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USGS2013

Hydrogeology, distribution, and volume of saline groundwater in the southern midcontinent and adjacent areas of the United States

The hydrogeology, distribution, and volume of saline water in 22 aquifers in the southern midcontinent of the United States were evaluated to provide information about saline groundwater resources that may be used to reduce dependency on freshwater resources. Those aquifers underlie six States in the southern midcontinent—Arkansas, Kansas, Louisiana, Missouri, Oklahoma, and Texas—and adjacent areas including all or parts of Alabama, Colorado, Florida, Illinois, Kentucky, Mississippi, Nebraska, New Mexico, South Dakota, Tennessee, and Wyoming and some offshore areas of the Gulf of Mexico. Saline waters of the aquifers were evaluated by defining salinity zones; digitizing data, primarily from the Regional Aquifer-System Analysis Program of the U.S. Geological Survey; and computing the volume of saline water in storage. The distribution of saline groundwater in the southern midcontinent is substantially affected by the hydrogeology and groundwater-flow systems of the aquifers. Many of the aquifers in the southern midcontinent are underlain by one or more aquifers, resulting in vertically stacked aquifers containing groundwaters of varying salinity. Saline groundwater is affected by past and present hydrogeologic conditions. Spatial variation of groundwater salinity in the southern midcontinent is controlled primarily by locations of recharge and discharge areas, groundwater-flow paths and residence time, mixing of freshwater and saline water, and interactions with aquifer rocks and sediments. The volume calculations made for the evaluated aquifers in the southern midcontinent indicate that about 39,900 million acre-feet (acre-ft) of saline water is in storage. About 21,600 million acre-ft of the water in storage is slightly to moderately saline (1,000–10,000 milligrams per liter [mg/L] dissolved solids), and about 18,300 million acre-ft is very saline (10,000–35,000 mg/L dissolved solids). The largest volumes of saline water are in the coastal lowlands (about 16,300 million acre-ft), Mississippi embayment and Texas coastal uplands (about 12,000 million acre-ft), and Great Plains (about 8,170 million acre-ft) aquifer systems. Of the 22 aquifers evaluated in this report, the Maha aquifer in the Great Plains aquifer system contains both the largest total volume of saline water (about 6,280 million acre-ft) and the largest volume of slightly to moderately saline water (about 5,150 million acre-ft).

Alabama;Arkansas;Colorado;Florida;Illinois;Kansas;↗

USGS2000

Microbial control of mineral–groundwater equilibria: Macroscale to microscale

Using field and laboratory experiments, the geomicrobiology of a petroleum-contaminated aquifer and the relationship between mineral alteration, groundwater chemistry, and microbial colonization were examined. Results indicate that indigenous microorganisms influence mineral weathering at two scales of interaction: macroscale processes that perturb general groundwater chemistry and therefore mineralwater equilibria; and microscale interactions, where attached organisms locally perturb mineral±water equilibria, potentially releasing limiting trace nutrients from the dissolving mineral. In the contaminated unconfined glacio-fluvial aquifer near Bemidji, Minnesota, USA, carbonate chemistry is influenced primarily at the macroscale. Under oxic conditions, respiration by native aerobic heterotrophs produces excess carbon dioxide that promotes calcite and dolomite dissolution. Aerobic microorganisms do not colonize dolomite surfaces and few occur on calcite. Within the anoxic groundwater, calcite overgrowths form on uncolonized calcite cleavage surfaces, possibly due to the consumption of acidity by dissimilatory iron-reducing bacteria. As molecular oxygen concentration increases downgradient of the oil pool, aerobes again dominate and residual hydrocarbons and ferrous iron are oxidized, resulting in macroscale carbonate-mineral dissolution and iron precipitation. Feldspars, in contrast, weather exclusively at the microscale near attached microorganisms, principally in the anoxic region of the plume. Native organisms preferentially colonize feldspars that contain trace phosphorus as apatite inclusions, apparently as a consequence of the low P concentration in the groundwater. These feldspars weather rapidly, whereas nearby feldspars without trace P are uncolonized and unweathered. Feldspar dissolution is accompanied by the precipitation of secondary minerals, sometimes on the bacterial cell wall itself. These observations suggest a tightly linked biogeochemical system whereby microbial processes control mineral diagenesis at many scales of interaction, and the mineralogy and mineral chemistry influence microbial ecology. Only the macroscale interaction, however, is easily observable by standard geochemical methods, and documentation of the microscale interactions requires microscopic examination of microorganisms on mineral surfaces and the locally intense diagenetic reactions that result.

Hydrogeology Journal↗

USGS1989

Hydrologic effects of pumpage from the Denver basin bedrock aquifers of northern El Paso County, Colorado

The Denver groundwater basin underlies a 6,700 sq-mi area in eastern Colorado. To assess current conditions of the four bedrock aquifers in the basin, water levels, streamflow gain and loss, and other data were collected. Current aquifer conditions in the southern part of the basin and likely response to various 100-year pumping scenarios were analyzed using a digital finite-difference model. Simulated predevelopment flow through the bedrock aquifers was about 59 cu ft/sec. Water level changes between 1978 and 1985, likely caused by variations in precipitation and in pumping and by lowering of the water table in the overlying Black Squirrel Creek alluvial aquifer, ranged from rises of more than 40 ft to declines of as much as 80 ft. In 1985, pumping from the bedrock aquifers was about 56 cu ft/sec. Simulations indicate that 43% of the pumpage came from a decrease in volume of groundwater in storage; 37% came from induced recharge and captured discharge. The remaining 20% came from a transient high rate of recharge from precipitation. A baseline 100-yr simulation, beginning in 1985, indicated minimal drawdowns for constant pumping at 1985 rates in the southern part of the basin. Other simulations indicated that the pumpage required to supply the needs of the projected population would be accompanied by drawdowns of as much as 1,300 ft and by large decreases in amount of groundwater in storage. Pumpage from a hypothetical well field, located where the aquifers are thickest , and from the aquifers underlying Colorado Springs also was simulated. (USGS)

Water-Resources Investigations Report↗

USGS1989

Effects of variations in recharge on groundwater quality

The predominant regional effect of recharge on municipal groundwater quality in Kansas is the dilution of mineralized water in aquifers with relatively shallow water tables. The individual dissolved constituents contributing most to the water-quality variations are sulfate and chloride, and the calcium and sodium accompanying them, which are derived from the dissolution of evaporite minerals within the aquifer or from saline formation water in bedrock underlying the aquifer. The relationship between recharge and groundwater-quality variation can be quantified by associating certain climatic indices, especially the Palmer Drought Index, with quality observations. The response time of the maximum water-quality change relative to the occurrence of drought or substantial recharge ranges from a month to 3 years depending on the aquifer characteristics, and is generally proportional to the saturated thickness and specific yield. The response time is also affected by discharge to and recharge from nearby streams and by the well construction, particularly the placement of the screened interval, and pumping stress.

Journal of Hydrology↗

USGS2014

Stream-water and groundwater quality in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area, Pottawatomie County, Oklahoma, 2012-13

The Citizen Potawatomi Nation needs to characterize their existing surface-water and groundwater resources in and near their tribal jurisdictional area to complete a water-resource management plan. Water resources in this area include surface water from the North Canadian and Little Rivers and groundwater from the terrace and alluvial aquifers and underlying bedrock aquifers. To assist in this effort, the U.S. Geological Survey (USGS), in cooperation with the Citizen Potawatomi Nation, collected water-quality samples at 4 sites on 3 streams and from 30 wells during 2012 and 2013 in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area in central Oklahoma. Stream samples were collected eight times on the North Canadian River at the upstream USGS streamflow-gaging station North Canadian River near Harrah, Okla. (07241550); at the downstream USGS streamflow-gaging station North Canadian River at Shawnee, Okla. (07241800); and on the Little River at the USGS streamflow-gaging station Little River near Tecumseh, Okla., (07230500). Stream samples also were collected three times at an ungaged site, Deer Creek near McLoud, Okla. (07241590). Water properties were measured, and water samples were analyzed for concentrations of major ions, nutrients, trace elements, counts of fecal-indicator bacteria, and 69 organic compounds. The highest concentrations of dissolved solids and chlorides were measured in stream-water samples collected at the Little River near Tecumseh station. The Secondary Maximum Contaminant Level (SMCL) for dissolved solids in drinking water of 500 milligrams per liter (mg/L) was exceeded in 7 of 8 stream-water samples, with a median concentration of 844 mg/L at that station. The 250-mg/L SMCL for chloride was exceeded in 5 of the 8 stream-water samples collected at that station. Median concentrations of total dissolved nitrogen were about an order of magnitude higher in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved nitrogen were 4.36 and 2.89 mg/L in stream-water samples collected at the two North Canadian River stations, 0.35 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.76 mg/L in stream-water samples collected at the Deer Creek site. Similar to nitrogen, median concentrations of total dissolved phosphorus were higher by about two orders of magnitude in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved phosphorus were 1.05 and 0.805 mg/L in stream-water samples collected at the two North Canadian River stations, 0.007 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.032 mg/L from the Deer Creek site. Dissolved concentrations of total nitrogen, nitrate-nitrogen, orthophosphorus, and total phosphorus were highest in stream-water samples collected at the two North Canadian River stations at low streamflows, indicating that wastewater effluent may have been a notable source of these nutrients. Concentrations of most trace elements increased with increasing streamflow in stream-water samples collected at the two North Canadian River stations, indicating that most trace elements are washed into the river by runoff from the land surface or resuspended from streambed sediments. In general, most trace-element concentrations were below respective Maximum Contaminant Levels (MCLs) for public drinking-water supplies, except for one stream-water sample with an arsenic concentration of 10.1 micrograms per liter (µg/L) collected from the North Canadian River and one stream-water sample with a barium concentration of 2,690 µg/L collected from the Little River. At least one stream-water sample from each of the four stream sites sampled in this study contained a lead concentration exceeding the SMCL of 15 µg/L. All of these samples were collected during high streamflows. A greater number of organic compounds were detected in stream-water samples collected at the two stations on the North Canadian River than in stream-water samples collected at the Tecumseh station and Deer Creek site. In the 8 stream-water samples collected at the upstream Harrah station, 213 detections of organic compounds were measured, whereas in 8 samples collected at the downstream Shawnee station, 203 detections of organic compounds were measured. In contrast, 59 detections of organic compounds were measured in the 8 stream-water samples collected at the Tecumseh station, and 25 detections of organic compounds were measured in the 3 stream-water samples collected at the Deer Creek site; however, the 8 detections of 7 organic compounds in the 2 equipment-blank samples is problematic for evaluating these data, especially for the Deer Creek and Little River samples because of the comparatively low detection frequency and should be taken into consideration when evaluating these results. Groundwater samples also were collected once from 30 wells producing water from the Garber-Wellington aquifer; Admire, Chase, and Council Grove Groups; the Vanoss Formation; and the terrace and alluvial aquifers along the North Canadian River. Water properties were measured, and samples were analyzed for concentrations of major ions, nutrients, trace elements, and selected radionuclides in groundwater. Of 30 wells sampled for this study, 26 were completed in bedrock aquifers, and 4 were completed in terrace and alluvial aquifers. In general, groundwater in the study area is very hard, with a median concentration of 180 mg/L as calcium carbonate in water samples collected from the 30 wells. Concentrations of sulfate exceeded the 250-mg/L SMCL in two groundwater samples, and dissolved solids concentrations exceeded the 500-mg/L SMCL in nine groundwater samples. Trace-element concentrations did not exceed respective MCLs in the 30 groundwater samples collected for this study. Concentrations of the radionuclide uranium ranged from 0.03 to 79.5 µg/L, with a median concentration of 1.9 µg/L in the 30 groundwater samples collected. Two of the groundwater samples collected for this study had uranium concentrations exceeding the MCL of 30 µg/L, with concentrations of 79.5 and 31.1 µg/L. Generally, uranium concentrations were highest in water samples collected from wells completed in the Wellington Formation and the Chase, Council Grove, and Admire Groups in the southern and eastern parts of the study area.

Oklahoma↗

USGS2023

Hydrologic effects of possible changes in water-supply withdrawals from, and effluent recharge to, the Kirkwood-Cohansey aquifer system, Winslow Township, Camden County, New Jersey

Winslow Township and the Camden County Municipal Utility Authority (CCMUA) developed a plan to shut down the Winslow sewage-treatment facility and associated effluent infiltration facility and transfer the effluent to the CCMUA sewage-treatment facility on the Delaware River in Camden, New Jersey. Winslow Township reduced groundwater withdrawals from the Kirkwood-Cohansey aquifer system to offset groundwater recharge lost with the cessation of effluent infiltration. The U.S. Geological Survey, in cooperation with Winslow Township and the CCMUA, collected data to evaluate conditions prior to cessation of effluent infiltration and installed two continuous-record streamflow-gaging stations. Streamflow measurements also were made at two low-flow partial-record sites, and groundwater levels were measured in 17 wells at high and low water-level periods (May and September 2010). A groundwater-flow model provides estimated changes in base flow of the Great Egg Harbor River under several groundwater-withdrawal and effluent infiltration scenarios. Water levels were measured in an observation well 480 feet (ft) from the infiltration lagoons during 1971–2010. A downward trend in water levels in the well prior to 1985 is attributed in part to increased impervious surfaces and groundwater withdrawals associated with development in the area that began in the early 1970s. From late 1985 to 2010, there was an upward trend in water levels in the well that is attributed to the construction of nearby effluent infiltration lagoons in 1985 and the increasing rate of effluent infiltration during the period. Recent and historical measurements made at the four surface-water sites were correlated with same-day discharges measured at three nearby index stations to estimate continuous low-flow record at the sites. Effects on base flow caused by reductions in groundwater withdrawals or the cessation of effluent infiltration in Winslow Township could not be ascertained from the available data with the statistical and analysis methods used. Groundwater discharge to streams (base flow) was simulated with a groundwater-flow model of the Great Egg Harbor and Mullica River Basins. Simulated monthly base flows using 2008–10 withdrawal rates and effluent recharge (Scenario 1) are generally about 1.5 million gallons per day (Mgal/d) greater than simulated base flows using 2003–07 withdrawal rates (Baseline Scenario) because of the 1.57 Mgal/d reduction in average withdrawals by Winslow Township from the Kirkwood-Cohansey aquifer system from 2003–07 to 2008–10. Simulated monthly base flows using 2008–10 withdrawals but without effluent infiltration (Scenario 2) are very similar to, but typically slightly lower than, Baseline Scenario base flows. Three hypothetical future distributions of groundwater withdrawals from existing Winslow Township wells are simulated, each without effluent infiltration and using the same groundwater withdrawal rate as Scenario 2, but with different hypothetical distributions of withdrawals among existing Winslow Township wells. The Scenario 3 and 4 base flows are greater than the Baseline Scenario base flows in all months, and the Scenario 5 base flows are less than the Baseline Scenario base flows in all months. The simulation results indicate that a reduction in average withdrawals from the Kirkwood-Cohansey aquifer system by 1.57 Mgal/d offsets the reduction of effluent infiltration by about the same rate, resulting in nearly unchanged base flows in the Great Egg Harbor River near Blue Anchor (01410820).

New Jersey↗

USGS1989

Relation between land use and ground-water quality in the upper glacial aquifer in Nassau and Suffolk Counties, Long Island, New York

The chemical quality of groundwater in the upper glacial (water-table) aquifer beneath the 10 types of land-use areas of Nassau and Suffolk Counties, NY was examined to evaluate the effect of human activities on groundwater. The highest median chloride and total dissolved-solids concentrations were found in wells in high-density residential areas (more than five dwellings/acre), and the highest median nitrate, sulfate, and calcium concentrations were found in wells in agricultural and high density residential areas. Relatively low median concentrations of inorganic chemical constituents were found in wells in undeveloped and low-density residential areas (1 or fewer/acre): volatile organic compounds were rarely detected in these same areas. The highest concentrations and most frequent detection of volatile organic compounds were in industrial and commercial areas. The most commonly detected volatile organic compounds were 1,1,1-trichloroethane (24% of wells), tetrachloroethylene (20%), trichloroethylene (18%), chloroform (9%), and 1,2-dichloroethylene (5%). The spatial distributions of trichloroethylene, chloroform and other volatile organic compounds in the upper glacial aquifer are directly correlated with population density in the two-county area. (USGS)

Water-Resources Investigations Report↗

USGS1986

Investigation of possible effects of surface coal mining on hydrology and landscape stability in part of the Powder River structural basin, northeastern Wyoming

The effects of surface coal mining on the surface- and groundwater systems in a 5,400 sq mi area in the Powder River Basin, Wyoming, that includes 20 major coal mines were evaluated using three approaches: A surface water model, a landscape-stability analysis, and a groundwater model. A surface water model was developed for the Belle Fourche River basin. The Hydrological Simulation Program-Fortran model was used to simulate changes in streamflow and changes in dissolved-solids and sulfate concentrations. Simulated streamflows resulting from less than average rainfall were small, changes in flow from premining to during-mining and postmining conditions were less than 2.5%, and changes in mean dissolved-solids and sulfate concentrations ranged from 1 to 7%. A landscape-stability analysis resulted in regression relations to aid in the reconstruction of reclaimed drainage networks. Hypsometric analyses indicate the larger basins are relatively stable, and statistical data from these basins may be used to design the placement of material within a mined basin to approximate natural, stable landscapes in the area. The attempt to define and simulate the groundwater system in the area using a groundwater-flow model was unsuccessful. The steady-state groundwater-flow model could not be calibrated. The modeling effort failed principally because of insufficient quantity and quality of data to define the spatial distribution of aquifer properties; the hydraulic-head distribution within and between aquifers; and the rates of groundwater recharge and discharge, especially for steady-state conditions. (USGS)

Water-Resources Investigations Report↗

USGS2016

Use of multiple age tracers to estimate groundwater residence times and long-term recharge rates in arid southern Oman

Multiple age tracers were measured to estimate groundwater residence times in the regional aquifer system underlying southwestern Oman. This area, known as the Najd, is one of the most arid areas in the world and is planned to be the main agricultural center of the Sultanate of Oman in the near future. The three isotopic age tracers 4 He, 14 C and 36 Cl were measured in waters collected from wells along a line that extended roughly from the Dhofar Mountains near the Arabian Sea northward 400 km into the Empty Quarter of the Arabian Peninsula. The wells sampled were mostly open to the Umm Er Radhuma confined aquifer, although, some were completed in the mostly unconfined Rus aquifer. The combined results from the three tracers indicate the age of the confined groundwater is < 40 ka in the recharge area in the Dhofar Mountains, > 100 ka in the central section north of the mountains, and up to and > one Ma in the Empty Quarter. The 14 C data were used to help calibrate the 4 He and 36 Cl data. Mixing models suggest that long open boreholes north of the mountains compromise 14 C-only interpretations there, in contrast to 4 He and 36 Cl calculations that are less sensitive to borehole mixing. Thus, only the latter two tracers from these more distant wells were considered reliable. In addition to the age tracers, δ 2 H and δ 18 O data suggest that seasonal monsoon and infrequent tropical cyclones are both substantial contributors to the recharge. The study highlights the advantages of using multiple chemical and isotopic data when estimating groundwater travel times and recharge rates, and differentiating recharge mechanisms.

Dhofar Mountains↗

USGS2008

Assessment of long-term salinity changes in an irrigated stream-aquifer system

Changes in salinity in groundwater and surface water in the Arkansas River valley of southeastern Colorado are primarily related to irrigation practices. A solute transport model was applied to an 11-mile reach of the valley to compute salinity changes in response to spatially and temporally varying stresses. The model was calibrated in 1973 using detailed field measurements made during 1971 and 1972. In 1973 the calibrated model was used to predict that a gradual long-term increase in groundwater salinity of about 2–3% per year would occur if the observed irrigation practices continued. The study area was resampled during the winter of 1982 to help evaluate if any long-term changes in salinity are actually occurring. Nonparametric and parametric statistical tests were used to help assess the significance of observed changes in groundwater salinity. These tests indicate that a statistically significant increase in salinity occurred between the winters of 1971 and 1972 (the model calibration period). However, a comparison of the winter 1972 and winter 1982 data indicates that no significant net change in salinity has occurred during this 10-year period. An analysis of the few available historical data (1895, 1923, 1959–1961, and 1964) supports the hypothesis that groundwater salinity in this irrigated area has reached a long-term dynamic equilibrium in response to irrigation practices. The model predictions of long-term salinity increases were invalid probably because the calibration period occurred during a short-term annual trend of increasing salinity in the river (and hence in leaky irrigation canals and in applied irrigation water), which was not representative of the long-term trend.

Colorado↗

USGS2011

Reinterpreting the importance of oxygen-based biodegradation in chloroethene-contaminated groundwater

Chlororespiration is common in shallow aquifer systems under conditions nominally identified as anoxic. Consequently, chlororespiration is a key component of remediation at many chloroethene-contaminated sites. In some instances, limited accumulation of reductive dechlorination daughter products is interpreted as evidence that natural attenuation is not adequate for site remediation. This conclusion is justified when evidence for parent compound (tetrachloroethene, PCE, or trichloroethene, TCE) degradation is lacking. For many chloroethene-contaminated shallow aquifer systems, however, nonconservative losses of the parent compounds are clear but the mass balance between parent compound attenuation and accumulation of reductive dechlorination daughter products is incomplete. Incomplete mass balance indicates a failure to account for important contaminant attenuation mechanisms and is consistent with contaminant degradation to nondiagnostic mineralization products like CO 2 . While anoxic mineralization of chloroethene compounds has been proposed previously, recent results suggest that oxygen-based mineralization of chloroethenes also can be significant at dissolved oxygen concentrations below the currently accepted field standard for nominally anoxic conditions. Thus, reassessment of the role and potential importance of low concentrations of oxygen in chloroethene biodegradation are needed, because mischaracterization of operant biodegradation processes can lead to expensive and ineffective remedial actions. A modified interpretive framework is provided for assessing the potential for chloroethene biodegradation under different redox conditions and the probable role of oxygen in chloroethene biodegradation.

Ground Water Monitoring and Remediation↗

USGS2021

Groundwater dynamics at Kīlauea Volcano and vicinity, Hawaiʻi

Kīlauea Volcano, on the Island of Hawaiʻi, is surrounded and permeated by active groundwater systems that interact dynamically with the volcanic system. A generalized conceptual model of Hawaiian hydrogeology includes high-level dike-impounded groundwater, very permeable perched and basal aquifers, and a transition (mixing) zone between freshwater and saltwater. Most high-level groundwater is associated with the low-permeability intrusive complexes that underlie volcanic rift zones and calderas and also act to compartmentalize the groundwater system. Hydrogeologic studies of Kīlauea in recent decades, accompanied by deep research drilling, have shown that high-level groundwater is more widespread than once understood, that permeability decreases dramatically at depth, particularly in rift zones, and that freshwater can occur at depths of as much as several kilometers below the local water table. Copious groundwater recharge causes near-surface conductive heat flow to be near zero over much of Kīlauea. Approximately 95 percent of groundwater discharge occurs offshore, accompanied by approximately 99 percent of the approximately 6,000 megawatts of heat supplied by magmatic intrusion. Here, we summarize current understanding of the groundwater system of Kīlauea Volcano and describe transient changes during the decade or more preceding the 2018 eruption sequence. The changes in groundwater chemistry and thermal structure beneath Kīlauea summit hold implications for volcanic-volatile transport and the potential for explosive volcanism. Between 2008 and 2018, the magma conduit beneath the lava lake likely created an adjacent zone of very hot rock that significantly delayed liquid groundwater inflow to the draining magma conduit. Sulfate concentrations in groundwater beneath Kīlauea summit, sampled at the National Science Foundation-funded drill hole 1.5 kilometers south-southwest of the lava lake, declined substantially between 2010 and present. This decline likely reflects, at least in part, the decreased effectiveness of volatile condensation and solution into groundwater (scrubbing). The vent opening in 2008 presumably focused volatile flux into the vicinity of the vent, and progressive drying of the surroundings further restricted interaction with the groundwater system. The decrease in sulfate concentrations in the drill hole between 2010 and 2018 likely reflects decreased effectiveness of scrubbing.

Hawaii↗

USGS2010

Simulation of Groundwater Mounding Beneath Hypothetical Stormwater Infiltration Basins

Groundwater mounding occurs beneath stormwater management structures designed to infiltrate stormwater runoff. Concentrating recharge in a small area can cause groundwater mounding that affects the basements of nearby homes and other structures. Methods for quantitatively predicting the height and extent of groundwater mounding beneath and near stormwater Finite-difference groundwater-flow simulations of infiltration from hypothetical stormwater infiltration structures (which are typically constructed as basins or dry wells) were done for 10-acre and 1-acre developments. Aquifer and stormwater-runoff characteristics in the model were changed to determine which factors are most likely to have the greatest effect on simulating the maximum height and maximum extent of groundwater mounding. Aquifer characteristics that were changed include soil permeability, aquifer thickness, and specific yield. Stormwater-runoff variables that were changed include magnitude of design storm, percentage of impervious area, infiltration-structure depth (maximum depth of standing water), and infiltration-basin shape. Values used for all variables are representative of typical physical conditions and stormwater management designs in New Jersey but do not include all possible values. Results are considered to be a representative, but not all-inclusive, subset of likely results. Maximum heights of simulated groundwater mounds beneath stormwater infiltration structures are the most sensitive to (show the greatest change with changes to) soil permeability. The maximum height of the groundwater mound is higher when values of soil permeability, aquifer thickness, or specific yield are decreased or when basin depth is increased or the basin shape is square (and values of other variables are held constant). Changing soil permeability, aquifer thickness, specific yield, infiltration-structure depth, or infiltration-structure shape does not change the volume of water infiltrated, it changes the shape or height of the groundwater mound resulting from the infiltration. An aquifer with a greater soil permeability or aquifer thickness has an increased ability to transmit water away from the source of infiltration than aquifers with lower soil permeability; therefore, the maximum height of the groundwater mound will be lower, and the areal extent of mounding will be larger. The maximum height of groundwater mounding is higher when values of design storm magnitude or percentage of impervious cover (from which runoff is captured) are increased (and other variables are held constant) because the total volume of water to be infiltrated is larger. The larger the volume of infiltrated water the higher the head required to move that water away from the source of recharge if the physical characteristics of the aquifer are unchanged. The areal extent of groundwater mounding increases when soil permeability, aquifer thickness, design-storm magnitude, or percentage of impervious cover are increased (and values of other variables are held constant). For 10-acre sites, the maximum heights of the simulated groundwater mound range from 0.1 to 18.5 feet (ft). The median of the maximum-height distribution from 576 simulations is 1.8 ft. The maximum areal extent (measured from the edge of the infiltration basins) of groundwater mounding of 0.25-ft ranges from 0 to 300 ft with a median of 51 ft for 576 simulations. Stormwater infiltration at a 1-acre development was simulated, incorporating the assumption that the hypothetical infiltration structure would be a pre-cast concrete dry well having side openings and an open bottom. The maximum heights of the simulated groundwater-mounds range from 0.01 to 14.0 ft. The median of the maximum-height distribution from 432 simulations is 1.0 ft. The maximum areal extent of groundwater mounding of 0.25-ft ranges from 0 to 100 ft with a median of 10 ft for 432 simulations. Simulated height and extent of groundwater mounding associ

Scientific Investigations Report↗

USGS2015

Evaluating connection of aquifers to springs and streams, Great Basin National Park and vicinity, Nevada

Federal agencies that oversee land management for much of the Snake Range in eastern Nevada, including the management of Great Basin National Park by the National Park Service, need to understand the potential extent of adverse effects to federally managed lands from nearby groundwater development. As a result, this study was developed (1) to attain a better understanding of aquifers controlling groundwater flow on the eastern side of the southern part of the Snake Range and their connection with aquifers in the valleys, (2) to evaluate the relation between surface water and groundwater along the piedmont slopes, (3) to evaluate sources for Big Springs and Rowland Spring, and (4) to assess groundwater flow from southern Spring Valley into northern Hamlin Valley. The study focused on two areas—the first, a northern area along the east side of Great Basin National Park that included Baker, Lehman, and Snake Creeks, and a second southern area that is the potential source area for Big Springs. Data collected specifically for this study included the following: (1) geologic field mapping; (2) drilling, testing, and water quality sampling from 7 test wells; (3) measuring discharge and water chemistry of selected creeks and springs; (4) measuring streambed hydraulic gradients and seepage rates from 18 shallow piezometers installed into the creeks; and (5) monitoring stream temperature along selected reaches to identify places of groundwater inflow. The Snake Range was formed by a generally normal-faulted uplift, where late Proterozoic and Cambrian siliciclastic rocks and metamorphic rocks are present at the highest altitudes and younger Paleozoic carbonate rocks are exposed along the flanks. The consolidated rocks are intruded by Jurassic to Tertiary age plutons, which are most common between the Lehman and Snake Creek drainage basins. Older Cenozoic rocks, including Oligocene volcanic rocks and Miocene sedimentary rocks, crop out locally and fill the basins that underlie Snake, Spring, and Hamlin Valleys. Younger Tertiary and Quaternary sedimentary (basin-fill) deposits overlie the older Cenozoic rocks. The rocks and deposits can be divided into three distinct aquifers. These aquifers include (1) basin-fill aquifers that consist of the permeable parts of the Cenozoic basin fill and some fractured or jointed Cenozoic volcanic rocks, (2) an upper carbonate-rock aquifer that consists of upper Paleozoic carbonate rocks overlying a regionally extensive middle Paleozoic siliciclastic confining unit, and (3) a lower carbonate-rock aquifer that consists of lower Paleozoic carbonate rocks. Secondary openings created by faults, shear zones, fractures, and, in the carbonate rocks, karst solution features, largely determine the water-transmitting properties of the volcanic- and carbonate-rock aquifers. The basin-fill aquifers are composed of a wide variety of rock types and have highly variable hydraulic properties. The three aquifers are stratigraphically and structurally heterogeneous, causing large variations in the ability to store and transmit water. The aquifers are separated by confining units in some areas and are in contact with each other in other areas, yet function as a single, composite aquifer system. Basin-fill aquifers most often overlie or adjoin the lower and upper carbonate-rock aquifers. Baker, Lehman and Snake Creek drainage basins were divided into five hydrologic zones on the basis of climate, geology, and topography. The five zones, from highest to lowest altitudes, are the mountain-upland, karst-limestone, upper-piedmont, lower-piedmont, and valley-lowland zones. The primary hydrologic connection between the mountain-upland and the valley-lowland zones is streamflow. Much of the streamflow from the mountain-upland zone is generated above tree line. Groundwater flow increases in the karst-limestone zone because of increased permeability caused by dissolution, which results in increased streamflow losses. Most of the increased groundwater flow is to springs near faults that form the boundary with the upper-piedmont zone. Thus, groundwater flow from the karst-limestone zone to the upper-piedmont zone was only 10 percent of the combined flow of streams and springs that exit the karst-limestone zone. About 60 percent of the water flowing from Rowland Spring in the Lehman Creek drainage basin was from streamflow losses along Baker Creek. The remaining flow from Rowland Spring comes from local recharge in the karst-limestone zone. In the upper-piedmont zone, the water table by Baker, Lehman and Snake Creeks was near the water level in the creeks for several hundred feet downstream from the karst-limestone zone. Water levels in piezometers along Snake Creek downstream from its confluence with Spring Creek were far below the streambed, indicating gravity drainage beneath this section of the creek. Estimated vertical hydraulic conductivity along a 3-mile reach of Snake Creek downstream of this confluence was 0.5 foot per day, which was an order of magnitude less than that estimated for Baker and Lehman Creeks. The low vertical hydraulic conductivity in the streambed along the lower reaches of Snake Creek results from chemical precipitation of calcite caused by off-gassing of carbon dioxide derived from springs at the end of the karst-limestone zone. The younger alluvial deposits thicken rapidly across faults that form the upper boundary of the lower-piedmont zone. The absence of springs or groundwater flow to the creeks upstream of these faults indicates they are not a complete barrier to groundwater flow. The water table was shallow in the valley-lowland zone in the Baker and Lehman Creek drainage basins, whereas the water table was more than 50 feet below land surface in the Snake Creek drainage basin. In contrast to thick basin fill in the valley-lowland zone in the Baker and Lehman Creek drainage basins, fractured and karst limestone underlie basin fill at relatively shallow depths in Snake Creek drainage basin. The underlying limestone acts as a drain for groundwater in the basin fill beneath Snake Creek. A groundwater divide in southern Spring Valley south of Baking Powder Flat separates groundwater flow to the flat from southeastward flow into northern Hamlin Valley. Groundwater flow from southern Spring Valley south of the groundwater divide into northern Hamlin Valley was estimated to range from 6,000 to 11,000 acre-feet per year. This groundwater does not flow to Big Springs in southern Snake Valley; rather, the source of water to Big Springs is groundwater recharge in the Big Spring Wash drainage basin and in nearby smaller drainage basins at the south end of the Snake Range. Groundwater flow from southern Spring Valley continues through the western side of Hamlin Valley before being directed northeast toward the south end of Snake Valley. This flow is constrained by southward-flowing groundwater from Big Spring Wash and northward-flowing groundwater beneath central Hamlin Valley. The redirection to the northeast corresponds to a narrowing of the width of flow in southern Snake Valley caused by a constriction formed by a steeply dipping middle Paleozoic siliciclastic confining unit exposed in the flanks of the mountains and hills on the east side of southern Snake Valley and shallowly buried beneath basin fill in the valley. The narrowing of groundwater flow could be responsible for the large area where groundwater flows to springs or is lost to evapotranspiration between Big Springs in Nevada and Pruess Lake in Utah.

Nevada↗

USGS2009

Development of a three-dimensional model of sedimentary texture in valley-fill deposits of Central Valley, California, USA

A three-dimensional (3D) texture model was developed to help characterize the aquifer system of Central Valley, California (USA), for a groundwater flow model. The 52,000-km 2 Central Valley aquifer system consists of heterogeneous valley-fill deposits. The texture model was developed by compiling and analyzing approximately 8,500 drillers’ logs, describing lithologies up to 950 m below land surface. The lithologic descriptions on the logs were simplified into a binary classification of coarse- and fine-grained. The percentage of coarse-grained sediment, or texture, was then computed for each 15-m depth interval. The model was developed by 3D kriging of the percentage of coarse-grained deposits onto a 1.6-km spatial grid at 15-m depth intervals from land surface down to 700 m below land surface. The texture model reflects the known regional, spatial, and vertical heterogeneity in the aquifer system. The texture model correlates to sediment source areas, independently mapped geomorphic provinces, and factors affecting the development of alluvial fans, thus demonstrating the utility of using tcdrillers’ logs as a source of lithologic information. The texture model is upscaled to a layered groundwater flow model for use in defining the hydraulic properties of the aquifer system.

California↗

USGS2012

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico↗

USGS1986

A reconnaissance water-quality appraisal of the Fountain Creek alluvial aquifer between Colorado Springs and Pueblo, Colorado, including trace elements and organic constituents

This report describes the hydrology and chemical quality of water in the stream-aquifer system along Fountain Creek and relates groundwater quality to land use, water use, and wastewater discharges. The alluvial aquifer, which is underlain by shale bedrock, is transmissive, extensively pumped, and primarily is recharged by Fountain Creek and irrigation-return flow. Groundwater flows south about 20 ft/day, average residence time is less than 10 yr. Land use primarily is urban in the northern one-third and agricultural in the southern two-thirds of the area. Major ions, boron, iron, lithium, selenium, strontium, and uranium increased in concentration downgradient. The largest concentrations of nitrogen and detergents were in the northern end of the area because of recharge of sewage effluent in Fountain Creek. Other trace elements usually were present in concentrations less than 20 mg/L. Volatile organic compounds were detected in water from 11 of 20 wells sampled. Samples from 4 of the 20 wells were analyzed for semivolatile organics using a closed-loop stripping technique, which detected additional compounds at nanogram/L concentrations. (USGS)

Water-Resources Investigations Report↗

USGS1987

Hydrogeology, degradation of ground-water quality, and simulation of infiltration from the Delaware River into the Potomac aquifers, northern Delaware

Brackish water is infiltrating from the Delaware River into the underlying Potomac aquifers in the Cretaceous Potomac Formation in northern Delaware. Evidence that infiltration at the river is actually occurring includes chloride concentrations in the aquifers that are above ambient levels and chemical characteristics of groundwater and river water that are similar. Water quality within the Potomac aquifers has been degraded by the infiltration of river water and by leachate from waste disposal sites. The ambient groundwater has chloride concentrations from 10 to 21 mg/L. Chemical analyses indicate that the ambient groundwater is a sodium magnesium calcium-chloride sulfate bicarbonate type. Areas of the Potomac aquifers that have been degraded have chloride concentrations from 40 to 8,600 m/L, with specific conductances of 200 to 27 ,200 microsiemens/cm at 25 C. Chemical analyses indicate the groundwater in these areas is a sodium-chlorate type. Two wells in the lower Potomac aquifer near the Wilmington Marine Terminal also have been affected by the infiltration of river water. Leachate from waste disposal sites has caused localized groundwater degradation in all three Potomac aquifers, especially north of the Delaware Memorial Bridge and at sites near Army Creek and Red Lion Creek. Chloride concentrations up to 8,600 mg/L have resulted from waste disposal leachate. Simulated infiltration of river water into the Potomac aquifers accounts for approximately 6 to 12% of the total aquifer recharge in the area of influence of the pumping. There is a direct correlation between the rate of infiltration of river water and the total well-field pumpage. The rate of infiltration of river water for the pumping scenarios ranged from 0.31 to 0.62 million gal/day. Simulations of freshwater injection demonstrated that 12 barriers wells, each injecting 300 gal/min, would be needed to create a barrier against the infiltration of river water in the upper Potomac aquifer, whereas the middle Potomac aquifer would require 7 wells in injecting 200 gal/min. (Author 's abstract)

Water-Resources Investigations Report↗