local tributaries, suggesting that the western Snake River Plain was isolated from the modern upper Snake River system. Between ca. 4.3 Ma and 2.2 Ma, the source area expanded to include eastern tributaries in conjunction with migration of high-standing topography of the Yellowstone hotspot. Our results challenge the long-held hypothesis of “capture” of the Snake River through Hells Canyon. Instead, we infer that Hells Canyon was a long-established route for outflow of lakes occupying the western Snake River Plain, possibly intermittently, during a ca. 10−2 Ma phase of slow regional incision, followed by rapid incision in Hells Canyon starting ca. 2 Ma in conjunction with erosion of the topographic barrier impounding Lake Idaho.

Idaho, Oregon

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Dendroseismological investigation of redwood trees along the North Coast section of the San Andreas Fault

Sequoia sempervirens (coast redwood) tree rings have the potential to annually resolve late-Holocene earthquakes on the northern San Andreas Fault based on direct (e.g., physical damage) and indirect (e.g., co-seismic environmental change) impacts, but scarcity of suitable samples and challenges crossdating this long-lived species have limited progress. More precise dating of the pre-1906 (penultimate) earthquake can improve hazard assessment and understanding of rupture segmentation. We target old trees (maximum >815 yr) along the North Coast section of the fault (increment cores via rope-climbing, 11 living trees; plunge cuts, 23 stumps) and employ complementary disturbance detection methods including radial-growth averaging (tree- and series-level), cataloging anatomical indicators (e.g., traumatic resin ducts, TRD), and dating structural components (e.g., reiterated trunks, leans). Multi-centennial ring-width chronologies at Fort Ross (1569−2023) and Gualala (1397−2023) promote continued study with incomplete crossdating limiting utilization of some series. Growth pulses (reductions, releases) and TRD dispersed across the record reflect dynamic environments that obfuscate detection of earthquake signals. The 1906 earthquake did not leave strong signatures on most trees, and when it did, within-tree response varied from normal presentation to discoloration, TRD, and missing rings. Synchrony of indicators at both locations identified 1678−1680 (6 of 15 trees) and 1698−1700 (8 of 16 trees) as the strongest disturbances among dated rings in the time range of the penultimate earthquake, peaking at 1698 (15.7 % of possible growth and anatomical indicators), but the triggering mechanisms for these events are unknown.

California

Seamless Geologic Map Database for the Intermountain West, United States: A foundational dataset for mineral systems analysis

The Intermountain West has a complex geologic history, resulting in the formation of a diverse array of mineral deposits. Effective mineral exploration requires understanding the spatial and temporal relationships among geologic processes and events, a key focus of the mineral systems approach to exploration. This paper presents the Intermountain West Seamless Geologic Map Database, a unified dataset designed to support mineral exploration. Integrating geologic provinces, structural settings, and hydrothermal alteration, the database leverages the Seamless Integrated Geologic Mapping (SIGMa) extension to the USGS Geologic Map Schema (GeMS) to standardize geologic data from varied sources. SIGMa's hierarchical stratigraphic organization and feature-level metadata enhance data interoperability and reusability, enabling seamless query, analysis, and visualization of lithology, structural features, mineral deposits, geochronology, hydrothermal alteration. volcanic activity, and By providing a regionally consistent and dynamically evolving geologic map, this database provides a foundational framework for mineral exploration and geologic research. It also allows for an efficient workflow that expedites the publication of integrated geologic map databases.

Conference Paper

Mineralization processes at Escanaba Trough

Escanaba Trough off northern California is the southernmost and only sediment covered segment of the Gorda Ridge. Hydrothermal mineralization was first discovered in Escanaba Trough in 1985, and subsequent investigations included the delineation of the NESCA (northern Escanaba) and SESCA (southern Escanaba) sections of Escanaba Trough, as well as drilling by Ocean Drilling Program (ODP) Leg 169 in 1996. Preliminary research conducted in the 1980s distinguished two classes of sulfide mineral assemblages within the Escanaba Trough: one dominated by pyrrhotite (Fe 1-x S) and one containing ‘mixed sulfides’ including chalcopyrite (CuFeS 2 ) and sphalerite (ZnS). In 2022, we conducted a research expedition to the Escanaba Trough to more thoroughly characterize mineralization processes and consider preservation of precipitated minerals throughout hydrothermally active and inactive sections of Escanaba Trough, with the specific objective of characterizing the host minerals, and processes of enrichment for specific elements which are currently listed as critical elements and can also be toxic under certain conditions (Sb, As, Ba, Co, Ga, Ge, Te). The following will include initial results from that work.

California

Fingerprinting magmatic REE deposit sources with zircon petrochronology

Carbonatites and associated alkaline silicate rocks are of considerable economic interest due to their enrichments in rare earth elements. The petrogenesis and source(s) of these complexes, however, are poorly understood. Models propose either mantle plume-derived carbon-rich melts or a mantle source enriched by subduction-related metasomatism. We use zircon trace elements to fingerprint carbonatite-alkaline complex sources, focusing on the economically significant 1.4 Ga Mountain Pass intrusive suite (MPIS). Autocrystic zircon from MPIS alkaline silicate rocks are enriched in Th and U relative to Nb suggesting a subduction influenced, oxidized source region. Lower Sc/Yb, higher Ti concentrations, and the absence of Eu anomalies in autocrystic zircon suggest derivation from a less hydrous, hotter, and deeper mantle source relative to arc-related 1.8–1.6 Ga inherited zircon. These data are best explained by syn- to post-collisional Mesoproterozoic reactivation of a subduction-metasomatized mantle source. The source and tectonic setting of the MPIS contrasts with Mesoproterozoic Gifford Creek and Bayan Obo carbonatites which exhibit plume-like compositions and are associated with rifts, suggesting different sources and tectonic settings for these economically significant deposits. We demonstrate that zircon petrochronology is a robust method for distinguishing carbonatite sources and can inform more targeted exploration strategies for critical mineral resources.

Conference Paper

Transit time modeling framework for predicting freshwater salinization in urban catchments

The salinity of inland freshwaters is rising globally, particularly in urban watersheds where winter road deicers are widely applied. Attributing stream salinity dynamics to specific sources and transport pathways remains challenging due to episodic salt inputs, engineered drainage, and strong coupling between hydrology and subsurface storage. We present a modeling framework that couples climate-driven deicer build-up and wash-off with transient transit time distribution theory to simulate salt transport through drainage, interflow, and groundwater pathways. Applied to an urban watershed in Northern Virginia (USA), the model reproduces ten years of high-frequency stream salinity measurements across daily-to-decadal timescales. The calibrated model implies an average deicer application of 206 tonnes Cl −1 yr −1 , or roughly one 20 kg bag of rock salt person −1 yr −1 when normalized by the 20,000 people living in the watershed. In winter months, higher infiltration routes a large fraction of snowmelt and deicers into shallow subsurface pathways, enhancing vadose-zone and interflow contributions to stream salinity. Limited subsurface storage capacity and seasonal hydrologic turnover flush excess chloride from the vadose zone and groundwater during subsequent summer storms. By linking climate-driven deicer inputs, hydrologic connectivity, and stream water age, the framework provides a transferable basis for diagnosing and managing freshwater salinization in urban watersheds.

Virginia

Potential corrosivity of untreated groundwater in Louisiana

Corrosive groundwater can cause lead, copper, and other metals to leach from pipes and plumbing fixtures in water distribution systems. Metals, if ingested, could lead to serious health implications to the nearly 2.9 million people in Louisiana who obtain their drinking water from groundwater sources. Four indices—the Langelier Saturation Index (LSI), Ryznar Stability Index (RSI), Puckorius Scaling Index (PSI), and the Potential to Promote Galvanic Corrosion (PPGC)—in addition to an analysis which normalized the results from the existing indices, the Combined Index (CI), were used to assess the corrosivity of groundwater in Louisiana and identify areas within eight major aquifers and aquifer systems with moderate to high corrosivity potential. The purpose of this study is to provide State and local governments, public water system managers, and the nearly 500,000 private well owners in Louisiana with information needed to manage drinking-water supplies and mitigate potential health risks related to leaching of metals from water pipes and fixtures. The average scores of untreated groundwater samples from approximately 375 wells by index are as follows: LSI, −1.28; RSI, 9.78; PSI, 9.34; and CI, 4.14. The PPGC does not produce a numerical score, but the total percentage of class counts can be used to assign a classification; overall, samples in Louisiana were classified as significant concern. The percentages of groundwater samples from wells classified as potentially corrosive, by index, are as follows: LSI, 53 percent; RSI, 94 percent; PSI, 81 percent; PPGC, 98 percent; and CI, 81 percent. The percentages of samples classified as indeterminate, by index, are as follows: LSI, 46 percent; RSI, 5 percent; PSI, 12 percent; PPGC, 0 percent; and CI, 18 percent.

Louisiana

Site response models based on geometric parameters for southern California sedimentary basins

Site response in sedimentary basins is influenced by complex three-dimensional (3D) features, including trapping of seismic waves, focusing of seismic energy and basin resonance. Current ground motion models (GMMs) incorporate basin effects using one-dimensional parameters like V S30 and shear wave velocity isosurface depths, which are limited in capturing lateral and 3D effects. To address these limitations, we develop seismic site response models based on novel parameters that represent multi-dimensional properties of the Los Angeles Basin (LAB) geometry and shear wave velocity. We define a basin shape for the LAB using depth to subsurface geologic interfaces associated with the oldest sedimentary deposits (depth to a particular shear wave velocity horizon, i.e., 1.5 km/s - z 1.5 ) and the depth to the crystalline basement ( z cb ) which are determined using geologic cross sections and community seismic velocity model profiles. We explore a suite of geometric descriptors computed for the LAB and southern California, from which three parameters with the greatest predictive potential are selected and evaluated using empirical ground motion residual analyses in combination with the Boore et al. GMM. The results demonstrate that the zonal heterogeneity index ( ), standard deviation of the absolute difference between z 1.5 and z cb ( ) and standard deviation of z cb ( ) each provide a reduction in site-to-site variability ( ϕ S2S ) of empirical GMMs. The reduction in ϕ S2S is period-dependent, with average decreases of 3%, 26% and 6% for , , and , respectively. Although these reductions are modest from an engineering application perspective, they are statistically significant, underscoring the inherent difficulty in fully characterising complex basin effects. Collectively, these findings indicate that the inclusion of basin-specific geometric parameters yields measurable, albeit incremental, improvements in site response prediction and establishes a framework for the progressive refinement of seismic hazard characterisation within sedimentary basins.

California

Revisiting an enigma on California's north coast: The Mw6.5 Fickle Hill earthquake of 21 December 1954

Many earthquakes occur along the North Coast of California in the vicinity of the Mendocino Triple Junction (MTJ), where the Pacific, Gorda, and North American (NA) plates meet, and on the adjacent plate boundaries. The MTJ marks the nexus of the Mendocino and San Andreas faults with the Cascadia subduction zone (CSZ). Historically, most large earthquakes around the MTJ have been within the offshore Gorda plate and its subducted portion beneath the NA plate. North of the MTJ, active faults mapped in the NA plate are part of the CSZ fold‐and‐thrust belt. Although some events have been detected in the NA plate, no large historic events have been associated with mapped surface faults. The 21 December 1954 M w 6.5 earthquake in Humboldt County is one possible exception. Using published data from catalogs and articles, unpublished data from Berkeley’s archives, and S ‐ P times interpreted from two U.S. Coast and Geodetic Survey (USCGS) accelerometers, we determine a probability cloud for the earthquake’s hypocenter using NonLinLoc. The highest probability location lies beneath Fickle Hill just east of the city of Arcata, California, at 40.87° N, 124.03° W, and ∼11 km depth. Using P ‐wave polarities from Berkeley stations and the digitized waveforms from the accelerometers, we find that the focal mechanism most consistent with the data indicates thrust movement with strike, dip, and rake of 350°, 10°, and 90°, respectively, at a depth of 14 km. Given the depth uncertainties of both this event and the megathrust, this implies that the earthquake most likely took place on the subduction interface rather than on the mapped faults in the Mad River fault zone that trend 322° and dip to the northeast. The revisited intensity in the epicentral region also supports a location beneath Fickle Hill to the east of the city of Arcata, California.

California, Idaho, Nevada, Oregon, Washington

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment

Recent applications of the USGS National Crustal Model for Seismic Hazard Studies

The U.S. Geological Survey is developing the National Crustal Model (NCM) for seismic hazard studies to facilitate modeling site, path, and source components of seismic hazard across the conterminous United States. The NCM is composed of a 1km grid of geophysical profiles, extending from the Earth’s surface into the upper mantle. It is constructed from a threedimensional (3D) geologic framework and geophysical rules that use (1) a petrologic and mineral physics database; (2) a 3D temperature model; and (3) a calibrated rock type- and age-dependent porosity model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters (VS30), the depths to 1.0 and 2.5 km/s shear-wave velocity (Z1.0 and Z2.5), and sediment thickness, can be computed from the NCM. As GMMs continue to improve in the future, other metrics could also be extracted or derived from the NCM, such as fundamental period, site attenuation (ko), a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis, including better accounting for path-dependent attenuation and geometric spreading, more accurate estimation of earthquake source properties such as hypocentral location and stress drop, and calculation of crustal strength profiles that inform estimates of the base of seismicity.

conterminous United States

Evolution of permeability and strength recovery of shear fracture under hydrothermal conditions

Geothermal energy is a clean and renewable resource that depends on the ability to move water through hot rock. In many locations, the ability to move water through rock requires the presence of extensive natural or human-made systems of fractures. However, these fracture systems are influenced by a variety of complex processes that occur at the temperature and pressure conditions found in geothermal reservoirs. To make geothermal systems more efficient, it is important to understand how these fractures evolve over time in response to these processes. This study explored how fractures in rock change under high-temperature and pressure conditions, like those found in geothermal reservoirs, through laboratory experiments and numerical simulations. In general fractures, tend to close due to pressure from the surrounding rock preventing the flow of water. One set of laboratory experiments revealed that fractures in granitic rock can weaken over time at elevated temperatures. These weak fractures can then slip slowly potentially keeping the fracture open for a longer period. This study also showed that at the highest temperature examined (250 °C) large differences between the chemical composition of the rock and the fluid moving through it could improve water flow temporarily likely due to the water dissolving parts of the rock. Flow rate predicted by models shows overall good agreement with the flow rate measured in our experiments but with some long time-scale variations that may be due to mechanical wear of the fracture surface. A second set of experiments found that, over the temperature range examined, the closure of fractures was caused by brittle failure driven by high stresses at points where fracture surfaces were in contact. This result suggests that fracture closure in geothermal reservoirs could be counteracted by maintaining high pore pressures. Additionally, we also tested a new method using electrical resistance to measure fracture closure in controlled systems with high precision.

Final Technical Report

Surface variable‐based machine learning for scalable arsenic prediction in undersampled areas

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed geologic logs, which limits their use in undersampled areas where improved guidance is most needed. We overcome these limitations by developing a machine learning model for Minnesota, USA, that predicts As exposure risk using only surficial variables from remote sensing and global data sets. Variables related to surface water hydrology and geomorphology are selected based on mechanistic links that control redox conditions and As mobilization. Local training was essential, and surficial geology variables that are more sensitive to local conditions were needed to maximize model accuracy. The resulting complete model was sufficiently sensitive to generate accurate and detailed risk maps and depth profiles of As concentrations above the 10 μg/L maximum contaminant level. Accuracy depended on local training data density. We identified a training data density of 0.07 wells/km 2 as a practical target for stable county-level performance. Maps of exceedance probabilities highlight priority areas for testing that are particularly important in rural communities that have received less sampling. These results support public health action by guiding where to install wells and where to test them, how much new sampling is needed, and where treatment outreach is most urgent.

Minnesota

Earthquake recurrence estimates for northern Caribbean faults from combinatorial optimization

We use combinatorial optimization to find the optimal spatial distribution of random samples of earthquakes (≥6.5) that minimize the misfit in target slip rates for all faults in the northeast Caribbean, and we derive magnitude-frequency relationships with uncertainties for these faults. Slip rates for many faults are derived from GPS block models, not direct measurements, because of their underwater locations. Predicted recurrence rates for eastern Hispaniola and Puerto Rico Trench faults are 220-450 yr for M7 and 3-5 kyr for M8, with maximum feasible magnitude of M8.2. The most frequent earthquakes with magnitudes ≥7.0 are predicted on the large upper plate strike-slip faults, Enriquillo (EF) and Septentrional Fault, commensurate with the historical record. Calais et al. (2023) suggested that shortening in western Hispaniola is accommodated on the offshore Jérémie and onshore Malpasse faults north and south of EF, instead of on terrestrial faults in western Hispaniola and EF. Because of our system-modeling approach, such a configuration predicts less frequent earthquakes on EF and on western Hispaniola and Muertos convergent zones. Recurrence times of a few 100s yr for M6.7 earthquakes is predicted on the submerged faults in Mona Passage, and infrequent M>7 earthquakes are predicted on the Virgin Islands faults.

Lesser Antilles

Geomorphic map of the Umatilla River corridor, Oregon

This map portrays the distribution of landforms along the Umatilla River in northeastern Oregon and covers a corridor 127 kilometers long from the confluence of the Umatilla River with the Columbia River upstream to Meacham Creek. The map encompasses the valley bottom and extends about 1 kilometer up the adjoining hillslopes. Map data are intended to support water quality and fisheries enhancement efforts pursuant to the First Foods, a resource-management approach that focuses on traditionally gathered foods including water, fish, big game, roots, and berries and calls attention to the reciprocity between people and the foods upon which humans depend. The Umatilla River drains about 6,300 square kilometers on the northwest slope of the Blue Mountains in northeast Oregon. Most of the drainage basin is underlain by Miocene basalt flows of the Columbia River Basalt Group. Younger, weakly lithified, late Miocene and early Pliocene gravel deposits of local origin (for example, McKay Formation) are mapped in a few places. Upland surfaces are mantled with windborne silt (loess) correlative with deposits elsewhere known as the Palouse Formation. Surfaces below an elevation of about 340 meters were inundated repeatedly by large Pleistocene glacial outburst floods, most emanating from glacial Lake Missoula in western Montana. In backflooded areas such as the lower Umatilla River valley, Missoula floods deposited extensive slack-water silt. Areas mapped as open water, active channel and tie channel, flood basin, valley bottom, and modified land constitute the geomorphic floodplain: the area subject to occasional inundation by the Umatilla River. Deposits and landforms within the floodplain are inset into Missoula flood deposits and hence postdate the 20–15-kilo-annum Missoula floods. Some floodplain deposits are no more than a few centuries old, as indicated by substantial erosion and deposition during the Umatilla River flood of February 2020, the largest since systematic measurements began in October 1903. Deposits and landforms of the floodplain are transient features within the longer-term incision of the Umatilla River into mid-Miocene flood basalts and younger gravel of the McKay Formation.

Oregon

Dietary bioavailability of uranium to a model freshwater invertebrate

Uranium (U) mining increases environmental exposures. Understanding how U is taken up by organisms can aid in evaluating the potential for bioaccumulation and toxicity. Although the importance of aqueous geochemical speciation is well recognized for U bioavailability after dissolved exposures, far less is known about the processes controlling U bioavailability after dietary exposures. This study characterizes the biogeochemical drivers of dietary U uptake in the freshwater snail Lymnaea stagnalis in laboratory experiments. Solids tested included benthic diatoms pre-exposed to dissolved U(VI), soils from contaminated U mine sites, and colloidal hydrous ferric oxide (HFO) synthesized in the presence of dissolved U(VI) or with U complexed by natural organic matter (NOM). Results showed that U was bioavailable from all solids. Uranium assimilation efficiency (AE), a proxy for dietary U bioavailability, varied among solids. AE was lowest for the U-contaminated soils (25 ± 17%) and highest for the U-laden diatoms (71 ± 13%). AE varied slightly among HFO preparations, suggesting modest influences of NOM and iron on U bioavailability. Increases in dietary U exposures reduced feeding rates, and the extent of feeding inhibition appeared inversely related to U bioavailability. The high U assimilation and range of bioavailability have implications for toxicity risks inferred without considering dietary uptake.

Environmental Science and Technology

Structural controls on splay fault rupture dynamics during Cascadia megathrust earthquakes

Great subduction earthquakes ( M w ≥ 8.0) can generate devastating tsunamis by rapidly displacing the seafloor and overlying water column. These potentially tsunamigenic seafloor offsets result from coseismic fault slip and deformation beneath or within the accretionary wedge. The mechanics of these shallow rupture phenomena and their dependence on subduction zone properties remain unresolved, partly due to the sparsity of offshore observations of shallow megathrust earthquake deformation. Here, we analyze how offshore structure influences shallow rupture mechanics and slip partitioning using 3D dynamic earthquake simulations of the Cascadia subduction zone (CSZ) megathrust with and without variably dipping seaward- or landward-vergent splay faults in the wedge that sole into the megathrust. Resulting tradeoffs between splay and megathrust slip reveal structural controls on rupture partitioning, with greater splay slip leading to less shallow megathrust slip updip. Gently dipping and seaward-vergent splays host more slip than those with steeper, landward-vergent splays. To isolate the underlying mechanisms, we compare models with Andersonian and plunging principal stresses. Results suggest distinct static and dynamic processes control the dip- and vergence-dependence of splay rupture: static (mis)alignment relative to far-field tectonic loading favors slip on more optimally oriented, shallowly dipping splay faults. In contrast, dynamic stress interactions of an updip-propagating megathrust rupture front with the free surface and potential branch faults favor forward branching onto seaward-vergent splays and inhibit backward branching onto landward-vergent splays. Resulting seafloor displacements suggest splay fault structure may influence coseismic tsunami source processes, highlighting the importance of dynamically viable rupture scenarios in subduction hazard assessments.

Cascadia subduction zone