USGS Science⌕ Search

SEARCH · USGS Science

Results for “Water Supply Paper”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,153 records · Page 64Linked to original sources
USGS1967

Form and stability of aluminum hydroxide complexes in dilute solution

Laboratory studies of solutions 4.53 x 10 -4 to 4.5 x 10 -5 molal (12.2-1.2 ppm) in aluminum, in 0.01 molal sodium perchlorate, were conducted to obtain information as to the probable behavior of aluminum in natural water. When the solutions were brought to pH 7.5-9.5 and allowed to stand for 24 hours, a precipitate was obtained which was virtually amorphous as shown by X-rays, and which had a solubility equivalent to that of boehmite. This precipitate had a hydrolysis constant (*Ks4) of 1.93 x 10 -13a. When solutions were allowed to stead at this pH range for 10 days, their precipitates gave the X-ray pattern of bayerite (*Ks4 = 1.11 > (10- 4). These hydrolysis constants were obtained at 25?C. and corrected to zero ionic strength and are in close agreement with other published values. The predominant dissolved form in this pH range is Al(OH) -4. Below neutral pH (7.0) the dissolved aluminum species consist of octahedral units in which each aluminum ion is surrounded by six water molecules or hydroxide ions. Single units such as Al(OH2)6 + 3 and AlOH(OH2)5+2 are most abundant below pH 5.0, and where the molar ratio (r) of combined hydroxide to total dissolved aluminum is low. When r is greater than 1.0, polymerization of the octahedral units occurs. When r is between 2.0 and 3.0, solutions aged for 10 days or more contained colloidal particles between 0.10 and 0.45 ? in diameter. Particles whose diameters were greater than 0.10 ? were identified by X-ray diffraction as gibbsite. Particles smaller than 0.10 ? were also present and were shown by means of the electron microscope to have a hexagonal crystal pattern. Structured material consisting of sheets of coalesced six-membered rings of aluminum ions held together by double OH bridges has a distinctive kinetic behavior. This property was used to determine amounts of polymerized material in solutions having r between 1.0 and 3.0 after aging times ranging from a few hours to more than 4 months. Aging increased the size and orderliness of the polymeric aggregates and was accompanied by a decrease in the pH of the solution. The kinetic experiments and stoichiometric data for solutions aged for long periods provided a means of determining activities of polymerized aluminum. From these values the solubility product for microcrystalline gibbsite was determined to be 2.24 x 10 -3, and its free energy of formation, -? 272.3 0.4 kcal per mole. Where polymerization was observed, the process did not stop with small polynuclear complexes containing a few aluminum ions, but proceeded with aging until macromolecules or colloidal-sized particles were formed.

Water Supply Paper↗
USGS1969

Solubility of aluminum in the presence of hydroxide, fluoride, and sulfate

The total concentration of aqueous dissolved species of aluminum that will be present in equilibrium with microcrystalline gibbsite at various levels of complexing ligand concentration are shown graphically. The graphs can be used to estimate aluminum solubility, at 25?C and 1 atmosphere total pressure, when the pH of the solution, its ionic strength, and the total sulfate and fluoride concentrations are known. The standard free energy of formation of cryolite calculated from solubility experiments is --745.4 ? 1.0 kcal per mole at 25?C. Diagrams are included showing the solubility of cryolite in terms of aluminum, fluoride, and sodium concentrations. The stability fields of cryolite and microcrystalline gibbsite and their solubilities also are shown on pH-[F] diagrams.

Water Supply Paper↗
USGS1972

Effect of aging on aluminum hydroxide complexes in dilute aqueous solutions

Aqueous aluminum solutions containing 4?10 -5 mole/liter aluminum and a constant total ionic strength of 10 -2, but with varying ratios of hydroxide to aluminum (OH:Al), were prepared. Progress of these solutions toward equilibrium conditions over aging periods of as much as 2 years was studied by determining the composition and pH of the solutions at various time intervals. The solutions, after mixing, were supersaturated with respect to both crystalline and amorphous forms of aluminum oxides and aluminum hydroxides. The compositions of the solutions were determined by use of a timed colorimetric analytical procedure which allowed the estimation of three separate forms of aluminum that have been designated Al a, Al b, and Al c. Form Al a appeared to be composed of monomeric species such as Al(H20)6+3, Al(OH)(H20)5+2, Al(OH)2(H20)4 +I and Al(OH)4-. Form Al b was polynuclear material containing perhaps 20-400 aluminum atoms per structure. It appeared to be a metastable material. Form Al c was composed of relatively large, microcrystalline, clearly solid AI(OH)3 particles. For each OH :Al ratio, the concentration of Al a remained constant with aging time, Al b decreased, and Al c increased. It appeared that Al b particles were increasing in size and ultimately were converted to Al c particles. After a few weeks' aging, Al c particles had the structure of gibbsite. In all solutions, equilibrium was only very slowly achieved, and the time required depended on the OH:Al ratio and how rapidly the solution was initially prepared (mixing time). Lower ratios caused a slower approach to equilibrium; sometimes equilibrium was not achieved even after several years' aging. The more slowly base was initially added (to obtain the proper OH:Al ratio), the more slowly was equilibrium approached. Ultimate equilibrium values of dissolved aluminum concentration and pH were consistent with known thermodynamic data on monomeric aluminum species. From data determined during the aging study and by considering Al b material to consist of extremely small solid gibbsite particles, it was possible to estimate the Gibbs free energy of the (001) crystal face (?F, the gibbsite 'face') and the. Gibbs free energy of the (110) and (100) crystal faces (?E, the gibbsite 'edge') of gibbsite in equilibrium with its saturated solution. These values were: ?F=1404 ? 24 ergs/cm 2, and ?E = 483 ?-84 ergs/cm 2.

Water Supply Paper↗
USGS1973

Chemical interactions of aluminum with aqueous silica at 25 degrees Celsius

Solutions containing from 10 -5 to 10 -2 moles per liter of aluminum and dissolved silica in various ratios were aged at pH levels between 4 and 10 at 25?C. A colloidal amorphous product having the composition of halloysite was produced in most solutions. It had a consistent and reversible equilibrium solubility equivalent to a standard free energy of formation of -8974 ? 1.0 kcal per mole for the formula A12Si2O5(OH)4. Some aging times were longer than 4 years, but most solutions gave consistent solubilities after only a few months of aging. Where silica concentrations were below about 10 -4 molar, microcrystalline gibbsite was formed below pH 6.0 and crystalline bayerite above pH 7.0, but only after much longer aging than was required for crystallization in silica-free solutions. Electron micrographs and diffraction patterns of the synthesized material indicate some crystallinity in the aluminosilicate, but no X-ray diffraction patterns could be obtained even in the material aged 4 years. Solubility relationships for solutions containing fluoride as well as silica and aluminum are explainable by using cryolite stabilities determined in previous work. Aluminum contents of 51 samples of water analyzed for other purposes are in reasonable agreement with the assumption of equilibrium with amorphous clay mineral species similar to the material synthesized in this work. Solubility calculations are summarized graphically for solutions of ionic strength of 0.01 and 0.10.

Water Supply Paper↗
USGS1975

Reactions of aqueous aluminum species at mineral surfaces

Aqueous aluminum solutions containing 4.5 ? 10 4 molar aluminum in 0.01 molar NaC104 were partly neutralized with NaOH to give OH:A1 mole ratios from 1.40 to 2.76. Measured amounts of montmorillonite, kaolinite, volcanic ash, or feldspathic sand were added to provide an area of inert surface. Reactions that occurred during 100 days of aging were compared with those in similar solutions without added surfaces, studied in earlier work. Adsorption of monomeric species Al(H20)6+3, AlOH(H2O)5+2, and Al(OH)2(H2O 4? on the added surfaces follows a cation exchange mass law equilibrium model, and adsorption is essentially complete in 1 hour. Only minor changes in monomeric aluminum species occurred after that. Rapid adsorption of polynuclear aluminum hydroxide species also occurs and follows the pattern of the Langmuir adsorption isotherm. In the absence of surfaces, the polynuclear ions slowly increase in size and become microcrystalline gibbsite during aging. Electron micrographs showed microcrystalline gibbsite was present or surfaces after aging only 2 days. However, the analytical data suggest this material must have been adsorbed after it had already attained a near-crystalline state. Adsorbed polynuclear aluminum hydroxide species were not extensively converted to microcrystalline gibbsite during 100 days of aging.

Water Supply Paper↗
USGS1967

Geology and hydrology between Lake McMillan and Carlsbad Springs, Eddy County, New Mexico

The hydrology of the Pecos River valley between Lake McMillan and Carlsbad Springs, Eddy County, N. Mex., is influenced by facies changes in rocks of Permian age. Water stored for irrigation leaks from Lake McMillan into evaporite rocks, principally gypsum, of the Seven Rivers Formation and from Lake Avalon into carbonate rocks of the Tansill Formation. This leakage returns to the Pecos River at Major Johnson Springs and Carlsbad Springs. The river has perennial flow between Major Johnson Springs and Lake Avalon, but it loses water into evaporite rocks of the Yates Formation in this reach. Ground-water movement is generally toward the Pecos River in aquifers in the Pecos River valley except in the Rustler Formation east of the river where it moves southeastward toward playas east of Lake Avalon. The chloride content of ground and surface waters indicates that surface water moves from some reaches of the Pecos River and from surface-storage reservoirs to aquifers and also indicates the degree of mixing of ground and surface waters. About 45,000 acre-feet of ground water is stored in highly permeable rocks in a 3-mile wide part of the Seven Rivers Formation between Lake McMillan and Major Johnson Springs. This water in storage comes from leakage from Lake McMillan and from alluvium north of the springs. The flow of Major Johnson Springs is derived from this aquifer. That part of the flow derived from the alluvium north of the springs averaged 13 cfs (cubic feet per second) from 1953 through 1959 ; about 8 cfs of this flow had not been previously measured at gaging stations on the Pecos River and its tributaries. The most favorable plans for increasing terminal storage of the Carlsbad Irrigation District are to construct a dam at the Brantley site (at the downstream end of Major Johnson Springs), or to use underground storage in the permeable Seven Rivers Formation between Lake McMillan and Major Johnson brings in conjunction with surface storage. To avoid excessive leakage from a reservoir at the Brantley site, the dam should be downstream from all sprints in the Major Johnson Springs area but upstream from a point where the river begin losing water to the Yates Formation.

Water Supply Paper↗
USGS1967

Swatara Creek basin of southeastern Pennsylvania: An evaluation of its hydrologic system

Local concentrations of population in the Swatara Creek basin of Pennsylvania find it necessary to store, transport, and treat water because local supplies are either deficient or have been contaminated by disposal of wastes in upstream areas. Water in the basin is available for the deficient areas and for dilution of the coal-mine drainage in the northern parts and the sewage wastes in the southern parts. Swatara Creek drains 576 square miles just east of Harrisburg, Pa., and is the largest tributary to the Susquehanna River from the north side below Harrisburg. It rises in the southern Pocono Mountains and flows southwestward across the Lebanon Plateau. On an average day Swatara Creek discharges more than 630 million gallons into the Susquehanna River at Middletown, Pa. In a year this amounts to about 23 inches of water over the entire basin and is the residual from an average annual precipitation of 45.5 inches. During an average year the flow in Swatara Creek from the upper third of the basin above Harper Tavern is always greater than 1,300 mgd (million gallons per day) for at least 15 days and is always greater than 25 mgd for at least 350 days. The daily streamflow from the basin averages 1.1 mgd per sq mi, but yields from different areas range from 0.97 to 1.22 mgd per sq mi. These variations are caused chiefly by differences in precipitation and land cover. The area of lowest yield is in the valleys west of Tremont, and the highest yields are in the Upper and Lower Little Swatara Creek subbasins. At high and medium stages the chemical character of the water in the streams is suitable for public and private supplies. At lower stages, defending on the areas and the amounts of contamination by coal-mine drainage and sewage pollution, the natural flow may require some treatment. At low stages the chemical characteristics of the natural flow not affected by man is almost identical with that of the ground water in the area drained by the stream. In general, the total dissolved solids range from about 25 to 400 parts per million and the hardness is as much as about 300 parts per million. The ground-water increment to the base flow of Swatara Creek averages about 240 mgd, or about 8.8 inches annually, for the basin. Generally, ground-water supplies in amounts of less than 0.5 mgd can be developed south of Blue Mountain. Supplies of several million gallons per day have been developed for industrial use from the permeable limestones in the south-central part of the basin. More intensive investigation in other parts of the basin would indicate areas where supplies of more than 0.5 mgd could be developed from properly spaced wells. The chemical character of water from wells depends largely on the host rock. In highly soluble rocks water contains large amount of dissolved solids; in more resistant rocks concentrations are lower. The chemical character of unpolluted ground water generally reflects the composition of the more readily soluble minerals in the local geologic environment. Areas contaminated by septic- tank effluent may have above normal amounts of nitrate and detergent products. Except where polluted, most ground water is suitable for public and industrial uses without extensive treatment. Sites for storage of surface water exist in the part of the basin lying in the valley and ridge area. As much as 30 to 40 percent of the annual flow could be impounded for release as low-flow augmentation for dilution of mine drainage and other wastes in the basin. Low sediment yields of supplying drainage areas would ensure a long life expectancy of reservoirs at these sites. Overbank flooding of the main stem of the Swatara Creek and its tributaries has occurred many times in the past. However, it has not been a hazard because urban development has not encroached on the flood plain. An inundation map of the August 1933 flood provides a basis that urban planners may use to avoid future damage. As water in the Swatara Creek moves downstream to the Susquehanna River, the flow is influenced consecutively by a large annual rainfall on the northern valley and ridge area, the wastes of surface and subsurface coal-mining activities, and less annual rainfall on the part of the basin lying in the Lebanon Plateau area; the flow is supplemented and further influenced by many tributaries and by the industrial and domestic wastes that are carried by these secondary streams. The annual precipitation ranges from 52 inches at the east edge and 49 inches at the west edge of the mountainous part of the basin to about 41 inches at the southwestern part at Middletown. The rainfall generally is adequate during the growing season to mature the crops. The mean annual temperature at Lebanon is about 52°F, and the growing season is about 180 days. In this report the basin has been divided into eight hydrologic zones, leased on runoff, natural use of water, and chemical character of water. Four zones lie in the valley and ridge area, three lie in the Lebanon Plateau area, and one lies in the highland along the southeastern basin boundary. In each of the zones the hydrologic characteristics are virtually the same, but they may be completely different from those in adjacent zones. The boundaries of the zones generally coincide with boundaries between geologic formations, and the areas in each zone include rocks of similar influence on water. Streams in zone 4 at the northeast edge of the plateau have the highest average surface runoff from 1.2 to 1.1 mgd per sq mi whereas those in zone 2 at the northwest edge of the valley and ridge area have the lowest, about 1.0 mgd. Streams in zone 8, along the southeast edge of the basin, have the largest sustained low-flow yield, about 0.26 to 0.19 mgd per sq mi; those in zone 5 overlying the Martinsburg Shale east of Harrisburg have the smallest sustained low-flow yields, 0.03 to 0.01 mgd. Streams in the limestone area of zone 7 have the greatest range in low-flow yields in any one zone from 0.60 to 0 mgd per sq mi. Low-flow yields in zones 1 through 4 range from 0.13 to 0.03 mgd per sq mi. Surface flows from zones 1 and 2 are generally acidic and contain high concentrations of sulfate, iron, and total dissolved solids especially where contaminated with mine wastes. Surface flows from zones 3 and 4 are dilute, slightly alkaline, and suitable for public water supplies. Surface flows from zones 5, 6, and 7 are alkaline and contain moderate concentrations of dissolved solids with waters of highest hardness occurring in zone 7. Surface flows from zone 8 are dilute to moderately mineralized and are relatively high in silica concentration. Nitrate concentrations are high in surf Fee flows below sewage outfalls and in ground water contaminated by septic tank effluent and industrial wastes. Average annual sediment yields of 550 to 650 tons per square mile are characteristic of zones 1 and 2 where strip mining has destroyed the forest cover and coal culm is carried into the streams. From agricultural lands on the Martinsburg Shale in zones 5 and 6, annual sediment yields range from 300 to 350 tons per square mile; but from agricultural lands on the siliceous rocks in zone 8 and zones 3 and 4 in the valley and ridge area, the sediment yield ranges from 200 to 250 tons annually per square mile. Lowest annual sediment yields in the basin are in the forested areas of siliceous rocks in zones 2, 3, 4, and 5, and in the sinkhole topography of the limestones in zone 7 where the yield ranges from 30 to 35 tons and 50 to 60 tons per square mile, respectively. The amount of ground water that can be developed in the basin is dependent on the ability of the underlying rocks to yield water to wells. More than 300 gpm (gallons per minute) can be obtained from wells in alluvial materials in the valley bottoms and in some of the limestones where large solution channels and fractures are penetrated by the wells. From 50 to 300 gpm can be obtained from wells in loosely cemented sandstones and in fractured limestones. From 10 to 50 gpm can be developed from wells in the shales and harder sandstones. The most dense rocks will yield from 1 to 10 gpm from fractures and crevices. Most wells yield water from the upper 350 feet of the formation, for this part contains the most fractures or solution channels. Studies show that the velocity at which a contaminant will move downstream in the basin is related to the discharge of the stream at the time. At a stream discharge of about 400 mgd at Pine Grove, a contaminant in Swatara Creek would require about 40 hours to move from Pine Grove to Middletown. As a result of dispersion and dilution, the maximum concentration of the contaminant at Middletown would be less than 20 percent the concentration at Pine Grove under these conditions. An evaluation of the availability of water in the basin indicates that about I,239 mgd enters as precipitation, 630 mgd leaves as streamflow, 580 mgd is evaporated and transpired, and 56 mgd is diverted for use by man. Not all the diversions for man's use are lost to the basin, as about 27 mgd is returned as sewage for reuse. About one-fourth of the waste water is returned to the ground and the remainder to stream drainageways. Of that diverted by man, 11.6 mgd is used for public supply and 44.4 mgd for industrial and private supplies. Diversions of streamflow furnish 86 percent of the public supply and 27 percent of the industrial supply, and ground-water sources yield the remainder. Municipal and private sewage treatment plants are upgrading the waste water in many places, but no provisions are being made for treatment other than natural dilution and assimilation for the 15 mgd of coal-nine drainage in the northern part of the basin. Technology for economic treatment of mine water is not available at this time, although research in this field is being done. Urbanization eastward from Harrisburg and around Lebanon has increased the population density of the basin. Densities of 500 people per square mile and water use exceeding 2.0 mgd per sq mi can be expected in the future. By the year 2000 the population of the basin may increase 60 percent; and if the per capita rate of use increases 0.5 percent per year the domestic requirements for water will be about two times the present use, or 23 mgd. Similarly, if the present 1:4 ratio of domestic use to industrial use of water continues, at least 89 mgd will be needed for industry in the future. Although an increase to twice the present use of water can be foreseen, or 112 mgd, water for the dilution and assimilation of wastes from treatment systems are not included. Providing water for dilution of wastes from treatment plants has not been a problem, but in the future the amounts needed for this purpose will be greater as the population increases. As water becomes more valuable, treatment of sewage wastes to reduce the biochemical-oxygen-demand load by at least 80 to 90 percent will be necessary to conserve water for more productive uses. As much as 100 mgd may be needed for waste dilution in the basin by year 2000. The present trends in suburban and light industrial development will probably persist in the basin. Problems arising through changes in economic value of water, conflicts in use, and alternatives in development are typical of those confronting the manager of a water-resource system.

Pennsylvania↗
USGS1968

Summary of floods in the United States during 1963

This report describes the most outstanding floods in the United States during 1963. The three most destructive floods occurred in March from Alabama to West Virginia and Ohio, in June in Nebraska, and in August in Buffalo, N.Y. Widespread disastrous floods struck the western slopes of the Appalachian Mountains from Alabama to West Virginia and Ohio as a result of three storms moving over the area during March 4-19. Precipitation during the first storm period, March 4-6, caused some major stream overflows and produced conditions favorable for high runoff from subsequent rainfall. Heavy rainfall on March 11-13 produced record-breaking floods on many streams in Tennessee, Kentucky, Virginia, and West Virginia. Noteworthy floods occurred in the bordering States of Alabama, Georgia, North Carolina, and Ohio. The third storm on If arch 16-19 was .significant because it prolonged the period of flooding and produced high-volume runoff in some areas. Twenty-six lives were lost, and more than 30,000 persons were forced from their homes. Damage to highways, railroads municipal and private property amounted to approximately \$98 million. Floods of June 24 in small basins in east-central Nebraska were the most severe known in the area. Discharges in many streams greatly exceeded the 50-year flood. Twenty-five cities and villages and more than 600 families suffered property loss. Three lives were lost. Property loss was about \$13 million. On July 29 the most severe rainstorm in 18 years occurred in western New York. On August 7, rains of near-record magnitude again fell over western New York, and record intensities were recorded in Buffalo for 1-, 2-, and 6-hour storms. The resulting floods on Scajaquada Creek were the highest recorded in a short period of record, and flood damage in Buffalo was estimated at \$35 million. In addition to the three floods mentioned above, 21 others of lesser magnitude are considered important enough to be included in this annual summary.

Water Supply Paper↗
USGS1966

Hydrology of Cornfield Wash area and effects of land-treatment practices, Sandoval County, New Mexico, 1951-60

The collection of runoff and sediment data was the primary objective of the 10-year (1951-60) study in the Cornfield Wash basin, which has an area of 21.3 square miles. However, reconnaissance investigations also were made of (1) precipitation; (2) the effects of reservoirs on runoff, erosion, and sediment yield; (3) the effects of range pitting on runoff, sediment, and vegetation yields; and (4) the effects of wire sediment barriers on sediment accumulations. Precipitation averaged 6.07 inches for the warm season (May 1 through October 31). From 1951 to 1955 much of the precipitation came in short torrential downpours. Since 1955, precipitation usually has been of lower intensity, resulting in a low runoff-precipitation ratio. The total composite inflow to the 19 reservoirs in the Cornfield Wash basin--12 constructed in 1950 and 7 constructed from 1953 to 1956--was 5,720 acre-feet. The reservoirs permanently retained 1,370 acre-feet of water, 43 percent of which was apparently lost by evaporation. The average seasonal runoff (1951-59) from the ephemeral streams of the Cornfield Wash basin and nearby watersheds can be expressed, with a high coefficient of correlation, by the equation: runoff = 29.4 (area) 0.82 acre-feet. This relation suggests that there is a good correlation between the size of the drainage basin and the basin characteristics that most influence travel time of runoff. Comparisons of readily measurable basin characteristics that influence travel time indicate: 1. Land slope is proportional to (area) .0.035; 2. Length of longest watercourse is proportional to (area) 0.52; 3. Distance along the longest watercourse from gaging station to a point opposite the center of drainage basin is proportional to (area)0.52; and 4. Equivalent channel slope is proportional to (area)- 0.027. Except for land slope, the coefficients of correlation for each of the basin characteristics-area relations were relatively high. The correlation between seasonal runoff (1951-60) from the small watersheds of the Cornfield Wash basin and the size of the drainage basin was improved after correcting for the influence of land slope. The original total storage capacity of the 19 reservoirs was reduced from 845 to 455 acre-feet as a result of the impoundment of 390 acre-feet of sediment. Backwater from the reservoirs influenced the deposition of an additional 20 acre-feet of sediment. The average annual accretion of sediment (1951-60) in the reservoirs of the Cornfield Wash basin can be expressed by the equation: sediment - 0.0119 (seasonal runoff) 1.3 (incised channel density) 0.71. By removing seasonal runoff as a variable, the average annual sediment accretion is proportional to (area) 1.19 (incised channel density) 1.3. Conservation and rehabilitation of damaged land were successful in some instances and only partly successful in others. The reservoirs are effective in inducing sediment accretion upstream; also, they stop the advance of abrupt headcuts below the reservoirs, but only as long as the spillage is not great and the spillway stays intact. In addition, the reservoirs are effective in reducing flood peaks. A longer period of study is necessary to define adequately the effectiveness of the wire sediment barriers. The data collected on range-pitting effects were not complete enough to. define the magnitude of the changes, if any, in runoff, sediment, and vegetation yields.

New Mexico↗
USGS1967

Hydrology of the Valley-fill and carbonate-rock reservoirs, Pahrump Valley, Nevada-California

This is the second appraisal of the water supply of Pahrump Valley, made 15 years after the first cooperative study. In the first report the average recharge was estimated to be 23,000 acre-feet per year, only 1,000 acre-feet more than the estimate made in this report. All this recharge was considered to be available for development. Because of the difficulty in salvaging the subsurface outflow from the deep carbonate-rock reservoir, this report concludes that the perennial yield may be only 25,000 acre-feet. In 1875, Bennetts and Manse Springs reportedly discharged a total of nearly 10,000 acre-feet of water from the valley-fill reservoir. After the construction of several flowing wells in 1910, the spring discharge began to decline. In the mid-1940's many irrigation wells were drilled, and large-capacity pumps were installed. During the 4-year period of this study (1959-62), the net pumping draft averaged about 25,000 acre-feet per year, or about twice the estimated yield. In 1962 Bennetts Spring was dry, and the discharge from Marse Spring was only 1,400 acre-feet. During the period February 1959-February 1962, pumping caused an estimated storage depletion of 45,000 acre-feet, or 15,000 acre-feet per year. If the overdraft is maintained, depletion of stored water will continue and pumping costs will increase. Water levels in the vicinity of the Pahrump, Manse, and Fowler Ranches declined more than ]0 feet in response to the pumping during this period, and they can be expected to continue to decline at ,the projected rate of more than 3 feet per year. The chemical quality of the pumped water has been satisfactory for irrigation and domestic use. Recycling of water pumped or irrigation, however, could result in deterioration of the water quality with time.

California, Nevada↗
USGS1967

Geology and ground-water resources of Laramie County, Wyoming

Laramie County, an area of 2,709 square miles, is in the southeast corner of Wyoming. Rocks exposed there range in age from Precambrian to Recent. The most extensive aquifers in the county are the White River Formation of Oligocene age, which is as much as 500 feet thick and consists predominantly of siltstone ; the Arikaree Formation of Miocene age, which consists of as much as 450 feet of very fine grained to fine-grained sandstone; and the Ogallala Formation of Miocene and Pliocene age, which consists ,of as much as 330 feet of gravel, sand, silt, and some cobbles and boulders. These formations are capable of yielding large ,supplies of water locally. Terrace deposits of Quaternary age yield moderate .to large supplies of water in the southeastern and northeastern parts of the county. In the Federal well field, large yields of water from the White River Formation are obtained from gravel lenses. In the eastern part of the county near Pine Bluffs, large yields are obtained from openings in .the siltstone of the White River. Previous investigators reported that the large yields were obtained in areas where the formation is fractured and fissured. The authors of this report believe that .the large yields from siltstone in the White River Formation are from pipes, sometimes called natural tunnels, rather than from fractures ,or fissures. Little is known about the water-bearing properties of the pro-Tertiary aquifers in the county, but water derived from the pro-Tertiary formations would probably be of poor quality, except in the vicinity of the outcrop near the western edge of the county. Precipitation is the principal source of recharge to the ground-water reservoirs. About 5 percent of the annual precipitation, or about 108,400 acre-feet per year, is estimated to be recharged. Only a small amount of additional recharge is from streams. The general movement of ground water is eastward, and the average gradient of the water table is about 40 feet per mile. The total amount ,of ground water pumped from wells in Laramie County during 1964 is estimated to be 28,000 acre-feet; about 6,000 acre-feet was used for municipal and industrial supplies, about 17,000 acre-feet was used for irrigation in the Pine Bluffs-Carpenter area, and about 5,000 acre-feet was used for other purposes. The balance of the recharge (80,400 acre-feet) is estimated to be discharged by the following means: 20 percent by underflow, 20 percent by streamflow, and 60 percent by evapotranspiration. The coefficient of transmissibility of the Ogallala Formation, determined by averaging data from 28 pumping tests made in the Cheyenne municipal well field, is about 16,000 gallons per day per foot. However, this figure is an average of the more permeable zones, and the average coefficient of transmissibility of the Ogallala in the county is probably much less because of the heterogeneous character of the formation. A coefficient of transmissibility of 3,800 gallons per day per foot was calculated for the Ogallala, in the same vicinity that the pumping tests were made, by using a regional method of analysis. Although the average transmissibility of the Ogallala is considered to be low, large yields are obtained from gravel stringers and lenses in the formation. The maximum perennial yield from the Cheyenne well field is estimated to be about 1.6 billion gallons per year. Moderate to large yields of water can be obtained in the north-central part of the county where the saturated thickness of the Arikaree Formation, or combined Arikaree and Ogallala Formations, is 200 feet or more. Ground water has been developed throughout the county, but development has been intensive only in the Cheyenne municipal well fields near Cheyenne and Federal and in the Pine Bluffs lowland. The water level has been lowered as much as 40 feet in the Cheyenne well field and somewhat less in the Federal well field.

Wyoming↗
USGS1967

Chemical quality of surface water in the Allegheny River basin, Pennsylvania and New York

The Allegheny River is the principal source of water to many industries and to communities in the upper Ohio River Valley. The river and its many tributaries pass through 19 counties in northwestern and western Pennsylvania. The population in these counties exceeds 3 million. A major user of the Allegheny River is the city of Pittsburgh, which has a population greater than The Allegheny River is as basic to the economy of the upper Ohio River Valley in western Pennsylvania as are the rich deposits of bituminous coal, gas, and oil that underlie the drainage basin. During the past 5 years many streams that flow into the Allegheny have been low flowing because of droughts affecting much of the eastern United States. Consequently, the concentration of solutes in some streams has been unusually high because of wastes from coal mines and oil wells. These and other water-quality problems in the Allegheny River drainage basin are affecting the economic future of some areas in western Pennsylvania. Because of environmental factors such as climate, geology, and land and water uses, surface-water quality varies considerably throughout the river basin. The natural quality of headwater streams, for example, is affected by saltwater wastes from petroleum production. One of the streams most affected is Kinzua Creek, which had 2,900 parts per million chloride in a sample taken at Westline on September 2, 1959. However, after such streams as the Conewango, Brokenstraw, Tionesta, Oil, and French Creeks merge with the Allegheny River, the dissolved-solids and chloride concentrations are reduced by dilution. Central segments of the main river receive water from the Clarion River, Redbank, Mahoning, and Crooked Creeks after they have crossed the coal fields of west-central Pennsylvania. At times, therefore, these streams carry coal-mine wastes that are acidic. The Kiskiminetas River, which crosses these coal fields, discharged sulfuric acid into the Allegheny at a rate of 299 tons a day during the 1962 water year (October 1, 1961, to September 30, 1962). Mine water affects the quality of the Allegheny River most noticeably in its lower part where large withdrawals are made by the Pittsburgh Water Company at Aspinwall and the Wilkinsburg-Penn Joint Water Authority at Nadine. At these places raw river water is chemically .treated in modern treatment plants to control such objectionable characteristics as acidity and excessive concentrations of iron and manganese. Dissolved-solids content in the river varies along its entire length. In its upper reaches the water of the Allegheny River is a sodium chloride type, and at low flow, the sodium chloride is more than half the dissolved solids. In its lower reaches the water is a calcium sulfate .type, and at low flow the calcium sulfate is more than half the dissolved solids. In middle segments of the river from Franklin to Kittanning, water is more dilute and of a mixed type. Many small and several larger streams in the upper basin--such as the Conewango, Brokenstraw, Kinzua, Tionesta, and French Creeks--support large populations of game-fish. Even in segments of the Clarion River, Mahoning, and Redbank Creeks, which are at times affected by coal-mine wastes, fish are present. Although different species withstand varying amounts of contaminants in water, the continued presence of the fish indicates that the water is relatively pure and suitable for recreation and many other uses.

Water Supply Paper↗
USGS1967

Ground-water conditions and geologic reconnaissance of the Upper Sevier River basin, Utah

The upper Sevier River basin is in south-central Utah and includes an area of about 2,400 .square miles of high plateaus and valleys. It comprises the entire Sevier River drainage basin above Kingston, including the East Fork Sevier River and its tributaries. The basin was investigated to determine general ground-water conditions, the interrelation of ground water and surface water, the effects of increasing the pumping of ground water, and the amount of ground water in storage. The basin includes four main valleys - Panguitch Valley, Circle Valley, East Fork Valley, and Grass Valley - which are drained by the Sevier River, the East Fork Sevier River, and Otter Creek. The plateaus surrounding the valleys consist of sedimentary and igneous rocks that range in age from Triassic to Quaternary. The valley fill, which is predominantly alluvial gravel, sand, silt, and clay, has a maximum thickness of more than 800 feet. The four main valleys constitute separate ground-water basins. East Fork Valley basin is divided into Emery Valley, Johns Valley, and Antimony subbasins, and Grass Valley basin is divided into Koosharem and Angle subbasins. Ground water occurs under both artesian and water-table conditions in all the basins and subbasins except Johns Valley, Emery Valley, and Angle subbasins, where water is only under water-table conditions. The water is under artesian pressure in beds of gravel and sand confined by overlying beds of silt and clay in the downstream parts of Panguitch Valley basin, Circle Valley basin, and Antimony subbasin, and in most of Koosharem subbasin. Along the sides and upstream ends of these basins, water is usually under water-table conditions. About 1 million acre-feet of ground water that is readily available to wells is stored in the gravel and sand of the upper 200 feet of saturated valley fill. About 570,000 acre-feet is stored in Panguitch Valley basin, about 210,000 in Circle Valley basin, about 6,000 in Emery Valley subbasin, about 90,000 in Johns Valley subbasin, about 36,000 in Antimony subbasin, about 90,000 in Koosharem subbasin, and about 60,000 in Angle subbasin. Additional water, although it is not readily available to wells, is stored in beds of silt and clay. Some ground water also is available in the bedrock underlying and surrounding the basins, although the bedrock formations generally are poor aquifers. The principal source of recharge to the valley fill in the upper Sevier River basin is infiltration from streams, canals, and irrigated fields. Some ground water also miles into the valley till from the bedrock surrounding the basins. The basin contains about 300 wells, most of which are less than 4 inches in diameter, are less than 250 feet deep, and are used for domestic purposes and stock watering. More than half the wells are flowing wells in Koosharem subbasin. Approximately 82,000 acre-feet of ground water was discharged in 1962 from the valley till. Springs discharged about 33,000 acre-feet, wells about 3,000, and drains about 3,000; and evapotranspiration from phreatophyte areas about 43,000 acre-feet. Springs in bedrock discharged an additional 75,000 acre-feet. Most of the water discharged by springs, wells, and drains was used for irrigation. The ground water in the basin generally is of good chemical quality. The water is excellent for irrigation and stock but is not as desirable for most domestic and industrial uses because of its hardness. The dissolved-solids content of the ground water generally increases slightly from the upstream end of the individual ground-water basins to. the downstream end owing mostly to repeated use of the water for irrigation. Surface water and ground water in the upper Sevier River basin are inter- connected, and the base flows of streams are affected by changes in ground- water levels. Increased pumping of ground water would result in (1) an increase in the recharge to the aquifers from surface-water sources or (2) a decrease in the discharge from streams, springs, flowing wells, and areas of phreatophytes or (3) a combination of these. About 43,000 acre-feet of ground water is now discharged annually by evapotranspiration from phreatophyte areas, and perhaps one-third of this loss, or about 14,000 acre-feet, could be salvaged by eliminating wet areas and phreatophytes. The areas where water could be salvaged are at the downstream ends of Panguitch Valley basin, Circle Valley basin, and Antimony subbasin. Most of the 14,000 acre-feet 'of water could be pumped from large-diameter wells or developed by properly designed drains without greatly affecting stream- flow and with only moderate effect on 'spring discharge. If the wells were properly located, the pumping would lower water levels and dry up wet areas where phreatophytes grow. Conjunctive use of ground water and surface water would facilitate the more efficient use of all water resources in the basin

Utah↗
USGS1966

Hydrology of the cavernous limestones of the Mammoth Cave area, Kentucky

The Mammoth Cave National Park in central Kentucky offers a unique opportunity to study the occurrence of ground water in limestone under natural conditions. Ground water occurs as perched and semiperched bodies in alternate sandstone, shale, and limestone formations and under water-table conditions at the approximate level of the Green River in thick soluble limestone. Three continuous recorders that operated for 5 years indicate that precipitation on the Mammoth Cave plateau recharges the underlying sandstone rapidly. Ground water from the sandstone discharges horizontally to the edges of the plateau and vertically to underlying formations. Some of the precipitation recharges underlying formations almost immediately through overland flow to sinkholes and free fall through open shafts to pools at the water table. Much of the precipitation on the Pennyroyal plain flows overland into sinkholes and then through solution openings to the Green River. Water from the Green River flows into limestone solution channels under Mammoth Cave plateau at some stages, and this water discharges again to the Green River downstream. The presence of salt water, high in chloride in the Green River, makes it possible to trace the movement of the river water through the underground streams. Graphs show relationships of chloride concentration, stage of the Green River, time, precipitation, ground-water levels, and stratigraphy.

Water Supply Paper↗
USGS1967

Reconnaissance of the chemical quality of surface waters of the Neches River basin, Texas

The kinds and quantities of minerals dissolved in the surface water of the Neches River basin result from such environmental factors as geology, streamflow patterns and characteristics, and industrial influences. As a result of high rainfall in the basin, much of the readily soluble material has been leached from the surface rocks and soils. Consequently, the water in the streams is usually low in concentrations of dissolved minerals and meets the U.S. Public Health Service drinking-water standards. In most streams the concentration of dissolved solids is less than 250 ppm (parts per million). The Neches River drains an area of about 10,000 square miles in eastern Texas. From its source in southeast Van Zandt County the river flows in a general southeasterly direction and empties into Sabine Lake, an arm of the Gulf of Mexico. In the basin the climate ranges from moist subhumid to humid, and the average annual rainfall ranges from 46 inches is the northwest to more than 52 inches in the southeast. Annual runoff from the basin has averaged 11 inches; however, runoff rates vary widely from year to year. The yearly mean discharge of the Neches River at Evadale has ranged from 994 to 12,720 cubic feet per second. The rocks exposed in the Neches River basin are of the Quaternary and Tertiary Systems and range in age from Eocene to Recent. Throughout most of the basin the geologic formations dip generally south and southeast toward the gulf coast. The rate of dip is greater than that of the land surface; and as a result, the older formations crop out to the north of the younger formations. Water from the outcrop areas of the Wilcox Group and from the older formations of the Claiborne Group generally has dissolved-solids concentrations ranging from 100 to 250 ppm; water from the younger formations has concentrations less than 100 ppm. The northern half of the basin has soft water, with less than 60 ppm hardness. The southern half of .the basin has very soft water, usually with less than 30 ppm hardness. The chloride concentrations are less than 20 ppm in surface water in the southern half of the basin and usually range from 20 to 100 ppm in the northern half of the basin. Concentrations greater than 100 ppm are found only where pollution is occurring. The Neches River basin has an abundance of surface water, but uneven distribution of runoff makes storage projects necessary to provide dependable water supplies. The principal existing reservoirs, with the exception of Striker Creek Reservoir, contain water of excellent quality. Chemical-quality data for the Striker Creek drainage area indicate that its streams are affected by .the disposal of brines associated with oil production. Sam Rayburn Reservoir began impounding water in 1965. The water impounded should prove of acceptable quality for most uses, but municipal and industrial wastes released into the Angelina River near Lufkin may have a degrading effect on the quality of the water, especially during extended periods of low flows. Water available for storage at the many potential reservoir sites will be of good quality; but, if the proposed salt-water barrier is to impound acceptable water, the disposal of oilfield brine into Pine Island Bayou should be discontinued.

Water Supply Paper↗