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At least 1,153 records · Page 64Linked to original sources
USGS2002

Estimating the magnitude of annual peak discharges with recurrence intervals between 1.1 and 3.0 years for rural, unregulated streams in West Virginia

Multiple and simple least-squares regression models for the log10-transformed 1.5- and 2-year recurrence intervals of peak discharges with independent variables describing the basin characteristics (log10-transformed and untransformed) for 236 streamflow-gaging stations were evaluated, and the regression residuals were plotted as areal distributions that defined three regions in West Virginia designated as East, North, and South. Regional equations for the 1.1-, 1.2-, 1.3-, 1.4-, 1.5-, 1.6-, 1.7-, 1.8-, 1.9-, 2.0-, 2.5-, and 3-year recurrence intervals of peak discharges were determined by generalized least-squares regression. Log10-transformed drainage area was the most significant independent variable for all regions. Equations developed in this study are applicable only to rural, unregulated streams within the boundaries of West Virginia. The accuracies of estimating equations are quantified by measuring the average prediction error (from 27.4 to 52.4 percent) and equivalent years of record (from 1.1 to 3.4 years).

Water-Resources Investigations Report↗
USGS2002

Water, ice, and meteorological measurements at South Cascade Glacier, Washington, 2000-01 balance years

Winter snow accumulation and summer snow, firn, and ice melt were measured at South Cascade Glacier, Washington, to determine the winter and net balances for the 2000 and 2001 balance years. In 2000, the winter balance, averaged over the glacier, was 3.32 meters, and the net balance was 0.38 meters. The winter balance was the ninth highest since the record began in 1959. The net balance was greater than 33 of the 41 years since 1959. In 2001, the winter balance was 1.90 meters, and net balance was -1.57 meters. The winter balance was lower than all but 4 years since 1959, and the net balance was more negative than all but 5 other years. Runoff was measured from the glacier basin and an adjacent non-glacierized basin. Air temperature, precipitation, humidity, wind speed and solar radiation were measured nearby. Ice displacements were measured for the 1998-2001 period.

Water-Resources Investigations Report↗
USGS2002

Detection of fresh ground water and a contaminant plume beneath Red Brook Harbor, Cape Cod, Massachusetts, 2000

Trichloroethene and tetrachloroethene were detected in ground water in a vertical interval from about 68 to 176 feet below sea level beneath the shoreline where the contaminant plume emanating from a capped landfill on the Massachusetts Military Reservation intersects Red Brook Harbor. The highest concentrations at the shoreline, about 15 micrograms per liter of trichloroethene and 1 microgram per liter of tetrachloroethene, were measured in samples from one well at about 176 feet below sea level. The concentrations of nutrients, such as nitrate and ammonium, and trace metals, such as iron and manganese, in these same samples are typical of uncontaminated ground water on Cape Cod. Fresh ground water (bulk electrical conductance less than 100 millisiemens per meter) is present beneath the harbor at 40 of 48 locations investigated within about 250 feet of the shoreline. Fresh ground water also was detected at one location approximately 450 feet from shore. The harbor bottom consists of soft sediments that range in thickness from 0 to greater than 20 feet and overlie sandy aquifer materials. Trichloroethene was detected at several locations in fresh ground water from the sandy aquifer materials beneath the harbor. The highest trichloroethene concentration, about 4.5 micrograms per liter, was measured about 450 feet from shore.

Massachusetts↗
USGS2002

Hydrogeology, ground-water use, and ground-water levels in the Mill Creek Valley near Evendale, Ohio

Withdrawals of ground water in the central Mill Creek Valley near Evendale, Ohio, caused water-level declines of more than 100 feet by the 1950s. Since the 1950s, management practices have changed to reduce the withdrawals of ground water, and recovery of water levels in long-term monitoring wells in the valley has been documented. Changing conditions such as these prompted a survey of water use, streamflow conditions, and water levels in several aquifers in the central Mill Creek Valley, Hamilton and Butler Counties, Ohio. Geohydrologic information, water use, and water levels were compiled from historical records and collected during the regional survey. Data collected during the survey are presented in terms of updated geohydrologic information, water use in the study area, water levels in the aquifers, and interactions between ground water and surface water. Some of the data are concentrated at former Air Force Plant 36 (AFP36), which is collocated with the General Electric Aircraft Engines (GEAE) plant, and these data are used to describe geohydrology and water levels on a more local scale at and near the plant. A comparison of past and current ground-water use and levels indicates that the demand for ground water is decreasing and water levels are rising. Before 1955, most of the major industrial ground-water users had their own wells, ground water was mined from a confined surficial (lower) aquifer, and water levels were more than 100 feet below their predevelopment level. Since 1955, however, these users have been purchasing their water from the city of Cincinnati or a private water purveyor. The cities of Reading and Lockland, both producers of municipal ground-water supplies in the area, shut down their well fields within their city limits. Because the demand for ground-water supplies in the valley has lessened greatly since the 1950s, withdrawals have decreased, and, consequently, water levels in the lower aquifer are 65 to 105 feet higher than they were in 1955. During the time of the water-level survey (November 2000), ground water was being pumped from four locations in the lower aquifer, including three municipalities and one remediation site. Effects of pumping in those four areas were evident from the regional water-level data. Overall, the direction of ground-water flow in the lower aquifer is from northeast to southwest along the primary orientation of the Mill Creek Valley in the study area. Water levels in shallower surficial aquifers were mapped at local scales centered on GEAE. Examination of well logs indicated that these aquifers (called shallow and water-table) are discontinuous and, on a regional scale, few wells were completed in these aquifers. Water levels in the shallow aquifer indicated that flow was from northeast to southwest except in areas where pumping in the lower aquifer or the proximity of Mill Creek may have been affecting water levels in the shallow aquifer. Water levels in the water-table aquifer indicated flow toward Mill Creek from GEAE.

Water-Resources Investigations Report↗
USGS2002

Sedimentation Survey of Lago Guerrero, Puerto Rico, May 2001

Lago Guerrero, a small reservoir owned by the Puerto Rico Electric Power Authority, is part of the Isabela Hydroelectric System and is located in Aguadilla, in northwestern Puerto Rico. The reservoir had a storage capacity of about 127,376 cubic meters in May 2001 and a maximum depth of about 5.8 meters. Records on dam construction and original topography and storage capacity were not available; therefore, sedimentation rates could not be determined. However, Lago Guerrero resumably was constructed during the 1930?s because it receives water from lago Guajataca, which was constructed in 1928. The May 2001 bathymetric survey of Lago Guerrero established baseline data that are essential to calculate sedimentation rates, sediment yields, storage loss, and sediment deposition sites within the reservoir.

Water-Resources Investigations Report↗
USGS2002

Sediment accumulation and distribution in Lake Kampeska, Watertown, South Dakota

Lake Kampeska is a natural lake of about 5,075 acres located within the city limits of Watertown, South Dakota. The lake is important as a water supply and recreational resource. Sediment accumulation has been a concern for many years, and several studies have been conducted to learn more about the sediment, including how fast it is accumulating. This study attempted to evaluate previously estimated sediment-accumulation rates and to describe the distribution of sediment in the lake. Analysis of cesium-137 concentrations in sediment cores and changes in lake-bottom elevation over time led to the conclusion that during about the last 50 years, the sediment has been accumulating at a rate on the order of 0.01 foot per year or less. Changes in lake-bottom elevation during this time period indicate that the only significant deposition occurred in the area near the connection of Lake Kampeska to the Big Sioux River. Direct physical measurements and marine seismic surveys indicate that the flat-bottom interior part of the lake has 10 feet or more of sediment over a relatively irregular subbottom.

Water-Resources Investigations Report↗
USGS2002

Calculation of individual isotope equilibrium constants for implementation in geochemical models

Theory is derived from the work of Urey to calculate equilibrium constants commonly used in geochemical equilibrium and reaction-transport models for reactions of individual isotopic species. Urey showed that equilibrium constants of isotope exchange reactions for molecules that contain two or more atoms of the same element in equivalent positions are related to isotope fractionation factors by , where is n the number of atoms exchanged. This relation is extended to include species containing multiple isotopes, for example and , and to include the effects of nonideality. The equilibrium constants of the isotope exchange reactions provide a basis for calculating the individual isotope equilibrium constants for the geochemical modeling reactions. The temperature dependence of the individual isotope equilibrium constants can be calculated from the temperature dependence of the fractionation factors. Equilibrium constants are calculated for all species that can be formed from and selected species containing , in the molecules and the ion pairs with where the subscripts g, aq, l, and s refer to gas, aqueous, liquid, and solid, respectively. These equilibrium constants are used in the geochemical model PHREEQC to produce an equilibrium and reaction-transport model that includes these isotopic species. Methods are presented for calculation of the individual isotope equilibrium constants for the asymmetric bicarbonate ion. An example calculates the equilibrium of multiple isotopes among multiple species and phases.

Water-Resources Investigations Report↗
USGS2002

Effects of urbanization and long-term rainfall on the occurrence of organic compounds and trace elements in reservoir sediment cores, streambed sediment, and fish tissue from the Santa Ana River basin, California, 1998

Organcochlorine compounds, semivolatile-organic compounds (SVOC), and trace elements were analyzed in reservoir sediment cores, streambed sediment, and fish tissue in the Santa Ana River Basin as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Three reservoirs were sampled in areas that have different degrees of urbanization. Streambed sediment and fish tissue collected at 12 sites were divided into two groups, urban and nonurban. More organochlorine compounds were detected in reservoir sediment cores, streambed sediment and fish tissue, and at higher concentrations at urban sites than at nonurban sites. At all sites, except West Street Basin, concentrations of organochlorine compounds were lower than the probable-effect concentration (PEC). At the highly urbanized West Street Basin, chlordane and p,p'-DDE exceeded the PEC throughout the historical record. The less stringent threshold-effect concentration (TEC) was exceeded for six compounds at eight sites. Most of the organochlorine compounds detected in streambed sediment and fish tissue were at urban sites on the Santa Ana River as opposed to its tributaries, suggesting accumulation and persistence in the river. More SVOCs were detected in reservoir sediment cores and streambed sediment, and at higher concentrations, at urban sites than at nonurban sites. At all the sites, except West Street Basin, concentrations of SVOCs were lower than the PEC. At West Street Basin, chrysene, pyrene, and total polycyclic-aromatic hydrocarbons exceeded the PEC throughout the historical record. The TEC was exceeded for 10 compounds at 3 sites. Most of the SVOCs were detected in streambed sediment at urban sites on tributaries to the Santa Ana River rather than the mainstem itself. The less frequent occurrence and lower concentrations in the Santa Ana River suggest that SVOCs are less persistent than organochlorine compounds, possibly as a result of volatization, gradation, or dilution. Most trace-element detections in reservoir sediment cores and streambed sediment were at urban sites, and the concentrations were generally higher than at nonurban sites. Lead and zinc exceeded their PECs at West Street Basin throughout the historical record; copper exceeded its PEC at Canyon Lake, an area of urban growth. The TEC was exceeded for 10 compounds at 11 sites. Frequency of detection and concentration did not differ between tributary and Santa Ana River sites, which may be attributed to the fact that trace elements occur naturally. Four trace elements (arsenic, copper, mercury, and selenium) had higher concentrations in fish tissue at nonurban sites than at urban sites. Concentrations decreased over time for organochlorine compounds at all three reservoirs, probably a result of the discontinued use of many of the compounds. Decreasing trends in SVOCs and trace elements were observed at West Street Basin, but increasing trends were observed at Canyon Lake. Concentrations of organochlorine compounds, SVOCs, and trace elements were higher during periods of above average rainfall at both West Street Basin and Canyon Lake.

Water-Resources Investigations Report↗
USGS2002

Interdecadal changes in the hydrometeorological regime of the Pacific Northwest and in the regional-to-hemispheric climate regimes, and their linkages

Selected hydrometeorological (HM) data for the Pacific Northwest, and regional-to-hemispheric atmospheric-circulation data and sea-surface temperature (SST) data for the North Pacific, are examined for three successive interdecadal periods that are subsets of the instrumental record in order to estimate if their characteristics have changed. The HM data included monthly precipitation totals for 50 sites in western Washington and 29 climate divisions of the Pacific Northwest, and streamflow averages for 112 sites in Washington, Oregon, and Idaho. The atmospheric data included the Southern Oscillation Index (SOI), an index of the Pacific/North America (PNA) circulation pattern, measures of the westerly and northerly components of geostrophic flow, and a subset of the Northern Hemisphere 700-millibar geopotential height data; this subset of 162 grid points includes the area between 15 degrees and 75 degrees N, 110 degrees W and 130 degrees E. The SST data are for a 5-degree grid between 20 degrees N and 60 degrees N, 110 degrees W and 130 degrees E. The atmospheric and SST data were examined not only because the HM regime is linked to regional-to-hemispheric climate regimes, but also to estimate the extent of climate shifts displayed by these data. Three subsets of the record were identified as pre-1947 (PRE), 1947-76 (BASE), and post-1976 (POST) water years, based on an analysis of the HM data and previous studies. For each subset, means were calculated for the water year (October-September), the runoff season (March-August), the winter season (October-February), and a baseflow season (August-September). Differences in means and in ratios of the means between the BASE period and the PRE and POST periods were examined for changes. Winter-season mean precipitation during both the PRE and POST periods was smaller than the BASE period, indicating a spatially consistent and distinct change in the HM regime during winter during the PRE and POST periods. For the runoff season, mean precipitation at most sites, in comparison to the BASE period, was smaller during the PRE period and larger during POST period, indicating that different HM regimes occurred during the runoff season for the PRE and POST periods. Water-year mean precipitation was less for both the PRE and POST periods because of decreases in winter-season precipitation; however, the water-year values for the POST period were not as small as those of the PRE period because more precipitation was concentrated in the runoff season. During both the PRE and POST periods, the mean water-year discharge was less than the BASE period for all but 15 of the 112 sites. Fourteen of the 15 sites were in a well-defined region (southern Idaho and southeastern Oregon), and 13 of the 14 had larger means only during the POST period. Winter-season streamflow was less for all but 11 sites during both PRE and POST periods; the largest decreases in the mean, more than 30 percent, were for an area in central Oregon. Except for the sites that had larger mean water-year discharge, runoff-season means also were less than those during the BASE period. Changes in the SOI and PNA index from the BASE period were generally similar to and consistent with those of the majority of the hydrologic data; dissimilarities were in well-defined regions and are attributed to the evolutionary nature of the regime shifts. Negative values of the SOI for the POST period were more persistent than those that have occurred during both the PRE and BASE periods. The changes in the PNA index and the geostrophic flow components during the POST period are consistent with drier and warmer conditions in the Pacific Northwest. The 700-millibar data display trends and differences between the BASE and POST periods; differences in composite anomalies for selected winter months between these periods show a well-defined PNA pattern. For many areas of the North Pacific, the record of SSTs shows a significant long-term trend

Water-Resources Investigations Report↗
USGS2003

Occurrence and distribution of dissolved trace elements in the surface waters of the Yakima River basin, Washington

The occurrence, distribution, and transport of dissolved (filtered-water) trace elements in the surface waters of the Yakima River Basin were assessed using data collected between 1999 and 2000 as part of the U.S. Geological Survey s National Water-Quality Assessment (NAWQA) Program. Samples were collected at 34 sites throughout the basin in August 1999, using a Lagrangian sampling design. From May 1999 through January 2000, samples also were collected weekly during the irrigation season and once per month during the nonirrigation season at three intensive fixed sites. Although the focus of this study was on 9 trace elements (aluminum, arsenic, barium, copper, iron, manganese, nickel, uranium, and zinc), 14 additional elements were analyzed in filtered water. Concentrations of most trace elements in filtered water generally were low and there were no exceedances of the U.S. Environmental Protection Agency (USEPA) freshwater aquatic-life water-quality criteria. The USEPA drinking-water standard for arsenic (10 µg/L) was exceeded in two samples that were collected under base-flow conditions during the nonirrigation season at Granger Drain. Over 40 percent of all filtered-water samples collected during this study exceeded the USEPA health advisory level of 2.0 µg/L for arsenic. Arsenic concentrations in agricultural drains were highest when the drains were primarily fed by shallow ground water, and concentrations in the Yakima River were highest when the river was fed primarily by agricultural return flow. The USEPA secondary maximum contaminant level for manganese (50 µg/L) was exceeded in three samples collected at Granger Drain during the nonirrigation season. Instantaneous arsenic loads calculated for August 1999 were similar to mean monthly loads determined in August 1989 at two intensive fixed sites located on the Yakima main stem. In August 1999, arsenic loads increased twofold between the Yakima River at river mile 72 above Satus and the Yakima River at Kiona at river mile 29.9. The dissolved arsenic loads for the Yakima River at Euclid Bridge at river mile 55 near Grandview and Yakima River at Kiona were within 13 percent of the August 1989 levels.

Water-Resources Investigations Report↗
USGS2002

Trend analysis of ground-water levels and spring discharge in the Yucca Mountain Region, Nevada and California, 1960-2000

Ground-water level and discharge data from 1960 to 2000 were analyzed for the Yucca Mountain region of southern Nevada and eastern California. Included were water-level data from 37 wells and a fissure (Devils Hole) and discharge data from five springs and from a flowing well. Data were evaluated for variability and for upward, downward, or cyclic trends with an emphasis on the period 1992-2000. Potential factors causing trends in water levels and discharge include ground-water withdrawal, infiltration of precipitation, earthquakes, evapotranspiration, barometric pressure, and earth tides. Statistically significant trends in ground-water levels or spring discharge from 1992 to 2000 were upward at 12 water-level sites and downward at 14 water-level sites and 1 spring-discharge site. In general, the magnitude of the change in water level from 1992 to 2000 was small (less than 2 feet), except where influenced by pumping or local effects such as possible equilibration from well construction or diversion of nearby surface water. Seasonal trends are superimposed on some of the long-term (1992-2000) trends in water levels and discharge. Factors causing seasonal trends include barometric pressure, evapotranspiration, and pumping. The magnitude of seasonal change in water level can vary from as little as 0.05 foot in regional aquifers to greater than 5 feet in monitoring wells near large supply wells in the Amargosa Farms area. Three major episodes of earthquake activity affected water levels in wells in the Yucca Mountain region between 1992 and 2000: the Landers/Little Skull Mountain, Northridge, and Hector Mine earthquakes. The Landers/Little Skull Mountain earthquakes, in June 1992, had the largest observed effect on water levels and on discharge during the study period. Monthly measurements of wells in the study network show that earthquakes affected water levels from a few tenths of a foot to 3.5 feet. In the Ash Meadows area, water levels remained relatively stable from 1992 to 2000, with some water levels showing small rising trends and some declining slightly. Possible reasons for water-level fluctuations at sites AD-6 (Tracer Well 3), AM-5 (Devils Hole Well), and AM-4 (Devils Hole) from 1960 to 2000 include climate change, local and regional ground-water withdrawals, and tectonic activity. In Jackass Flats, water levels from 1992 to 2000 in six wells adjacent to Fortymile Wash displayed either small upward trends or no upward or downward trend. Comparison of trends in water levels from 1983 to 2000 for these six wells shows good correlations between all wells and suggests a common mechanism controlling water levels in the area. Of the likely controls on the system--precipitation or pumping in Jackass Flats--precipitation appears to be the predominant factor controlling water levels near Fortymile Wash. Water levels in the heavily pumped Amargosa Farms area declined from about 10 to 30 feet from 1964 to 2000. Water-level declines accelerated beginning in the early 1990's as pumping rates increased substantially. Pumping in the Amargosa Farms area may affect water levels in some wells as far away as 5-14 miles. The water level at site DV-3 (Travertine Point 1 Well) and discharge at site DV-2 (Navel Spring), both in the Death Valley hydrographic area, had downward trends from 1992 to 2000. The cause of these downward trends may be linked to earthquakes, pumping in the Amargosa Farms area, or both.

Water-Resources Investigations Report↗
USGS2002

Trace elements and organic compounds in streambed sediment and fish tissue of coastal New England streams, 1998-99

Streambed sediment and fish tissue were collected at 14 river sites in eastern New England during low-flow conditions in 1998 and 1999 as part of the New England Coastal Basins (NECB) study of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. Sampling sites were selected over a range of urban settings. Population densities at selected sites ranged from 26 to 3,585 people per square mile, and urban land use ranged from 1 to 68 percent. The streambed sediment samples were analyzed for a total of 141 contaminants, including 45 trace elements, 32 organochlorine compounds, and 64 semi-volatile organic compounds. The fish tissue samples were analyzed for 22 trace elements and 28 organochlorine compounds. Concentrations of selected contaminants in both streambed sediment and fish tissue correlated more strongly with population density than with other watershed characteristics. Cadmium, copper, lead, mercury, zinc, total polycyclic aromatic hydrocarbons (PAHs), total polychlorinated biphenyls (PCBs), dichloro diphenyl trichloroethane and metabolites (DDTM), and total chlordane in streambed sediment all showed strong positive correlations with population density (rho = 0.71 to 0.85, p value = 0.005 to <0.001). Correlations between population density and selected contaminants in fish tissue were less significant than with streambed sediment (rho = 0.62 to 0.72, p value = 0.03 to 0.008). Organic carbon concentrations were correlated with concentrations of arsenic, selenium, total PAHs, total PCBs, and DDTM in streambed sediment. The relation between concentrations of contaminants in streambed sediment and fish tissue was stronger for organochlorine compounds (rho = 0.75 to 0.55, p = 0.005 to 0.065) than for trace elements (rho = 0.63 to 0.53, p = 0.029 to 0.069). The NECB study area had the highest median concentrations of lead, mercury, total PAHs, total PCBs, and DDTM in streambed sediment and the highest median concentration of PCBs in fish tissue compared to 45 other NAWQA study units across the Nation. Concentrations of many of these constituents in streambed sediment also were frequently above the consensus-based Sediment-Quality Guidelines for the protection of wildlife, suggesting they are a threat to the health of aquatic biota in New England.

Water-Resources Investigations Report↗
USGS2002

Water quality of springs in the Valley and Ridge Physiographic Province in the upper Tennessee River basin, 1997

In the fall of 1997, 35 springs in the carbonate rocks of the Valley and Ridge Physiographic Province of the upper Tennessee River Basin were sampled for nutrients, fecal-indicator bacteria, pesticides, and volatile organic compounds (VOCs) as part of the National Water-Quality Assessment (NAWQA) Program. About half of the randomly selected springs were used as untreated domestic drinking-water supplies, either by direct pumpage from the spring or as roadside filling sites. Nutrient concentrations generally were less than 2 milligrams per liter. Nitrate, the most frequently detected nutrient, ranged from 0.091 to 2.17 milligrams per liter, with a median concentration of 1.16 milligrams per liter. Fecal-indicator bacteria were detected at all springs, with total coliform ranging from 10 to 1,900 colonies per 100 milliliters and Escherichia coli ranging from less than 1 to 660 colonies per 100 milliliters. Concentrations of bacteria at all springs sampled exceeded bacteriological drinking-water standards for public water supplies. Eight pesticides or degradation byproducts, all below U.S. Environmental Protection Agency drinking-water maximum contaminant levels, were detected in samples from 24 of the 35 springs. The most frequently detected pesticide was atrazine and its degradation byproduct, deethylatrazine, which were found in water samples from 57 and 54 percent of the springs, respectively. Some pesticides were detected more frequently in water samples from the springs than in ground-water samples from wells in similar NAWQA studies nationwide. Concentrations of VOCs in the springs also were below maximum contaminant levels. The most frequently detected VOCs were chloroform (20 springs), methyl chloride (18 springs), styrene (12 springs), and tetrachloroethene (11 springs). These detection frequencies of VOCs are consistent with the national NAWQA results when comparing wells and springs in a mixture of urban and rural land uses.

Water-Resources Investigations Report↗
USGS2002

Response of the St. Croix River pools, Wisconsin and Minnesota, to various phosphorus-loading scenarios

The pools in the lower reach of the St. Croix National Scenic Riverway, Wisconsin and Minnesota, and the adjoining Lake Mallalieu, are eutrophic because of high phosphorus loading. To determine how changes in phosphorus loading would affect the trophic status of these pools, the water-quality model, BATHTUB, was used to simulate existing (1999) water quality and simulate the water quality with various phosphorus-loading scenarios. Water quality in the pools may respond differently during different flow regimes; therefore, sensitivity and scenario evaluations were performed not only for 1999, but also for a simulated period with relatively low flows throughout the basin (using flow data from 1988) and for a simulated period with relatively high flows throughout the basin (using flow data from 1996). On the basis of the BATHTUB simulations, linear increases in phosphorus loading should cause the following changes in water quality in each of the pools: linear increases in phosphorus concentrations, although at a smaller rate than the increase in loading; non-linear increases in chlorophyll a concentrations, with a smaller relative response with higher phosphorus loading; increase in the frequency of algal blooms, with a higher frequency of intense algal blooms; and slightly decreased water clarity. The response in water quality to changes in the phosphorus loading should be relatively similar regardless of the flow regime. Reducing phosphorus loading by about 50 percent would be necessary for the Lake St. Croix pools to be classified as mesotrophic with respect to phosphorus and chlorophyll a concentrations, whereas a larger reduction in phosphorus loading would be needed for Lake Mallalieu to be classified as mesotrophic. Even with these reductions, water clarity will remain poor because of the high non-algal turbidity and stained water in the pools.

Minnesota, Wisconsin↗
USGS2002

Investigation of water quality and aquatic-community structure in Village and Valley Creeks, City of Birmingham, Jefferson County, Alabama, 2000-01

The U.S. Geological Survey conducted a 16-month investigation of water quality, aquatic-community structure, bed sediment, and fish tissue in Village and Valley Creeks, two urban streams that drain areas of highly intensive residential, commercial, and industrial land use in Birmingham, Alabama. Water-quality data were collected between February 2000 and March 2001 at four sites on Village Creek, three sites on Valley Creek, and at two reference sites near Birmingham?Fivemile Creek and Little Cahaba River, both of which drain less-urbanized areas. Stream samples were analyzed for major ions, nutrients, fecal bacteria, trace and major elements, pesticides, and selected organic constituents. Bed-sediment and fish-tissue samples were analyzed for trace and major elements, pesticides, polychlorinated biphenyls, and additional organic compounds. Aquatic-community structure was evaluated by conducting one survey of the fish community and in-stream habitat and two surveys of the benthic-invertebrate community. Bed-sediment and fish-tissue samples, benthic-invertebrates, and habitat data were collected between June 2000 and October 2000 at six of the nine water-quality sites; fish communities were evaluated in April and May 2001 at the six sites where habitat and benthic-invertebrate data were collected. The occurrence and distribution of chemical constituents in the water column and bed sediment provided an initial assessment of water quality in the streams. The structure of the aquatic communities, the physical condition of the fish, and the chemical analyses of fish tissue provided an indication of the cumulative effects of water quality on the aquatic biota. Water chemistry was similar at all sites, characterized by strong calcium-bicarbonate component and magnesium components. Median concentrations of total nitrogen and total phosphorus were highest at the headwaters of Valley Creek and lowest at the reference site on Fivemile Creek. In Village Creek, median concentrations of nitrite and ammonia increased in a downstream direction. In Valley Creek, median concentrations of nitrate, nitrite, ammonia, organic nitrogen, suspended phosphorus, and orthophosphate decreased in a downstream direction. Median concentrations of Escherichia coli and fecal coliform bacteria were highest at the most upstream site of Valley Creek and lowest at the reference site on Fivemile Creek. Concentrations of enterococci exceeded the U.S. Environmental Protection Agency criterion in 80 percent of the samples; concentrations of Escherichia coli exceeded the criterion in 56 percent of the samples. Concentrations of bacteria at the downstream sites on Village and Valley Creeks were elevated during high flow rather than low flow, indicating the presence of nonpoint sources. Surface-water samples were analyzed for chemical compounds that are commonly found in wastewater and urban runoff. The median number of wastewater indicators was highest at the most upstream site on Valley Creek and lowest at the reference site on Fivemile Creek. Concentrations of total recoverable cadmium, copper, lead, and zinc in surface water exceeded acute and chronic aquatic life criteria in up to 24 percent of the samples that were analyzed for trace and major elements. High concentrations of trace and major elements in the water column were detected most frequently during high flow, indicating the presence of nonpoint sources. Of the 24 pesticides detected in surface water, 17 were herbicides and 7 were insecticides. Atrazine, simazine, and prometon were the most commonly detected herbicides; diazinon, chlorpyrifos, and carbaryl were the most commonly detected insecticides. Concentrations of atrazine, carbaryl, chlorpyrifos, diazinon, and malathion periodically exceeded criteria for the protection of aquatic life. Trace-element priority pollutants, pesticides, and other organic compounds were detected in higher concentrations in bed sediment at the Village and Valley Creek sites t

Water-Resources Investigations Report↗
USGS2003

Occurrence and transport of cadmium, lead, and zinc in the Spokane River basin, Idaho and Washington, water years 1999-2001

A water-quality investigation of the Clark Fork-Pend Oreille and Spokane River Basins began in 1997 as part of the U.S. Geological Survey National Water-Quality Assessment Program. As part of the investigation, selected streams in the Spokane River Basin were sampled for trace metals during water years 1999–2001. These data, combined with data collected as part of a U.S. Environmental Protection Agency Remedial Investigation/ Feasibility Study, were used to assess the occurrence, loads, and transport of cadmium, lead, and zinc at 21 streamflow-gaging stations in the Spokane River Basin. Concentrations of dissolved and total cadmium, lead, and zinc varied widely both at and among stations. At most stations, dissolved cadmium and zinc composed most of the total concentrations; dissolved lead generally composed less than 10 percent of the total lead concentration. From the South Fork Coeur d’Alene River near Mullan downstream to the South Fork Coeur d’Alene River near Pinehurst, concentrations of trace metals increased 2 to 4 orders of magnitude. The mean flow-weighted concentrations of total cadmium, lead, and zinc near Pinehurst for water years 1999–2001 were 5.7, 80, and 810 micrograms per liter ( µg/L), respectively. On the Coeur d’Alene River near Harrison, downstream from the confluence of the metal-enriched South Fork and the relatively dilute North Fork Coeur d’Alene River, the mean flow-weighted concentrations of total cadmium, lead, and zinc were 1.6, 88, and 240 µg/L, respectively. Trace-metal concentrations were smaller in the Spokane River than in the Coeur d’Alene River because of dilution and retention in Coeur d’Alene Lake. The mean flowweighted concentrations of total cadmium, lead, and zinc in the Spokane River near Post Falls were 0.32, 3.1, and 71 µg/L, respectively. Regression models relating the mass transport, or load, of trace metals to changes in stream discharge and time were successful in simulating the variability in trace-metal concentrations and loads. The median coefficient of determination for the load models for the 21 stations was largest for total lead (92 percent) and smallest for dissolved and total cadmium (82 percent). Whereas most of the cadmium and zinc loads in the Spokane River Basin were derived from the South Fork Coeur d’Alene River, most of the lead load was derived from the Coeur d’Alene River downstream from the confluence of the North and South Forks. Major tributary sources of trace metals to the South Fork Coeur d’Alene River were Canyon Creek, Ninemile Creek, and Government Gulch. These three tributaries contributed about 3,000 pounds of cadmium, 23,000 pounds of lead, and 310,000 pounds of zinc annually to the South Fork Coeur d’Alene River. Erosion and transport of sediment-bound lead in the Coeur d’Alene River was the primary source of total lead, accounting for almost 400,000 pounds annually during water years 1999–2000. Ground-water discharge in the area of the Bunker Hill Superfund site was a major source of zinc in the South Fork Coeur d’Alene River, contributing more than 250,000 pounds per year. During water years 1999–2000, the average annual loads of cadmium, lead, and zinc transported from the Coeur d’Alene, St. Joe, and St. Maries Rivers to Coeur d’Alene Lake were 8,900, 500,000, and 1.4 million pounds, respectively. The Coeur d’Alene River accounted for more than 99 percent of the total load of each of these three metals entering the lake. About 4,600 pounds of cadmium, 44,000 pounds of lead, and 980,000 pounds of zinc were transported from Coeur d’Alene Lake into the Spokane River. Between the Spokane River near Post Falls, Idaho, and the Spokane River at Long Lake, Washington, there was an annual net loss of about 2,600, 20,000, and 250,000 pounds of cadmium, lead, and zinc, respectively. About 2,000 pounds of cadmium, 24,000 pounds of lead, and 730,000 pounds of zinc were transported annually downstream from Long Lake toward the Columbia River.

Idaho;Washington↗