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Hydrogeology of stratified drift in Farmington, Connecticut: Available data and future needs

The purpose of this report is twofold. The first is to update hydrogeologic information on the major stratified-drift deposits that underlie much of Farmington. The second is to outline data requirements for future ground-water evaluation and management. The scope of the report is limited to the stratified drift, as it is the only aquifer capable of sustaining large withdrawals for public or industrial supply. This aquifer is composed of interbedded layers of gravel, sand, silt and clay. Most of this material was deposited by glacial meltwaters, but locally the aquifer contains some unconsolidated deposits of nonglacial origin. The most extensive stratified-drift deposits are in the valleys of the Farmington and Pequabuck Rivers.(See plate B.) A few small areas of stratified drift near East Farmington Heights and Oakland Gardens are not discussed in this report as their potential for large-scale development is slight.

Connecticut

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas

Field-trip guide to Mount Hood, Oregon, highlighting eruptive history and hazards

This guidebook describes stops of interest for a geological field trip around Mount Hood volcano. It was developed for the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon. The intent of this guidebook and accompanying contributions is to provide an overview of Mount Hood, including its chief geologic processes, magmatic system, eruptive history, local tectonics, and hazards, by visiting a variety of readily accessible localities. We also describe coeval, largely monogenetic, volcanoes in the region. Accompanying the field-trip guidebook are separately authored contributions that discuss in detail the Mount Hood magmatic system and its products and behavior (Kent and Koleszar, this volume); Mount Hood earthquakes and their relation to regional tectonics and the volcanic system (Thelen and Moran, this volume); and young surface faults cutting the broader Mount Hood area whose extent has come to light after acquisition of regional light detection and ranging coverage (Madin and others, this volume). The trip makes an approximately 175-mile (280-kilometer) clockwise loop around Mount Hood, starting and ending in Portland. The route heads east on Interstate 84 through the Columbia River Gorge National Scenic Area. The guidebook points out only a few conspicuous features of note in the gorge, but many other guides to the gorge are available. The route continues south on the Mount Hood National Scenic Byway on Oregon Route 35 following Hood River, and returns to Portland on U.S. Highway 26 following Sandy River. The route traverses rocks as old as the early Miocene Eagle Creek Formation and overlying Columbia River Basalt Group of middle Miocene age, but chiefly lava flows and clastic products of arc volcanism of late Miocene to Holocene age.

Oregon

Tectonic controls on volcanism and associated hydrothermal activity in a sediment-dominated mid-ocean ridge; Escanaba Trough

Mid-ocean ridges, the Earth's most extensive volcanic system, exhibit unique characteristics in sediment-dominant environments. Thick sediment cover insulates the crust and channels fluid along pathways that can lead to the formation of distinct crustal alteration patterns, exceptionally large mineral deposits, and specialized chemosynthetic ecosystems. This study presents an interdisciplinary investigation into the tectonics of the Escanaba Trough, a heavily sedimented axial valley at the southern Gorda Ridge in the Northeast Pacific Ocean. A primary challenge in such environments is overcoming the masking effect of thick sediments on basement structures that control magmatic and hydrothermal activity. We address this by employing three-dimensional (3D) magnetic modeling of high-resolution near-seafloor magnetic data collected by an autonomous underwater vehicle (AUV). The 2022 surveys with AUV Sentry provided data for 3D magnetic susceptibility models, refining our understanding of the geometry of sub-sediment laccoliths/saucer-shaped sills and hydrothermal alteration. In conjunction with a new 1:100,000 scale lithostratigraphic map, we outline the tectonic controls on the emplacement of Escanaba Trough's three main volcanic centers, characterize the geometry of its spreading segments, and provide volumetric data on the distribution of sub-sediment volcanism in the southern Gorda Ridge.

Escanaba Trough, Pacific Ocean

U.S. Geological Survey Groundwater Climate Response Network, 2024

As of October 2024, the U.S. Geological Survey (USGS) operated 588 sites across the United States and its territories as part of the Groundwater Climate Response Network (CRN). The CRN is comprised of wells selected to monitor the effects of climate variability, such as droughts, on groundwater levels nationwide. The CRN includes nearly 500 locations with real-time data and more than 100 sites with non-real-time data available to the public on the CRN web mapper and the USGS National Water Dashboard.

General Information Product

Estimating the probability of export restrictions to inform mineral criticality

To assess risks associated with advanced technologies’ supply chain disruptions, governmental agencies and others have developed mineral “criticality” assessments, with criticality described using the economic impact and probability of supply chain disruptions. Previous work developed subjective supply risk indicators to approximate this probability, typically combining several factors such as supply diversity and trading partners’ political stability, where indicator weightings can substantially impact results. This work explicitly quantifies export barrier probability using an ensemble of machine learning classifiers, with probability estimates informed by exogenous variables, including prior barrier implementation and global export dominance. Major differences in high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. The Supplementary Data File provides export barrier probability estimates for each analyzed country-commodity pair, enabling a direct, quantitative, objective contribution to assessing mineral criticality, enhancing risk identification and prioritization for policymakers.

Resources, Conservation, and Recycling

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

AAPG Wiki

Summary of results from electromagnetic and galvanic soundings on Kilauea Iki lava lake, Hawaii

The purpose of this report is to summarize various electrical sounding studies made on the Kilauea Iki lava lake and to present some of the preliminary interpretations that resulted from the measurements. The following discussion is not intended as a complete interpretation, but is intended to summarize the major points made in an invited oral presentation at the American Geophysical Union fall meeting held in San Francisco, Calif. on December 6, 1976. This paper was part of a group of papers dealing with various geophysical studies recently made on the Kilauea Iki lava lake. A general plan map of Kilauea Iki lava lake is shown in figure 1. Electromagnetic (EM) loop-loop soundings, D.C. resistivity soundings, and VLF apparent resistivity measurements were made on the lave lake surface. All of these surveys were made to determine the geoelectric structure of the lava lake and to determine parameters of the molten basaltic lens that exist in the partially solidified lava lake.

Hawaii

Geophysical modeling of a possible blind geothermal system near Battle Mountain, NV

The northeastern portion of the Reese River basin in north-central Nevada is the focus of detailed geophysical and geological studies as part of the INGENIOUS project, which aims to identify new, commercially viable hidden geothermal systems in the Great Basin region of the western U.S. This location, herein referred to as Argenta Rise, occupies a broad (~15km wide) left-step between major range-front fault systems along the northwestern edge of the Shoshone Range and Argenta Rim, with numerous ENE-striking intra-basin faults presumably accommodating sinistral-normal oblique slip across the step-over. Four discrete regions have been identified within the study area that have favorable structural settings for hosting a blind hydrothermal system. However, with no definitive or extensive surface manifestations of an active hydrothermal system (e.g., geysers, steam vents, sinter, etc.), detailed geophysical studies are necessary to resolve subsurface geology and structure, and identify zones of enhanced structural complexity that may promote hydrothermal fluid flow. Hence, we collected high-resolution gravity, MT, and rock property data (density, magnetic susceptibility), and analyzed the recently acquired GeoDAWN aeromagnetic data to characterize potential geothermal resources in this region. Using the new geophysical datasets, we jointly modeled gravity and magnetic data along a series of intersecting 2D profiles that integrated information from recent, local-scale fault mapping. Rock property measurements performed on outcrops and hand samples throughout the study area constrained the models. The MT data were used to construct a 3D resistivity model that highlights the location of inferred alteration and fluids in the subsurface. Combined MT and potential field results reveal which structures may be most important for controlling hydrothermal fluid migration, as well as which geologic units may host hydrothermal fluids. Our gravity derived depth to basement surface coincides well with the base of shallow conductive anomalies, suggesting hydrothermal fluids may be confined to basin fill sediments and volcanics. This work supports our development of 3D geophysical and geologic models that are focused along the western flank of the northern Shoshone Range and aids the process of selecting sites for temperature gradient drilling.

Nevada

Estimating the probability of export restrictions to inform mineral criticality

As demand for advanced technologies rises, mineral commodities will increase in geopolitical importance. To assess risks associated with mineral commodity supply chain disruptions, governmental agencies and others have developed "criticality" assessments, with criticality described using the economic impact and probability of supply chain disruptions. In previous work, subjective supply risk indicators were developed to approximate this probability, typically combining several factors such as supply diversity and political stability of trading partners, where indicator weightings can substantially impact results. This work explicitly quantifies trade barrier probability using an ensemble of several machine learning classifiers, with probability estimates informed by exogenous variables such as prior trade barrier implementation and global export dominance. Major differences in the high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. This approach enables a direct, quantitative, objective approach to assessing trade barrier probability, enhancing risk identification and prioritization for policymakers.

SSRN

A geographic dataset of rocky reefs habitat areas of particular concern for the United States West Coast

The United States National Marine Fisheries Service determines “essential fish habitat (EFH)” for federally managed species in coordination with regional fishery management councils, considers adverse effects to those habitats, and provides information to further habitat conservation and enhancement. Identifying discrete subsets of EFH as “habitat areas of particular concern (HAPC)” can help focus conservation, management, and research efforts. In 2006, the Pacific Fishery Management Council designated rocky reefs along the United States (U.S.) West Coast as HAPCs for groundfishes because of their ecological significance, sensitivity to human impacts, and relative rarity. To better understand where rocky reefs occur, we (1) located rocky reef areas that were not included in the 2006 rocky reef dataset, and (2) incorporated best available data into a refined geographic dataset that enables visualization. Our update shows that rocky reefs are distributed throughout the U.S. West Coast continental margin, are patchier than previously known, and comprise 8% of the extent of all data inputs. This updated dataset will inform resource management decisions in coastal and marine environments.

California, Oregon, Washington

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research

Tectonic implications of transitional melting regimes from petrological, geochronological, and compositional characterization of the ophiolitic Seventymile terrane, Alaska, USA

New geochemical, U-Pb geochronology, and Sr-Nd-Hf isotope data provide evidence for the tectonic evolution of the Seventymile terrane in interior Alaska, USA. Ultramafic and mafic rocks of the Seventymile terrane are thought to represent components of a dismembered ophiolite and provide unique constraints on regional terrane evolution and accretion. The Seventymile ophiolite represents fragments of the Devonian to Permian Slide Mountain Ocean (SMO) that separated allochthonous and parautochthonous continental fragments of western North America. It now occurs as multiple thrust sheets containing Permian mafic and ultramafic rocks overlying and/or possibly imbricated with amphibolite-facies supracrustal rocks of allochthonous Yukon-Tanana terrane and parautochthonous North America. Seventymile klippen contain variably serpentinized peridotite, primarily harzburgite, low-grade meta-mafic rocks, and minor oceanic sedimentary rocks (argillite, chert, limestone, and metasandstone). Mafic rocks include gabbro to diabase, typically as dikes, veinlets, or rare massive stocks intruding peridotite. Mafic rocks also include greenstones of the Seventymile assemblage in klippen structurally underlying, and in shear zone contact with, ultramafic klippen. New trace element and radiogenic isotope data from mafic magmatic rocks associated with the Seventymile ultramafic bodies show evidence for a weakly subduction-modified mantle source, like the mantle source of normal mid-ocean-ridge basalt (N-MORB) or back-arc basin basalt (BABB). Seventymile assemblage greenstones are more heterogeneous. They range from N-MORB to enriched mid-ocean-ridge basalt (E-MORB) and ocean-island basalt (OIB), with a subset of samples indicative of continental arc affinity. These geochemistry results indicate that distinct tectonic environments are represented by at least two, and possibly three, lithological and structural units comprising the Seventymile terrane. Hf-Nd isotope systematics are consistent with a depleted MORB mantle (DMM)−like component that overlaps with Pacific MORB. Primary zircon is rare, but new in situ U-Pb data for gabbro and greenstone indicate ca. 274−272 Ma peak zircon and titanite crystallization. Scattered younger zircons define a ca. 255 Ma zircon peak and correspond to secondary crystallization associated with baddeleyite reaction of high-Si fluids during low-grade metamorphism. If Seventymile suites are contemporaneous, obduction associated with the closure of the SMO resulted in the stacking of ophiolitic packages representing distinct tectonomagmatic settings across the transition from pericontinental, to epicontinental, to distal ocean back-arc. Intrusions hosted in klippe of ultramafic rocks, plus the least subduction-modified greenstones underlying them, geologically and compositionally resemble Slide Mountain rocks of the Campbell Range formation in eastern Yukon and may provide a new piercing point across the Tintina fault.

Alaska, British Columbia

Earthquake-hazard exposure of residents with potential access and functional needs in the United States

Earthquake response plans and earthquake early warning (EEW) systems designed for general populations may not consider potential access and functional needs (AFN) of individuals with physical, sensory, cognitive, or social limitations. Previous efforts to map the distribution of these populations have focused on social-vulnerability indices that ignore or oversimply these limitations. The descriptive and exploratory analysis summarized in this United States (U.S.) case study addresses this gap by identifying and integrating spatially explicit data for AFN-related residential populations, earthquake hazards, and county and county equivalents for the conterminous U.S., Alaska, Puerto Rico, and Hawaii. We focus on 13 AFN-related attributes that relate to an individual's ability to access information contained in an EEW alert, to understand and process earthquake information or observed ground shaking, and to take self-protective actions based on this information and physical cues of an earthquake. Depending on the demographic attribute, there are millions to tens of millions of U.S. residents with AFN-related attributes in areas considered to have varying likelihoods (2%, 10%, and 50%) of exceedance of a damaging earthquake in the next 50 years. Although these amounts represent low percentages at the national level, the percentage of individuals with AFN-related attributes in many counties and county equivalents substantially exceeds national percentages. No one county, county equivalent, U.S. state, or U.S. territory has the highest percentage of individuals in all AFN-related attributes; therefore, future efforts to increase individual resilience to earthquakes may benefit from understanding the local context of individuals with potential access and functional needs.

International Journal of Disaster Risk Reduction

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho

Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S

Mineral chemistry perspective on remobilization of stored magma at Kamakai'a Hills, Southwest Rift Zone of Kilauea, Island of Hawai'i, USA

Differentiated magmas stored in the rift zones of Kīlauea have received more attention in recent years following eruption of andesite during the early phase of 2018 lower East Rift Zone activity. Despite this growing interest, some of the most voluminous eruptions of differentiated rift zone magmas remain poorly studied. One such eruption, and the most voluminous exposed differentiated flow field at Kīlauea, is the Kamakaiʻa Hills. This eruption took place in the Southwest Rift Zone of Kīlauea, a region that is hypothesized to contain a long-lived rift zone reservoir. The Kamakaiʻa Hills flow field encompasses >250 × 10 6 m 3 of basaltic andesite and basalt compositions with a mineral assemblage of orthopyroxene + clinopyroxene + plagioclase during its early ʻaʻā phase and clinopyroxene + plagioclase + olivine during its late pāhoehoe phase. To better understand storage conditions and magma accumulation, this study focuses on major, minor, and trace elements from the mineral assemblage present within the early ʻaʻā and late pāhoehoe phases. The diversity of clinopyroxene and plagioclase compositions within the early ʻaʻā and late pāhoehoe phases, as well as diverse compositions of plagioclase and orthopyroxene within the early ʻaʻā phase, suggest multiple magma bodies and limited pre-eruption magma mixing within the broader Kamakaiʻa Hills reservoir. Oscillatory zoning patterns (particularly in clinopyroxene) imply processes such as recharge events, magma mixing or mingling, or convection within a differentially cooling, chemically stratified reservoir over protracted time intervals, whereas only limited resorbed mineral textures indicate incomplete mixing of heat and chemically distinct magmas during the dike intrusion that triggered the eruption. Mineral-mineral and mineral-melt thermobarometry indicate predominantly shallow (≤2.5 km depth) crustal storage conditions of the cooled, differentiated magma (∼1100 °C and cooler for the basaltic andesites) to hotter temperatures for the basalts (all >1100 °C). Despite the known large standard errors estimated for mineral-melt and mineral-mineral barometry (10s to >100 MPa), the calculated pressures and depths broadly correspond with earthquake swarm depths beneath the Kamakaiʻa Hills, and drill core and fluid inclusion barometry storage depths of differentiated magmas within the lower East Rift Zone. The Kamakaiʻa Hills differentiated magmas have H 2 O contents (∼0.5 wt%, using plagioclase-melt hygrometry) equivalent to typical Kīlauea basalts. Our data and interpretations demonstrate a complex, long-lived rift zone storage system that consisted of multiple magma bodies and was mobilized into eruption through intrusion of a hotter and more primitive summit-derived (uprift) magma.

Hawaii